REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.     

Thermal‐infrared remote sensing of surface water–groundwater exchanges in a restored anastomosing channel (Upper Rhine River,France)

Ecohydrological processes are a key element to consider in functional river restorations. In the framework of a LIFE+ European restoration program, we have investigated the potential for airborne thermal‐infrared remote sensing to map surface water–groundwater exchanges and to identify their driving factors. We focused our attention on anastomosing channels on an artificial island of the Upper Rhine River (Rohrschollen), where a new channel was excavated from the floodplain to reconnect an older channel in its upstream part. These hydraulic engineering works led to an increased inflow from the Rhine Canal. Here, we propose an original data treatment chain to (a) georeference the thermal‐infrared images in geographic information system based on visible images, (b) detect and correct data errors, and (c) identify and locate thermal anomalies attributed to groundwater inputs and hyporheic upwellings. Our results, which have been compared to morpho‐sedimentary data, show that groundwater upwelling in the new channel is controlled by riffle–pool sequences and bars. This channel is characterized by large bedload transport and morphodynamic activity, forming riffles and bars. In the old channel, where riffle–pool sequences no longer exist, due to impacts of engineering works and insufficient morphodynamic effects of the restoration, thermal anomalies appeared to be less pronounced. Groundwater inputs seem to be controlled by former gravel bars outcropping on the banks, as well as by local thinning of the low‐permeability clogging layer on the channel bed.     

The influence of variable topography on the depositional behaviour of pyroclastic density currents: The examples of the Upper Pollara eruption (Salina Island,southern Italy)

Stratigraphic reconstruction of the Upper Pollara eruption has allowed for the inference of eruptive mechanisms and the distillation of a sedimentological model for pyroclastic density currents (PDCs) moving across variable topography. The pre-eruptive topography in the study area was characterised by a tuff ring-like morphology, with both inward and outward dipping slopes. Highly viscous, moderately porphyritic, dacitic to rhyolitic magmas fed the eruption, which was characterised by a Vulcanian eruptive style. The stratigraphic succession was divided into five eruption units (EUs), which result from different phases of the eruption separated by stases. Sustained columns occurred only during EU1, while PDC generation dominates EU2–5. Lithofacies analysis of the PDC deposits indicates the prevalence of massive coarse-grained deposits on the inner slopes of the Pollara crater, which are interpreted as the deposits of a flow-boundary zone dominated by granular flow or fluid escape regimes. Dune-bedded, massive to stratified lithofacies dominate the outer slopes of the Pollara crater, and are interpreted as the deposits of PDCs with flow-boundary zones in which traction played a major role. Thin, massive PDC deposits are exposed on the sub-horizontal Malfa terrace, and are interpreted as representative of flow-boundary zones dominated by a granular flow regime. The occurrence of stacked deposits indicates that most of the PDCs were characterised by unsteady pulsatory behaviour, with development of trains of pulses during their transport. The downcurrent lithofacies transitions observed for the Upper Pollara deposits have finally been compared with other similar lithofacies associations which have been described for short-lived PDCs at tuff rings, in order to discuss the influence of pre-eruptive topography on lithofacies association.     

Phosphorus in sediments of high-elevation lakes in the Sierra Nevada (California): implications for internal phosphorus loading

In high-elevation lakes of the Sierra Nevada (California), increases in phosphorus (P) supply have been inferred from changes in phytoplankton growth during summer. To quantify rates of sediment P release to high-elevation Sierran lakes, we performed incubations of sediment cores under ambient and reducing conditions at Emerald Lake and analyzed long-term records of lake chemistry for Emerald and Pear lakes. We also measured concentrations of individual P forms in sediments from 50 Sierra Nevada lakes using a sequential fractionation procedure to examine landscape controls on P forms in sediments. On average, the sediments contained 1,445 µg P g^?1, of which 5 % was freely exchangeable, 13 % associated with reducible metal hydroxides, 68 % associated with Al hydroxides, and the remaining 14 % stabilized in recalcitrant pools. Multiple linear regression analysis indicated that sediment P fractions were not well correlated with soluble P concentrations. In general, sediments behaved as net sinks for P even under reducing conditions. Our findings suggest that internal P loading does not explain the increase in P availability observed in high-elevation Sierran lakes. Rather, increased atmospheric P inputs and increased P supply via dissolved organic C leaching from soils may be driving the observed changes in P biogeochemistry.     

