Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

Evolution of karst in Messinian gypsum (Monferrato,Northern Italy)

In the Tertiary Basin of Piedmont (Northern Italy) a 100-150 m thick Messinian sedimentary succession crops out, composed of pre-evaporitic clays, gypsum beds and post-evaporitic lacustrine-marine fine-grained sediments. In the Monferrato area the thickness of the evaporite sequence is highly variable (0-140 m) due to an important erosion surface formed at the end of the evaporite cycle and carved in the gypsum beds. Epigenic caves probably formed during this short intra-Messinian phase of emersion. Cave sediments contain benthonic and planctonic foraminiferal associations ranging in age from Burdigalian to Upper Pliocene. These sediments have probably been deposited in recent times, although it cannot be completely ruled out that they accumulated in caves developed in Upper Messinian times. The formation of the most important caves of this area probably started at the end of the Messinian under epigenic conditions. Possibly, those inherited caves enlarged slowly during the Quaternary in an intrastratal and confined hypogene karst system.     

Microstructure and geochemistry studies on Messinian gypsum deposits from the Northern Coast of Egypt

Messinian gypsum deposits from Dir El-Baraqan area, Northern Coast of Egypt, were investigated by stable sulfur isotope method, X-ray diffraction, infrared spectroscopy, optical microscopy, and scanning electron microscopy to differentiate features formed under substantial microbial influences as indicator of paleoenvironments. Petrographically, gypsum deposits were classified into three types: biolaminated gypsum, disordered selenite, and swallow-tail selenitic crystals. Biolaminated gypsum is characterized by regular alternating dark and light laminae, which were formed due to the seasonal environmental changes in Dir El-Baraqan area. Stable sulfur isotope data show that the gypsum deposits are characterized by δ³⁴S values ranging from +18.1 to +28.1 ‰. In swallow-tail gypsum, the δ³⁴S values are characterized by a narrow range (from +20.0 to +20.2 ‰) which is considered as the primary phase. In biolaminated gypsum, the δ³⁴S values ranged from +22.8 to +28.1 ‰ which is considered as the secondary phase. However, the white laminae are characterized by δ³⁴S values ranging from +22.8 to +24.1 ‰, while dark laminae are characterized by δ³⁴S values ranging from +27.2 to +28.1 ‰. The high δ³⁴S values of dark laminae revealed the increasing activity of sulfate-reducing bacteria.     

Origin and evolution of a salty gypsum/anhydrite karst spring: the case of Poiano (Northern Apennines, Italy)

Poiano is the largest karst spring of the Emilia Romagna region (northern Italy). It drains an aquifer of unique properties composed of anhydrite with halite lenses at depth and gypsum at the surface (both with high NaCl content). Hydrogeological research has been undertaken using automatically recorded hourly data on temperature, electrical conductivity, and water level. Water feeding the Poiano spring is restricted within the gypsum/anhydrite outcrop between the Lucola, Sologno and Secchia rivers. Karstification in the Upper Secchia Valley only concerns the gypsum rocks mainly present along the border and in the shallower parts of the sulfate outcrop and does not appear to occur at depth. Data strongly support the hypothesis that the salt content in the spring water derives from active halokinetic movements. For the first time, the fundamental hydrogeological importance of the anhydrite part inside the sulfate rocks is demonstrated. If gypsum prevails over anhydrite the karst drainage network can extend deep into the rocks following a network of fractures and fissures. Instead, if in the deep parts of the aquifer anhydrite prevails over gypsum, the karst evolution cannot take place at depth and the structure of the underground drainage paths only follows near-surface paths in gypsum.     

Deep-water clastic evaporites deposition in the Messinian Adriatic foredeep (northern Apennines,Italy): did the Mediterranean ever dry out?

