La β-decay constant estimated from geochronological studies

LaCe ages are reported for two sets of Finnish pegmatites, Lövböle and Mustikkamäki, and for an Amiˆtsoq gneiss, Greenland. When λ_β¹³⁸La value (2.29 × 10⁻¹² yr⁻¹) obtained by radioactivity measurement [1] is used for the chronological calculation, the LaCe ages (2129, 2325, 3271 Myr) evaluated for these rocks are 18–35% older than the SmNd ages for the same samples. To make the LaCe age fit to the SmNd age for the same sample, a new value of (2.77 ± 0.21) × 10⁻¹² yr⁻¹ is evaluated for λ_β¹³⁸La. In this calculation, the LaCe and SmNd ages reported for a Bushveld gabbro [2] have been also taken into account together with those for the Lövböle pegmatite and the Mustikkamäki pegmatite, while the Amiˆtsoq gneiss (GGU110999) has been omitted because of the complicated thermal history of this sample.     

Neodymium isotopic study of Baffin Bay water: sources of REE from very old terranes

Water samples were collected from Baffin Bay and surrounding areas in order to evaluate this region as a potential source of Nd from old continental material to Atlantic water. The isotopic data ranged from ε_Nd(0) = −9.0 to −26 with most of the data around ε_Nd(0) = −20 compared with values of North Atlantic Deep Water (NADW) with ε_Nd(0) = −13.5. The concentration of Nd in Baffin Bay waters was as high as 6 × 10⁻¹² g/g compared with 2.5 × 10⁻¹² g/g for NADW. The combination of low ε_Nd and high Nd concentration indicates that Baffin Bay may be a significant source of Nd from very old crustal material. A simple box model was used to evaluate the contribution to the Nd budget of NADW and it was concluded that a substantial fraction of the Nd from ancient crustal sources that is required to maintain the isotopic composition of NADW could be supplied by Baffin Bay outflow.     

Hemolytic activity and fatty acids composition in the ichthyotoxic dinoflagellate Cochlodinium polykrikoides isolated from Bahía de La Paz, Gulf of California

The hemolytic activity of the dinoflagellate Cochlodinium polykrikoides from Bahía de La Paz, Gulf of California was investigated as part of the ichthyotoxic mechanism of this microalga. Two different kinds of erythrocytes, fish and human, were tested for the hemolytic assay. Since fatty acids have been associated with hemolytic activity in C. polykrikoides, the composition of fatty acids of this dinoflagellate was also analyzed. The concentration of C. polykrikoides causing 50% hemolysis (HE₅₀) was 4.88 and 5.27 × 10⁶ cells L⁻¹, for fish and human erythrocytes, respectively. According to the standard curve of saponin, an equivalence between the hemolytic activity of saponin and the dinoflagellate concentration was found with 1 μg saponin mL⁻¹ equivalent to 1 × 10⁶ cells L⁻¹ of C. polykrikoides. The polyunsaturated fatty acids: hexadecaenoic (16:0), docosahexaenoic (22:6 n3) and octadecapentaenoic (18:5 n3) were found in an abundance of 62% of total fatty acids.     

Hydrothermal vent waters at 13°N on the East Pacific Rise: isotopic composition and gas concentration

Gas concentrations and isotopic compositions of water have been measured in hydrothermal waters from 13°N on the East Pacific Rise. In the most Mg-depleted samples ( 5 × 10⁻³ moles/kg) the gas concentrations are: 3–4.5 × 10⁻⁵ cm³ STP/kg helium, 0.62–1.24 cm³ STP/kg CH₄, 10.80–16.71 × 10⁻³ moles/kg CO₂. The samples contain large quantities (95–126 cm³/kg) of H₂ and some carbon monoxide (0.26–0.36 cm³/kg) which result from reaction with the titanium sampling bottles. δ¹³C in methane and CO₂ (−16.6 to −19.5 and −4.1 to −5.5 respectively) indicate temperatures between 475 and 550°C, whereas δ¹³C_CO is compatible with formation by reduction of CO₂ on Ti at 350°C close to the sampling temperature.³He/⁴He are very homogeneous at (7.5 ± 0.1)R_A(³He/⁴He = 1.0 × 10⁻⁵) and very similar to already published data as well as CH₄/³He ratios between 1.4 and 2.1 × 10⁶.¹⁸O and D in water show enrichments from 0.39 to 0.69‰ and from 0.62 to 1.49‰ respectively. These values correspond to W/R ratios of 0.4–7. The distinct¹⁸O enrichments indicate that the isotopic composition of the oceans is not completely buffered by the hydrothermal circulations. The³He-enthalpy relationship is discussed in terms of both hydrothermal heat flux and³He mantle flux.     