Levels and distribution of tris-(2,3-dibromopropyl) isocyanurate and hexabromocyclododecanes in surface sediments from the Yellow River Delta wetland of China

The levels and distribution of tris-(2,3-dibromopropyl) isocyanurate (TBC) and hexabromocyclododecanes (HBCDs) of surface sediments in the Yellow River Delta wetland had been investigated. The concentrations of TBC and ∑ HBCDs ranged from 0.20 to 29.03 ng·g^? 1 dw and below limits of detections (LODs) to 20.25 ng·g^? 1 dw. The average composition profile of three HBCDs isomers were 10.1%, 6.1% and 83.8% for α-, β- and γ-HBCD, respectively. Moreover, correlation analysis indicated there are similar sources among three isomers and positive correlations between total organic carbon (TOC) content and concentrations of TBC and HBCDs. The mass inventory of TBC,α-, β-, γ-HBCD, ΣHBCDs in surface sediments of Yellow River Delta wetland were estimated about 725.50, 72.76, 44.29, 548.34, 665.39 kg. Therefore, further investigations on potential human health and environmental risk assessments of TBC and HBCDs were needed.     

Rare and vulnerable species in the mollusc communities in the mining subsidence reservoirs of an industrial area (The Katowicka Upland, Upper Silesia, Southern Poland)

Pollution of the water environment by mining waters is a problem not only in Poland, but worldwide. This study investigated the mollusc communities in seven mining subsidence reservoirs affected by coal mine output (the Katowicka Upland, Upper Silesia, Southern Poland). The objective of the survey was to determine the relationship between the molluscs and their environments and to evaluate the ecological-conservation value of freshwater habitats which support rare and vulnerable molluscs. From 1993 to 2005, 23 mollusc species were recorded. Our result confirmed an invasion by Potamopyrgus antipodarum (Gray, 1843), whose density varied from 2 to 2422 individuals/m² in the waters of the Katowicka Upland. A few rare and vulnerable species were found, e.g. Acroloxus lacustris (Linnaeus, 1758), Hippeutis complanatus (Linnaeus, 1758), Ferrissia wautieri (Mirolli, 1960), Anodonta anatina (Linnaeus, 1758), Musculium lacustre (O.F. Müller, 1774) or Pisidium casertanum (Poli, 1791). Principal component analysis showed a positive correlation between mollusc density and pH, the concentration of chlorides, the total hardness, alkalinity and total dissolved solids, and a negative correlation between the number of species and phosphates. Because of the distinctive environmental features of the mining subsidence reservoirs in Czułów, the research area has provided a refuge for wildlife.     

Boron isotopic fractionation in laboratory inorganic carbonate precipitation: Evidence for the incorpora-tion of B(OH)_3 into carbonate

A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.34 was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3) between carbonate and B(OH)3 in seawater range 0.937 and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and collabo-rators show that the αcarb-3 values between carbonate and B(OH)3 in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ 11B4-pH curves and neither do they exactly parallel any theoretical δ 11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3 with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4- in carbonate . Hence, in the reconstruction of the paleo-pH of sea-water from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic frac-tionation factor (α4-3) between B(OH)4- and B(OH)3 is not suitable. Instead, an empirical equation should be established.     