A new genetic facies model for deep-water clastic evaporites is presented, based on work carried out on the Messinian Gessoso-solfifera Formation of the northern Apennines during the last 15 years. This model is derived from the most recent siliciclastic turbidite models and describes the downcurrent transformations of a parent flow mainly composed of gypsum clasts. The model allows clearer comprehension of processes controlling the production and deposition of clastic evaporites, representing the most common evaporite facies of the northern Apennines, and the definition of the genetic and stratigraphic relationship with primary shallow-water evaporites formed and preserved in marginal settings. Due to the severe recrystallization processes usually affecting these deposits, petrographic and geochemical analyses are needed for a more accurate interpretation of the large spectrum of recognized gravity-driven deposits ranging from debrisflow to low-density turbidites. Almost all the laminar ‘balatino’ gypsum, previously considered a deep-water primary deposit, is here reinterpreted as the fine-grained product of high to low-density gravity flows. Facies associations permit the framing of the distribution of clastic evaporites into the complex tectonically controlled depositional settings of the Apennine foredeep basin. The Messinian Salinity Crisis occurred during an intense phase of geodynamic reorganization of the Mediterranean area that also produced the fragmentation of the former Miocene Apennine foredeep basin. In this area, primary shallow-water evaporites equivalent to the Mediterranean Lower Evaporites, apparently only formed in semi-closed thrust-top basins like the Vena del Gesso Basin. The subsequent uplift and subaerial exposure of such basins ended the evaporite precipitation and promoted a widespread phase of collapse leading to the resedimentation of the evaporites into deeper basins. Vertical facies sequences of clastic evaporites can be interpreted in terms of the complex interplay between the Messinian tectonic evolution of the Apennine thrust belt and related exhumation–erosional processes. The facies model here proposed could be helpful also for better comprehension of other different depositional and geodynamic contexts; the importance of clastic evaporites deposits has been overlooked in the study of other Mediterranean areas. Based on the Apennine basins experience, it is suggested here that evaporites diffused into the deeper portions of the Mediterranean basin may consist mainly of deep-water resedimented deposits rather than shallow-water to supratidal primary evaporites indicative of a complete basin desiccation.     

Intra‐messinian gypsum palaeokarst in the Northern Apennines and its palaeogeographic implications

A short intra‐Messinian continental period has been recognised in some North Italian gypsum areas, mostly under the form of palaeokarst deposits. This emersion appears to have occurred only locally, and is explained as caused by the intra‐Messinian tectonic phase and a major sea level lowering. Evidences of this palaeokarst are mostly small, although at some places the palaeontological content of its fillings is of great importance. The discovery near Zola Predosa (Bologna) of a new intra‐Messinian extensive karst system and of its infilling sheds new light on the importance of this karst episode.     

Organic geochemical studies of a Messinian evaporitic basin,northern Apennines (Italy) I: Hydrocarbon biological markers for a hypersaline environment

This paper describes the occurrence and significance of hydrocarbons present in two bituminous marl layers and one distinct gypsum layer from a Messinian sedimentary basin, where hypersaline conditions prevailed. Several new compounds were detected and tentatively identified: of these 20R and 20S 4α, 24-dimethyl-5α(H),14β(H),17β(H) and 20R and 20S 4β,24-dimethyI-5α(H),14β(H),17β(H) cholestanes; 4-methylspirosterenes; 4,4-dimethyl-5α(H),14β(H),17β(H) pregnanes and homopregnanes are discussed in this paper. Several of these compounds might be considered as biological markers for a (hyper)saline environment. The short side chain 4-desmethylsteranes, 5α(H),14β(H),17β(H), 5α(H),14β(H),17α(H) and 5α(H),14α(H), 17α(H) pregnanes and homopregnanes, are the most abundant compounds in the extract from the gypsum sample. It is suggested that in this case these compounds do not reflect the stage of diagenesis but are related to certain organisms exclusively occurring in hypersaline environments. In addition the very low pristane/phytane ratio, often considered as an indicator for anoxicity, could also be interpreted as a useful indicator for hypersalinity.     

