Hydrochemical tracers in the middle Rio Grande Basin,USA: 2. Calibration of a groundwater-flow model

The calibration of a groundwater model with the aid of hydrochemical data has demonstrated that low recharge rates in the Middle Rio Grande Basin may be responsible for a groundwater trough in the center of the basin and for a substantial amount of Rio Grande water in the regional flow system. Earlier models of the basin had difficulty reproducing these features without any hydrochemical data to constrain the rates and distribution of recharge. The objective of this study was to use the large quantity of available hydrochemical data to help calibrate the model parameters, including the recharge rates. The model was constructed using the US Geological Surveys software MODFLOW, MODPATH, and UCODE, and calibrated using ¹⁴C activities and the positions of certain flow zones defined by the hydrochemical data. Parameter estimation was performed using a combination of nonlinear regression techniques and a manual search for the minimum difference between field and simulated observations. The calibrated recharge values were substantially smaller than those used in previous models. Results from a 30,000-year transient simulation suggest that recharge was at a maximum about 20,000 years ago and at a minimum about 10,000 years ago.

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Resumen La calibración de un modelo de aguas subterráneas con el apoyo de datos hidroquímicos ha demostrado que la recarga relativamente baja en la cuenca media del Río Grande es probablemente responsable de una depresión de aguas subterráneas en el centro de la cuenca y de la presencia de una cantidad considerable de agua del Río Grande en el acuífero del Grupo Santa Fe. Los modelos propuestos con anterioridad para la cuenca tenían dificultades para reproducir estas características ya que no tenían datos hidroquímicos que permitieran delimitar los ritmos y distribución de recarga. El objetivo del presente estudio consistió en utilizar una gran cantidad de datos hidroquímicos disponibles para ayudar a calibrar los parámetros del modelo, incluyendo los ritmos de recarga. El modelo se construyó utilizando los modelos MODFLOW, MODPATH, y UCODE del USGS, mientras que la calibración se realizó en base a concentraciones de ¹⁴C y a la posición de ciertas zonas definidas con los datos hidroquímicos. La estimación de parámetros se realizó en base a una combinación de técnicas de regresiones no lineares y a una búsqueda a viva fuerza del error mínimo entre los datos observados y los simulados. Los valores de recarga calibrados fueron significativamente más bajos que los estimados en los modelos anteriores. Los resultados de una simulación transitoria de 30,000 años sugieren que la recarga durante la última glacial máxima (LGM) fue diez veces el ritmo moderno, pero que la recarga que ocurrió inmediatamente después de la LGM fue más baja que el ritmo moderno.

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Résumé Le calibrage dun modèle hydrogéologique avec laide de données hydrochimiques a démontré que la recharge relativement faible dans le Grand Bassin du Middle Rio est vraisemblablement responsable dune dépression des eaux souterraines dans le centre du bassin et de la présence dune quantité substantielle deau du Rio Grande dans laquifère du Groupe de Santa Fe. Les modèles antérieurs avaient des difficultés à reproduire ses conclusions sans laide de données hydrochimiques pour contraindre les taux et la distribution de la recharge. Lobjectif de cette étude était dutiliser une grande quantité de données hydrochimiques permettant de calibrer les paramètres du modèle, et notamment les taux de recharge. Le modèle a été construit avec les logiciels MODFLOW, MODPATH et UCODE, et calibré en utilisant les concentrations en ¹⁴C et la position de certaines zones définies par les données hydrochimiques. Lestimation de certains paramètres a été réalisée en utilisant une combinaison de techniques de régression non linéaire et une méthode de recherche exhaustive (Brute Force Search) de lerreur minimum entre les résultats des observations et les simulations. Les valeurs de la recharge calibrée sont substantiellement plus basses que celles estimées dans les modèles antérieurs. Les résultats dune simulation en régime transitoire sur 30.000 ans suggèrent que la recharge au maximum de la dernière glaciation (last glacial maximum, LGM) était 10 fois supérieure au taux actuel, mais que la recharge qui a suivit la LGM était plus bas que la recharge actuelle.

