Quantifying baseflow and water-quality impacts from a gravel-dominated alluvial aquifer in an urban reach of a large Canadian river

Groundwater discharge and non-point source (NPS) loading were evaluated along an urban reach of an eastern-slopes Rocky Mountains river (Bow River, Canada) to understand sources of water-quality impacts and baseflow. The discharge did not increase measurably over a 16-km reach. Groundwater in the river-connected alluvial aquifer was a mixture of river and prairie groundwater, with elevated chloride concentrations (average 379 mg L^–1) from road salt. Alluvial groundwater was the major NPS of chloride discharging to the river. Although the mass-flux based estimates of groundwater discharge were small (mean 0.02 m³ s^–1 km^–1, SD = 0.04 m³ s^–1 km^–1, n?=?30), the associated chloride mass flux over 16 km was significant (equivalent to that discharged from the city’s largest wastewater-treatment-plant effluent). Although local groundwater baseflow was previously thought to contribute significantly to overwinter baseflow in this reach, little contribution was measured in this study. Low baseflow generation is consistent with long-term river discharge data that show almost all of the baseflow generation occurs in the Rocky Mountain reach. Thus, local watershed areas are important for water-quality protection, but climate change in the headwaters is most salient to long-term flow.     

Tracing stream leakage towards an alluvial aquifer in a mountain basin using environmental isotopes

Stream–aquifer relationships in mountain basins are of great relevance because they control the water balance and, with it, the amount of resources (whether surface water or ground water) available for ecological and human demands. In this paper, this relationship is studied using environmental isotopes (δ¹⁸O and δD) to identify the occurrence of stream recharge in the Arbúcies River basin (NE Spain). Isotopic data from 51 natural springs define the local altitudinal gradient. This function is weighted by the proportional area above each point, given by the hypsometric curve, in order to estimate the isotopic stream water content as the contribution of runoff from incremental elevations. Stream water isotopes from two surveys are compared with hypsometrically averaged isotopic values to check for the appropriateness of this approach. Results show that it is more suitable when subsurface flows from surface formations, such as alluvial deposits, are the main contributors to stream discharge than when it derives from a single rainfall event. The characterization of stream isotope values is used as a key factor in identifying stream leakage to an unconfined alluvial aquifer in the lower reach of the Arbúcies River.     

An integrated approach for aquifer vulnerability mapping using GIS and rough sets: study from an alluvial aquifer in North India

A modified DRASTIC model in a geographic information system (GIS) environment coupled with an information-analytic technique called ‘rough sets’ is used to understand the aquifer vulnerability characteristics of a segment of the lower Kali watershed in western Uttar Pradesh, India. Since the region is a flat plain, topography (T) is removed as a potential control. Other parameters are the same as in DRASTIC, hence the new model is termed as DRASIC. The rough set technique is employed to provide insight into the relative vulnerabilities of different administrative units (blocks) within the study area. Using rough sets, three important factors are computed: strength, certainty and coverage. Strength indicates how the vulnerability characteristics vary in the entire area, certainty gives the relative fractions of low, medium and high vulnerability regions within a particular block, and coverage computes the percentage of a particular vulnerability state in each block. The purpose of the work is to demonstrate the utility of this integrated approach in classifying different administrative blocks in the study area according to their aquifer vulnerability characteristics. This approach is particularly useful for block-level planning and decision making for sustainable management of groundwater resources.     

Hydrologic and hydrogeologic analyses of an alluvial aquifer underlying Kushabhadra-Bhargavi River basin,Odisha, India

