Enrichment and distribution of shale oil in the Cretaceous Qingshankou Formation,Songliao Basin,Northeast China

The Songliao Basin is a large-scale petroliferous basin in China. With a gradual decline in conventional oil production, the exploration and development of replacement resources in the basin is becoming increasingly important. Previous studies have shown that the Cretaceous Qingshankou Formation (K₂qn) has favorable geological conditions for the formation of shale oil. Thus, shale oil in the Qingshankou Formation represents a promising and practical replacement resource for conventional oil. In this study, geological field surveys, core observation, sample tests, and the analysis of well logs were applied to study the geochemical and reservoir characteristics of shales, identify shale oil beds, build shale oil enrichment models, and classify favorable exploration areas of shale oil from the Cretaceous Qingshankou Formation. The organic matter content is high in shales from the first member of the Cretaceous Qingshankou Formation (K₂qn¹), with average total organic carbon (TOC) content exceeding 2%. The organic matter is mainly derived from lower aquatic organisms in a reducing brackish to fresh water environment, resulting in mostly type I kerogen. The vitrinite reflectance (Ro) and the temperature at which the maximum is release of hydrocarbons from cracking of kerogen occurred during pyrolysis (T_max) respectively range from 0.5% to 1.1% and from 430 °C to 450 °C, indicating that the K₂qn¹ shales are in the low-mature to mature stage (Ro ranges from 0.5% to 1.2%) and currently generating a large amount of oil. The favorable depth for oil generation and expulsion is 1800–2200 m and 1900–2500 m, respectively as determined by basin modeling. The reserving space of the K₂qn¹ shale oil includes micropores and mircofractures. The micropore reservoirs are developed in shales interbedded with siltstones exhibiting high gamma ray (GR), high resistivity (Rt), low density (DEN), and slightly abnormal spontaneous potential (SP) in the well-logging curves. The microfracture reservoirs are mainly thick shales with high Rt, high AC (acoustic transit time), high GR, low DEN, and abnormal SP. Based on the shale distribution, geochemical characteristics, reservoir types, fracture development, and the process of shale oil generation and enrichment, the southern Taikang and northern Da'an are classified as two favorable shale oil exploration areas in the Songliao Basin.     

Architecture of lacustrine mass-transport complexes in the Mesozoic Songliao Basin,China

3-D seismic data and wireline log profiles of the Central Depression in the Songliao Basin exhibit four lacustrine mass-transport complexes (MTCs) in the second and the third members of the Upper Cretaceous Nenjiang Formation. The mass-transport complex named MTC-A lies in the north of the Daqing Anticline with an area of approximately 95 km² and a maximum thickness of 62 m. It consists of five laterally and vertically stacked blocks striking E-W and has a convex-downslope front. The mass-transport complex named MTC-C is located in the south of the Daqing Anticline consisting of seven blocks. This MTC strikes NNE-SSW and has an area of approximately 61.5 km² and a maximum thickness of 55 m. MTC-B, the mass-transport complex lying in the middle of the Daqing Anticline, consists of three vertically stacked blocks and has a semi-circular outline striking E-W. MTC-B has an area of approximately 24 km² and a maximum thickness of 92 m. Along the Daqing Anticline from north to south, the three MTCs distribute in lacustrine facies in the NNE direction. The mass-transport complex named MTC-D located in the southeast of the Daqing Anticline has an area of approximately 150 km² with a maximum thickness of 135 m striking E-W, which is rich in mudstones. MTC-D is characterized by the three-layer architecture vertically consisting of a dragged layer at the bottom, a slumped layer in the middle, and a stable layer at the top. Besides, in the plane view, MTC-D can be divided into three parts according to the sliding distance and stacking pattern of the slip blocks: the detaching area, the stacking area and the drifting area. The MTCs are characterized by thickening upslope and thin-out downslope. Siltstones and very fine sandstones occur in 2–4 beds that are cumulatively 0.8–7 m thick in the upslope and central parts of the MTCs. The edges of the blocks are composed of mudstone. Seismic amplitude slices reveal arcuate or straight ridges on the block surfaces with a spacing density of 4–10 per kilometer and a height ranging from 25 to 40 m. The arcuate ridge paleo-morphology on the MTC surfaces suggests that blocks are slump bodies. The estimated minimum water depth at the time of the MTC emplacement is 30–70 m, and the sliding distance is 2–10 km. From 3-D seismic amplitude slices, no feeding channel connected to the mass-transport complexes is found. Besides, coupled with the continuous ridges on blocks and the clear and flat lateral edges suggest that mass-transport complexes belong to the prodelta slump bodies. Thus, the triggering mechanism of the MTCs may be closely related to earthquakes caused by volcanic activities with the evidence of three cinerite layers shown in the well cores.     