     

Use of hydrogeochemistry and environmental isotopes for evaluation of groundwater in Qingshuihe Basin,northwestern China

Hydrogeochemistry and environmental isotope data were utilized to understand origin, geochemical evolution, hydraulic interconnection, and renewability of groundwater in Qingshuihe Basin, northwestern China. There are four types of groundwater: (1) shallow groundwater in the mountain front pluvial fans, originating from recent recharge by precipitation, (2) deep paleo-groundwater of the lower alluvial plains, which was formed long ago, (3) shallow groundwater in the lower alluvial plains, which has undergone evaporation during the recharge process, and (4) mixed groundwater (shallow and deep groundwater in the plain). The main water types are Na–HCO₃, which dominates type (1), and Na–SO₄, which dominates types (2) and (3). Geochemical evolution in the upper pluvial fans is mainly the result of CO₂ gas dissolution, silicates weathering and cation exchange; in the lower alluvial plains, it is related to mineral dissolution. The evaporative enrichment only produces significant salinity increases in the shallow groundwater of the lower alluvial plains. Shallow groundwater age in the upper plain is 10 years or so, showing a strong renewability. Deep groundwater ages in the lower plain are more than 200 years, showing poor renewability. In the exploitation areas, the renewability of groundwater evidently increases and the circulation period is 70–100 years.     

Hydrochemical and isotopical tracers in the lacustrine aquifer of the Cerro Prieto area, Baja California, México

A series of patterns in the chemical and isotopic composition of the groundwater of the Cerro Prieto area have been recognized. These patterns were used to define four hydrochemical and isotopical zones in the area. One of these areas located at the east side was found to be the source of recharge, while another in the central part is where an older aquifer exist in lacustrine deposits. The low permeability of the area causes the aquifer to act as an aquitard, which at least is partly surrounded by an interface zone where mixing of waters occurs. Tritium and radiocarbon method revealed that the aquitard is an isolate system whose residence time is of 32 ka.     

The hydrochemical characteristics and evolution of groundwater and surface water in the Heihe River Basin, northwest China

A combination of isotopic and chemical indicators has been used to characterize rainfall, surface water and groundwater in the Heihe River Basin, China. Surface- vs. groundwater chemistry data enabled geographical zones and chemical types to be differentiated. The dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite determine Na⁺, Cl^?, Mg²⁺, Ca²⁺, $ {\text{SO}}^{{2 - }}_{4} A combination of isotopic and chemical indicators has been used to characterize rainfall, surface water and groundwater in the Heihe River Basin, China. Surface- vs. groundwater chemistry data enabled geographical zones and chemical types to be differentiated. The dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite determine Na⁺, Cl⁻, Mg²⁺, Ca²⁺, and chemistry, but other processes such as evaporation, ion exchange, and deposition also influence the water composition. The majority of deep confined groundwaters are tritium-free and less mineralized than in the shallow aquifer. Radiocarbon values in the deeper groundwaters range from 18.8 to 38.9 pmc, and 80 pmc probably represents the upper limit of initial ¹⁴C activity; this yields ages of approximately 5,960–11,971 years BP, which is about 3,000 years older than those calculated by models in previous work. The shallow aquifer exhibits fairly high and variable tritium activities (4–75 TU), evidence of recent recharge and low residence time (<60 years), which is in line with estimates from previous work. Isotopic signatures indicate formation of deeper groundwaters in a colder and wetter climate during the late Pleistocene and Holocene. The results suggested that significant changes are urgently needed in water-use strategy to achieve sustainable development.

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Résumé Une combinaison de plusieurs indicateurs isotopiques et chimiques a été utilisée dans le but de caractériser les précipitations, les eaux de surface et les eaux souterraines dans le Bassin de la Rivière Heihe, en Chine. La confrontation des chimies des eaux souterraines et de surface a permis de différentier plusieurs secteurs géographiques et faciès chimiques. Les compositions chimiques en Na⁺, Cl⁻, Mg²⁺, Ca²⁺, et sont déterminées par la dissolution de la halite, du sel de Glauber, du gypse, de la dolomite et de la calcite, mais d’autres processus peuvent également avoir une influence, comme l’évaporation, les échanges de bases et la sédimentation. La majorité des eaux souterraines captives profondes ne contiennent pas de tritium, et sont moins minéralisées que dans l’aquifère superficiel. Les valeurs de carbone 14 dans l’aquifère le plus profond sont comprises entre 18.8 et 38.9 pcm, pour une valeur maximum probable d’activité initiale de 80 pcm; les ages estimés correspondants sont compris entre 5,960 et 11,971 ans, soit environ 3,000 ans de plus que ceux calculés auparavant par les modèles. L’aquifère superficiel présente des activités tritium plut?t élevées et variables (4 à 75 UT), démontrant l’existence d’une alimentation récente et d’un temps de résidence faible (<60 ans), ce qui concorde avec les études antérieures. Les signatures isotopiques indiquent une alimentation des eaux souterraines les plus profondes au cours d’épisodes climatiques plus froids et plus humides qu’actuellement, à la fin du Pléistocène et à l’Holocène. Les résultats suggèrent que des changements significatifs dans la planification des usages de l’eau sont nécessaires et urgents dans des perspectives d’exploitation durable.

