辽东硼矿床矿石的稀土元素特征及其地质意义

辽东硼矿床赋存于辽东古元古代的镁质火山-沉积地层中.矿石与含矿岩系具密切的交代继承关系：（1）矿石与含矿镁质岩石具交代继承的矿物组成、结构构造;（2）矿石的稀土元素特征主要受含矿岩系岩石的控制,在混合岩化弱的含矿岩系中,矿石的稀土元素特征与含矿镁质岩石相似,而在混合岩化强的含矿岩系中的矿石与混合岩的稀土元素特征相近;（3）辽东的硼矿床的形成是在混合岩作用过程中形成的含硼成矿流体交代镁质岩石的结果.     

中国镁质碳酸盐岩型温石棉矿床的成矿规律

镁质碳酸盐岩型温石棉矿床是成矿热液交代镁质碳酸盐岩生成的,一般均产于地台环境。按地台稳定性不同,成矿环境分为地台隆起区的基底建造类型和地台拗陷区的盖层建造类型。产于地台隆起区的矿床,以前震旦纪镁质碳酸盐岩为控矿层位。产于太古代及早、中元古代深变质结晶基底中的矿床,由区域变质及混合岩化过程中的变质热液交代碳酸盐岩成矿。产于晚元古代浅变质褶皱基底(扬子准地台)中的矿床,以岩浆期后热液或接触交代(湿矽卡岩)热液为成矿热液来源。产于地台拗陷区的矿床,均以震旦纪镁质碳酸盐岩为控矿层位。其成矿时期较晚,一般与拗陷区内岩浆活动同期,由岩浆期后热液或接触交代(湿矽卡岩)热液对镁质碳酸盐岩进行交代成矿。     

部分熔融与高级变质岩流变机制——以内蒙古大青山高级变质岩为例

部分熔融作用与高级变质岩变形作用是相互制约,变形作用能够提高岩石部分熔融程度,降低熔融温度。熔体存在影响和制约岩石强度和变形机制。大青山高级岩经历了下部地壳构造层次变质变形和深熔作用改造,形成了复杂构造要素组合。宏观与微观构造特点表明:高级变质岩变形机制主要为熔体增强颗粒边界扩散和颗粒流动,使岩石发生大规模的塑性流动。在宏观上形成了不对称流动组构、熔融线理、岩石和矿物条带、层内底辟褶皱和大型穹窿构造。但是,在微观上矿物颗粒变形不明显,晶内变形组构不发育,表现为三边平衡结构,与静态结晶变质岩结构相似,形成了地壳深部构造层次上变质构造岩-构造片麻岩。     

辽东-吉南硼矿的控矿因素及成矿作用研究

文章从区域成矿理论出发,分析了含硼岩系、镁质容矿岩石、区域变质及混合岩化热液交代作用、构造控制和改造等4大控矿因素在成矿过程中的作用。研究表明,含硼岩系、镁质容矿岩石是硼矿形成的物质基础,区域变质及混合岩化作用、构造改造活动是硼矿形成的必要条件;辽东-吉南硼矿的成矿作用为原始火山-沉积初始富集和部分熔融含硼热液交代镁质岩石的成矿作用过程。     

辽东硼矿的成矿机制及成矿模式

为了解辽东硼矿的成矿机制及建立成矿模式, 分析了含硼岩系、镁质容矿岩石、区域变质作用及混合岩化作用、构造等四大控矿因素, 发现含硼岩系具富硼特征, 容矿岩石具富镁特点并可成为硼质的沉淀剂, 含硼岩系中硼在区域变质和混合岩化过程中得到进一步活化形成含硼热液, 含硼热液在有利的构造空间交代镁质岩石即可形成镁硼酸盐型硼矿.含硼岩系、镁质容矿岩石是硼矿形成的物质基础, 区域变质及混合岩化作用、构造活动是硼矿形成的必要条件.辽东硼矿成矿模式为原始火山-沉积初始富集和部分熔融含硼热液交代镁质岩石.      