Geochemistry,origin, and accumulation of petroleum in the Eocene Wenchang Formation reservoirs in Pearl River Mouth Basin,South China Sea: A case study of HZ25-7 oil field

The Pearl River Mouth Basin in the South China Sea has accumulated >2 km of Eocene sediments in its deep basin, and has become the exploration focus due to the recent discoveries of the HZ25-7 oil field in the Eocene Wenchang (E₂w) Formation. In this study, the geochemical characteristics of potential source rocks and petroleum in the HZ25-7 oil field are investigated and the possible origins and accumulation models developed. The analytical results reveal two sets of potential source rocks, E₂w and Enping (E₂e) formations developed in the study area. The semi-deep-to-deep lacustrine E₂w source rocks are characterized by relatively low C₂₉ steranes, low C₁₉/C₂₃ tricyclic terpane (<0.6), low C₂₄ tetracyclic terpane/C₃₀ hopane (<0.1), low trans-trans-trans-bicadinane (T)/C₃₀ hopane (most <2.0), and high C₃₀ 4-methyl sterane/ΣC₂₉ sterane (>0.2) ratios. In contrast, the shallow lacustrine and deltaic swamp-plain E₂e source rocks are characterized by relatively high C₂₉ steranes, high C₁₉/C₂₃ tricyclic terpane (>0.6), high C₂₄ tetracyclic terpane/C₃₀ hopane (>0.1), variable yet overall high T/C₃₀ hopane, and low C₃₀ 4-methyl sterane/ΣC₂₉ sterane (<0.2) ratios. The relatively low C₁₉/C₂₃ tricyclic terpane ratios (mean value: 0.39), low C₂₄ tetracyclic terpane/C₃₀ hopane ratios (mean value: 0.07), high C₃₀ 4-methyl sterane/ΣC₂₉ sterane ratios (mean value: 1.14), and relatively high C₂₇ regular sterane content of petroleum in the HZ25-7 oil field indicate that the petroleum most likely originated from the E₂w Formation mudstone in the Huizhou Depression. One stage of continuous charging is identified in the HZ25-7 oil field; oil injection is from 16 Ma to present and peak filling occurs after 12 Ma. Thin sandstone beds with relatively good connectivity and physical properties (porosity and permeability) in the E₂w Formation are favorable conduits for the lateral migration of petroleum. This petroleum accumulation pattern implies that the E₂w Formation on the western and southern margins of the Huizhou Depression are favorable for petroleum accumulation because they are located in a migration pathway. Thus exploration should focus in these areas in the future.     

Geochemical overview and undiscovered gas resources generated from Hamitabat petroleum system in the Thrace Basin,Turkey

Since the first drill in 1957, three oil, 19 gas and condensate fields have been discovered in the Thrace Basin. However, any petroleum system with its essential elements and processes has not been assigned yet. This study consists of two parts, (1) geochemical overview of the previous work in order to get a necessary help to construct a petroleum system and (2) calculation of quantitative undiscovered hydrocarbon resources generated from this system. An extensive overview study showed that the primary reservoir and source rocks in the Thrace Basin are the Middle Eocene Hamitabat sandstones and shales, respectively, hence it appears that the most effective petroleum system of the Thrace Basin becomes the Hamitabat (!) petroleum system. Currently, 18.5 billion m³ of in-place gas, 2.0 million m³ (12.7 million bbl) in-place waxy oil as well as minor amount of associated condensate were discovered from this system. This study showed that the regional distribution of the oil and gas fields almost overlapped with the previously constructed pod of active Hamitabat shales implying that short and up-dip vertical migration pathway of hydrocarbons from the source to trapping side was available. Thermal model demonstrated that hydrocarbon generation from the Hamitabat shales commenced in the Early Miocene. The amount of quantitative gas generation based on the mean-original TOC = 0.94 wt%, mean-original HI = 217 HC/g TOC and the volume of the pod of active source rock = 49 km³ is approximately 110 billion m³ of gaseous hydrocarbons that results in a high generation–accumulation efficiency of 17% when 18.5 billion m³ of already discovered hydrocarbons are considered.     

