Effect of finely divided admixtures on the scattering of light in “pure” filtered water

We consider the problem of disagreement between the theoretical and experimental values of the spectral volume scattering function of “pure” filtered water. To explain this disagreement, we advance a hypothesis of existence of two-dimensional space correlations between the locations of a finely divided suspension in the liquid. We deduce analytic relations for the scattering of light in the approximation of statistically equilibrium distribution of particles over the surfaces of spheres randomly arranged in the medium. The experimental data on the volume scattering function of “pure” filtered water (the sizes of particles do not exceed 0.2 μm) are analyzed. The results of numerical analysis according to the model of spherical surface distribution of finely divided particles in water are in qualitative agreement with the spectral volume scattering function of filtered water. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 2, pp. 46–56, March–April, 2008.     

孔压探杆贯入及潮汐作用下超孔压响应规律研究

Excess pore water pressure is an important parameter that can be used to analyze certain physical characteristics of sediment. In this paper, the excess pore water pressure of subseafloor sediment and its variation with tidal movement was measured following the installation of a wharf in Qingdao, China by using a fiber Bragg grating(FBG) piezometer. The results indicated that this FBG piezometer is effective in the field. The measured variation of excess pore water pressure after installation is largely explained by the dissipation of excess pore water pressure. The dissipation rate can be used to estimate the horizontal consolidation coefficient, which ranged from1.3×10~(–6) m~2/s to 8.1×10~(–6) m~2/s. The measured values during tidal phases are associated with the variability of tidal pressure on the seafloor and can be used to estimate the compressibility and the permeability of the sediment during tidal movement. The volume compression coefficient estimated from tidal oscillation was approximately2.0×10~(–11) Pa~(–1), which was consistent with the data from the laboratory test. The findings of this paper can provide useful information for in situ investigations of subseafloor sediment.     

Numerical Method for the Solution of the Equation of Radiation Transfer. Reflection and Transmission Coefficients for an Optically Thin Plane-Parallel Layer

We study the problem of the choice of initial approximation for the reflection and transmission coefficients in numerical methods based on the principle of “interaction.” The disadvantages of the approximation of single scattering are demonstrated and the regularities of propagation of light in media with strongly anisotropic scattering are analyzed. Semianalytic expressions proposed for the evaluation of the initial approximation enable one to determine the characteristics of the light field in plane-parallel media with relative errors of about 10⁻⁵ within the framework of the algorithm of “adding” of layers. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 3, pp. 62–72, May–June, 2005.     

Radar estimation of water content in cumulonimbus clouds

The method and results of radar researches of vertically and volumetric integrated water content in powerful cumulonimbus (Cb) clouds obtained for the first time are considered. It is established that in hailstorms of Northern Caucasus vertically integrated liquid (VIL) water content varies in limits from 8 up to 50 kg/m², in shower clouds—from 0.5 up to 12 kg/m², in Nimbostratus (Ns) clouds—it is usual less than 0.5 kg/m² and in clouds with a drizzle—less than 0.05 kg/m². The main water content of hailstorms in a stage of development is concentrated in their supercooled layer, in a maturity stage—in a layer from the ground up to height 8–10 km and in a stage of dissipation—in a ground layer. The ratio of VIL of the supercooled and warm parts of cloud allows estimating hail dangers of clouds and stage of their development. It is shown that the volume of hailstorms varies in limits from 10³ up to 5 × 10⁴ km³ and their volumetric integrated mass (VIM) of water content — from 10⁵ up to 6 × 10⁶ tons. The volume of hail localization seldom exceeds 5–25% from total cloud volume, but its contribution to VIM achieves 30–60%. Speed of precipitation formation in powerful hailstorms achieves 1 × 10⁴−5 × 10⁵ tons/min and the same order of value has speed of recession of VIM in their stage of dissipation.     