Passive‐roof thrusting in the Messinian Vena del Gesso Basin (Northern Apennines,Italy): constraints from field data and analogue models

We present the results of a study of the Vena del Gesso Basin (Romagna Apennines, Italy) integrating field analyses and analogue modelling. This basin represents one of the best‐preserved top‐thrust basins in the Northern Apennines foreland and is one of the few examples where primary evaporites, related to the Messinian salinity crisis of the Mediterranean, widely crop out. The structural style affecting the Messinian gypsum is examined to get insights into the mechanism responsible for the overall deformation features recognizable in the area. The evaporites are completely detached at the base and widespread back‐thrusts, repeatedly doubling these deposits, strongly contrast with the regional forelandward vergence of structures in the Apennines. On the basis of the comparison between field data and experimental results, the features characterising this area can be described as the result of the deformation linked to the sequential activation of an obliquely propagating passive‐roof duplex. Analogue models evidenced the major role played (1) by syntectonic erosion that promoted the development of passive‐roof duplex style, as well as (2) the role of décollement level pinch‐out that determined an oblique progression of deformation. Finally our data lead to reconsider the palaeoenvironmental reconstruction concerning the onset of the Messinian salinity crisis in the Mediterranean. Copyright © 2007 John Wiley & Sons, Ltd.     

Topography and palaeogeographic evolution of a middle Miocene foredeep basin plain (Northern Apennines, Italy)

The Marnoso–arenacea basin was a narrow, northwest–southeast trending, foredeep of Middle–Late Miocene age bounded to the southwest by the Apennine thrust front. The basin configuration and evolution were strongly controlled by tectonics.

Geometrical and sedimentological analysis of Serravallian turbidites deposited within the Marnoso–arenacea foredeep, combined with palaeocurrent data (turbidite flow provenance, reflection and deflection), identify topographic irregularities in a basin plain setting in the form of confined troughs (the more internal Mandrioli sub-basin and the external S. Sofia sub-basin) separated by an intrabasinal structural high. This basin configuration was generated by the propagation of a blind thrust striking northwest to southeast, parallel to the main trend of the Apennines thrust belt.

Ongoing thrust-induced sea bed deformation, marked by the emplacement of large submarine landslides, drove the evolution of the two sub-basins. In an early stage, the growth and lateral propagation of a fault-related anticline promoted the development of open foredeep sub-basins that were replaced progressively by wedge-top or piggy-back basins, partially or completely isolated from the main foredeep. Meanwhile, the depocenter shifted to a more external position and the sub-basins were incorporated within an accretionary thrust belt.     

Large reactivated landslides in weak rock masses: a case study from the Northern Apennines (Italy)

This case study paper is about a large rotational rock and earth slide—earth flow located in the Secchia River Valley, in the Northern Apennines of Italy, that has displayed multiple reactivation phases between 2002 and 2004. The main geological constraints of the mass movement are related to the overlap of flysch rock masses over clayey complexes that allows rock slides to take place in the source area. The disarrangement and weathering of rock masses following slope movements causes large amount of fine-grained debris to be accumulated on the slope and mobilised by earth sliding and flowing. Analysis of rainfall data at the onset of reactivation events has proved that they occurred after periods with cumulated values higher than the averages of the last 30 years. The quantification of the morphological modifications induced by these reactivations has been made possible by comparing pre- and post-event digital elevation models. Depletion and accumulation has been in the range of 30 m in different parts of the slope. In particular, an advancement of the landslide toe of more than 400 m, which caused a 30-m thick landslide tip to deposit, has been clearly seen. Monitoring data regarding subsurface movements and surface tension crack widening (tension cracks so large as to be properly described at trenches) has shown that sliding surfaces as deep as 43 m exist in the upper part of the landslide, while the accumulation lobe has moved by sliding and flowing over surfaces as deep as some 10 m. Velocities of cm/day have been recorded in the deep surfaces and in widening trenches of the source area, while the advancement of the accumulation lobe has been estimated as having velocities of up to 10 m/day. Groundwater in the landslide body has been observed at depths of 5–15 m in the upper areas, while it is estimated as being at the ground level in the toe. On this basis, it is concluded that the landslide still has a high potential for further development, both in the upper landslide zone and in the toe area.     

