Prognosis of the state （eutrophication and pollution） of freshwater ecosystems on the example of long-term research into Lake Baikal

Systematic （monthly） observations of changes in the components of trophic status in the pelagic zone of Baikal were carried out during years of spring blooms of almost pure cultures： Gymnodinium （1965）, Aulocoseira bai-calensis （1968）, Synedra acus （1969）, Nitzschia acicularis （1984 and 1987）, picocyanobacteria （2004-2005）. The research period coincided with various anthropogenic impacts on Baikal ecosystem： （1） the period of the natural state of the lake （until 1969）; （2） the period of weak anthropogenic impact （until 1985）; and （3） the period of acute anthropogenic impact. In the third period the following was found in the deep-water part of the lake： the episodic appearance of ammonium and nitrite nitrogen; change in the components of suspended matter （SM）; disturbed patterns of seasonal changes in SM content, chlorophyll-a, organic forms of carbon, nitrogen and phosphorus; the average annual concentrations of suspended organic carbon, nitrogen and phosphorus have increased considerably; the vertical distribution pattern of minerals and organic forms of nitrogen and phosphorus have been disturbed; finally, an observed inverse correlation between winter nitrogen content and the spring concentration of chlorophyll-a （1986-1989） would indicate the presence of toxins in the lake. This led to the study of POPs in Baikal and the Baikal region. Investigations undertaken during 2004-2005 in the pelagic coastal zones of the lake indicated the presence of toxic pollutants in southern Baikal （the correlation between winter nitrogen content and spring concentration of chlorophyll-a is inverse and equals 0.99 and 1.00 respectively）. Toxicants that enter the lake during the iced-over period mainly enter the trophogenic layer, as wastewaters are warmer than the lake waters, depress the development of endemic spring diatomic algae and lead to a rise in the trophic status.     

Stress–strain history from the geological evolution of the Orvieto and Radicofani cliff slopes (Italy)

The study proposes geological evolution models for the cliff slopes of the two Italian towns of Orvieto (Umbria) and Radicofani (Tuscany). The models were validated by the use of a stress–strain numerical modelling, implemented by the finite-difference code FLAC 5.0. The numerical modelling was approached in a sequential way, by assuming specific stiffness values related to the evolutionary stages. For this purpose, unconventional laboratory tests were performed aiming at reproducing the stress path related to the geological evolution model, using standard equipment for CID triaxial testing. The geological evolution models infer that deformation in both cases is driven by stress reduction. At the Orvieto plateau, stress reduction is induced by stress relief involving a tuff plate; in the case of Radicofani, stress reduction is due to stress release in consequence of lateral erosion of clay. Numerical simulations refine the lithotechnical zoning of the two investigated slopes, introducing a stress–strain criterion in addition to the conventional geological and geomechanical ones.     

History of the geological evolution of the Tsil’ma River basin (midle Timan) in the Devonian

The results of bio- and lithostratigraphic studies of the Givetian-Frasnian rocks in the Tsil’ma River basin are reported. They suggest regularities in sedimentation: distinct rhythmicity and similar succession in the structure of formations. We have identified five palynocomplexes that characterize the formations and make it possible to accomplish a confident biostratigraphic subdivision of sections. Their correlation with coeval complexes in the adjacent areas has been accomplished. The results made it possible to unravel specific features of miospore assemblages formed in the continental and coastal-marine facies.     

Formation Conditions of Basic Granulites and High-Alumina Gneiss of the Baikal–Muya Belt (Northern Baikal Area)

The Kichera zone of the Baikal–Muya Belt consists of alternating tectonic plates with rocks of different metamorphic facies. Garnet–cordierite–sillimanite gneiss from the tectonic fragment in granite–gneiss of the Baikal massif with an age of 755 ± 15 Ma from the Goremyka plate and two-pyroxene schist of the granulite complex with an age of 617 ± 5 Ma from the Boguchan plate were studied. Thermobarometric studies of these key metamorphic rocks were carried out using the avPT (THERMOCALC) and TWEEQU (TWQ 2.01) methods. The P–T parameters estimated for the cordierite?sillimanite gneiss of the Goremyka plate correspond to the boundary between the amphibolite and granulite facies. Granulites of the Boguchan plate belong to the HT–LP type. Exhumation of metamorphic rocks could be caused by extension upon the evolution of the Late Baikal rifting.     

