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1.
The carbon isotopic composition of organic matter from lake sediments has been extensively used to infer variations in productivity. In this paper, based on the study of the contents and δ13C values of organic matter in different types of lakes, it has been found that δ13C values of organic matter have different responses to lake productivity in different lakes. As to the lakes dominated by aqutic macrophytes such as Lake Caohai, organic matter becomes enriched in 13C with increasing productivity. As to the lakes dominated by aquatic algae such as Lake Chenghai, δ13C values of organic matter decrease with increasing productivity, and the degradation of aquatic algae is the main factor leading to the decrease of δ13C values of organic matter with increasing productivity. Therefore, we should be cautious to use the carbon isotopic composition of organic matter to deduce lake productivity.  相似文献   

2.
The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results, sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical equilibrium. Thermal waters in the area are characterized by Na+–Cl–HCO3, while the cold waters by CaHCO3 facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ18O and δ2H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8 to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs water quality in terms of irrigation purposes in shallow groundwaters, such as Na+, B, and Cl, are highy probably expected to increase in time.  相似文献   

3.
Sediment cores were collected from deep-water areas of Lake Chenghai, China in June 1997. The vertical profile of 137Cs activity gives reliable geochronological results. The results also indicate that sediment accumulation rates in deep-water areas of Lake Chenghai were relatively constant in recent decades, averaging 0.43 g cm− 2 y− 1, despite a variable organic carbon influx. 210Pbeq (= 226Ra) activity was relatively constant also, with an average value of 54.3 ± 3.2 Bq kg− 1. Vertical profiles of 210Pbex (= 210Pbtotal − 226Ra) decreased exponentially, resulting in somewhat lower sediment accumulation rates (0.3 g cm− 2 y− 1). These lower rates are likely less reliable, as the relatively large fluctuations in 210Pbex activities correlate closely to the organic carbon (Corg) content of the sediments. For example, the vertical profile of 210Pbex activity displays peaks at mass depths of 3.7-4.7 g cm− 2 (10-12 cm) and 10-11 g cm− 2(25-28 cm), similar to the maxima in the vertical profile of Corg. This phenomenon must be related to the delivery of particulate organic matter (POM) from the water to the sediments, or to watershed soil erosion. Since the mean atomic ratios of Horg / Corg and Corg / Norg in Lake Chenghai sediments are 5.5 and 7.0, respectively, indicating that POM was predominantly derived from the remains of authigenic algae, this eliminates watershed erosion rates as a primary control on lake sedimentation rates as resolved by 210Pbex. Sedimentation fluxes (F(Corg)) of particulate organic carbon since 1970 varied between 60 to 160 g m− 2 y− 1, and appeared to closely influence variations in 210Pbex concentrations. For example, sedimentation fluxes of 210Pbex (F(210Pbex)) showed maxima in the years 1972-1974 and 1986-1989, likely reflecting historical variations of lake biological productivity or carbon preservation.  相似文献   

4.
太湖北部底泥中氮、磷的空间变化和环境意义   总被引:34,自引:5,他引:34  
以太湖底泥为研究对象,通过分析不同形态N,P的含量,揭示太湖北部底泥N,P的区域和垂向变化特征,探讨了主要营养元素的环境意义。太湖北部底泥N,P的高值区分布在五里湖,梅梁湾北部和竺山湖北部,有效氮的分布与总氮的分布一致。相关分析表明,有效磷与无机磷具有很好的正相关性,N,P的含量还与粘土矿物的含量成正比。柱状样的N,P垂直变化显示,数千年人类的活动并未明显影响底泥中N,P的含量,而在近代则明显增加。底泥中大量的N,P主要来自生活污水,其次是农田肥料和围网养殖。  相似文献   

5.