This paper deals with the analysis of groundwater condition in an alluvial aquifer system underlying Kushabhadra-Bhargavi River basin of Odisha, India. The rainfall data and river-stage data of the Kushabhadra River were analyzed for the periods of 1995–2009 and 1991–2010, respectively. Using the available lithologic data, geologic profiles along North-South and East-West sections were prepared and stratigraphy analysis was performed to characterize aquifers and confining layers present in the river basin. The results of stratigraphic analyses indicated that a two-layered aquifer system consisting of an unconfined aquifer and a confined aquifer exists in the study area. The thickness of unconfined aquifer varies from 3.4 to 46.5 m, whereas that of confined aquifer varies from 3.1 to 80.3 m over the basin with an interconnecting confining layer of thickness ranging from 2.1 to 60.0 m. The rainfall-groundwater dynamics and hydraulic connectivity were also investigated for gaining insights into groundwater characteristics. The analysis of groundwater levels indicated that the correlation among the 14 sites is better for most pairs of the sites (r = 0.50 to 0.96) in case of pre-monsoon season’s data and annual data as compared to monsoon and post-monsoon season’s data. This indicates good hydraulic connectivity among the observed sites in the study area. The significant seasonal groundwater fluctuations in the study area indicate appreciable recharge to the aquifer during the monsoon season. The findings obtained and insights gained from this study can be helpful for the water managers and decision makers to understand groundwater dynamics for the efficient planning and management of vital groundwater resources in the region. It is recommended that groundwater monitoring should be continued at more sites to understand long-term spatio-temporal characteristics of groundwater in the study area.     

Comparison of groundwater recharge estimation techniques in an alluvial aquifer system with an intermittent/ephemeral stream (Queensland,Australia)

This study demonstrates the importance of the conceptual hydrogeological model for the estimation of groundwater recharge rates in an alluvial system interconnected with an ephemeral or intermittent stream in south-east Queensland, Australia. The losing/gaining condition of these streams is typically subject to temporal and spatial variability, and knowledge of these hydrological processes is critical for the interpretation of recharge estimates. Recharge rate estimates of 76–182 mm/year were determined using the water budget method. The water budget method provides useful broad approximations of recharge and discharge fluxes. The chloride mass balance (CMB) method and the tritium method were used on 17 and 13 sites respectively, yielding recharge rates of 1–43 mm/year (CMB) and 4–553 mm/year (tritium method). However, the conceptual hydrogeological model confirms that the results from the CMB method at some sites are not applicable in this setting because of overland flow and channel leakage. The tritium method was appropriate here and could be applied to other alluvial systems, provided that channel leakage and diffuse infiltration of rainfall can be accurately estimated. The water-table fluctuation (WTF) method was also applied to data from 16 bores; recharge estimates ranged from 0 to 721 mm/year. The WTF method was not suitable where bank storage processes occurred.     

Exploration of an alluvial aquifer in Oman by time-domain electromagnetic sounding

 One-third of the population of Oman depends upon groundwater extracted from the alluvium of the Batinah Plain, on the coast of the Gulf of Oman. Deep geophysical exploration techniques were used to determine the depth and nature of the alluvium and the boundaries of the aquifer. The base and structural controls of the alluvial basin at its contact with Tertiary marine sediments and Cretaceous ophiolite were mapped with seismic reflection data, recorded originally for oil exploration. The base of the alluvium dips northward from the foothills of the Northern Oman Mountains, reaching a maximum depth of 2000 m at the coast. The varying facies of the alluvium are grossly characterised by different, overlapping ranges of electrical resistivity, depending largely on the clay content and degree of cementation. Resistivities near the coast are reduced by saline intrusion. These variations of resistivity were mapped with time-domain electromagnetic sounding along 400 km of profile, to distinguish among the three zones of the alluvial aquifer. The wedge of saline intrusion was also delineated, up to 10 km from the coast. The thickness of the saturated gravel aquifer ranges from 20–160 m in an area greater than 600 km². Received, April 1997 · Revised, January 1998 · Accepted, April 1998     

Modelling the vulnerability of groundwater to contamination in an unconfined alluvial aquifer in Pakistan

The area of Thal Doab is located in the Indus Basin and is underlain by a thick alluvial aquifer called the Thal Doab aquifer (TDA). The TDA is undergone intense hydrological stress owing to rapid population growth and excessive groundwater use for livestock and irrigated agricultural land uses. The potential impact of these land uses on groundwater quality was assessed using a DRASTIC model in a Geographic Information System environment. Seven DRASTIC thematic maps were developed at fixed scale and then combined into a groundwater vulnerability map. The resultant vulnerability index values were grouped into four zones as low, moderate, high and very high. The study has established that 76% of the land area that is underlain by the TDA has a high to very high vulnerability to groundwater contamination mainly because of a thin soil profile, a shallow water table and the presence of soils and sediments with high hydraulic conductivity values. In addition, only 2 and 22% of the total area lie in low and moderate vulnerability zones, respectively. The outcomes of this study can be used to improve the sustainability of the groundwater resource through proper land-use management.     