Basin modeling of the Late Miocene Zeit source rock in the Sudanese portion of Red Sea Basin: Implication for hydrocarbon generation and expulsion history

The Late Miocene Zeit Formation is exposed in the Red Sea Basin of Sudan and represents an important oil-source rock. In this study, five (5) exploratory wells along Red Sea Basin of Sudan are used to model the petroleum generation and expulsion history of the Zeit Formation. Burial/thermal models illustrate that the Red Sea is an extensional rift basin and initially developed during the Late Eocene to Oligocene. Heat flow models show that the present-day heat flow values in the area are between 60 and 109 mW/m². The variation in values of the heat flow can be linked to the raise in the geothermal gradient from margins of the basin towards offshore basin. The offshore basin is an axial area with thick burial depth, which is the principal heat flow source.The paleo-heat flow values of the basin are approximately from 95 to 260 mW/m², increased from Oligocene to Early Pliocene and then decreased exponentially prior to Late Pliocene. This high paleo-heat flow had a considerable effect on the source rock maturation and cooking of the organic matter. The maturity history models indicate that the Zeit Formation source rock passed the late oil-window and converted the oil generated to gas during the Late Miocene.The basin models also indicate that the petroleum was expelled from the Zeit source rock during the Late Miocene (>7 Ma) and it continues to present-day, with transformation ratio of more than 50%. Therefore, the Zeit Formation acts as an effective source rock where significant amounts of petroleum are expected to be generated in the Red Sea Basin.     

Oil migration through preferential petroleum migration pathway (PPMP) and polycyclic faults: A case study from the Shijiutuo Uplift,Bohai Bay basin,China

The Shijiutuo uplift is an oil enriched uplift in the offshore Bohai Bay Basin. Petroleum migration is a key factor for oil enrichment in Neogene reservoirs far away from the hydrocarbon kitchen. In this article, an integration of geological, geophysical and geochemical analyses are employed to investigate the petroleum migration and accumulation on the Shijiutuo uplift. Hydrocarbons in the QHD32-6 and QHD33 oilfields are mainly originated from the third (E₂s₃) and first (E₂s₁) member of the Shahejie Formation. The shallow traps have significant contributions of late-stage E₂s₁-derived oil. Lateral petroleum migration is a major mechanism forming large oilfields on the Shijiutuo uplift. The large oilfields have multiple hydrocarbon kitchens, multiple source rocks, and numerous preferential petroleum migration pathways (PPMPs). Once petroleum arrives at the structural highs on the Shijiutuo uplift through the Guantao Formation (N₁g) carrier-beds, neotectonic faults cutting through Guantao (N₁g) and Minghuazhen (N₁m^L) formations could serve as effective conduits for vertical petroleum migration. Neotectonic faults have experienced polycyclic fault activities. Fluid inclusions indicate episodic hydrocarbon charging. Crude oils display duplex properties of biodegradation and non-biodegradation, which is strong evidence for multiple and episodic oil charging on the Shijiutuo uplift. Finally, episodic petroleum charging along polycyclic neotectonic faults causes the late-stage E₂s₁-derived oils to occur in the shallow reservoirs.     

Origins of heavy oils in the Erlian Basin, ne China

The Erlian Basin is located in the Central Asia-Mongolian fold belt between the Siberian and Sino-Korean Cratons. It is a Mesozoic continental rift basin composed of 52 individual fault-depressions. The main phase of rifting took place during the Early Cretaceous when a series of fluvial-lacustrine sediments were deposited. Each depression forms an independent sedimentary system and behaves as an independent petroleum system. Hydrocarbon source rocks are found in the upper Arshan and lower Tengger Formations. These are mainly type II source rocks and are mainly located in oil generation window at the present day. A series of oilfields and commercial oil flows have been found in the basin, highlighting its good petroleum potential. Many of these oils are heavy.Six oil samples from the Anan and ten from the Jirgalangtu Depressions have been subjected to routine geochemical analytical techniques in order to evaluate the origins. The methods used include gas chromatography of the saturated and aromatic hydrocarbon fractions, gas-chromatography-mass-spectrometry of the saturated hydrocarbon fraction and stable carbon isotope analyses. The trace metal elements of the biodegraded oils from the Jirgalangtu Depression were also analysed by atomic absorption spectroscopy.Two types of heavy oils : primary and biodegraded were identified on the basis of these data. The former includes both immature and mature heavy oils. A filtering-and-spill process was proposed to explain the origin of primary mature heavy oils (or tar-mat) in the Anan Depression. The biodegraded oils from the Jirgalangtu Depression were ranked and classified in terms of the degree of biodegradation, using a series of geochemical parameters based on the gas chromatographic concentrations and biomarker fingerprints of gas-chromatography-mass-spectrometry of the saturated hydrocarbon fraction. The relationship between oil saturation and porosity indicates that the heavy oils in the Jirgalangtu Depression were biodegraded after they accumulated.     