Geochemical mapping based on geological units: a case study from the Marnoso-arenacea formation (Northern Apennines,Italy)

Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyze their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso-arenacea formation. This middle–upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyzes) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain-sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.     

蒸发岩中硫同位素的地球化学特征及其沉积学意义——以思茅盆地MZK- 3井为例

思茅盆地目前是中国唯一的含古代固体钾盐矿床的沉积盆地,其钾盐形成时代、物源特征、海侵方向等多年来一直存在争议。本文依据海相硬石膏的形成条件、存在形式、同位素分馏机理,重点分析了盆地内MZK-3井蒸发岩硫同位素的地球化学特征。结果表明:①岩盐中的硬石膏在蒸发盆地析岩盐阶段即可形成,单独成层的硬石膏是由原始沉积的石膏经历了沉积埋藏升温进而脱水而成;②岩盐中硬石膏的硫同位素值具有"双峰"特征,分别为14‰～16‰和8‰～10‰或6‰～8‰,这体现了硫酸盐的双重来源——原始海水中的硫酸盐和陆源淡水输入的硫酸盐或火山活动提供的硫源;③硬石膏层的硫同位素在区域上具有对比性,结合~(87)Sr/~(86)Sr值的特征,认为其代表了海相的沉积环境;④硬石膏层的硫同位素值平面上由南向北降低,可能反映了在此方向陆源淡水或火山活动对蒸发岩盆地的影响逐渐增强,进而说明这可能也是海侵的方向。可见对硬石膏硫同位素的研究,不仅在沉积学上能揭示物源、沉积环境、海侵方向等信息,更能对研究区钾盐矿床勘查提供有益的参考。     

Tectono-sedimentary analysis of a complex,extensional, Neogene basin formed on thrust-faulted,Northern Apennines hinterland: Radicofani Basin,Italy

Large NW–SE oriented, Neogene–Quaternary structural depressions, up to about 200 km long and 25 km wide, have developed on the western side (hinterland) of the Northern Apennines over thrust substrate. The depressions are now, for the most part, laterally bounded by normal faults and are longitudinally separated into basins by transfer zones. A debate exists in the literature as to whether these basins have developed as half-graben under a predominantly extensional regime since late Miocene, or as thrust-top basins under a predominantly compressional regime that has continued until the Pleistocene. The Radicofani Basin is one of the best-preserved basins. It developed mainly during the late Miocene–Early Pliocene in the southern half of the Siena–Radicofani structural depression, and is now bounded on the east by normal faults that transect a thrust anticline “nose“ in the substrate, to the north by a substrate high or transfer zone, and to the south and west by Quaternary igneous/volcanic edifices. The basin experienced variable differential tectonic and associated sedimentation along linking, normal boundary faults. Along its eastern margin it shows the development of thick (∼600 m) alluvial fans that developed in relay areas between boundary faults and transverse faults and transfer zones. Well-exposed sections generally show upward transitions from conglomeratic alluvial fans, to shoreface sandstone, to offshore mudstones. Locally, the transition is marked by deltas primarily characterised by thick gravelly, sandy, stacked cross-sets The thicker, sandy-gravel to gravelly-sand cross-sets (5–8 m thick) are interpreted as Gilbert-type deltas; interstratified thinner (0.5–1 m thick), generally openwork gravelly strata are part of delta topset assemblages and probably represent prograding fluvial bars. Tectonic movements provided the accommodation space for the total, ∼2700 m thick basin fill. Sea level fluctuations that led to the repeated development of the cross-sets may also have been influenced by climatic or eustatic changes, possibly related to the effects of early Antarctic glaciations.Some features of the Radicofani Basin can be found in both extensional and compressional basins. However, the position of the basin in the mountain chain and the development of alluvial fans, fandeltas and associated deposits along the main boundary fault, combined with structural evidence from seismic lines, show that during the early Pliocene this basin best conforms to existing models of half-graben.     

