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1.
Cathelijne de Busser 《GeoJournal》2006,67(4):283-294
Contrary to the absence of a uniform Spanish identity (a phenomenon that is often referred to as Spain being a ‘nation of
nations’), Spain’s confessional map is remarkably homogeneous. From the beginning of its existence as a political conglomeration,
Spain has been a mono-confessional Catholic territory. Even at present, Catholicism is an intrinsic feature of Spanish society
and – though officially a secular state – of state policy. A closer look at Spain’s religious situation and its corresponding
pattern of church–state relations reveals, however, some recent cracks in the century’s old bond between Spain and Catholicism.
Particularly secularization and religious pluralism challenge Spain’s mono-confessional Catholic nature, a development that
fits well into Spain’s post-Francoist focus on Europe and European (secular) values. This paper discusses Spanish church–state
relations from the beginning of its political existence until present times. Special attention will be paid to more recent
societal developments and their impact on religious Spain and church–state relations.
相似文献
Cathelijne de BusserEmail: |
2.
Alexey D. Krindatch 《GeoJournal》2006,67(4):267-282
This paper first traces the major changes in the relationship between the (Orthodox) Church and State in the different Russian
polities, using Madeley’s framework of historic mono-confessional blocs and multi-confessional belts. Second, it outlines
the recent tendencies and characteristic features of church–state relations in today’s Russia. Third, using data from sociological
surveys, it analyses the current dominant popular perceptions and societal attitudes towards religion and the State, including
religious freedom. Being part of the historic mono-confessional Orthodox bloc, the different Russian polities produced different
models of church–state relations: from a symphony of religious and political powers, through a forced nationalization of the
Orthodox Church (Russian Empire from the époque of Peter the Great until revolution of 1917), and forced secularisation (during
the Soviet Union), to a return of mutual support of (Orthodox) Church and State despite a formal (constitutional) separation
in Putin’s Russia. 相似文献
3.
Elżbieta Bilska-Wodecka 《GeoJournal》2006,67(4):341-355
According to Madeley’s (2003) comparative framework of state–church relations in Europe, Poland is part of the historic Northeast-Southeast multi-confessional
culture belt. The aim of this paper is to analyse the historic relationships between the Polish state and church in relation
to this framework with special attention to the post-Second World War period and to the consequences for the Polish religious
landscape. In contrast to the multi-confessionality of the historic Polish polities, after the Second World War Poland became
a mono-confessional, Roman-Catholic country. Territorial changes, the resettlement of people and the annihilation of the Jewish
population by the Nazis were responsible for this religious homogenisation. Consequently, the relationship between state and
church was almost completely confined to the relationship with the Roman-Catholic Church. During the 45 years of communist
dominance, that church became the largest public organisation independent of the state authorities and played the most important
role in the struggle against the ‘atheisation’ of Polish society as a consequence of the strong support for the church by
the majority of people. The post–1989 period is characterised by a liberalisation towards non-Catholic religious communities
and – after an initial reluctance – a positive attitude of the Polish Roman-Catholic Church (strongly supported by the Polish
Pope John Paul II) towards the Polish membership of the European Union.
相似文献
Elżbieta Bilska-WodeckaEmail: |
4.