柴北缘夹榴辉岩的片麻岩（片岩）地球化学、Sm-Nd和U-Pb同位素研究——深俯冲的前寒武纪变质基底？

在柴北缘的鱼卡-锡铁山-沙柳河一带,出露夹有榴辉岩透镜体的花岗质片麻岩(正片麻岩)和副片麻岩(片岩)。地球化学和Sm-Nd同位素数据显示副片麻岩(片岩)与正片麻岩具有类似的地球化学成分和一致的Nd模式年龄(1.88～2.18Ga),结合副片麻岩(片岩)局部包在正片麻岩中的野外关系,正片麻岩可能为副片麻岩(片岩)原地熔融作用的产物。U-Pb锆石测定表明熔融作用产生的正片麻岩的岩浆形成时代为952Ma。另外,这些夹榴辉岩的片麻岩(片岩)也与柴北缘北侧不夹榴辉岩的深变质基底片麻岩和中南祁连地块的变质基底片麻岩有相似Sm-Nd同位素特征和近一致Nd模式年龄(1.87～2.26Ga)。表明它们具有明显的亲缘关系,可能来源于具有古元古代晚期地壳形成年龄的同一变质基底。然而,与柴北缘北 侧和祁连地块的深变质基底岩石不同的是,这套含榴辉岩的片麻岩(片岩)明显遭受了早古生代变质作用的影响,正片麻岩锆石U-Pb测定获得的下交点年龄为478±44Ma,与柴北缘地区榴辉岩的变质锆石的年龄在误差范围内一致;而已在都兰地区副片麻岩锆石中柯石英包体的发现也证明了含榴辉岩的片麻岩(片岩)与榴辉岩一样同样经历了UHP变质作用。因此,我们认为柴北缘含榴辉岩的片麻岩虽然具有与相邻变质基底相似的早期演化历史,但在早古生代又与所夹的榴辉岩     

"罗田穹隆"中的下地壳俯冲成因榴辉岩及其地质意义

在“罗田穹隆”中发现了下地壳俯冲成因榴辉岩．榴辉岩呈透镜状或板状产于含石榴子石条带状片麻岩中．新鲜的榴辉岩主要由石榴子石、绿辉石、金红石等组成．含少量退变质的角闪石、斜长石、紫苏辉石、透辉石、(钛)磁铁矿和石英等．研究区榴辉岩以保留早期麻粒岩相变质矿物残留体以及经受晚期麻粒岩相和角闪岩相退变为特征．指示它们由扬子镁铁质下地壳麻粒岩相岩石俯冲到深部发生变质并形成榴辉岩．然后折返至下地壳发生麻粒岩相退变，由于麻粒岩相退变质阶段仅以后成合晶形式出现．因而它们可能在下地壳停留时间不长．就又进一步被构造抬升至中上地壳而发生角闪岩相退变．大别山造山带乃至扬子板块北缘现今缺乏厚层镁铁质下地壳．它们也很少出露地表．推测这些俯冲的镁铁质下地壳可能已拆离再循环进人地幔．从而为“罗田穹隆”的形成和演化以及大别山高压-超高压岩石的形成与折返机制等研究提供了关键性的岩石学证据。     

哀牢山构造带晚渐新世地壳深熔与熔/流体迁移:锆石U-Pb年龄与微量元素证据

哀牢山构造带是青藏高原东南缘重要的边界构造带,其内出露的深变质岩系一直被认为是古老的变质基底岩石。利用LA-ICP-MS原位微区分析技术对哀牢山深变质岩系锆石进行U-Pb年龄、微量元素分析。结果表明深变质岩系的原岩有728±8Ma、727±3Ma、231±4Ma的花岗质岩石和其它年龄的碎屑岩,变质时代为27.8~23.7Ma。综合野外地质特征和分析结果,我们认为哀牢山深构造带在晚渐新世27.8~23.7Ma发生了大规模的地壳深熔作用,现今所见深变质岩系是由不同时代、不同岩性的原岩在晚渐新世(27.8~23.7Ma)变质形成,不全是古老的变质基底岩石。深熔过程中熔/流体发生了明显的迁移。哀牢山变质带具有混合岩化特征的岩石很可能是峰期变质作用后减压熔融的产物。晚渐新世地壳深熔作用与左行走滑剪切是哀牢山深变质带折返过程中近似同时发生的两种不同变质表现形式,两者相互影响、相互制约。     