湖泊沉积物Rb/Sr比值通常被视为流域化学风化强度的代用指标, 然而不同湖泊沉积物Rb/Sr比值的古气候意义有时也存在一定差异。本研究以六盘山朝那湫湖泊73cm长度(1743~2012A.D.的沉积序列)岩芯沉积物Rb/Sr比值为分析对象, 结合同一岩芯其他主要元素以及古气候代用指标(TOC、C/N比值、δ13Corg等)指示的环境变化信息, 对朝那湫湖泊沉积物Rb/Sr比值在十年/数十年尺度上的古气候意义进行综合判别。研究结果显示: 朝那湫湖泊沉积物中的Rb、Sr元素主要以残渣态赋存, Rb/Sr比值与其他陆源组分元素有较好的相关性, Rb/Sr比值变化主要受控于陆源碎屑物质输入。Rb/Sr比值与同一岩芯TOC、C/N比值、δ13Corg等降水代用指标以及邻近区域树轮等古气候记录的对比结果表明: 在十年/数十年尺度上, 气候偏干期, 陆源碎屑物质输入较多, 沉积物Rb/Sr比值减小; 气候偏湿期, 陆源碎屑物质输入较少, 沉积物Rb/Sr比值增大。这主要是由朝那湫流域降水特点和植被覆盖共同决定的, 同时也暗示朝那湫流域物理风化和化学风化强度可能呈反向变化。因此, 在将Rb/Sr比值作为流域化学风化强度的代用指标之前, 有必要对湖泊沉积物的Rb、Sr元素的赋存形态进行辨别, 并结合湖泊自身沉积环境以及其他古气候指标进行综合分析, 方可获得更加全面准确的流域物理侵蚀搬运或化学风化信息。

  相似文献   

6.
The sediments in Lake Huguang Maar in coastal South China were previously thought to originate mainly from wind-blown dust transported from North China, such that the lake sediments recorded the varying strength of the Asian winter monsoon. An alternative explanation was that the local pyroclastic rocks supplied the lake sediments, but the actual contributions from the different sources remained unclear. Geochemical analyses including 87Sr/86Sr and 143Nd/144Nd and trace elements support the local pyroclastic rock as the dominant source: < 22% of the total Sr in the lake sediments and  17% of the Nd arises from the distant source. Nb/Ta and Zr/Hf for the lake sediments are identical to those for the local rock but differ from the ratios for the wind-blown dust, and chondrite-normalized rare earth element patterns for the lake sediments are similar to those for the local rock and soil, but differ from those for the distant source. The sediments in Lake Huguang Maar are probably input into the lake through runoff and thus controlled by the hydrology of the lake. Wind-blown dust transported by the Asian winter monsoon from arid North China is only a minor contribution to the sediments.  相似文献   

7.
Caliche is a fairly widespread pedogenic carbonate that commonly has been used to reconstruct palaeoclimatological conditions. Stable isotopic analyses of three types of caliche nodules from Mission Bay, Texas, provide insights into the values and limitations in palaeoenvironmental interpretations. Soft incipient nodules (type I) and partially lithified chalky nodules (type II), composed of low Mg‐calcite, are in situ pedogenic products in the late Quaternary soils; they represent young to intermediate caliche nodules with no obvious diagenesis and, with constraints, can be used to investigate palaeoenvironmental conditions. The well‐lithified hard nodules (type III) dispersed on the beach and shallow bay exhibit complex shapes, fabrics, mineralogy and geochemical compositions. They are mature nodules that have undergone substantial diagenesis and, therefore, are believed to have lost their initial environmental signatures. The incipient nodules in the presently active grey soil and the older subjacent brown soil display significantly different δ13C values, ?8·4 and ?4·4‰, respectively, which indicates a change in palaeovegetation from C3/C4 mixed to C3‐dominated flora. The δ13C values probably reflect a marked climate shift from warm and dry to cool and wet conditions in the middle Holocene. However, in the same grey soil, there is a sub‐set of incipient caliche nodules with δ13C values around 0·1‰, which is probably due to the input of localized carbon sources in the soil (e.g. shell fragments). The occurrence of essentially identical nodules appearing from the same modern soil horizon with significantly different δ13C values questions the universal reliability of this type of data for palaeoenvironmental interpretation. This study demonstrates that, whereas the stable isotopic compositions of caliche nodules can be used for palaeoenvironmental reconstruction, diagenesis and the influence of localized carbonate sources in the soils could lead to erroneous interpretations.  相似文献   

8.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite and quartz veins. The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock, alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite, volcanic tuff, phosphatic rock and chert breccia. The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon.  相似文献   

9.
On the basis of different photosynthetic pathways.there is an obvious difference in δ^13C values between C3 and C4 plants,In terms of this characteristic,we analyzed the organic carbon content (forestlands:1.81%-16.00%;farmland:0.45%-2.22%) and δ^13C values(forestlands:-23.86‰--27.12‰;farmland:-19.66‰--23.26‰)of three profile-soil samples either in farmland or in forestland near the Maolan Karst virgin forest,where there were developed plant C3 plants previously and now are C4 plants.Results showed that the deforestation has accelerated the decomposition rate of soil organic matter and reduced the proportion of active components in soil organic matter and thus soil fertility.  相似文献   

