Crustal structure of the Central Precordillera of San Juan,Argentina (31°S) using teleseismic receiver functions

The subduction of the Nazca plate under the South American plate around 31°S is characterized by flat slab geometry. The (Chilean) Pampean flat slab of Argentina associated with the subduction of the Juan Fernandez ridge lies in a region of a series of foreland uplifts corresponding to the thin-skinned Precordillera and basement cored Sierras Pampeanas ranges. The SIEMBRA project deployed 40 broadband stations in 2008–2009 in both the Precordillera and the Sierras Pampeanas with the aim to foster the understanding of the entire central Andean flat slab region. One of the SIEMBRA station (DOCA) located on the western flank of Sierra de la Invernada in the Central Precordillera appears particularly appropriate to study the crustal structure and eventually detect discontinuities related to terranes establishment. We thus performed a receiver function analysis using teleseismic data recorded at the DOCA station during the SIEMBRA project and from October 2011 to June 2012 using a broadband UNSJ (National University of San Juan) seismic station with the purpose to obtain crustal images with details of the intracrustal structure consistent with a mechanism that could explains both the observed earthquake depths and the uplift pattern in the Central Precordillera. Our results show that the Moho beneath the Precordillera lies at a depth of about 66 km. The Moho signal appears diminished and behaves irregularly as a function of azimuthal orientations. Although this observation could be the result of an irregular geometry it also correlates with the hypothesis of partial eclogitisation in the lower crust. Two mid-crustal discontinuities have also been revealed. The shallower one could correspond to a décollement level between the Precordilleran strata and the Cuyania basement at 21 km depth. The deeper one which the presence has been matched with a sharp decrease of the crustal seismic activity drove us to the hypothesis of a major change in crustal composition at 36 km. Finally the flat portion of the subducted slab has been imaged lying at about 100 km depth.     

Geodynamic evolution of the Eastern Sierras Pampeanas (Central Argentina) based on geochemical, Sm–Nd, Pb–Pb and SHRIMP data

Whole-rock geochemical analyses using major and trace elements in combination with the Sm–Nd and Pb–Pb isotope systems, together with SHRIMP age dating on metasedimentary rocks from the Sierras de Chepes, the Sierras de Córdoba, the Sierra Norte and the San Luis Formation in the Sierra de San Luis, have been carried out to unravel the provenance and the geodynamic history of the Eastern Sierras Pampeanas, Central Argentina. The geochemical and the Sm–Nd data point to a slightly stronger mafic and less-fractionated material in the provenance area of the Sierras de Córdoba when compared to the other units. The T_DM model ages from the Sierras de Chepes (~1.82 Ga) and the Sierra Norte (~1.79 Ga) are significantly older than the data from the Sierras de Córdoba (1.67 Ga). The Pb data are homogeneous for the different units. Only the ²⁰⁸Pb/²⁰⁴Pb ratios of some samples from the Sierras de Córdoba are higher. A late Pampean detrital zircon peak around 520 Ma from the Sierras de Chepes is in accordance with the new data from the San Luis Formation. This is similar to the literature data from the Famatina Belt located to the northwest of the Sierras de Chepes and also fits the detrital zircon peaks in the Mesón group. These maximum depositional ages were also reported from some locations in the Puncoviscana Formation but are absent in the Sierras de Córdoba. An improved model for the development of the Eastern Sierras Pampeanas in the area between the Sierras de Córdoba and the Puncoviscana Formation is provided. This gives new insights into the late Pampean development of the Sierra de San Luis and the complex development of the Eastern Sierras Pampeanas. This new model explains the younger detrital ages in the Puncoviscana Formation compared with the older ages of the Sierras de Córdoba. Another model of the Sierra de San Luis explains the younger depositional ages of the Pringles Metamorphic Complex and the San Luis Formation when compared to the Nogolí Metamorphic Complex and the Conlara Metamorphic Complex. Additionally, the rather fast change of the high-grade metamorphic conditions in the Pringles Metamorphic Complex and the low-grade metamorphic conditions in the San Luis Formation is explained by extension, the ascent of (ultra) mafic material and later folding and erosion.     