The petrology of some volcanic rocks from the British Tertiary province: The islands of Rhum,Eigg, Canna,and Muck

On Rhum, Eigg, Canna and Muck Tertiary volcanics rest upon a Mesozoic or Pre-Mesozoic basement. Aphyric, olivine-phyric, and plagioclase-phyric basalts are recognized. The aphyric basalts are mildly alkaline or transitional types with either a few percent normative nepheline or normative hypersthene. They have anomalously low concentrations of Rb, Sr and K₂O compared to Tertiary tholeiites from the same province.Aphyric hawaiites, and mugearties are found on all the islands, but are particularly abundant on Rhum. The volcanics from Bloodstone Hill, Rhum, originally described as mugearites are anomalous in that they are quartz normative and contain both augite and hypersthene, in contrast to the normal one-pyroxene rocks of the alkali basalt-trachyte association (Muir and Tilley, 1961). These volcanics have closer affinities to the icelandites, the presence of basic plagioclase xenocrysts suggesting an hybrid origin.Olivine and plagioclase are involved in the low-pressure fractionation of the transitional basalts, whereas pyroxene and titanomagnetie play only minor roles. Consequently, the suppression of titanomagnetite crystallization results in an initial trend towards iron enrichment. The presence of both oversaturated and undersaturated derivitives following the hawaiite stage of differentiation, reflects variation in the amount of extracted pyroxene and titanomagnetite.Felsites and pitchstones intrude the volcanic pile on Eigg. The felsites carry corroded quartz crystals and rare alkali feldspar. The more crystal rich pitchstones generally contain augite, hypersthene, zoned plagioclase and titanomagnetite. One from Rudh an Tancaird contains alkali feldspar, titanomagnetite and ferrohedenbergite.Whole rock analyses and microprobe analyses of feldspars and pyroxenes indicate that the acid volcanics are not genetically related to the basalt-hawaiite-mugearite lineage. The felsites appear to have been derived from Torridonian arkose by partial melting, but the pitchstones could only be derived by anatexis of Lewisian gneiss basement (see Dunham, 1968) substantially more basic than that outcropping on Rhum.It is suggested that the low concentrations of Rb, Sr, and K₂O in the alkaline and transitional basalts, mitigates against extensive pre-eruptive differentiation. Possibly the basalts could have been derived by partial melting of a mantle depleted in these elements.     

辽西太古代建平变质杂岩的地球化学和变质作用的PTt轨迹

太古代建平变质杂岩主要由高Na/K比的、原岩为英云闪长岩-奥长花岗岩-花岗闪长岩系列(TTG)侵入岩的中性麻粒岩和片麻岩、少量变沉积岩、基性麻粒岩、斜长角闪岩和变超基性岩组成。各类岩石具有明显不同的地球化学特征。结合野外关系考虑,斜长角闪岩和基性麻粒岩可与世界其他高级区内的变质拉斑玄武岩对比;TTG片麻岩,中性麻粒岩、紫苏花岗岩和斜长质片麻岩可能由镁铁质源岩部分熔融而成。变质作用的演化轨迹为反时针型。因此,本区可与冀东、内蒙、南印度和苏格兰的刘易斯等高级地体对比。     

