Facies characteristics and magma–water interaction of the White Trachytic Tuffs (Roccamonfina Volcano, southern Italy)

 The Quaternary White Trachytic Tuffs Formation from Roccamonfina Volcano (southern Italy) comprises four non-welded, trachytic, pyroclastic sequences bounded by paleosols, each of which corresponds to small- to intermediate-volume explosive eruptions from central vents. From oldest to youngest they are: White Trachytic Tuff (WTT) Cupa, WTT Aulpi, WTT S. Clemente, and WTT Galluccio. The WTT Galluccio eruption was the largest and emplaced ∼ 4 km³ of magma. The internal stratigraphy of all four WTT eruptive units is a complex association of fallout, surge, and pyroclastic flow deposits. Each eruptive unit is organized into two facies associations, Facies Association A below Facies Association B. The emplacement of the two facies associations may have been separated by short time breaks allowing for limited reworking and erosion. Facies Association A consists of interbedded fallout deposits, surge deposits, and subordinate ignimbrites. This facies association involved the eruption of the most evolved trachytic magma, and pumice clasts are white and well vesiculated. The grain size coarsens upward in Facies Association A, with upward increases of dune bedform wavelengths and a decrease in the proportion of fine ash. These trends could reflect an increase in eruption column height from the onset of the eruption and possibly also in mass eruption rate. Facies Association B comprises massive ignimbrites that are progressively richer in lithic clast content. This association involved the eruption of more mafic magma, and pumice clasts are gray and poorly vesiculated. Facies Association B is interpreted to record the climax of the eruption. Phreatomagmatic deposits occur at different stratigraphic levels in the four WTT and have different facies characteristics. The deposits reflect the style and degree of magma–water interaction and the local hydrogeology. Very fine-grained, lithic-poor phreatomagmatic surge deposits found at the base of WTT Cupa and WTT Galluccio could record the interaction of the erupting magma with a lake that occupied the Roccamonfina summit depression. Renewed magma–water interaction later in the WTT Galluccio eruption is indicated by fine grained, lithic-bearing phreatomagmatic fall and surge deposits occurring at the top of Facies Association A. They could be interpreted to reflect shifts of the magma fragmentation level to highly transmissive, regional aquifers located beneath the Roccamonfina edifice, possibly heralding a caldera collapse event. Received: 26 August 1996 / Accepted: 27 February 1998     

Complex spatter- and pumice-rich pyroclastic deposits from an andesitic caldera-forming eruption: the Siwi pyroclastic sequence,Tanna, Vanuatu

The small- to moderate-volume, Quaternary, Siwi pyroclastic sequence was erupted during formation of a 4 km-wide caldera on the eastern margin of Tanna, an island arc volcano in southern Vanuatu. This high-potassium, andesitic eruption followed a period of effusive basaltic andesite volcanism and represents the most felsic magma erupted from the volcano. The sequence is up to 13 m thick and can be traced in near-continuous outcrop over 11 km. Facies grade laterally from lithic-rich, partly welded spatter agglomerate along the caldera rim to two medial, pumiceous, non-welded ignimbrites that are separated by a layer of lithic-rich, spatter agglomerate. Juvenile clasts comprise a wide range of densities and grain sizes. They vary between black, incipiently vesicular, highly elongate spatter clasts that have breadcrusted pumiceous rinds and reach several metres across to silky, grey pumice lapilli. The pumice lapilli range from highly vesicular clasts with tube or coalesced spherical vesicles to denser finely vesicular clasts that include lithic fragments.Textural and lithofacies characteristics of the Siwi pyroclastic sequence suggest that the first phase of the eruption produced a base surge deposit and spatter-poor pumiceous ignimbrite. A voluminous eruption of spatter and lithic pyroclasts coincided with a relatively deep withdrawal of magma presumably driven by a catastrophic collapse of the magma chamber roof. During this phase, spatter clasts rapidly accumulated in the proximal zone largely as fallout, creating a variably welded and lithic-rich agglomerate. This phase was followed by the eruption of moderately to highly vesiculated magma that generated the most widespread, upper pumiceous ignimbrite. The combination of spatter and pumice in pyroclastic deposits from a single eruption appears to be related to highly explosive, magmatic eruptions involving low-viscosity magmas. The combination also indicates the coexistence of a spatter fountain and explosive eruption plume for much of the eruption.Editorial responsibility: R. Cioni     

Tephra-fall deposits from the 1992 eruption of Crater Peak, Alaska: implications of clast textures for eruptive processes