Distribution and ecological relevance of fine sediments in organic-enriched lagoons: the case study of the Cabras lagoon (Sardinia, Italy)

In organic-enriched sedimentary systems, like many Mediterranean coastal lagoons, a detailed analysis of sediment grain size composition and partitioning within the muds is crucial to investigate sedimentological trends related to both hydrodynamic energy and basin morphology. In these systems, sediment dynamics are particularly important because the partitioning and transport of fine sediments can strongly influence the redistribution and accumulation of large amounts of organic matter, and consequently the distribution of benthic assemblages and the trophic status and functioning of a lagoon. Nevertheless, studies on benthic-sediment relationships have been based mainly on a rather coarse analysis of sediment grain size features. In muddy systems, however, this approach may impede a proper evaluation of the relationships and effects of the distribution of fine sediment and organic matter on the biotic benthic components. Here we show that the distribution of sedimentary organic matter (OM) and total organic carbon (TOC) in the Cabras lagoon (Sardinia, Italy) can be explained (i.e., predicted) as a function of a nonlinear increase in the amount of the cohesive fraction of sediments (< or = 8 microm grain size particles) and that this fraction strongly influences the structure, composition and distribution of macrobenthic assemblages. Even in such a homogeneously muddy system, characterized by "naturally" occurring impoverished communities, impaired benthic assemblages were found at < or = 8 microm, OM, TOC contents of about 77%, 11% and 3.5%, respectively. A review of studies conducted in Mediterranean coastal lagoons highlighted a lack of direct integrated analysis of sediment features and the biotic components. We suggest that, especially in organic-enriched coastal lagoons, monitoring programs should primarily investigate and consider the cohesive fraction of sediments in order to allow a better assessment of benthic-sediment relationships and ecological quality of the system.     

青海湖流域50年来(1956-2007年)河川径流量变化趋势——以布哈河和沙柳河为例

通过对青海湖流域布哈河和沙柳河50年来的河川径流量分析发现,布哈河和沙柳河年径流量50年来没有显著的变化趋势,这两条河流的河川径流量对青海湖水位下降所起的作用不明显;布哈河月平均流量的年际变化在1月、2月和3月有减少的趋势,沙柳河月平均流量的年际变化在1月、2月、4月和5月亦有减少的趋势;布哈河的径流量大于沙柳河的径流量,在55%-91%频率范围内,布哈河的径流量小于沙柳河的径流量,在其它频率范围内,布哈河的径流量显著大于沙柳河的径流量,在一年中,布哈河和沙柳河的月径流量具有显著的差异;布哈河来水丰沛期是20世纪60年代,贫乏期是90年代,70和80年代为平水期;沙柳河月径流量从20世纪60年代到90年代一直比较稳定,没有发生显著的变化.     

Total and labile metals in surface sediments of the tropical river-estuary system of Marabasco (Pacific coast of Mexico): Influence of an iron mine

Marabasco is a tropical river-estuary system comprising the Marabasco river and the Barra de Navidad Lagoon. The river is impacted by the Pe?a Colorada iron mine, which produces 3.5 million tons of pellets per year. Thirteen surface sediment samples were collected in May 2005 (dry season) in order to establish background levels of Al, Cd, Co, Cu, Fe, Ni, Pb, and Zn in the system and to ascertain the potential mobility of metals in the sediments. Analyses were carried out in the fraction finer than 63 microm, and labile metals extracted according the BCR procedure. Certified reference materials were used for validation of methods. Total concentrations of Cd, Co, Cu, Ni, Pb, and Zn were in the range of 0.05-0.34, 6-95, 0.7-31, 9-26, 2-18, and 53-179 mgkg(-1), respectively; Al and Fe ranges of 24-127, and 26-69 mgg(-1) correspondingly. Cadmium was found to be significantly labile in the sediments (20-100%), followed by Co (0-35%), Ni (3-16%) and Zn (0-25%), whereas the labile fraction for Cu, Fe and Pb was almost negligible (<4%). According with the total metal concentrations, background levels and normalised enrichment factors (NEF) of the metals studied, the impact of the Pe?a Colorada iron mine on the Marabasco system is lower than expected when compared with other similar World systems influenced by mining activities.     