Reinhard Henkel 《GeoJournal》2006,67(4):307-316
In the wake of the Reformation, the bitterest religious wars were fought on the territories of what is now Germany. It was
here, however, that the rule “cuius region, eius religio” was found as well which can be interpreted as a first step towards
religious tolerance. Germany has been characterised by a religious dualism between the Roman Catholic and the Protestant (Lutheran
and Reformed) Church since then. Both had the status of state churches until the First World War. Since then, they are still
by far the dominant religious communities in the country but they regard themselves wrongly to be Volkskirchen (people’s churches). They, as well as a number of smaller religious communities, enjoy the status of a corporation under
public law. This status includes the right to collect church tax from members through state channels. The federal German state
system is mirrored by a similar federal character of the Protestant Church, which is a union of regional churches. When Germany
was reunited in 1990, the Volkskirche principle was reintroduced in East Germany although Christians had become a minority there due to 40 years of strong influence
of Communism. Secularisation and pluralisation have changed the religious landscape in Germany especially after 1960. The
two big churches have lost large numbers of members, and new religious communities have arrived. In the light of Europe growing
together, the Protestant Church in Germany, being the largest in numbers in Europe, has initiated stronger cooperation between
the different Protestant churches in the European countries, many of which are organised as national churches. Islam has come
to Germany mainly through Turkish labour migrants. The country has only recently changed its self-perception into being a
society with a large immigrant minority, which is to stay; therefore it will certainly take some time until Muslims are fully
accommodated.
相似文献
Reinhard HenkelEmail: |
5.
Zoltán Cséfalvay 《GeoJournal》1994,32(4):351-361
After 1989, the East Central European countries had to face three major challenges: stabilization and modernization of their economies and the transition to a market economy. Hungary, partly because of the early liberalization of the command economic regime enjoyed a significant competitive edge in the region in all three areas. The stabilization, modernization and restructuring of the economy was followed by the strengthening of processes of regional differentiation, the fast gaining on, and loosing of importance by certain areas and settlements. The capital city and the agglomeration area around it became the centre of the Hungarian as well as East Central European economic changes in all respects, the Western Transdanubian area is speedily integrating with the North Italian, Austrian, Southern German economic region, while the Southern parts of the country are presently in a state of transition and a prolonged crisis can be forecasted for the Eastern regions of the country. 相似文献
6.
Marina A. Yudovskaya Vadim V. Distler Ilya V. Chaplygin Andrew V. Mokhov Nikolai V. Trubkin Sonya A. Gorbacheva 《Mineralium Deposita》2006,40(8):828-848
The distribution of gold in high-temperature fumarole gases of the Kudryavy volcano (Kurile Islands) was measured for gas, gas condensate, natural fumarolic sublimates, and precipitates in silica tubes from vents with outlet temperatures ranging from 380 to 870°C. Gold abundance in condensates ranges from 0.3 to 2.4 ppb, which is significantly lower than the abundances of transition metals. Gold contents in zoned precipitates from silica tubes increase gradually with a decrease in temperature to a maximum of 8 ppm in the oxychloride zone at a temperature of approximately 300°C. Total Au content in moderate-temperature sulfide and oxychloride zones is mainly a result of Au inclusions in the abundant Fe–Cu and Zn sulfide minerals as determined by instrumental neutron activation analysis. Most Au occurs as a Cu–Au–Ag triple alloy. Single grains of native gold and binary Au–Ag alloys were also identified among sublimates, but aggregates and crystals of Cu–Au–Ag alloy were found in all fumarolic fields, both in silica tube precipitates and in natural fumarolic crusts. Although the Au triple alloy is homogeneous on the scale of microns and has a composition close to (Cu,Ni,Zn)3(Au,Ag)2, transmission electron microscopy (TEM) shows that these alloy solid solutions consist of monocrystal domains of Au–Ag, Au–Cu, and possibly Cu2O. Gold occurs in oxide assemblages due to the decomposition of its halogenide complexes under high-temperature conditions (650–870°C). In lower temperature zones (<650°C), Au behavior is related to sulfur compounds whose evolution is strongly controlled by redox state. Other minerals that formed from gas transport and precipitation at Kudryavy volcano include garnet, aegirine, diopside, magnetite, anhydrite, molybdenite, multivalent molybdenum oxides (molybdite, tugarinovite, and ilsemannite), powellite, scheelite, wolframite, Na–K chlorides, pyrrhotite, wurtzite, greenockite, pyrite, galena, cubanite, rare native metals (including Fe, Cr, Mo, Sn, Ag, and Al), Cu–Zn–Fe–In sulfides, In-bearing Pb–Bi sulfosalts, cannizzarite, rheniite, cadmoindite, and kudriavite. Although most of these minerals are fine-grained, they are strongly idiomorphic with textures such as gas channels and lamellar, banded, skeletal, and dendrite-like crystals, characteristic of precipitation from a gas phase. The identified textures and mineral assemblages at Kudryavy volcano can be used to interpret geochemical origins of both ancient and modern ore deposits, particularly gold-rich porphyry and related epithermal systems. 相似文献
7.
