Distribution and temporal variation of cadmium in the St. Lawrence river basin

Samples of raw water were collected at regular intevals at two transects in the St. Lawremce River and four of its tributaries from March to November 1991 and from April to June 1992. Water samples were analyzed for both the dissolved and the particulate phase for cadmium (Cd), organic carbon, iron and manganese. Mean dissolved Cd concentration was 10±5 ng/L and no spatial variability was observed. Higher concentrations were found during high flow periods, suggesting an uptake of cadmium by phytoplankton during summer. In addition, dissolved cadmium did not appear to be associated with either DOC, dissolved Fe or dissolved Mn. The mean particulate Cd concentration was 1.3±1.1 μg/g, with almost all stations presenting the same concentration except the Yamaska River, which had a concentration of 0.5±0.2 μg/g. Particulate Cd showed a negative correlation with suspended particulate matter and a positive correlation with particulate organic carbon and particulare manganese. Fifty-nine percent of the cadmium was found to be in the particulate phase. Partition coefficients for cadmium (Kd), organic carbon (Kc), iron (KdFe) and manganese (KdMn) were calculated for each sample. Log Kd varied from 3.9 to 5.9, with an average of 5.0±0.4. Log Kd decreased with increasing particulate, matter as did Log Kc and Log KdMn. No significant correlation was found between Log Kd and Log Kc, suggesting that the distribution of cadmium between the dissolved and the particulate phase is not influenced by the distribution of organic carbon. In contrast, positive correlations were observed between Log Kd, Log KdFe and Log KdMn. Cadmium distribution appears to be influenced by Fe and Mn distribution.     

Temporal variation of codaQ during Hualien earthquake of 1986 in eastern Taiwan

The May 20, 1986, Hualien earthquake sequence occurred on the northeastern coast of Taiwan. TheM=6.1 (GS mb) mainshock was followed by a large number of closely-clustered aftershocks with the largest being anM=5.5 event. One seismic station, TWD of the Taiwan Telemetered Seismographic Network, is located in the surface projection of the source region and provides excellent recordings of the entire earthquake sequence. These recordings, plus events occurring in the same source area preceding the mainshock, offer a unique opportunity to study the spatial and temporal variations of codaQ in a region of active subduction. A simple technique is devised that uses the envelope of the coda waveform to enable a quick determination of the codaQ from drum records. For recordings with a peak power at about 8 Hz, the following findings have been obtained: 1. The ambient codaQ near an active subduction region was as low as 145; 2. There was no significant decrease in codaQ within the period beginning one year and four months prior to the mainshock; 3. There was a significant drop of codaQ immediately after the mainshock; this drop lasted approximately two days before returning to the ambient level; 4. CodaQ values varied with focal depth.     

太湖水系结构特点及其功能的变化

太源水系上游为树状排列的河流,下游为扇形排水系统,全区江河湖海相贯通,受海潮和江流的作用,下游水系多变,防洪抗灾能力脆弱。近年来,虽经治理,该水系仍出现了“中雨大灾”,水资源不足及水质污染突出等一系列功能性的变化。     

Biweekly periodic variation of the Kuroshio axis northeast of Taiwan as revealed by ocean high-frequency radar

An analysis of surface current data obtained from 2002 to 2005 using long-range high-frequency radar provides the first evidence for the presence of biweekly (11–14 day) periodic variations of the Kuroshio axis northeast of Taiwan. This analysis clarifies the spatiotemporal characteristics of these variations and reveals that cyclonic/anticyclonic eddies propagating along the shelf slope from the vicinity of the deep channel east of Taiwan induce these variations northeast of Taiwan. The behavior of the cyclonic/anticyclonic eddies on the shelf slope is well explained by 2nd-mode interior shelf waves advected by the Kuroshio's mean flow. Remote effects from the vicinity of the deep channel east of Taiwan, or from outside the East China Sea, are believed to play an important role in the generation of these biweekly periodic variations of the Kuroshio axis northeast of Taiwan. Moreover, on the shelf slope, these variations cause an onshore current across the shelf slope, suggesting topographically controlled upwelling. Therefore, the biweekly periodic variations of the Kuroshio axis northeast of Taiwan might contribute not only to the onshore transport of Kuroshio surface water but also to transport nutrient-rich Kuroshio subsurface water onto the shelf in the East China Sea.     

