Conservation of the freshwater pearl mussel (Margaritifera margaritifera) in the river Rede,UK: Identification of instream indicators for catchment-scale issues

The freshwater pearl mussel (Margaritifera margaritifera) is declining throughout its entire range. On the river Rede, North-East England, the population has been equally declining and shows no apparent recruitment. The study presented here aimed at characterizing water quality and habitat conditions for pearl mussels to identify possible indicators of pressures on the population and inform a restoration and conservation strategy. Water quality monitoring revealed levels of turbidity and suspended sediments to be above the limit set for functional pearl mussel rivers. Substrate sampling revealed silt was present at all sites. A loss of redox potential between the water column and the substrate occurred at all sites, indicating non suitable conditions for juvenile pearl mussels. These investigations suggest that fine sediment input in the river could be one of the factors preventing the development and survival of juvenile mussels while adults face water quality largely affected by high turbidity and high phosphate load. Restoration strategy for the Rede pearl mussel population should focus mainly on limiting sediment and nutrient input in the river throughout the catchment in order to improve habitat for juvenile pearl mussels. This work highlights the need for a catchment-based approach in order to succeed in the conservation of a fragile species.     

Spectrophotometric discrimination of river dissolved organic matter

There is a need to be able to differentiate the dissolved organic matter (DOM) fraction in river waters. Research in the 1970s and 1980s has attempted to utilize both absorbance and fluorescence to distinguish between DOM fractions in river waters, but both were limited by the available technology. Total organic carbon content has, therefore, been widely used as a standard method of measuring DOM concentration, although it has little power to differentiate DOM fractions. Recent advances in fluorescence spectrophotometry enable rapid and optically precise analysis of DOM. Here, we show how a combination of both fluorescence and absorbance can be used to discriminate statistically between spatial variations of DOM in tributaries in a small catchment of the Ouseburn, NE England. The results of the discriminant analysis suggest that about 70% of the samples can be correctly classified to its tributary. Discriminant function 1 explains 60·8% of the variance in the data and the fulvic‐like fluorescence intensity has the largest absolute correlation within this function; discriminant function 2 explains a further 21·5% of the variance and the fulvic‐like fluorescence emission wavelength has the largest absolute correlation within this function. The discriminant analysis does not correctly classify all tributaries every time, and successfully discriminates between the different tributaries 70% of the time. Occasions when the tributary waters are less well discriminated are due to either episodic pollution events (at two sites) or due to tributaries that have strong seasonal trends in spectrophotometric parameters, which allows the sites to be misclassified. Results suggest that spectrophotometric techniques have considerable potential in the discrimination of DOM in rivers. Copyright © 2002 John Wiley & Sons, Ltd.     

Spatiotemporal variation of streambed quality and fine sediment deposition in five freshwater pearl mussel streams,in relation to extreme drought,strong rain and snow melt

Oxygenated streambeds are considered a key requirement for the successful recruitment of stream fauna, including highly endangered freshwater pearl mussel Margaritifera margaritifera. Excessive amounts of fines impede exchange between open water and interstitial, leading to colmation and low oxygen levels in the juvenile habitat. Understanding the dynamic relationship between sediment delivery, transport, deposition and remobilization in relation to anthropogenic drivers is still poorly understood, yet is essential for conservation and restoration.This study analysed spatiotemporal sediment dynamics and interstitial habitat quality in five pearl mussel streams at the border region between Bavaria, Saxony and the Czech Republic during 2018 and 2019, comparing extremely dry periods with higher discharge events caused by snow melt and rainfall. Physicochemical habitat conditions within the streambed and sediment deposition were recorded in high spatial resolution along the stream courses, with a particular focus on the effects of tributaries and outflows of man-made fishponds.Habitat conditions were unsuitable for juvenile pearl mussels at the majority of sites, indicated by pronounced differences in physicochemical parameters between open water and the substrate, independent of discharge conditions. Sediment deposition varied markedly between discharge events, in terms of both the quality and quantity of deposits. Snow melt resulted in the highest sedimentation rates, but the smallest proportion of fine particles. During low flow conditions, fine sediment deposition was highly variable, ranging from 0.048 to 4.170 kg/week/m², mostly independent of flow velocity. High spatiotemporal variation was observed within and amongst stream systems, revealing different longitudinal patterns of fine sediment deposition, with catchment land use as the main driver. Temporal variability in sediment deposition was mainly associated with the discharge condition while abiotic parameters varied mainly with season.The high site-specificity of sedimentation rates and substrate conditions in response to different discharge events highlights the importance of an adapted conservation management which considers anthropogenic effects at the local scale.     

