Nitrate in the atmospheric boundary layer of the tropical South Pacific: Implications regarding sources and transport

Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m^–3 at each of these stations: 0.107±0.011 g m^–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m^–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m^–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of ²¹⁰Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with ⁷Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m^–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.     

Measurements of solar radiation and estimation of optical depth in the high Andes of Peru

Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (_wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (_ray) and ozone (_oz) optical depths were obtained from published tabulations. Subtracting _ray, _oz, and _wv from yielded estimates of aerosol optical depth _aer. The components _ray and _oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; _aer also decreases towards the higher elevations. Particularly pronounced is the decrease of _aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures     

Scavenging Efficiency of ‘Aerosol Carbon’ and Sulfate in Supercooled Clouds at Mt. Sonnblick (3106 m a.s.l., Austria)

Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (_SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (_AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both _SO and _AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, _SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m³. In the case of aerosol carbon, we obtained a more gradual increase of _AC up to an LWC of 0.5 g/m³. At higher LWCs, _{_} remained relatively constant at 0.60. As the differences between _SO and _A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.     

Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2

The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O₂ of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O₂ versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(H_{decomposition}–H_{O 2 reaction}), between these two reactions pathways. For (H)[22–0.5(H_{O 2 reaction})], alkoxy radical decomposition dominates over the reaction with O₂ at room temperature and atmospheric pressure of air, while for (H)[25-0.5(H_{O 2 reaction})], the O₂ reaction dominates over decomposition (where the units of H are in kcal mol^–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.     

On the mean monthly equivalent potential temperature and rainfall in West Africa

Summary Rainfall in West Africa is examined in relation to monthly mean equivalent potential temperature ( _e )at the earth's surface. The study revealed that monthly mean equivalent potential temperature ( _e ) and monthly rainfall (R) generally decreased northwards from the equator.A good relationship existed betweenR and _e in the northern zone of West Africa (i.e., north of 7.5° N). No definite relationship existed in the southern zone. In the northern zone, the departure of _e from its annual mean ( ) first became positive about a month before the onset of the rains. Positive departures from ) generally resulted in more than normal (or average) rainfall in this zone. In general, little or no rainfall occurred in West Africa whenever _e was less than 320 K.

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Zusammenfassung Der Niederschlag (MonatssummeR) in Westafrika wird in Zusammenhang mit der mittleren monatlichen Äquivalent-temperatur ( _e ) an der Erdoberfläche untersucht. Es zeigte sich, daß die Monatswerte beider Elemente im allgemeinen vom Äquator nach Norden abnehmen.ZwischenR und _e ergab sich für das nördliche Westafrika (nördlich von 7.5° N) eine gute, für die südliche Zone jedoch keine beweisbare Übereinstimmung. In der nördlichen Zone übertraf _e das Jahresmittel erstmals etwa einen Monat vor Beginn der Regenzeit. Positive Abweichungen vom mittleren _e hatten immer übernormalen Niederschlag in dieser Zone zur Folge. Dagegen gab es wenig oder keinen Niederschlag in Westafrika, wenn _e unter 320 K lag.

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With 7 Figures     

Observed variations of σθ and σΦ in the nocturnal drainage flow in a deep valley

The variations of and in the drainage flow in the Brush Creek valley of western Colorado are investigated using data from Doppler acoustic sodars and instrumented towers. The data were obtained on two experimental nights during the 1984 ASCOT field study. There is good agreement between the variations derived from low-level observations of the sodars and those derived from the towers located throughout the valley. The observed hourly average and in the nocturnal drainage flow are about 20 ° to 25 ° and 5 °, respectively; these values are much larger than those generally observed over flat terrain during nighttime stable conditions. After sunrise (about 0600 MST), as the valley warms and the flow direction changes to up-valley, these parameters increase sharply to their peak values at about 0800 MST and then decrease to their normal daytime values after about two hours.In the drainage flow, the hourly average varies inversely with wind speed according to the relation u 0.7ms^-1. The vertical standard deviation is much less enhanced by complex terrain than the horizontal standard deviation. The observed values are predicted fairly well by the local similarity theory.Oak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 andOak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 and     

Théorie des oscillations annuelles et diurnes de la température à la surface des continents et des océans

Résumé On détermine analytiquement les températures absoluesT (z, t) etT (z, t) dans l'air et dans le substrat terrestre, au voisinage de la surface de séparation de ces milieux, sous la condition que le rayonnement global varie dans le temps selon une fonction périodique simple ou quelconque. A cette fin, on s'attache à résoudre le système des deux équations de la chaleur dans l'air et dans le substrat terrestre en tenant compte de toutes les conditions physiques déterminantes du problème. Celles-ci interviennent dans l'équation énergétique aux limites pour le plan de séparationz=0. Un minimum d'hypothèses simplificatrices confère une plus haute valeur pratique aux résultats. Leur limitation principale réside dans le fait que les diffusivités turbulentesK etK _w de l'air et de l'Océan sont supposées constantes. On retrouve le résultat classique selon lequel l'onde thermique est déphasée sur le rayonnement global et jouit d'une amplitude proportionnelle à celle de ce rayonnement. Toutefois, l'amortissement thermique et le déphasage dépendent cette fois de la somme + des «propriétés thermiques» du substrat et de l'air, et étant alternativement dominant selon qu'il s'agit des Continents ou des Océans. Dans ce dernier cas, la théorie des oscillations thermiques est traitée d'abord en admettant l'existence d'une couche d'eau isothermique. On établit ensuite la théorie plus réaliste qui considère à la fois la diffusivité thermique turbulenteK _w et le coefficient d'extinctionq du rayonnement global dans l'Océan. Le point de départ de la théorie est l'équation de la chaleur dans un milieu semi-transparent. Les résultats montrent que l'onde thermique de surface subit un amortissement complémentaire dû au facteurq, le déphasage sur le rayonnement global pouvant atteindre 91 jours alors que cette limite n'est que de 45 jours pour les Continents. La discussion des résultats théoriques montre leur bon accord quantitatif avec les faits observés. On termine par quelques applications de la théorie; on montre notamment que celle-ci valide rationnellement la théorie astronomique des phases climatiques quaternaires.

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Summary Absolute temperaturesT (z, t) andT (z, t) near the interface of air and terrestrial substratum are analytically determined, under the condition that the total radiation varies with time according to a simple or to any other periodic function. To achieve this, the system of two equations of heat in air and terrestrial substratum is resolved in taking into account all the determining physical conditions of the problem. These conditions are considered in the energy boundary equation for the surface of separationz=0. A minimum number of simplifying hypotheses give a higher practical value to the results whose principal limitation lies in the fact that eddy conductivitiesK andK _w of air and ocean water are supposed to be constant. The classical result that the thermal wave differs in phase from the total radiation and gives an amplitude proportional to that radiation is confirmed. However, the thermal damping and the lag in phase depend here of the sum + of the thermal properties of the substratum and the air, and being preponderant for continents and oceans respectively. In the last case, the theory of thermal oscillations is first studied with the aid of the hypothesis of an isothermal water layer. Then a more realistic theory is established which considers in addition the eddy diffusivityK _w and the extinction coefficientq of the total radiation in the ocean. The basis of the theory is the heat equation for a semi-transparent medium. The results show that the surface thermal wave suffers a further damping due toq. In addition, the maximum temperature may lag behind the maximum radiation by as much as 91 days as against a maximum of 45 days for the continents. The discussion of the theoretical results shows their good quantitative agreement with the observations. Some practical applications of the theory are given. For example the validity of the astronomical theory of the climatic changes during the Quaternary period is rationally justified.

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Zusammenfassung Die absoluten TemperatureT (z, t) undT (z, t) von Luft und terrestrischer Unterlage in der Nähe der Trennschicht der beiden Medien werden analytisch bestimmt mit der Bedingung, daß die Globalstrahlung nach einer einfachen oder einer beliebigen periodischen Funktion mit der Zeit variiert. Zu diesem Zweck wird versucht, under Berücksichtigung aller bestimmenden physikalischen Bedingungen des Problems das System der beiden Wärmegleichungen für Luft und für das terrestrische Substrat zu lösen. Diese gehen in der Energiegleichung für die Grenzbédingungen der Trennflächez=0 ineinander über. Ein Minimum an vereinfachenden Hypothesen erhöht den praktischen Wert der Resultate; die Annahme der Konstanz des AustauschkoeffizientenA=K undA _w = _w A _w der Luft und des Ozeans bildet die wichtigste Einschränkung. Das klassische Resultat, nach dem die Wärmewelle zur Globalstrahlung in Phase verschoben und ihre Amplitude proportional zur Strahlungsamplitude ist, wird bestätigt. Die Abschwächung der thermischen Amplitude sowie die Phasenverschiebung hängen aber von der Summe + der thermischen Eigenschaften der Unterlage und der Luft ab; wobei oder überwiegt, je nachdem es sich um die Kontinente oder die Ozeane handelt. Für den letzteren Fall Wird die Theorie der Wärmeschwankungen zuerst unter der Annahme der Existenz einer isothermen Wasserschicht behandelt. Hernach wird die allgemeiner gültige Theorie entwickelt, welche gleichzeitig den TurbulenzaustauschA _w und den Extinktionskoeffizientenq der Globalstrahlung im Ozean in Betracht zieht. Den Ausgangspunkt für die Theorie bildet die Wärmegleichung für ein Strahlungsdurchlässiges Medium. Die Resultate zeigen, daß die Oberflächenwärmewelle eine Abschwächung entsprechend dem Faktorq erfährt; dabei kann die Phasenverschiebung gegenüber der Globalstrahlung 91 Tage erreichen, während die maximale Verschiebung für die Kontinente nur 45 Tage beträgt. Die Vergleichung der theoretischen Resultate ergibt deren gute quantitative Übereinstimmung mit den Beobachtungstatsachen. Zum Schluß werden einige Anwendungen der Theorie gebracht; so wird z. B. gezeigt, daß diese eine sinngemäße Rechtfertigung der Gültigkeit der astronomischen Theorie der quaternären klimatischen Phasen gestattet.

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Institut belge pour l'Encouragement de la Recherche Scientifique Outre-Mer (IBERSOM), 3, rue Montoyer, Bruxelles, Belgique.     

The effects of orography on precipitation

In this paper, a model simulating the effects of topography and altitude on precipitation is presented. Topography has its maximum effect on precipitation when the angle which the wind makes with the slope direction approaches zero and the inclination of the slope is near 45°. The smaller the angle , the greater the influence of slope on precipitation. When <45°, the larger the inclination, the greater the influence of slope on precipitation and the less the difference in precipitation between the windward and the leeward slopes. When <45°, the reverse holds. But for in the range of 0°–45° and in the range 30°–60°, differences in precipitation on both the windward and leeward slopes are not so well marked and can be neglected in general. In condition of uniform slope inclination, precipitation on the windward slope increases with altitude at first and then decreases after attaining a height (H _m ) of maximum precipitation; alsoH _m is greater, the drier the air mass. When the terrain on the windward side is stepped in shape, it is possible that more than one height of maximum precipitation will occur.     

Diurnal variation of horizontal wind direction fluctuations in complex terrain at Geysers,Cal.

Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km² Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s^-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.     

The von Kármán constant determined by large eddy simulation

The present study explores the extent to which the logarithmic region of the adiabatic atmospheric boundary layer can be modeled using a three-dimensional large eddy simulation. A value of the von Kármán constant (_LES) is obtained by determining the slope of a logarithmic portion of the velocity profile. Its numerical value is found to be dependent on the value of the Smagorinsky-Model Reynolds number, Re_SM: the value of _LES increases with Re_SM. Results indicate that _LES approaches a value of 0.35 as Re_SM reaches about 7.75 × 10⁵ for the largest domain. The sensitivity of _LES to the profile region over which it is evaluated has been tested. Results show that _LES is not sensitive to the depth of this evaluation region when we employ five grids above the sub-grid buffer layer where sub-grid-scale effects dominate. The maximum _LES is obtained when the lower boundary of the evaluation region is just above the top of the sub-grid-scale buffer layer. This result is consistent with modelled mean speed and resolved-scale shear stress profiles.     

An improved calibration for tethered balloon wind measurements

A previously published technique for using tethered spherical balloons as anemometers for measuring light low-level winds has been further developed. Earlier data on the relationship between the aerodynamic drag coefficient and the Reynolds number of spherical rubber balloons were combined with a large number of new data and re-analysed; and the errors in the relationship were estimated. The results allowed a more accurate calculation of wind speed from the deflection of a tethered balloon from the vertical. When combined with a new technique for calculating the effects of the tether, this enabled light to moderate low-level winds at fixed heights up to 600 m or more to be measured with simple, cheap, and readily mobile equipment; and a slight modification of the technique allowed measurement of winds in and above fog. Wind speeds measured by the ballon technique showed reasonably good agreement with measurements by an anemometer carried beneath the balloon.Glossary of Symbols a, b, c Coefficients in the relationship between lnC _d and lnR - A Quantity under square root in solution for lnV whena0 - C _d Wind drag coefficient for balloon - C _dc Value ofC _d given by calibration curve of Table I - D Dynamic wind pressure force on balloon - F Buoyant free lift of balloon with load - Re Reynold's number of balloon (sphere) - R = Re/10⁵ - r Radius of sphere - T Tension in tether - V Wind speed - ₈₃() =(lnC _dc -lnC _d ) when 83° , or 0 for other - Error in lnC _d - Elevation of tether where attached to balloon - Elevation of balloon from ground tether point - Molecular viscosity of air - Ratio of circumference to diameter of circle - Density of air     

The use of σ T as a temperature scale in the atmospheric surface layer

The standard deviation of temperature _T is proposed as a temperature scale and as a velocity scale to describe the behaviour of turbulent flows in the Atmospheric Surface Layer (ASL), instead of _* andu _* of the Monin—Obukhov similarity theory, and ofT _f andU _f used for free convection stability conditions. On the basis of experimental evidence reported in the literature, it is shown that _T T _f andv _* U _f in the free convection region, and _{T *} andv _* U _* in nearneutral and stable conditions. This implies that the proposed scales can be applied for all stabilities. Furthermore, a new length scale is proposed and its relation with Obukhov length is given. Also, a simple semi-empirical expression is presented with which _T andv _* can be evaluated in a rather simple way. Some examples of practical applications are given, e.g., a stability classification for unstable conditions.     

