Evolution of structurally contrasting anatectic migmatites in the 3-kbar Ballachulish aureole, Scotland

Abstract Anatectic migmatites of contrasting structural style are found adjacent to the contacts of the Ballachulish Igneous Complex, Argyllshire, Scotland. On the east flank, evidence for migmatization is largely restricted to the local development of millimetre-centimetre scale Kfs + Qtz-rich leucocratic segregations, which accompany fragmentation of brittle hornfels layers and ductile deformation of mm-cm scale semipelitic layers. Large volumes of semipelitic rock rich in feldspar and quartz on the east flank show no migmatitic features, and bedding is usually preserved undisturbed right up to the contact. On the west flank, in contrast, similar semipelitic rocks show widespread migmatitic features and disruption of layering is substantial and widespread over a 400 m wide zone. Within the west-flank migmatites, 1–100 cm scale rigid bedding fragments (schollen) may be suspended and disoriented in a semipelitic matrix that underwent ductile deformation. The P-T conditions on both flanks are in the same range: 3 kbar and 650–700°C. The contrast in gross structural style is believed to result from differences in the volumes of melt produced and differences in the proportion of rock in which the critical melt fraction of the rocks was exceeded. On the east flank, only on a mm-cm scale was enough melt locally accumulated to cause disruption of some layers and segregation of melt. On the west flank, melting proceeded substantially in a broad tract of semipelitic rocks, resulting in larger scale contrasts in rheology that led to the present chaotic structures in this zone. Because migmatization occurred at a pressure too low for muscovite dehydration melting, and at temperatures too low for substantial biotite dehydration melting, the different amounts of melting on the east and west flanks most probably resulted from the introduction of differing amounts of externally derived water. On the east flank, and throughout most of the aureole, the absence of melting even in quartzofeldspathic protoliths indicates that there was no substantial movement of fluid towards or away from the igneous complex during migmatization. The contrasting situation on the west flank may have resulted from devolatilization of underlying quartz diorite magma (? 690–710°C), which released heat and fluids into the overlying quartz- and feldspar-rich semipelites (solidus temperature ? 650–680°C).     

U—Pb Dating of Anatectic Migmatites in the Yunkai Block,Gaozhou,Western Guangdong

The regional migmatites in the Yunkai Block were formed under low-pressure metamorphism.The majority of their protolith are biotite-rich peraluminous gneisses.Detailed field observations,and studies of petrology,spatial distribution of minerals and geochemistry suggest that the leucosomes were derived from anatexis.The single grain zircon U-Pb dating data indicate that a pulse of migmatization occurred at 394-449 Ma and may have resulted from the large-scale Caledonian magmatism in the Yunkai Block.     

The evolution of trace element concentrations in basic rocks from Israel and their petrogenesis

The geochemistry of tholeiitic rocks, alkali olivine basalts and basanites of The Mesozoic province of Israel has been studied. The elemental concentration in the magmas was treated in terms of batch melting followed by fractional crystallization processes. During the latter process, the crystallizing minerals from effusive and hypabyssal bodies match the conditions of maintaining surface equilibrium with the melt (Rayleigh Law). According to the incompatible characteristics of the LIL elements which were determined, they can be divided into two groups: (1) those elements (La, Ce, Ta, Th, Hf) which maintain incompatibility for rocks having D.I. <63, and (2) those elements which can be regarded as incompatible in rocks with further restrictions for U and Ba (D.I.<50); for P₂O₅ (Ni>75 ppm); for Sr (Ni>200 ppm). Assuming that the mantle has [La] _n = 1 the spectrum of the rocks studied was generated by 0.5% to 3.2% partial melting from a single garnet peridotite source rock. The source rocks appear to be quite homogeneous with only a slightly LREE-enriched pattern. For the above melting range the D _s (bulk distribution coefficient between the source rocks and the melts) values for Ta, La, Ce, Th, U, P₂O₅, Sr, Ba, and Hf were found to be 0.0012, 0.002, 0.0029, 0.0031, 0.0039, 0.0082, 0.0083, 0.01, and 0.015, respectively. If the mantle has [La] _n =2, then for the range of 1 to 6.4% melting, the D _s values would be 0.002, 0.0035, 0.0053, 0.0055, 0.007, 0.0152, 0.0153, 0.019, and 0.027, respectively.     