Determination of hydraulic parameters of an unconfined alluvial aquifer by the floodwave-response technique

Groundwater constitutes a vital component of the water-resource system. Adequate knowledge of aquifer parameters is of utmost importance for proper groundwater management. In the present study, an attempt has been made to critically analyze the river–aquifer interaction and to explore the practicability and reliability of the floodwave-response technique in estimating the hydraulic parameters of the Konan aquifer, Japan. The analysis of the pertinent hydrologic and hydrogeologic data revealed a strong relationship between the Monobe River stage and the groundwater levels over a major portion of the Konan basin. Inverse modeling, using the floodwave-response model at four sites, yielded high values of hydraulic diffusivity that ranged from 16 to 194 m²/s. However, the overall average aquifer diffusivity was found to be reasonable (0.7–3.5 m²/s). All the selected flood events were not found suitable for determining reasonable values of hydraulic diffusivity at a given site. Using the optimal diffusivities at two sites and the aquifer transmissivity from the pumping tests at these sites, the storage coefficient values were estimated as those of truly confined aquifers. In contrast, reasonable values of storage coefficient were obtained based on the average aquifer diffusivity estimates. The sensitivity analysis of the floodwave-response model indicated that the optimal hydraulic diffusivity is very sensitive to the distance parameters of the model, which necessitate precise measurement of these parameters. It is concluded that a judicious application of the floodwave-response technique is essential, especially in the case of unconfined aquifers.

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Resumen El agua subterránea constituye un componente vital de los sistemas de recursos hídricos. El conocimiento adecuado de los parámetros del acuífero es de suma importancia para el manejo apropiado del agua subterránea. En el presente estudio se ha realizado un intento para analizar críticamente la interacción río-acuífero y explorar la confiabilidad y utilidad de la técnica de respuesta de onda de crecida para estimar los parámetros hidráulicos del acuífero Konan, Japón. El análisis de datos hidrológicos e hidrogeológicos pertinentes muestra una relación fuerte entre el nivel del Río Monobe y los niveles de agua subterránea en gran parte de la cuenca Konan. El modelizado de inversión utilizando el modelo de respuesta de onda de crecida en cuatro sitios generó valores altos de difusividad hidráulica que varían de 16 a 194 m²/s. Sin embargo, se encontró que la difusividad promedio global del acuífero tenía valores razonables (0.7 a 3.5 m²/s). Todos los eventos de crecida seleccionados no fueron encontrados satisfactorios para determinar valores razonables de difusividad hidráulica en un sitio determinado. Utilizando las difusividades óptimas en dos sitios y la transmisividad del acuífero proveniente de pruebas de bombeo en esos sitios se estimaron valores del coeficiente de almacenamiento como los que se obtendrían para acuíferos completamente confinados. En contraste, se obtuvieron valores razonables del coeficiente de almacenamiento basados en los cálculos de difusividades promedio del acuífero. Los análisis de sensitividad del modelo de respuesta de onda de crecida indicaron que la difusividad óptima hidráulica es muy sensitiva a los parámetros de distancia del modelo por lo que se necesitan mediciones precisas de esos parámetros. Se concluye que es esencial una aplicación sensata de la técnica de respuesta de onda de crecida, especialmente en el caso de acuíferos no confinados.

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Resumé Leau souterraine constitue une composante vitale des systèmes de ressource en eau. Une connaissance adéquate des paramètres des aquifères est importante pour une gestion correcte de ces systèmes. Dans cette étude, la démarche consiste à analyser linteraction rivière–aquifère de manière critique et dexplorer la technique permettant destimer les paramètres hydrauliques de laquifère Konan, Japon. Lanalyse pertinente des données hydrologiques et hydrogéologiques révèle une relation forte entre le niveau de la rivière Monobe et les niveaux piézométriques sur une grande partie du bassin de Konan. La modélisation inverse utilisant le modèle de réponse aux vagues de crue sur quatre sites fournit des valeurs de diffusivité comprises entre 16 et 194 m²/s. Néanmoins la valeur moyenne de diffusivité est apparue raisonnable (entre 0.7 et 3.5 m²/s). Tous les évènements de crue nont pas été retenus comme permettant de calculer avec une bonne fiabilité la diffusivité sur un site donné. En utilisant les données optimales de diffusivité provenant de deux sites, et la transmissivité fournie par les essais de pompage, le coefficient demmagasinement a été déterminé et correspond bien à un aquifère confiné. Par contraste, des valeurs raisonnables de coefficient demmagasinement ont été déterminées par estimation de la diffusivité moyenne de laquifère. Lanalyse de sensibilité du modèle de réponse aux vagues de crue indique que la diffusivité hydraulique optimale est très sensible à la distance utilisée dans le modèle, qui nécessite dés lors une mesure précise. En conclusion il est essentiel que ce type dapplication doit tre judicieusement mis en oeuvre, et spécialement dans le cadre daquifères captifs.

