Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny

New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.     

The Guelb Moghrein Cu–Au deposit: Neoarchaean hydrothermal sulfide mineralization in carbonate-facies iron formation

The Guelb Moghrein copper–gold deposit in the Islamic Republic of Mauritania reopened in 2006 and has produced copper concentrate and gold since then. The deposit is hosted in Neoarchaean–Palaeoproterozoic Fe–Mg carbonate-dominated metamorphic rocks interpreted as carbonate-facies iron formation. It forms tabular orebodies controlled by shear zones in the hanging wall and footwall of this meta-iron formation. Copper and gold are hosted in a complex sulfide ore in tectonic breccia replacing Fe–Mg carbonate and magnetite. Hydrothermal monazite dates the mineralization at 2492 ± 9 Ma. Two types of aqueous fluid inclusions suggest fluid mixing at 0.75–1.80 kbar and ~ 410 °C as the mineralization and precipitation mechanism, which is temporally coincident with regional retrograde metamorphism at 410 ± 30 °C (garnet-biotite). Distal alteration zones are enriched in K, Rb and Cu, whereas orebodies are depleted in K, Rb, Sr and Ba. The copper–gold mineralization at Guelb Moghrein formed during retrograde shearing in metamorphic rocks and contemporaneous hydrothermal alteration. The stable isotope signature of alteration and ore minerals suggest an external crustal fluid source. Fluids were focused in the reactive and competent meta-iron formation. Potassium alteration, magnetite and copper–gold mineralization suggest an IOCG mineral system akin similar deposits in Australia and Brazil.     

Petrological and geochronological constraints on lower crust exhumation during Paleoproterozoic (Eburnean) orogeny,NW Ghana,West African Craton

New petrological and geochronological data are presented on high‐grade ortho‐ and paragneisses from northwestern Ghana, forming part of the Paleoproterozoic (2.25–2.00 Ga) West African Craton. The study area is located in the interference zone between N–S and NE–SW‐trending craton‐scale shear zones, formed during the Eburnean orogeny (2.15–2.00 Ga). High‐grade metamorphic domains are separated from low‐grade greenstone belts by high‐strain zones, including early thrusts, extensional detachments and late‐stage strike‐slip shear zones. Paragneisses sporadically preserve high‐pressure, low‐temperature (HP–LT) relicts, formed at the transition between the blueschist facies and the epidote–amphibolite sub‐facies (10.0–14.0 kbar, 520–600 °C), and represent a low (~15 °C km^?1) apparent geothermal gradient. Migmatites record metamorphic conditions at the amphibolite–granulite facies transition. They reveal a clockwise pressure–temperature–time (P–T–t) path characterized by melting at pressures over 10.0 kbar, followed by decompression and heating to peak temperatures of 750 °C at 5.0–8.0 kbar, which fit a 30 °C km^?1 apparent geotherm. A regional amphibolite facies metamorphic overprint is recorded by rocks that followed a clockwise P–T–t path, characterized by peak metamorphic conditions of 7.0–10.0 kbar at 550–680 °C, which match a 20–25 °C km^?1 apparent geotherm. These P–T conditions were reached after prograde burial and heating for some rock units, and after decompression and heating for others. The timing of anatexis and of the amphibolite facies metamorphic overprint is constrained by in‐situ U–Pb dating of monazite crystallization at 2138 ± 7 and 2130 ± 7 Ma respectively. The new data set challenges the interpretation that metamorphic breaks in the West African Craton are due to diachronous Birimian ‘basins’ overlying a gneissic basement. It suggests that the lower crust was exhumed along reverse, normal and transcurrent shear zones and juxtaposed against shallow crustal slices during the Eburnean orogeny. The craton in NW Ghana is made of distinct fragments with contrasting tectono‐metamorphic histories. The range of metamorphic conditions and the sharp lateral metamorphic gradients are inconsistent with ‘hot orogeny’ models proposed for many Precambrian provinces. These findings shed new light on the geodynamic setting of craton assembly and stabilization in the Paleoproterozoic. It is suggested that the metamorphic record of the West African Craton is characteristic of Paleoproterozoic plate tectonics and illustrates a transition between Archean and Phanerozoic orogens.     