An anticyclonic eddy in the intermediate layer of the Luzon Strait in Autumn 2005

The complicated flow pattern in the intermediate layer of the Luzon Strait could directly affect the efficiency of the water and energy exchange between the South China Sea (SCS) and the North Pacific. Here we present a subsurface anticyclonic eddy in the Luzon Strait deduced using observations conducted in October 2005. On the basis of the hydrographic and current measurements, an anticyclonic eddy was found in the intermediate layer, i.e., about 26.8–27.3σ_θ, 500–900 m. It captures part of the SCS Intermediate Water outflow in the northern Luzon Strait, and carries it to flow southward and then westward back into the SCS in the southern Luzon Strait, with volume transport of about 1.9 × 10⁶ m³ s⁻¹. The simulated results from Hybrid Coordinate Ocean Model also suggest the existence of this anticyclonic eddy that develops and lingers for a month long.     

Ground-truthing 11- to 12-kHz side-scan sonar imagery in the Norwegia–Greenland Sea: Part I: Pockmarks on the Vestnesa Ridge and Storegga slide margin

 Numerous small (50- to 300-m-diameter) strong-backscatter objects were imaged on the 1200- to 1350-m deep crest of Vestnesa Ridge (Fram Strait) and along the 900- to 1000-m deep northeast margin of the Storegga slide valley. Ground-truthing identified most of these objects as 2- to 10-m-deep pockmarks, developed within soft, acoustically stratified silty clays (typical wet bulk density: 1400–1600 kg m^-3; sound speed: 1480– 1505 m s^-1; porosity, 65–75%; shear strength: 5–10 kPa; water content: 80–120%; and thermal conductivity: 0.8–0.9 W m^-1 deg C^-1 in the top 3 m). Gas wipeouts, enhanced reflectors, and reflector discontinuities indicate recent or ongoing activity, but the absence of local heat flow anomalies suggests that any upward fluid flows are modest and/or local.     

Geoacoustic and physical properties of carbonate sediments of the Lower Florida Keys

 Near-surface sediment geoacoustic and physical properties were measured from a variety of unconsolidated carbonate sediments in the Lower Florida Keys. Surficial values of compressional and shear speed correlate with sediment physical properties and near-surface acoustic reflectivity. Highest speeds (shear 125–150 m s^-1; compressional 1670–1725 m s^-1) are from sandy sediments near Rebecca Shoal and lowest speeds (shear 40–65 m s^-1; compressional 1520–1570 m s^-1) are found in soft, silty sediments which collect in sediment ponds in the Southeast Channel of the Dry Tortugas. High compressional wave attenuation is attributed to scattering of acoustic waves from heterogeneity caused by accumulation of abundant shell material and other impedance discontinuities rather than high intrinsic attenuation. Compared to siliciclastic sediments, carbonate sediment shear wave speed is high for comparable values of sediment physical properties. Sediment fabric, rather than changes due to the effects of biogeochemical processes, is responsible for these differences.     

Absolute Volume Transports of the Oyashio Referred to Moored Current Meter Data Crossing the OICE

During November 2000–June 2002, both direct current measurements from deployment of a line of five moorings and repeated CTD observations were conducted along the Oyashio Intensive observation line off Cape Erimo (OICE). All the moorings were installed above the inshore-side slope of the Kuril-Kamchatka Trench. Before calculating the absolute volume transports, we compared vertical velocity differences of relative geostrophic velocities with those of the measured velocities. Since both the vertical velocity differences concerned with the middle three moorings were in good agreement, the flows above the continental slope are considered to be in thermal wind balance. We therefore used the current meter data of these three moorings, selected among all five moorings, to estimate the absolute volume transports of the Oyashio referred to the current meter data. As a result, we estimated that the southwestward absolute volume transports in 0–1000 db are 0.5–12.8 × 10⁶ m³/sec and the largest transport is obtained in winter, January 2001. The Oyashio absolute transports in January 2001, crossing the OICE between 42°N and 41°15′ N from the surface to near the bottom above the continental slope, is estimated to be at least 31 × 10⁶ m³/sec. This revised version was published online in July 2006 with corrections to the Cover Date.     