     

大理冲积扇含水层非均质性分布规律研究

洪-冲积扇的非均质性分布规律对含水层渗流和污染物迁移研究、地下水污染管理、控制及修复具有重要意义。本文以大理点苍山东麓隐仙溪洪-冲积扇为例,对其水动力条件、沉积构造模型、地形坡度与运移距离的关系进行探讨。研究表明,冲积扇沉积非均质受水动力条件影响,当水动力较好时,沉积颗粒物为砾石和漂砾,填充泥质和粉砂质,水动力较弱时沉积多为砂质和粘土颗粒,扇面整体以水流河道为中心轴呈扇形沉积;冲积扇沉积颗粒物的分选性和磨圆度受地形坡度的影响,地形坡度大沉积颗粒物分选性和磨圆度差,搬运距离越远分选性和磨圆度越好;扇顶因水动力强,坡度大,沉积物分选性和磨圆度差,层理不发育,扇中扇缘随着水动力条件及地形坡度减弱,沉积物分选性和磨圆度逐渐变好,层理较为发育,沉积为水平或均匀层理。     

Hydrochemical characteristics and seasonal variations in groundwater quality of an alluvial aquifer in parts of Central Ganga Plain,Western Uttar Pradesh,India

The present study was undertaken to assess major ion chemistry of groundwater in parts of the Central Ganga Plain and observe seasonal variations in its chemical quality. Systematic sampling was carried out during November 2005 and June 2006. The major ion chemistry of groundwater shows large variations, so much so that at times the meteoric signature seems to be completely obliterated. In many samples the concentrations of SO₄, NO₃ and F are above the permissible limit for human consumption. The graphical treatment of major ion chemistry helps in identifying four types of groundwater. All possible ionic species such as NaCl, KCl, NaHCO₃, NaSO₄, KNO₃, NaNO₃, CaHCO₃, MgHCO₃, MgSO₄ are likely to occur in groundwater system. The observed chemical variations may be attributed to sediment water interaction, ion exchange, dissolution mechanisms and anthropogenic influences such as application of fertilizers and effluents from sugar factories and paper mills. A general increase in TDS is observed in samples during June 2006. The increase in salinity is attributed to evaporation from water table, irrigation return flows, anthropogenic activities and below average rainfall in 2005 and 2006. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Recharge areas and geochemical evolution of groundwater in an alluvial aquifer system in the Sultanate of Oman

A regional hydrogeochemical model was developed to evaluate the geochemical evolution of different groundwaters in an alluvial aquifer system in the Interior of Oman. In combination with environmental isotopes the model is able to extract qualitative and quantitative information about recharge, groundwater flow paths and hydraulic connections between different aquifers. The main source of water to the alluvial aquifer along the flow paths of Wadi Abyadh and Wadi Muaydin in the piedmont is groundwater from the high-altitude areas of the Jabal Akhdar and local infiltration along the wadi channels. In contrast, the piedmont alluvial aquifer along Wadi Halfayn is primarily replenished by lateral recharge from the ophiolite foothills to the east besides smaller contributions from the Jabal Akhdar and local infiltration. Further down gradient in the Southern Alluvial Plain aquifer a significant source of recharge is direct infiltration of rain and surface runoff, originating from a moisture source that approaches Oman from the south. The model shows that the main geochemical evolution of the alluvial groundwaters occurs along the flow path from the piedmont to the Southern Alluvial Plain, where dedolomitization is responsible for the observed changes in the chemical and carbon isotope composition in these waters.

