Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

A reassessment of the soil sink for atmospheric carbon tetrachloride based upon static flux chamber measurements

Static flux chamber measurements of CCl₄ uptake by soils in boreal, subtropical and tropical forests have been used to reassess the sink strength for this ozone depleting chemical. Happell and Roche (Geophys. Res. Lett. 30(2), 1088–1091, 2003) used flux estimates from soil concentration gradients to calculate a partial CCl₄ atmospheric lifetime (τ_soil) of 90 years. More recently, it is has been assumed that a better estimate of τ_soil is 195 years (Montzka et al. 2011). In the work here, the rate of CCl₄ uptake was calculated from 453 flux chamber measurements using an exponential fit to the chamber CCl₄ concentration change with time. This analysis indicated that the flux rate estimate in Happell and Roche (Geophys. Res. Lett. 30(2) 1088–1091, 2003) was overestimated by 2.75, yielding a new estimate of τ_soil for CCl₄ of 245 years. Significant correlations of CCl₄ uptake to temperature, soil moisture, or time of year were not observed. This work provides additional evidence that CCl₄ uptake by soils is a common process and needs to be considered when developing an atmospheric budget for this compound.     

Climate change impacts on ecosystems and the terrestrial carbon sink: a new assessment

Climate output from the UK Hadley Centre's HadCM2 and HadCM3 experiments for the period 1860 to 2100, with IS92a greenhouse gas forcing, together with predicted patterns of N deposition and increasing CO₂, were input (offline) to the dynamic vegetation model, Hybrid v4.1 (Friend et al., 1997; Friend and White, 1999). This model represents biogeochemical, biophysical and biogeographical processes, coupling the carbon, nitrogen and water cycles on a sub-daily timestep, simulating potential vegetation and transient changes in annual growth and competition between eight generalized plant types in response to climate.Global vegetation carbon was predicted to rise from about 600 to 800 PgC (or to 650 PgC for HadCM3) while the soil carbon pool of about 1100 PgC decreased by about 8%. By the 2080s, climate change caused a partial loss of Amazonian rainforest, C₄ grasslands and temperate forest in areas of southern Europe and eastern USA, but an expansion in the boreal forest area. These changes were accompanied by a decrease in net primary productivity (NPP) of vegetation in many tropical areas, southern Europe and eastern USA (in response to warming and a decrease in rainfall), but an increase in NPP of boreal forests. Global NPP increased from 45 to 50 PgC y⁻¹ in the 1990s to about 65 PgC y⁻¹ in the 2080s (about 58 PgC y⁻¹ for HadCM3). Global net ecosystem productivity (NEP) increased from about 1.3 PgC y⁻¹ in the 1990s to about 3.6 PgC y⁻¹ in the 2030s and then declined to zero by 2100 owing to a loss of carbon from declining forests in the tropics and at warm temperate latitudes — despite strengthening of the carbon sink at northern high latitudes. HadCM3 gave a more erratic temporal evolution of NEP than HadCM2, with a dramatic collapse in NEP in the 2050s.     

Investigation of parameters controlling the soil sink of atmospheric molecular hydrogen

Enclosure measurements have been performed on a bare mineral soil at an experimental field site near Heidelberg, Germany. From observed molecular hydrogen (H₂) mixing ratio changes in the enclosure, deposition velocities were calculated ranging from  8.4 × 10⁻³  to  8.2 × 10⁻² cm s⁻¹  and with an annual mean value of  3.1 × 10⁻² cm s⁻¹  . In the studied range of  2– 27 °C  , the uptake showed a significant temperature dependence. However, this turned out not to be the primary driving mechanism of the uptake flux. Soil moisture content, co-varying with temperature, was identified as the major parameter being responsible for the diffusive permeability of H₂ in the soil and the final rate of H₂ uptake. A simple Millington–Quirk diffusion model approach could largely explain this behaviour and yielded a diffusion path length of H₂ in the studied soil of only 0.2–1.8 cm, suggesting that total H₂ consumption occurs within the first few centimetres of the soil. The diffusion model, when applied to continuous measurements of soil moisture content, atmospheric pressure, temperature and the mixing ratio of H₂ in the atmosphere, could largely reproduce the measured deposition flux densities, assuming a mean thickness of the diffusion path length of 0.7 cm.     