Christina Wanhainen Kjell Billström Olof Martinsson Holly Stein Roger Nordin 《Mineralium Deposita》2005,40(4):435-447
Host rocks to the Aitik Cu–Au–Ag deposit in northern Sweden are strongly altered and deformed Early Proterozoic mica(-amphibole)
schists and gneisses. The deposit is characterised by numerous mineralisation styles, vein and alteration types. Four samples
were selected for Re–Os molybdenite dating and 12 samples for U–Pb titanite dating in order to elucidate the magmatic/hydrothermal
and metamorphic history following primary ore deposition in the Aitik Cu–Au–Ag deposit. Samples represent dyke, vein and alteration
assemblages from the ore zone, hanging wall and footwall to the deposit. Re–Os dating of molybdenite from deformed barite
and quartz veins yielded ages of 1,876±10 Ma and 1,848±8 Ma, respectively. A deformed pegmatite dyke yielded a Re–Os age of
1,848±6 Ma, and an undeformed pegmatite dyke an age of 1,728±7 Ma. U–Pb dating of titanite from a diversity of alteration
mineral associations defines a range in ages between 1,750 and 1,805 Ma with a peak at ca. 1,780 Ma. The ages obtained, together
with previous data, bracket a 160-Ma (1,890–1,730 Ma) time span encompassing several generations of magmatism, prograde to
peak metamorphism, and post-peak cooling; events resulting in the redistribution and addition of metals to the deposit. This
multi-stage evolution of the Aitik ore body suggests that the deposit was affected by several thermal events that ultimately
produced a complex ore body. The Re–Os and U–Pb ages correlate well with published regional Re–Os and U–Pb age clusters, which
have been tied to major magmatic, hydrothermal, and metamorphic events. Primary ore deposition at ca. 1,890 Ma in connection
with intrusion of Haparanda granitoids was followed by at least four subsequent episodes of metamorphism and magmatism. Early
metamorphism at 1,888–1,872 Ma overlapping with Haparanda (1,890–1,880 Ma) and Perthite-monzonite (1,880–1,870 Ma) magmatism
clearly affected the Aitik area, as well as late metamorphism and Lina magmatism at 1,810–1,774 Ma and TIB1 magmatism at 1,800 Ma.
The 1,848 Ma Re–Os ages obtained from molybdenite in a quartz vein and pegmatite dyke suggests that the 1,850 Ma magmatism
recorded in parts of northern Norrbotten also affected the Aitik area. 相似文献
8.
A. Pavese 《Physics and Chemistry of Minerals》2002,29(1):43-51
The P–V–T equation of state (EoS) models of Birch–Murnaghan, Vinet and Poirier–Tarantola have been compared with one another and discussed
in the light of their ability to reproduce thermoelastic functions and parameters by means of fitting to pressure–volume–temperature
data artificially generated for spinel, corundum and forsterite. Numerical simulations relying upon semi-empirical potentials,
lattice dynamics and the quasiharmonic approximation have been used to generate P–V–T data. The results obtained indicate that all the P–V–T EoSs tested predict bulk modulus at ambient conditions with errors confined, at worst, within a few percent, and reproduce
correctly its dependence on temperature. The derivatives of the bulk modulus versus P and PT are less satisfactorily modelled. The bulk thermal expansion is determined by EoSs within a few percent error, but the deviations
increase significantly if the approximation of linear dependence of EoS on temperature is used (linearised thermal pressure
model).