Archosauriform remains from the Late Triassic of San Luis province,Argentina, Quebrada del Barro Formation,Marayes–El Carrizal Basin

Here we present archosauriform remains from ‘Abra de los Colorados’, a fossiliferous locality at Sierra de Guayaguas, NW San Luis Province. Two fossiliferous levels were identified in outcrops of the Quebrada del Barro Formation (Norian), which represent the southernmost outcrops of the Marayes–El Carrizal Basin. These levels are composed by massive muddy lithofacies, interpreted as floodplain deposits. The specimens consist of one incomplete maxilla (MIC-V718), one caudal vertebra (MIC-V719), one metatarsal (MIC-V720) and one indeterminate appendicular bone (MIC-V721). The materials can be assigned to Archosauriformes but the fragmentary nature and lack of unambiguous synapomorphies preclude a more precise taxomic assignment. The maxilla is remarkably large and robust and represents the posterior process. It preserved one partially erupted tooth with ziphodont morphology. This bone shows some anatomical traits and size match with ‘rauisuchians’ and theropods. MIC-V719 corresponds to a proximal caudal vertebra. It has a high centrum, a ventral longitudinal furrow, expanded articular processes for the chevrons, a posteriorly displaced diapophysis located below the level of the prezygapophyses, and short prezygapophyses. This vertebra would be from an indeterminate archosauriform. MIC-V720 presents a cylindrical diaphysis, with a well-developed distal trochlea, which present resemblances with metatarsals of theropods, pseudosuchians, and silesaurids, although the size matches better with theropods. MIC-V721 has a slender diaphysis and a convex triangular articular surface, and corresponds to an indeterminate archosauriform. Despite being fragmentary, these materials indicate the presence of a diverse archosauriforms association from Late Triassic beds of San Luis. Thus, they add to the faunal assemblage recently reported from this basin at San Juan Province, which is much rich and diverse than the coeval paleofauna well known from Los Colorados Formation in the Ischigualasto–Villa Union Basin.     

Petrology, geochemistry and mineralization of the Las Águilas and Virorco mafic–ultramafic bodies, San Luis Province, Argentina

The layered mafic–ultramafic rocks in the Sierras de San Luis, Argentina (Las Águilas, Las Higueras and Virorco), constitute a 3–5-km-wide belt that extends over 100 km from NE to SW. They carry a sulphide mineralization consisting of pyrrhotite, pentlandite and chalcopyrite, in veins and as disseminated to massive ore. Disseminated spinels are frequently associated with the sulphide minerals as well as platinum group minerals. A strong correlation between S, Ni, Co, Cu, Cr, Pt and Pd indicates the presence of one to three levels of mineralization within the ultramafic units. The maximum concentration of these elements coincides with the units containing platinum group minerals (PGM) and spinel group minerals. This clear relationship constitutes a good prospecting guide in the search for layers with high-grade ore, probably associated with deeper stratigraphic levels where ultramafic rocks are dominant. The bulk rock chemistry and concentrations of metals and platinum group elements as well as textural evidence suggest that the parental magma was mafic with tholeiitic affinities and MgO rich. The Las Águilas layered mafic–ultramafic body and the remaining bodies in the area bear similar characteristics to well-known stratified complexes developed in extensional tectonic regimes, as it is the case of Jinchuan (China), Kabanga (Tanzania) and Fiambala (Argentina).     

