Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania

On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.     

A multi-disciplinary study of the 2002–03 Etna eruption: insights into a complex plumbing system

The 2002–03 Mt Etna flank eruption began on 26 October 2002 and finished on 28 January 2003, after three months of continuous explosive activity and discontinuous lava flow output. The eruption involved the opening of eruptive fissures on the NE and S flanks of the volcano, with lava flow output and fire fountaining until 5 November. After this date, the eruption continued exclusively on the S flank, with continuous explosive activity and lava flows active between 13 November and 28 January 2003. Multi-disciplinary data collected during the eruption (petrology, analyses of ash components, gas geochemistry, field surveys, thermal mapping and structural surveys) allowed us to analyse the dynamics of the eruption. The eruption was triggered either by (i) accumulation and eventual ascent of magma from depth or (ii) depressurisation of the edifice due to spreading of the eastern flank of the volcano. The extraordinary explosivity makes the 2002–03 eruption a unique event in the last 300 years, comparable only with La Montagnola 1763 and the 2001 Lower Vents eruptions. A notable feature of the eruption was also the simultaneous effusion of lavas with different composition and emplacement features. Magma erupted from the NE fissure represented the partially degassed magma fraction normally residing within the central conduits and the shallow plumbing system. The magma that erupted from the S fissure was the relatively undegassed, volatile-rich, buoyant fraction which drained the deep feeding system, bypassing the central conduits. This is typical of most Etnean eccentric eruptions. We believe that there is a high probability that Mount Etna has entered a new eruptive phase, with magma being supplied to a deep reservoir independent from the central conduit, that could periodically produce sufficient overpressure to propagate a dyke to the surface and generate further flank eruptions.Editorial responsibility: J. Donnelly-Nolan     

Miocene lamproite volcanoes in south-eastern Spain—an association of phreatomagmatic and magmatic products

A series of small Miocene (8.3–6.7 Ma) lamproite rock occurrences (as monogenetic volcanoes and/or dykes) cover a large area in southeastern Spain. These rocks are associated with extensional basins filled by Neogene deposits in the Betic and Subbetic structural units. At Cancarix (Sierra de las Cabras), Calasparra, Barqueros, Cerro de Monagrillo, Jumilla, and Vera, eruptions occurred, whereas at Fortuna, Mula and Zeneta there were only small-scale intrusions (mainly dykes). This paper describes volcanic centers at Cancarix, Calasparra and Barqueros, which show initial phreatomagmatic eruptions driven by interaction of rising lamproite magma with groundwater. Tuff ring formed during this volcanic activity. Subsequent activity consisted of dome extrusion in the vent areas of Cancarix and Calasparra and by explosive to effusive magmatic activity accompanied by extensive lava flows at Barqueros.Calasparra and Cancarix are relatively symmetric monogenetic tuff rings filled by late stage massive vertical plug, extruded as degassed crystalline high-viscosity magma along the volcanic conduit. Barqueros was initially a tuff ring, whose late stage Hawaiian-style fountaining generated spatter and clastogenic lavas that built the intra-tuff ring cone of Cabezo del Morron. Finally, extensive lava flows spread from the base of the cone toward the northern part of the edifice. Variations in the tectonic (extensional regime) and local hydrogeologic conditions (shallow aquifers) influenced the occurrence of these lamproite volcanoes. Late stage magma rise was dependent on the magmatic volatile regime, being already degassed at Calasparra and Cancarix, by showing higher viscosity (high crystallization rate) of intra-tuff ring dome extrusions, or still rich in volatiles at Barqueros, displaying lower viscosity lava fountaining and then lava flows.     