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Resumen Se ha utilizado una combinación de indicadores isotópicos y químicos para caracterizar la precipitación, el agua superficial y el agua subterránea en la Cuenca del Río Heihe, China. Los datos químicos de aguas superficiales frente a las subterráneas no permiten diferenciar zonas geográficas y tipos químicos. La disolución de halita, sal de Glauber, yeso, dolomita y calcita determina la química de Na⁺, Cl⁻, Mg²⁺, Ca²⁺, y , pero otros procesos, como evaporación, intercambio de iones y precipitación influyen también en la composición del agua. La mayoría de las aguas subterráneas profundas confinadas no tienen Tritio y están menos mineralizados que el acuífero superficial. Los valores de radiocarbono en las aguas subterráneas más profundas oscilan entre 18.8 y 38.9 pmc, y el valor de 80 pmc representa probablemente el límite superior de la actividad inicial de ¹⁴C; proporcionando edades de aproximadamente 5,960–11,971 a?os BP, que son unos 3,000 a?os más antiguas de las calculadas mediante modelización en trabajos previos. El acuífero superficial tiene actividades de tritio bastante más altas y variables (4–75 UT), evidenciando una recarga reciente y unos tiempos de residencia bajos (<60 a?os), lo cual está en la línea de lo estimado en trabajos previos. Los datos isotópicos apuntan a la formación de aguas subterráneas más profundas en un clima más frío y húmedo durante el Pleistoceno superior y el Holoceno. Los resultados sugieren que se necesita hacer cambios significativos en la estrategia de uso del agua para alcanzar un desarrollo sostenible.

     

Environmental isotopic study on the recharge and residence time of groundwater in the Heihe River Basin, northwestern China

The recharge and origin of groundwater and its residence time were studied using environmental isotopic measurements in samples from the Heihe River Basin, China. δ¹⁸O and δD values of both river water and groundwater were within the same ranges as those found in the alluvial fan zone, and lay slightly above the local meteoric water line (δD=6.87δ¹⁸O+3.54). This finding indicated that mountain rivers substantially and rapidly contribute to the water resources in the southern and northern sub-basins. δ¹⁸O and δD values of groundwater in the unconfined aquifers of these sub-basins were close to each other. There was evidence of enrichment of heavy isotopes in groundwater due to evaporation. The most pronounced increase in the δ¹⁸O value occurred in agricultural areas, reflecting the admixture of irrigation return flow. Tritium results in groundwater samples from the unconfined aquifers gave evidence for ongoing recharge, with mean residence times of: less than 36 years in the alluvial fan zone; about 12–16 years in agricultural areas; and about 26 years in the Ejina oasis. In contrast, groundwater in the confined aquifers had ¹⁴C ages between 0 and 10 ka BP.     

Movement of water through the thick unsaturated zone underlying Oro Grande and Sheep Creek Washes in the western Mojave Desert,USA

Previous studies indicate that a small quantity of recharge occurs from infiltration of streamflow in intermittent streams in the upper Mojave River basin, in the western Mojave Desert, near Victorville, California. Chloride, tritium, and stable isotope data collected in the unsaturated zone between 1994 and 1998 from boreholes drilled in Oro Grande and Sheep Creek Washes indicate that infiltration of streamflow occurs to depths below the root zone, and presumably to the water table, along much of Oro Grande Wash and near the mountain front along Sheep Creek Wash. Differences in infiltration at sites along each wash are the result of hydrologic variables such as proximity to the mountain front, quantity of streamflow, and texture of the subsurface deposits. Differences in infiltration between the washes are the result of large-scale geomorphic processes. For example, Oro Grande wash is incised into the Victorville fan and infiltration has occurred at approximately the same location over recent geologic time. In contrast, Sheep Creek Wash overlies an active alluvial fan and the stream channel can move across the fan surface through time. Infiltration does not occur to depths below the root zone at control sites outside of the washes. Electronic Publication     