New age constraints on metamorphism,metasomatism and gold mineralisation at Plutonic Gold Mine,Marymia Inlier,Western Australia

The Plutonic Well Greenstone Belt (PWGB) is located in the Marymia Inlier between the Yilgarn and Pilbara cratons in Western Australia, and hosts a series of major Au deposits. The main episode of Au mineralisation in the PWGB was previously interpreted to have either accompanied, or shortly followed, peak metamorphism in the late Archean at ca 2650 Ma with a later, minor, event associated with the Capricorn Orogeny. Here we present new Pb isotope model ages for sulfides and Rb–Sr ages for mica, as well as a new ²⁰⁷Pb–²⁰⁶Pb age for titanite for samples from the Plutonic Gold Mine (Plutonic) at the southern end of the PWGB. The majority of the sulfides record Proterozoic Pb isotope model ages (2300–2100 Ma), constraining a significant Au mineralising event at Plutonic that occurred >300 Myr later than previously thought. A Rb–Sr age of 2296 ± 99 Ma from muscovite in an Au-bearing sample records resetting or closure of the Rb–Sr system in muscovite at about the same time. A younger Rb–Sr age of 1779 ± 46 Ma from biotite from the same sample may record further cooling, or resetting during a late-stage episode of metasomatism in the PWGB. This could have been associated with the 1820–1770 Ma Capricorn Orogeny, or a late-stage hydrothermal event potentially constrained by a new ²⁰⁷Pb–²⁰⁶Pb age of 1725 ± 26 Ma for titanite in a chlorite–carbonate vein. This titanite age correlates with a pre-existing age for a metasomatic event dated at 1719 ± 14 Ma by U–Pb ages of zircon overgrowths in a sample from the Marymia Deposit. Based on the Pb-isotope data presented here, Au mineralising events in the PWGB are inferred to have occurred at ca 2630, 2300–2100 Ma, during the Glenburgh and Capricorn orogenies, and 1730–1660 Ma. The 2300–2100 Ma event, which appears to have been significant based on the amount of sulfide of this age, correlates with the inferred age for rifting of the Marymia Inlier from the northern margin of the Yilgarn Craton. The texturally-later visible Au may have been deposited during the Glenburgh and Capricorn orogenies.     

U–Pb detrital zircon ages of sediments from the Firgoun and Niamey areas (eastern border of West African Craton,West Niger)

This study uses field observations and new U–Pb ages of detrital zircon grains from three samples to question the stratigraphic position of the Firgoun and Niamey siliciclastic sediments, presumed to be Neoproterozoic in age. Sharing several lithological similarities with the Late Cryogenian “Triad” of the Taoudenni, Gourma, and Volta basins, the uppermost siliciclastic sediments of the Firgoun and Niamey areas were likely also deposited during this period. This is corroborated by matrix-supported diamictites with faceted or striated pebbles as well as by structures resembling cryoturbation processes. However, the detrital zircon U–Pb age record that we present here for the lowermost deposits of Firgoun and Niamey provides mainly Paleoproterozoic ages, and very few Archean ages, altogether in a range from 1822 ± 9 to 3392 ± 9 Ma. Therefore, the new data only show that the Firgoun and Niamey sediments were deposited before about 1800 Ma. Nevertheless, the U–Th–Pb zircon age data allows examining the possible provenance of the sediments. We show that the latter was likely in the westerly close vicinity of the studied areas. The Archean zircons are likely inherited, and possibly originating from a more westerly source. The nearby source of the Niamey and Firgoun sediments suggests that a high topographic relief was still existing in the south-central part of the West African Craton in the Mid Neoproterozoic.     