Multiple levels of magma storage during the 1980 summer eruptions of Mount St. Helens, WA

Transitions in eruptive style—explosive to effusive, sustained to pulsatory—are a common aspect of volcanic activity and present a major challenge to volcano monitoring efforts. A classic example of such transitions is provided by the activity of Mount St. Helens, WA, during 1980, where a climactic Plinian event on May 18 was followed by subplinian and vulcanian eruptions that became increasing pulsatory with time throughout the summer, finally progressing to episodic growth of a lava dome. Here we use variations in the textures, glass compositions and volatile contents of melt inclusions preserved in pyroclasts produced by the summer 1980 eruptions to determine conditions of magma ascent and storage that may have led to observed changes in eruptive activity. Five different pyroclast types identified in pyroclastic flow and fall deposits produced by eruptions in June 12, July 22 and August 7, 1980, provide evidence for multiple levels of magma storage prior to each event. Highly vesicular clasts have H₂O-rich (4.5–5.5 wt%) melt inclusions and lack groundmass microlites or hornblende reaction rims, characteristics that require magma storage at P≥160 MPa until shortly prior to eruption. All other clast types have groundmass microlites; P_H20 estimated from both H₂O-bearing melt inclusions and textural constraints provided by decompression experiments suggest pre-eruptive storage pressures of ∼75, 40, and 10 MPa. The distribution of pyroclast types within and between eruptive deposits can be used to place important constraints on eruption mechanisms. Fall and flow deposits from June 12, 1980, lack highly vesicular, microlite-free pyroclasts. This eruption was also preceded by a shallow intrusion on June 3, as evidenced by a seismic crisis and enhanced SO₂ emissions. Our constraints suggest that magma intruded to a depth of ≤4 km beneath the crater floor fed the June eruption. In contrast, eruptions of July and August, although shorter in duration and smaller in volume, erupted deep volatile-rich magma. If modeled as a simple cylinder, these data require a step-wise decrease in effective conduit diameter from 40–50 m in May and June to 8–12 m in July and August. The abundance of vesicular (intermediate to deep) clast types in July and August further suggests that this change was effected by narrowing the shallower part of the conduit, perhaps in response to solidification of intruded magma remaining in the shallow system after the June eruption. Eruptions from July to October were distinctly pulsatory, transitioning between subplinian and vulcanian in character. As originally suggested by Scandone and Malone (1985), a growing mismatch between the rate of magma ascent and magma disruption explains the increasingly pulsatory nature of the eruptions through time. Recent fragmentation experiments Spieler et al. (2004) suggest this mismatch may have been aided by the multiple levels at which magma was stored (and degassed) prior to these events.Editorial responsibility: J Stix     

Monitoring the 2004 andesitic block-lava extrusion at Volcán de Colima,México from seismic activity and SO2 emission

The 2004 andesitic block-lava extrusion at Volcán de Colima, México was accompanied and followed by numerous seismic signals associated with rockfalls, pyroclastic flows and explosive events. We analyze temporal variations in the number of rockfalls and explosions, the seismic signal duration of rockfalls and the energy of the explosion and compare this with both the rate of magma discharge and SO₂ emission. Characteristics of seismic signals and SO₂ emission are compared with those observed during the 1998–1999 Volcán de Colima block-lava extrusion. For both eruptions, the explosive activity was low during the lava extrusion and increased after its termination. The variation in the daily number and the total duration of rockfall seismic signals gives a good reflection of the development of the lava emission process. An increase in magmatic degassing (SO₂ flux) was observed some days before the onset of lava extrusion. The degassing strongly decreased some days before the peak in the rate of the 1998–1999 lava emission but reached its peak together with the peak in the rate of the 2004 lava emission. These features of seismic activity and SO₂ emission demonstrate that they are good tools for monitoring the extrusion process.     

Breadcrust bombs as indicators of Vulcanian eruption dynamics at Guagua Pichincha volcano,Ecuador