Search for hidden pearl mussel populations at the Russian section of the Baltic Sea

The freshwater pearl mussel Margaritifera margaritifera (L., 1758) is considered to be a critically endangered species. It is important to obtain information on the distribution and status of the surviving populations of the species, but in Russia this work is still problematic due to the size of the country’s territory, combined with the insufficient number of available specialists. “Searching rules” have been proposed to remotely identify potential pearl mussel habitats in rivers. The most important criteria are relating to the lakes found at the rivers’ sources, as well as to the extent of the deforestation along river basins. About 200 watercourses of the Russian section of the Baltic Sea basin were evaluated using these “rules”. As a result, two previously unknown, viable populations were discovered (comprising about 53,000 specimens), while the absence of pearl mussels was made evident among some rivers which were traditionally believed to be their habitats. The obtained data provides an update on the status of pearl mussels in Russian territories located south of the 61 st degree of latitude. There are 10 populations of this species; 4 of them are almost extinct, 6 are relatively numerous but declining. The total number of pearl mussels hardly exceeds 90,000 individuals.     

The role of floodplains in attenuating contaminated sediment fluxes in formerly mined drainage basins

Many upland river catchments in the UK have been historically mined for metals such as lead (Pb) and zinc (Zn), and as part of the mining process large quantities of metal contaminated sediment were released into the river system. The levels of sediment associated heavy metal contamination in river systems are largely controlled by the volumes of contaminated sediment released into the river and fluvial processes (e.g. erosion and deposition). As a consequence, the contamination patterns are often highly variable, which can make it difficult to create accurate assessments of the volumes of contaminated sediment remaining within the system. This paper uses a combination of techniques to establish the volumes of metal contaminated sediment remaining within the River Swale, UK. Firstly, using detailed field sampling and a geographical information system (GIS), it estimates the volumes of sediment remaining within one formerly mined tributary (Gunnerside Beck) which is then extrapolated to represent the contaminant volumes on other tributaries of the River Swale. Secondly, combining fresh field data with a range of existing data, volumes of contaminated sediment on the main stream of the River Swale are established. This two tier approach shows that significant volumes of contaminated sediment remain within the River Swale, with over 32 000 tonnes of Pb within the mined tributaries and 123 000 tonnes within the main channel belt of the River Swale itself. This represents approximately 28% of the Pb produced in the Swale catchment. Given these volumes and present day rates of removal, it may take over 5000 years for all of the metal rich sediment to be removed from the catchment. If the contaminated sediment is used as a tracer, present day rates of reworking of floodplain sediment can be calculated to be 0·02% per year. Copyright © 2008 John Wiley & Sons, Ltd.     

STATISTICAL RELATIONS BETWEEN GEOMORPHIC PARAMETERS- A CASE STUDY OF THE YUNNAN REACH OF THE LANCANGJIANG RIVER IN SOUTHWESTERN CHINA

The properties of rivers and their catchments can be expressed by statistical relationships between geomorphic parameters. These statistical relationships may reveal some inherent differences in geomorphic evolution for different reaches or different order tributaries of a river basin. A case study was undertaken of the Yunnan reach of the Langcangjiang River. The catchment area, channel length and gradient of the first-, second- and third-order tributaries all with catchment areas larger than 100 km2 in the Yunnan reach were the main geomorphic parameters evaluated. The correlation between catchment area and channel length as well as between catchment area and channel gradient with respect to the total tributaries, different reach tributaries, and different order tributaries were revealed using statistical methods. In general, the channel length as a function of catchment area, was best expressed by a quadratic function where channel length increases with increasing catchment area (half parabola), while the channel gradient as a function of catchment area is best expressed by an exponential decay function. Comparison of the best-fit formulas revealed the following phenomena: the lower Yunnan reach tributaries and the first-order tributaries have a dominant effect on geomorphic parameters of the total tributaries. In addition, the statistical relationships indicate that the river geomorphic system in the upper and lower Yunnan reaches evolved differently. This study method used to differentiate river characteristics by determining statistical relationships between geomorphic parameters may be extended to other rivers and their catchments.     