汰内井水氡年变异常与台湾地区强震的关系

通过对汰内井水氡多年年变动态的分析 ,发现台湾地区强震前后汰内井水氡值表现出持续高值、年变规律畸变等异常 ,这些异常多为中期与中短期异常 ,有时也有短临异常和震后效应 ;利用中国地震局“八五”攻关软件《SHEP》对汰内井 1987～ 1999年氡测值进行层次跟踪中期预测分析 ,发现其预测结果与台湾 1987年以来发生的 4次强震在时间上有较好的对应关系     

An analysis of the seasonal variation of disturbance in georesistivity

Four types of disturbances in the seasonal variation in georesistivity are presented in the light of specific circumstances in China. As the results of theoretic calculation for the models and in comparison of the calculated results with the seasonal variations observed at 40 georesistivity stations, the following points are found: (1) The seasonal variation in georesistivity is caused by the change in resistivity of the surface layer, especially by the annual variation of phreatic level when the sounding depth is too shallow. This is one of the disturbances and thus has no relation to the origin of earthquake. The feature and amplitude of the seasonal variation depend on the types of disturbance models, geoelectric cross sections and sounding depth. (2) The seasonal variation in georesistivity usually has the same sign as that of the change in resistivity of shallow layer and thus the normal seasonal change appears. However, as far as the K or Q types of geoelectric cross sections are concerned, the abnormal seasonal variation in georesistivity starts to appear with a certain electrode spacing, when the interference layer is located in the first layer. (3) Both abnormal and normal seasonal variations in georesistivity will be smaller than 2% when the sounding depth is greater than 300 m. Therefore, the seasonal variations can be removed or restrained when the location of observation has been properly chosen or the electrode spacing is enlarged enough to obtain a sufficient sounding depth.     

Abiotic features and macroinvertebrate colonization of the hyporheic zones of two tributaries of the river Elbe (Germany)

Whole-ecosystem experiments may reach statistical pertinence when reference and treatment sites are compared. Therefore at least two similar systems must be found. To this aim we tried to answer the question if the hyporheic zones of both streams have similar features. We postulated that both streams would be unsuitable for a comparison in an ecosystem experiment if the structure of their hyporheic invertebrate communities differs significantly. Although pH, electrical conductivity and nitrate concentration differed in the surface water, variability of all chemical criteria studied in the hyporheic zones was much lower between the two streams compared to the variability within each stream. Thus the structure of both hyporheic invertebrate communities did not differ significantly. Because of this uniformity both streams are regarded to be suitable for a comparison in a whole-ecosystem experiment.     

地磁场长期变化和日长十年尺度变化的周期特征

根据历史地磁场模型GUFM1、第10代国际参考地磁场（IGRF10）模型和日长资料,采用小波变换方法,分析了地磁场磁矩、能量、西向漂移等参数的长期变化和日长十年尺度变化的周期分量及其时变特征.结果表明,1800～2005年期间,偶极子磁场长期变化有82年和48年准周期分量,它们与日长变化的周期没有直接关系.非偶极子磁场参数的长期变化与日长变化有66年和32年准周期分量,66年准周期比32年准周期强.在66年准周期分量,西向漂移比日长变化超前8.8年,非偶极子磁场能量比日长变化滞后15.6年.日长十年尺度波动和地磁场长期变化的起源不存在因果关系.     

Isomer specific determination of hexabromocyclododecanes (HBCDs) in small cetaceans from the South China Sea--Levels and temporal variation

A diastereoisomer (alpha, beta, and gamma) specific analytical method for measuring hexabromocyclododecanes (HBCDs) was developed using liquid chromatography-tandem mass spectrometry (LC-MS-MS). The method developed was applied to analyze blubber of small cetaceans to divulge the distribution and temporal variation of HBCDs in the Asian marine environment. HBCDs were detected in all the blubber samples of finless porpoises (Neophocaena phocaenoides) and Indo-Pacific humpback dolphins (Sousa chinensis) collected from the South China Sea during 1990-2001. Concentrations of HBCDs were higher in humpback dolphins (31-380 ng/g lipid) than in finless porpoises (4.7-55 ng/g lipid), which can be attributed to habitat differences. Average concentrations of alpha-HBCD in finless porpoises increased from 9.5 ng/g lipid in 1990 to 35 ng/g lipid in 2000/01. alpha-HBCD was predominant among the three isomers with some exceptions in finless porpoises collected in 1990. This is the first report on HBCDs contamination in marine mammals from Southeast Asia.     