The establishment of a GPS deformation network in the ethiopian rift valley

In April and May 1989 the satellite Global Positioning System (GPS) was employed in the establishment of three deformation networks in the Ethiopian Rift Valley. The net E1 consists of 6 points of about 100–270 km interdistances, with two points located on each of the African and the Somalian plate and two points down in the rift. In addition two separate GPS traverses were established: one (E2) runs across the rift, and one (E3) runs about 500 km along the rift.The remeasurement of a 175 km long baseline included in two subcampaigns indicates a repeatability of the GPS observations of the order of 1×10⁻⁷ and 3×10⁻⁷ for slope distance and ellipsoidal height, respectively.Along the E2 traverse GPS/trigonometric levelled geoid undulations and gravimetric geoid undulations agree well, while the discrepancy along the E3 traverse needs further analysis.     

Crustal neon: a striking uniformity

By combining data from a diverse suite of crustal fluid samples representing a broad geographical distribution, we have identified a well-defined nucleogenic (crustal) neon component. The neon is produced from (α, n) and (n, α) nuclear interactions involving nuclei of O, Mg, and F [1]. In the limiting case of ²⁰Ne/²²Ne = 0, the composition is: ²¹Ne/²²Ne = 0.47 ± 0.01 and ²¹Ne/⁴He = (0.46 ± 0.08) × 10⁻⁷. A crustal O/F ratio of 110 (atomic) calculated from the ²¹Ne/²²Ne ratio is 4–10 times less than the average crustal O/F ratio. The discrepancy can be accounted for by an enhanced O/F ratio within the 10–40 μm range of the U-Th-generated α-particles.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Crustal strain observation for nine years with a laser strainmeter in Kobe, Japan

We carried out precise crustal strain observation using a laser strainmeter system at the Rokko-Takao station in Kobe, Japan from 1989 to 1997. The long-term strain record is characterized by remarkable annual changes of the order of 2–3×10⁻⁶ and linear strain accumulation of −4.4×10⁻⁷/year (in contraction). The annual strain changes are inversely proportional to temperature changes that precede the strain changes by about 1 month. The apparent annual strain changes were mainly caused by refractive-index changes in the light path due to the ambient temperature changes. After eliminating the annual temperature effect, linear strain accumulation is corrected to be −6.3−6.7×10⁻⁷/year. Residual strains show the oscillating behavior, in which the oscillating cycle seems to become shorter and shorter as time goes by. During the period, a destructive earthquake of M=7.2 occurred near the Kobe City on 17 January 1995. We investigated the oscillating behavior in secular variations of ground-strains by introducing the deterministic approach of earthquake prediction to search for the “critical point” of the occurrence of an earthquake in the extended power law equation. However, we could not obtain a unique solution to determine eight unknown parameters including the “critical point”. This may be mainly due to lack of data for 4 months from August to November in 1994 by the failure of the laser source before the occurrence of earthquake on 17 January 1995. After removing environmental effects and tidal components, we carefully re-examined strain changes in 7 days and 1 day before the occurrence of the earthquake, but we could not detect anomalous strain changes exceeding 1×10⁻⁸ before the earthquake.     