粤西云开地块内高州地区深熔混合岩的锆石U-Pb年龄

云开地块区域混合岩是在低压变质作用基础上形成的。多数古成体原岩是富黑云母的过铝质片麻岩。混合岩野外特征、岩石学、矿物空间分布和地球化学综合研究均表明,该区浅色体是深熔成因的。单颗粒锆石定年结果表明,混合岩形成于加里东期,其时代为３９４ ～４４９Ｍａ,这期混合岩化作用可能与云开地块大规模的加里东期岩浆活动有关。     

海南岛印支-燕山期花岗岩年代学格架与成因

海南岛分布着大面积的印支-燕山期岩浆岩, 是华南岩浆活动的重要组成部分。近年来, 对这些花岗岩已开展了一系列工作, 但其年代学格架仍需完善, 成因类型及源区性质仍需限定, 区域构造机制仍存在争议。本文详细梳理了已发表的海南岛晚古生代-中生代花岗岩地球化学和年代学数据, 结合作者近年来的相关工作, 对海南岛花岗岩的年代学格架和岩石地球化学特征进行总结, 并对源岩、岩浆演化过程和地球动力学背景进行讨论。海南岛印支期(二叠纪-三叠纪)花岗岩(部分具有片麻状构造)整体以NE走向展布, 形成于278~225Ma, 峰期为240Ma。岩相学和地球化学研究表明, 此期岩浆活动形成了具有不同地球化学特征的S型、I型和A型花岗岩。其中, S型花岗岩(278~241Ma)与I型花岗岩(272~233Ma)均为高钾钙碱性花岗岩, 具有较低的全岩锆饱和温度(平均 < 750℃), 低于大规模角闪石分解引起的脱水熔融所需的温度, 可能是由底侵玄武质岩浆释放的水加入到下地壳诱发部分熔融的产物; A型花岗岩(257~225Ma)的全岩锆饱和温度较高(>800℃), 表明源区无流体加入或为已有花岗岩生成的去水源岩在高温条件下脱水熔融形成。此外, 本区还存在少量燕山期花岗岩, 包括燕山早期(侏罗纪)岩浆活动(如本研究识别出的161Ma高钾钙碱性I型花岗岩)以及集中在白垩纪的三期侏罗纪-白垩纪岩浆活动(按年龄可分为: ca.120Ma、ca.110~90Ma和ca.70Ma, 峰期为ca.100Ma)。地球化学数据表明燕山期花岗岩具有高钾钙碱性I型特征, 源区中有幔源年轻组分的加入。据此, 本文作者认为: (1)印支-燕山期大规模的花岗岩浆作用与古太平洋板块向华南大陆俯冲有关; (2)古太平洋板块向华南大陆的俯冲可能起始于早-中二叠世(ca. 280Ma), 结束于晚白垩世末期(ca. 70Ma); (3)自二叠纪起至白垩纪末期安第斯型活动大陆边缘结束, 海南岛保存了古太平洋俯冲相关的岩浆活动记录。

     

广西花山-姑婆山燕山期花岗岩的地球化学特征及成因研究

广西花山-姑婆山燕山期花岗岩体以高硅、高钾、富碱、低磷、准铝质为特征，具有较高的TFeO/MgO值，富集大离子亲石元素、高场强元素和稀土元素，普遍出现褐帘石，应归属于富钾的钙碱性花岗岩（KCG）系列岩石，相当于高钾钙碱性I型花岗岩。产生于后造山陆内挤压向拉张转换的地球动力学背景下，其形成与岩石圈伸展-减薄、亏损地幔岩浆的上涌和富含金云母-钾质碱镁闪石的岩石圈地幔的部分熔融有关。     

Trace element compositions of submicroscopic inclusions in coated diamond: A tool for understanding diamond petrogenesis

