Secondary ferrimagnetic minerals in Welsh soils: a comparison of mineral magnetic detection methods and implications for mineral formation

A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe₃S₄, during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution.     

Palaeoclimatic implications of the magnetic record from loess/palaeosol sequence Viatovo (NE Bulgaria)

Loess-palaeosol deposits in the lower Danube area represent the southeastern edge of the loess cover in Europe. Detailed rock magnetic investigations of the loess/palaeosol sequence in Viatovo in NE Bulgaria reveal that magnetite and maghemite of very fine superparamagnetic grain size are responsible for the magnetic enhancement of palaeosol units. A detailed palaeoclimatic record is obtained through high-resolution measurements of magnetic susceptibility, frequency dependent magnetic susceptibility and CaCO₃ content. Magnetic proxies indicate a more warm and humid climate during the development of the older palaeosol units (S₄–S₆).     

The rock magnetic signal of climate change in the maar lake sequence of Lac St Front (France)

Rock magnetic properties of the maar lake sediments of Lac St Front (Massif Central, France) reflect environmental changes during the last climatic cycle. High magnetic concentrations are measured in the sediments deposited under glacial climatic conditions, while lower concentrations correspond with more temperate climatic periods. Low- and high-temperature measurements indicate that the remanence is carried by (titanium-poor) magnetite. However, some maghemite and haematite is present in sediments deposited under temperate conditions.
Normalized intensities and coercivities of the anhysteretic remanent magnetization (ARM) are clearly higher for the sediments deposited during the temperate climatic periods of the Eemian, St Germain I, II and Mid-glacial than for glacial sediments, but other magnetic parameters hardly differ between these groups. Due to slight differences in magnetic composition and possible effects of grain interactions, it is not straightforward to relate this different ARM behaviour to magnetic grain-size variations. For the Holocene sediments, rock magnetic parameters indicate a larger grain size. This trend is also suggested by granulometric experiments with an optical laser granulometer. Dissolution of smaller grains is the most likely explanation for this larger grain size.
Changes in magnetic composition and grain size are extremely limited for the glacial sediments, but magnetic concentration varies considerably. Magnetic concentration maxima in the glacial sediments of Lac St Front correlate with those of the nearby Lac du Bouchet (Thouveny et al. 1994). Correlating the susceptibility records of these sequences with the δ¹⁸O record of the GRIP ice cores (Thouveny et al. 1994) suggests that magnetic concentration maxima may correspond with short cold climatic episodes, associated with Heinrich events.     

Comparison of magnetic and gamma ray logging for correlations in chronology and lithology: example from the Aquitanian Basin (France)

Precise time and facies correlations between drilled holes are fundamental for a better understanding of the geological evolution of sedimentary basins. A downhole magnetic measurement device called the geological high-sensitivity magnetic tool (GHMT) has been run within two wells drilled by Gaz de France in the Landes oil-field (southwest France) as part of a gas storage exploration program. The method of interpretation of downhole magnetic measurements yielded a magnetostratigraphy within each well, allowing absolute dating and time correlations between the wells.
  Magnetic susceptibility and natural gamma ray intensity are useful parameters for establishing high-resolution lithological correlations at a basin scale. We present a correlation parameter established from a simultaneous analysis of the susceptibility and the gamma ray logs within each well. The correlation parameter appears to provide a new tool for delineating lithological elements when local lithological changes are too subtle to show clear well-to-well correlations either from susceptibility logs or from gamma ray logs. This new approach is interpreted as a sensitive way to detect relative variations between the detrital and clay content of the penetrated sediment.     