Mesozoic and Cenozoic structural deformation in the NW Tarim Basin,China: a case study of the Piqiang–Selibuya Fault

The Piqiang–Selibuya Fault is the most significant fault in the NW Tarim Basin, China. It has attracted increasing attention because of the discovery of a series of oil (gas) fields in and around the fault zone. The structural characteristics and evolution of the Piqiang–Selibuya Fault remain controversial. Field geological surveys and seismic data interpretation reveal that the fault has experienced three stages of activity. The thicknesses of the Permian and Miocene strata on opposing sides of the fault are clearly different, and these reveal that the fault has experienced two stages of significant thrusting. The first stage took place at the end of the Triassic and was associated with the Qiangtang Block amalgamated to the south margin of Eurasia. The second stage occurred at the end of the Miocene and might have been caused by the northwards overthrusting of the Pamir. These two stages of thrusting led to the lower–middle Cambrian detachment layer in the eastern part of the Keping thrust belt being 2 km shallower than in the western part. Since the Pliocene, the southern Tien Shan orogenic belt has been reactivated and thrust towards the interior of the Tarim Basin, and a series of ENE–WSW-trending thrust sheets have formed in the Keping thrust belt. Because of the different depth of the detachment layer on the opposing sides of the Piqiang–Selibuya Fault, the number and spacing of thrust sheets formed to the east of the fault differ from those to the west. This dissimilar deformation led to the strike–slip displacement on the Piqiang–Selibuya Fault. The three stages of fault activity record three important tectonic events in the NW Tarim Basin. Qualitative analysis of this activity helps us better understand the influence of the far-field effect of the collisions that occurred on the southern margin of the Eurasia plate on the structural deformation of the NW Tarim Basin.     

From intra-oceanic subduction to arc accretion and arc-continent collision: Insights from the structural evolution of the Río San Juan metamorphic complex,northern Hispaniola

The Río San Juan metamorphic complex exposes a segment of a high-pressure subduction-accretionary complex built during Caribbean island arc-North America continental margin convergence. It is composed of accreted arc- and oceanic-derived metaigneous rocks, serpentinized peridotites and minor metasediments forming a structural pile. Combined detailed mapping, structural and metamorphic analysis, and geochronology show that the deformation can be divided into five main events (D1–D5). An early subduction-related D1 deformation and M1 metamorphism produced greenschist (mafic rocks of the Gaspar Hernández peridotite-tectonite), blueschist and eclogite (metamafic blocks in the Jagua Clara mélange), high-P epidote-amphibolite and eclogite (Cuaba unit), and lower blueschist and greenschist-facies conditions (Morrito unit). This was followed by M2 decompression and cooling in the blueschist, greenschist and low-P amphibolite-facies conditions. The shape of the retrograde P-T path, the age of the exhumation-related D2 structures, and the tectonic significance of D2 deformation are different in each structural unit. Published U–Pb and ⁴⁰Ar/³⁹Ar plateau ages and T-t/P-t estimations reveal diachronic Turonian-Coniacian to Maastrichtian retrograde M2 metamorphism in the different structural units of the complex, during a consistent D2 top-to-the-NE/ENE tectonic transport. Regionally, a similar top-to-the-ENE tectonic transport also took place in the metasedimentary nappes of the Samaná complex during the Eocene to earliest Miocene. This kinematic compatibility indicates a general northeastward progradation of deformation in the northern Caribbean convergent margin, as the successive tectonic incorporation of arc, oceanic and continental-derived terrains to the developing Caribbean subduction-accretionary complex took place. D3–D5 deformations are discontinuous and much less penetrative, recording the evolution from ductile to brittle conditions of deformation in the complex. The D3 event substantially modified the nappe-stack and produced open folds with amplitudes up to kilometer-scale. The Late Paleocene-Eocene D4 structures are ductile to ductile–brittle thrusts and inverse shear bands. D5 is a Tertiary, entirely brittle deformation that had considerable influence in the geometry of the whole complex. From the Miocene to the Present, it has been cut and laterally displaced by a D5 sinistral strike-slip fault system associated with the Septentrional fault zone.     

The Neoproterozoic–Phanerozoic section of the Anabar–Lena province: structural framework,geological model,and petroleum potential

Much work at A.A. Trofimuk Institute of Petroleum Geology and Geophysics (Novosibirsk) has been done to synthesize geological and geophysical data from the Siberian Arctic and Arctic shelf. Namely, seismic-geological modeling and petroleum potential assessment have been performed for the Neoproterozoic–Phanerozoic section of the Anabar–Lena province in the northern Sakha Republic (Yakutia). The results include seismic-geological division, a set of structural maps, and structural, paleotectonic, and facies analysis. The study shows that Riphean, Vendian, Cambrian, and Permian sequences are of interest in terms of petroleum potential; oil and gas may accumulate in traps of different types.     