Study on the Cretaceous turbidite and reservoir features in the Qingshankou Formation in northern Songliao Basin,NE China

Based on analysis of well and drilling data, cores, sediment grains and 3D seismic data, four types of turbidites–slope fan, channelized, laminated and sublacustrine fan turbidite–are identified in Members 1 and 2 of the Qingshankou Formation in northern Songliao Basin. The slope fan turbidite is located in Members 1 and 2 of the Qingshankou Formation. It is dominated by silt and fine sand and is distributed in an SN-trending ribbon zone along the slope break at delta front in the western part of the basin. The channelized turbidite is located at the bottom of Member 1 of the Qingshankou Formation. It is dominated by silt and fine sand and is distributed in an SN-trending strip-shaped zone along the Qijia-Gulong sag, with funnel-shaped sublacustrine fans at the end. The laminated turbidite body is located in Member 2 of the Qingshankou Formation. It is dominated by siltstone and argillaceous siltstone and is distributed continuously in a tongue-shaped zone along the northern delta front towards the lacustrine region, with belt-like distributaries at the central part and sublacustrine fans at the end. Low-permeability and low-yield lithologic reservoirs are formed near the delta front within the slope fan turbidite and channelized turbidite. There are “sweet spots” in local regions, where reservoir reform techniques are required to attain high industrial yields. Laminated turbidite and sublacustrine fans can form unconventional and continuous reservoirs that generally have no natural productivity; industrial production is impossible until horizontal drilling and multistage volume fracturing are employed. Therefore, the research results are important to the exploration of unconventional oil and gas reservoirs in northern Songliao Basin.     

Petroleum generation and charge history of the northern Dongying Depression,Bohai Bay Basin,China: Insight from integrated fluid inclusion analysis and basin modelling

The petroleum generation and charge history of the northern Dongying Depression, Bohai Bay Basin was investigated using an integrated fluid inclusion analysis workflow and geohistory modelling. One and two-dimensional basin modelling was performed to unravel the oil generation history of the Eocene Shahejie Formation (Es3 and Es4) source rocks based on the reconstruction of the burial, thermal and maturity history. Calibration of the model with thermal maturity and borehole temperature data using a rift basin heat flow model indicates that the upper interval of the Es4 source rocks began to generate oil at around 35 Ma, reached a maturity level of 0.7% R_o at 31–30 Ma and a peak hydrocarbon generation at 24–23 Ma. The lower interval of the Es3 source rocks began to generate oil at around 33–32 Ma and reached a maturity of 0.7% R_o at about 27–26 Ma. Oil generation from the lower Es3 and upper Es4 source rocks occurred in three phases with the first phase from approximately 30–20 Ma; the second phase from approximately 20–5 Ma; and the third phase from 5 Ma to the present day. The first and third phases were the two predominant phases of intense oil generation.Samples from the Es3 and Es4 reservoir intervals in 12 wells at depth intervals between 2677.7 m and 4323.0 m were investigated using an integrated fluid inclusion workflow including petrography, fluorescence spectroscopy and microthermometry to determine the petroleum charge history in the northern Dongying Depression. Abundant oil inclusions with a range of fluorescence colours from near yellow to near blue were observed and were interpreted to represent two episodes of hydrocarbon charge based on the fluid inclusion petrography, fluorescence spectroscopy and microthermometry data. Two episodes of oil charge were determined at 24–20 Ma and 4–3 Ma, respectively with the second episode being the predominant period for the oil accumulation in the northern Dongying Depression. The oil charge occurred during or immediately after the modelled intense oil generation and coincided with a regional uplift and a rapid subsidence, suggesting that the hydrocarbon migration from the already overpressured source rocks may have been triggered by the regional uplift and rapid subsidence. The expelled oil was then charged to the already established traps in the northern Dongying Depression. The proximal locations of the reservoirs to the generative kitchens and the short oil migration distance facilitate the intimate relationship between oil generation, migration and accumulation.     

A comparative study between present and palaeo-heat flow in the Qiangtang Basin,northern Tibet,China

The Qiangtang Basin is a significant prospective area for hydrocarbon and gas hydrate resources in the Tibetan Plateau, China. However, relatively little work has been performed to characterise heat flow in this basin, which has restricted petroleum and gas hydrate exploration. In this study, we compare present and palaeo-heat flow in the Qiangtang Basin to provide information on geothermal regime, hydrocarbon generation and permafrost that is necessary for further petroleum and gas hydrate exploration. We base our study on temperature data from a thermometer well, thermal conductivity tests, vitrinite reflectance data, homogenisation temperature data from fluid inclusions, stratigraphic information and a time-independent modelling approach. Our results indicate that in the central Qiangtang Basin, the present thermal gradient is approximately 15.5 °C/km, and heat flow is approximately 46.69 mW/m². Heat flow in the Qiangtang Basin is not relatively stable since the Early Jurassic, as previous research has suggested, and it is generally decreasing with time. Additionally, there is a clear difference between the hottest thermal regime of the southern and northern Qiangtang Depressions during Cretaceous to Pleistocene time. In the southern Qiangtang Depression, the palaeogeothermal gradient is approximately 32.0 °C/km, and palaeo-heat flow is approximately 70 mW/m². However, in the northern Qiangtang Depression, the palaeogeothermal gradient exceeds 81.8 °C/km, and palaeo-heat flow is greater than 172.09 mW/m². The high thermal regime in the northern Qiangtang Depression is driven mainly by hydrothermal convection. Gas reservoirs are possible targets for hydrocarbon exploration in this depression. Currently, the northwestern part of the northern Qiangtang Depression is the most favourable area for gas hydrate exploration in the Qiangtang Basin.     