Influence of stock origin and environmental conditions on the survival and growth of juvenile freshwater pearl mussels (Margaritifera margaritifera) in a cross-exposure experiment

The freshwater pearl mussel (Margaritifera margaritifera) is a highly specialized and sensitive freshwater bivalve, whose survival in the juvenile phase is indicative of high quality habitats. This contribution investigates the use of juvenile freshwater pearl mussels as bioindicators, considering the influence of mussel stock and study stream conditions on juvenile performance, as described by survival and growth rates. A standardized cross experiment was carried out investigating juvenile performance in four different pearl mussel stocks originating from the Rhine, Danube and Elbe drainages, representing distinct genetic conservation units. The juveniles were exposed in five study streams which were selected to integrate pearl mussel streams with different water qualities and recruitment status of the mussel population. Per study stream, five standard mesh cages containing an equal number of 20 (10 × 2) juvenile pearl mussels per stock in separate chambers were installed. Survival and growth rates of juveniles were checked after three months (i.e. before their first winter) and after nine months (i.e. after their first winter). Mussel stock and study stream conditions significantly influenced juvenile performance. Growth rates were determined by study stream conditions and increased with stream water temperature, organic carbon and C/N ratios. Survival rates varied stock-specifically, indicating different levels of local adaptation to their native streams. Due to the detection of stream-specific differences in juvenile performance, freshwater pearl mussels appear suitable as bioindicators. However, a careful consideration of stock-specificity is necessary to avoid false interpretation of bioindication results. The comparison of stock-specific survival in native versus non-native streams implicates that exposure of juveniles outside their native habitats is able to increase breeding success or else serve for risk spreading in breeding programs.     

Estimating daily inflows of large lakes using a water‐balance‐based runoff coefficient scaling approach

Daily river inflow time series are highly valuable for water resources and water environment management of large lakes. However, the availability of continuous inflow data for large lakes is still relatively limited, especially for large lakes situated within humid plain regions with tens or even hundreds of tributaries. In this study, we choose the fifth largest freshwater Lake Chaohu in China as our study area to introduce a new approach to reconstruct historical daily inflows at ungauged subcatchments of large lakes. This approach makes use of water level, lake surface rainfall, evaporation from the lake, and catchment rainfall observations. Rainfall–runoff relationship at a reference catchment was analysed to select rainfall input and estimate run‐off coefficient firstly, and the run‐off coefficient was then transferred to ungauged subcatchments to initially estimate daily inflows. Run‐off coefficient was scaled to adjust daily inflows at ungauged subcatchments according to water balance of the lake. This approach was evaluated using sparsely measured inflows at eight subcatchments of Lake Chaohu and compared with the commonly used drainage area ratio method. Results suggest that the inflow time series reconstructed from this approach consistent well to corresponding observations, with mean R² and Nash–Sutcliffe efficiency values of 0.69 and 0.6, respectively. This approach outperforms drainage area ratio method in terms of mean R² and Nash–Sutcliffe efficiency values. Accuracy of this approach holds well when the number of water‐level station being used decreased from four to one.     

Insights into agricultural influences and weathering processes from major ion patterns

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.     

The status of freshwater pearl mussel in the Czech Republic: Several successfully rejuvenated populations but the absence of natural reproduction

The freshwater pearl mussel was historically abundant in many streams and rivers in the Elbe, Oder, and Danube Basins in the Czech Republic, Central Europe. By the 21st century, the mussels had become extinct in the lower and middle altitudes, and current populations are only present near the upper limit of their natural range. The current population of this mussel is estimated to be only 1% of the historical abundance. The population decline was related to the negative impacts of pollution from industry, intense agriculture, forestry, and sewage water. The freshwater pearl mussel habitat has also been impacted by watercourse regulations and has been fragmented by dams and weirs. All of these impacts have resulted in failure of the reproductive cycle; the last significant cohort of juveniles settled approximately 30 – 40 years ago. Therefore, this species is considered critically endangered, and an action plan was developed to conserve the populations in the Czech Republic. Special measures were conducted between 1984 and 2005 to improve the age structure of elderly populations. Fish infected with millions of glochidia were released in two locations, and over 53,000 captive-bred juveniles that were three to five years old were released in seven locations. Only the latter approach resulted in a small number of subadults that gradually emerged from the substratum to the bottom surface, as confirmed by monitoring efforts. Despite simultaneous efforts to restore mussel habitat over the last 25 years, natural reproduction still does not occur in the Czech Republic. Therefore, complete restoration of oligotrophic streams is the key to the future presence and natural reproduction of freshwater pearl mussels in the Czech Republic.     