Palaeomagnetism of Palaeozoic ultrabasic rocks from the Sudetes Mts (SW Poland): tectonic implications

A complex palaeomagnetic, rock-magnetic and mineralogical study of ultrabasic rocks from the Sowie Góry Block (GSB) and Jordanów–Gogołów Serpentinite Massif (JGSM) revealed the presence of several components of natural remanent magnetization (NRM). The authors found three groups of Palaeozoic as well as Triassic and Recent components of the geomagnetic field. The Palaeozoic components of NRM are carried mainly by magnetite of several generations formed during several serpentinization episodes. Permo-Carboniferous component (A1) present overall the Sudetes was isolated in one JGSM and two GSB exposures, whereas the Late Devonian–Early Carboniferous component (A2) was found in two exposures from the GSB. The corresponding remanent components were already revealed in palaeontologically dated sediments from other West Sudetic units. In the GSB, it was probably acquired during its unroofing dated isotopically for ca. 370–360 Ma. The newly determined group of Palaeozoic directions (A3) was found in three localities from JGSM and in two from GSB is interpreted as the oldest overprint. In JGSM, it was acquired probably shortly after the first oceanic serpentinization phase dated isotopically for ca. 400 Ma. Its acquisition in GSB corresponds to the time of emplacement of ultrabasic xenoliths dated isotopically at ca. 390 Ma. So we suppose that the mean A3 calculated for five exposures corresponds to the 380–400 Ma time span and that at that period both massifs formed one microplate. Mean inclination of A3 places this microplate at 380–400 Ma at the palaeolatitude of 23°S, whereas the West Sudetes were situated during the Early Devonian at 16°S. We suggest that during the Early Devonian the microplate comprising GSB and JGSM massifs was situated to the south from the West Sudetes and accreted them during Middle–Late Devonian.     

A theoretical and experimental comparison of the anisotropies of magnetic susceptibility and remanence in rocks and minerals

Summary. Susceptibility, thermo-remanent magnetization (TRM) and isothermal remanent magnetization (IRM) anisotropy ellipsoids have been determined for several rock samples. The results indicate that the ellipsoid of initial susceptibility is less anisotropic than the TRM and low field IRM ellipsoids which are found experimentally to be of identical shape. This suggests that palaeomagnetic data for anisotropic rocks may be corrected by using the anisotropy ellipsoid determined from magnetically non-destructive low field IRM measurements. Such IRM measurements can also be used to obtain anisotropy axes of samples which are inherently anisotropic but which have a susceptibility which is too weak to be accurately measured. The results for a series of artificial anisotropic samples containing magnetite particles of different sizes (in the range 0.2–90 μm) were very similar to those for the rocks. In contrast, a comparison of the susceptibility and IRM ellipsoids for anisotropic samples containing particles from a magnetic tape gave very different results in accordance with theory. Such results imply that susceptibility and IRM ellipsoids could be used to determine whether anisotropic rocks contain uniaxial single-domain particles (magnetization confined to the easy axis) or whether the particles are essentially multidomain.     

Anisotropy of magnetic susceptibility investigations of the St Malo dyke swarm (Brittany, France): emplacement mechanism of doleritic intrusions

A high-quality aeromagnetic survey of northern Brittany (line spacing 250  m; flight elevation 150  m) has been used to delineate the Lower Carboniferous St Malo dyke swarm in detail. The dyke swarm fans at its northern and southern ends, and is affected by N60° sinistral transcurrent faults. After restoration of these offsets, the full structure trends in a N–S direction. Small dykes are not imaged, and only one-third of the swarm is evidenced by magnetism. Gravity and magnetic modelling shows that the swarm overlies a single N–S elongated magma chamber.
  The distribution of K _max inclinations of anisotropy of magnetic susceptibility (AMS) suggests that the dykes display a fanning magma flow in section. Computed K _max inclinations are usually shallower than the measured geological dips, probably because the flow becomes more disturbed as the dyke becomes shallower. We observe that the mean susceptibility values increase when the magma flow is steeper than about 70°.
  A detailed cross-section of St Briac dyke, which is part of the St Malo dyke swarm, reveals that the main carrier of magnetization is magnetite in the centre of the dyke and magnetite + maghaemite on its rims. The emplacement of the St Malo dyke swarm could have been contemporaneous with the N60° shearing which displaced the dyke swarm by about 20  km. The dyke swarm is cut at its southern end by an E–W-orientated fault which probably acted during Late Carboniferous times.     