Tracing of deeply-buried source rock: A case study of the WC9-2 petroleum pool in the Pearl River Mouth Basin, South China Sea

The identification of a deeply-buried petroleum-source rock, owing to the difficulty in sample collection, has become a difficult task for establishing its relationship with discovered petroleum pools and evaluating its exploration potential in a petroleum-bearing basin. This paper proposes an approach to trace a deeply-buried source rock. The essential points include: determination of the petroleum-charging time of a reservoir, reconstruction of the petroleum generation history of its possible source rocks, establishment of the spatial connection between the source rocks and the reservoir over its geological history, identification of its effective source rock and the petroleum system from source to trap, and evaluation of petroleum potential from the deeply-buried source rock. A case study of the W9-2 petroleum pool in the Wenchang A sag of the Pearl River Mouth Basin, South China Sea was conducted using this approach. The W9-2 reservoir produces condensate oil and gas, sourced from deeply-buried source rocks. The reservoir consists of a few sets of sandstone in the Zhuhai Formation, and the possible source rocks include an early Oligocene Enping Formation mudstone and a late Eocene Wenchang Formation mudstone, with a current burial depth from 5000 to 9000 m. The fluid inclusion data from the reservoir rock indicate the oil and the gas charged the reservoir about 18–3.5 Ma and after 4.5 Ma, respectively. The kinetic modeling results show that the main stages of oil generation of the Wenchang mudstone and the Enping mudstone occurred during 28–20 Ma and 20–12 Ma, respectively, and that the δ¹³C₁ value of the gas generated from the Enping mudstone has a better match with that of the reservoir gas than the gas from the Wenchang mudstone. Results from a 2D basin modeling further indicate that the petroleum from the Enping mudstone migrated upward along the well-developed syn-sedimentary faults in the central area of the sag into the reservoir, but that the petroleum from the Wenchang mudstone migrated laterally first toward the marginal faults of the sag and then migrated upward along the faults into shallow strata. The present results suggest that the trap structure in the central area of the sag is a favorable place for the accumulation of the Enping mudstone-derived petroleum, and that the Wenchang mudstone-derived petroleum would have a contribution to the structures along the deep faults as well as in the uplifted area around the sag.     

Oil-bearing inclusions in vein quartz and calcite and,bitumens in veins: Testament to multiple phases of hydrocarbon migration in the Barrandian basin (lower Palaeozoic), Czech Republic

The petroleum charge history of the Barrandian basin was investigated by analysing quartz and calcite and organic phases that occur in veins and fractures cutting dolerite sills within the Liteň Formation (Silurian). The geochemical characteristics of fluid inclusions trapped in vein quartz and calcite, vein bitumens and adjacent potential source rocks when combined with burial and thermal history data reflect the presence of at least three separate hydrocarbon charge episodes. Solid highly reflecting (R_max = 0.92–1.49%) bitumen provides information on the first and oldest episode of oil migration. The precursor oil was probably derived relatively early during diagenesis from nearby organic-rich sediments and was subsequently thermally altered to form the solid bitumen.     

Petroleum source rock characterisation and hydrocarbon generation modeling of the Cretaceous sediments in the Jiza sub-basin,eastern Yemen