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

Hydrogeologic controls on groundwater recharge and salinization: a geochemical analysis of the northern Hueco Bolson aquifer, Texas, USA

Identification of hydrogeologic controls on groundwater flowpaths, recharge, and salinization is often critical to the management of limited arid groundwater resources. One approach to identifying these mechanisms is a combined analysis of hydrogeologic and hydrochemical data to develop a comprehensive conceptual model of a groundwater basin. To demonstrate this technique, water samples were collected from 33 discrete vertical zone test holes in the Hueco Bolson aquifer, located within the Trans-Pecos Texas region and the primary water resource for El Paso, Texas, USA and Juárez, Mexico. These samples were analyzed for a suite of geochemical tracers and the data evaluated in light of basin hydrogeology. On the basis of δ²H and δ¹⁸O data, two regional recharge sources were recognized, one originating from western mountain-fronts and one from through-flow of the adjacent Tularosa aquifer. Chloride concentrations were strongly correlated with lithologic formations and both Cl/Br and ³⁶Cl ratios suggested the primary chloride source is halite dissolution within a specific lithologic unit. In contrast, sulfur isotopes indicated that most sulfate originates from Tularosa basin Permian gypsum sources. These results yielded a more comprehensive conceptual model of the basin, which suggested that chloride salinization of wells is the result of upconing of waters from the Fort Hancock formation.     

Environmental isotopic and hydrochemical study of groundwater in the Ejina Basin,northwest China

The study investigates the groundwater evolution and its residence time in the Ejina Basin, northwest China according to isotope and hydrochemical analyses results. The groundwater chemistry is mainly controlled by the dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite, also influenced by other processes such as evaporation, ion exchange, and deposition. Based on tritium content in atmospheric precipitation and by adopting a model with exponential time distribution function, the mean residence time of the unconfined aquifer groundwater with fairly high tritium activities (21–49 TU) is evaluated. The results show that these groundwaters have low residence time (5–120 years) and are renewable. In contrast, the deep confined groundwaters are tritium-free and radiocarbon values range from 18.3 to 26.7 pmc. According to the most commonly used ¹⁴C correction models, the radiocarbon groundwater ages were calculated which yield ages of approximately 4,087–9,364 years BP. Isotopic signatures indicate formation of deep confined groundwaters in a colder and wetter climate during the late Pleistocene and Holocene. It is suggested that long-term, rational water usage guide should be set up for the Heihe River Basin as a whole to permit a considerable discharge to the Ejina Basin.     

Isotopes in the Hueco Bolson aquifer, Texas (USA) and Chihuahua (Mexico): local and general implications for recharge sources in alluvial basins

Stable isotope data for the Hueco Bolson aquifer (Texas, USA and Chihuahua, Mexico) distinguish four water types. Two types relate to recharge from the Rio Grande: pre-dam (pre-1916) river water with oxygen-18 and deuterium (δ¹⁸O, δD, ‰) from (?11.9, ?90) to (?10.1, ?82), contrasts with present-day river water (?8.5, ?74) to (?5.3, ?56). Pre-dam water is found beneath the Rio Grande floodplain and Ciudad Juárez, and is mixed with post-dam river water beneath the floodplain. Two other types relate to recharge of local precipitation; evidence of temporal change of precipitation isotopes is present in both types. Recharge from the Franklin and Organ Mountains plots between (?10.9, ?76) and (?8.5, ?60) on the global meteoric water line (GMWL), and is found along the western side of the Hueco Bolson, north of the Rio Grande. Recharge from the Diablo Plateau plots on an evaporation trend originating on the GMWL near (?8.5, ?58). This water is found in the southeastern Hueco Bolson, north of the river; evaporation may be related to slow recharge through fine-grained sediment. Pre-dam water, recognizable by isotope composition, provides information on groundwater residence times in this and other dammed river basins.     

Deep reaching fluid flow in the North East German Basin: origin and processes of groundwater salinisation

Major element chemistry, rare-earth element distribution, and H and O isotopes are conjointly used to study the sources of salinisation and interaquifer flow of saline groundwater in the North East German Basin. Chemical analyses from hydrocarbon exploration campaigns showed evidence of the existence of two different groups of brines: halite and halite Ca–Cl brines. Residual brines and leachates are identified by Br^?/Cl^? ratios. Most of the brines are dissolution brines of Permian evaporites. New analyses show that the pattern of rare-earth elements and yttrium (REY) are closely linked to H and O isotope distribution. Thermal brines from deep wells and artesian wells indicate isotopically evaporated brines, which chemically interacted with their aquifer environment. Isotopes and rare-earth element patterns prove that cross flow exists, especially in the post-Rupelian aquifer. However, even at depths exceeding 2,000 m, interaquifer flow takes place. The rare-earth element pattern and H and O isotopes identify locally ascending brines. A large-scale lateral groundwater flow has to be assumed because all pre-Rupelian aquifer systems to a depth of at least 500 m are isotopically characterised by Recent or Pleistocene recharge conditions.     

Distinguishing groundwater flow paths in different fractured-rock aquifers using groundwater chemistry: Dandenong Ranges, southeast Australia

Major ion geochemistry is used to qualitatively interpret groundwater residence times within an aquifer, and the extent of mixing between aquifers with distinctive mineralogy. In conjunction with hydraulic heads and stable isotope geochemistry, flow paths and inter-aquifer exchange are defined in a fractured-rock aquifer system in the Dandenong Ranges, southeast Australia. Stable isotopes indicate modern seasonal recharge throughout the system. At high elevations in the sub-catchment, which includes both marine Silurian-Devonian sedimentary and Tertiary basalt aquifers, Cl is derived primarily from cyclic salts, and differences in mineralogy result in groundwater from the basalt aquifer having higher TDS contents (123–262 mg/L) and (Ca+Mg)/Na ratios (0.9–1.3) than groundwater from the sedimentary aquifer (TDS: 55–79 mg/L; (Ca+Mg)/Na: 0.1–0.2). At low elevations, in areas of local groundwater discharge, the more regional flow system in the Silurian-Devonian sediments contains additional Cl from water–rock interaction and has distinctly higher TDS contents (517–537 mg/L). Differences in groundwater chemistry between the aquifers and between shallower and deeper flow systems highlights areas of inter-aquifer mixing. This is particularly important for aquifer vulnerability where groundwater quality in the deeper aquifer may be impacted by surface activities.

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Resumen Se ha utilizado geoquímica de iones mayores para interpretar cualitativamente los tiempos de residencia del agua subterránea dentro de un acuífero, y el grado de mezcla entre acuíferos con mineralogía característica. De manera conjunta con presiones hidráulicas y geoquímica de isótopos estables, se han definido trayectorias de flujo e intercambio entre acuíferos en un sistema de acuífero de roca fracturada en las Sierras Dandenong, sureste de Australia. Los isótopos estables indican recarga estacional moderada a través del sistema. A elevaciones altas en la sub-cuenca que incluye acuíferos sedimentarios Silúrico-Devónicos y acuíferos basálticos Terciarios, Cl se deriva principalmente de sales cíclicas. Las diferencias en mineralogía resultan en agua subterránea del acuífero basáltico que tiene mayores contenidos TDS (123–262 mg/L) y mayor relación (Ca+Mg)/Na (0.9–1.3) que el agua subterránea de los acuíferos sedimentarios (TDS:55–79 mg/L; (Ca+Mg)/Na: 0.1–0.2). A elevaciones bajas, en áreas de recarga local de agua subterránea, el sistema de flujo más regional en los sedimentos Silúrico-Devónicos contiene Cl adicional que se deriva de la interacción roca-agua y típico contenido TDS más alto (517–537 mg L). Las diferencias en la química del agua subterránea entre los acuíferos y entre los sistemas de flujo más profundo y más somero resalta áreas de mezcla entre acuíferos. Esto es particularmente importante para la vulnerabilidad del acuífero donde la calidad del agua subterránea en el acuífero más profundo puede ser impactada por las actividades superficiales.