Detection of detached forced-regressive nearshore wedges: a case study from the central-southern Siena Basin (Northern Apennines, Italy)

The detection of detached nearshore wedges formed in response to relative sea-level drops is considered one of the hottest topics in sequence stratigraphic analysis due to their importance as reservoir analogues. In fact, they usually constitute sandy and porous bodies generally encased in impermeable clay, thus presenting a good potential as traps for fluids. This paper focuses on the sequence stratigraphic analysis of the Pliocene deposits cropping out in the central-southern sector of the Siena Basin (Tuscany, Italy), a post-collisional basin of the Northern Apennines. The exposed sedimentary succession was investigated through a detailed sedimentological and stratigraphic approach, integrated by biostratigraphic analyses, aimed at a better characterization of the infilling history of this sector of the basin. Specifically, this study revealed the occurrence of repeated facies shifts that allowed the identification of two depositional sequences. In detail, a thick sand-rich body far from the basin margins, and previously considered as a turbiditic lobe, has been reinterpreted as formed in a nearshore setting during a fall in relative sea level. This body is totally encased in offshore clay, and due to the lack of physical connection with the related HST deposits, it has to be considered as a detached forced-regressive wedge. The present work led to the recognition of some sedimentological and stratigraphic features typical of falling stage systems tract deposits (e.g. presence of intrabasinal recycled materials, sedimentological evidence of a pre-existing fluvial network subsequently eroded) that can provide useful clues for the identification of detached forced-regressive nearshore wedges in core studies and poorly exposed settings.     

The architecture of an incipient oceanic basin: a tentative reconstruction of the Jurassic Liguria-Piemonte basin along the Northern Apennines–Alpine Corsica transect

In this paper, a scenario for the early evolution of the Jurassic oceanic Liguria-Piemonte basin is sketched. For this purpose, four selected examples of ophiolite sequences from the Northern Apennines and Corsica are described and analyzed. In the External Ligurian units (Northern Apennines), the ocean–continent transition of the Adria plate was characterized by a basement made up of subcontinental mantle and lower continental crust, covered by extensional allochthons of upper crust. Both, the basement rocks and the extensional allochthons are cut by basaltic dikes and covered by basalts and pelagic deposits. The conjugate ocean–continent transition of the Corsica margin, represented by the Balagne nappe (Corsica), was composed of mantle peridotites and gabbros covered by basaltic flows and minor breccias, that in addition include continent-derived clasts. By contrast, the innermost (i.e., closest to the ocean) preserved area observed in the Internal Ligurian (Northern Apennines) and Inzecca (Corsica) units consists of former morphological highs of mantle peridotites and gabbros, bordered by small basins where the basement is covered by a volcano-sedimentary complex, characterized by ophiolitic breccias and cherts interlayered with basaltic flows. The overall picture resulting from our reconstructions suggests an asymmetric architecture for the Liguria-Piemonte basin with a central area bounded by two different transition zones toward the continental margins. This architecture can be interpreted as the result of a rifting process whose development includes a final stage characterized by passive, asymmetric extension of the lithosphere along an east-dipping detachment fault system.     

Organic geochemical studies of a Messinian evaporitic basin, northern Apennines (Italy)—II Isoprenoid and n-alkyl thiophenes and thiolanes

Series of n-alkyl and isoprenoid thiophenes and thiolanes, most of which have not been previously reported, have been identified in an extract from a Messinian (Upper Miocene) marl layer deposited under hypersaline, euxinic conditions. The identifications were based on mass spectra and Chromatographic data of synthesized reference compounds and on comparison of mass spectra, relative retention times and response on the FPD. Their specific structures and their distribution patterns show similarities with those of the alkanes. Inorganic sulphur is therefore considered to be incorporated into specific lipid moieties from (archae)bacterial and/or algal input during diagenesis. A biosynthetic origin of these compounds is also possible, however. The organic sulphur compounds encountered are thought to be indicators of a hypersaline depositional environment.     