Controls on hydrothermal Fe oxide–Cu–Au–Co mineralization at the Guelb Moghrein deposit, Akjoujt area, Mauritania

The Guelb Moghrein Fe oxide–Cu–Au–Co deposit, with a total resource of 23.6 Mt at 1.88% Cu, 1.41 g/t Au, and 143 g/t Co, is hosted by an extensive metacarbonate body. However, it is restricted to up to 30-m wide tabular breccia zones developed parallel to discrete shear zones that transect the host metacarbonates. The Fe–Mg clinoamphibole–chlorite schists represent up to 1-m thick interlayer metasediments and localized viscous shearing in these shear zones. Siderite of the metacarbonate body was deformed into a breccia and was replaced by an ore and alteration assemblage comprised of Fe–Mg clinoamphibole, magnetite, pyrrhotite, chalcopyrite, graphite, Fe–Co–Ni arsenides, arsenopyrite, cobaltite, uraninite, and Bi–Au–Ag–Te minerals. In contact with wall rock amphibolites, the metacarbonate body is enveloped by an alteration halo up to 40 m wide, consisting of biotite, actinolite, grunerite, chlorite, calcite, albite, and quartz. The Guelb Moghrein ore body is structurally controlled by shear zones that developed in the footwall of a regional thrust zone. This thrust separates greenschist facies quartz–sericite schists and biotite–garnet–quartz schists of the Sainte Barbe volcanic unit in the hanging wall from amphibolite facies metavolcanic rocks, metacarbonates, and the Guelb Moghrein ore body of the Akjoujt metabasalt unit in the footwall. Peak temperatures of the latter unit are estimated by hornblende–plagioclase thermometry at 580±40°C. Thrusting was retrograde for the Akjoujt metabasalt unit, but prograde for the Sainte Barbe volcanic unit at P–T conditions of about 410±30°C and 2–3 kbar (garnet–biotite thermometry). Structural and petrological evidences suggest that the ore fluids migrated along the shear zones and reacted with the siderite in the metacarbonate. This evolution and the setting of Guelb Moghrein in the fold-and-thrust belt of the Pan-African to Variscan Mauritanides (Mauritania, West Africa) resemble Proterozoic Fe oxide–Cu–Au–Co deposits such as examples from the Tennant Creek and Mount Isa Inliers, Australia.Electronic Supplementary Material Supplementary material is available for this article at     

Detrital zircon record of the Paleoproterozoic to Mesoproterozoic cratonic basins in the São Francisco Craton

Paleoproterozoic to Mesoproterozoic cratonic basins in the São Francisco Craton are classified into three megasequences: Statherian, Calymmian–early Ectasian, and Stenian–early Tonian sequences. The location, depositional age, and provenance of these sequences are reflected in their detrital zircon U–Pb age distributions. A minimum of five detrital zircon age distributions are distinguishable: i) the Archean and Rhyacian distribution, which is restricted to the Calymmian interval at Chapada Diamantina; ii) the Rhyacian distribution, which occurs in the Statherian, Calymmian, and Stenian intervals and generally precedes the Proterozoic distribution; iii) the Proterozoic distribution, which always succeeds the Rhyacian distribution and appears in the Brasília Belt and Southern Espinhaço; iv) the mixed Archean and Proterozoic distribution, restricted to the Stenian interval at the Southern Brasília Belt; and v) the Statherian distribution, which is present in the Statherian interval at Espinhaço Basin and is recycled into the Calymmian and Stenian intervals at Chapada Diamantina. Based on the Hf isotope compositions of the detrital zircons, most of the sequences are predominantly sourced from Archean juvenile terrains and from Archean and Paleoproterozoic evolved terrains. The exception is the Paranoá Group, western São Francisco Craton, whose positive ɛHf(t) values suggest juvenile Paleoproterozoic sources such as the Goiás Massif. The Archean zircons from Chapada Diamantina have Hf depleted mantle model ages ranging from Paleoarchean to Neoarchean and are mainly derived from the Gavião Block within northeastern São Francisco Craton. The model unify a dataset spanning hundreds of millions of years of the depositional record over a large area of central and eastern Brazil. The records will assist researchers in unraveling the sedimentary and tectonic history of the Archean and Paleoproterozoic continents from new data collected regionally and in other continents.     