Cloning and expression of alpha class glutathione S-transferase gene from the small hermaphroditic fish Rivulus marmoratus (Cyprinodontiformes, Rivulidae)

In order to assess its potential as a biomarker of aquatic pollution, an alpha class glutathione S-transferase gene (GSTalpha gene) was cloned from the small hermaphroditic fish Rivulus marmoratus. The R. marmoratus GSTalpha gene spanned 1.3 kb, consisting of 6 exons encoding 221 amino acid residues. It showed high similarity to zebrafish GST. We named this R. marmoratus GSTalpha gene as rm-GSTalpha. The cDNA of the rm-GSTalpha gene was also investigated for its phylogeny, tissue-specific and chemical-induced expression. Rm-GSTalpha was subcloned into a 6 x His-tagged pCRT7 TOPO TA expression vector to produce the recombinant 6 x His-tagged rm-GST protein. This will be used in future to raise an rm-GSTalpha antibody for use in the study of phase II metabolism involved in detoxification. We also exposed R. marmoratus to 300 microg/l of 4-nonylphenol in water, and found approximately 4-fold induction of R. marmoratus GSTalpha mRNA in the treated animals. In this paper, we discuss the characteristics of the R. marmoratus GSTalpha gene as well as its potential use in relation to environmental pollution.     

Comments on stable isotope geothermometry: the system quartz-water

We show that the results of quartz-water partial oxygen exchange experiments under hydrothermal conditions are determined primarily by exchange between water and dissolved silica species and not by diffusion in the solid. Hence, these experiments do not provide an accurate value of the variation of fractionation with temperature but only a rough indication of it. We conclude that the Bottinga and Javoy [1] equation, relying on this type of information and on the precise calculation of the coefficient A ( = −3.7) in the thermometric equation 1000 ln α = A + B × 10⁶/T², is not seriously questioned by these¹⁷O,¹⁸O partial exchange experiments.     

The 1975 sub-terminal lavas, mount etna: a case history of the formation of a compound lava field

The 1975 sub-terminal activity was characterised by low effusion rates (0.3–0.5 m³ s⁻¹) and the formation of a compound lava field composed of many thousands of flow units. Several boccas were active simultaneously and effusion rates from individual boccas varied from about 10⁻⁴ to 0.25 m³s⁻¹. The morphology of lava flows was determined by effusion rate (E): aa flows with well-developed channels and levees formed when E > 2 × 10⁻³ m³ s⁻¹, small pahoehoe flows formed when 2 × 10⁻³ m³ s⁻¹ >E > 5 > 10⁻⁴ m³ s⁻¹ and pahoehoe toes formed when E < 5 × 10⁻⁴ m³ s⁻¹. There was very little variation with time in the effusion temperature, composition or phenocryst content of the lava.New boccas were commonly formed at the fronts of mature lava flows which had either ceased to flow or were moving slowly. These secondary boccas developed when fluid lava in the interior of mature aa flows either found a weakness in the flow front or was exposed by avalanching of the moving flow front. The resulting release of fluid lava was accompanied by either partial drainage of the mature flow or by the formation of a lava tube in the parent flow. The temperature of the lava forming the new bocca decreased with increasing distance from the source bocca (0.035°C m⁻¹). It is demonstrated from the rate of temperature decrease and from theoretical considerations that many of the Etna lavas still contained a substantial proportion of uncooled material in their interior as they came to rest. The formation of secondary boccas is postulated to be one reason why direct measurements of effusion rates tend, in general, to overestimate the total effusion rates of sub-terminal Etna lava fields.     

Transport ofBe andBe in the ocean

Beryllium isotopes (¹⁰Be and⁹Be) have been measured in suspended particles of < 1 mm size collected by mid-water sediment traps deployed in the eastern Pacific at MANOP sites H (6°32′N, 92°50′W, water depth 3600 m) and M (8°50′N, 104°00′W, 3100 m). For comparison, surface sediments from box cores taken from the two sites were also studied. The concentrations of¹⁰Be and⁹Be in sediment-trap particles are about an order of magnitude smaller than those in the bottom sediments which contain about 8 × 10⁹ and 6 × 10¹⁶ atoms g⁻¹ of¹⁰Be and⁹Be, respectively. The sediment trap samples collected from 50 m off the bottom showed significant (26–63%) contributions from resuspended bottom sediments. The¹⁰Be/⁹Be ratio in trap samples varies from 3 to 20 × 10⁻⁸. The variation may partly result from varied proportion of authigenic/detrital material. The fluxes of both isotopes exhibit a very strong seasonality. The fluxes of¹⁰Be into the traps at about 1500 m are estimated as 9 × 10⁵ and 4 × 10⁵ atoms cm⁻² a⁻¹ at sites H and M respectively. These values are to be compared with the fluxes into the sediments of 4–5 × 10⁵ atoms cm⁻² a⁻¹ at both locations. Good correlations exist between¹⁰Be,⁹Be and²⁷Al indicating that the primary carrier phase(s) for the beryllium isotopes in the water column may be aluminosilicates.     