 The 1992 eruption of Crater Peak, Mount Spurr, Alaska, involved three subplinian tephra-producing events of similar volume and duration. The tephra consists of two dense juvenile clast types that are identified by color, one tan and one gray, of similar chemistry, mineral assemblage, and glass composition. In two of the eruptive events, the clast types are strongly stratified with tan clasts dominating the basal two thirds of the deposits and gray clasts the upper one third. Tan clasts have average densities between 1.5 and 1.7 g/cc and vesicularities (phenocryst free) of approximately 42%. Gray clasts have average densities between 2.1 and 2.3 g/cc, and vesicularities of approximately 20%; both contain abundant microlites. Average maximum plagioclase microlite lengths (13–15 μm) in gray clasts in the upper layer are similar regardless of eruptive event (and therefore the repose time between them) and are larger than average maximum plagioclase microlite lengths (9–11 μm) in the tan clasts in the lower layer. This suggests that microlite growth is a response to eruptive processes and not to magma reservoir heterogeneity or dynamics. Furthermore, we suggest that the low vesicularities of the clasts are due to syneruptive magmatic degassing resulting in microlitic growth prior to fragmentation and not to quenching of clasts by external groundwater. Received: 5 September 1997 / Accepted: 1 February 1998     

Ignimbrites of the Roque Nublo group, Gran Canaria, Canary Islands

 Non-welded, lithic-rich ignimbrites, hereintermed the Roque Nublo ignimbrites, are the most distinctive deposits of the Pliocene Roque Nublo group, which forms the products of second magmatic cycle on Gran Canaria. They are very heterogeneous, with 35–55% volume lithic fragments, 15-30% mildly vesiculated pumice, 5–7% crystals and 20–30% ash matrix. The vitric components (pumice fragments and ash matrix) are largely altered and transformed into zeolites and subordinate smectites. The Roque Nublo ignimbrites originated from hydrovolcanic eruptions that caused rapid and significant erosion of vents thus incorporating a high proportion of lithic clasts into the eruption columns. These columns rapidly became too dense to be sustained as vertical eruption columns and were transformed into tephra fountains which fed high-density pyroclastic flows. The deposits from these flows were mainly confined to palaeovalleys and topographic depressions. In distal areas close to the coast line, where these palaeovalleys widened, most of the pyroclastic flows expanded laterally and formed numerous thin flow units. The combined effect of the magma–water interaction and the high content of lithic fragments is sufficient to explain the characteristic low emplacement temperature of the Roque Nublo ignimbrites. This fact also explains the transition from pyroclastic flows into lahar deposits observed in distal facies of the Roque Nublo ignimbrites. The existence of hydrovolcanic eruptions generating high-density pyroclastic flows, unable to efficiently separate the water vapour from the vitric components during transport, also accounts for the intense zeolitic alteration in these deposits. Received: 5 November 1996 / Accepted: 3 March 1997     

Degassing and microlite crystallization during pre-climactic events of the 1991 eruption of Mt. Pinatubo, Philippines

 Dacite tephras produced by the 1991 pre-climactic eruptive sequence at Mt. Pinatubo display extreme heterogeneity in vesicularity, ranging in clast density from 700 to 2580 kg m^–3. Observations of the 13 surge-producing blasts that preceded the climactic plinian event include radar-defined estimates of column heights and seismically defined eruptive and intra-eruptive durations. A comparison of the characteristics of erupted material, including microlite textures, chemical compositions, and H₂O contents, with eruptive parameters suggests that devolatilization-induced crystallization of the magma occurred to a varying extent prior to at least nine of the explosive events. Although volatile loss progressed to the same approximate level in all of the clasts analyzed (weight percent H₂O=1.26-1.73), microlite crystallization was extremely variable (0–22%). We infer that syn-eruptive volatile exsolution from magma in the conduit and intra-eruptive separation of the gas phase was facilitated by the development of permeability within magma residing in the conduit. Correlation of maximum microlite crystallinity with repose interval duration (28–262 min) suggests that crystallization occurred primarily intra-eruptively, in response to the reduction in dissolved H₂O content that occurred during the preceding event. Detailed textural characterization, including determination of three-dimensional shapes and crystal size distributions (CSD), was conducted on a subset of clasts in order to determine rates of crystal nucleation and growth using repose interval as the time available for crystallization. Shape and size analysis suggests that crystallization proceeded in response to lessening degrees of feldspar supersaturation as repose interval durations increased. We thus propose that during repose intervals, a plug of highly viscous magma formed due to the collapse of vesicular magma that had exsolved volatiles during the previous explosive event. If plug thickness grew proportionally to the square root of time, and if magma pressurization increased during the eruptive sequence, the frequency of eruptive pulses may have been modulated by degassing of magma within the conduit. Dense clasts in surge deposits probably represent plug material entrained by each subsequent explosive event. Received: 4 December 1997 / Accepted: 13 September 1998     