Mesoproterozoic fluid events affecting Archean crust in the northern Olympic Cu–Au Province,Gawler Craton: insights from 40Ar/39Ar thermochronology

The Olympic Cu–Au Province, Gawler Craton, is host to the Olympic Dam and Prominent Hill iron oxide–copper–gold (IOCG) deposits. Both of these deposits and the region between the two are covered by Neoproterozoic to Cenozoic sediment, making inferences about prospectivity in this portion of the Olympic Domain reliant on geophysical interpretation and sparse drill hole information. We present new U–Pb zircon sensitive high resolution ion microprobe (SHRIMP) dates from two basement intersecting drill holes in the region between Olympic Dam and Prominent Hill that show bimodal volcanism occurred at 2555 ± 5 Ma, and was followed by intrusion of tonalite at 2529 ± 6 Ma. Laser ⁴⁰Ar/³⁹Ar dating of biotite and muscovite from the tonalite yields ages around ca 2000 Ma, consistent with slow cooling trends observed in Archean rocks elsewhere in the northern Gawler Craton. Step heating experiments on K-feldspar from the same tonalite yields an age spectrum with older ages around 1740 Ma from the highest temperature steps becoming progressively younger to a minimum of 1565 Ma in the lowest temperature heating steps; this is consistent with either Paleoproterozic cooling to final closure of K-feldspar by 1565 Ma or a reheating event at ca 1565 Ma, with the latter more likely, given the evidence for sub-solidus alteration of the K-feldspar. Sericite within hematite–sericite–chlorite altered portions of the tonalite yield a poorly defined age of ca 1.6 Ga. Taken together the ⁴⁰Ar/³⁹Ar data providing evidence for a fluid event affecting this region between Olympic Dam and Prominent Hill during the early Mesoproterozoic. Low temperature quartz–carbonate–adularia veins occur in <10 cm wide fractures within basalt in one drill hole in this region. Adularia from these veins yields ⁴⁰Ar/³⁹Ar ages that span from ca 1.3–1.1 Ga. This age range is interpreted to approximate either the timing of adularia formation during a hydrothermal event or the timing of resetting of the ⁴⁰Ar/³⁹Ar systematics within the adularia as a result of fluid flow in this sample. This is evidence for a mid-Mesoproterozoic fluid event in the Gawler Craton and necessitates a reconsideration of the long-term stability of the craton, as it appears to have been affected, at least locally, by fluid flow related to a much larger event within the Australian continent, the Musgrave Orogeny.     

Geochemistry and geochronology of the ~620 Ma gold-associated Batouri granitoids,Cameroon

The Batouri gold mining area in southeastern Cameroon is part of the Adamawa–Yadé Domain of the Central African Fold Belt (Pan-African). It is underlain by a variety of granitic rocks, including alkali-feldspar granite, syeno-monzogranite, granodiorite, and tonalite. Geochemical data suggest that these rocks formed by differentiation of I-type tonalitic magma under oxidizing conditions in a continental volcanic arc setting. U–Pb dating of zircons from gold-associated monzogranite-granodiorite at Kambélé gave concordant ages of 619 ± 2 and 624 ± 2 Ma, while Ar–Ar dating of alkali-feldspar granite yielded a non-plateau maximum age of 640–620 Ma. These ages imply that the Batouri granitoids were emplaced during the collision of the West African Craton and the Congo Craton.

The geochemical characteristics of the Batouri granitoids as well as their oxidized state (magnetite series) are typical of gold-associated felsic rocks in subduction settings elsewhere. The similarities in age, composition, and geochemical affinities of these granitoids with those reported from other localities in the Adamawa–Yadé Domain reinforce the earlier assumption that the granitic rocks of this domain represent parts of a regional-scale batholith, with commonly small-scale, high-grade auriferous quartz veins in structurally favourable sites. The spatial and temporal association of gold mineralization and the Batouri granitoids may suggest potential for regional-scale, high-tonnage, granite-related gold ore.     