Ore mineralization related to geological evolution of the Karkonosze–Izera Massif (the Sudetes,Poland) — Towards a model

The Karkonosze–Izera Massif is a large tectonic unit located in the northern periphery of the Bohemian Massif. It includes the Variscan Karkonosze Granite (about 328–304 Ma) surrounded by the following four older units:

• -Izera–Kowary (the Early Paleozoic continental crust of the Saxothuringian Basin),
• -Ještĕd (the Middle Devonian to Lower Viséan sedimentary succession deposited on the NE passive margin of the Saxothuringian Terrane), out of the present study area,
• -Southern Karkonosze (metamorphosed sediments and volcanics filling the Saxothuringian Basin), out of the present study area,
• -Leszczyniec (Early Ordovician, obducted fragment of Saxothuringian Basin sea floor).

The authors present a genetic model of ore mineralization in the Karkonosze–Izera Massif, in which ore deposits and ore minerals occurrences are related to the successive episodes of the geological history of the Karkonosze–Izera Massif:

• -formation of the Saxothuringian Basin and its passive continental margin (about 500–490 Ma)
• -Variscan thermal events:
  • -regional metamorphism (360–340 Ma)
  • -Karkonosze Granite intrusion (328–304 Ma)
• -Late Cretaceous and Neogene-to-Recent hypergenic processes.

The oldest ore deposits and ore minerals occurrences of the Karkonosze–Izera Massif are represented by pyrite and magnetite deposits hosted in the Leszczyniec Unit as well as by magnetite deposit and, presumably, by a small part of tin mineralization hosted in the Izera–Kowary Unit. All these deposits and occurrences were subjected to the pre-Variscan regional metamorphism.Most of the Karkonosze–Izera Massif ore deposits and occurrences are related to the Karkonosze Granite intrusion. This group includes a spatially diversified assemblage of small ore deposits and ore mineral occurrences of: Fe, Cu, Sn, As, U, Co, Au, Ag, Pb, Ni, Bi, Zn, Sb, Se, S, Th, REE, Mo, W and Hg located within the granite and in granite-related pegmatites, in the close contact aureole of the granite and within the metamorphic envelope, at various distances from the granite. Assuming world standards, all these deposits are now uneconomic. Various age determinations indicated that ore formation connected with the Karkonosze Granite might have taken place mostly between about 326 and 270 Ma.The last ore-forming episode in the Karkonosze–Izera Massif is related to hypergenic processes, particularly important in the northern part of the massif, in the Izera–Kowary Unit where some uranium deposits and occurrences resulted from the infiltration of ore solutions that originated from the weathering of pre-existing accumulations of uranium minerals. A separate problem is the presence of oxidation zones of ore deposits and occurrences, both the fossil and the recent.A full list of ore minerals identified in described deposits and occurrences of the Karkonosze–Izera Massif together with relevant, key references is presented in the form of an appendix.     

Crystallization history of Paleozoic granitoids in the Ol’khon region,Lake Baikal (SHRIMP-II zircon dating)

At the Center of Isotope Studies of the A.P. Karpinsky Russian Geological Research Institute, the structure and isotope composition of zircons from two granitoid complexes, the age of their sequential growth zones, and the hosted inclusions have been studied using a SHRIMP-II ion mass spectrometer. The zircons consist of deformed cores with crystalline melt inclusions and of shells: inner, with glassy, partly devitrified inclusions, and outer metamorphogene, with fluid inclusions. Judging from the zircon zoning, crystallization of melts of both complexes proceeded in several stages: (1) The generation of melts and the beginning of zircon core growth (505 and 493 Ma) were synchronous with the overthrusting in the Ol’khon region; (2) The rapid ascent of melts (the inner shell, 479 and 475 Ma) together with the host rocks was caused by upthrust faulting and shear dislocations; (3) The metamorphogene shell (456 Ma) reflects the second stage of metamorphism. At the same time, the Shara-Nur migmatite–granite complex corresponds in composition, structures, and textures to syncollisional K-granites, whereas the differentiated Khaidai gabbro-diorite–diorite–granodiorite–granite complex is close in geochemical features (similar to those of the Anga sequence metavolcanics) and the mantle (juvenile) source of substance to the recent island-arc magmatism. It is suggested that the Caledonian island-arc magmatism was close in time to the accretion of the sediments of back-arc basin (Ol’khon Group) to the continental margin, on the one hand, and to the island-arc block, on the other.     