Trace element compositions of submicroscopic inclusions in both the core and the coat of five coated diamonds from the Democratic Republic of Congo (DRC, formerly Zaire) have been analyzed by Laser Ablation Inductively Coupled Mass Plasma Spectrometry (LA-ICP-MS). Both the diamond core and coat inclusions show a general 2-4-fold enrichment in incompatible elements relative to major elements. This level of enrichment is unlikely to be explained by the entrapment of silicate mantle minerals (olivine, garnet, clinopyroxene, phlogopite) alone and thus submicroscopic fluid or glass inclusions are inferred in both the diamond coat and in the gem quality diamond core. The diamond core fluids have elevated High Field Strength Element (Ti, Ta, Zr, Nb) concentrations and are enriched in U relative to inclusions in the diamond coats and relative to chondrite. The core fluids are also moderately enriched in LILE (Ba, Sr, K). Therefore, we suggest that the diamond cores contain inclusions of silicate melt. However, the Ni content and Ni/Fe ratio of the trapped fluid are very high for a silicate melt in equilibrium with mantle minerals; high Ni and Co concentrations in the diamond cores are attributed to the presence of a sulfide phase coexisting with silicate melt in the diamond core inclusions. Inclusions in the diamond coat are enriched in LILE (U, Ba, Sr, K) and La over the diamond core fluids and to chondrite. The coats have incompatible element ratios similar to natural carbonatite (coat fluid: Na/Ba ≈0.66, La/Ta≈130). The coat fluid is also moderately enriched in HFSE (Ta, Nb, Zr) when normalized to chondritic Al. LILE and La enrichment is related to the presence of a carbonatitic fluid in the diamond coat inclusions, which is mixed with a HFSE-rich hydrous silicate fluid similar to that in the core. The composition of the coat fluid is consistent with a genetic link to group 1 kimberlite.     

张广才岭北部苇河花岗岩基的地球化学特征与岩石成因

张广才岭北部苇河花岗岩基的地质学、岩相学、全岩主量和微量及锆石Hf 同位素的详细解析显示: 苇河花岗岩基主体岩性为花岗闪长岩、二长花岗岩、正长--碱长花岗岩及少量的石英闪长岩和英云闪长岩,不同岩石类型之间呈侵入接触关系。岩石富硅富铝,为准铝质--弱过铝质岩石( A/CNK = 0. 97 ～ 1. 03) ,全碱( K₂O + Na₂O) 含量为6. 56% ～ 9. 10%,主要为高钾钙碱性系列I 型花岗岩。稀土和微量元素组成上,均富集LREE、Rb、Th、U、K、Hf,相对亏损Nb、Ta、P、Ti,δEu 从中等程度负异常到弱正异常。不均匀的锆石Hf 同位素成分( εHf ( t) = ( － 6. 68 ～ + 12. 13) ,TDM2 = 464 ～ 1 657 Ma) 表明,岩浆主体来源于显生宙--新元古代时期从亏损地幔中增生的基性下地壳物质,局部同化了更古老的地壳物质。     

Volatile control of contrasting trace element distributions in peralkaline granitic and volcanic rocks

Anomalous enrichments of Zr (>500 ppm), Zn (> 100 ppm), Nb (>25 ppm), Y (>60 ppm), Th (>20 pm), U (> 5 ppm), LREE (>230 ppm) and HREE (>35ppm), and high Rb/Sr (>5) characterize peralkaline granites, in contrast to their peraluminous and calc-alkaline equivalents. Within the peralkaline suite, comenditic and pantelleritic volcanics exhibit two- to five-fold increases in the concentrations of these trace elements over comagmatic granites. These cannot be explained by crystal- liquid fractionation processes, and require the evolution of a sodium-enriched fluid. Corresponding trace element increases in the granites in areas of alkali metasomatism support this argument, and reflect the partial confinement of this volatile phase within the high-level magma chambers. REE studies in particular might eventually allow an evaluation of the role of Cl⁻ versus F⁻ and CO₃-complexing in the evolution of the volatile fluid.     

延边天佛指山花岗岩的形成时代及成因

延边天佛指山花岗岩年代学和地球化学研究表明,花岗岩中的锆石U-Pb年龄为(188.5±2.2)Ma,其侵位时间为早侏罗世。岩石总体上具有高硅、低铝、贫钙镁及富碱的特征,属高钾钙碱性系列I型花岗岩;富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、Th、U、K等,相对亏损高场强元素(HFSE)Zr、Hf、Y、Yb等,显著亏损Ba、Nb、Ta、P、Ti等元素,δEu呈轻微程度负异常。该花岗岩岩浆源于地壳物质的部分熔融,可能形成于与古太平洋板块俯冲相关联的活动大陆边缘环境。     