Conjugation with the Central Asian Foldbelt: Interpretation of the 3DV and Tynda–Amurzet Transects

In this paper we consider the results of geological interpretation of 3DV (Tommot–Skovorodino segment) and Tynda–Amurzet geophysical transects crosscutting the Aldan Shield and the Stanovoi Granite–Greenstone Domain of the Siberian Platform; the Selengino–Stanovoi, Mongolia–Okhotsk, and Gobi–Hinggang foldbelts; and the Argun and Mamyn microcontinents with a total extent of sections of about 1000 km and depth of about 40 km. The data of previous studies and follow-up electric conductivity information have been used. The data of geological mapping, subject studies, and insights into the deep-seated structure of the considered territory obtained with a complex of geophysical methods are discussed. It is shown that Mesozoic strike-slip and thrust faults play the leading role in the present-day structure of the territory and in control rifting and mantle diapirism. It is suggested that Californian-type metamorphic nuclei, which are of structure-forming significance for adjacent territories in the west, have also developed in the studied region.     

Recent progress on combining geomorphological and geochronological data with ice sheet modelling,demonstrated using the last British–Irish Ice Sheet

Palaeo-ice sheets are important analogues for understanding contemporary ice sheets, offering a record of ice sheet behaviour that spans millennia. There are two main approaches to reconstructing palaeo-ice sheets. Empirical reconstructions use the available glacial geological and chronological evidence to estimate ice sheet extent and dynamics but lack direct consideration of ice physics. In contrast, numerically modelled simulations implement ice physics, but often lack direct quantitative comparison with empirical evidence. Despite being long identified as a fruitful scientific endeavour, few ice sheet reconstructions attempt to reconcile the empirical and model-based approaches. To achieve this goal, model-data comparison procedures are required. Here, we compare three numerically modelled simulations of the former British–Irish Ice Sheet with the following lines of evidence: (a) position and shape of former margin positions, recorded by moraines; (b) former ice-flow direction and flow-switching, recorded by flowsets of subglacial bedforms; and (c) the timing of ice-free conditions, recorded by geochronological data. These model–data comparisons provide a useful framework for quantifying the degree of fit between numerical model simulations and empirical constraints. Such tools are vital for reconciling numerical modelling and empirical evidence, the combination of which will lead to more robust palaeo-ice sheet reconstructions with greater explicative and ultimately predictive power.     

Geology of the epithermal Ag–Au Huevos Verdes vein system and San José district, Deseado massif, Patagonia, Argentina