Vulcanian eruptions are common at many volcanoes around the world. Vulcanian activity occurs as either isolated sequences of eruptions or as precursors to sustained explosive events and is interpreted as clearing of shallow plugs from volcanic conduits. Breadcrust bombs characteristic of Vulcanian eruptions represent samples of different parts of these plugs and preserve information that can be used to infer parameters of pre-eruption magma ascent. The morphology and preserved volatile contents of breadcrust bombs erupted in 1999 from Guagua Pichincha volcano, Ecuador, thus allow us to constrain the physical processes responsible for Vulcanian eruption sequences of this volcano. Morphologically, breadcrust bombs differ in the thickness of glassy surface rinds and in the orientation and density of crack networks. Thick rinds fracture to create deep, widely spaced cracks that form large rectangular domains of surface crust. In contrast, thin rinds form polygonal networks of closely spaced shallow cracks. Rind thickness, in turn, is inversely correlated with matrix glass water content in the rind. Assuming that all rinds cooled at the same rate, this correlation suggests increasing bubble nucleation delay times with decreasing pre-fragmentation water content of the melt. A critical bubble nucleation threshold of 0.4–0.9 wt% water exists, below which bubble nucleation does not occur and resultant bombs are dense. At pre-fragmentation melt H₂O contents of >∼0.9 wt%, only glassy rinds are dense and bomb interiors vesiculate after fragmentation. For matrix glass H₂O contents of ≥1.4 wt%, rinds are thin and vesicular instead of thick and non-vesicular. A maximum measured H₂O content of 3.1 wt% establishes the maximum pressure (63 MPa) and depth (2.5 km) of magma that may have been tapped during a single eruptive event. More common H₂O contents of ≤1.5 wt% suggest that most eruptions involved evacuation of ≤1.5 km of the conduit. As we expect that substantial overpressures existed in the conduit prior to eruption, these depth estimates based on magmastatic pressure are maxima. Moreover, the presence of measurable CO₂ (≤17 ppm) in quenched glass of highly degassed magma is inconsistent with simple models of either open- or closed-system degassing, and leads us instead to suggest re-equilibration of the melt with gas derived from a deeper magmatic source. Together, these observations suggest a model for the repeated Vulcanian eruptions that includes (1) evacuation of the shallow conduit during an individual eruption, (2) depressurization of magma remaining in the conduit accompanied by open-system degassing through permeable bubble networks, (3) rapid conduit re-filling, and (4) dome formation prior to the subsequent explosion. An important part of this process is densification of upper conduit magma to allow repressurization between explosions. At a critical overpressure, trapped pressurized gas fragments the nascent impermeable cap to repeat the process.     

Video and seismic observations of Strombolian eruptions at Erebus volcano,Antarctica

Between 1986 and 1990 the eruptive activity of Erebus volcano was monitored by a video camera with on-screen time code and recorded on video tape. Corresponding seismic and acoustic signals were recorded from a network of 6 geophones and 2 infrasonic microphones. Two hundred Strombolian explosions and three lava flows which were erupted from 7 vents were captured on video. In December 1986 the Strombolian eruptions ejected bombs and ash. In November 1987 large bubble-bursting Strombolian eruptions were observed. The bubbles burst when the bubble walls thinned to ∼ 20 cm. Explosions with bomb flight-times up to 14.5 s were accompanied by seismic signals with our local size estimate, “unified magnitudes” (m_u), up to 2.3. Explosions in pools of lava formed by flows in the Inner Crater were comparatively weak.     

Characterizing high energy explosive eruptions at Stromboli volcano using multidisciplinary data: An example from the 9 January 2005 explosion

Stromboli is well known for its persistent, normal explosive activity, consisting of intermittent, mild to moderate, Strombolian explosions that typically occur every 10–20 min. All tephras erupted during this activity usually fall back into the crater terrace, and consist of volatile-poor scoriae fed by Highly Porphyritic (HP) magma. More occasionally, large explosions or “paroxysms” eject a greater quantity of tephra, mainly consisting of HP scoriae and pumice clasts of Low Porphyritic (LP) magma, but also including large lithic blocks. In addition to this activity, between 2004 and 2006 high energy explosions, displaying an intermediate eruptive style between that of normal and paroxysmal explosions in terms of column height, duration and tephra dispersal, were observed to occur at a frequency of one to eight events per year. While many volcanological, geochemical and geophysical studies have focused in the last few years on the two end-members of activity, i.e. normal or paroxysmal, a detailed investigation on these intermediate types of events has not been carried out yet. Here we report of a study on the 9 January 2005 explosion, one of the high energy explosions during which the main fountaining phase lasted nearly a minute causing ejection of coarse bombs up to a height of 120 m, and of ash and lapilli to > 200 m. An accompanying ash plume rose up to 500 m at the end of the explosion. We present a multidisciplinary approach that integrates the results from analysis of live-camera images with compositional and textural characterization of the erupted products. Major element composition of glassy groundmass and 3D views of textures in the erupted scoriae support the hypothesis based on volcanological observations that this explosion falls between normal and paroxysmal activity, for which we use the term “intermediate”. By comparing the video-camera images of the 9 January 2005 explosion with volcanological features of other high energy explosions that occurred at Stromboli between June 2004 and October 2006, we find that three additional events can be considered intermediate explosions, suggesting that this type of activity may be fairly common on this volcano. The results of this study, although preliminary given our limited dataset, clearly indicate that the methodology used here can be successfully applied to better define the range of eruptive styles typifying the normal explosive activity, potentially improving our capability of eruption forecasting and assessing volcanic hazard at Stromboli.     