粤西大金山花岗岩体地球化学特征及岩石成因探讨

大金山花岗岩体是一个与广东省大金山钨锡多金属矿床有关的隐伏岩体,岩性主要由中细粒黑云母花岗岩和似斑状黑云母花岗岩组成。大金山花岗岩体具有高硅、富碱、贫镁钙、准铝质的特点,属于高钾钙碱性系列;微量元素以富集Rb、Th、U而亏损Nb、Eu、Ti为特征;稀土元素含量较高,中细粒黑云母花岗岩和似斑状黑云母花岗岩稀土元素含量分别为203.36×10-6-248.42×10-6、243.76×10-6-255.08×10-6,似斑状黑云母花岗岩稀土元素含量略高,中细粒黑云母花岗岩略富集重稀土而似斑状黑云母花岗岩则富集轻稀土;两者均具有强烈的Eu负异常,δEu值分别为0.004-0.009、0.059-0.13。中细粒黑云母花岗岩和似斑状黑云母花岗岩的εHf(t)值分别为-2.05--8.64、-0.92--6.57;两阶段Hf模式年龄(tDM2)分别为1 277-1 692 Ma和1 204-1 556 Ma。综合区域地质背景和大金山花岗岩体的地球化学特征,认为大金山花岗岩体形成于地壳拉张-伸展的构造背景下,是中元古代地壳部分熔融的产物。     

The major and trace element chemistry of kaersutite and its bearing on the petrogenesis of alkaline rocks

New major and trace element analyses are presented for 7 kaersutites from basic alkaline rocks. K/Rb ratios lie between 1209 and 4276. Rb is low, averaging 6 ppm. Sr ranges from 532 to 1060 ppm and Ba from 181 to 701 ppm. Zr averages 109 ppm, Nb 44 ppm and V 390 ppm. There is a moderate enrichment in light REE. Zn correlates with FeO + Fe₂O₃ but the concentrations of Ni, Co, Cr, Cu and Pb are variable. Large variations in trace element concentration in kaersutites reflect only small variations in the melt when the distribution coefficient for a given element strongly favours the amphibole.Kaersutite is significant in the petrogenesis of alkaline rocks as a possible accessory phase in the upper mantle source regions, and as an important phase in the fractionation of basic alkaline liquids over a wide range of pressures.     

北京房山岩体锆石U-Pb年龄和Sr、Nd、Pb同位素与微量元素特征及成因探讨

本文首次用SHRIMP锆石U-Pb测年法获得房山岩体主期侵入岩-花岗闪长岩的年龄为130．7±1．4Ma,证明房山岩体主体岩石形成于早白垩世。综合该岩体两期侵入宕的常量、微量、稀土元素和同位素及构造环境特征,发现房山岩体侵入岩具有许多与埃达克岩(adakite)极其相似的独特的岩石地球化学特征,但又与Defant和Drummond(1990)定义的典型埃达克岩(O型)有明显差别,与中国东部C型埃达克岩更为接近,或也称之为中国东部燕山期高Sr低Y型中酸性火成岩。本文通过房山岩体Sr、Nd、Pb同位素的系统研究,发现在143Nd／144Nd-87Sr／86Sr图解上,两期岩石投影点均落在EM Ⅰ型富集地幔范围之内,暗示其物质来源与富集地幔有关;钾长石Pb同位素特征也说明房山岩体岩浆来源与EM Ⅰ型富集地幔和下地壳关系密切。结合前人的碳、氢、氧同位素研究成果,认为房山岩体物质来源较深,与上地幔和下地壳有关。此外,发现房山岩体两期侵入岩的εNd(t)值(-13．6--14．2)远高于华北地台区古老下地壳的εNd(t)值(-32--44),而与汉诺坝二辉麻粒岩包体的εNd(t)值(-8--18)近似。由于现有的研究已确证汉诺坝二辉麻粒岩包体是由幔源基性岩浆在晚古生代-中生代时底侵到下地壳底部构成的年青下地壳的一部分,故推测房山岩体的物质来源与华北地台古老下地壳关系不大,而可能与年青下地壳关系密切。在此基础上,提出房山岩体两期岩石形成的两阶段模式:第一阶段可能发生于中生代早期,由于软流体 (层)上涌导致富集岩石圈地幔部分熔融生成带有富集地幔印记的玄武岩浆,该岩浆底侵到下地壳底部,冷却成为年青下地壳的一部分;第二阶段发生于中生代晚期,由于当时软流圈呈蘑菇云状大规模上升,热侵蚀面抬升到壳-幔过渡带,导致早中生代新底侵的玄武质下地壳在榴辉岩-麻粒岩相条件下部分熔融生成C型埃达克质岩浆(也即高Sr低Y型中酸性火成岩浆) 并上侵而成为房山岩体。     