喜马拉雅造山带的部分熔融与淡色花岗岩成因机制

喜马拉雅造山带核部由高级变质岩和淡色花岗岩组成,是研究大陆碰撞造山带部分熔融与花岗岩成因的天然实验室.基于最新研究成果,探讨了喜马拉雅造山带核部变质作用的条件、类型以及P-T轨迹、部分熔融的方式与程度及熔体成分以及变质作用与部分熔融的时间和持续过程.相关证据表明,造山带核部经历了高压麻粒岩相至榴辉岩相变质作用,具有以增温增压进变质和近等温降压退变质为特征的顺时针型P-T轨迹.这些高压变质岩石发生了长期持续的高温变质与部分熔融.在泥质岩石的进变质过程中白云母和黑云母脱水熔融可以形成不同成分的熔体.同时,总结了淡色花岗岩的形成时间、地球化学特征和源区熔融方式,结果表明碰撞造山过程中加厚下地壳的脱水熔融形成了喜马拉雅造山带的淡色花岗岩.      

Carbonate-orthopyroxenites (sagvandites) from Troms, northern Norway

Massive carbonate-orthopyroxenites occur in tectonic lenses within narrow zones of high-grade regional metamorphism of the Caledonian mountain belt. Typical country rocks are garnet-kyanite-biotite gneisses, amphibolites, or lime silicate marbles. Some of the pelitic country rocks exhibit water-deficient mineral assemblages, others have endured partial melting. Original peridotites (dunites and, possibly, saxonites) are believed to have reacted with highly CO₂-bearing, SiO₂-enriched gas phases emanating from neighbouring silicate marbles, essentially according to the equations forsterite + CO₂ →estatite + magnesite, and forsterite SiO₂ →estatite. This metasomatism as well as the high-grade metamorphism of the country rocks may have taken place under essentially the same pressure temperature conditions, i.e. under at least 6 kb and 630°C.     

内蒙古大青山高级变质岩韧性剪切带及其流变机制

大青山高级变质岩不仅记录华北克拉通早期大陆形成演化历史,也保留了中下部地壳岩石流变信息,它们经历了下部地壳构造层次高角闪岩相-麻粒岩相条件变质变形、深熔作用改造,形成了复杂构造样式和构造要素组合.韧性剪切带是高级变质岩中主要构造形迹,控制着早前寒武纪高级变质岩主体构造格架.依据野外地质产状、变形特征与构造要素叠加改造关系,韧性剪切带划分为早期近水平顺层伸展型和晚期陡倾韧性剪切带.近水平顺层伸展韧性剪切带呈残留状保留在后期变形改造较弱部位上,主要沿着不同地质单元或者岩性层界面上发育,是在伸展变形体制下形成的.晚期陡倾韧性剪切带呈近东西方向展布,规模较大,叠加和改造早期构造形迹,形成于晚期造山挤压构造环境中,以左行滑移为主.这两种韧性剪切带都形成于地壳中深部构造层次高角闪岩相-麻粒岩相条件下,变形机制主要为熔体增强颗粒边界扩散和颗粒流动,使岩石发生大规模的塑性流动.在宏观上形成了不对称流动组构、条纹条带构造、熔融线理、层内流动褶皱等构造形迹,在微观上矿物晶体没有发生明显塑性变形,均匀消光,晶体为三边平衡结构,与静态变质结构相似,形成了地壳深部构造层次上变质构造岩-构造片麻岩.      

藏南定结淡色花岗岩--基底隆升降压熔融成因的地质证据

西藏南部定结地区高喜马拉雅结晶基底中淡色花岗岩体紧靠藏南拆离断层内部产出．野外地质和岩相学特征显示其为S型、分两期侵入的淡色花岗岩体——早期的黑云母淡色花岗岩和晚期的白云母淡色花岗岩。基底副变质岩中广泛分布淡色花岗岩脉体．在基底副变质岩中的淡色花岗岩脉体中发现紫苏辉石暗色麻粒岩残留体，这表明本区高喜马拉雅淡色花岗岩源岩为基底副变质岩，且基底副变质岩是在基底快速隆升降压的条件下发生缺水熔融生成的淡色花岗岩岩浆。     

Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland: Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.     