Formation, Distribution and Volume Transport of the North Pacific Intermediate Water Studied by Repeat Hydrographic Observations

In order to examine the formation, distribution and transport of North Pacific Intermediate Water (NPIW), repeated hydrographic observations along several lines in the western North Pacific were carried out in the period from 1996 to 2001. NPIW formation can be described as follows: (1) Oyashio water extends south of the Subarctic Boundary and meets Kuroshio water in intermediate layers; (2) active mixing between Oyashio and Kuroshio waters occurs in intermediate layers; (3) the mixing of Oyashio and Kuroshio waters and salinity minimum formation around the potential density of 26.8σ_θ proceed to the east. It is found that Kuroshio water flows eastward even in the region north of 40°N across the 165°E line, showing that Kuroshio water extends north of the Subarctic Boundary. Volume transports of Oyashio and Kuroshio components (relative to 2000 dbar) integrated in the potential density range of 26.6–27.4σθ along the Kuroshio Extension across 152°E–165°E are estimated to be 7–8 Sv (10⁶ m³s⁻¹) and 9–10 Sv, respectively, which is consistent with recent work. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characteristics of the optical volume scattering function of sea water

The volume scattering function, σ(?), was observed for unpolarized green light near 5300 Å in a variety of water bodies over a wide range of scattering angle, ?. These data, includingin situ values measured to an extreme foward angle of 0.2^o, permit a statistical study of parameters describing the shape of the σ(?) curve and provide detailed information on small angle contributions to forward scattering. The angular limit, θ_1/2, which determines one-half the total scattering coefficient upon integration of σ(?) over small angles, is determined from measured data and ranges between about 2^o for clear ocean water and about 5^o for turbid coastal water. Use of σ(?), measured at a single fixed angle, is investigated further as an indicator of the total scattering coefficient, and results of other studies showing a high correlation between the total scattering coefficient and σ(45^o) are further substantiated.     

Oxygen Utilization and Organic Carbon Remineralization in the Upper Water Column of the Pacific Ocean

As a part of the JGOFS synthesis and modeling project, researchers have been working to synthesize the WOCE/JGOFS/DOE/NOAA global CO₂ survey data to better understand carbon cycling processes in the oceans. Working with international investigators we have compiled a Pacific Ocean data set with over 35,000 unique samples analyzed for at least two carbon species, oxygen, nutrients, chlorofluorocarbon (CFC) tracers, and hydrographic parameters. We use these data here to estimate in-situ oxygen utilization rates (OUR) and organic carbon remineralization rates within the upper water column of the Pacific Ocean. OURs are derived from the observed apparent oxygen utilization (AOU) and the water age estimates based on CFCs in the upper water and natural radiocarbon in deep waters. The rates are generally highest just below the euphotic zone and decrease with depth to values that are much lower and nearly constant in water deeper than 1200 m. OURs ranged from about 0.02–10 μmol kg⁻¹yr⁻¹ in the upper water masses from about 100–1000 m, and averaged = 0.10 μmol kg⁻¹yr⁻¹ in deep waters below 1200 m. The OUR data can be used to directly estimate organic carbon remineralization rates using the C:O Redfield ratio given in Anderson and Sarmiento (1994). When these rates are integrated we obtain an estimate of 5.3 ± 1 Pg C yr⁻¹ for the remineralization of organic carbon in the upper water column of the Pacific Ocean. This revised version was published online in July 2006 with corrections to the Cover Date.     

Intermediate Circulation in the Northwestern North Pacific Derived from Subsurface Floats