10.
This article presents the results of a geochemical investigation of sediments from Lake Druzno (northern Poland), a reservoir fed by freshwater from the catchment, with periodic input of brackish water from Vistula Lagoon. This study analyzed the spatial variation in heavy metal content in surface sediments as well as the temporal changes in metal content in two sediment cores dated using the 210Pb method. In the surface sediments, the highest metal concentrations were recorded in the northern part of the lake, with lower concentrations in the central and southern parts. Absolute values of metal concentrations in the cores were low, but normalization with respect to Al showed an increase during the second half of the 20th century. Mean enrichment factors (EF) in sediments from the second half of the 20th century ranged from insignificant (1–1.2) for Fe to (1.55–3.3) for Cu, Cd, Pb and Zn. The sediments deposited before 1950 had lower EF values (>1.5) and had low variability. Results from both the surface sediments and the cores indicate that the main source of lake pollution is brackish water intrusion from the Vistula Lagoon via the contaminated River Elbląg.  相似文献   

11.
Enriched13C/12C ratios with δ13C ∼3%0 (w.r.t PDB) of two Late Riphean (∼ 700-610 Ma) intracratonic carbonate successions viz., Bhander Limestone of Vindhyan Basin and Raipur Limestone of Chattisgarh Basin suggest higher organic productivity during this period. This view is supported by sedimentological evidence of higher biohermal growth and consequent increase in depositional relief in the low gradient ramp settings inferred for these basins. Oxygen isotope analysis of these carbonates show distinct segregation between enriched deeper water carbonate mudstone and depleted shallow water stromatolite facies that received fresh water influx. This shows that facies-specific analyses can be useful in understanding the depositional setting of these sediments.  相似文献   

12.
Glacial deposits occurring close to the Vendian-Cambrian boundary were discovered long ago in several regions of Asia and West Africa. New data of recent years confirm earlier observation and specify age constraints of these deposits. In certain sections, glacial sediments rest on beds with the Upper Vendian fossils (Vendotaenia sp., Sabellidites remains, and microfossils). In the Hoggar Highland, they discordantly overlie magmatic rocks ca. 560 Ma old. In the East Sayan Mts., the Upper Vendian Cloudina sp. have been found in the diamictite matrix. In Central Asia and Northwest China, cap dolomites conformably overlying glacial deposits grade upward into the chert-phosphatic sediments containing fossils (Tarim region), which are characteristic of the Anabarites trisulcatus Zone in the Nemakit-Daldynian Stage. Fossils of this zone have been found directly above glacial deposits in the East Sayan. According to all these data, the respective Baykonurian glaciation, as it is termed in this work, either antedated the Nemakit-Daldynian Age or was concurrent to its commencement. The glaciation is correlative with a significant negative δ13C excursion of ?5 to ?10‰. Judging from recent paleotectonic reconstructions, the Baykonurian glaciation was not regional in rank and left records in both hemispheres of the Earth. This glaciation resumes the well-known succession of the great glaciation event in the terminal Late Precambrian, i.e., the Sturtian, Marinoan, and Gaskiers glaciations. Hence, one cannot ignore the Baykonurian glaciation when analyzing the geological, biospheric, and biotic history of the Late Precambrian.  相似文献   

13.
Lipids extracted from lacustrine deposits in the paleolake Qarhan of the Qaidam basin in the northeastern Tibetan Plateau were determined by conventional gas chromatography-mass spectrometry. Several series of biomarkers were identified, mainly including n-alkanes, n-alkan-2-ones, n-alkanoic acids, branched alkanes, triterpenoids and steroids, indicative of various biogenic contributions. On the basis of cluster analysis, the n-C15, n-C17, n-C19 alkanes were proposed to be derived from algae and/or photosynthetic bacteria, the n-C21, n-C23, n-C25 homologues from aquatic plants, and the n-C29, n-C31 homologues from vascular plants. In contrast, the n-C27 alkane is not categorized in the n-C29 and n-C31 group of alkanes, probably due to more complex origins including both aquatic and vascular plants, and/or differential biodegradation. Stratigraphically, layers-2, 4 and 5 were found to show a close relationship in n-alkane distribution, associated with a positive shift in carbon isotope composition of bulk organic matter (δ13Corg), inferring a cold/dry period. Layers-1 and 6 were clustered together in association with a negative δ13Corg, excursion, probably indicating a relatively warm/humid climate. The potential coupling between the n-alkane distributions and δ13Corg, suggests a consequence of vegetation change in response to climate change, with the late MIS3 being shown to be unstable, thought to be the climatic optimum in the Tibetan Plateau. Our results suggest that the cluster analysis used in this study probably provides an effective and authentic method to investigate the n-alkane distribution in paleolake sediments.  相似文献   