SOVETSKAYA GEOLOGIYA (SOVIET GEOLOGY) IN COVER-TO-COVER TRANSLATION, 1960, NOS. 11 AND 12

The Río Negro-Juruena Province (RNJP) occupies a large portion of the western part of the Amazonian Craton and is a zone of complex granitization and migmatization. Regional metamorphism, in general, occurred in the upper amphibolite facies. The granites and gneisses of the RNJP yield Rb-Sr and Pb-Pb whole-rock isochron dates ranging from 1.8 Ga to 1.55 Ga, with initial ⁸⁷Sr/⁸⁶Sr ratios of ～ 0.703 and a single-stage model μ₁ value of ～ 8.1. In order to improve the geochronological control, SHRIMP U-Pb zircon ages, conventional U-Pb zircon ages, and additional Pb-Pb whole-rock isochron ages were determined for samples of granitoids and gneisses from the Papuri-Uaupés and Guaviare-Orinoco rivers areas (northern part of the province) and Jamari-Machado rivers and Pontes de Lacerda areas (southern part). The granitoids from the northern part of the province yield conventional U-Pb zircon ages of 1709 ± 17 Ma and 1521 ± 31 Ma, and SHRIMP U-Pb concordant zircon results of 1800 ± 18 Ma. Samples of gneissic rocks from the southern part of the RNJP yielded SHRIMP U-Pb concordant ages of 1750 ± 24 Ma and 1570 ± 17 Ma and a Pb-Pb whole-rock isochron age of 1717 ± 120 Ma. These new U-Pb and Pb-Pb results confirm the previous Rb-Sr and Pb-Pb geochronological evidence that the main magmatic episodes within the RNJP occurred between 1.8 and 1.55 Ga, and suggest that this crustal province constitutes a segment of continental crust newly added to the Amazonian Craton at the end of the Early Proterozoic. In the area of the RNJP, there are several anorogenic rapakivi-type granite plutons. Because of the absence of recognized Archean material within the basement rocks, it is reasonable to consider the Early to Middle Proterozoic continental crust as the magmatic source for the rapakivi granite intrusions.     

Provenance of late Paleoproterozoic cover sequences in the central Gawler Craton: exploring stratigraphic correlations in eastern Proterozoic Australia using detrital zircon ages,Hf and Nd isotopic data

Provenance data from Paleoproterozoic and possible Archean sedimentary units in the central eastern Gawler Craton in southern Australia form part of a growing dataset suggesting that the Gawler Craton shares important basin formation and tectonic time lines with the adjacent Curnamona Province and the Isan Inlier in northern Australia. U–Pb dating of detrital zircons from the Eba Formation, previously mapped as the Paleoproterozoic Tarcoola Formation, yields exclusively Archean ages (ca 3300–2530 Ma), which are consistent with evolved whole-rock Nd and zircon Hf isotopic data. The absence of Paleoproterozoic detrital grains in a number of sequences (including the Eba Formation), despite the proximity of voluminous Paleoproterozoic rock units, suggests that the Eba Formation may be part of a Neoarchean or early Paleoproterozoic cover sequence derived from erosion of a multi-aged Archean source region. The ca 1715 Ma Labyrinth Formation, unconformably overlying the Eba Formation, shares similar depositional timing with other basin systems in the Gawler Craton and the adjacent Curnamona Province. Detrital zircon ages in the Labyrinth Formation range from Neoarchean to Paleoproterozoic, and are consistent with derivation from >1715 Ma components of the Gawler Craton. Zircon Hf and whole-rock Nd isotopic data also suggest a source region with a mixed crustal evolution (ε_Nd –6 to –4.5), consistent with what is known about the Gawler Craton. Compared with the lower Willyama Supergroup in the adjacent Curnamona Province, the Labyrinth Formation has a source more obviously reconcilable with the Gawler Craton. Stratigraphically overlying the Eba and Labyrinth Formations is the 1656 Ma Tarcoola Formation. Zircon Hf and whole-rock Nd isotopic data indicate that the Tarcoola Formation was sourced from comparatively juvenile rocks (ε_Nd –4.1 to + 0.5). The timing of Tarcoola Formation deposition is similar to the juvenile upper Willyama Supergroup, further strengthening the stratigraphic links between the Gawler and Curnamona domains. Additionally, the Tarcoola Formation is similar in age to extensive units in the Mt Isa and Georgetown regions in northern Australia, also shown to be isotopically juvenile. These juvenile sedimentary rocks contrast with the evolved underlying sequences and hint at the existence of a large-scale ca 1650 Ma juvenile basin system in eastern Proterozoic Australia.     