Cretaceous sedimentary rocks of the Mukalla, Harshiyat and Qishn formations from three wells in the Jiza sub-basin were studied to describe source rock characteristics, providing information on organic matter type, paleoenvironment of deposition and hydrocarbon generation potential. This study is based on organic geochemical and petrographic analyses performed on cuttings samples. The results were then incorporated into basin models in order to understand the burial and thermal histories and timing of hydrocarbon generation and expulsion.The bulk geochemical results show that the Cretaceous rocks are highly variable with respect to their genetic petroleum generation potential. The total organic carbon (TOC) contents and petroleum potential yield (S₁ + S₂) of the Cretaceous source rocks range from 0.43 to 6.11% and 0.58–31.14 mg HC/g rock, respectively indicating non-source to very good source rock potential. Hydrogen index values for the Early to Late Cretaceous Harshiyat and Qishn formations vary between 77 and 695 mg HC/g TOC, consistent with Type I/II, II-III and III kerogens, indicating oil and gas generation potential. In contrast, the Late Cretaceous Mukalla Formation is dominated by Type III kerogen (HI < 200 mg HC/g TOC), and is thus considered to be gas-prone. The analysed Cretaceous source rock samples have vitrinite reflectance values in the range of 0.37–0.95 Ro% (immature to peak-maturity for oil generation).A variety of biomarkers including n-alkanes, regular isoprenoids, terpanes and steranes suggest that the Cretaceous source rocks were deposited in marine to deltaic environments. The biomarkers also indicate that the Cretaceous source rocks contain a mixture of aquatic organic matter (planktonic/bacterial) and terrigenous organic matter, with increasing terrigenous influence in the Late Cretaceous (Mukalla Formation).The burial and thermal history models indicate that the Mukalla and Harshiyat formations are immature to early mature. The models also indicate that the onset of oil-generation in the Qishn source rock began during the Late Cretaceous at 83 Ma and peak-oil generation was reached during the Late Cretaceous to Miocene (65–21 Ma). The modeled hydrocarbon expulsion evolution suggests that the timing of oil expulsion from the Qishn source rock began during the Miocene (>21 Ma) and persisted to present-day. Therefore, the Qishn Formation can act as an effective oil-source but only limited quantities of oil can be expected to have been generated and expelled in the Jiza sub-basin.     

Comparative petroleum systems analysis of the interior basins of Turkey: Implications for petroleum potential

The interior basins of Turkey remain effectively unexplored and their petroleum systems are poorly understood. This paper presents a comparative summary of the geological evolution, petroleum potential and prospectivity of the Central (Tuz Gölü, Sivas and Çankırı) and East Anatolian (Muş-Hınıs, Pasinler-Horasan and Tercan-Aşkale) basins using geological, seismic, geochemical and petrophysical data, and a series of quantitative basin models. The studied basins are ranked on the basis of source effectiveness, reservoir quality, seal efficiency, and the timing of hydrocarbon expulsion and migration relative to trap formation. A qualitative risk assessment, based on the elements of the petroleum system, is used to evaluate the likelihood of hydrocarbon discovery in each of the basins. This study shows that the chance of hydrocarbon discovery in the East Anatolian basins is unlikely-very unlikely and Tuz Gölü, Sivas and Çankırı basins are equally likely/unlikely-unlikely, likely and unlikely, respectively. Heavy oil and minor gas associated with two mature petroleum systems were discovered in the Tuz Gölü basin. Various trap forming mechanisms such as salt tectonics and Middle Eocene compression, accompanied by the effective sealing capacity of the Eocene evaporites favor the hydrocarbon exploration potential of the Tuz Gölü basin. The highest exploration risk in the Tuz Gölü basin arises from the poor quality sandstone reservoirs. The biggest risk factor in the Eastern Anatolian basins is insufficient thermal maturity, despite the presence of good quality source rocks. The Sivas basin is one of the most promising interior basins of Turkey due to the presence of multiple mature petroleum systems and high quality reservoirs. There is a high chance of accumulation of multi-phase hydrocarbons in the Eocene and Miocene traps. The major problem in the Sivas basin is the lack of an efficient seal rock. The Çankırı basin contains all of the necessary elements of an ideal petroleum system except the presence of an organic-rich source rock. Thus, the chance of hydrocarbon discovery in the Çankırı basin is low.     

A basin modeling and organic geochemistry study in the Vallecitos syncline,San Joaquin Basin,California

The Vallecitos syncline is a westerly structural extension of the San Joaquin Basin. The Vallecitos oil field, comprised of eight separate areas that produce from Cretaceous and Paleogene reservoirs, accounted for 5.4 MMB of oil and 5.6 BCF associated of gas through 2010. However, exploration for oil and gas in the Vallecitos area is challenging due to structural complexity and limited data. The purpose of this study is to evaluate whether source rocks are actively generating petroleum in the Vallecitos syncline and to improve our understanding of burial history and timing of hydrocarbon generation. We conducted biomarker analysis on twenty-two oil samples from the Vallecitos syncline. Source-related biomarkers show two genetic groups of oil, which originated from two different source rocks. These results differ from earlier published interpretations in which the Kreyenhagen Formation is the only source rock in the Vallecitos syncline, and suggest that the Cretaceous Moreno Formation in the syncline also is an active source rock.Stratigraphic evidence and modeling suggest that late Cenozoic episodes of erosion due to folding and uplift removed significant overburden on the flanks of the syncline. To better understand the petroleum systems and clarify the total active source rocks in the area, 2D burial histories were generated through the Vallecitos syncline. A published cross-section through the deepest part of the syncline was selected to conduct thermal history, basin evolution, and migration analyses. The 2D model results indicate that the lower Kreyenhagen Formation has various maturities within the formation at different locations in the present-day syncline. The basal part of the Kreyenhagen Formation is in the dry gas window and maturity decreases away from the central part to the flanks. It remains immature along shallow portions of the present-day flanks. In contrast, the basal part of the Moreno Formation achieved extremely high maturity (past the gas generation zone) but is in the oil generation zone on the flanks of the syncline at shallow depth. All of our geochemical and 2D model results suggest that there are two active source rocks in the Vallecitos syncline. Accordingly, we propose that there are two active petroleum systems in the Vallecitos syncline.     