Sub-volcanic crystallization at Stromboli (Aeolian Islands, southern Italy) preceding the Sciara del Fuoco sector collapse: evidence from monzonite lithic suite

 We describe texture, mineralogy and whole-rock composition of cognate monzonite sub-volcanic clasts within debris flow deposits related to the 5000 years catastrophic phreatomagmatic eruption probably linked to the Sciara del Fuoco sector collapse. The debris flows are at the top of accretionary lapilli-rich ash deposits overlying potassic (KS, shoshonites) lavas of the Neostromboli period. The monzonites are inferred to be crystallized in situ, at low P, at the side walls and/or roof margins of a shallow magma chamber and to be cogenetic with the KS Neostromboli extrusives. They can be considered "ideal orthocumulates" since they approximately retain a bulk liquid composition and possibly represent "slowly cooled equivalents" of their KS shoshonite host rock. The "closure temperature" of final solidification of the monzonite lithic suite was estimated through ternary-feldspar geothermobarometry, plagioclase–K-feldspar and K-feldspar–biotite equilibria and is in the range of 750–790  °C with a maximum –logfO₂ around 15.1–15.3. The estimated pressure of crystallization is <0.5 kbar. Potassic lavas and dikes, previously emplaced during the Neostromboli period, also resemble the monzonites in both major trace elements and mineral chemistry. The cogenetic relationship between KS Neostromboli extrusives and the monzonite host-rock magma from which the sub-volcanic clasts were derived is clear evidence that a shallow magma chamber existed between the caldera collapse of the Vancori period and the Sciara del Fuoco sector collapse (i.e. between 13 000 and 5000 years). The monzonite clasts were derived from crystallization at very shallow depth (ca. 1 km) and strongly support the hypothesis of violent decompression of the shallow magmatic plumbing system during the Sciara del Fuoco sector collapse. Climax of the regressive landslide event, with maximum disruption of the chamber walls, took place during emplacement of the debris flows, i.e. during the late stage of the Neostromboli phreatomagmatic eruption. Received: 15 September 1996 / Accepted: 5 May 1997     

Progressive assembly of a massive layer of ignimbrite with a normal-to-reverse compositional zoning: the Zaragoza ignimbrite of central Mexico

The Zaragoza ignimbrite and two enclosing rhyodacite pumice fall layers were emplaced during the 15 km³ (DRE), ∼0.1 Ma Zaragoza eruption from Los Humeros volcanic centre, 180 km east of Mexico City. The ignimbrite comprises several massive flow-units, the largest of which locally exceeds 20 m in thickness and is regionally traceable. It comprises massive lapilli-ash with vertical elutriation pipes, and has a fine-grained inverse-graded base and a pumice concentration zone at the top. It also exhibits an unusual gradational ‘double’ vertical compositional zonation that is widely traceable. A basal rhyodacitic (67.6–69 wt% SiO₂) zone grades up via a mixed zone into a central andesitic (58–62 wt% SiO₂) zone, which, in turn, grades up into an upper rhyodacitic (67.6–69 wt% SiO₂) zone. Zoning is also defined by vertical variations in lithic clast populations. We infer that pyroclastic fountaining fed initially rhyodacite pumice clasts to a sustained granular fluid-based pyroclastic density current. The composition of the pumice clasts supplied to the current then gradually changed, first to andesite and then back to rhyodacite. Inverse grading at the base of the massive layer may reflect initial waxing flow competence. The pumice concentration at the top of the massive layer is entirely rhyodacitic and was probably deposited during waning stages of the current, when the supply of andesitic pumice clasts had ceased. The return to rhyodacitic composition may have been the result of eruption-conduit modification during collapse of Los Potreros caldera, marked in the ignimbrite by a widespread influx of hydrothermally altered lithic blocks, and/or a decrease in draw-up depth from a compositionally stratified magma chamber as the eruptive mass flux waned. The massive layer of ignimbrite thins locally to less than 2 m, yet it still shows the double zonation. Correlation of the zoning suggests that the thin massive layer is stratigraphically condensed, and aggraded relatively slowly during the same time interval as did the much thicker (≤50 m) massive layer.Editorial responsibility: J McPhie     