Palaeogeography and crustal evolution of the Ossa–Morena Zone,southwest Iberia,and the North Gondwana margin during the Cambro-Ordovician: a review of isotopic evidence

Cambro-Ordovician palaeogeography and fragmentation of the North Gondwana margin is still not very well understood. Here we address this question using isotopic data to consider the crustal evolution and palaeogeographic position of the, North Gondwana, Iberian Massif Ossa–Morena Zone (OMZ). The OMZ preserves a complex tectonomagmatic history: late Neoproterozoic Cadomian orogenesis (ca. 650–550 Ma); Cambro-Ordovician rifting (ca. 540–450 Ma); and Variscan orogenesis (ca. 390–305 Ma). We place this evolution in the context of recent North Gondwana Cambro-Ordovician palaeogeographic reconstructions that suggest more easterly positions, adjacent to the Sahara Metacraton, for other Iberian Massif zones. To do this we compiled an extensive new database of published late Proterozoic–Palaeozoic Nd model ages and detrital and magmatic zircon age data for (i) the Iberian Massif and (ii) North Gondwana Anti-Atlas West African Craton, Tuareg Shield, and Sahara Metacraton. The Nd model ages of OMZ Cambro-Ordovician crustal-derived magmatism and Ediacaran-Ordovician sedimentary rocks range from ca. 1.9 to 1.6 Ga, with a mode ca. 1.7 Ga. They show the greatest affinity with the Tuareg Shield, with limited contribution of more juvenile material from the Anti-Atlas West African Craton. This association is supported by detrital zircons that have Archaean, Palaeoproterozic, and Neoproterozoic radiometric ages similar to the aforementioned Iberian Massif zones. However, an OMZ Mesoproterozoic gap, with no ca. 1.0 Ga cluster, is different from other zones but, once more, similar to the westerly Tuareg Shield distribution. This places the OMZ in a more easterly position than previously thought but still further west than other Iberian zones. It has been proposed that in the Cambro-Ordovician the North Gondwana margin rifted as the Rheic Ocean opened diachronously from west to east. Thus, the more extensive rift-related magmatism in the westerly OMZ than in other, more easterly, Iberian Massif zones fits our new proposed palaeogeographic reconstruction.     

First Evidence of the Archean Age of Orogenic Gold of the Russian Part of the Karelian Craton (Fennoscandian Shield): Sm–Nd Mineral Isochron for Gold-Bearing Metasomatites of the Novye Peski Deposit

One unsolved problem of Archean metallogeny of the Russian part of the Fennoscandian Shield is related to the period of formation of orogenic gold deposits, the age of which was previously considered Early Proterozoic. Comprehensive studies identified the complex evolution of ores from the Novye Peski deposit and the first Neoarchean Sm–Nd isochron isotopic age (2583 ± 16 Ma) of the formation of orogenic gold of the Karelian Craton. A significant positive ε_Nd(t) value of +4.7 of gold-bearing metasomatites probably points to the link between the ore-forming fluid and the deep mantle source.

     

Linking gold mineralization to regional-scale drivers of mineral systems using in situ U–Pb geochronology and pyrite LA-ICP-MS element mapping