Isotopic abundances of water of crystallization of gypsum from the Miocene evaporite formation,Carpathian Foredeep,Poland

For sulfates of Miocene evaporites in the Carpathian Foredeep, the waters of crystallization of gypsum (w.c.g.) have $\text{δD = ?38 to ?113\%.}$ and $\text{δ}{}^{18}\text{O = 0 to ?11\%.}$ (SMOW). The $\text{δ}{}^{34}\text{S}$ and $\text{δ}{}^{18}\text{O}$ values of the sulfates are uniform and consistent with a marine origin. It is proposed that the original w.c.g. was equilibrated with marine water. Subsequently, it re-equilibrated towards very isotopically light water (δD ～ ?100%., δ¹⁸O ～ ?14%) during a glacial or postglacial period and is now trending towards current waters circulating through the deposits (δD ～ ?50%., δ¹⁸ ～ ?7%). The extent of reequilibration increased with decreasing crystal size.     

Late Miocene fish otoliths from the Colombacci Formation (Northern Apennines,Italy): implications for the Messinian ‘Lago‐mare’ event

A fish otolith assemblage from the Messinian ‘Lago‐mare’ deposits of the Colombacci Formation cropping out in the Montecalvo in Foglia Syncline, Marche, central Italy, is described. The assemblage displays a low diversity and consists of seven taxa belonging to three families: the Gobiidae, Myctophidae and Sciaenidae. Sciaenid otoliths are the most abundant elements representing 88% of the entire assemblage. The palaeoecological analysis reveals a coastal shallow marine environment strongly influenced by continental outflow. The low diversity and high abundance of the euryecious sciaenids are indicative of a very simplified food web, which probably represented an ecological response to the fluctuating environmental parameters and available food resources. The fish remains documented here provide an unambiguous evidence that normal marine conditions were present in the Mediterranean, at least in the upper part of the ‘Lago‐mare’ event, and unquestionably demonstrate that the marine refilling preceded the Mio‐Pliocene boundary. These findings clearly demonstrate that fishes, because of their mobility and migratory behaviour, represent a useful tool for the large‐scale interpretation of the environmental conditions of the Messinian Mediterranean water body. The necessity of a new scenario of palaeoenvironmental evolution for the post‐evaporitic Messinian of the Mediterranean is also discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Geochemical mapping based on geological units: A case study from the Marnoso-arenacea formation (Northern Apennines,Italy)

Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyse their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso–Arenacea formation. This Middle-Upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso Arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyses) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain- sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.     

Tectono-sedimentary evolution of the External Liguride units (Northern Apennines,Italy): insights in the pre-collisional history of a fossil ocean-continent transition zone

Abstract

In the Northern Apennines, the External Liguride (EL) units are interpreted as derived from the domain that joined the Ligure–Piemontese oceanic basin to the Adriatic plate continental margin. The EL units can be divided into two different groups according to the lithostratigraphic features of the basal complexes underlying the Upper Cretaceous–Lower Tertiary carbonate flysch (e.g. Helminthoid flysch). The first group includes the western successions characterized by Santonian–Campanian sedimentary melanges where slide blocks of lherzolitic mantle, gabbros, basalts, granulites, continental granitoids are represented. The second group is represented by the eastern successions where the Cenomanian–Campanian basal complexes mainly consist of sandstones and conglomerates where the mafic and ultramafic rocks are scarce or completely lacking. Their original substrate is represented by the Middle Triassic to Lower Cretaceous, mainly platform carbonate deposits, found as slices at the base of the eastern successions.

The stratigraphic features shown by the basal complexes allow the reconstruction of their source area that is assumed to be also representative for the pre-Upper Cretaceous setting. The proposed reconstruction suggests the occurrence in the EL domain of two distinct domains. The eastern domain was characterized by a thinned and faulted continental crust belonging to the Adriatic continental margin. The western domain was instead floored by subcontinental mantle associated with lower and upper continental crust, representing the ocean–continent transition. This setting is interpreted as the result of the opening of the Ligure–Piemontese oceanic basin by passive rifting, mainly developed by simple shear, asymmetric extension of the continental crust. © 2001 Éditions scientifiques et médicales Elsevier SAS