Three magmatic components in the 1973 eruption of Eldfell volcano,Iceland: Evidence from plagioclase crystal size distribution (CSD) and geochemistry

The 1973 eruption of Eldfell volcano, Iceland, appears to have been a short, simple event, but textural and geochemical evidence suggest that it may have had three different magmatic components. The first-erupted fissure magmas were chemically evolved, rich in plagioclase (∼ 18%) and had shallow, straight crystal size distribution (CSD) curves. The early lavas were less evolved chemically, had lower plagioclase contents (∼ 13%) and steeper, slightly concave up CSDs. The late lavas were chemically similar to the early lavas, but even richer in plagioclase than the initial magmas (∼ 24%) and had the steepest CSDs. There was no chemical evidence for plagioclase fractionation, but compositional diversity could be produced by clinopyroxene fractionation which must have occurred at depth. We propose that the eruption started with old, coarsened (Ostwald ripened) magma left over from a previous eruption, possibly that which produced Surtsey Island ten years earlier. The early flows may be mixtures of small amounts of this old magma with a new, low crystallinity, uncoarsened magma or a completely new magma. The late flows are another new magma from depth, chemically similar to the early flows, but which has grown plagioclase under increasing saturation (undercooling) perhaps during its ascent. All three magmatic components may have originated from the same parent, but had varying degrees of clinopyroxene fractionation, plagioclase nucleation and growth, and coarsening.     

Analysis of stable components for extended-range(10-30 days) weather forecast:A case study of continuous overcast-rainy process in early 2009 over the mid-lower reaches of the Yangtze River

A continuous overcast-rainy weather(CORW) process occurred over the mid-lower reaches of the Yangtze River(MLRYR) in China from February 14 to March 9 in 2009,with a large stretch and long duration that was rarely seen in historical records.Using the empirical orthogonal function(EOF),we analyzed the geopotential height anomaly field of the NCEP-DOE Reanalysis II in the same period,and defined the stable components of extended-range(10-30 days) weather forecast(ERWF).Furthermore,we defined anomalous and climatic stable components based on the variation characteristics of the variance contribution ratio of EOF components.The climatic stable components were able to explain the impact of climatically averaged information on the ERWF,and the anomalous stable components revealed the abnormal characteristics of the continuous overcast-rainy days.Our results show that the stable components,especially the anomalous stable components,can maintain the stability for a longer time(more than 10 days) and manifest as monthly scale low-frequency variation and ultra-long-wave activities.They also behave as ultra-long waves of planetary scale with a stable and vertically coherent structure,reflect the variation of general circulation in mid-high latitudes,display the cycle of the zonal circulation and the movement and adjustment of the ultra-long waves,and are closely linked to the surface CORW process.     

Anomalous strontium and lead isotope signatures in the off-rift Öræfajökull central volcano in south-east Iceland: Evidence for enriched endmember(s) of the Iceland mantle plume?

The currently active off-rift central volcano Öræfajökull in south-east Iceland sits unconformably on much older (10–12 Ma) and eroded crust. The composition of recent volcanics ranges from basalt to rhyolite, but the series is more sodic alkaline than the common rift zone tholeiitic suites. In this study we present Sr, Nd, Pb and O isotopic data for a suite of Öræfajökull samples. The complete suite shows typical mantle values for oxygen isotopes. The ⁸⁷Sr/⁸⁶Sr ratios (average of 15 SAMPLES=0.703702) of the modern Öræfajökull rocks (basalts as well as rhyolites) are much higher than observed so far for any other Icelandic rocks. The ¹⁴³Nd/¹⁴⁴Nd ratios (average=0.512947; n=15) are lower than for rift rocks, but similar to rocks of the off-rift Snæfellsnes volcanic zone. Furthermore, the Öræfajökull rocks are enriched in the ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb isotope ratios compared to Icelandic rift basalts. The enriched nature of the suite indicates that Öræfajökull samples a source component that has characteristics common with EM2 type mantle. Furthermore, it is concluded that the silicic rocks of Öræfajökull formed by fractional crystallization from mafic melts rather than by partial melting of older crust.     