Petrology of gabbroic xenoliths in 1960 Kilauea basalt: crystalline remnants of prior (1955) magmatism

The 1960 Kapoho lavas of Kilauea’s east rift zone contain 1–10 cm xenoliths of olivine gabbro, olivine gabbro-norite, and gabbro norite. Textures are poikilitic (ol+sp+cpx in pl) and intergranular (cpx+pl±ol±opx). Poikilitic xenoliths, which we interpret as cumulates, have the most primitive mineral compositions, Fo_82.5, cpx Mg# 86.5, and An_80.5. Many granular xenoliths (ol and noritic gabbro) contain abundant vesicular glass that gives them intersertal, hyaloophitic, and overall ‘open’ textures to suggest that they represent ‘mush’ and ‘crust’ of a magma crystallization environment. Their phase compositions are more evolved (Fo_80–70, cpx Mg# 82–75, and An_73–63) than those of the poikilitic xenoliths. Associated glass is basaltic, but evolved (MgO 5 wt%; TiO₂ 3.7–5.8 wt%). The gabbroic xenolith mineral compositions fit existing fractional crystallization models that relate the origins of various Kilauea lavas to one another. FeO/MgO crystal–liquid partitioning is consistent with the poikilitic ol-gabbro assemblage forming as a crystallization product from Kilauea summit magma with ∼8 wt% MgO that was parental to evolved lavas on the east rift zone. For example, least squares calculations link summit magmas to early 1955 rift-zone lavas (∼5 wt% MgO) through ∼28–34% crystallization of the ol+sp+cpx+pl that comprise the poikilitic ol-gabbros. The other ol-gabbro assemblages and the olivine gabbro-norite assemblages crystallized from evolved liquids, such as represented by the early 1955 and late 1955 lavas (∼6.5 wt% MgO) of the east rift zone. The eruption of 1960 Kapoho magmas, then, scoured the rift-zone reservoir system to entrain portions of cumulate and solidification zones that had coated reservoir margins during crystallization of prior east rift-zone magmas. Received: January 7, 1993/Accepted: November 23, 1993     

Evolution of the late Pleistocene Mojanda–Fuya Fuya volcanic complex (Ecuador), by progressive adakitic involvement in mantle magma sources

The Mojanda–Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of viscous Si-rich andesitic lavas and dacitic domes, and the emission of a thick sequence of pyroclastic-flow and fallout deposits which include two voluminous rhyolitic layers. An intermediate construction phase at Fuya Fuya is represented by a mainly effusive cone, andesitic in composition (San Bartolo edifice), the construction of which was interrupted by a major sector collapse in the Late Pleistocene. Finally, a complex of thick siliceous lavas and domes was emplaced within the avalanche amphitheatre, forming the Upper Fuya Fuya volcanic centre. This paper shows that the general evolution from an effusive to an explosive eruptive style is related to a progressive adakitic contribution to the magma source. Although all the rocks of the complex are included in the medium-K field of continental arcs, the Fuya Fuya suite (61–75 wt.% SiO₂) shows depletion in Y and HREE and high Sr/Y and La/Yb values, compared to the less silicic Mojanda suite (55–66.5 wt.% SiO₂). The Mojanda calc-alkaline suite was generated by partial melting of an adakite-metasomatised mantle source that left a residue with 2% garnet, followed by fractional crystallization of dominant plagioclase + pyroxene + olivine at shallow, intra-crustal depths. For Fuya Fuya, geochemical and mineralogical data suggest either (1) partial melting of a similar metasomatised mantle with more garnet in the residue (4%), followed by fractional crystallization involving plagioclase, amphibole and pyroxene, or (2) mixing of mafic mantle-derived magma from the Mojanda suite and slab melts, followed by the same fractional crystallization process.     

The Middle Scoria sequence: A Holocene violent strombolian, subplinian and phreatomagmatic eruption of Okmok volcano, Alaska

The Middle Scoria deposit represents an explosive eruption of basaltic andesite magma (54 wt. % SiO₂) from Okmok volcano during mid-Holocene time. The pattern of dispersal and characteristics of the ejecta indicate that the eruption opened explosively, with ash textural evidence for a limited degree of phreatomagmatism. The second phase of the eruption produced thick vesicular scoria deposits with grain texture, size and dispersal characteristics that indicate it was violent strombolian to subplinian in style. The third eruptive phase produced deposits with a shift towards grain shapes that are dense, blocky, and poorly vesicular, and intermittent surge layers, indicating later transitions between magmatic (violent strombolian) to phreatomagmatic (vulcanian) eruptive styles. Isopach maps yield bulk volume estimates that range from 0.06 to 0.43 km³, with ~ 0.04 to 0.25 km³ total DRE. The associated column heights and mass discharge values calculated from isopleth maps of individual Middle Scoria layers are 8.5 – 14 km and 0.4 to 45 × 10⁶ kg/s. The Middle Scoria tephras are enriched in plagioclase microlites that have the textural characteristics of rapid magma ascent and relatively high degrees of effective undercooling. Those textures probably reflect the rapid magma ascent accompanying the violent strombolian and subplinian phases of the eruption. In the later stages of the eruption, the plagioclase microlite number densities decrease and textures include more tabular plagioclase, indicating a slowing of the ascent rate. The findings on the Middle Scoria are consistent with other explosive mafic eruptions, and show that outside of the two large caldera-forming eruptions, Okmok is also capable of producing violent mafic eruptions, marked by varying degrees of phreatomagmatism.     

Rift-related Jurassic basaltic phreatomagmatic volcanism in the central Transantarctic Mountains: precursory stage to flood-basalt effusion

 The Middle Jurassic Kirkpatrick flood basalts and comagmatic Ferrar intrusions in the Transantarctic Mountains represent a major pulse of tholeiitic magmatism related to early stages in the breakup of Gondwana. A record of the volcano-tectonic events leading to formation of this continental flood-basalt province is provided by strata underlying and only slightly predating the Kirkpatrick lavas. In the central Transantarctic Mountains, the lavas rest on widespread (≥7500 km²) tholeiitic pyroclastic deposits of the Prebble Formation. The Prebble Formation is dominated by lahar deposits and is an unusual example of a regionally developed basaltic lahar field. Related, partly fault-controlled pyroclastic intrusions cut underlying strata, and vents are represented by the preserved flanks of two small tephra cones associated with a volcanic neck. Lahar and air-fall deposits typically contain 50–60% accidental lithic fragments and sand grains derived from underlying Triassic – Lower Jurassic strata in the upper part of the Beacon Supergroup. Juvenile basaltic ash and fine lapilli consist of nonvesicular to scoriaceous tachylite, sideromelane, and palagonite, and have characteristics indicating derivation from hydrovolcanic eruptions. The abundance of accidental debris from underlying Beacon strata points to explosive phreatomagmatic interaction of basaltic magma with wet sediment and groundwater, which appears to have occurred in particular where rising magma intersected upper Beacon sand aquifers. Composite clasts in the lahar deposits exhibit complex peperitic textures formed during fine-scale intermixing of basaltic magma with wet sand and record steps in subsurface fuel-coolant interactions leading to explosive eruption. The widespread, sustained phreatomagmatic activity is inferred to have occurred in a groundwater-rich topographic basin linked to an evolving Jurassic rift zone in the Transantarctic Mountains. Coeval basaltic phreatomagmatic deposits of the Mawson and Exposure Hill Formations, which underlie exposures of the Kirkpatrick Basalt up to 1500 km to the north along strike in Victoria Land, appear to represent other parts of a regional, extension-related Middle Jurassic phreatomagmatic province which developed immediately prior to rapid outpouring of the flood basalts. This is consistent with models which assign an important role to lithospheric stretching in the generation of flood-basalt provinces. Received: 28 August 1995 / Accepted: 18 April 1996     

Eruptive history and petrology of Mount Drum volcano,Wrangell Mountains,Alaska

Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80×200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occurred in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km³ of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO₂, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in ⁸⁷Sr/⁸⁶Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and disequilibrium mineral assemblages. In addition, some dacites and andesites contain Mg and Ni-rich olivines and/or have high MgO, Cr, Ni, Co, and Sc contents that are not in equilibrium with the host rock and indicate mixing between basalt or cumulate material and more evolved magmas. Incompatible element variations suggest that fractionation is responsible for some of the compositional range between basaltic andesite and dacite, but the rhyolites have K, Ba, Th, and Rb contents that are too low for the magmas to be generated by fractionation of the intermediate rocks. Limited Sr-isotope data support the possibility that the rhyolites may be partial melts of underlying volcanic rocks. Received March 13, 1993/Accepted September 10, 1993     

Formation of the mid-fifteenth century Kuwae caldera (Vanuatu) by an initial hydroclastic and subsequent ignimbritic eruption