Daily Course of CO2 Fluxes in the Atmosphere–Water System and Variable Fluorescence of Phytoplankton during the Open-Water Period for Lake Baikal according to Long-Term Measurements

The process of gas exchange of CO₂ in the atmosphere–water system and its relation to the daily course of variable fluorescence of phytoplankton is studied on the basis of long-term (2004–2014) measurements during the open water period for Lake Baikal. It is found that the decrease in photosynthetic activity of plankton is almost synchronous to the increase in the CO₂ flux from atmosphere to water. It follows from comparison of the spring and summer data with December measurements that the daily decrease in variable fluorescence of phytoplankton is caused by the internal daily rhythm of the photosynthetic activity of plankton.

     

Study of the elemental composition of suspended particles in large northern- Asian lakes (Baikal and Khubsugul)

Lakes Baikal (Russia) and Khubsugul (Mongolia) are rift freshwater water bodies. The maximal depth of Baikal is 1642 m, that of Khubsugul -238 m. One of the important aspects in the study of suspended matter is its geochemical composition which depends on…     

Integrated geophysical and geological methods to investigate the inner and outer structures of the Quaternary Mýtina maar (W-Bohemia,Czech Republic)

The Mýtina maar is the first known Quaternary maar in the Bohemian Massif. Based on the results of Mrlina et al. (J Volcanol Geother Res 182:97–112, 2009), a multiparametric geophysical (electrical resistivity tomography, gravimetry, magnetometry, seismics) and geological/petrochemical research study had been carried out. The interpretation of the data has provided new information about the inner structure of the volcanic complex: (1) specification of the depth of post-volcanic sedimentary fill (up to ~100 m) and (2) magnetic and resistivity signs of one (or two) hidden volcanic structures interpreted as intrusions or remains of a scoria cone. The findings at the outer structure of the maar incorporate the (1) evidence of circular fracture zones outside the maar, (2) detection and distribution of volcanic ejecta and tephra-fall deposits at the surface, and (3) indications from electrical resistivity tomography and gravity data in the area between the Mýtina maar and ?elezná h?rka scoria cone, interpreted as a palaeovalley, filled by volcaniclastic rocks, and aligned along the strike line (NW–SE) of the Tachov fault zone. These findings are valuable contributions to extend the knowledge about structure of maar volcanoes in general. Because of ongoing active magmatic processes in the north-east part of the Cheb Basin (ca. 15–30 km north of the investigation area), the Mýtina maar-diatreme volcano and surroundings is a suitable key area for research directed to reconstruction of the palaeovolcanic evolution and assessment of possible future hazard potential in the Bohemian Massif.     

Stages of Tectono-Magmatic Activity in the Border Zone of the Siberian Platform and the Tannuola–Khamsara Segment of the CAFB (According to the Results of U–Pb Isotope Studies)

Doklady Earth Sciences - Based on the dating of metamorphic and igneous rocks of the northeastern part of the Khamsara terrane, the main stages of tectono-magmatic activity at the border of two...     

Sources and Provenances of Late Cenozoic Sand Deposits of the Ol’khon Island (Baikal Rift Zone)

Doklady Earth Sciences - Geochronological (LA–ICP–MS) U–Th–Pb studies of detrital zircon of the Late Cenozoic sand deposits on Ol’khon Island have been performed. It...     

New finds of middle and late jurassic radiolarians in the siliceous-clayey and clastic rocks of the Nadan’khada-Bikin terrane (Jurassic accretionary wedge, western Sikhote Alin) and their geological significance

The lithostratigraphic analysis of the paleo-oceanic sediments in the Bikin segment of the Nadan’khada-Bikin terrane of the Jurassic accretionary wedge revealed late Bajocian and early to middle Bathonian radiolarians in the siliceous-clayey rocks constituting its southern part in the Perepelinaya-Cheremshanka and Kedrovka areas. Siltstones from the central part of the Bikin segment in the upper reaches of the Vasil’eka River contain radiolarians of the terminal late Tithonian age. Combined with the known dates available for siliceous-clayey rocks from the western part of the Nadan’khada Alin Range and the Ulitka-Zolotoi Klyuch area, these data made it possible to define three stages in the formation of the Bikin segment of the Nadan’khada-Bikin terrane of the accretionary wedge: the terminal Middle Jurassic, the late Tithonian, and the Berriasian. The formation of this segment lasted approximately 25 Ma.     