Net, actual, and potential sediment-water interface NH4 fluxes in the northern Gulf of Mexico (NGOMEX): Evidence for NH4 limitation of microbial dynamics

A new approach, combining ¹⁵NH₄⁺ isotope dilution and continuous-flow techniques, provided estimates of “actual” and “net” NH₄⁺ flux and sediment NH₄⁺ demand (SAD) at the sediment-water interface (SWI) of sites in the northern Gulf of Mexico (NGOMEX). The sites included a hypoxic site (C6), two sites with intermediate oxygen levels (B7 and F5), and a normoxic site (CT). Control cores without isotope addition and other cores from the same site treated with ¹⁵NH₄⁺ labeled overflowing water differentiated between net and actual regeneration flux and actual vs. potential uptake flux of NH₄⁺. Experiments were conducted in 2008 before (July) and after (September) two successive hurricanes (Gustav and Ike) and in January and August, 2009. Actual regeneration was significantly higher than net flux at most sites. Net flux did not differ significantly in most sites/dates, but the actual regeneration, and the actual and potential uptake, showed temporal and spatial variation; the flux at the hypoxic site was more active than non-hypoxic sites. SAD, the difference between potential and actual NH₄⁺ uptake flux, was higher at the hypoxic site than at non-hypoxic sites before and after the hurricanes in 2008 and during the hypoxia season in 2009. SAD related negatively to bottom water DO values. Conclusions: (1) net flux often underestimated actual regeneration, (2) hurricane activity decreased N dynamics, and (3) microbial N limitation status at the hypoxic site related to NH₄⁺ removal processes that were independent of oxygen (e.g., anaerobic heterotrophic uptake or anammox). These results indicate a rather consistent NH₄⁺ demand at the SWI during the hypoxic season and suggest that reduced nitrogen may limit microbial dynamics in the region.     

Landslide phenomena in the area of Pomarico (Basilicata–Italy): methods for modelling and monitoring

This paper takes into consideration landslide phenomena in the clayey slopes facing the built-up area of Pomarico which is situated in the southern part of the “Fossa Bradanica”, in Basilicata (Italy). Based on the great number of geologic, geomorphologic and historic informations a geotechnical model of the slope was built. Particular attention has been paid to define the geotechnical parameters of the soil and which mechanical models are to be used. The studies point out a correlation between the water level in the detritus cover and the stability condition of the slope showing that phenomena at first located at the foot of the slope spread quickly towards its summit as the piezometric height increases.     

A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.     

Geochemistry of khondalites from the central portion of North China craton (NCC): implications for the continental cratonization in the Neoarchean

Within the high-grade metamorphic basement, the central portion of North China Craton (NCC), a group of Neoarchean khondalites (KS) is identified. They are characterized by large ion lithophile elements (LILE) enrichment, lower abundances of Zr, Hf and Sr. Their rare earth element (REE) distribution has significant LREE enrichment and negative Eu anomalies. The protoliths of KS are interpreted as feldspathic quartzite, shale or pelite and carbonite, deposited in a shallow sea upon cratonic shelf distant from the land. KS's source region might be dominated by granitic rocks, with a minor amount of TTG, underwent comparatively severe chemical weathering. Considering relevent tectonic constraints, we suggest that khondalites from central portion of NCC, an important metamophosed sedimentary cover, are the most significant exogenetic marker of Neoarchean continental cratonization for NCC.     

Structural features of Panarea volcano in the frame of the Aeolian Arc (Italy): Implications for the 2002–2003 unrest

Panarea, characterized by gas unrest in 2002–2003, is the volcanic island with the least constrained structure in the eastern-central Aeolian Arc (Italy). Based on structural measurements, we define here its deformation pattern relative to the Arc. The main deformations are subvertical extension fractures (63% of data), normal faults (25%) and dikes (12%). The mean orientation of the extension fractures and faults is N38°E, with a mean opening direction of N135° ± 8°, implying extension with a moderate component of dextral shear. These data, matched with those available for Stromboli volcano (pure opening) and Vulcano, Lipari and Salina volcanoes (predominant dextral motions) along the eastern-central Arc, suggest a progressive westward rotation of the extension direction and an increase in the dextral shear. The dextral shear turns into compression in the western arc. The recent unrest at Panarea, coeval to that of nearby Stromboli, may also be explained by the structural context, as both volcanoes lie along the portion of the Arc subject to extension.