The San José district is located in the northwest part of the Deseado massif and hosts a number of epithermal Ag–Au quartz veins of intermediate sulfidation style, including the Huevos Verdes vein system. Veins are hosted by andesitic rocks of the Bajo Pobre Formation and locally by rhyodacitic pyroclastic rocks of the Chon Aike Formation. New ⁴⁰Ar/³⁹Ar constraints on the age of host rocks and mineralization define Late Jurassic ages of 151.3 ± 0.7 Ma to 144.7 ± 0.1 Ma for volcanic rocks of the Bajo Pobre Formation and of 147.6 ± 1.1 Ma for the Chon Aike Formation. Illite ages of the Huevos Verdes vein system of 140.8 ± 0.2 and 140.5 ± 0.3 Ma are 4 m.y. younger than the volcanic host rock unit. These age dates are among the youngest reported for Jurassic volcanism in the Deseado massif and correlate well with the regional context of magmatic and hydrothermal activity. The Huevos Verdes vein system has a strike length of 2,000 m, with several ore shoots along strike. The vein consists of a pre-ore stage and three main ore stages. Early barren quartz and chalcedony are followed by a mottled quartz stage of coarse saccharoidal quartz with irregular streaks and discontinuous bands of sulfide-rich material. The banded quartz–sulfide stage consists of sulfide-rich bands alternating with bands of quartz and bands of chlorite ± illite. Late-stage sulfide-rich veinlets are associated with kaolinite gangue. Ore minerals are argentite and electrum, together with pyrite, sphalerite, galena, chalcopyrite, minor bornite, covellite, and ruby silver. Wall rock alteration is characterized by narrow (< 3 m) halos of illite and illite/smectite next to veins, grading outward into propylitic alteration. Gangue minerals are dominantly massive quartz intergrown with minor to accessory adularia. Epidote, illite, illite/smectite, and, preferentially at deeper levels, Fe-chlorite gangue indicate near-neutral pH hydrothermal fluids at temperatures of >220°C. Kaolinite occurring with the late sulfide-rich veinlet stage indicates pH < 4 and a temperature of <200°C. The Huevos Verdes system has an overall strike of 325°, dipping on average 65° NE. The orientations of individual ore shoots are controlled by vein strike and intersecting north-northwest-striking faults. We propose a structural model for the time of mineralization of the San José district, consisting of a conjugate shear pair of sinistral north-northwest- and dextral west-northwest-striking faults that correspond to R and R′ in the Riedel shear model and that are related to master faults (M) of north-northeast-strike. Veins of 315° strike can be interpreted as nearly pure extensional fractures (T). Variations in vein strike predict an induced sinistral shear component for strike directions of >315°, whereas strike directions of <315° are predicted with an induced dextral strike–slip movement. The components of the structural model appear to be present on a regional scale and are not restricted to the San José district.     

The Cambrian–Ordovician diorite–granodiorite–granite association of the Mamyn Terrane (Central Asian Fold Belt): U–Pb geochronological and geochemical data

Doklady Earth Sciences - New results of U–Pb geochronological and geochemical studies of rocks that form two structurally different massifs in the Mamyn Terrane are presented here. It has...     

Kinematic analysis of a transtensional fault system: The Atuel depocenter of the Neuquén basin,southern Central Andes,Argentina

The Atuel depocenter of the Neuquén basin originated as an Upper Triassic to Lower Jurassic rift system, later inverted during the Andean contractional deformation. In order to study the extensional architecture and the kinematic evolution of this depocenter, we collected a large amount of field and sub-surface data, consisting of slip data from outcrop-scale normal faults, thickness and facies distribution within the synrift deposits, and structural data from angular and progressive unconformities. The Atuel depocenter has a NNW trend, showing a bimodal distribution of NNW and WNW major faults (first and second order faults). On the other hand, from kinematic indicators measured on outcrop-scale faults (third and fourth order faults), we found a mean NE internal extension direction, which is oblique to the general trend of the sub-basin. Taking these particular characteristics into account, we interpreted the Atuel depocenter as an oblique rift system. We evaluated two mechanisms in order to explain the development of this transtensional system: 1) reactivation of upper-crustal NNW-oriented Paleozoic shear zones, and 2) oblique stretching of a previous NNW-oriented lithospheric weakness zone.     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

Devil in the detail; The 1150–1000 Ma magmatic and structural evolution of the Ngaanyatjarra Rift,west Musgrave Province,Central Australia

Mafic and felsic rocks units of the Musgrave Province originally attributed to the c. 1075 Ma Giles Event of the greater Warakurna Large Igneous Province (LIP) are shown to be part of a complex sequence of magmatic and tectonic events punctuated over a span of at least 50 m.y. New geochronology and mapping resolve a sequence of at least 10 magmatic pulses with hiati of up to 10 m.y. consistent with a long-lived intracontinental rift setting. This rift, here named the Ngaanyatjarra Rift, features giant layered mafic-ultramafic Giles intrusions cut by a 10 km wide mafic-felsic magmatic shear zone. The latter is temporally related to the Warakurna LIP, however it is not clear that the Giles intrusions actually form part of the Warakurna LIP. Macroscopic folding and the formation of the large synmagmatic transpressional shear zone attest to synmagmatic basin inversion in the early stages of the rift. The extensive mafic to felsic volcanic rocks of the Tollu Group (traditionally grouped with the Giles Event) were emplaced 25–50 m.y. later than the c. 1075 Ma Warakurna LIP.     