Structure of the Earth’s crust and tectonic evolution history of the Southern Indian Ocean (Antarctica)

The Southern Indian Ocean comprises large sedimentary basins of the Riiser-Larsen Sea (western sector); the Cosmonauts, Cooperation (Commonwealth), Davis seas (central sector); and the Mawson-d’Urville seas (eastern sector). The main tectonic provinces of the Southern Indian Ocean (Antarctica) have been outlined as a result of comprehensive interpretation of the geophysical data. Special attention is paid to determining the boundary between the rifted continental and oceanic crust. The basin of the Riiser-Larsen Sea was formed in the Early Jurassic under the action of the Karoo mantle plume. The intrusive complex, as a remote manifestation of the mantle plume, occurs along the inner boundary of the marginal rift. Opening of the ocean in the basin of Riiser-Larsen Sea started about 160 Ma ago and was characterized by rearrangement of plate motion and intense volcanic activity at the early stage. In the basin of the Cosmonauts, Cooperation, and Davis seas, the final stage of rifting was accompanied by the rise of the lithospheric mantle and by intrusive magmatism. The opening of the ocean started here 134 Ma ago. Emplacement of the Kerguelen plume resulted in jumping of ridges and detachment of continental crustal blocks from the Indian margin with the formation of the Kerguelen Plateau (microcontinent). The basin of the Mawson-d’Urville seas has evolved under conditions of long-term rifting since the Late Jurassic and is characterized by an extended zone of mantle unroofing. Breakup of the lithosphere between Australia and Antarctica developed asynchronously over a time interval of 95–65 Ma ago with propagation of MOR from the west eastward. The research was carried out using a great body of geophysical information (～140000 km of CDP seismic profiling, more than 250 stations of seismic refraction sounding, and more than 250000 km of magnetic and gravity profiles) obtained by expeditions from many countries over more than 30 years.     

The Late Pleistocene distribution of vicuñas (Vicugna vicugna) and the “extinction” of the gracile llama (“Lama gracilis”): New molecular data

We present the results of a palaeogenetic analysis of two Late Pleistocene camelids originating in southern Chile. Our analysis of two mitochondrial DNA fragments (control region and cytochrome b gene) reveals that these specimens do not belong to an extinct taxon, but rather to extant vicuña (Vicugna vicugna), whose modern distribution is restricted to the extreme elevations of the Andes, more than 3500 km to the north of where these specimens originated. Our results also suggest fossil specimens from Patagonia that are currently assigned to the extinct taxon Lama gracilis, may actually belong to V. vicugna, implying a continuous distribution of the latter from the southern tip of South America to the Andes during the Final Pleistocene. The haplotypes of both specimens are not present in modern populations, suggesting a loss of genetic diversity concomitant with the contraction of the vicuña geographical distribution during the Final Pleistocene or early Holocene.     

Radon in “nonradonic” ground waters of the Baikal region: Spatial and temporal variations

Based on the analysis of radon concentrations in several dozen springs and wells, three groups were distinguished for the waters classified as “nonradonic.” The spatial regularities of the distribution of these groups were revealed, along with the quantitative characteristic of the anomalies and the background, in view of their belonging to the Baikal and Transbaikal hydromineral provinces of the region.     

Platinum group element (PGE) geochemistry to understand the chemical evolution of the Earth’s mantle

Platinum group elements (PGE: Os, Ir, Ru, Rh, Pt, Pd) are important geochemical and cosmochemical tracers. Depending on physical and chemical behaviour the PGEs are divided into two subgroups: IPGE (Ir, Os, Ru) and PPGE (Pd, Pt, Rh). Platinum group elements show strong siderophile and chalcophile affinity. Base metal sulfides control the PGE budget of the Earth’s mantle. Mantle xenoliths contain two types of sulfide populations: (1) enclosed within silicate minerals, and (2) interstitial to the silicate minerals. In terms of PGE characters the included variety shows IPGE enriched patterns — similar to the melt-depleted mantle harzburgite, whereas the interstitial variety shows PPGE enriched patterns — resembling the fractionated PGE patterns of the basalt. These PGE characters of the mantle sulfides have been interpreted to be representative of multi-stages melting process of the mantle that helped to shape the chemical evolution of the Earth.