The global-average production rate ofBe

Precipitation collected in continuously open containers for about a year at seven sites around the United States was analyzed for¹⁰Be,⁹⁰Sr,²¹⁰Pb and²³⁸U. Based on these data and long-term precipitation,⁹⁰Sr and²¹⁰Pb delivery patterns, the stratospheric, tropospheric and recycled¹⁰Be components in the collections were estimated and the global¹⁰Be production rate was assessed. Single station production rate estimates range from 0.52 × 10⁶ atoms cm⁻² yr⁻¹ to 2.64 × 10⁶ atoms cm⁻² yr⁻¹. The mean value is 1.21 × 10⁶ atoms cm⁻² yr⁻¹ with a standard error of 0.26 × 10⁶ atoms cm⁻² yr⁻¹.     

Helium isotopic variability within single diamonds from the Orapa kimberlite pipe

The distribution and isotopic composition of helium has been measured in a suite of well-characterized one-carat diamonds from the Orapa kimberlite, Botswana. Crushing of the diamonds in vacuo indicates that most of the helium is contained by the matrix (generally greater than 90%), rather than by the inclusions. Step-heating experiments, performed on inclusion-free fragments remaining after crushing, indicate that the³He/⁴He ratio is variablewithin individual diamonds. The fragments, as small as 10 mg, were heated in two timed steps, both at 2000°C. In every case, lower³He/⁴He ratios are observed in the first graphitization step (0.05–3 × atmospheric), while the last heating step releases helium with systematically higher³He/⁴He ratio (30–80 × atmospheric). We suggest that this internal isotopic variability is the result of stepwise graphitization: the first heating step initiates graphitization, which nucleates around defects, and the second heating step graphitizes the relatively defect-free regions of the diamond. The³He/⁴He ratio measured, using the partial graphitization technique, differs by up to a factor of 100 within a single specimen. The inclusion-free fragments release small quantities of helium below 2000°C, which suggests that helium release is obtained only by graphitization. The³He contents of the monocrystalline diamonds are relatively constant (at 3 × 10⁻¹³ cm³ STP/gram) and indicate that most of the isotopic variability is due to radiogenic⁴He. The variations in⁴He content are either related to zoning of Th and U in the diamonds (i.e., in-situ decay), to zoning of inherited⁴He, or to implantation of α-particles from a Th and U rich environment (i.e., kimberlite). Because the Orapa diamonds were mined from roughly 40 m depth in the kimberlite, spallation reactions from cosmic ray interactions are not a significant source of³He. However, calculations based on the age of the kimberlite (90 m.y.) and reasonable Th and U abundances suggest that most of the³He in the Orapa diamonds could be produced by⁶Li(n, α)T in the diamond. Although this may not be true of all diamonds, nuclear reactions in the crust and mantle (including spallation reactions at the surface) can explain many of the high³He/⁴He ratios previously reported for diamonds.     

Turbulence measurements in a submarine canyon

Profiles of velocity turbulence in Monterey Canyon, made with a recently developed expendable probe, show the existence of a very turbulent bottom boundary layer. The turbulent flow is up to 170 m thick and has peak microscale shears of 1 m s⁻¹ per meter. The rate of dissipation of kinetic energy, based on the observed shear variance, averaged over the depth of the turbulent boundary layer ranged from 70 to 500 × 10⁻⁶W m⁻³. Temperature measurements indicate that the flow was up canyon at a time of low tide. The upper bound for the vertical eddy viscosity is estimated to be17 × 10⁻⁴m²s⁻¹ and for the vertical eddy diffusivity is estimated to be 15 × 10⁻⁴m²s⁻¹. The large vertical scale and the intensity of the observed boundary layer suggest that the flow in Monterey Canyon may be important for the renewal and circulation of water over the continental shelf in the bay area.     