The role of syn-eruptive vesiculation on explosive basaltic activity at Mt. Etna,Italy

We investigated the dynamics of explosive activity at Mt. Etna between 31 August and 15 December 2006 by combining vesicle studies in the erupted products with measurements of the gas composition at the active, summit crater. The analysed scoria clasts present large, connected vesicles with complex shapes and smaller, isolated, spherical vesicles, the content of which increases in scoriae from the most explosive events. Gas geochemistry reports CO₂/SO₂ and SO₂/HCl ratios supporting a deep-derived gas phase for fire-fountain activity. By integrating results from scoria vesiculation and gas analysis we find that the highest energy episodes of Mt. Etna activity in 2006 were driven by a previously accumulated CO₂-rich gas phase but we highlight the lesser role of syn-eruptive vesicle nucleation driven by water exsolution during ascent. We conclude that syn-eruptive vesiculation is a common process in Etnean magmas that may promote a deeper conduit magma fragmentation and increase ash formation.     

Lava effusion — A slow fuse for paroxysms at Stromboli volcano?

The 2007 effusive eruption of Stromboli followed a similar pattern to the previous 2002–2003 episode. In both cases, magma ascent led to breaching of the uppermost part of the conduit forming an eruptive fissure that discharged lava down the Sciara del Fuoco depression. Both eruptions also displayed a ‘paroxysmal’ explosive event during lava flow output. From daily effusion rate measurements retrieved from helicopter- and satellite-based infrared imaging, we deduce that the cumulative volume of lava erupted before each of the two paroxysms was similar. Based on this finding, we propose a conceptual model to explain why both paroxysms occurred after this ‘threshold’ cumulative volume of magma was erupted. The gradual decompression of the deep plumbing system induced by magma withdrawal and eruption, drew deeper volatile-rich magma into the conduit, leading to the paroxysms. The proposed model might provide a basis for forecasting paroxysmal explosions during future effusive eruptions of Stromboli.     

Volcanism in Iceland in historical time: Volcano types,eruption styles and eruptive history