Joint evaluation of gravity, electrical and magnetotelluric methods for geothermal potential of fractured Aptian reefal carbonates in the Hmaima–El Gara area (Oued Serrat basin, Central–Western Tunisia)

Hmaima–El Gara area is located in Central–Western Tunisia and is known as an important geothermal province. In this study, we attempt to delineate the subsurface structures of the area using integrated interpretation of gravity, electrical and magnetotelluric data. The Hmaima thermal aquifer, associated with fractured Aptian reefal limestones, is characterized by high gravity and high resistivity. Horizontal gradient and Euler deconvolution method has been applied to the gravity data and provided fast information about both the depth and trends of the shallower subsurface structures in the area. As several of the mapped lineaments correlate with published geological fault trends, the other lineaments may be indicators of new insights for hydrothermal exploitation in the Hmaima–El Gara area (economical potential favorite zones).     

Modification of a Palaeoproterozoic porphyry-like system: Integration of structural,geochemical, petrographic,and fluid inclusion data from the Aitik Cu–Au–Ag deposit,northern Sweden

The Aitik Cu–Au–Ag deposit in the Gällivare area in northern Sweden is Sweden's largest sulphide mine with an annual production of 35 Mt of ore, and the biggest open pit operation in northern Europe. It is proposed in the present study that the Aitik deposit represents a Palaeoproterozoic, strongly metamorphosed porphyry copper deposit that was affected ca. 100 Ma later by a regional IOCG-type hydrothermal event. Consequently, the Aitik deposit might represent a mixed ore system where an early copper mineralisation of porphyry type has been overprinted by later regional IOCG mineralisation.Several attempts have previously been made to genetically classify the Aitik Cu–Au–Ag deposit as a distinct ore type. New geochemical, petrographic, structural, and fluid inclusion results combined with published data have provided the opportunity to present new ideas on the genesis and evolution of the Aitik Cu–Au–Ag deposit. The emplacement of a ca. 1.9 Ga quartz monzodiorite that host the ore at Aitik was related to subduction processes and volcanic arc formation, and synchronous with quartz vein stockwork formation and porphyry copper mineralisation. Highly saline aqueous (38 wt.% NaCl) fluid inclusions in the stockwork veins suggest entrapment at 300 °C and a pressure of nearly 3 kbar, a high pressure for a typical porphyry copper ore, but consistent with conditions at associated deep root zones of intrusion-related magmatic–hydrothermal systems. The highly saline fluid formed disseminated and vein-type ore of mainly chalcopyrite and pyrite within comagmatic volcaniclastic rocks, and caused potassic alteration (biotite, microcline) of the host rocks. The early porphyry copper mineralising event was followed, and largely overprinted, by CO₂ and aqueous medium- to high-salinity (16–57 wt.% salts) fluids related to a ca. 1.8 Ga tectonic and metamorphic event (peak conditions 500–600 °C and 4–5 kbar). Extensive deformation of rocks and redistribution of metals occurred. Magnetite enrichment locally found within late veins, and late amphibole–scapolite and K feldspar alterations within the deposit, are some of the features at Aitik implying that aqueous fluids responsible for IOCG-mineralisation (200–500 °C and ~ 1 kbar) and extensive Na–Ca alteration in the region during the 1.8 Ga tectonic event also affected the Aitik rocks, possibly leading to addition of copper ± gold.     