Sedimentologically significant tributaries: catchment‐scale controls on sediment (dis)connectivity in the Lockyer Valley,SEQ, Australia

The nature of catchment‐scale sediment (dis)connectivity is the primary influence on sediment delivery to trunk streams and controls the particle size distribution of channel bed sediments. Here, we examine the distribution of major sediment buffers (floodplains, terraces, alluvial fans, trapped tributary fills), barriers (weirs), and effective catchment area (i.e. sediment contributing area) to characterize the potential for coarse sediment (dis)connectivity in 20 tributaries of Lockyer Creek, in the Lockyer Valley, SEQ. We then analyse the distribution of trunk stream sedimentary links to determine how certain tributaries or disconnecting features (buffers and barriers) influence downstream patterns of bed sediment fining along Lockyer Creek. We find that buffering increases downstream in the Lockyer Valley, and that tributary position and shape influence the space available for sediment buffering. Correspondingly, the spatial extent of sediment buffers impacts the distribution of effective catchment area, which influences the sedimentological significance of individual tributaries. Tributary sediment connectivity, the extent of overbank flows (floodwater zones), and weir locations all exert an additional influence on the distribution of sediment links along the trunk stream. These controls are related to the physiographic and climatic setting of the Lockyer Valley, and anthropogenic influences in this system. We conclude that controls on sediment connectivity and bed load sediment characteristics are highly variable between catchments, and that sediment (dis)connectivity merits equal consideration with tributary basin/channel size when determining controls on tributary–trunk stream relationships and channel sediment regime. Copyright © 2017 John Wiley & Sons, Ltd.     

The role of landscape setting in minimizing hydrogeomorphic impacts of flow regulation

The Tongariro Power Development Scheme (TPDS) is used to regulate flow in the headwaters of the largest catchment on the North Island of New Zealand (the Waikato). Two small dams, the Rangipo Dam and the Poutu Intake Dam, were constructed in 1973 and 1983. The flow regime of the river is managed to divert freshes into the power scheme, but allows flows larger than 100 m³ s^?1 to be released, to rework and transport sediment through the catchment. Analysis of aerial photos and maps spanning 1928 to 2007, alongside field measurements, show that there have been few hydrogeomorphic adjustments since dam construction. This includes limited changes to channel geometry, channel planform and bed material organization immediately downstream of the dams. In addition, offsite effects are minimal, both 500 m downstream of each dam, and in the more sensitive, less confined reaches in the lower catchment (11 km downstream of the Poutu Intake dam). The limited changes can be attributed to the locations of the dams within reaches characterised by bedrock gorges and confined within terraces. These locations act to flush sediments and impose margins that allow minimal adjustment of the channel. Bed material within this reach is characterised by the presence of a boulder lag. This is sourced from long-term incision into lahar deposits, and acts to limit the rate of incision, creating a steep and stable base upon which active fractions are transported. Just as importantly, significant storage in the low-relief volcanic plateau located in the upper catchment acts to disconnect and store the high sediment yields generated by active volcanic cones in the western sub-catchment upstream of the dams. This limits the rate of sediment supply to regulated reaches. Findings from this study show that analysis of reach-scale controls is essential in framing dam site locations in relation to the distribution of reaches and landscape units across the catchment. In this instance, tributary inputs downstream of the dams do not replenish the sediment and flow removed at the dam locations, as has been observed in other regulated systems. Rather, the river itself is resilient to change and flow variability is well managed allowing geomorphically effective floods to occur. Landscape setting is a key consideration in determining the hydrogeomorphic impact of flow regulation.     