The large-scale volcanic lineaments in Iceland are an axial zone, which is delineated by the Reykjanes, West and North Volcanic Zones (RVZ, WVZ, NVZ) and the East Volcanic Zone (EVZ), which is growing in length by propagation to the southwest through pre-existing crust. These zones are connected across central Iceland by the Mid-Iceland Belt (MIB). Other volcanically active areas are the two intraplate belts of Öræfajökull (ÖVB) and Snæfellsnes (SVB). The principal structure of the volcanic zones are the 30 volcanic systems, where 12 are comprised of a fissure swarm and a central volcano, 7 of a central volcano, 9 of a fissure swarm and a central domain, and 2 are typified by a central domain alone.Volcanism in Iceland is unusually diverse for an oceanic island because of special geological and climatological circumstances. It features nearly all volcano types and eruption styles known on Earth. The first order grouping of volcanoes is in accordance with recurrence of eruptions on the same vent system and is divided into central volcanoes (polygenetic) and basalt volcanoes (monogenetic). The basalt volcanoes are categorized further in accordance with vent geometry (circular or linear), type of vent accumulation, characteristic style of eruption and volcanic environment (i.e. subaerial, subglacial, submarine).Eruptions are broadly grouped into effusive eruptions where >95% of the erupted magma is lava, explosive eruptions if >95% of the erupted magma is tephra (volume calculated as dense rock equivalent, DRE), and mixed eruptions if the ratio of lava to tephra occupy the range in between these two end-members. Although basaltic volcanism dominates, the activity in historical time (i.e. last 11 centuries) features expulsion of basalt, andesite, dacite and rhyolite magmas that have produced effusive eruptions of Hawaiian and flood lava magnitudes, mixed eruptions featuring phases of Strombolian to Plinian intensities, and explosive phreatomagmatic and magmatic eruptions spanning almost the entire intensity scale; from Surtseyan to Phreatoplinian in case of “wet” eruptions and Strombolian to Plinian in terms of “dry” eruptions. In historical time the magma volume extruded by individual eruptions ranges from ∼1 m³ to ∼20 km³ DRE, reflecting variable magma compositions, effusion rates and eruption durations.All together 205 eruptive events have been identified in historical time by detailed mapping and dating of events along with extensive research on documentation of eruptions in historical chronicles. Of these 205 events, 192 represent individual eruptions and 13 are classified as “Fires”, which include two or more eruptions defining an episode of volcanic activity that lasts for months to years. Of the 159 eruptions verified by identification of their products 124 are explosive, effusive eruptions are 14 and mixed eruptions are 21. Eruptions listed as reported-only are 33. Eight of the Fires are predominantly effusive and the remaining five include explosive activity that produced extensive tephra layers. The record indicates an average of 20–25 eruptions per century in Iceland, but eruption frequency has varied on time scale of decades. An apparent stepwise increase in eruption frequency is observed over the last 1100 years that reflects improved documentation of eruptive events with time. About 80% of the verified eruptions took place on the EVZ where the four most active volcanic systems (Grímsvötn, Bárdarbunga–Veidivötn, Hekla and Katla) are located and 9%, 5%, 1% and 0.5% on the RVZ–WVZ, NVZ, ÖVB, and SVB, respectively. Source volcano for ∼4.5% of the eruptions is not known.Magma productivity over 1100 years equals about 87 km³ DRE with basaltic magma accounting for about 79% and intermediate and acid magma accounting for 16% and 5%, respectively. Productivity is by far highest on the EVZ where 71 km³ (∼82%) were erupted, with three flood lava eruptions accounting for more than one half of that volume. RVZ–WVZ accounts for 13% of the magma and the NWZ and the intraplate belts for 2.5% each. Collectively the axial zone (RVZ, WVZ, NVZ) has only erupted 15–16% of total magma volume in the last 1130 years.     

Pre-eruptive physical conditions of El Reventador volcano (Ecuador) inferred from the petrology of the 2002 and 2004–05 eruptions

A petrological study of the eruptive products of El Reventador allowed us to infer the magmatic processes related to the 2002 and 2004–05 eruptions of this andesitic stratovolcano. On November 3, 2002, El Reventador experienced a highly explosive event, which was followed by emplacement of two lava flows in November–December 2002. Silica contents range from 62 to 58 wt.% SiO₂ for the November 3 pyroclastic deposits to 58–56 and 54–53 wt.% SiO₂ for the successive lava flows. In November 2004 eruptive activity resumed supplying four new lava flows (56–54 wt.% SiO₂) between November 2004 and August 2005.     

Reconstructing the largest explosive eruptions of Mt. Ruapehu,New Zealand: lithostratigraphic tools to understand subplinian–plinian eruptions at andesitic volcanoes

We analysed the tephra record of Mt. Ruapehu for the period 27,097 ± 957 to ~10,000 cal. years BP to determine the largest-scale explosive eruptions expected from the most active New Zealand andesitic volcano. From the lithostratigraphic analysis, a systematic change in the explosive behaviour is identified from older deposits suggesting dry magmatic eruptions and steady eruptive columns, characterised by frothy to expanded pumice fabrics, to younger deposits that are products of unsteady conditions and collapsing columns, characterised by microvesicular, fibrous, and colour-banded pumice fabrics. The end-members were separated by eruptions with steady columns linked to water–magma interaction and highly unstable conduit walls. Dry magmatic eruptions producing steady plinian columns were most common between 27,097 ± 957 and shortly after 13,635 + 165 cal. years BP. Following this time, activity continued with eruptions that produced dominantly oscillating unsteady columns, which engendered pyroclastic density currents, until ~10 ka when there was an abrupt transition at Mt. Ruapehu since which eruptions have been an order of magnitude lower in intensity and volume. These data demonstrate long-period transitions in eruption behaviour at an andesitic stratovolcano, which is critical to understand if realistic time-variable hazard forecasts are to be developed.     