In order to examine the formation, distribution and synoptic scale circulation structure of North Pacific Intermediate Water (NPIW), 21 subsurface floats were deployed in the sea east of Japan. A Eulerian image of the intermediate layer (density range: 26.6–27.0σ_θ) circulation in the northwestern North Pacific was obtained by the combined analysis of the movements of the subsurface floats in the period from May 1998 to November 2002 and historical hydrographic observations. The intermediate flow field derived from the floats showed stronger flow speeds in general than that of geostrophic flow field calculated from historical hydrographic observations. In the intermediate layer, 8 Sv (1 Sv ≡ 10⁶ m³s⁻¹) Oyashio and Kuroshio waters are found flowing into the sea east of Japan. Three strong eastward flows are seen in the region from 150°E to 170°E, the first two flows are considered as the Subarctic Current and the Kuroshio Extension or the North Pacific Current. Both volume transports are estimated as 5.5 Sv. The third one flows along the Subarctic Boundary with a volume transport of 5 Sv. Water mass analysis indicates that the intermediate flow of the Subarctic Current consists of 4 Sv Oyashio water and 1.5 Sv Kuroshio water. The intermediate North Pacific Current consists of 2 Sv Oyashio water and 3.5 Sv Kuroshio water. The intermediate flow along the Subarctic Boundary contains 2 Sv Oyashio water and 3 Sv Kuroshio water. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characterization of the solar light field within the ocean mesopelagic zone based on radiative transfer simulations

The solar light field within the ocean from the sea surface to the bottom of the mesopelagic zone was simulated with a radiative transfer model that accounts for the presence of inelastic radiative processes associated with Raman scattering by water molecules, fluorescence of colored dissolved organic matter (CDOM), and fluorescence of chlorophyll-a contained in phytoplankton. The simulation results provide a comprehensive characterization of the ambient light field and apparent optical properties (AOPs) across the entire visible spectral range within the depth range 200–1000 m of the entire mesopelagic zone for varying chlorophyll-a concentration and seawater optical properties in the mixed surface layer of the ocean. With increasing depth in the mesopelagic zone, the solar irradiance is reduced by ~9–10 orders of magnitude and exhibits a major spectral maximum in the blue, typically centered around a light wavelength of 475 nm. In the green and red spectral regions, the light levels are significantly lower but still important owing to local generation of photons via inelastic processes, mostly Raman scattering and to a lesser extent CDOM fluorescence. The Raman scattering produces a distinct secondary maximum in irradiance spectra centered around 565 nm. Comparisons of our results with light produced by the radioactive decay of the unstable potassium isotope contained in sea salt (⁴⁰K) indicates that the solar irradiance dominates over the ⁴⁰K-produced irradiance within the majority of the mesopelagic zone for most scenarios considered in our simulations. The angular distribution of radiance indicates the dominance of downward propagation of light in the blue and approach to uniform distribution in the red throughout the mesopelagic zone. Below the approximate depth range 400–500 m, the shape of the angular distribution is nearly invariant with increasing depth in the green and red and varies weakly in the blue. The AOPs at any light wavelength also assume nearly constant values within the deeper portion of the mesopelagic zone. These results indicate that the mesopelagic light field reaches a nearly-asymptotic regime at depths exceeding ~400–500 m.     

Phytoplankton biomass and size fractions in surface waters of the Australian sector of the southern ocean

We collected surface water along the 142nd E meridian from Tasmania to Antarctica in December 1999. We measured temperature, salinity and total chlorophyll a; additionally, we collected suspended particle size fractions and used fluorometric analysis to determine the quantity of chlorophyll a in each of four cell size classes: picoplankton (<3 μm), two nanoplankton fractions (3–10 μm and 10–20 μm) and microplankton (> 20 μm). Changes in temperature and salinity show that we crossed 6 water masses separated by 5 fronts. We found low abundance (<0.2 mg m⁻³) of chlorophyll in all size classes, with the exception of higher values near the continent (0.2 to 0.4 mg m⁻³). Lowest chlorophyll values (<0.1 mg m⁻³) were found in the Polar Frontal Zone (51° to 54°S). Microplankton made up the largest portion of total chlorophyll throughout most of the region. We conclude that biomass of all phytoplankton fractions, especially pico-and nanoplankton, was constrained by limiting factors, most probably iron, throughout the region and that ecosystem dynamics within a zone are not circumpolar but are regionalized within sectors.     