Helium accumulation in groundwater, III. Limits on helium transfer across the mantle-crust boundary beneath Australia and the magnitude of mantle degassing

The groundwaters of the Great Artesian Basin (Australia) have been previously shown to be accumulating in-situ production helium for groundwaters ages < 50 kyr and an external helium flux equivalent to whole crustal production for groundwater ages > 100 kyr [1,2]. New helium isotope measurements show that the observed in-situ production helium (³He/⁴He 1.6 × 10⁻⁸) is isotopically distinct from the crustal degassing helium flux (³He/⁴He 6.6 × 10⁻⁸). Furthermore, the crustal degassing helium isotope ratio is marginally in excess of the whole crustal production ratio (³He/⁴He= 3.5 × 10⁻⁸) and the production ratio in a variety of continental rock types. This suggests that the upper limit on volatile transport across the mantle-crust boundary beneath the (relatively) stable and “complacent” Australian continent can be characterized by a “conductive-diffusive” helium/heat flux ratio of 2.6 × 10⁶⁴He atoms mW⁻¹ s⁻¹ which is two orders of magnitude less than the “intrusive-volcanic” ratio of 2.9 × 10⁸⁴He atoms mW⁻¹ s⁻¹ measured at the Galapagos [16]. These results constrain the transcrustal mantle degassing fluxes of⁴He and⁴⁰Ar to be much less than the mid-ocean ridge degassing fluxes; which are much less than the degassing of⁴He and⁴⁰Ar from continental crust. Thus, the degassing of the Earth's interior is dominated by magmatic processes but the dominant fluxes of⁴He and⁴⁰Ar to the atmosphere must come from the continental crust.     

Nickel isotope heterogeneity in the early Solar System

We report small but significant variations in the ⁵⁸Ni/⁶¹Ni-normalised ⁶⁰Ni/⁶¹Ni and ⁶²Ni/⁶¹Ni ratios (expressed as ε⁶⁰Ni and ε⁶²Ni) of bulk iron and chondritic meteorites. Carbonaceous chondrites have variable, positive ε⁶²Ni (0.05 to 0.25), whereas ordinary chondrites have negative ε⁶²Ni (− 0.04 to − 0.09). The Ni isotope compositions of iron meteorites overlap with those of chondrites, and define an array with negative slope in the ε⁶⁰Ni versus ε⁶²Ni diagram. The Ni isotope compositions of the volatile-depleted Group IVB irons are similar to those of the refractory CO, CV carbonaceous chondrites, whereas the other common magmatic iron groups have Ni isotope compositions similar to ordinary chondrites. Only enstatite chondrites have identical Ni isotope compositions to Earth and so appear to represent the most appropriate terrestrial building material. Differences in ε⁶²Ni reflect distinct nucleosynthetic components in precursor solids that have been variably mixed, but some of the ε⁶⁰Ni variability could reflect a radiogenic component from the decay of ⁶⁰Fe. Comparison of the ε⁶⁰Ni of iron and chondritic meteorites with the same ε⁶²Ni allows us to place upper limits on the ⁶⁰Fe/⁵⁶Fe of planetesimals during core segregation. We estimate that carbonaceous chondrites had initial ⁶⁰Fe/⁵⁶Fe < 1 × 10^− 7. Our data place less good constraints on initial ⁶⁰Fe/⁵⁶Fe ratios of ordinary chondrites but our results are not incompatible with values as high as 3 × 10^− 7 as determined by in-situ measurements. We suggest that the Ni isotope variations and apparently heterogeneous initial ⁶⁰Fe/⁵⁶Fe results from physical sorting within the protosolar nebula of different phases (silicate, metal and sulphide) that carry different isotopic signatures.     