Volcaniclastic deposits from the North Arch volcanic field, Hawaii: explosive fragmentation of alkalic lava at abyssal depths

Submarine explosive eruptions are generally considered to become less likely with increasing depth due to the increasing hydrostatic pressure of the overlying water column. Volcaniclastic deposits from the North Arch volcanic field, north of Oahu, have textural characteristics of explosive fragmentation yet were erupted in water depths greater than 4,200 m. The most abundant volcaniclastic samples from North Arch are clast-supported with highly vesicular, angular pyroclasts. They are most likely near-vent pyroclastic fall deposits formed in eruption columns of limited height. Interbedded with highly vesicular pillow lava, they form low (50 to 200 m), steep-sided cones around the vents. Less common are stratified samples with graded bedding; one such sample includes a layer of roughly aligned, platy, bubble-wall glass fragments (resembling littoral limu o Pele) that may have been deposited by density currents. In addition to bubble-wall glass shards, numerous glass fragments with spherical, delicate spindle and ribbon shapes, and Pele's hair-like glass strands occur in the finer size fraction (<0.5 mm) of some samples. They are probably more distal fallout. Another sample, consisting of glass fragments dispersed in a marine clay matrix, was apparently reworked and deposited farther from the vents by bottom currents. Glass compositions include low-(∼0.4-0.6 wt%) and medium-K₂O (>0.6 wt%) alkalic basalt, basanite, and nephelinite. Sulfur and chlorine abundances are high, reaching a maximum of 1,800 and 1,300 ppm, respectively. The ubiquitous presence of limu o Pele fragments, regardless of glass composition, suggests that bursts of Strombolian-like activity accompanied most eruptions. Coalescing vesicles observed in larger pyroclasts and some pillow lava suggests accumulation of volatiles. Since the great hydrostatic pressure makes steam expansion impossible, a volatile-rich, supercritical magmatic fluid probably drove the eruptions. If these volatile-rich magmas had erupted in shallow water or subaerially, tall fountains would most likely have resulted. The great hydrostatic pressure (>40 MPa) limited fountain and eruption column heights.     

The San Venanzo maar and tuff ring,Umbria, Italy: eruptive behaviour of a carbonatite-melilitite volcano

The late Pleistocene San Venanzo maar and nearby Pian di Celle tuff ring in the San Venanzo area of Umbria, central Italy, appear to represent different aspects of an eruptive cycle accompanied by diatreme formation. Approximately 6x10⁶ m³ of mostly lapillisized, juvenile ejecta with lesser amounts of lithics and 1x10⁶ m³ of lava were erupted. The stratigraphy indicates intense explosive activity followed by lava flows and subvolcanic intrusions. The pyroclastic material includes lithic breccia derived from vent and diatreme wall erosion, roughly stratified lapilli tuff deposited by concentrated pyroclastic surge, chaotic scoriaceous pyroclastic flow and inverse graded grain-flow deposits. The key feature of the pyroclastics is the presence of concentric-shelled lapilli generated by accretion around the lithics during magma ascent in the diatreme conduits. The rock types range from kalsilite leucite olivine melilitite lavas and subvolcanic intrusions to carbonatite, phonolite and calcitic melilitite pyroclasts. Juvenile ejecta contain essential calcite whose composition and texture indicate a magmatic origin. Pyroclastic carbonatite activity is also indicated by the presence of carbonatite ash beds. The San Venanzo maar-forming event is believed to have been trigered by fluid-rich carbonatite-phonolite magma. The eruptive centre the moved to the Pian di Celle tuff ring, where the eruption of degassed olivine melilititic magma and late intrusions ended magmatic activity in the area. In both volcanoes the absence of phreatomagmatic features together with the presence of large amounts of primary calcite suggests carbonatite segregation and violent exsolution of CO₂ which, flowing through the diatremes, produced the peculiar intrusive pyroclastic facies and triggered explosions.     

