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Secondary carbonates deposited inside caves have been considered as good archives of past climate variations at orbital, millennial to centennial, and de-cadal to annual timescales[1-3]. Change in δ 13C value is generally believed to reflect a change in the ratio of C4 to C3 plants, which have different photosynthetic pathways[4]. However, for given vegetation, the bio-genic CO2 production in soils can cause δ 13C to vary from ?12‰ to ?4‰[5]. Also, enhanced precipitation can lead to rapi…  相似文献   

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