Preliminary reconstruction of sediment-source linkages for the past 6000 yr at the Petit Lac d'Annecy, France, based on mineral magnetic data

An 8 m core from the central plain of the Petit Lac d'Annecy, France, two floodplain cores, river bedload sediments and several hundred soil samples from the catchment have been studied using magnetic techniques. The soils, mainly developed on limestones and local glacial tills, show widespread magnetic enhancement with higher ferrimagnetic concentrations and contents of SP grains than found in the lake sediments. Some soils show significant concentrations of canted antiferromagnetic minerals (mainly haematite). Using magnetic quotient parameters the surface soils are classified into four mineralogical types. The lake and floodplain sediment properties over the past 6000 yrs can largely be explained by the erosion and deposition of these sources, with a smaller superimposed biogenic (magnetosomes) signal. Derived sediment-source linkages allow the construction of several hypotheses about geomorphological changes in the catchment system: (i) the long-term erosion of high altitude unweathered substrates has gradually increased towards the present day; (ii) the erosion of high altitude soils has increased within the last 1000 yrs, possibly during the period of the 'Little Ice Age'; (iii) shifts towards an increased erosion of surface lowland soil occurred ~2000 and 1000 yrs ago and may be linked to an accelerated accretion of floodplain overbank deposits; (iv) there has been a significant storage of surface soil within floodplains, which leads to an underestimation of the importance of soil erosion in the lake sediment records; (v) the sediment transported by high magnitude, low frequency flood events has shifted in source from high altitude soils before ~1000 cal. yr BP to lowland and mid-altitude free draining soils after ~1000 cal. yr BP.     

The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

Use of magnetic hysteresis properties and electron spin resonance spectroscopy for the identification of volcanic ash: a preliminary study

This initial study investigates the possible use of hysteresis parameters and electron spin resonance (ESR) spectroscopy to identify and correlate volcanic ash. ESR and hysteresis properties are sensitive to characteristics such as the chemical composition, mineralogy, and grain size and shape. These characteristics are determined by the tectonic setting of the volcano and by the magmatic and eruptive history of the volcanic ash. Hysteresis properties and ESR spectra, therefore, should be distinct for each ash eruption and may help to identify the eruptive source of the ash and to correlate ash from unknown sources. We conducted ESR spectroscopy at room temperature and magnetic hysteresis measurements on 19 samples of a single ash, the 1974 October 14 eruption of the Fuego volcano, Guatemala, and on single samples of ash obtained from eight different volcanoes. The Fuego ash samples were obtained at increasing distances from the volcano. For the single Fuego ash, ESR spectra and hysteresis parameters become increasingly similar as the distance from the volcano increases. At distances greater than 30 km, ESR spectra and hysteresis properties are uniform. The variability of magnetic and ESR properties with distance from Fuego is due to the preferential fall-out of phenocrysts closer to the volcano. At large distances, the ash is more uniform, containing more glass and microcrystals. All eight ash samples from the different volcanoes can be distinguished from the distal Fuego 1974 October 14 ash using ESR spectra and hysteresis parameters. These results suggest that ESR and hysteresis measurements have a potential to be used as tools to identify distal ash when used in conjunction with geochemical, mineralogical and/or other types of data.     

Fidelity and time resolution of the magnetostratigraphic record in Siwalik sediments: high-resolution study of a complete polarity transition and evidence for cryptochrons in a Miocene fluviatile section

The Surai Khola section in southwest Nepal, a 5000 m continuously exposed record of fluvial sedimentation since Middle Miocene, was revisited for high-resolution magnetostratigraphy in sequences with expected cryptochrons and reversals of the geomagnetic field. Polarity intervals with durations of a few tens of thousands of years are recorded as zones of stable palaeomagnetic directions. Polarity transitions are recorded as zones with complex demagnetization behaviour of specimens in the sedimentary column. Almost antiparallel palaeoremanence directions, residing in different haematite phases in the same specimens, could generally not be separated properly by thermal demagnetization. Differing demagnetization paths for neighbouring specimens during a reversal suggest that measured transitional directions are not true geomagnetic field directions, but rather are generated by the superposition of variable amounts of at least two almost antiparallel components of magnetization. Accompanying studies of recent river sand deposits demonstrate that these sediments acquire a true depositional remanent magnetization (DRM) with considerable inclination errors and scattered directions for individual specimens.