Variscan vs Cadomian tectonothermal activity in northwestern sectors of the Teplá-Barrandian zone, Czech Republic: constraints from 40Ar/39Ar ages

Five muscovite concentrates from high-grade, pelitic metasedimentary basement rocks exposed in northwestern sectors of the Teplá-Barrandian zone (Czech Republic) record ⁴⁰Ar/³⁹Ar mineral plateau ages which range between ca. 376 and 362?Ma. Hornblende concentrates from metagabbro (Mariánské Lánzě complex) and fine-grained basement amphibolite display plateaux which define ³⁶Ar/⁴⁰Ar vs ³⁹Ar/⁴⁰Ar isotope-correlation ages of ca. 370 and ca. 375 Ma. The mineral ages are interpreted to date relatively rapid cooling through appropriate argon retention temperatures following early phases of Variscan (Early Devonian) regional metamorphism. A slate/phyllite basement sample collected within lower-grade metasedimentary rocks in southeastern portions of the Teplá-Barrandian zone is characterized by an internally discordant ⁴⁰Ar/³⁹Ar whole-rock age spectrum which suggests partial Variscan rejuvenation of intracrystalline argon systems which had cooled through appropriate argon retention temperatures following an initial regional metamorphism at or prior to ca. 500 Ma (Cadomian). Hornblende from undeformed diorite of the Kdyn? complex records a well-defined ⁴⁰Ar/³⁹Ar age plateau which corresponds to an isotope-correlation age of ca. 516?Ma. This is interpreted to date post-magmatic cooling following emplacement.     

Volcanism on a Proterozoic continental margin in northwestern Queensland

The oldest rocks exposed in northwestern Queensland are metamorphosed calc-alkaline volcanics (Leichhardt Metamorphics), which are intruded by elongate tonalitic to granitic batholiths (Kalkadoon Granite). These rocks are overlain by a less metamorphosed sequence containing basic lavas (Magna Lynn Metabasalt) overlain by extensive ignimbritic rhyolite and dacite (Argylla Formation). Sequences of basalt and psammite overlie the rhyolite unconformably and are overlain in turn unconformably by psammitic, pelitic, carbonate and possibly evaporitic sediments and minor volcanics. Younger granites intrude these rocks.The mineral assemblages of the Leichhardt Metamorphics, Magna Lynn Metabasalt and Argylla Formation indicate greenschist and lower amphibolite facies of metamorphism. The rocks contain no glass and some are obviously recyrstallized; however, phenocrysts, lithic fragments, spherulites, amygdales and flow-top breccias are still recognizable.Sixty-nine of the least deformed volcanic and sub-volcanic rocks were analysed for major elements and up to twenty trace elements. Element dispersion in these analyses indicated that metasomatism was probably of limited extent. The Magna Lynn Metabasalt is similar to low-potassium tholeiite, as it has less than 0.5% potash, high normative hypersthene, some normative quartz and typical Ti/Zr/Y ratios. The acid volcanics have calc-alkaline affinities although andesite is not common and the alumina content is relatively low. They have high K/Na ratios and their trace elements (especially Ba, Sr, Rb, Zr and Ce) are similar to Andean volcanics. The tholeiitic sequences that overlie the calc-alkaline volcanics in northwestern Queensland resemble the basaltic sequences of western U.S.A. that also overlie calc-alkaline volcanics.The predominantly calc-alkaline volcanics of northwestern Queensland are believed to have formed at a continental margin similar to that in the Andean region. The younger tholeiitic lavas and minor continental acid volcanism possibly accompanied crustal tension. Later regional metamorphism and intrusion of large granite batholiths stabilized the region.     