Proterozoic orogens commonly host a range of hydrothermal ores that form in diverse tectonic settings at different times. However, the link between mineralization and the regional-scale tectonothermal evolution of orogens is usually not well understood, especially in areas subject to multiple hydrothermal events.Regional-scale drivers for mineral systems vary between the different classes of hydrothermal ore, but all involve an energy source and a fluid pathway to focus mineralizing fluids into the upper crust. The Mount Olympus gold deposit in the Proterozoic Capricorn Orogen of Western Australia, was regarded as an orogenic gold deposit that formed at ca. 1738 Ma during the assembly of Proterozoic Australia. However,the trace element chemistry of the pyrite crystals closely resembles those of the Carlin deposits of Nevada,with rims that display solid solution gold accompanied by elevated As, Cu, Sb, Hg, and Tl, surrounding gold-poor cores. New SHRIMP UeP b dating of xenotime intergrown with auriferous pyrite and ore-stage alteration minerals provided a weighted mean~(207) Pb*/~(206) Pb* date of 1769 ± 5 Ma, interpreted as the age of gold mineralization. This was followed by two discrete episodes of hydrothermal alteration at 1727 ± 7 Ma and 1673 ± 8 Ma. The three ages are linked to multiple reactivation of the crustal-scale Nanjilgardy Fault during repeated episodes of intracratonic reworking. The regional-scale drivers for Carlin-like gold mineralization at Mount Olympus are related to a change in tectonic regime during the final stages of the intracratonic 1820 -1770 Ma Capricorn Orogeny. Our results suggest that substantial sized Carlin-like gold deposits can form in an intracratonic setting during regional-scale crustal reworking.     

High-grade Paleoproterozoic reworking in the southeastern Gawler Craton,South Australia ∗

SHRIMP U–Pb geochronology and monazite EPMA chemical dating from the southeast Gawler Craton has constrained the timing of high-grade reworking of the Early Paleoproterozoic (ca 2450 Ma) Sleaford Complex during the Paleoproterozoic Kimban Orogeny. SHRIMP monazite geochronology from mylonitic and migmatitic high-strain zones that deform the ca 2450 Ma peraluminous granites indicates that they formed at 1725 ± 2 and 1721 ± 3 Ma. These are within error of EPMA monazite chemical ages of the same high-strain zones which range between 1736 and 1691 Ma. SHRIMP dating of titanite from peak metamorphic (1000 MPa at 730°C) mafic assemblages gives ages of 1712 ± 8 and 1708 ± 12 Ma. The post-peak evolution is constrained by partial to complete replacement of garnet–clinopyroxene-bearing mafic assemblages by hornblende–plagioclase symplectites, which record conditions of ～600 MPa at 700°C, implying a steeply decompressional exhumation path. The timing of Paleoproterozoic reworking corresponds to widespread deformation along the eastern margin of the Gawler Craton and the development of the Kalinjala Shear Zone.     

First evidence for Cambrian rift-related magmatism in the West African Craton margin: The Derraman Peralkaline Felsic Complex

West of the southern, Archean, part of the Reguibat Rise of the West African Craton the Oulad Dlim Massif consists of metamorphic nappes stacked during the Mauritanides (Variscan) orogeny. In the Derraman region, about 12 km west of the nappes, we have found strongly deformed hypersolvus aegirine-riebeckite A1-type granites with SHRIMP zircon U–Pb ages of ca. 525 ± 3 Ma, ε(Nd)_525Ma (− 5.2 to − 6.8.) and Nd model ages T_CR ≈ 1.85 Ga. These granites define two km-sized bodies and a few smaller satellites. One body is emplaced within a 3.12 Ga leucocratic gneiss. The other body and its satellites are emplaced within an Archean low-grade metasedimentary sequence with detrital zircons that have ages that peak at 2.84 Ga, 2.91 Ga, and 3.15 Ga. These Archean gneisses and metapelite rocks define a tectonic unit, hereafter called the Derraman-Bulautad-Leglat (DBL) unit, which was formed from the Reguibat basement at the very margin of the WAC. The ~ 525 Ma Derraman granites are the oldest post-Archean rocks in this unit and were generated in an intraplate rifting environment from melting of crustal fenites during the ubiquitous Cambrian rifting event that affected this part of northern Gondwana. At the present level of knowledge, however, we cannot decide whether the “old” Nd isotope signature of Derraman granites resulted from melting of an old (Paleoproterozoic) fenite source or reflects the signature of the mantle-derived metasomatising fluids. The just-discovered Derraman granites are strikingly similar to other rift-related Cambrian–Ordovician hypersolvus aegirine–riebeckite granites widespread in North Gondwana. Understanding the potential connections between them would help to understand the Cambrian–Ordovician breakdown of northern Gondwana.     