Frequent eruptions of Mount Rainier over the last ∼2,600 years

Field, geochronologic, and geochemical evidence from proximal fine-grained tephras, and from limited exposures of Holocene lava flows and a small pyroclastic flow document ten–12 eruptions of Mount Rainier over the last 2,600 years, contrasting with previously published evidence for only 11–12 eruptions of the volcano for all of the Holocene. Except for the pumiceous subplinian C event of 2,200 cal year BP, the late-Holocene eruptions were weakly explosive, involving lava effusions and at least two block-and-ash pyroclastic flows. Eruptions were clustered from ∼2,600 to ∼2,200 cal year BP, an interval referred to as the Summerland eruptive period that includes the youngest lava effusion from the volcano. Thin, fine-grained tephras are the only known primary volcanic products from eruptions near 1,500 and 1,000 cal year BP, but these and earlier eruptions were penecontemporaneous with far-traveled lahars, probably created from newly erupted materials melting snow and glacial ice. The most recent magmatic eruption of Mount Rainier, documented geochemically, was the 1,000 cal year BP event. Products from a proposed eruption of Mount Rainier between AD 1820 and 1854 (X tephra of Mullineaux (US Geol Surv Bull 1326:1–83, 1974)) are redeposited C tephra, probably transported onto young moraines by snow avalanches, and do not record a nineteenth century eruption. We found no conclusive evidence for an eruption associated with the clay-rich Electron Mudflow of ∼500 cal year BP, and though rare, non-eruptive collapse of unstable edifice flanks remains as a potential hazard from Mount Rainier. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users. T. W. Sisson and J. W. Vallance contributed equally to this study.     

Effects of eruption and lava drainback on the H2O contents of basaltic magmas at Kilauea Volcano

 Lava drainback has been observed during many eruptions at Kilauea Volcano: magma erupts, degasses in lava fountains, collects in surface ponds, and then drains back beneath the surface. Time series data for melt inclusions from the 1959 Kilauea Iki picrite provide important evidence concerning the effects of drainback on the H₂O contents of basaltic magmas at Kilauea. Melt inclusions in olivine from the first eruptive episode, before any drainback occurred, have an average H₂O content of 0.7±0.2 wt.%. In contrast, many inclusions from the later episodes, erupted after substantial amounts of surface degassed lava had drained back down the vent, have H₂O contents that are much lower (≥0.24 wt.% H₂O). Water contents in melt inclusions from magmas erupted at Pu'u 'O'o on the east rift zone vary from 0.39–0.51 wt.% H₂O in tephra from high fountains to 0.10–0.28 wt.% H₂O in spatter from low fountains. The low H₂O contents of many melt inclusions from Pu'u 'O'o and post-drainback episodes of Kilauea Iki reveal that prior to crystallization of the enclosing olivine host, the melts must have exsolved H₂O at pressures substantially less than those in Kilauea's summit magma reservoir. Such low-pressure H₂O exsolution probably occurred as surface degassed magma was recycled by drainback and mixing with less degassed magma at depth. Recognition of the effects of low-pressure degassing and drainback leads to an estimate of 0.7 wt.% H₂O for differentiated tholeiitic magma in Kilauea's summit magma storage reservoir. Data for MgO-rich submarine glasses (Clague et al. 1995) and melt inclusions from Kilauea Iki demonstrate that primary Kilauean tholeiitic magma has an H₂O/K₂O mass ratio of ∼1.3. At transition zone and upper mantle depths in the Hawaiian plume source, H₂O probably resides partly in a small amount of hydrous silicate melt. Received: 31 March 1997 / Accepted: 17 November 1997     