In the mid-fifteenth century, one of the largest eruptions of the last 10 000 years occurred in the Central New Hebrides arc, forming the Kuwae caldera (12x6 km). This eruption followed a late maar phase in the pre-caldera edifice, responsible for a series of alternating hydromagmatic deposits and airfall lapilli layers. Tuffs related to caldera formation ( 120 m of deposits on a composite section from the caldera wall) were emitted during two main ignimbritic phases associated with two additional hydromagmatic episodes. The lower hydromagmatic tuffs from the precaldera maar phase are mainly basaltic andesite in composition, but clasts show compositions ranging from 48 to 60% SiO₂. The unwelded and welded ashflow deposits from the ignimbritic phases and the associated intermediate and upper hydromagmatic deposits also show a wide compositional range (60–73% SiO₂), but are dominantly dacitic. This broad compositional range is thought to be due to crystal fractionation. The striking evolution from one eruptive style (hydromagmatic) to the other (magmatic with emission of a large volume of ignimbrites) which occurred either over the tuff series as a whole, or at the beginning of each ignimbritic phase, is the most impressive characteristic of the caldera-forming event. This strongly suggests triggering of the main eruptive phases by magma-water interaction. A three-step model of caldera formation is presented: (1) moderate hydromagmatic (sequences HD 1–4) and magmatic (fallout deposits) activity from a central vent, probably over a period of months or years, affected an area slightly wider than the present caldera. At the end of this stage, intense seismic activity and extrusion of differentiated magma outside the caldera area occurred; (2) unhomogenized dacite was released during a hydromagmatic episode (HD 5). This was immediately followed by two major pyroclastic flows (PFD 1 and 2). The vents spread and intense magma-water interaction at the beginning of this stage decreased rapidly as magma discharge increased. Subsequent collapse of the caldera probably commenced in the southeastern sector of the caldera; (3) dacitic welded tuffs were emplaced during a second main phase (WFD 1–5). At the beginning of this phase, magma-water interaction continued, producing typical hydromagmatic deposits (HD 6). Caldera collapse extended to the northern part of the caldera. Previous C¹⁴ dates and records of explosive volcanism in ice from the south Pole show that the climactic phase of this event occurred in 1452 A.D.     

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.     

Lateral variations within coarse co-ignimbrite lithic breccias of the Kos Plateau Tuff, Greece

 Coarse, co-ignimbrite lithic breccia, Ebx, occurs at the base of ignimbrite E, the most voluminous and widespread unit of the Kos Plateau Tuff (KPT) in Greece. Similar but generally less coarse-grained basal lithic breccias (Dbx) are also associated with the ignimbrites in the underlying D unit. Ebx shows considerable lateral variations in texture, geometry and contact relationships but is generally less than a few metres thick and comprises lithic clasts that are centimetres to a few metres in diameter in a matrix ranging from fines bearing (F2: 10 wt.%) to fines poor (F2: 0.1 wt.%). Lithic clasts are predominantly vent-derived andesite, although clasts derived locally from the underlying sedimentary formations are also present. There are no proximal exposures of KPT. There is a highly irregular lower erosional contact at the base of ignimbrite E at the closest exposures to the inferred vent, 10–14 km from the centre of the inferred source, but no Ebx was deposited. From 14 to <20 km from source, Ebx is present over a planar erosional contact. At 16 km Ebx is a 3-m-thick, coarse, fines-poor lithic breccia separated from the overlying fines-bearing, pumiceous ignimbrite by a sharp contact. This grades downcurrent into a lithic breccia that comprises a mixture of coarse lithic clasts, pumice and ash, or into a thinner one-clast-thick lithic breccia that grades upward into relatively lithic-poor, pumiceous ignimbrite. Distally, 27 to <36 km from source Ebx is a finer one-clast-thick lithic breccia that overlies a non-erosional base. A downcurrent change from strongly erosional to depositional basal contacts of Ebx dominantly reflects a depletive pyroclastic density current. Initially, the front of the flow was highly energetic and scoured tens of metres into the underlying deposits. Once deposition of the lithic clasts began, local topography influenced the geometry and distribution of Ebx, and in some cases Ebx was deposited only on topographic crests and slopes on the lee-side of ridges. The KPT ignimbrites also contain discontinuous lithic-rich layers within texturally uniform pumiceous ignimbrite. These intra-ignimbrite lithic breccias are finer grained and thinner than the basal lithic breccias and overlie non-erosional basal contacts. The proportion of fine ash within the KPT lithic breccias is heterogeneous and is attributed to a combination of fluidisation within the leading part of the flow, turbulence induced locally by interaction with topography, flushing by steam generated by passage of pyroclastic density currents over and deposition onto wet mud, and to self-fluidisation accompanying the settling of coarse, dense lithic clasts. There are problems in interpreting the KPT lithic breccias as conventional co-ignimbrite lithic breccias. These problems arise in part from the inherent assumption in conventional models that pyroclastic flows are highly concentrated, non-turbulent systems that deposit en masse. The KPT coarse basal lithic breccias are more readily interpreted in terms of aggradation from stratified, waning pyroclastic density currents and from variations in lithic clast supply from source. Received: 21 April 1997 / Accepted: 4 October 1997     

Heterogeneous andesite–dacite ejecta in 26–16.6 ka pyroclastic deposits of Tongariro Volcano,New Zealand: the product of multiple magma-mixing events

The previously poorly documented 26–16.6 ka interval of pyroclastic volcanism from Tongariro Volcano is marked by three distal lapilli fall units (Rt1-3) exposed in ring-plain deposits. The distal Rt1-3 units are tentatively correlated to proximal scoria deposits on the upper slopes of North Crater based on their dispersal patterns, petrography and geochemistry. Lapilli in each of the Rt1-3 deposits are characterised by variable groundmass crystallinity, vesicularity and colour within individual clasts. Matrix glasses are mostly microlite-free, and compositionally diverse across the deposits (SiO₂ = 62–75 wt%), with wide composition ranges occurring within single clasts. The glasses represent different melts that were mingled and mixed shortly before eruption; a finding supported by widely variable Fe–Ti oxide equilibrium temperature estimates (∼830–1,200°C). Ranges of 30–160°C (typically 70°C) occur within individual clasts. Some clinopyroxene crystals display Mg-rich (∼Mg #88) rim zones around homogeneous low-Mg (∼Mg #68) cores, with abrupt transition zones. This zoning is interpreted as resulting from the injection of a more mafic melt into a stagnating, resident magma. Crystal-melt equilibria indicate that several episodes of mafic intrusion occurred, to produce hybrid melts with zoned crystals forming isolated ponds within the resident magma. Variable mixing from the percolation of melts and the coalescence of melt ponds would explain the wide range of melt compositions and equilibrium temperatures observed in the ejecta. The magma heterogeneity was preserved by quenching on prompt eruption, with much of the short-duration chaotic mixing of melts and crystals occurring in the conduit. The Rt1-3 eruptions were from an open magmatic system consisting of one or more long-lived stagnant crystal mush zones, from which eruptions were rapidly triggered by new injections of mafic magmas from greater depths. A similar pattern of magmatic dynamics was observed in the much smaller 1995 eruptions of the neighbouring Ruapehu Volcano.     

Magma mingling in an andesite pyroclastic flow of the Pourahu Member, Ruapehu volcano, New Zealand

We describe a magma mingling episode from Ruapehu volcano between two andesite magmas, one very much minor in volume relative to the other. The event acted to trigger eruption of the andesitic Pourahu pyroclastic flow which is preserved in a thick sequence of tephras and laharic deposits in the southeastern ring plain of the volcano. The predominant andesite is pale brown coloured and porphyritic containing phenocrysts of plagioclase-clinopyroxene-orthopyroxene-Fe-Ti oxides. Rare clasts of a darker andesite are different texturally, less vesicular, and contain distinctive microphenocrysts of plagioclase and quench olivine. Equally rare clasts, of streaky pumice consisting of interbanded ‘dark’ and ‘light’ andesite attest to mingling between these two andesite components.Chemical analyses of discrete clasts demonstrate that the Pourahu pyroclastic flow andesites span much of the compositional spectrum of Ruapehu andesites. This observation demonstrates heterogeneity in the products of a relatively small eruption. The darker clast analyses and those from associated distal fall deposits lie within the fields defined by the dominant light coloured clasts. Phenocryst and microphenocryst geothermometry suggest slightly higher temperatures in the dark component. However, glasses from groundmass and phenocryst inclusions in the same specimen may differ considerably, leading us to conclude that many phenocrysts are in fact xenocrystic and were incorporated in the melts as they migrated towards the surface.We prefer a model in which a small volume of hot andesite magma injects a vent-feeding magma chamber, triggering vesiculation and eruption. We infer that the process of magma withdrawal extended downward into the magma body causing the dark component to intermingle with the lighter (dominant) component, ‘sucking’ more dark magma into the chamber. Our observations are entirely consistent with the existence of a plexus of small, possibly interlinked magma chambers beneath Ruapehu.     