Gold deposits associated with the gabbroic rocks at Tirek area,western Hoggar,Algeria: fluid inclusion study

The Tirek gold deposit hosted in the Archean shield is one of the richest sources of mined gold for Algeria. The deposit is controlled by the East Ouzzal shear zone (EOSZ), a transcurrent N–S lithospheric fault. The EOSZ is a late Pan-African dextral-ductile shear zone separating two contrasting Precambrian domains: the Archean In Ouzzal block to the west (Orthogenesis with subordinate metasediments reworked and granulitized during the ca. 2 Ga Eburnean event) and a middle Proterozoic block to the east involved in the ca. 600 Ma Pan-African event. The auriferous quartz veins are mainly oriented in two directions, N–S veins hosted in mylonitic rocks and NE–SW veins hosted in gabbroic or gneissic bands. The NE–SW veins contain the richest ore. Gold ore is found in a system of veins and lenticular quartz veinlets arranged in anastomosing networks. The hydrothermal alteration associated with these veins is characteristically a carbonate-sericite-albite-pyrite assemblage. Gold is the main metal of economic importance; it is disseminated in the quartz as grains or fibers along microcracks and as microscopic grains in the host rocks. Microthermometric results and Raman laser data from fluid inclusions demonstrate that the ore-forming fluids contained H₂O-CO₂±CH₄ and were low salinity. Homogenization temperatures are commonly 250–310 °C. In the Tirek deposit, the role of the shear zone that hosts the mineralization was to drain the hydrothermal fluid. Interactions between the fluid and the mafic host rocks and CO₂ also contributed to the formation of the hydrothermal gold deposit at Tirek.     

Ordovician high-grade metamorphism of a newly recognised late Neoproterozoic terrane in the northern Harts Range,central Australia

Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800–875 °C and >9–10 kbar) and subsequent decompression in a kilometre‐scale, E‐W striking zone of noncoaxial, high‐grade (c. 700–735 °C and 5.8–6.4 kbar) deformation. However, new SHRIMP U‐Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta‐volcaniclastics) yield ²⁰⁶Pb/²³⁸U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield ²⁰⁶Pb/²³⁸U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400–300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475–460 Ma & 400–300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300–1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed.     

A deep borehole in the East European platform margin: Petrologic and isotopic-geochronologic data

The petrologic and isotopic-geochronologic study of basement rocks that were penetrated by a deep borehole in the marginal part of the East European Platform revealed that its section overlain by the Vendian-Paleozoic sedimentary cover is Early Proterozoic in age and largely consists of aluminous migmatized biotite, biotite-cordierite, and biotite-cordierite-sillimanite gneisses, which are intruded by granites, plagiogranites, and metatonalites. The lower part of the section is dominated by amphibole schists and amphibolites with subordinate nonmetamorphosed dolerite dikes and pegmatite veins. By metamorphism parameters (T = 630–680°C, P = 2–4 kbar), the metamorphic complex may be considered as the shallowest one, compared with other Early Proterozoic complexes, developed at least in the southwestern part of Fennoscandia. The progressive decrease in the mineral-formation pressure observed in the Lower Proterozoic metamorphic rocks southward, away from the Karelian Craton is likely explained by the tectonic transport (thrusting) of the Svecofennides over the margin of the Karelian Craton and their subsequent deeper erosion near the craton. The magmatic crystallization of metamorphic palgiogranites, penetrated at depths of 925–928 and 1004 m, is estimated by the U-Pb ID-TIMS method on zircons to occur 1860 ± 9 Ma ago. It is shown that by their age, the REE composition, and isotopic-geochemical characteristics, these rocks are close to the plagiogranites formed in the southeastern extremity of the Svecofennnian belt in the present-day northern Ladoga region and the Karelian Isthmus. No rocks, which could be correlated by their lithology with the Archean rocks of the Karelian Craton, are found.     

Evolution of subcontinental lithospheric mantle beneath eastern China: Re–Os isotopic evidence from mantle xenoliths in Paleozoic kimberlites and Mesozoic basalts

The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of ∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton.