The effect of concentration and temperature on the conductivity ratio of potassium chloride solutions to standard seawater of salinity 35 ‰(Cl 19.3740 ‰)

The ratiosZ_{K,t}of electrical conductivities of potassium chloride (KCI) solutions of known concentration (K) to standard seawater at the same temperature have been measured at15degC and24degC for solutions withZ_{k,15}between 0.96 and 1.04. The "normal" concentration (N or K_{N}) givingZ_{N,15}= 1was found to beK_{N} = 32.4356gKCI/kg solution. The effect of temperature onZ_{N,t}was measured over the range15degC to30degC. Equations are given for KCI concentration as a function ofZ_{15}and the inverse function, forZ_{15}/Z_{24}as a function ofZ_{24}(to allow use of a laboratory salinometer for the KCI-seawater comparisons), andZ_{N,t}as a function of temperature.     

The concentration of the KCl solution whose conductivity is that of standard seawater (35 ‰) at 15°C

The concentration of the potassium chloride solution (KCI) which has the same conductivity as15degC at P79 standard seawater corrected to35.0000permilhas been evaluated. The variation of the conductivity ratio of KCI solutions to standard seawater (35permil) has been measured between 14.8 and15.2degC for KCI solutions whose concentration varies from 32 to 33 g.kg^-1.     

Determination of the concentration of potassium chloride solution having the same electrical conductivity, at 15°C and infinite frequency, as standard seawater of salinity 35.0000 ‰ (Chlorinity 19.37394 ‰)

The absolute electrical conductivity at15degC of several lots of standard seawater has been measured with great precision as a function of chlorinity. Potassium chloride (KCI) solutions of known concentration and having almost the same conductivity were also measured and the concentration giving the same conductivity at15degC as35.0000permilstandard seawater (Chl =19.37394permil) was found to be 32.4352 g/kg.     

Conductivity/salinity/temperature relationship of diluted and concentrated standard seawater

The conductivity ratio of diluted and concentrated standard seawater has been measured very accurately in a salinity range from 0 to42permiland at temperature from -1 to30degC. All the data have been fitted into polynomials which are compared with previous data. The specific conductance of seawater is deduced and a polynomial for the full range of salinity and temperature is proposed. Data presented in this paper have been used, with those of Dauphinee presented in this issue, to elaborate the new "Practical Salinity Scale 1978."     

The extension of the Practical Salinity Scale 1978 to low salinities

The Practical Salinity Scale (PSS) 1978 is defined only for salinities within the range 2-42. We have investigated the relationship between mass-determined salinity, electrical conductivity, and temperature for salinities between 0 and 2 with the aim of developing an extension to the Practical Salinity Scale 1978. The paper presents our data, on the basis of which the following correction is proposed to extend the validity of the equations defining the scale to the entire 0-42 range:S=summin{i=0}max{5} (a_{i}+b_{i}f(t))R_{t}^{i/2}-frac{a_{0}}{1 + 1.5x + x^{2}}-frac{b_{0}f(t)}{1+y^{1/2} + y + y^{3/2}}wheref(t)=frac{(t-15)}{1 + k(t-15)x=400R_{t}y=100R_{t}and the constanta_{i}, b_{i}, andkare defind by the Practical Salinity Scale 1978.     

A portable salinometer based on direct measurement of the conductivity ratioR_{t}

A new portable salinometer has been developed which is based On a direct determination of the conductivity ratioR_{t} = (C_{x}/ C_{s})_{t}of sample(x)to standard(s)seawater in a dual-cell, continuous-flow system. The new salinometer requires only 10 ml of unknown and much less of standard, drawn from the source bottles through fine Teflon tubes, to obtain complete flushing and several repeat readings to the order ofpm0.001, in salinity. The system is autobalancing over the full range of conductivity ratio from 0 to 1.3 and in the future will be direct reading in salinity units. The amount of standard water required is so low that standard water ampoules, at the rate of l/day, can be used as the source. The method used offers a possibility of a direct measurement of salinity in the ocean by measuringR_{t}in situ.     

A versatile sonar system for ocean research and fisheries applications

An echo sounder has been developed with features ideally suited to oceanographic and fisheries research. Instruments commonly used for such research are inaccurate, limited in dynamic range, unstable, and generally inflexible. An effort has been made to overcome these deficiencies with the sonar system discussed here. The echo sounder to be described has a time-varied-gain receiver (20 log_{10} Ror40 log_{10} R + 2alphaR) accurate to withinpm0.5dB over a 100-dB range. The equivalent dynamic range is 140 dB (the ratio of the maximum signal at minimum gain to the equivalent input noise at maximum gain in a 4-kHz bandwidth). The temperature stability ispm0.5dB from10degto35degC at any range. Operating parameters, including frequency, can be easily altered to accommodate a variety of needs.     

A low-power hypsometer-type barometer for remote weather stations

The paper describes a low-power barometer intended for remote weather stations, but also meeting the requirements for manned stations and airports, in which the condensation temperature of carbon disulphide (CS2) is used to determine the barometric pressure(p). A heated cylindrical bulb with a re-entrant well for a thermistor through the bottom and an internal radiation shield is 1/3 filled with CS2. Helical springs assist CS2migration on wetted surfaces and allow liquid and vapor to pass one another in the small diameter exit-condenser tube. A miniature Dewar flask gives thermal insulation and a 0.01-mm beryllium-copper diaphragm transmits the external pressure. The condensation temperature is read with a simple Wheatstone bridge and dc amplifier giving an outputV_{0} = 0.5(p- 100 Pa)V. Pulsed power with the pulse length controlled by a second thermistor on the outlet tube is used for efficiency. Long term tests of a number of barometers have given power levels around 40 mW at20degC and indicated maximum drifts ofpm50Pa/year,pml0Pa/day, andpm2Pa short term.     

The practical salinity scale 1978 and its antecedents

The history of the definition of salinity and the methods of computing It are traced from the beginning of the twentieth century until the present. Difficulties that have arisen in existing practices are discussed, in particular, the situation regarding reduction of in-situ CTD observations. The Practical Salinity Scale 1978 is an attempt to remove the shortcomings; it has been recommended for international acceptance. The basis for this new scale is an equation relating the ratio of the electrical conductivity of the seawater sample to that of a standard potassium chloride solution (KCI) at15degC atmospheric pressure. The samples used were prepared from standard seawater diluted with distilled water or evaporated by weight. Finally, the set of new equations for CTD data reduction is given, based upon the work of authors whose papers are appearing elsewhere in this volume.     

Tsunami detectability using open-ocean bottom pressure fluctuations

Rationale for the measurement of open-ocean tsunami signatures are presented, and available pertinent data are reviewed. Models for tsunami signature and background noise are proposed in order to synthesize an optimum tsunami receiver. Using these models, the minimum tsunami amplitude (in cm) to yield the probability of correct tsunami detectionP_{D} = 0.999and probability of false alarmP_{F} = 10^{-3}is found to be0.718/sqrt{f_{0}}, wheref_{0}is the tsunami dominant frequency (in cycles/h). A realizable receiver is proposed and its performance is evaluated using actual tsunami signatures. It is demonstrated that the detection of a tsunami with an average amplitude as small as 0.7 cm is possible for theP_{D}andP_{F}as above. Simulation results using synthesized background noise are shown. Tidal effects on the receiver performance also are considered and are found negligible for a certain range of the receiver parameters, resulting in a considerable reduction of the signal processing required.     

Active microwave measurement from space of sea-surface winds

Radar backscatter measurements from the ocean were made at 13.9 GHz from Skylab. The radar signal increased rapidly with wind speed over the entire range of winds encountered, and for angles of incidence of30degand larger. Signals observed were normalized to a nominal incidence angle (from values withinpm2degof the nominal) and to a nominal upwind observation direction, using a theoretical model that has been verified as approximately true with aircraft experiments. The wind speed was regressed against the resulting scattering coefficientssigma^{0}and the values ofbetain windpropto sigma^{0beta}were obtained for incident angles of1deg , 17deg , 32deg , 43deg,and50deg, and for vertical, horizontal, and cross polarizations. For the three larger angles,betavaries from 0.3 to 0.6. Observations during the summer and winter Skylab missions were treated separately because of possible differences caused by an accident to the antenna between the two sets of observations. The results are in general agreement with the theory [26] in all cases, with the winter and cross-polarized agreement somewhat better than that for summer like-polarized data. The "objective analysis" method used for determining "surface-truth" winds in the Skylab experiment was tested by comparing results obtained at weather ships (using all other ship reports to produce the analysis) with the observations made by the weather ships themselves. In most cases, the variance about the regression line between objective analysis and weather-ship data actually exceeded that about the regression line between objective analysis and backscattcr data!     

Properties of superresonant systems of spherical scatterers

Systems of identical precisely spaced bubbles or similar monopole scatterers in water-e.g., inflated balloons or thin-walled shells-insonified at frequenciesomega_{SR}dose to their fundamental radial resonanceomega_{0}(bubble) frequency may themselves display resonance modes or superresonances (SR's) [1]. Ordinary single-bubble resonances magnify the local free-field pressure amplitudep_{1}by a factor(ka)^{-1},abeing the radius andkthe wavenumber in water: for air bubbles or balloons in water, this factor is of the order of 70. Under SR conditions each member of the system amplifies the local free-field amplitude by a further factor of order(ka)^{-1}. Depending upon geometry and other constraints, the pressure fieldP_{SR}on the surface and in the interior of each scatterer will then be in the range of10^{3}p_{1}to5 times 10^{3} p_{1}. This paper investigates the sensitivity of this phenomenon to small departures from the ideal model. In particular, it examines the effect of small differences in scatter positioning and volumes in the context of an SR system consisting of two bubbles/balloons close to the boundary of a thin elastic plate overlying a fluid half-space. It is found that, to observe the SR phenomenon, radii and positions should be controlled to within approximately 1/2 percent.P_{SR}is also sensitive to the angle of incidence of the plane wave train. For the simple system examined here, this sensitivity is considerable for either flexural wave trains or volume acoustic waves incident upon the bubble/ balloon pair (doublet). Practical uses of the phenomenon may range from the design of passive high-Qacoustical filter/amplifiers and acoustical lenses to improved source efficiencies.     

Motion stability measurements of a submarine-towed extremely low-frequency receiving platform

The design and ultimate performance of an extremely low-frequency (ELF) superconducting quantum interference device (SQUID) antenna that is mounted in a submarine-towed buoy depends critically on the motion spectrum of the buoy. Motion spectrum measurements from near dc to 100 Hz were conducted on a hydrodynamically stabilized buoy while being towed in the 650-m towing basin of the David Taylor Naval Ship Research and Development Center, Carderock, MD. The spectra show that the angular motion of the buoy can be held to4 times 10^{-6}rad/sqrt{Hz}or less within the ELF receiver bandwidth of 30-130 Hz, as long as properly streamlined fairings are used on the hydrofoil trailing edges in order to prevent oscillations from vortex shedding. Low-frequency oscillations of the buoy were3 times 10^{-3}rad/sqrt{Hz}or less for frequencies down to 0.025 Hz. This performance of the buoy is sufficient to permit it to serve as a towed platform for the NRL prototype SQUID receiver.     

Effect of a snow cover on microwave backscatter from sea ice

The effect of a snow cover on sea ice upon radar backscatter at microwave frequencies (X- andKu-baud) can be important. The effect of scattering from the snow cover on thesigmadegof first-year ice is shown to be severe (5 cm of dry snow can raisesigmadegby 8 dB at 9 GHz), while that onsigmadegof multiyear ice is shown to be smaller. The low thermal conductivity of snow compared to that of sea ice effectively raises the temperature of the upper surface of the ice, resulting in higher dielectric constants for the ice, thereby modifying the backscatter both from the ice surface and from the scattering volume. The temperature effect of a 10-cm snow cover on 3-m-thick multiyear ice is to lower thesigmadegby only about 0.3 dB for air temperature of-20degC. The effect on 1-m-thick first-year ice is even less. Hence, the volume-scattering effect of snow is more important than the temperature effect. The presence of a wet snow cover can block the volume-scattering contribution of the multiyear ice. The effect of wet snow cover on first-year ice should be smaller than that Of dry, snow, becausesigmadegof wet snow is lower than that of dry snow.     

再探温跃层有孔虫B/Ca与温度和[CO32-]的依赖性及其在24 ka以来热带西太平洋次表层碳酸盐系统重建中的应用

The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [ CO_3~(2-)] is the dominant control on the partition coefficient(K_D) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei(300–355 μm) and Pulleniatina obliquiloculata(355–400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states(Δ[ CO_3~(2-)]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients(R~2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters(e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between K_D values of N. dutertrei and P. obliquiloculata and carbonate system parameters(e.g.,[ CO_3~(2-)], DIC, ALK, pH and [ HCO_3~-]) in the study area reflect chemical links between the K_D denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the K_D of N.dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei(300–355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [ CO_3~(2-)] show an increase with time, and the record of subsurface seawater pCO_2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO_2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO_2 in the study area was promoted by enhanced upwelling in the Southern Ocean.     

High-resolution mapping of oceanic wind fields with skywave radar

The direction of the mean surface wind field in the North Pacific Ocean was mapped on September 25 and 26, 1973, over an area of3 times 10^{6}(km)²by OTH-B HF radar. A spatial resolution of 60 km in range and 15 km in cross range was used at points spaced by 150 km in range and 80 km in cross range. Wind directions were inferred from the upwind/downwind first-order Bragg ratio and the measure of the maximum ratio occuring for radial winds at points near each observation. Over 90 percent of the recorded data were usable for this purpose.High spatial resolution is essential to make detailed measurements of the wind speed and direction across and along an atmospheric cold front. The location of the atmospheric cold front derived from the wind field agreed well with the ESSA VIII satellite frontal location.     

Practical experience with the Variosens equipment in measuring chlorophyll concentrations and fluorescent tracer substances, like rhodamine, fluorescein, and some new substances

The quantitative measurement of the dispersion of matter in large bodies of water, e.g., in ocean currents [1], needs an optoelectronic fluorometer of very high sensitivity due to the great quantities of the required fluorescent substances like rhodamine B or fluorescein that would otherwise be required. The basis of a new tracer technology of very high sensitivity is the use of pulsed bluish light for excitation [6], [7]. The instrument described here is known as the Variosens. It is able to measure concentrations of fluorescent substances down to10^{-11}and has a logarithmic scale covering a concentration range of about 1:3000. The fluorescence is excited by means of a xenon spark at a frequency of 10/s with stabilized light emission. A wide-band optical filter defines the exact spectral range of the required exciting light. The receiver operates with a narrow-band optical filter by measuring the fluorescent radiation of the tracer substance used. This filter must have a very high blocking factor. Without filters the instrument uses backscatter to measure the quantity of suspended particles in the water in milligrams/liter.     

Attenuation Measurements Across Surface-Ship Wakes and Computed Bubble Distributions and Void Fractions

A surface ship's wake is composed of several hydrodynamic phenomena. A large part of that wake contains a mixture of air bubbles of various sizes in turbulent water. Eventually, as the wake ages, the turbulence subsides and bubbles begin to rise at rates that are determined by their sizes. These bubbles of various sizes and concentrations control the propagation of acoustic signals inside and across a wake. To further our understanding of these phenomena, a series of three continuous-wave (CW)-pulsed signals were transmitted across a wake as the wake aged. Each transmission contained a set of four 0.5-ms-long pulses. The 12 pulses ranged over frequencies from 30 to 140 kHz in 10-kHz steps. The acoustic attenuations across wakes that were due to varying bubble-size densities within the wakes were determined experimentally. From those data, estimates of the bubble densities as functions of the speed of the wake-generating ship, the wake's age, and acoustic frequency were calculated. From the bubble-density results, power-law fits and void fractions are calculated. The attenuation measurements were taken at 7.5-m intervals behind the wake-generating ship and continued for about 2 km. The experiment was run for wakes generated at ship speeds of 12- and 15-kn wakes, and the 15-kn run was repeated for consistence determination. The bubble densities were observed to have power-law forms with varying parameters with the strongest, for early ages, having an exponent of ${-}$3.6 and a void fraction of 4 $times$ 10$^{-7}$ , and with both diminishing for older wakes, as might be expected.      

Static and dynamic modeling of a SAR imaged ocean scene

A number of models exist that attempt to explain wave imagery obtained with a synthetic aperture radar (SAR). These models are of two types; static models that depend on instantaneous surface features and dynamic models that employ surface velocities. Radar backscatter values (sigma_{0}) were calculated from 1.3- and 9.4-GHz SAR data collected off Marineland, FL. Thesigma_{0}data (averaged over many wave trains) collected at Marineland can best be modeled by the Bragg-Rice-Phillips model which is based on roughness variation and the complex dielectric constant of oceans. This result suggests that capillaries on the surface of oceanic waves are the primary cause for the surface return observed by a SAR. Salinity and temperature of the sea at small and medium incidence angles produce little effect upon sea-surface reflection coefficients atX-band, for either of the linear polarizations. The authors' observation of moving ocean, imaged by the SAR and studied in the SAR optical correlator, support a theory that the ocean surface appears relatively stationary in the absence of currents. The reflecting surface is most likely moving slowly (i.e., capillaries) relative to the phase velocity of the large gravity waves.