The trace element compositions of S-type granites: evidence for disequilibrium melting and accessory phase entrainment in the source

Within individual plutons, the trace element concentrations in S-type granites generally increase with maficity (total iron and magnesium content and expressed as atomic Fe + Mg in this study); the degree of variability in trace element concentration also expands markedly with the same parameter. The strongly peraluminous, high-level S-type granites of the Peninsular Pluton (Cape Granite Suite, South Africa) are the product of biotite incongruent melting of a metasedimentary source near the base of the crust. Leucogranites within the suite represent close to pure melts from the anatectic source and more mafic varieties represent mixtures of melt and peritectic garnet and ilmenite. Trace elements such as Rb, Ba, Sr and Eu, that are concentrated in reactant minerals in the melting process, show considerable scatter within the granites. This is interpreted to reflect compositional variation in the source. In contrast, elements such as LREE, Zr and Hf, which are concentrated within refractory accessory phases (zircon and monazite), show well-defined negative correlations with increasing SiO₂ and increase linearly with increasing maficity. This is interpreted to reflect coupled co-entrainment of accessory minerals and peritectic phases to the melt: leucocratic rocks cannot have evolved from the more mafic compositions in the suite by a process of fractional crystallisation because in this case they would have inherited the zircon-saturated character of this hypothetical earlier magma. Trace element behaviour of granites from the Peninsular Pluton has been modelled via both equilibrium and disequilibrium trace element melting. In the disequilibrium case, melts are modelled as leaving the source with variable proportions of entrained peritectic phases and accessory minerals, but before the melt has dissolved any accessory minerals. Thus, the trace element signature of the melt is largely inherited from the reactants in the melting reaction, with no contribution from zircon and monazite dissolution. In the equilibrium case, melt leaves the source with entrained crystals, after reaching zircon and monazite saturation. A significant proportion of the rocks of the Peninsular Pluton have trace element concentrations below those predicted by zircon and monazite saturation. In the case of the most leucocratic rocks all compositions are zircon undersaturated; whilst the majority of the most mafic compositions are zircon oversaturated. However, in both cases, zircon is commonly xenocrystic. Thus, the leucocratic rocks represent close to pure melts, which escaped their sources rapidly enough that some very closely match the trace element disequilibrium melting model applied in this study. Zircon dissolution rates allow the residency time for the melt in the source to be conservatively estimated at less than 500 years.     

Isotopic and trace element constraints on the petrogenesis of lavas from the Mount Adams volcanic field,Washington

Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources, a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators of slab-fluids such as (Sr/P) _n and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. δ ¹⁸O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal interaction in this juvenile arc, in stark contrast to Os isotopes, which are highly sensitive to interaction with young, mafic material in the lower crust.     

Boninites as windows into trace element mobility in subduction zones

Boninites are subduction-related rocks originating from re-melting of highly depleted mantle sources left after extraction of tholeiitic melts. Due to their depleted nature, the incompatible trace element inventory of boninites is virtually entirely inherited from slab components without a significant contribution from the refractory mantle wedge. Thus, boninites constitute an excellent window into processes controlling trace element mobilization at the slab-mantle wedge interface. In order to constrain the behaviour of trace elements in subduction zones with a special emphasis on high field strength elements, we analyzed low-Ca boninites and associated tholeiitic basalts from Cape Vogel, Papua New Guinea (PNG) and compare them with compositions of high-Ca boninites and associated tholeiitic basalts from Cyprus. High-precision HFSE (Nb, Ta, Zr, Hf, W) concentration data of the boninites and associated tholeiitic basalts were obtained by isotope dilution. Major, trace element, and Sr-Nd-Hf-Pb isotope compositions clearly document a significant contribution of slab-derived melts involved in the petrogenesis of the PNG boninites, whereas only fluid-like subduction components were involved in the petrogenesis of the PNG basalts and the Cyprus suite. Low-Ca boninites from PNG are derived from a more refractory mantle source (∼21% depletion) than the high-Ca boninites from Cyprus (∼11% depletion) and their respective tholeiitic precursors (<10% depletion). In agreement with the more depleted nature of their mantle source, boninites exhibit a significantly stronger overprint by slab components. High-precision HFSE data indicate that, in comparison to LILE, a somewhat lower but measurable mobilization of all investigated HFSE in both slab-derived fluids and melts is evident. Modelling calculations demonstrate that the subduction components dominate the LILE budget and also largely control LREE and HFSE abundances in the boninite sources. Notably, the increasing influence of slab-derived fluids results in a decrease of the negative Nb-Ta anomaly, most likely reflecting a similar mobility of Nb-Ta and LREE at higher pressures near the critical point of fluid-melt miscibility. Ratios of Zr/Hf and Nb/Ta in the melt-like slab components dominating in the sources of the PNG boninites were probably fractionated in equilibrium with garnet-amphibolitic mafic oceanic crust. HFSE ratios in the Cyprus boninites are best explained by dehydration of subducted pelagic sediments in the absence of Ti-rich phases such as rutile. Our results also confirm previous assertions that the mobility of HFSE decreases in the order Sb > W-Mo > Nb-Ta > Zr-Hf. Furthermore, Mo-W systematics may provide a potential novel tracer for the amount, composition and redox state of subducted pelagic sediments that contribute to the geochemical budget of intra-oceanic arc systems.     