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Resumen Un modelo hidrogeoquímico regional fue desarrollado, para evaluar la evolución geoquímica de diferentes aguas subterráneas en un sistema acuífero aluvial ubicado en el interior de Omán. El modelo, en combinación con isótopos ambientales, es capaz de obtener información cualitativa y cuantitativa sobre recarga, direcciones de flujo de agua subterránea y sobre las conexiones hidráulicas entre diferentes acuíferos. La fuente principal de agua para el acuífero aluvial en el piedemonte son las aguas subterráneas, a lo largo de las direcciones de flujo del Wadi Abyadh y del Wadi Muaydin, desde las áreas de gran altura de Jabal Akhdar y como infiltración local a lo largo de los canales del wadi. En contraste, el acuífero aluvial del piedemonte a lo largo del Wadi Halfayn, esta alimentado principalmente por recarga lateral desde las partes bajas de las montañas de ofiolitas hacia el Este, además por pequeñas contribuciones desde el Jabal Akhdar e infiltración local. Siguiendo gradiente abajo en el acuífero de la Llanura Aluvial del Sur, allí tanto la infiltración directa de lluvia, como la escorrentía superficial constituyen fuentes significativas de recarga, las cuales se originan en una fuente de humedad que llega a Omán proveniente del Sur. El modelo muestra, que la evolución geoquímica principal de las aguas subterráneas en el aluvión, sucede a lo largo de la dirección de flujo, que va desde el piedemonte hacia la Llanura Aluvial Sur, en donde el proceso de des-dolomitización es el responsable de los cambios observados en la composición química y también del contenido de isótopos de carbono en estas aguas.

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Résumé On a développé un modèle régional hydrogéochimique pour évaluer lévolution géochimique des différentes eaux souterraines dans le système aquifère de lintérieur dOman. Avec la contribution des isotopes denvironnement, le modèle est capable de fournir des informations qualitatives et quantitatives sur la recharge, les directions découlement et sur les connections hydrauliques entre les différents aquifères du système. La source principale pour laquifère situé au long de la direction découlement des oueds de Abdyah et de Muaydin dans le piémont est leau souterraine provenant des zones de haute altitude de Jabal Akhbar ainsi que linfiltration locale au long des canaux de loued. Par contre, à part dune petite contribution provenant des infiltrations locaux et de Jabal Akhbar, l aquifère alluvial de Wadi Halfayan est en principal alimenté par la recharge latérale provenant des ophiolites situées dans la partie est. Les plus importantes sources de recharge dans laval de laquifère de la Plaine Alluviale sont linfiltration directe et le ruissellement provenant dune source dhumidité qui sapproche dOman par le sud. Le modèle montre que la principale évolution géochimique se produise au long de la direction découlement qui part de piémont de la Plaine Alluviale du Sud, où le procès de dédolomisation est responsable pour les changements observés dans la composition géochimique et en carbone des eaux.

     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

A preliminary assessment of hydrogeological features and selected anthropogenic impacts on an alluvial fan aquifer system in Greece

An investigation was carried out to delineate the hydrogeologic framework and to understand groundwater quality of the Kompsatos River fan aquifer system, northeastern Greece, as well as to assess environmental impact induced by human activities. As groundwater is the only major source of water in this area, it is important to know the effect of geological formations, and anthropogenic activities on groundwater chemistry and environment. A thorough hydrogeological study was performed during the period 2004–2007. The differential river gauging method was used for estimating the volume of water leaking from (or discharging into) the river. Groundwater samples were collected from 89 monitoring wells, during the summer period of 2007, and analyzed for major ions and trace elements. A potential reservoir of groundwater is formed within the Kompsatos River fan. The aquifer system/Kompsatos River interaction is the outstanding feature of this area. Ca–Mg–HCO₃–SO₄ is the dominant water type as a result of dissolving carbonate salts. B, Ba, Mn, Li, Sr, and Zn are the most abundant trace elements in groundwater. Both the major-ion chemistry and trace element enrichment of the groundwater are controlled by mineral dissolution and water–rock interaction. Nitrate contamination of groundwater is related to agricultural practices. An improperly constructed drainage system led locally to salinization of groundwater. Channelization has caused considerable disruption to the river ecosystem. The eventual construction of a dam on the river will adversely affect the environment and the aquifer system. The lack of managerial policy for water is putting environmental resources and water supply in jeopardy.     