Demographic history,range size and habitat preferences of the groundwater amphipod Niphargus puteanus (C.L. Koch in Panzer, 1836)

Niphargus puteanus is the oldest described species of its genus and, in the past, was used as a taxonomic annotation for any subterranean amphipod record. For that reason, no clear knowledge exists about its actual range size and habitat preferences. We here applied a molecular taxonomic and phylogeographical approach based on mitochondrial and nuclear DNA to shed light on its distribution and to infer its demographic history. Furthermore, we analysed aquifer types and water flow regimes to provide a clearer picture of the species’ ecological requirements.Our results indicate that N. puteanus is widely distributed north of the Alps, having its core range in the geomorphological natural region of the ‘South German Scarplands’ (SGS). Additionally, isolated satellite populations exist in the Taunus and the Sauerland, and two single individuals were collected in Luxembourg and in Austria, respectively. The species’ maximal distribution range reaches 756 km between the two single-specimen records and 371 km within the SGS. A very high haplotype diversity was observed, revealing the presence of seven haplotype groups. All the haplogroups were present in the SGS and exhibited distinct spatial-genetic patterns. We thus inferred a high degree of population isolation, with the SGS being a potential long-term refugium for N. puteanus. Historical drift of specimens along major riverine networks (Rhine, Danube) may provide an evolutionary dispersal mechanism explaining the formation of satellite populations.From an ecological perspective, populations of N. puteanus were found to be closely associated with fast-flowing spring environments within fissured aquifers. This species should therefore be classified as both crenophile and stygophile, effectively exploiting resources of surface as well as subsurface spring waters.     

北京地区地磁场Sq强度的季节变化和长期变化

本文利用北京地区的北京台（BJI）和北京十三陵台（BMT）的地磁场X、Y和Z分量时均值数据,研究了1960年至2013年期间该地区地磁场Sq强度的季节变化和长期变化.结果表明：（1）BJI台和BMT台的地磁场Sq不仅变幅相近,而且具有一致的地方时变化、季节变化、太阳活动周变化和长期变化.（2）BJI台和BMT台Sq强度的逐月变化,其中A_Sq（X）主要表现为春秋增强而冬夏减弱的季节变化.A_Sq（Y）呈现出夏季增强的半年变化.A_Sq（Z）变化较为复杂.虽然在5月和9月出现减小,但是总体来看,其变化曲线也具有夏季增强的半年变化特征.同时,Sq强度与太阳活动F₁₀₇指数之间存在明显的正相关关系,具有一致的11年太阳活动周变化和长期变化,反映出了Sq与太阳活动之间的密切关系.（3）BJI台和BMT台Sq强度差值dA_Sq表明,在大多数年份,两个台站的Sq强度之差一般不超过±2 nT,同时没有明显的季节或年周期变化特征.在2000年和2001年太阳活动高年,dA_Sq出现显著增强,最大可达12.3 nT.反映出了北京地区Sq场强度梯度的剧烈扰动与太阳活动之间的密切关系,意味着在太阳活动高年,Sq电离层发电机电流的局部结构可能发生了明显的改变.

     

强化生态浮床原位修复技术对污染河流浮游动物群落结构的影响

对强化生态浮床原位修复技术修复南方重污染感潮河流过程中浮游动物的种群动态变化进行研究,探讨浮游动物群落结构变化特征与河流水质改善状况的相互关系.结果显示,经强化生态浮床处理后,重污染感潮河流水质得到改善,浮游动物的种类由修复工程实施前的5种增加到49种,且由单一耐污种转变为多种种类共存;示范区各月浮游动物个体丰度较对照...     