Partial melting in the Inzie Head gneisses: the role of water and a petrogenetic grid in KFMASH applicable to anatectic pelitic migmatites

A sequence of prograde isograds is recognized within the Dalradian Inzie Head gneisses where pelitic compositions have undergone variable degrees of partial melting via incongruent melting reactions consuming biotite. Three leucosome types are identified. At the lowest grades, granitic leucosomes containing porphyroblasts of cordierite (CRD‐melt) are abundant. At intermediate grades, CRD‐melt mingles with garnetiferous leucosomes (GT‐melt). At the highest grades, CRD‐melt coexists with orthopyroxene‐bearing leucosomes (OPX‐melt), while garnet is conspicuously absent. The prograde metamorphic field gradient is constrained to pressures of 2–3 kbar below the CRD‐melt isograd, and no greater than 4.5 kbar at the highest grade around Inzie Head. A petrogenetic grid, calculated using thermocalc , is presented for the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) system for the phases orthopyroxene, garnet, cordierite, biotite, sillimanite, H₂O and melt with quartz and K‐feldspar in excess. For the implied field gradient, the reaction sequence predicted by the grid is consistent with the successive prograde development of each leucosome type. Compatibility diagrams suggest that, as anatexis proceeded, bulk compositions may have been displaced towards higher MgO content by the removal of (relatively) ferroan granitic leucosome. An isobaric (P = 4 kbar) T–a_H2O diagram shows that premigmatization fluids must have been water‐rich (a_H2O > 0.85) and suggests that, following the formation of small volumes of CRD‐melt, the system became fluid‐absent and melting reactions buffered a_H2O to lower values as temperatures rose. GT‐ and OPX‐melt formed by fluid‐absent melting reactions, but a maximum of 7–11% CRD‐melt fraction can be generated under fluid‐absent conditions, much less than the large volumes observed in the field. There is strong evidence that the CRD‐melt leucosomes could not have been derived by buoyantly aided upwards migration from levels beneath the migmatites. Their formation therefore required a significant influx of H₂O‐rich fluid, but in a quantity insufficient to have exhausted the buffering capacity of the solid assemblage plus melt. Fluid : rock ratios cannot have exceeded 1 : 30. The fluid was channelled through a regionally extensive shear zone network following melt‐induced failure. Such an influx of fluid at such depths has obvious consequences for localized crustal magma production and possibly for cordierite‐bearing granitoids in general.     

黑龙江宝山一带海西晚期强过铝花岗岩地质地球化学及岩石成因

黑龙江宝山地区在构造上位于兴蒙造山带东部的松嫩地块和佳木斯地块之间的伊春-延寿花岗岩带北段,区内分布大面积的古生代-中生代花岗岩.其中海西晚期花岗岩,岩性主要为碱长花岗岩、二长花岗岩和花岗闪长岩等,锆石U-Pb法 LA-ICP MS测年结果为252.6±3 Ma.其主量元素表现出富Si、略富Al、富碱质和低Mg、低Ca的特点;微量元素表现出富集Rb、Nd、K、Pb、U和亏损Nb、Ta、P、Ti等高场强元素的特点,并且Sr、Ba呈明显的负异常;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,轻重稀土元素分馏程度较高.岩石总体上属于高钾钙碱性花岗岩,是岩浆经历了高度结晶分异作用的产物.矿物化学和岩石地球化学特征表明其特征类似于S型花岗岩,源岩物质来自于地壳.