Geospatial Investigation into Groundwater Pollution and Water Quality Supported by Satellite Data: A Case Study from the Evros River (Eastern Mediterranean)

Managing water resources, in terms of both quality and quantity, in transboundary rivers is a difficult and challenging task that requires efficient cross-border cooperation and transparency. Groundwater pollution risk assessment and mapping techniques over the full catchment area are important tools that could be used as part of these water resource management efforts, to estimate pollution pressures and optimize land planning processes. The Evros river catchment is the second largest river in Eastern Europe and sustains a population of 3.6 million people in three different countries (Bulgaria, Turkey and Greece). This study provides detailed information on the main pollution sources and pressures in the Evros catchment and, for the first time, applies, assesses and evaluates a groundwater pollution risk mapping technique using satellite observations (Landsat NDVI) and an extensive dataset of field measurements covering different seasons and multiple years. We found that approximately 40 % of the Greek part of the Evros catchment is characterized as of high and very high pollution risk, while 14 % of the study area is classified as of moderate risk. Both the modeled and measured water quality status of the river showed large spatiotemporal variations consistent with the strong anthropogenic pressures in this system, especially on the northern and central segments of the catchment. The pollutants identified illustrate inputs of agrochemicals and urban wastes in the river. High correlation coefficients (R between 0.79 and 0.85) were found between estimated pollution risks and measured concentrations of those chemical parameters that are mainly attributed to anthropogenic activities rather than in situ biogeochemical processes. The pollution risk method described here could be used elsewhere as a decision support tool for mitigating the impact of hazardous human activities and improving management of groundwater resources.     

Modelling sediment (dis)connectivity across a river network to understand locational-transmission-filter sensitivity for identifying hotspots of potential geomorphic adjustment

Rivers act as ‘jerky conveyor belts’ that transmit fluxes of flow and sediment downstream. This transmission of fluxes can be highly variable within a drainage basin resulting in either abrupt or gradational sediment (dis)connectivity patterns and processes. This study assesses sediment (dis)connectivity across a basin as a means to understand the locational, transmission and filter sensitivity properties of a fluvial system. Drawing upon the case study of Richmond River Catchment, New South Wales, Australia we use the concepts of effective catchment area and buffers, along with graph theory and an empirical sediment transport model CASCADE (Catchment Sediment Connectivity and Delivery), to assess (1) the degree to which modelled sediment cascades along the river network are connected or disconnected (2) how the position, pattern and configuration of (dis)connection facilitates or restricts geomorphic adjustment in different parts of a catchment, and (3) use the findings as a basis to explain the locational-transmission-filter sensitivity of the catchment. We use this analysis to segregate supply limited and transport limited reaches and identify various controls on sediment dynamics: in-stream sediment storage units, junctions between different geomorphic river types, tributary confluences and sediment storage units within partly confined floodplain units. Such analysis lays the foundation for network scale identification of potential hotspots of geomorphic adjustment.     

Annual estimates of water and solute export from 42 tributaries to the Yukon River

Annual export of 11 major and trace solutes for the Yukon River is found to be accurately determined based on summing 42 tributary contributions. These findings provide the first published estimates of tributary specific distribution of solutes within the Yukon River basin. First, we show that annual discharge of the Yukon River can be computed by summing calculated annual discharges from 42 tributaries. Annual discharge for the tributaries is calculated from the basin area and average annual precipitation over that area using a previously published regional regression equation. Based on tributary inputs, we estimate an average annual discharge for the Yukon River of 210 km³ year^–1. This value is within 1% of the average measured annual discharge at the U.S. Geological Survey gaging station near the river terminus at Pilot Station, AK, for water years 2001 through 2005. Next, annual loads for 11 solutes are determined by combining annual discharge with point measurements of solute concentrations in tributary river water. Based on the sum of solutes in tributary water, we find that the Yukon River discharges approximately 33 million metric tons of dissolved solids each year at Pilot Station. Discharged solutes are dominated by cations calcium and magnesium (5.65 × 10⁹ and 1.42 × 10⁹ g year^–1) and anions bicarbonate and sulphate (17.3 × 10⁹ and 5.40 × 10⁹ g year^–1). These loads compare well with loads calculated independently at the three continuous gaging stations along the Yukon River. These findings show how annual solute yields vary throughout a major subarctic river basin and that accurate estimates of total river export can be determined from calculated tributary contributions. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA.     