On the Response of the Greenland Ice Sheet to Greenhouse Climate Change

Numerical computations are performed with the three-dimensional polythermal ice-sheet model SICOPOLIS in order to investigate the possible impact of a greenhouse-gas-induced climate change on the Greenland ice sheet. The assumed increase of the mean annual air temperature above the ice covers a range from T = 1°C to 12°C, and several parameterizations for the snowfall and the surface melting are considered. The simulated shrinking of the ice sheet is a smooth function of the temperature rise, indications for the existence of critical thresholds of the climate input are not found. Within 1000 model years, the ice-volume decrease is limited to 10% of the present volume for T 3°C, whereas the most extreme scenario, T = 12°C, leads to an almost entire disintegration, which corresponds to a sea-level equivalent of 7 m. The different snowfall and melting parameterizations yield an uncertainty range of up to 20% of the present ice volume after 1000 model years.     

The behaviour of aerosol optical depth during clear summer days in Athens,Greece

Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s^–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures     

AN E – ε – ℓ TURBULENCE CLOSURE SCHEME FOR PLANETARY BOUNDARY-LAYER MODELS: THE NEUTRALLY STRATIFIED CASE

The standard E – model generates aplanetary boundary layerthat appears to be much too deep. The cause of theproblem is traced to the equation for the dissipationrate () of turbulent kinetic energy (E), specifically theparameterization of dissipation production anddestruction. In the context of atmosphericboundary-layer modelling, we argue that a part of thedissipation production should be modelled as the inputto the spectral cascade from the energy-containingpart of the spectrum, with a characteristic length , while the equilibrium imbalancebetween local production and destruction ofdissipation is modelled as proportional toE2/E, as in the standard model. Wepropose an E – – turbulence closurescheme, in which both the mixing length, m, and are prescribed. The importance ofthe equation is diminished, though itstill determines the dissipation rate in the Eequation.     

Effects of heat and water vapor transport on eddy covariance measurement of CO2 fluxes

Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO₂ concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO₂, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO₂. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= _cw for CO₂, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux _c w. Thus, when the net flux of CO₂ is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., _c w = – _c w. Corrections for the mean convective flux are particularly significant for CO₂ because _cw and _c w are often of similar magnitude. The correct measurement of the net CO₂ flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.     

Effect of finite sampling on atmospheric spectra

The effect of a finite averaging time on variances is well known, but its effect on power spectra is less clearly understood. We present numerical solutions for the spectral distortion arising from sampling over a finite time interval T and show that the commonly used filter function (1 – sinc²f T), valid for variances, is a reasonable approximation for power spectra only when T 10 _m , where f is the cyclic frequency, and _m is the dominant time scale of the process. Our results exhibit an increasingly steeper low-frequency roll-off as T decreases relative to _m , indicating that the measured spectrum is subject to a greater suppression of the lower frequencies (f > 1/T) than predicted by (1 – sinc²f T). This suppression is, in a sense, compensated by an overestimation of spectral estimates in the frequency range f 1/T.     

Estimating product yields of carbon-containing products from the atmospheric photooxidation of ambient air alkenes

The yields of products have been calculated for the reactions of hydroxyl radicals and ozone with 19 of the two-through-six carbon anthropogenic alkenes. Based on their rate of reaction, mechanisms of reactions and the ambient air distribution for these alkenes their seasonal ambient air yields have been estimated.Aldehydes predominate as products irrespective of season, with smaller yields of several ketones. Other minor products include carboxylic acids, carbon monoxide, carbon dioxide, and alkenes. About a two-fold increase is estimated in the yields of hot biradicals and their products from summer to winter.One sensitivity analysis was made by recomputing yields at a different OH radical to O₃ concentration than assumed most likely in the calculations discussed above. In addition, the sensitivity of product yields to an estimated range of seasonally averaged sunset-to-sunrise NO₃ radical concentrations was calculated. The effects of free radical reactions are discussed, but these are believed to make a relatively minor contribution within the NO _x -rich atmospheres that contain anthropogenic alkenes.The uncertainties in product yields associated with the range of NO₃ radical concentrations assumed present is relatively small for aldehydes, as is the decrease in yield of the one carbon hot biradical. Larger uncertainties occur for ketones. Significant decreases in yields occur for larger hot biradicals, especially the branched-chain hot radicals in the presence of NO₃ radicals.     

Occurrence of roll circulations in a shallow boundary layer

Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z _i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.     

On the similarity in atmospheric fluctuations of carbon dioxide,water vapor and temperature over vegetated fields

This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)^-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.