14.
杭州西湖与运河沉积物铅同位素组成及其示踪意义   总被引:8,自引:0,他引:8  
西湖底部表层沉积淤泥与沉积柱中沉积物的铅同位素组成存在明显的差异。沉积柱中206Pb/207Pb=1.1906±0.0029(2σ),208Pb/206Pb=2.0858±0.0074(2σ),而表层沉积淤泥的206Pb/207Pb=1.1705~1.1726,208Pb/206Pb=2.1052~2.1069,存在明显的异常。沉积柱中铅同位素组成演变特征表明,西湖沉积柱的上部受到了现代人为的铅污染,污染物厚度35cm左右,其中顶部10cm污染较为严重。与杭州市有关环境样品的铅同位素背景对比表明,西湖的铅污染主要来源于汽车尾气排放铅。运河(杭州段)0~30cm的沉积柱中除个别样品外,206Pb/207Pb=1.1543~1.1705,208Pb/206Pb=2.1011~2.1540,与西湖沉积柱下部沉积物中的铅同位素组成明显不同,而与西湖表层沉积淤泥的铅同位素组成一致,这表明运河沉积物存在显著的铅污染。对比表明,运河铅污染也主要来自汽车尾气,同时煤铅可能也有一定的贡献。根据西湖沉积柱中铅污染的深度与平均沉积速率估计,杭州地区的铅污染开始于1910年代,但到1970年代铅污染明显加剧。  相似文献   

15.
The relationship between the variation of δ 18O in precipitation in Yarlungzangbo River basin and the moisture flux was analyzed with NCEP/NCAR reanalysis grid data and δ 18O in precipitation at four stations (Lazi, Nugesha, Yangcun and Nuxia) of the region investigated. In terms of spatial variations, there is obviously a positive correlation between them for the entire basin. With the decrease in moisture flux from the downstream to the upstream area, δ 18O in precipitation became gradually decreased. However, in terms of temporal variations, higher δ 18O in precipitation during spring is linked to small moisture flux while low δ 18O in precipitation during summer is linked to large moisture flux. A model involving meteorological data from NCEP/NCAR was subsequently set up which successfully traced the moisture transport trajectories at Yangcun station. Based on the traced moisture transport trajectories and the δ 18O in precipitation at Yangcun station, the relationship between δ18O in precipitation in Yarlungzangbo River basin and the moisture transport history was discussed. We found that the humid marine air mass from the Indian Ocean in general has significantly lower δ 18O values than the continental air mass from the north or local re-evaporation. The fluctuation of δ 18O in precipitation during the monsoon season is very pronounced; the lower values are usually related to farther distance and multilayer moisture transport, as well as moisture crossing the Himalaya Mountains. __________ Translated from Advances in Earth Science, 2007, 22(8): 842–850 [译自: 地球科学进展]  相似文献   

16.
1IntroductionSoilorganicmatter (SOM)isakeysourceofnutrientsforplantgrowth ,itisessentialforthemaintenanceofsoilstructureanditcontributestotheabilityofsoiltoretainnutrientsandwater.AnimprovedunderstandingofSOMdynamicsiscentraltothedevelopmentofmoreenvironmentallysoundandsustainablepracticesofagriculturalmanagement (Collinsetal.,2 0 0 0 ) .Avarietyofcon ceptualmethodshavebeenusedtodescribetheprocessesofSOMaccumulationandturnover (Jen kinsonandRayner,1 977;Duxburyetal.1 989;Partonetal.,1 99…  相似文献   

17.
Uranium-series dating of oxygen and carbon isotope records for stalagmite SJ3 collected in Songjia Cave, central China, shows significant variation in past climate and environment during the period 20-10 ka. Stalagmite SJ3 is located more than 1000 km inland of the coastal Hulu Cave in East China and more than 700 km north of the Dongge Cave in Southwest China and, despite minor differences, displays a clear first-order similarity with the Hulu and Dongge records. The coldest climatic phase since the Last Glacial Maximum, which is associated with the Heinrich Event 1 in the North Atlantic region, was clearly recorded in SJ3 between 17.6 and 14.5 ka, in good agreement in timing, duration and extent with the records from Hulu and Dongge caves and the Greenland ice core. The results indicate that there have been synchronous and significant climatic changes across monsoonal China and strong teleconnections between the North Atlantic and East Asia regions during the period 20-10 ka. This is much different from the Holocene Optimum which shows a time shift of more than several thousands years from southeast coastal to inland China. It is likely that temperature change at northern high latitudes during glacial periods exerts stronger influence on the Asian summer monsoon relative to insolation and appears to be capable of perturbing large-scale atmospheric/oceanic circulation patterns in the Northern Hemisphere and thus monsoonal rainfall and paleovegetation in East Asia. Climatic signals in the North Atlantic region propagate rapidly to East Asia during glacial periods by influencing the winter land-sea temperature contrast in the East Asian monsoon region.  相似文献   