Genesis of the Proterozoic Mangabeira tin–indium mineralization,Central Brazil: Evidence from geology,petrology, fluid inclusion and stable isotope data

The Mangabeira deposit is the only known Brazilian tin mineralization with indium. It is hosted in the Paleo- to Mesoproterozoic Mangabeira within-plate granitic massif, which has geochemical characteristics of NYF fertile granites. The granitic massif is hosted in Archean to Paleoproterozoic metasedimentary rocks (Ticunzal formation), Paleoproterozoic peraluminous granites (Aurumina suite) and a granite–gneiss complex. The mineralized area comprises evolved Li-siderophyllite granite, topaz–albite granite, Li–F-rich mica greisens and a quartz–topaz rock, similar to topazite. Two types of greisens are recognized in the mineralized area: zinnwaldite greisen and Li-rich muscovite greisen, formed by metasomatism of topaz–albite granite and Li-siderophyllite granite, respectively. Cassiterite occurs in the quartz–topaz rock and in the greisens. Indium minerals, such as roquesite (CuInS₂), yanomamite (InAsO₄·2H₂O) and dzhalindite (In(OH₃)), and In-rich cassiterite, sphalerite, stannite group minerals and scorodite are more abundant in the quartz–topaz rock, and are also recognized in albitized biotite granite and in Li-rich muscovite greisen. The host rocks and mineralized zones were subsequently overprinted by the Brasiliano orogenic event.Primary widespread two-phase aqueous and rare coeval aqueous-carbonic fluid inclusions are preserved in quartz from the topaz–albite granite, in quartz and topaz from the quartz–topaz rock and in cassiterite from the Li-rich muscovite greisen. Eutectic temperatures are − 25 °C to − 23 °C, allowing modeling of the aqueous fluids in the system H₂O–NaCl(–KCl). Rare three-phase H₂O–NaCl fluid inclusions (45–50 wt.% NaCl equiv.) are restricted to the topaz–albite granite. Salinities and homogenization temperatures of the aqueous and aqueous-carbonic fluid inclusions decrease from the topaz–albite granite (15–20 wt.% NaCl equiv.; 400 °C–450 °C), to the quartz–topaz rock (10–15 wt.% NaCl equiv.; 250 °C–350 °C) and to the greisen (0–5 wt.% NaCl equiv.; 200 °C–250 °C). Secondary fluid inclusions have the same range of salinities as the primary fluid inclusions, and homogenize between 150 and 210 °C.The estimated equilibrium temperatures based on δ¹⁸O of quartz–mica pairs are 610–680 °C for the topaz–albite granite and 285–370 °C for the Li-rich muscovite greisens. These data are coherent with measured fluid inclusion homogenization temperatures. Temperatures estimated using arsenopyrite geothermometry yield crystallization temperatures of 490–530 °C for the quartz–topaz rock and 415–505 °C for the zinnwaldite greisens. The fluids in equilibrium with the topaz–albite granite have calculated δ¹⁸O and δD values of 5.6–7.5‰ and − 67 to − 58‰, respectively. Estimated δ¹⁸O and δD values are mainly 4.8–7.9‰ and − 60 to − 30‰, respectively, for the fluids in equilibrium with the quartz–topaz rock and zinnwaldite greisen; and 3.4–3.9‰ and − 25 to − 17‰, respectively, for the Li-rich muscovite greisen fluid. δ³⁴S data on arsenopyrite from the quartz–topaz rock vary from − 1.74 to − 0.74‰, consistent with a magmatic origin for the sulfur. The integration of fluid inclusion with oxygen isotopic data allows for estimation of the minimum crystallization pressure at ca. 770 bar for the host topaz–albite granite, which is consistent with its evolved signature.Based on petrological, fluid inclusion and isotope data it is proposed that the greisens and related Mangabeira Sn–In mineralization had a similar hydrothermal genesis, which involved exsolution of F-rich, Sn–In-bearing magmatic fluids from the topaz–albite granite, early formation of the quartz–topaz rock and zinnwaldite greisen, progressive cooling and Li-rich muscovite greisen formation due to interaction with meteoric water. The quartz–topaz rock is considered to have formed in the magmatic-hydrothermal transition. The mineralizing saline and CO₂-bearing fluids are interpreted to be of magmatic origin, based on the isotopic data and paragenesis, which has been documented as characteristic of the tin mineralization genetically related to Proterozoic within-plate granitic magmatism in the Goias Tin Province, Central Brazil.     