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Résumé Les ions majeurs sont utilisés pour interpréter quantitativement les temps de résidence des eaux souterraines dans les aquifères, et létendue des zones de mélange entre les aquifères de différentes minéralogies. En regard de la répartition des charges hydrauliques et des informations données par les isotopes stables, les écoulements et les échanges inter-aquifères sont définis dans un aquifère fracturé dans le Dandenong Ranges, SE de lAustralie. Les isotopes stables indiquent des recharges modernes et saisonnières à travers le système aquifère. A haute altitude dans le sous-bassin versant, qui inclut des sédiments du Siluro-Dévonien et des basaltes du Tertiaire, le chlore est dabord dérivé des sels cycliques, et des différences minéralogiques dans les eaux souterraines sont observées selon laquifère : basalte tertiaire (TDS: 123–262 mg/L; Ca+Mg/Ca: 0.9 à 1.3) et sédiments primaires (TDS: 55–79 mg/L; Ca+Mg/Ca: 0.1–0.2). Aux basses altitudes, dans les zones locales de décharge des eaux souterraines, les écoulements les plus régionaux possèdent des teneurs plus élevées en Chlore en provenance des interactions eau—roche, et des TDS plus élevées (515–537 mg/L). Des différences dans la chimie des eaux souterraines entre les aquifères et entre les systèmes découlement de surface et les écoulements profonds mettent en lumière les zones de mélange inter-aquifère. Ceci est particulièrement important pour la définition de la vulnérabilité où la qualité des eaux souterraines en profondeur peuvent subir les impacts des activités de surface.

     

Deep groundwater flow and geochemical processes in limestone aquifers: evidence from thermal waters in Derbyshire, England, UK

Thermal waters potentially provide information on geochemical processes acting deep within aquifers. New isotopic data on groundwater sulphate, inorganic carbon and strontium in thermal and non-thermal waters of a major limestone aquifer system in Derbyshire, England, UK, are used to constrain sulphate sources and groundwater evolution. Shallow groundwaters gain sulphate from oxidation of sulphide minerals and have relatively ¹³C-depleted dissolved inorganic carbon (DIC). Thermal waters have relatively high Sr/Ca and more ¹³C-enriched DIC as a result of increased water–rock interaction. In other respects, the thermal waters define two distinct groups. Thermal waters rising at Buxton have higher Mg, Mn and ⁸⁷Sr/⁸⁶Sr and lower Ca and SO₄, indicating flow from deep sandstone aquifers via a high permeability pathway in the limestone. By contrast, Matlock-type waters (97% of the thermal flux) have elevated sulphate concentrations derived from interaction with buried evaporites, with no chemical evidence for flow below the limestone. About 5% of the limestone area's groundwater flows to the Matlock group springs via deep regional flow and the remainder flows via local shallow paths to many non-thermal springs. Gypsum dissolution has produced significant tertiary porosity and tertiary permeability in the carbonate aquifer and this is an essential precursor to the development of karstic drainage.

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Resumen Las aguas termales potencialmente proporcionan información sobre procesos geoquímicos que actúan a profundidad en acuíferos. Nuevos datos isotópicos de sulfatos, carbón inorgánico y estroncio en aguas termales y no-termales de un acuífero importante de caliza en Derbyshire, Inglaterra se utilizan para delinear las fuentes de sulfato y la evolución de aguas subterráneas.Las aguas subterráneas no muy profundas adquieren sulfato a través de la oxidación de minerales de sulfuro y poseen carbón inorgánico disuelto (DIC) relativamente deplatado de ¹³C. Las aguas termales muestran un ratio Sr/Ca relativamente alto y poseen (DIC) más enriquecido en¹³C, como resultado de la mayor interacción de roca-agua. En otros aspectos, los aguas termales definen dos grupos distintivos. Las aguas termales que ascienden en Buxton tienen mas Mg, Mn y ⁸⁷Sr/⁸⁶Sr y menos Ca and SO₄, indicando flujo de acuíferos de areniscas profundas por un sendero de alta permeabilidad en la caliza.En contraste el tipo de agua - Matlock (97% del flujo termal) posee altas concentraciones de sulfato, derivado por interacción con evaporitas enterradas, sin evidencia química de flujo debajo de la caliza. Aproximadamente 5% del agua del área de la caliza se fluye al grupo de manantiales de Matlock a través de un flujo regional profundo y el resto fluye por senderos locales poco profundos a muchos de los manantiales no-termales. La disolución de yeso ha producido porosidad terciaria importante así como permeabilidad en el acuífero de carbonato y este es un precursor esencial del desarrollo de drenaje kárstico.

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Résumé Les eaux thermales peuvent apporter des informations sur les processus géochimiques dans les aquifères profonds. De nouvelles données isotopiques sur les sulfates présents dans les eaux souterraines, le carbone inorganique et le strontium dans les eaux thermales et non thermales d'un système aquifère calcaire majeur dans le Derbyshire, Angleterre, Royaume Uni, sont utilisées pour comprendre les sources de sulfates et l'évolution des eaux souterraines. Les eaux souterraines phréatique s'enrichissent en sulfate via l'oxydation des minéraux sulfatés et ont un Carbone Inorganique Dissous (DIC) relativement appauvri en¹³C. Les eaux thermales ont un rapport Sr/Ca relativement plus élevé et un DIC plus enrichi en¹³C, du fait de l'interaction accrue des eaux avec les roches. En d'autres mots, les eaux thermales définissent deux groupes distincts. Les eaux thermales remontant à Buxton ont un Mg, un Mn et un rapport ⁸⁷Sr/⁸⁶Sr plus hauts, mais un Ca et SO₄ plus faible, indiquant un écoulement à travers les zones perméables des aquifers gréseux. Par contraste, les eaux du type de Matlock (97% du flux thermique), possèdent des concentrations élevées en sulfates, provenant de l'interaction des eaux avec les évaporites enfouies, tandis qu'il n'existe aucune évidence chimique d'un écoulement sous les calcaires. Sur environ 5% de la surface des calcaires, les eaux souterraines alimentent des sources non-thermales. La dissolution du Gypse a produit une porosité tertiaire significative et une perméabilité dans les aquifères calcaires, et ceci est un précurseur essentiel au développement du drainage karstique.

     

Hydrochemistry and isotope geochemistry as tools for groundwater hydrodynamic investigation in multilayer aquifers: a case study from Lomellina, Po plain, South-Western Lombardy, Italy

A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers.     

Hydrochemical framework of groundwater in the Ankobra Basin,Ghana

Hydrochemical and stable isotope (¹⁸O and ²H) analyses of groundwater samples were used to establish the hydrochemistry of groundwater in the Ankobra Basin. The groundwater was generally mildly acidic, low in conductivity and undersaturated with respect to carbonate phases. Major ions except bicarbonate were low and dissolved silica was moderately high. Silicate minerals weathering is probably the main process through which major ions enter the groundwater. Groundwater samples clustered tightly along the Global Meteoric Water Line suggesting integrative, smooth and rapid recharge from meteoric origin. The majority of the boreholes and a few hand dug wells cluster towards the Ca–Mg–HCO₃ dominant section of the phase diagram, in conformity with the active recharge and short residence time shown by the isotope data. Aluminium, arsenic, manganese, iron and mercury were the only trace metals analysed with concentrations significantly above their respective detection limits. Approximately 20%, 5%, 40% and 25% respectively of boreholes had aluminium, arsenic, iron and manganese concentrations exceeding the respective WHO maximum acceptable limits for drinking water. The relatively large percentage of boreholes with high concentration of aluminium reflects the acidic nature of the groundwater.     

Use of chloride-mass balance and environmental isotopes for evaluation of groundwater recharge in the alluvial aquifer, Wadi Tharad, western Saudi Arabia

Groundwater recharge estimation has become a priority issue for humid and arid regions, especially in regions like Saudi Arabia, where the precipitation varies over space and time as a result of topography and seasonality. Wadi Tharad is a typical arid area in western Saudi Arabia. Within its drainage area of 400 km², the groundwater system shows a graded hydrochemical zonation from the hydrocarbonate in the upper reach to the chloride zone in the lower reach. The saturation index (SI) varies depending on the concentrations of carbonate minerals; the mean for calcite and dolomite is about in equilibrium (e.g., zero value). As halite and gypsum indices are negative, it is undersaturated. Isotopic compositions of H and O in the groundwater show that the groundwater recharge resources are mainly from meteoric water. The chloride-mass balance method was refined to estimate the amount of recharge, which is probably 11% of the effective annual rainfall. These results can be used to improve the accuracy of future groundwater management and development schemes.     

Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA

Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ¹⁸O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration.     

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.     

Salinization of groundwater in the Nefzawa oases region,Tunisia: results of a regional-scale hydrogeologic approach

Groundwater pumped from the semi-confined Complexe Terminal (CT) aquifer is an important production factor in irrigated oases agriculture in southern Tunisia. A rise in the groundwater salinity has been observed as a consequence of increasing abstraction from the aquifer during the last few decades. All sources of contamination were investigated using hydrochemical data available from the 1980s. Water samples were taken from drains and observation wells tapping both the CT and the phreatic aquifers and analyzed with regard to chemistry, temperature, isotopes and other environmental tracers. Local salinization mechanisms are suggested, i.e. the upwelling of saline water from the underlying, confined Continental Intercalaire (CI) aquifer, as well as backflow of agricultural drainage water. At this stage, the main salt pan, the Chott el Djerid, is not a contamination source. A finite difference model was also developed to simulate groundwater flow and contaminant transport in the oases. Calibration for the period 1950–2000 was carried out in order to adjust geological and chemical system parameters. The simulation of planned extraction projects predicts a worsening of the present situation. Maintenance of the present abstraction regime will not reduce or stop the salinity increase.