A tale of two magmas,Fuego, Guatemala

Fuego volcano in Guatemala erupted in 1974 in a basaltic sub-Plinian event, which has been well documented and studied. In 1999, after a period of quiescence lasting 20 years, Fuego erupted again, this time less violently, but with persistent low-level activity. This study investigates the link between these episodes. Previous melt inclusion studies have shown magma erupted in 1974 to have been a volatile-rich hybrid tapped from a vertically extensive system. By contrast, magma erupted in 1999 and 2003 is similar in composition to that erupted in 1974, but melt inclusions are more evolved. Although melt inclusions from the later period are CO₂ rich (up to ∼1,500 ppm), they have low H₂O concentration (max 1.5 wt.%, compared to ∼6 wt.% in 1974). These melt inclusions have a modified H₂O concentration due to diffusive re-equilibration at shallow pressures. Despite this diffusive exchange, both eruptions show evidence of recent mingling of the same low and higher K melts, one of which was slightly cooler than the other and as a result traversed the amphibole stability field. (²¹⁰Pb/²²⁶Ra) data on selected bulk rock samples from 1974 suggest that whereas the cooler, more evolved end-member may have been degassing since the last major eruption in the 1930s, the warmer end-member intruded at most a decade prior to the 1974 eruption. The two end-members are thus batches of the same magma emplaced shallowly ∼30 years apart during which time the older batch was cooled and differentiated before mixing with the younger influx. The presence of the same two melts in the later eruptions suggests that magma in 1999 and 2003 is partly residual from 1974. The current eruptive activity is clearing the system of this residual magma prior to an expected new magma batch.     

Reconstruction of the eruptive history of Usu volcano,Hokkaido, Japan,inferred from petrological correlation between tephras and dome lavas

Usu volcano has erupted nine times since 1663. Most eruptive events started with an explosive eruption, which was followed by the formation of lava domes. However, the ages of several summit lava domes and craters remain uncertain. The petrological features of tephra deposits erupted from 1663 to 1853 are known to change systematically. In this study, we correlated lavas with tephras under the assumption that lava and tephra samples from the same event would have similar petrological features. Although the initial explosive eruption in 1663 was not accompanied by lava effusion, lava dome or cryptodome formation was associated with subsequent explosive eruptions. We inferred the location of the vent associated with each event from the location of the associated lava dome and the pyroclastic flow deposit distribution and found that the position of the active vent within the summit caldera differed for each eruption from the late 17th through the 19th century. Moreover, we identified a previously unrecognized lava dome produced by a late 17th century eruption; this dome was largely destroyed by an explosive eruption in 1822 and was replaced by a new lava dome during a later stage of the 1822 event at nearly the same place as the destroyed dome. This new interpretation of the sequence of events is consistent with historical sketches and documents. Our results show that petrological correlation, together with geological evidence, is useful not only for reconstructing volcanic eruption sequences but also for gaining insight into future potential disasters.     

Cristobalite in the 2011–2012 Cordón Caulle eruption (Chile)

Cristobalite is a low-pressure high-temperature polymorph of SiO₂ found in many volcanic rocks. Its volcanogenic formation has received attention because (1) pure particulate cristobalite can be toxic when inhaled, and its dispersal in volcanic ash is therefore a potential hazard; and (2) its nominal stability field is at temperatures higher than those of magmatic systems, making it an interesting example of metastable crystallization. We present analyses (by XRD, SEM, EPMA, Laser Raman, and synchrotron μ-cT) of representative rhyolitic pyroclasts and of samples from different facies of the compound lava flow from the 2011–2012 eruption of Cordón Caulle (Chile). Cristobalite was not detected in pyroclasts, negating any concern for respiratory hazards, but it makes up 0–23 wt% of lava samples, occurring as prismatic vapour-deposited crystals in vesicles and/or as a groundmass phase in microcrystalline samples. Textures of lava collected near the vent, which best represent those generated in the conduit, indicate that pore isolation promotes vapour deposition of cristobalite. Mass balance shows that the SiO₂ deposited in isolated pore space can have originated from corrosion of the adjacent groundmass. Textures of lava collected down-flow were modified during transport in the insulated interior of the flow, where protracted cooling, additional vesiculation events, and shearing overprint original textures. In the most slowly cooled and intensely sheared samples from the core of the flow, nearly all original pore space is lost, and vapour-deposited cristobalite crystals are crushed and incorporated into the groundmass as the vesicles in which they formed collapse by strain and compaction of the surrounding matrix. Holocrystalline lava from the core of the flow achieves high mass concentrations of cristobalite as slow cooling allows extensive microlite crystallization and devitrification to form groundmass cristobalite. Vapour deposition and devitrification act concurrently but semi-independently. Both are promoted by slow cooling, and it is ultimately devitrification that most strongly contributes to total cristobalite content in a given flow facies. Our findings provide a new field context in which to address questions that have arisen from the study of cristobalite in dome eruptions, with insight afforded by the fundamentally different emplacement geometries of flows and domes.