The leaky sink: persistent obstacles to a forest carbon sequestration program based on individual projects

Abstract

One strategy for mitigating the increase in atmospheric carbon dioxide is to expand the size of the terrestrial carbon sink, particularly forests, essentially using trees as biological scrubbers. Within relevant ranges of carbon abatement targets, augmenting carbon sequestration by protecting and expanding biomass sinks can potentially make large contributions at costs that are comparable or lower than for emission source controls. The Kyoto protocol to the framework convention on climate change includes many provisions for forest and land use carbon sequestration projects and activities in its signatories' overall greenhouse gas mitigation plans. In particular, the protocol provides a joint implementation provision and a clean development mechanism that would allow nations to claim credit for carbon sequestration projects undertaken in cooperation with other countries. However, there are many obstacles for implementing an effective program of land use change and forestry carbon credits, especially measurement challenges. This paper explains the difficulty that even impartial analysts have in assessing the carbon offset benefits of projects. When these measurement challenges are combined with self-interest, asymmetries of information, and large numbers, it prevents to a project-based forest and land use carbon credit program may be insurmountable.     

The leaky sink: persistent obstacles to a forest carbon sequestration program based on individual projects

One strategy for mitigating the increase in atmospheric carbon dioxide is to expand the size of the terrestrial carbon sink, particularly forests, essentially using trees as biological scrubbers. Within relevant ranges of carbon abatement targets, augmenting carbon sequestration by protecting and expanding biomass sinks can potentially make large contributions at costs that are comparable or lower than for emission source controls. The Kyoto protocol to the framework convention on climate change includes many provisions for forest and land use carbon sequestration projects and activities in its signatories’ overall greenhouse gas mitigation plans. In particular, the protocol provides a joint implementation provision and a clean development mechanism that would allow nations to claim credit for carbon sequestration projects undertaken in cooperation with other countries. However, there are many obstacles for implementing an effective program of land use change and forestry carbon credits, especially measurement challenges. This paper explains the difficulty that even impartial analysts have in assessing the carbon offset benefits of projects. When these measurement challenges are combined with self-interest, asymmetries of information, and large numbers, it prevents to a project-based forest and land use carbon credit program may be insurmountable.     

Study of metal aerosol systems as a sink for atmospheric SO2

The chemical removal of SO₂ in the presence of different aerosol systems has been investigated in laboratory experiments using a dynamic flow reactor. The aerosols consisted of wetted particles containing one of the following substances: MnCl₂, Mn(NO₃)₂, MnSO₄, CuCl₂, Cu(NO₃)₂, CuSO₄, FeCl₃, NaCl. The SO₂ removal rate R was measured as a function of the SO₂ gas phase concentration (SO₂)_g, the spatial metal concentration C_Me, and the relative humidity rH in the reactor. A first-order dependence with regard to (SO₂)_g was observed for each type of aerosol. For the Mn(II) and Cu(II) aerosols R was found to be a non-linear function of C_Me except for MnSO₄ and Cu(NO₃)₂ particles. The removal rate showed a significant increase with the relative humidity particularly when rH was close to the deliquescence point of the wetted particles. Among the Mn(II) and Cu(II) aerosols investigated Mn(NO₃)₂ was found to be most efficient for the chemical removal of SO₂ at atmospheric background conditions, especially in haze and fog droplets. The results further indicate that the catalytic oxidation of S(IV) in such aerosol systems may be as efficient as its oxidation by H₂O₂ in cloud water.     