Received: 30 January 2001 / Accepted: 16 June 2001 相似文献
9.
Jian-Wei Li Xin-Fu Zhao Mei-Fu Zhou Paulo Vasconcelos Chang-Qian Ma Xiao-Dong Deng Zorano Sérgio de Souza Yong-Xin Zhao Gang Wu 《Mineralium Deposita》2008,43(3):315-336
The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower
reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite
and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon
U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an 40Ar/39Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling
slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm),
Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However,
they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions,
with (87Sr/86Sr)
t
= 0.7062–0.7067, ɛ
Nd(t) = −4.37 to −4.63, (176Hf/177Hf)
t
= 0.282469–0.282590, and ɛ
Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite
was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts
related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as
indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the
compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe3+–Fe2+–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and
Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing
data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic
Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an
intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has
been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim. 相似文献
10.
We present new Re–Os molybdenite age data on three porphyry Cu–Mo–Au deposits (Yulong, Machangqing, and Xifanping). These deposits are associated with the Himalayan adakitic magmatism that occurred in a continental collision environment, controlled by large-scale Cenozoic strike-slip faults in the eastern Indo–Asian collision zone. Three distinct episodes of Cu–Mo–Au mineralization are recognized. At Yulong, Re–Os isotopic data of four molybdenite samples from sulfide-quartz veins in the quartz–sericite alteration zone yield an isochron with an age of 40.1±1.8 Ma (2σ), coincident to a zircon sensitive high-mass resolution ion microprobe (SHRIMP) age of 40.9±0.1 Ma for the host monzogranite. The molybdenite Re–Os dates, together with K–Ar, Rb–Sr, U–Pb, and 40Ar/39Ar dates on the pre- and intra-ore porphyries, suggest that Cu–Mo–Au mineralization formed during the late stage (∼40 Ma) of regional porphyry magmatism, but hydrothermal activity probably lasted to at least ∼36 Ma. At Machangqing, molybdenite Re–Os data from the K–silicate and quartz–sericite alteration zones yield an isochron with an age of 35.8±1.6 Ma (2σ), which is identical to the zircon SHRIMP and bulk-rock Rb–Sr ages (35∼36 Ma) of the host granite, but older than bulk-rock K–Ar dates (31∼32 Ma) for associated Au-bearing quartz syenite with advanced argillic alteration. At Xifanping, five molybdenite samples from the K–silicate alteration zone yield the youngest Re–Os isochron age in the area, at 32.1±1.6 Ma (2σ). The Re–Os molybdenite dates here are younger than K–Ar ages (33.5∼34.6) for hydrothermal biotite and actinolite. There is a positive correlation between the absolute age of the deposits and their Cu and Au reserves in the eastern Indo–Asian collisional zone. Episodic stress relaxation probably caused multiple magmatic intrusions, which most likely resulted in three episodes of Cu–Mo–Au mineralization in the eastern Indo–Asian collision zone. 相似文献
11.
Shao-Yong Jiang Yong-Quan Chen Hong-Fei Ling Jing-Hong Yang Hong-Zhen Feng Pei Ni 《Mineralium Deposita》2006,41(5):453-467
The Lower Cambrian black shale sequence of the Niutitang Formation in the Yangtze Platform, South China, hosts an extreme metal-enriched sulfide ore bed that shows >10,000 times enrichment in Mo, Ni, Se, Re, Os, As, Hg, and Sb and >1,000 times enrichment in Ag, Au, Pt, and Pd, when compared to average upper continental crust. We report in this paper trace- and rare-earth-element concentrations and Pb–Pb isotope dating for the Ni–Mo–PGE–Au sulfide ores and their host black shales. Both the sulfide ores and their host black shales show similar trace-element distribution patterns with pronounced depletion in Th, Nb, Hf, Zr, and Ti, and extreme enrichment in U, Ni, Mo, and V compared to average upper crust. The high-field-strength elements, such as Zr, Hf, Nb, Ta, Sc, Th, rare-earth elements, Rb, and Ga, show significant inter-element correlations and may have been derived mainly from terrigenous sources. The redox sensitive elements, such as V, Ni, Mo, U, and Mn; base metals, such as Cu, Zn, and Pb; and Sr and Ba may have been derived from mixing of seawater and venting hydrothermal sources. The chondrite-normalized REE patterns, positive Eu and Y anomalies, and high Y/Ho ratios for the Ni–Mo–PGE–Au sulfide ores are also suggestive for their submarine hydrothermal-exhalative origin. A stepwise acid-leaching Pb–Pb isotope analytical technique has been employed for the Niutitang black shales and the Ni–Mo–PGE–Au sulfide ores, and two Pb–Pb isochron ages have been obtained for the black shales (531±24 Ma) and for the Ni–Mo–PGE–Au sulfide ores (521±54 Ma), respectively, which are identical and overlap within uncertainty, and are in good agreement with previously obtained ages for presumed age-equivalent strata.Editorial handling: R. Coveney Jr. 相似文献
12.
The Guelb Moghrein Fe oxide–Cu–Au–Co deposit, with a total resource of 23.6 Mt at 1.88% Cu, 1.41 g/t Au, and 143 g/t Co, is hosted by an extensive metacarbonate body. However, it is restricted to up to 30-m wide tabular breccia zones developed parallel to discrete shear zones that transect the host metacarbonates. The Fe–Mg clinoamphibole–chlorite schists represent up to 1-m thick interlayer metasediments and localized viscous shearing in these shear zones. Siderite of the metacarbonate body was deformed into a breccia and was replaced by an ore and alteration assemblage comprised of Fe–Mg clinoamphibole, magnetite, pyrrhotite, chalcopyrite, graphite, Fe–Co–Ni arsenides, arsenopyrite, cobaltite, uraninite, and Bi–Au–Ag–Te minerals. In contact with wall rock amphibolites, the metacarbonate body is enveloped by an alteration halo up to 40 m wide, consisting of biotite, actinolite, grunerite, chlorite, calcite, albite, and quartz. The Guelb Moghrein ore body is structurally controlled by shear zones that developed in the footwall of a regional thrust zone. This thrust separates greenschist facies quartz–sericite schists and biotite–garnet–quartz schists of the Sainte Barbe volcanic unit in the hanging wall from amphibolite facies metavolcanic rocks, metacarbonates, and the Guelb Moghrein ore body of the Akjoujt metabasalt unit in the footwall. Peak temperatures of the latter unit are estimated by hornblende–plagioclase thermometry at 580±40°C. Thrusting was retrograde for the Akjoujt metabasalt unit, but prograde for the Sainte Barbe volcanic unit at P–T conditions of about 410±30°C and 2–3 kbar (garnet–biotite thermometry). Structural and petrological evidences suggest that the ore fluids migrated along the shear zones and reacted with the siderite in the metacarbonate. This evolution and the setting of Guelb Moghrein in the fold-and-thrust belt of the Pan-African to Variscan Mauritanides (Mauritania, West Africa) resemble Proterozoic Fe oxide–Cu–Au–Co deposits such as examples from the Tennant Creek and Mount Isa Inliers, Australia.Electronic Supplementary Material Supplementary material is available for this article at 相似文献
13.
Zoran Seat Stephen W. Beresford Benjamin A. Grguric Rob S. Waugh Jon M. A. Hronsky M. A. Mary Gee David I. Groves Charter I. Mathison 《Mineralium Deposita》2007,42(6):551-581
The Nebo–Babel Ni–Cu–platinum-group element (PGE) sulphide deposit in the West Musgrave Block, Western Australia, is the largest
nickel sulphide discovery in the last 10 years. The deposit is hosted within a concentrically zoned, olivine-free, tube-like
(chonolithic), gabbronorite intrusion associated with the, approximately, 1,078-Ma Giles Complex-layered intrusions in the
Warakurna large igneous province. Emplaced into sulphide-free amphibolite facies orthogneiss, the fault-offset Nebo–Babel
chonolith extends for 5 km and has a cross-section of 1 × 0.5 km. Igneous mineralogy, fabrics, and textures are well preserved.
The lithostratigraphy includes variably textured leucogabbronorites (VLGN) that form an outer shell around mineralised gabbronorite
(MGN), with barren gabbronorite (BGN) and oxide–apatite gabbronorite (OAGN) in the middle and lower parts of the chonolith.
Mineral and whole-rock geochemistry indicate that the units become progressively evolved in the order: VLGN, MGN, BGN, and
OAGN, and that incompatible trace-element concentrations increase downwards within the MGN and BGN. The mineralisation, which
is confined to the early, more primitive units (VLGN and MGN), occurs as massive sulphide breccias and stringers and as disseminated
gabbronorite-hosted sulphides. The massive sulphides were emplaced late in the intrusive sequence, have different PGE chemistry
and Cu tenor to the disseminated sulphides, and have undergone sulphide fractionation. The distribution of disseminated sulphides,
which are primary magmatic in origin, is related to chonolith geometry and magma flow regimes, rather than to gravitational
settling. Sulfur-bearing country rocks are absent in the Nebo–Babel deposit area, and thus, local crustal S addition was unlikely
to have been the major mechanism in achieving sulphide immiscibility. The Nebo–Babel intrusion is part of an originally continuous
magma chonolith with multiple and related magma pulses. The parental magma was medium- to low-K tholeiite with 8–9 wt% MgO.
The initial magma pulse (VLGN), the most primitive and sulphide saturated, was probably emplaced along a linear weakness in
the country rock. After crystallisation of VLGN, marginally more fractionated, sulphide-saturated magma was injected through
the thermally insulated core of the conduit, forming the MGN. Successive pulse(s) of more fractionated magma (BGN) were emplaced
in the core of the intrusion. After magma flow ceased, closed system crystal fractionation produced consistent mineral and
chemical fractionation trends within BGN and OAGN. After crystallisation, the intrusion was overturned and then offset by
the Jameson Fault resulting in the apparent ‘reverse’ chemical and mineral trends in Nebo–Babel. 相似文献
14.
Granites and primary tin mineralization in the Erzgebirge were dated using (1) conventional U–Pb dating of uraninite inclusions
in mica, (2) Rb–Sr dating of inclusions in quartz that represent highly evolved melts, (3) Re–Os dating of magmatic–hydrothermal
molybdenite, and (4) chemical Th–U–Pb dating of uraninite. Conventional isotope dilution and thermal ion mass spectrometry
and chemical Th–U–Pb dating of uraninite in granites from the Ehrenfriedersdorf mining district provide ages of 323.9 ± 3.5
Ma (2σ; Greifenstein granite) and 320.6 ± 1.9 and 319.7 ± 3.4 Ma (2σ, both Sauberg mine), in agreement with U–Pb apatite ages of 323.9 ± 2.9 and 317.3 ± 1.6 Ms (2σ, both Sauberg mine). Rb–Sr analysis of melt inclusions from Zinnwald gives highly radiogenic Sr isotopic compositions that,
with an assumed initial Sr isotopic composition, permit calculation of precise ages from single inclusions. The scatter of
the data indicates that some quartz-hosted melt inclusions have been affected by partial loss of fluid exsolved from the melt
inclusion. Re–Os dating of two molybdenite samples from Altenberg provides ages of 323.9 ± 2.5 and 317.9 ± 2.4 Ma (2σ). Together with age data from the literature, our new ages demonstrate that primary tin mineralization and the emplacement
of the large Sn-specialized granites in the Erzgebirge fall in a narrow range between 318 and 323 Ma. Primary Sn mineralization
occurred within a short interval during post-collisional collapse of the Variscan orogen and was essentially synchronous over
the entire Erzgebirge. In contrast to earlier claims, no systematic age difference between granites of the eastern and western
Erzgebirge was established. Furthermore, our data do not support a large age range for Late-Variscan granites of the Erzgebirge
(330–290 Ma), as has been previously suggested. 相似文献
15.
16.
M. Zhai A. B. Kampunzu M. P. Modisi Z. Bagai 《International Journal of Earth Sciences》2006,95(3):355-369
The Francistown plutonic rocks at the south-western margin of the Zimbabwe craton consist of three igneous suites: Sanukitoid, Tonalite–Trondhjemite–Granite (TTG) suites and High-K granites. The TTG suite is subdivided into High Aluminum-TTG (HA-TTG) and Low Aluminum-TTG (LA-TTG) sub-suites. Their Rb–Sr isotope systems were partially homogenized by post-crystallization thermo–tectonic events, in which hydrothermal solutions and migmatization played an important role. Therefore, the Rb–Sr isochron age of 2427±54 Ma can only be regarded as a lower limit to the Francistown plutonic rock age. The large errors in the Sm–Nd isochron dates of Francistown granitoids indicate that these dates are not really constrained. In this study we compared the rock types of Francistown and adjacent areas, adopting the precise U, Th–Pb single zircon SHRIMP ages from the Vumba area as references. For TTG and Sanukitoid suites, the age we adopted is ca. 2.7 Ga, which is close to their depleted-mantle Sm–Nd model ages (T
DM). For High-K granites, the age adopted is ca. 2.65 Ga, which is also close to their Sm–Nd isochron age. The highest ε
Nd
t
values of Sanukitoids and TTG are +2.1 and +2.3, respectively. The positive ε
Nd
t
values and trace element geochemistry support partial melting of a depleted mantle and young oceanic crust for the genesis of Sanukitoid and the TTG suites respectively. The lowest ε
Nd
t
values of Sanukitoids and TTGs are −1.0 and −1.1, respectively, indicating contamination by continental crust, up to 10 and 14%, respectively. The ε
Nd
t
values of TTG decrease with decreasing Al2O3 and Sr contents and increasing Eu negative anomalies (Eu*–Eu), suggesting that the TTG magmas underwent a coupled fractionation crystallization and crustal contamination, and that the LA-TTG was the product of the fractionation and contamination of the HA-TTG sub-suite. In contrast, negative ε
Nd
t
values for the High-K granites (from −0.4 to −3.5) indicate the involvement of LA-TTG and some materials from an old continental crust in their genesis. The products of partial melting of both oceanic and continental crusts at the south-western margin of the Zimbabwe craton occurred within a short time interval (from 2.7 to 2.65 Ga ago) suggesting that the Francistown plutonic rocks were formed in a active continental margin environment, where a young ocean plate (Limpopo oceanic plate) subducted underneath an old continental plate (Zimbabwe craton). 相似文献
17.
Hartmut Beurlen Marcelo R. R. Da Silva Rainer Thomas Dwight R. Soares Patrick Olivier 《Mineralium Deposita》2008,43(2):207-228
The Borborema Pegmatitic Province (BPP), northeastern Brazil, is historically important for tantalum mining and also famous
for top-quality specimens of exotic Nb–Ta oxides and, more recently, for the production of gem quality, turquoise blue, ‘Paraíba
Elbaite.’ With more than 750 registered mineralized rare-element granitic pegmatites, the BPP extends over an area of about
75 by 150 km in the eastern part of the Neoproterozoic Seridó Belt. The Late Cambrian pegmatites are mostly hosted by a sequence
of Neoproterozoic cordierite–sillimanite biotite schists of the Seridó Formation and quartzites and metaconglomerates of the
Equador Formation. The trace-element ratios in feldspar and micas allow to classify most pegmatites as belonging to the beryl–columbite
phosphate subtype. Electron microprobe analyses (EMPA) of columbite, tapiolite, niobian–tantalian rutile, ixiolite and wodginite
group minerals from 28 pegmatites in the BPP are used to evaluate the effectiveness of Nb–Ta oxide chemistry as a possible
exploration tool, to trace the degree of pegmatite fractionation and to classify the pegmatites. The columbite group mineral
composition allows to establish a compositional trend from manganoan ferrocolumbite to manganocolumbite and on to manganotantalite.