18.
沾化凹陷新近系馆陶组(Ng)广泛发育了一陆相螺化石层.来自螺化石层上下沉积层位的馆陶组和明化镇组(Nm)泥灰岩的C、O、Sr、Nd同位素的分析结果显示,螺化石层所在Ng4段泥灰岩具有比其上下部泥灰岩较低的δ13C值和较高的δ18O值,而螺化石埋藏层位的泥灰岩具有相对较低的δ13C和87Sr/86Sr值以及相对较高的δ18O值.143Nd/144Nd比值在剖面上的变化不明显,反映Ng、Nm沉积时期凹陷具有稳定的物源区;而C、O、Sr同位素组成的系统变化则指示了古沉积环境的变化.其中Ng4段沉积时期气候相对干热,Ng3、Nm1 2段沉积时期气候相对湿热;螺化石层泥灰岩所表现出的低87Sr/86Sr值和螺化石壳体相对高的δ13C和δ18O值可能代表了区域上一次重要的气候干热化事件,该时期大气降水明显减少,湖泊蒸发量较大,使得盆地的水体盐度增加,水体中87Sr/86Sr降低和δ18O值增加,同时水体营养生物和河流输入的营养物质减少,致使田螺最终死亡.随后环境气候相对湿热,生物生产力提高和碎屑物质供应的增加使得87Sr/86Sr值和δ13C值增加,大气降水补给导致沉积介质的δ18O值降低.  相似文献   

19.
This paper attempts at full characterization of the unique global 8.2 Kyr B.P. cooling event. Significant atmospheric cooling started during 9.5–8.5 Kyr B.P. when the Sun was extremely quiet during three periods of ∼ 50–100 years. The flood of melt water in the N. Atlantic from glacial lakes during the demise of the Laurentide ice sheet, starting at ∼ 8.5 Kyr B.P., adds to the atmospheric cooling. Climatic forcing events occurred at 8.5 Kyr B.P., at 8.2 Kyr B.P. and finally at 8.06 Kyr B.P., leading to concurrent increases or decreases in the atmospheric Δ14C levels, completely consistent with the climatic forcing proposed here.  相似文献   

20.
刘添文  潘越  胡成  王清  陈植华  史婷婷 《中国地质》2021,48(5):1429-1440
黏性土的渗透系数极低,水分及溶质在黏性土中运移速率慢、耗时长,本次研究通过分析大别山区-江汉平原三水转换野外科学试验场(下文简称"试验场")ZK1、ZK2钻孔剖面土壤水、大气降雨D、18O同位素测试数据与孝感站(站号57482)多年年降雨量数据,确定了厚层黏性土土壤水入渗补给年份与深度的对应关系。结果表明:试验场区黏性土垂向岩性差异较小,无明显分层现象,土壤水分以"活塞流"的方式向下运移,夏、秋季的大气降雨为土壤水的主要补给来源;ZK1(取样间隔0.5~2.7 m,深度15 m)的土壤水δD、δ18O值随着埋深的增大出现周期性的波动,ZK2(取样间隔0.1 m,深度6.2 m)的土壤水δD、δ18O值随着埋深的增大出现分层波动现象;确定了黏性土层0~6.2 m深度对应的降雨入渗补给年份,并通过18O的峰值位移法计算得出降雨入渗补给在黏性土层的垂向运移速度为10.8~15.0 cm/a,年均入渗补给量为43.1~58.1 mm,占多年年均降雨量的4.01%,推算出降雨入渗补给需要近130年的时间才能穿透试验场厚层黏性土补给至地下水含水层,表明该厚层黏性土的防污性能良好。本研究所揭示大气-土壤界面下黏性土土壤水分入渗迁移历史演化特征及补给年际对应关系,对江汉平原区地下水环境保护、生态环境改善、旱涝灾害防治等具有重要意义。  相似文献   

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