Petroleum retention in the Mandal Formation,Central Graben,Norway

Upper Jurassic organic matter-rich, marine shales of the Mandal Formation have charged major petroleum accumulations in the North Sea Central Graben including the giant Ekofisk field which straddles the graben axis. Recent exploration of marginal basin positions such as the Mandal High area or the Søgne Basin has been less successful, raising the question as to whether charging is an issue, possibly related to high thermal stability of the source organic matter or delayed expulsion from source to carrier.The Mandal Formation is in part a very prolific source rock containing mainly Type II organic matter with <12 wt.-% TOC and HI < 645 mg HC/g TOC but Type III-influenced organofacies are also present. The formation is therefore to varying degrees heterogeneous. Here we show, using geochemical mass balance modelling, that the petroleum expulsion efficiency of the Mandal Formation is relatively low as compared to the Upper Jurassic Draupne Formation, the major source rock in the Viking Graben system. Using maturity series of different initial source quality from structurally distinct regions and encompassing depositional environments from proximal to distal facies, we have examined the relationship between free hydrocarbon retention and organic matter structure. The aromaticity of the original and matured petroleum precursors in the Mandal source rock plays a major role in its gas retention capacity as cross-linked monoaromatic rings act on the outer surface of kerogen as sorptive sites. However, oil retention is a function of both kerogen and involatile bitumen compositions. Slight variations in total petroleum retention capacities within the same kerogen yields suggest that texture of organic matter (e.g. organic porosity) could play a role as well.     

Hydrocarbon charging and accumulation history in the Niudong Buried Hill Field in the Baxian Depression,eastern China

The Niudong Buried Hill Field, which lies in the Baxian Depression of the Bohai Bay Basin, is the deepest oil/gas accumulation in eastern China. Its Precambrian dolomite reservoir occurs at burial depths of 5860 m–6027 m. This paper attempts to document the hydrocarbon charging and accumulation history in this field, which could greatly enhance the understanding of the mechanisms for the formation of deep hydrocarbon accumulations. Our previous study of oil trapped in fluid inclusions has demonstrated that the ratio parameters of the fluorescence spectral intensities at 425 nm and 433 nm (Q_425/433 ratio), and at 419 nm and 429 nm (Q_419/429 ratio) can be more effective for revealing hydrocarbon charging history than the previously-used fluorescence parameters such as Lambda max and red/green quotient as well as fluorescence colors. The hydrocarbon charging and accumulation history in the Niudong Buried Hill Field was studied with an integrated approach involving the application of these two spectral parameters of petroleum inclusion fluorescence as well as utilization of other data including homogenization temperatures of aqueous inclusions coeval with petroleum inclusions, and cross-cutting relationships of cements and “oil veins” in pores and fractures. The results indicate that the dolomite reservoir in the Niudong Buried Hill Field experienced three episodes of hydrocarbon charging. In the first two episodes (between 38.5Ma and 25Ma), the low mature and mature oils, which were derived from source rocks in the Sha-4 Member of the Eocene Shahejie Formation, migrated into the reservoir, but part of them leaked out due to normal faulting at the updip margin of the buried hill. These early-charged oils were preserved mainly in small pores in micritic dolomites by oil-wettability and capillary pressure. In the Neogene, the basin subsided as a whole and local faults at the updip margin became inactive and played a sealing role. By approximately 13Ma, the source rocks became highly mature and the generated hydrocarbons then migrated into the reservoir and accumulated. Therefore, the last charging is the most important for hydrocarbon accumulation in the Niudong Buried Hill Field.     