Incorporation rate measurements of <Superscript>10</Superscript>Be, <Superscript>230</Superscript>Th, <Superscript>231</Superscript>Pa,and <Superscript>239,240</Superscript>Pu radionuclides in manganese crust in the Pacific Ocean: A search for extraterrestrial material

In order to estimate the deposition rate of extraterrestrial material onto a manganese crust in a search for supernova debris, we analyzed the contents of ¹⁰Be, ²³⁰Th, ²³¹Pa, and ^239,240Pu in a sample of manganese crust collected from the North Pacific Ocean. On the basis of the depth profile of ¹⁰Be, the growth rate of the manganese crust was determined to be 2.3 mm Myr⁻¹. The uptake rates of ¹⁰Be, ²³⁰Th, and ²³¹Pa onto the manganese crust were estimated to be 0.22–0.44%, 0.11–0.73%, and 1.4–4.5%, respectively, as compared to the deposition rates onto the deep-sea sediments near the sampling station, while that for ^239,240Pu was 0.14% as compared to the total inventory of seawater and sediment column. Assuming that sinking particles represent 0.11–4.5% of the uptake rates, the deposition rate of extraterrestrial material onto the manganese crust was estimated to be 2–800 μg cm⁻²Myr⁻¹ according to the uptake of ¹⁰Be onto the manganese crust. Further, our estimate is similar to the value of 9–90 μg cm^{− 2}Myr⁻¹ obtained using the integrated global production rate of ¹⁰Be and the deposition rate of ¹⁰Be onto the manganese crust.     

Sedimentation rates and subsidence in the Southern Tyrrhenian Basin

The petrophysical properties of sediment drill core samples recovered from the Sardinian margin and the abyssal plain of the Southern Tyrrhenian Basin were used to estimate the downhole change in porosity and rates of deposition and mass accumulation. We calculated how the deposited material has changed its thickness as a function of depth, and corrected the thickness for the compaction. The corresponding porosity variation with depth for terrigenous and pelagic sediments and evaporites was modelled according to an exponential law. The mass accumulation rate for the Plio-Quaternary is on average 4.8×10⁴ kg m⁻² my⁻¹ on the Sardinian margin and for the Pliocene in the abyssal plain. In the latter area, the Quaternary attains its greatest thickness and a mass accumulation rate of 11–40×10⁴ kg m⁻² my⁻¹. The basement response to sediment loading was calculated with Airy-type backstripping. On the lower part of the Sardinian margin, the basement subsidence rate due to sediment loading has decreased from a value of 300 m my⁻¹ in the Tortonian and during the Messinian salinity crisis (7.0–5.33 Ma) to about 5 m my⁻¹ in the Plio-Quaternary. In contrast, on the abyssal plain this rate has changed from 8–50 m my⁻¹ during the period 3.6–0.46 Ma, to 95–130 m my⁻¹ since 0.46 Ma, with the largest values in the Marsili Basin. The correlation between age and the depth to the basement corrected for the loading of the sediment in the ocean domain of the Tyrrhenian Basin argues for a young age of basin formation.     

Roles of mode waters in the formation and maintenance of central water in the North Pacific

This study describes the three-dimensional distributions of the Turner angle (Tu) and the potential vorticity (PV) of the main pycnocline water in the subtropical North Pacific (10–50°N, 120°E–120°W) using a large in situ CTD data set taken by the Argo profiling floats during June to October of 2001–2009 to clarify the detailed distribution of the central water and the mode waters as well as the relationship between these water masses. The ventilated part of the main pycnocline water (σ _θ < 26.7 kg m⁻³) in the subtropical gyre generally displays a sharp peak in Tu value of 59° in the histogram. The Tu histograms for 10° × 10° geographical boxes mostly show that the mode for the Tu value is 59° too, but they also show some regional differences, suggesting some types of relations with the North Pacific mode waters. To further investigate this relationship, the appearance probability density function of the central water (defined as the main pycnocline water with Tu = 56°–63°) and those of the mode waters with PVs lower than the critical value on each isopycnal surface were analyzed. The distribution area of the central mode water (CMW) corresponds so well with that of the central water that a direct contribution of the CMW to the formation and maintenance of the central water is suggested. On the other hand, the distribution areas of subtropical mode water (STMW), Eastern STMW, and transition region mode water do not correspond to that of the central water. Nevertheless, indirect contributions of these mode waters to the formation and maintenance of the central water through salt finger type convection or diapycnal mixing are suggested.     