Peak surface strains during strong earthquake motion

Peak amplitudes of surface strains during strong earthquake ground motion can be approximated by ε = Aν_max/β₁, where ν_max is the corresponding peak particle velocity, β₁ is the velocity of shear waves in the surface layer, and A is a site specific scaling function. In a 50 m thick layer with shear wave velocity β₁ 300 m/s, A 0·4 for the radial strain ε_rr, A 0·2 for the tangential strain ε_rθ, and A 1·0 for the vertical strain, ε_z. These results are site specific and representative of strike slip faulting and of soil in Westmoreland, in Imperial Valley, California. Similar equations can be derived for other sites with known shear wave velocity profile versus depth.     

The case for a martian origin of the shergottites, II. Trapped and indigenous gas components in EETA 79001 glass

Analysis of nitrogen and light noble gases in a large sample of glass (lithology C) from the antarctic shergottite EETA 79001 yields a minimumδ¹⁵N > +300‰ for the isotopic composition of nitrogen trapped in the glass. The new data fall on the mixing line through the martian atmospheric composition defined byδ¹⁵N vs.⁴⁰Ar/¹⁴N for two smaller samples analyzed previously. The results from all three samples are consistent with a two-component nitrogen system in which 84 ppb of trapped martian atmospheric N is mixed in variable proportions with another, more thermally labile N component during stepped heating. This second component, which appears to be indigenous to the glass rather than adsorbed from air and is present in amounts that vary by more than a factor of 3 from sample to sample, may represent volatiles from the martian interior. Data from crystalline phases of several SNC meteorites indicate that the indigenous gas may haveδ¹⁵N < −35‰ and³⁶Ar/¹⁴N 3 × 10⁻⁶, similar to the enstatite chondrites.Neon compositions in EETA 79001 glass samples suggest an earth-like value of 10.1 ± 0.7 for the unknown²⁰Ne/²²Ne ratio in the martian atmosphere. The nitrogen-argon correlation systematics yield trapped⁴⁰Ar/³⁶Ar= 2260 ± 200, within error of the Viking value. There is evidence that³⁶Ar/³⁸Ar in the martian atmosphere is4.1 ± 0.2, strikingly different from terrestrial or typical chondritic ratios near 5.3. Attribution of this low value to excess³⁸Ar generated over martian history by galactic cosmic-ray (GCR) spallation of surface materials would be difficult for a number of reasons, among them the excessive GCR fluences required and the absence of a corresponding²¹Ne excess.     

Implications for eruptive processes as indicated by sulfur dioxide emissions from K lauea Volcano, Hawai‘i, 1979–1997

K lauea Volcano, Hawai‘i, currently hosts the longest running SO₂ emission-rate data set on the planet, starting with initial surveys done in 1975 by Stoiber and his colleagues. The 17.5-year record of summit emissions, starting in 1979, shows the effects of summit and east rift eruptive processes, which define seven distinctly different periods of SO₂ release. Summit emissions jumped nearly 40% with the onset (3 January 1983) of the Pu‘u ‘ ‘ -K paianaha eruption on the east rift zone (ERZ). Summit SO₂ emissions from K lauea showed a strong positive correlation with short-period, shallow, caldera events, rather than with long-period seismicity as in more silicious systems. This correlation suggests a maturation process in the summit magma-transport system from 1986 through 1993. During a steady-state throughput-equilibrium interval of the summit magma reservoir, integration of summit-caldera and ERZ SO₂ emissions reveals an undegassed volume rate of effusion of 2.1×10⁵ m³/d. This value corroborates the volume-rate determined by geophysical methods, demonstrating that, for K lauea, SO₂ emission rates can be used to monitor effusion rate, supporting and supplementing other, more established geophysical methods. For the 17.5 years of continuous emission rate records at K lauea, the volcano has released 9.7×10⁶ t (metric tonnes) of SO₂, 1.7×10⁶ t from the summit and 8.0×10⁶ t from the east rift zone. On an annual basis, the average SO₂ release from K lauea is 4.6×10⁵ t/y, compared to the global annual volcanic emission rate of 1.2×10⁷ t/y.