Speculative petroleum systems of the southern Pelotas Basin,offshore Uruguay

The Pelotas Basin of Brazil and Uruguay represents a frontier basin with under-explored hydrocarbon potential. Although oil and gas accumulations have yet to be identified, only 21 exploratory wells have been drilled in an area of more than 330,000 km², 20 of which are located in the Brazilian portion of the basin. A detailed study of the petroleum system of offshore Uruguay has strong potential to contribute to a better characterization of the capacity of the basin to generate and accumulate hydrocarbons. Three stages have previously been recognized during the evolution of Pelotas basin: (1) a prerift phase which preserved Paleozoic and Mesozoic units of the Paraná Basin; (2) an Early Cretaceous volcano-sedimentary synrift phase; and (3) a Cretaceous to Cenozoic postrift phase deposited during the passive margin stage. In this study, we use sequence stratigraphy methodology to interpret 2D multichannel seismic sections of the southern segment of the Pelotas Basin in the Uruguayan Atlantic margin. This analysis allows us to identify depositional sequences, systems tracts and the distribution of the main elements of the potential petroleum systems. Following our analysis, we propose six speculative petroleum systems (SPS) in the Pelotas Basin. The first SPS is related to the prerift phase and is represented by a Lower Permian restricted marine source rock and reservoirs related to Permian to Upper Jurassic aeolian and fluvial sandstones. The second SPS corresponds to the synrift phase and is constituted by a Barremian lacustrine source rock with reservoirs of alluvial/fluvial sandstones of the same age. The other four proposed SPS are associated with the postrift phase, represented by marine source rocks related to Aptian-Albian, Cenomanian-Turonian and Paleocene transgressions, all of which are identified in the region and interpreted in seismic lines from Uruguay. These postrift SPS have predominantly siliciclastic reservoirs represented by Early Cretaceous aeolian sandstones and Cretaceous to Cenozoic deltaic sandstones and turbidites.     

Properties and shale oil potential of saline lacustrine shales in the Qianjiang Depression,Jianghan Basin,China

The geochemical and petrographic characteristics of saline lacustrine shales from the Qianjiang Formation, Jianghan Basin were investigated by organic geochemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and low pressure nitrogen adsorption analysis. The results indicate that: the saline lacustrine shales of Eq3 member with high oil content are characterized by type I and type II oil-prone kerogen, variable TOC contents (1.0–10.0 wt%) and an early-maturity stage (R_o ranges between 0.41 and 0.76%). The mineral compositions of Eq3 saline shale show strong heterogeneity: brittle intervals with high contents of quartz and carbonate are frequently alternated with ductile intervals with high glauberite and clay contents. This combination might be beneficial for oil accumulation, but may cause significant challenges for the hydraulic stimulation strategy and long-term production of shale oil. The interparticle pores and intraparticle pores dominate the pore system of Eq3 shale, and organic matter hosted pores are absent. Widely distributed fractures, especially tectonic fractures, might play a key role in hydrocarbon migration and accumulation. The pore network is contributed to by both large size inorganic pores and abundant micro-factures, leading to a relatively high porosity (2.8–30.6%) and permeability (0.045–6.27 md) within the saline shale reservoir, which could enhance the flow ability and storage capacity of oil. The oil content (S₁ × 100/TOC, mg HC/g TOC and S₁, mg HC/g rock) and brittleness data demonstrate that the Eq3^3x section has both great potential for being a producible oil resource and hydraulic fracturing. Considering the hydrocarbon generation efficiency and properties of oil, the mature shale of Eq3 in the subsidence center of the Qianjiang Depression would be the most favorable zone for shale oil exploitation.     

Shale gas accumulation potential of the Upper Cretaceous Qingshankou Formation in the southeast Songliao Basin,NE China

The purpose of this paper is to provide both quantitative and qualitative visual analyses of the nanometer-scale pore systems of immature and early shales, as well as to discuss the biogenic shale gas accumulation potential of the Upper Cretaceous section of the Songliao Basin. To achieve these goals, mineralogical compositions were determined using transmitted and reflected light petrography, X-ray diffractometry and scanning electron microscopy (SEM), while the nanostructure morphology and pore size distributions (PSDs) were quantified using field emission scanning electron microscopy (FE-SEM) and low-pressure nitrogen gas adsorption (LP-N₂GA). The results of these analyses indicate that nanometer-scale pores are well developed in the immature and low-maturity shale, and that these shales contain many types of reservoir pores. The mudstone layer of the Qingshankou Formation (K₂qn) contains a high permeability characteristic and good rock fracturing conditions, while it is also thick (>9 m in thickness) and rich in fine organic matter. Overall, analysis of the entire formation using source rock and reservoir evaluations indicate that the first member of the Qingshankou Formation (K₂qn₁) has a greater shale gas accumulation potential than the second and third members of the Qingshankou Formation (K₂qn_2-3).