Temporal variations in magma composition at Merapi Volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity

Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 ¹⁴C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO₂) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO₂) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO₂ contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO₂ range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.     

The rhyolitic–andesitic eruptive history of Cotopaxi volcano,Ecuador

At Cotopaxi volcano, Ecuador, rhyolitic and andesitic bimodal magmatism has occurred periodically during the past 0.5 Ma. The sequential eruption of rhyolitic (70–75% SiO₂) and andesitic (56–62% SiO₂) magmas from the same volcanic vent over short time spans and without significant intermingling is characteristic of Cotopaxi’s Holocene behavior. This study documents the eruptive history of Cotopaxi volcano, presenting its stratigraphy and geologic field relations, along with the relevant mineralogical and chemical nature of the eruptive products, in order to determine the temporal and spatial relations of this bimodal alternation. Cotopaxi’s history begins with the Barrancas rhyolite series, dominated by pumiceous ash flows and regional ash falls between 0.4 and 0.5 Ma, which was followed by occasional andesitic activity, the most important being the ample andesitic lava flows (∼4.1 km³) that descended the N and NW sides of the edifice. Following a ∼400 ka long repose without silicic activity, Cotopaxi began a new eruptive phase about 13 ka ago that consisted of seven rhyolitic episodes belonging to the Holocene F and Colorado Canyon series; the onset of each episode occurred at intervals of 300–3,600 years and each produced ash flows and regional tephra falls with DRE volumes of 0.2–3.6 km³. Andesitic tephras and lavas are interbedded in the rhyolite sequence. The Colorado Canyon episode (4,500 years BP) also witnessed dome and sector collapses on Cotopaxi’s NE flank which, with associated ash flows, generated one of the largest cohesive debris flows on record, the Chillos Valley lahar. A thin pumice lapilli fall represents the final rhyolitic outburst which occurred at 2,100 years BP. The pumices of these Holocene rhyolitic eruptions are chemically similar to those of older rhyolites of the Barrancas series, with the exception of the initial eruptive products of the Colorado Canyon series whose chemistry is similar to that of the 211 ka ignimbrite of neighboring Chalupas volcano. Since the Colorado Canyon episode, andesitic magmatism has dominated Cotopaxi’s last 4,400 years, characterized by scoria bomb and lithic-rich pyroclastic flows, infrequent lava flows that reached the base of the cone, andesitic lapilli and ash falls that were carried chiefly to the W, and large debris flows. Andesitic magma emission rates are estimated at 1.65 km³ (DRE)/ka for the period from 4,200 to 2,100 years BP and 1.85 km³ (DRE)/ka for the past 2,100 years, resulting in the present large stratocone.     

Erosion by pyroclastic flows on Lascar Volcano, Chile

 Pyroclastic flows generated in the 19–20 April 1993 eruption of Lascar Volcano, Chile, produced spectacular erosion features. Scree and talus were stripped from the channels and steep slopes on the flanks of the volcano. Exposed bedrock and boulders suffered severe abrasion, producing smoothed surfaces on coarse breccias and striations and percussion marks on bedrock and large boulders. Erosional furrows developed with wavelengths of 0.5–2 m and depths of 0.1–0.3 m. Furrows commonly nucleated downstream of large boulders or blocks, which are striated on the upstream side, and thereby produced crag-and-tail structures. Erosive features were produced where flows accelerated through topographic restrictions or where they moved over steep slopes. The pyroclastic flows are inferred to have segregated during movement into lithic-rich and pumice-rich parts. Lithic-rich deposits occur on slopes up to 14°, whereas pumice-rich deposits occur only on slopes less than 4°, and mainly at the margins and distal parts of the 1993 fan. The lithic-rich deposits contain large (up to 1 m) lithic clasts eroded from the substrate and transported from the vent, whereas pumice-rich deposits contain only small (typically <2 cm) lithic clasts. These observations suggest that lithic clasts segregated to the base of the flows and were responsible for much of the erosive phenomena. The erosive features, distribution of lithic clasts and deposit morphology indicate that the 1993 flows were highly concentrated avalanches dominated by particle interactions. In some places the flows slid over the bedrock causing abrasion and long striations which imply that large blocks were locked in fixed positions for periods of about 1 s. However, shorter striae at different angles, impact marks, segregation of the deposits into pumice- and lithic-rich parts, and mixing of bedrock-derived lithic clasts throughout the deposits indicate that clasts often had some freedom of movement and that jostling of particles allowed internal mixing and density segregation to occur within the flows. Received: 15 July 1996 / Accepted: 15 January 1997