Towards a volcanic–structural balance: relative importance of volcanism, folding, and remobilisation of nickel sulphides at the Perseverance Ni–Cu–(PGE) deposit, Western Australia

Perseverance is a world-class, komatiite-hosted nickel sulphide deposit situated in the well-endowed Leinster nickel camp of the Agnew–Wiluna greenstone belt, Western Australia. The mine stratigraphy at Perseverance trends north-northwest (NNW), dips steeply to the west, and is overturned. Stratigraphic footwall units lie along the western margin of the Perseverance Ultramafic Complex (PUC). The PUC comprises a basal nickel sulphide-bearing orthocumulate- to mesocumulate-textured komatiite that is overlain by a thicker, nickel sulphide-poor, dunite lens. Hanging wall rocks include rhyodacite that is texturally and compositionally similar to footwall volcanic rocks. These rocks separate the PUC from a second sequence of nickeliferous, E-facing, spinifex-textured komatiite units (i.e. the East Perseverance komatiite). Past workers argue for a conformable stratigraphic contact between the PUC and the East Perseverance komatiite and conclude that the PUC is extrusive. This study, however, clearly demonstrates that these komatiite sequences are discordant, implying that the PUC may have intruded rhyodacite country rock as a sill with subsequent structural juxtaposition against the East Perseverance komatiite. Early N–S shortening associated with the regional D_I deformation event (corresponding to the local D_P1 to D_P3 events at Perseverance) resulted in the heterogeneous partitioning of strain along the margins of the competent dunite. A mylonite developed in the more ductile footwall rocks along the footwall margin of the PUC, while isoclinal F₃ folds, such as the Hanging wall limb and Felsic Nose folds, formed in low-mean stress domains along the fringes of the elongated dunite lens. Strata-bound massive and disseminated nickel sulphides were passively fold thickened in hinge areas of isoclinal folds, whereas basal massive sulphides lubricated fold limbs and promoted thrust movement along shallowly dipping lithological contacts. Massive sulphides were physically remobilised up to 20 m from their primary footwall position into deposit-scale fold hinges to form the 1A and Felsic Nose orebodies. First-order controls on the geometry of the Perseverance deposit include the thermomechanical erosion of footwall rocks and the channelling of the mineralised komatiitic magma. Second- or third-order controls are several postvolcanic deformation events, which resulted in the progressive folding and shearing of the footwall contact, as well as the passive fold thickening of massive and disseminated sulphide orebodies. Massive sulphides were physically remobilised into multiple generations of fold hinges and shear zones. Important implications for near-mine exploration in the Leinster camp include identifying nickeliferous komatiite units, defining their three-dimensional geometry, and targeting fold hinge areas. Fold plunge directions and stretching lineations are indicators of potential plunge directions of massive sulphide orebodies.     

Ordovician igneous and metamorphic units in southeastern Puna: New U–Pb and Sm–Nd data and implications for the evolution of northwestern Argentina

New field, petrological, geochemical, and geochronological data (U–Pb and Sm–Nd) for Ordovician rock units in the southeastern Puna, NW Argentina, indicate two lithostratigraphic units at the eastern–northeastern border of salar Centenario: (1) a bimodal volcanosedimentary sequence affected by low- to medium-grade metamorphism, comprising metasediments associated with basic and felsic metavolcanic rocks, dated 485 ± 5 Ma, and (2) a plutonic unit composed of syenogranites to quartz-rich leucogranites with U–Pb zircon ages between 462 ± 7 and 475 ± 5 Ma. Felsic metavolcanic and plutonic rocks are peraluminous and show similar geochemical differentiation trends. They also have similar Sm–Nd isotopic compositions (T_DM model ages of 1.54–1.78 Ga; ε_Nd(T) values ranging from −3.2 to −7.5) that suggest a common origin and derivation of the original magmas from older (Meso-Paleoproterozoic?) continental crust. Mafic rocks show ε_Nd(T) ranging from +2.3 to +2.5, indicating a depleted mantle source. The data presented here, combined with those in the literature, suggest Ordovician magmatism mainly recycles preexisting crust with minor additions of juvenile mantle-derived material.