End member and Bayesian mixing models consistently indicate near-surface flowpath dominance in a pristine humid tropical rainforest

The impacts of forest conversion on runoff generation in the tropics have received much interest, but scientific progress is still hampered by challenging fieldwork conditions and limited knowledge about runoff mechanisms. Here, we assessed the runoff generation, flow paths and water source dynamics of a pristine rainforest catchment in Costa Rica using end member mixing analysis (EMMA) and a Bayesian mixing model (MixSIAR). Geochemical tracer data collected over a 4-week field campaign were combined with tritium data used to assess potential deeper groundwater flow pathways to the perennial stream. The streamflow composition was best captured using three end-members, namely throughfall, shallow (5–15 cm) and deeper (15–50 cm) soil water. We estimated the end-member contributions to the main stream and two tributaries using the two mixing approaches and found good agreement between results obtained from EMMA and MixSIAR. The system was overwhelmingly dominated by near-surface sources, with little evidence for deeper and older groundwater as tritium-derived baseflow mean transit time was between 2.0 and 4.4 years. The shallow soil flow pathway dominated streamflow contributions in the main stream (median 39% and 49% based on EMMA and MixSIAR, respectively), followed by the deeper soil (32% and 31%) and throughfall (25% and 19%). The two tributaries had even greater shallow soil water contributions relative to the main stream (83% and 74% for tributary A and 42% and 63% for tributary B). Tributary B had no detectable deep soil water contribution, reflecting the morphology of the hillslope (steeper slopes, shallower soils and lower vegetation density compared to hillslope A). Despite the short sampling campaign and associated uncertainties, this study allowed to thoroughly assess runoff generation mechanisms in a humid tropical catchment. Our results also provide a first comparison of two increasingly used mixing models and suggest that EMMA and MixSIAR yield comparable estimates of water source partitioning in this tropical, volcanic rainforest environment.     

Influence of storm-related sediment storage on the sediment delivery from tributary catchments in the upper Waipaoa River,New Zealand

Although much is known about overall sediment delivery ratios for catchments as components of sediment production and sediment yield, little is known about the component of temporary sediment storage. Sediment delivery ratios focused on the influence of storm-related sediment storage are measured at Matakonekone and Oil Springs tributaries of the Waipaoa River basin, east coast of New Zealand. The terrace deposits of both tributaries show abundant evidence of storm-related sedimentation, especially sediment delivered from Cyclone Bola, a 50 year return rainfall event which occurred in 1988. The sediment delivery ratio is calculated by dividing the volume of sediment transported from a tributary to the main stream by the volume of sediment generated at erosion sites in the tributary catchment. Because the sediment delivery volume is unknown, it can be calculated as the difference between sediment generation volume and sediment storage volume in the channel reach of the tributary. The volume of sediment generated from erosion sites in each tributary catchment was calculated from measurements made on aerial photographs dating from 1960 (1:44 000) and 1988 (1:27 000). The volume of sediment stored in the tributary can be calculated from measurements of cross-sections located along the tributary channel, which are accompanied by terrace deposits dated by counting annual growth rings of trees on terrace surfaces. Sediment delivery ratios are 0·93 for both Matakonekone catchment and Oil Springs catchment. Results indicate that Oil Springs catchment has contributed more than twice the volume of sediment to the Waipaoa River than the Matakonekone catchment (2·75 × 10⁶ m³ vs 1·22 × 10⁶ m³). Although large volumes of sediment are initially deposited during floods, subsequent smaller flows scour away much of these deposits. The sediment scouring rate from storage is 1·25 × 10⁴ m³ a⁻¹ for Matakonekone stream and 0·83 × 10⁴ m³ a⁻¹ for Oil Springs stream. Matakonekone and Oil Springs channels respond to extreme storms by instantaneously aggrading, then gradually excavating the temporarily stored sediment. Results from Matakonekone and Oil Springs streams suggest a mechanism by which event recurrence interval can strongly influence the magnitude of a geomorphic change. Matakonekone stream with its higher stream power is expected to excavate sediment deposits more rapidly and allow more rapid re-establishment of storage capacity. Copyright © 1999 John Wiley & Sons, Ltd.     