冀东青龙-双山子地区新太古代高镁安山岩-镁闪长岩锆石U-Pb年代学、地球化学及大地构造意义

冀东地区位于华北克拉通北缘,学术界对该地区新太古代岩浆作用的成因模式及构造背景一直存在争议,因此对冀东青龙-双山子地区的新太古代变质表壳岩及侵入岩进行了系统的同位素年代学及岩石地球化学研究.锆石LA-MC-ICP-MS U-Pb年代学结果显示变安山岩的形成时代为2 576 Ma,辉长闪长岩-英云闪长岩-石英闪长岩的侵入时代为2 484~2 535 Ma.岩石地球化学特征显示,较早期的变安山岩部分属高镁安山岩类,源自俯冲板片脱水流体交代地幔楔的部分熔融;而稍晚的侵入岩类为具有埃达克质岩石特征的镁闪长岩类,源区具有熔体交代地幔楔部分熔融的特征;整体构成高镁安山岩-埃达克质镁闪长岩组合.结合区域上的同位素年代学及地球化学报道,冀东青龙-双山子地区新太古代应处于活动大陆边缘构造背景.      

Multi-stage pseudomorphic replacement of garnet during polymetamorphism: 1. Microstructures and their interpretation

Metapelites from the southern aureole of the Vedrette di Ries tonalite (eastern Alps) were variably overprinted by contact and earlier regional metamorphic events during pre-Alpine and Alpine metamorphic cycles. In these rocks, starting from a primary garnet mica-schist (garnet stage), a complex sequence of transformations, affecting the site of the garnet, has been recognized. In the outermost part of the aureole, the primary garnet sites are occupied by nodules of kyanite (kyanite stage). Closer to the tonalite, kyanite is replaced by staurolite (staurolite stage), which in turn is pseudomorphed by muscovite (muscovite stage). The aggregates of kyanite do not overgrow garnet directly; they post-date a stage (fibrolite stage) represented by the pseudomorphic alteration of garnet into fibrolitic sillimanite plus biotite. A further sericite stage is likely to have occurred between the fibrolite and kyanite stages. Preservation of the sub-spherical garnet shape during all these transformations and persistence of mineralogical and textural relicts from earlier stages were favoured by the very low strain experienced by the rocks since the garnet stage. The textural sequence is in agreement with the metamorphic history of this part of the Austroalpine basement of the Eastern Alps: the garnet and fibrolite stages, and the coeval main foliation of the samples, are referred to the high-grade Hercynian metamorphism; the kyanite stage to the Eo-Alpine metamorphism; the staurolite and muscovite stages to the Oligocene contact metamorphism. It is suggested that kyanite growth as microgranular aggregates took place in polymetamorphic rocks where static, high- P /low- T  metamorphism overprinted high- T  assemblages that contained sillimanite or andalusite.     

Petrology, Origin and Metamorphic History of Proterozoic-aged Granulites of the Natal Metamorphic Province, Southeastern Africa

The geochemistry of the Leisure Bay Formation, Natal Metamorphic Province suggests that its protoliths were greywackes, pelites and arkoses that were deposited in an oceanic island arc environment. These rocks contain the mineral assemblage biotite + hypersthene + cordierite (with hercynite inclusions) + garnet + quartz + feldspar. Numerous generations of garnet genesis are evident from which a long history of metamorphism can be interpreted. M₁ involved syn-D₁ high temperature/low pressure metamorphism (4kb and >850^oC) and dehydration melting to produce essentially anhydrous assemblages particularly in the vicinity of, and probably related to the intrusion of the Munster Suite sills. The inclusions of hercynite in cordierite and the garnet + quartz symplectites after hypersthene + plagioclase (550^oC and 5kb) suggests isobaric cooling after M₁. This indicates an anticlockwise P-T loop related to the early intrusion of subduction related calc-alkaline magmatic rocks. M₂ involved syn-D₂ dehydration melting of hydrous assemblages possibly related to the emplacement of many A-type rapakivi charnockite granitoids, which provided heat and loading. The D₂ tectonism post-dated all lithologies in the region, except for syn- to late-D₂ granitoid plutons, and is interpreted as a transpressional tectonothermal reworking of pre-existing (Proterozoic) crust at 1030Ma.