Considering the influence of sequestration duration and carbon saturation on estimates of soil carbon capacity

Rates of soil C sequestration have previously been estimated for a number of different land management activities, and these estimates continue to improve as more data become available. The time over which active sequestration occurs may be referred to as the sequestration duration. Integrating soil C sequestration rates with durations provides estimates of potential change in soil C capacity and more accurate estimates of the potential to sequester C. In agronomic systems, changing from conventional plow tillage to no-till can increase soil C by an estimated 16±3%, whereas increasing rotation intensity can increase soil C by an estimated 6±3%. The increase in soil C following a change in rotation intensity, however, may occur over a slightly longer period (26 yr) than that for tillage cessation (21 yr). Sequestration strategies for grasslands have, on average, longer sequestration durations (33 yr) than for croplands. Estimates for sequestration rates and durations are mean values and can differ greatly between individual sites and management practices. As the annual sequestration rate declines over the sequestration duration period, soil C approaches a new steady state. Sequestration duration is synonymous with the time to which soil C steady state is reached. However, soils could potentially sequester additional C following additional changes in management until the maximum soil C capacity, or soil C saturation, is achieved. Carbon saturation of the soil mineral fraction is not well understood, nor is it readily evident. We provide evidence of soil C saturation and we discuss how the steady state C level and the level of soil C saturation together influence the rate and duration of C sequestration associated with changes in land management.     

How the future of the global forest sink depends on timber demand,forest management,and carbon policies

Deforestation has contributed significantly to net greenhouse gas emissions, but slowing deforestation, regrowing forests and other ecosystem processes have made forests a net sink. Deforestation will still influence future carbon fluxes, but the role of forest growth through aging, management, and other silvicultural inputs on future carbon fluxes are critically important but not always recognized by bookkeeping and integrated assessment models. When projecting the future, it is vital to capture how management processes affect carbon storage in ecosystems and wood products. This study uses multiple global forest sector models to project forest carbon impacts across 81 shared socioeconomic (SSP) and climate mitigation pathway scenarios. We illustrate the importance of modeling management decisions in existing forests in response to changing demands for land resources, wood products and carbon. Although the models vary in key attributes, there is general agreement across a majority of scenarios that the global forest sector could remain a carbon sink in the future, sequestering 1.2–5.8 GtCO2e/yr over the next century. Carbon fluxes in the baseline scenarios that exclude climate mitigation policy ranged from −0.8 to 4.9 GtCO2e/yr, highlighting the strong influence of SSPs on forest sector model estimates. Improved forest management can jointly increase carbon stocks and harvests without expanding forest area, suggesting that carbon fluxes from managed forests systems deserve more careful consideration by the climate policy community.     

The land cover and carbon cycle consequences of large-scale utilizations of biomass as an energy source

The use of modern biomass for energy generation has been considered in many studies as a possible measure for reducing or stabilizing global carbon dioxide (CO₂) emissions. In this paper we assess the impacts of large-scale global utilization of biomass on regional and grid scale land cover, greenhouse gas emissions, and carbon cycle. We have implemented in the global environmental change model IMAGE the LESS biomass intensive scenario, which was developed for the Second Assessment Report of IPCC. This scenario illustrates the potential for reducing energy related emission by different sets of fuel mixes and a higher energy efficiency. Our analysis especially covers different consequences involved with such modern biomass scenarios. We emphasize influences of CO₂ concentrations and climate change on biomass crop yield, land use, competition between food and biomass crops, and the different interregional trade patterns for modern biomass based energy. Our simulations show that the original LESS scenario is rather optimistic on the land requirements for large-scale biomass plantations. Our simulations show that 797 Mha is required while the original LESS scenario is based on 550 Mha. Such expansion of agricultural land will influence deforestation patterns and have significant consequenses for environmental issues, such as biodiversity. Altering modern biomass requirements and the locations where they are grown in the scenario shows that the outcome is sensitive for regional emissions and feedbacks in the C cycle and that competition between food and modern biomass can be significant. We conclude that the cultivation of large quantities of modern biomass is feasible, but that its effectiveness to reduce emissions of greenhouse gases has to be evaluated in combination with many other environmental land use and socio-economic factors.     

Influence of soil moisture on the Sahelian climate prediction II

Summary The sensitivity of short-term climate to soil moisture parameterization has been investigated using the Florida State University Global Spectral Model. This is done through the implementation of a simple and realistic soil moisture availability in a prognostic equation for the surface temperature.The results from two seasonal simulations between 11 May and 31 August 1979 are discussed with an emphasis on the Sahelian regions. These experiments indicated that most of the significant changes that resulted from the new parameterization occurred at and near the surface. Above the surface, land surface effects were strongly diffused and for most of the cases were not conclusively discernible. At the surface, however, soil moisture appeared to be a parameter of large influence. Important modulations in the surface temperature were obtained. The time dependence of the soil moisture availability has led to an evolution of the surface heat sources in the model resulting in an apparent northward propagation of the centers of maximum temperature as the rainfall season progressed over the north African continent from May to August. This has had an important effect on the distribution of the primary variables and showed significant departures from the control.The interaction introduced by the new scheme between the physical processes parameterized in the model, has resulted in a differential modification of the rainfall distribution, and the changes in the hydrological cycle have remarkably affected the summer Sahelian rainfall.With 20 Figures     

Characteristics of the atmospheric heat source and moisture sink over the Qinghai-Tibetan Plateau during the second TIPEX of summer 1998 and their impact on surrounding monsoon

Summary ?Using the data of 6 automatic heat balance observation (AWS) stations and a data set of 52 surface observation stations over the Qinghai-Tibetan Plateau (“the Plateau”) and surroundings, the horizontal distribution is studied of “apparent atmospheric heat sources” 〈Q ₁〉 and of “apparent atmospheric moisture sinks” 〈Q ₂〉. The AWS stations were established during the period May to August 1998 of the Tibetan Plateau Meteorological Experiment (second TIPEX) by a cooperation of China and Japan. For this period the Plateau mean of 〈Q ₁〉 is positive. Its value of 74 W/m² is a little greater than a climate value and than values from MONEX and the first TIPEX in 1979, respectively. Also the corresponding 〈Q ₂〉 is positive. Hence during that time the Plateau is a heat source and a moisture sink. A day-to-day change of 〈Q ₁〉 and 〈Q ₂〉 is more pronounced over the middle and east part of the Plateau than over the west part. Diagnostics accompanied by numerical simulations are used to study the daily relationship between 〈Q ₁〉 over the Plateau and the weather over China and Asia for this summer. The results suggest that 〈Q ₁〉 may affect precipitation over northern China and position of the west Pacific subtropical high. Abnormal southward retreat of this Pacific high seems to have caused the second flood over the middle and lower Yangtse river basin in July. Received May 20, 2001; revised February 2, 2002     

Influence of soil moisture on simulations of katabatic flow

Summary Simulations of katabatic flow with a two-dimensional dynamic numerical model with a soil parameterization indicate that downslope flow developed over a moist slope is weaker than that over a dry slope. This agrees with earlier findings that daytime anabatic (upslope) flow is weaker over a moister slope. But, whereas the weaker anabatic flow is produced because surface evaporation prevents the moist slope from heating as much as a dry slope, the weaker katabatic flow is produced over moist slopes because (1) the soil thermal conductivity is greater in moist soil, and (2) downward longwave radiation flux from the atmosphere to the surface is greater because of higher humidity in the air near the surface from evaporation. The higher thermal conductivity allows warmer soil temperatures (heat) to diffuse upward to the soil surface and prevents the surface temperature from becoming as cold in the moist run as in the dry run.With 6 Figures     

2006年夏季川渝地区伏旱与低频大气热源的关系

利用NCEP/NCAR再分析资料和中国地面观测站的逐日降水资料,研究了2006年夏季中国川渝地区的伏旱与亚洲地区大气低频振荡的联系.结果表明,2006年夏季中国川渝地区降水低频振荡的主要周期约为60 d;在川渝严重干旱期的7月下旬至8月上旬,经向上由于川渝地区上空低频热汇、广西和海南及其以西地区上空低频热源的影响,在1...     

Phase inconsistency as a major source of error in NGFS forecast

Climate Dynamics - South Asian monsoon exhibits multiscale spatiotemporal variability. Analyzing the nature and behavior of numerical weather forecast error associated with these space-time...