Modelling the response of an alluvial aquifer to anthropogenic and recharge stresses in the United States Southern Great Plains

This paper uses Visual MODFLOW to simulate potential impacts of anthropogenic pumping and recharge variability on an alluvial aquifer in semi-arid northwestern Oklahoma. Groundwater withdrawal from the aquifer is projected to increase by more than 50% (relative to 1990) by the year 2050. In contrast, climate projections indicate declining regional precipitation over the next several decades, creating a potential problem of demand and supply. The following scenarios were simulated: (1) projected groundwater withdrawal, (2) a severe drought, (3) a prolonged wet period, and (4) a human adjustment scenario, which assumes future improvements in water conservation measures. Results indicate that the combined impacts of anthropogenic pumping and droughts would create drawdown of greater than 12 m in the aquifer. Spatially, however, areas of severe drawdown will be localized around large-capacity well clusters. The worst impacts of both pumping and droughts will be on stream–aquifer interaction. For example, the projected aquifer pumpage would lead to a total streamflow loss of 40%, creating losing stream system regionally. Similarly, a severe drought would lead to a total streamflow loss of >80%. A post-audit of the model was also carried out to evaluate model performance. By simulating various stress scenarios on the alluvial aquifer, this study provides important information for evaluating management options for alluvial aquifers.     

灌溉对景泰灌区年潜在蒸散量的影响

基于蒸散发互补相关原理,定量分析和预测了引黄灌溉发展对甘肃景泰灌区年潜在蒸散量的影响。景泰灌区从1972年开始引黄灌溉,年蒸发皿蒸发量和潜在蒸散量随着灌溉引水消耗的增大而减小,其中空气动力学项下降的趋势非常明显,潜在蒸散量的变化主要受到风速下降和相对湿度增大的影响,与引黄灌溉有密切关系。根据互补相关平流-干旱模型分析了年潜在蒸散量随灌区耗水量的变化规律,并在假定年降水量和年潜在蒸散量中辐射项保持多年平均值的情况下,预测了不同耗水量情景下的年潜在蒸散量。     

Helium, radon and radiocarbon studies on a regional aquifer system of the North Gujarat-Cambay region, India

The study reports the age evolution of groundwater as it flows from the recharge area through a regional alluvial aquifer system in North Gujarat-Cambay region in western India. Radiocarbon (¹⁴C), ⁴He and ⁴He / ²²²Rn dating methods have been employed. Sediments from a drill core in the Cambay Basin were also analysed for uranium (U) and thorium (Th) concentrations and the measured values have been used to estimate the ⁴He and ²²²Rn production rate for groundwater age calculations. Additionally, factors controlling the distribution of ²²²Rn, ⁴He and temperature anomalies in groundwater, vis-à-vis their relation to the tectonic framework and lithology of the study area, have also been examined.The multi-isotope study indicated a reasonable correspondence in groundwater age estimates by the three methods employed. The groundwater ¹⁴C ages increased, progressively, in the groundwater flow direction: from the foothills of Aravalli Mountains in the east, and reached a value of ∼35 ka towards the region of lowest elevation, linking Little Rann of Kachchh (LRK)-Nalsarovar (NS)-Gulf of Khambhat (GK) in the western part of the study area. In this region, groundwater ages obtained for free flowing thermal wells and springs employing ⁴He and ⁴He / ²²²Rn systematics are in the order of million years. Such anomalous ages are possibly due to enhanced mobilisation and migration of ‘excess helium’ from hydrothermal circulation vents along deep-seated faults. Excluding such anomalous cases and considering all uncertainties, presently estimated ⁴He and ⁴He / ²²²Rn groundwater ages are in reasonable agreement with ¹⁴C age estimates in the Cambay Basin for helium release factor (Λ_He) value of 0.4 ± 0.3. The ⁴He method also indicated west-southwards progression of groundwater ages up to ∼100 ka beyond the Cambay Basin.Large ‘excess helium’ concentrations are also seen to be generally associated with anomalous groundwater temperatures (> 35 °C) and found to overlie some of the basement faults in the study area, particularly along the east and the west flanks of the Cambay Basin. Groundwater ²²²Rn activities in most of the study area are 800 ± 400 dpm/l. But, a thermal spring at Tuwa on the east flank of the Cambay Basin, having granitic basement at shallow depth, recorded the highest ²²²Rn activity (∼63,000 dpm/l).