The anomalous variation of the lightning activity in southern China during the 1997/98 El Ni(n~)o event

This paper presents the EOF analysis results of the lightning density (LD) anomalies for the different seasons in southeastern China and Indochina Peninsula by using the OTD/LIS database (June 1995 to Feb. 2003) of the global LD with 2.5°×2.5° resolution offered by Global Hydrology Resource Center. It is shown that the LD positive anomalies in the region occurred at the same time of NINO3 SSTA steep increase in the spring of 1997 and remained to be a higher level till the next spring, as well the corresponding anomaly percent maximum in different seasons was 89%, 30%, 45%, 498% and 55% successively from the beginning to the end of the 1997/98 El Ni(~n)o event (ENSO). The centre of the LD positive anomalies for the spring or winter season is located at southeastern China and the adjacent coastal areas, but it for the summer or autumn season is located at the southern Indochina Peninsula and Gulf of Thailand, whose position for each season in the ENSO as contrasted with the normal years has a westward shift, and especially for winter or spring season a northward shift at the same time. In addition, an analysis of the interannual variations in the LD anomaly percent, convective precipitation and H-CAPE days in southern China shows that each among the three anomaly percents is correlative with the other for the positive anomaly zone and Kuroshio area. The relative variation of LD during the El Ni (~n)o period is the highest among the three rates and is larger than that during the non-El Ni(~n)o period, meaning that the response of lightning activities to the ENSO is the most sensitive in both areas. But the response of lightning activities and precipitation to the ENSO appears to be more complex and diversified either in Kuroshio area or in the Qinghai-Tibet Plateau and northwestern and northeastern China.     

河北省地磁场变化规律研究

利用河北省地磁台1986～2005年的地磁观测资料,对该地区地磁场长期变化规律进行总结分析.这进一步认识了河北省地磁场变化规律及其特征,为地震预报提供有实用价值的第一手资料十分有意义.     

The secular variation of the geomagnetic field in Egypt in the last 5000 years

The palaeo-intensities (F _a) of the geomagnetic field in Egypt at some ages are determined by archaeomagnetic measurements and found to be:F _a=36.2 T at 3100 B.C., F_a=46.8 T at 3000 B.C.,F _a=36.5 T at 2780 B.C., 49.0 T at 2500 B.C., 36.4 T at 2200 B.C., 57.5 T at 1990 B.C., 62.1 T atca 1400 B.C., 61.5 T at 1400 B.C., 69.9 T at 600 B.C., 59.3 T at 550 B.C., 79.9 T at 460 B.C., 73.7 T at 450 B.C., 69.7 T at 320 B.C., 56.2 T at A.D. 50, 64.9 T, at A.D. 400, 54.4 T at A.D. 300, 57.5 T at A.D. 700 and 43.0 T at A.D. 1975.The palaeo-inclinations (I _a) at some ages are found to be:I _a=24.2° at 420 B.C., 44° at A.D. 50, 60.7° at A.D. 703 and 42° at A.D. 1795.The measured values ofF _a are affected by the anisotropy of magnetic susceptibility of the samples by 13% to 20% of the expected correct value. The suitable correction of this effect is by multiplyingF by 1/((1+0.2(/90)) andF by 1/((1–0.13 (/90)), whereF andF are the resultant values ofF _a if the laboratory field is perpendicular or parallel to the wall of the sample during the Thelliers' experiments, respectively, and is the angle between the direction of natural remnant magnetization of the sample and the direction of the laboratory field.The results of this paper, together with the previous results for Egypt and the neighbourhoods, lead to the production of the secular variation curve of the geomagnetic field in Egypt for the last 5000 years. The intensity of the field shows a periodicity of about 400 years with multiples.     

辽河太子河流域藻类植物群落结构及其季节变化

2010年9月到2011年9月分4次对太子河流域的藻类植物群落组成、丰度及优势种进行调查分析.共设置17个采样点,经鉴定共有藻类植物8门120属328种(包括21种变种).藻类植物群落以硅藻最多,有36属144种,占总体的43.77%;其次是绿藻,有49属117种,占总体的35.56%;蓝藻居第3位,有22属38种,占总体的11.85%.调查期间,太子河流域藻类植物细胞丰度在夏、秋季较高,丰度平均值分别为6.80×10⁷和3.29×10⁷cells/L;在春季较低,丰度平均值为1.36×10⁷cells/L.优势度分析显示,太子河流域各季节的藻类植物优势种都在5种以上,主要优势种有巨颤藻(Oscillatoria princeps Vauch.)、链丝藻(Hormidium flaccidum(Kütz.)Br.)、偏生毛枝藻(Stigeoclonium subsecundum(Kütz.)Haz.)等.藻类植物的Jaccard种类相似性指数在0.19~0.46之间.太子河流域藻类植物种类组成及细胞丰度均有明显的季节变化.