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Résumé L’eau souterraine pompée dans l’aquifère semi-captif du Complexe Terminal (CT) est un facteur de production important pour l’agriculture des oasis irriguées du sud de la Tunisie. Une augmentation de la salinité de l’eau souterraine a été considérée comme la conséquence de l’augmentation des prélèvements dans l’aquifère au cours des dernières décades. Toutes les sources de contamination ont été étudiées à l’aide de données hydro-chimiques disponibles depuis les années 80. Des échantillons d’eau ont été prélevés dans des drains et des puits d’observation qui captent à la fois le CT et les aquifères phréatiques; la chimie, la température, les isotopes ainsi que d’autres traceurs environnementaux ont été analysés. Des processus locaux de salinisation sont proposés, comme par exemple la remontée d’eau salée en provenance de l’aquifère captif du Continental Intercalaire (CI) sous-jacent, ainsi que le reflux des eaux du drainage agricole. A ce stade, le principal marais salé, le Chott el Djerid, n’est pas une source de contamination. Un modèle aux différences finies a également été élaboré pour simuler les écoulements souterrains et le transport de contaminants dans les oasis. Une calibration pour la période 1950–2000 a été effectuée afin d’ajuster les paramètres des systèmes géologique et chimique. La simulation de projets planifiés d’extraction prédit une aggravation de la situation actuelle. La conservation du régime d’extraction actuel ne réduira ou ne stoppera pas l’augmentation de la salinité.

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Resumen El agua subterránea que se bombea del acuífero semi-confinado Terminal Complejo (CT) es un importante factor de producción en la agricultura de riego con oasis en el sur de Túnez. Se ha observado un incremento en la salinidad del agua subterránea como consecuencia de la abstracción creciente del acuífero durante las últimas décadas. Se investigaron todas las fuentes de contaminación usando datos hidroquímicos disponibles de la década de 1980s. Las muestras de agua se tomaron de drenajes y pozos de observación alojados tanto en el CT como los acuíferos freáticos y se analizaron en relación con química, temperatura, isótopos y otros trazadores ambientales. Se sugieren mecanismos de salinización local, i.e. el ascenso de agua salada a partir del acuífero confinado subyacente Intercalado Continental (CI), así como también retorno de flujo de agua de drenaje agrícola. En esta etapa, el pan salado principal, el Chott el Djerid, no es una fuente de contaminación. También se desarrolló un modelo de diferencia finita para simular el flujo de agua subterránea y el transporte de contaminantes en los oasis. Se calibró el modelo para el periodo 1950–2000 para de este modo ajustar parámetros del sistema químico y geológico. La simulación de los proyectos de extracción que se han planeado predice un empeoramiento de la situación actual. El mantenimiento del régimen de extracción actual no reducirá o detendrá el incremento de salinidad.

     

Hydrogeochemistry and isotope analyses used to determine groundwater recharge and flow in low-gradient catchments of the province of Buenos Aires,Argentina

The region known as Pampa Plain, in Argentina, is a vast area characterized by slopes of less than 0.05%. The surface sediment is silty sand, mainly Aeolian, referred to as Pampean Loess, which is a phreatic aquifer unit of utmost importance for the water supply of the region. On account of the slight gradient, hydrogeological analyses using only hydraulic measurements are difficult to perform, often leading to confusing results. Thus, the study presented relies on hydrochemical modeling and isotopic determinations as well. The study area comprises three catchments in the inter-mountainous area corresponding to El Moro, Tamangueyú and Seco creeks, and covering 2,570 km² in the province of Buenos Aires. Measurements of piezometric levels and samples of groundwater, surface water and rainwater were carried out between January and March 2005. Major ion results were analyzed by means of hydrochemical graphs and hydrogeochemical modelling using NETPATH. The resulting data show that it is possible to identify local changes in recharge, flow direction and stream/groundwater relationship by using hydrochemical and isotopic information, which may become a useful and more precise tool for the study of particularly flat landscapes.