Impact of deforestation on pearl mussel habitats in the Russian section of the Baltic Sea basin

Changes in the vegetation cover associated with intensive forest extermination may have a strong effect on the riverine environment, including the chances of survival for bivalve mollusc populations in small streams and rivers. In order to check this hypothesis, drainage area properties of the rivers with extinct and existing pearl mussel populations in the Russian section of the Baltic Sea basin were compared. Preservation of forest vegetation along the river banks of the studied rivers was correlated with the presence of pearl mussel populations. Traditional agriculture turned out to be, in some cases, more harmful for river ecosystems than urbanization and industrialization.     

Weathering,Sr fluxes,and controls on water chemistry in the Lake Qinghai catchment,NE Tibetan Plateau

Strontium (Sr) concentrations and isotopic ratios have been measured in a series of water and rock samples from most of the major tributaries of the Lake Qinghai basin on the north‐eastern Tibetan Plateau. Dissolved Sr and ⁸⁷Sr/⁸⁶Sr show ranges of 488–12 240 nmol/l and 0·710497–0·716977, respectively. These data, together with measurements of major cations and anions in rivers and their tributaries and various lithologies of the catchment, were used to determine the contributions of Sr and its isotopic expense to rivers and lakes. Our results demonstrate that the chemical components and ⁸⁷Sr/⁸⁶Sr ratios of the alkaline waters are derived from mixing of carbonate and silicate sources, with the former contributing 72 ± 18% dissolved Sr to rivers. The difference in tributary compositions stems from the lithology of different river systems and low weathering intensity under a semi‐arid condition. Variation in ⁸⁷Sr/⁸⁶Sr ratios places constraint on the Sr‐isotopic compositions of the main tributaries surrounding Lake Qinghai. The water chemistry of the Buha River, the largest river within the catchment underlain by the late Paleozoic marine limestone and sandstones, dominates Sr isotopic composition of the lake water, being buffered by the waters from the other rivers and probably by groundwater. However, the characteristic chemical composition of the lake itself differs remarkably from the rivers, which can be attributed to precipitation of authigenic carbonates (low‐magnesium calcite, aragonite, and dolomite), though this does not impact the Sr isotope signature, which may remain a faithful indicator in paleo‐records. Regarding the potential role of groundwater input within the Lake Qinghai systems in the water budget and water chemistry, we have also determined the Sr concentration and ⁸⁷Sr/^S6Sr ratio of groundwater from diverse environments. This has allowed us to further constrain the Sr isotope systematic of this source. A steady‐state calculation gives an estimate for the groundwater flux of 0·19 ± 0·03 × 10⁸ m³/yr, accounting for about 8% of contemporary lake Sr budget. Copyright © 2010 John Wiley & Sons, Ltd.     

Spatial–temporal variability in water quality and macro-invertebrate assemblages in the Upper Mara River basin,Kenya

Tropical rivers display profound temporal and spatial heterogeneity in terms of environmental conditions. This aspect needs to be considered when designing a monitoring program for water quality in rivers. Therefore, the physico-chemical composition and the nutrient loading of the Upper Mara River and its two main tributaries, the Amala and Nyangores were monitored. Initial daily, and later a weekly monitoring schedule for 4 months spanning through the wet and dry seasons was adopted. Benthic macro-invertebrates were also collected during the initial sampling to be used as indicators of water quality. The aim of the current study was to investigate the physico-chemical status and biological integrity of the Upper Mara River basin. This was achieved by examining trends in nutrient concentrations and analyzing the structure, diversity and abundance of benthic macro-invertebrates in relation to varying land use patterns. Sampling sites were selected based on catchment land use and the level of human disturbance, and using historical records of previous water quality studies. River water pH, dissolved oxygen, electrical conductivity (EC), temperature, and turbidity were determined in situ. All investigated parameters except iron and manganese had concentration values within allowable limits according to Kenyan and international standards for drinking water. The Amala tributary is more mineralized and also shows higher levels of pH and EC than water from the Nyangores tributary. The latter, however, has a higher variability in both the total phosphorus (TP) and total nitrogen (TN) concentrations. The variability in TP and TN concentrations increases downstream for both tributaries and is more pronounced for TN than for TP. Macro-invertebrate assemblages responded to the changes in land use and water quality in terms of community composition and diversity. The study recommends detailed continuous monitoring of the water quality at shorter time intervals and to identify key macro-invertebrate taxa that can be used to monitor changes of the water quality in rivers of the Mara basin as a result of anthropogenic changes.