Phytoplankton pigment change as a photoadaptive response to light variation caused by tidal cycle in Ariake Bay,Japan

Underwater light environment and photosynthetic accessory pigments were investigated in Ariake Bay in order to understand how change of the pigments occurs in response to the tidal-induced changes in underwater light conditions. We hypothesize that phytoplankton increases photo-protective pigments and decreases light-harvesting pigments under higher light condition in the mixed layer caused by tidal cycle. Contribution rates of non-phytoplankton particles (a _nph (400–700)) for light attenuation coefficient (K _d ) was highest (32–85%), and those of phytoplankton particles (a _ph (400–700)), dissolved organic matter (a _g (400–700)) and water were 6–32, 6–21 and 5–23%, respectively. Mean K _d was higher during the spring tide (0.55 ± 0.23 m⁻¹) than the neap tide (0.44 ± 0.16 m⁻¹), and the K _d difference was caused by the substances resuspension due to the tidal current. In contrast, ratios of photo-protective pigments (diadinoxanthin and diatoxanthin) per chlorophyll a ((DD+DT)/Chl a) were higher during the neap tide (0.10 ± 0.03 mg mg-Chl a ⁻¹) than the spring tide (0.08 ± 0.03 mg mg-Chl a ⁻¹). And there was significant positive correlation between (DD+DT)/Chl a and mean relative PAR in the mixed layer ($ \overline {I_{mix} } $ \overline {I_{mix} } ). Moreover, there was significant negative correlation between ratios of light-harvesting pigments (fucoxanthin) per Chl a (Fuco/Chl a) and $ \overline {I_{mix} } $ \overline {I_{mix} } . These results suggested that phytoplankton in Ariake Bay increase photo-protective pigments and decrease light-harvesting pigments in the higher light condition of less turbid, shallower mixed layer during neap tide than spring tide.     

Absorption spectroscopy of microalgae,cyanobacteria, and dissolved organic matter: Measurements in an integrating sphere cavity

A device for integrating cavity absorption measurements (ICAM) with an internal diameter of 80 mm suitable for field research is described. The spectral features of the light absorption by some cyanobacteria, green algae, and diatoms in the integrating sphere were studied and the dependences of the absorption on the cell concentration were determined in comparison with the conventional measurements in a 1-cm cuvette. The sensitivity of the chlorophyll estimation with the ICAM reached 0.2–0.5 mg m⁻³. The results of the ICAM application for the direct analysis of the natural phytoplankton and dissolved organic (“yellow“) matter in the Black Sea and the Sea of Japan are described.     

Possible Density Change of the Origin of North Pacific Intermediate Water Due to Double Diffusion in the Mixed Water Region

In this study we test Talley's hypothesis that Oyashio winter mixed-layer water (26.5–26.6σ _θ) increases its density to produce the North Pacific Intermediate Water (NPIW) salinity minimum (26.7– 26.8σ_θ) in the Mixed Water Region, assuming a combination of cabbeling and double diffusion. The possible density change of Oyashio winter mixed-layer water is discussed using an instantaneous ratio of the change of temperature and salinity along any particular intrusion (R _l ). We estimate the range of R _l ^DD required to convert Oyashio winter mixed-layer water to the NPIW salinity minimum due to double diffusion, and then assume double-diffusive intrusions as this conversion mechanism. A double-diffusive intrusion model is used to estimate R _l ^DD in a situation where salt fingering dominates vertical mixing, as well as to determine whether Oyashio winter mixed-layer water can become the NPIW salinity minimum. Possible density changes are estimated from the model R _l ^DD by assuming the amount of density change due to cabbeling. From these results, we conclude that Oyashio winter mixed-layer water contributes to a freshening of the lighter layer of the NPIW salinity minimum (around 26.70σ_θ) in the MWR.