This trend is typical of complex spodumene- and/or lepidolite-subtype pegmatites. It clearly contrasts with another trend,
from ferrocolumbite through ferrotantalite to ferrowodginite and ferrotapiolite compositions, typical of pegmatites of the
beryl–columbite phosphate subtype. Large scatter and anomalous trends in zoned crystals partially overlap and conceal the
two main evolution patterns. This indicates that a large representative data set of heavy mineral concentrate samples, collected
systematically along cross-sections, would be necessary to predict the metallogenetic potential of individual pegmatites.
Other mineral species, e.g. garnets and/or tourmaline, with a more regular distribution than Nb–Ta oxides, would be more appropriate
and less expensive for routine exploration purposes. The currently available Nb–Ta oxide chemistry data suggest the potential
for highly fractionated Ta–Li–Cs pegmatites in the BPP, so far undiscovered, and encourages further, more detailed research. 相似文献
18.
The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern
part of the Panagyurishte mineral district. It lies within the Banat–Srednegorie metallogenic belt, which extends from Romania
through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech
deposit have been affected by propylitic, quartz–sericite, and advanced argillic alteration, but the igneous textures have
been preserved. Alteration processes have resulted in leaching of Na2O, CaO, P2O5, and Sr and enrichment in K2O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field
strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during
the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks
are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the
Chelopech magmatism, were dated by high-precision U–Pb geochronology. Zircons of an altered andesitic body, which has been
thrust over the deposit, yield a concordant 206Pb/238U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech.
Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean 206Pb/238U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted
by hydrothermal alteration give a concordant 206Pb/238U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech
epithermal high-sulfidation deposit. 176Hf/177Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the Chelopech area and the
about 92-Ma-old Elatsite porphyry–Cu deposit, suggest two different magma sources in the Chelopech–Elatsite magmatic area.
Magmatic rocks associated with the Elatsite porphyry–Cu deposit and the dacitic dome-like body north of Chelopech are characterized
by zircons with ɛHfT90 values of ∼5, which suggest an important input of mantle-derived magma. Some zircons display lower ɛHfT90 values, as low as −6, and correlate with increasing 206Pb/238U ages up to about 350 Ma, suggesting assimilation of basement rocks during magmatism. In contrast, zircon grains in andesitic
rocks from Chelopech are characterized by homogeneous 176Hf/177Hf isotope ratios with ɛHfT90 values of ∼1 and suggest a homogeneous mixed crust–mantle magma source. We conclude that the Elatsite porphyry–Cu and the
Chelopech high-sulfidation epithermal deposits were formed within a very short time span and could be partly contemporaneous.
However, they are related to two distinct upper crustal magmatic reservoirs, and they cannot be considered as a genetically
paired porphyry–Cu and high-sulfidation epithermal related to a single magmatic–hydrothermal system centered on the same intrusion. 相似文献
19.
Victor L. Vinograd Bjoern Winkler Daniel J. Wilson Andrew Putnis Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544
Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca3Fe2Ge3O12 and Ca4Ge4O12. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca2+ and Ge4+ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite. 相似文献
20.
Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike–sill system exposed in the Candelaria open pit have been dated with the U–Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz–monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu–Au mineralization (Re–Os molybdenite ages at ∼115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria–Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz–monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu–Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified 40Ar/39Ar and K/Ar systematic in some areas. 相似文献