Stability of fine‐grained TT‐OSL and post‐IR IRSL signals from a c. 1 Ma sequence of aeolian and lacustrine deposits from the Nihewan Basin (northern China)

We tested the suitability of the fine‐grained quartz (4–11 μm) Optical Stimulated Luminescence (OSL) and thermally‐transferred OSL (TT‐OSL), and the fine‐grained polymineral (4–11 μm) post‐infrared IRSL (post‐IR IRSL or pIRIR) signals for dating samples from aeolian‐lacustrine deposits from the Xiaochangliang archaeological profile in the Nihewan Basin, China; these deposits include material from the Jaramillo subchron (c. 1.0 Ma). In the upper aeolian section, the OSL and pIRIR₂₉₀ ages are consistent with each other, and show that the upper 8.8 m was deposited between c. 0.3 and c. 140 ka. The luminescence ages indicate a major discontinuity in deposition between the aeolian and the older lacustrine deposits. Below this hiatus at 9.4 m (i.e. in the lacustrine sediments) all three signals are found to be in field saturation (no further systematic increase in burial dose with depth) despite the TT‐OSL signal (apparent mean burial dose ~880 Gy) being well below saturation on the laboratory growth curve. This is in contrast to the pIRIR₂₉₀ signal, which saturates in the field at a level consistent with laboratory saturation. This results in a practical upper limit to the measured burial dose of ~900 Gy (2D₀). Thus for the TT‐OSL and pIRIR₂₉₀ signals, the upper limits for dating lacustrine deposits are <260 ka and c. 240 ka, respectively. These results have major implications for the appropriate future application of these signals. The ages of our lacustrine samples cannot be regarded as necessarily accurate ones; nevertheless, these ages provide the first long series absolute chronology for study of local palaeolithic and geomorphic evolution history aside from the magnetostratigraphical results available before this research.     

Mercury in lake sediments of the Precambrian Shield near Huntsville, Ontario, Canada

 Long sediment cores (>1 m) were collected from eight Precambrian Shield lakes in southern Ontario, Canada and analyzed for mercury (Hg), loss-on-ignition (LOI), and a suite of 36 other elements. Results indicated at least 100-fold variation in sediment Hg concentrations between lakes in close proximity (from 450 ppb), comparable to the variation reported for lakes across the whole of Canada. Strong areal correlations between Hg concentrations and LOI (r ² =0.77), between Hg and other trace element concentrations (Pb, Zn, Cd, Sb, As, Br), and similarities in the vertical concentration profiles of Hg and LOI, all point to the importance of organic matter in the release, transport and redistribution of metals in watershed systems. The spatial pattern of Hg concentrations in deep, precolonial sediments (>20 cm) was found to mirror the pattern of Hg concentrations in modern surface sediments, an observation that was confirmed in a follow-up survey (r ² =0.85;n=25 lakes), indicating that natural processes govern the unequal distribution of Hg among these lakes. Between-lake differences in surface sediment Hg concentrations normalized to organic carbon (Hg/C) were also reflected by Hg concentrations in smallmouth bass normalized to 35 cm length (R ² =0.63;n=15 lakes). The latter relationship suggests that smallmouth bass and lake sediment indicators provide mutually supportive information regarding Hg loading to the lacustrine environment from geological sources in the watershed system. Received: 31 October 1996 · Accepted: 27 May 1997     

Dissolved noble gases in the porewater of lacustrine sediments as palaeolimnological proxies

This paper presents results from the numerical modelling of the transport of atmospheric noble gases (He, Ne, Ar, Kr, Xe), tritiated water and ³He produced by radioactive decay of ³H, in unconsolidated lacustrine sediment. Two case studies are discussed: (1) the evolution of ³H and ³He concentrations in the sediment porewater of Lake Zug (Switzerland) from 1953 up to the present; and (2) the response of dissolved atmospheric noble gas concentrations in the sediment porewater of a subtropical lake to an abrupt climatic change that occurred some 10 kyr before the present. (1) Modelled ³H and ³He porewater concentrations are compared with recent data from Lake Zug. An estimate of the effective diffusion coefficients in the sediment porewater is derived using an original approach which is also applicable also to lakes for which the historical ³H and ³He concentrations in the water column are unknown. (2) The air/water partitioning of atmospheric noble gases is sensitive to water temperature and salinity, and thus provides a mechanism by which these environmental variables are recorded in the concentrations of atmospheric noble gases in lakes. We investigate the feasibility of using noble gas concentrations in the porewater of lacustrine sediments as a proxy for palaeoenvironmental conditions in lakes. Numerical modelling shows that heavy noble gases in sediment porewater, because of their comparatively small diffusion coefficients and the strong temperature sensitivity of their equilibrium concentrations, can preserve concentrations corresponding to past lake temperatures over times on the order of 10 kyr. Noble gas analysis of sediment porewaters therefore promises to yield valuable quantitative information on the past environmental states of lakes.     

Origin of arsenic in the groundwater of the Rioverde basin, Mexico

Groundwater in the semiarid Rioverde basin in the northern part of Mexico was investigated with respect to major and minor elements including arsenic, as well as As(III) and As(V). The total arsenic concentrations varied from less than 5 to 50 g/L. The in situ arsenic determination method produced reliable results with deviations from -5.6 to 2.2 g/L compared to laboratory HGAAS. Since arsenic and barium were found to be inversely correlated, it was suspected that precipitation of barium arsenate controlled arsenic solubility. Thermodynamically modeling by means of PHREEQC indicated that BaHAsO₄·H₂O (not BaAsO₄) might be a limiting phase, however only at higher concentrations than those determined in this study. Increased arsenic groundwater concentrations were found with lacustrine sediments and decreased concentrations with fluvial Quaternary sediments. Increased total arsenic concentrations correlate with increased As(III) concentrations in the groundwater of the lacustrine sediments.     

过程响应理论及其在湖相碳酸盐岩中的应用——以辽河西部凹陷中北部地区Es_4为例

过程响应理论是在地球系统科学基础上提出的一种盆地沉积学研究方法,主要包括过程研究和响应研究两个方面,强调盆地演化过程对其沉积过程的控制意义。论文运用过程响应理论对辽河坳陷西部凹陷中北部地区Es4碳酸盐岩进行了研究,取得了很好的效果。研究表明,湖相碳酸盐岩的形成和分布在时间和空间上受湖盆演化过程控制明显,有利的地形和水动力条件、有利的气候和水介质条件、有利的物源和白云岩化条件,这三个关键要素,共同铸就了辽河坳陷西部凹陷中北部地区Es4湖相碳酸盐岩的沉积环境。运用过程响应理论,综合考虑碳酸盐岩沉积作用关键三要素,是建立更具指导作用和更具参考价值的湖相碳酸盐岩综合沉积模式的基础。     

A re-evaluation of Ophiomorpha burrows in the Wealden Group (Lower Cretaceous) of southern England

Attribution of burrows in the Wealden Group of southern England to Ophiomorpha is rejected. The burrows are essentially cylindrical, unlined and with a meniscate fill. Any outer knobbly appearance is due to diagenetic poikilotopic cementation or to differential weathering of a mudchip-sand fill. The variable nature of meniscate fill reflects passage of the producer through the thin-bedded, alternating sand-mud sediments or along sand-mud interfaces. The burrows are assigned to Beaconites, though, since the identity of this ichnotaxon has been questioned, reference is also made to Taenidium. Two ichnoassociations are recognized: (1) a Beaconites antarcticus-Scoyenia (or Taenidium-Scoyenia) association (Weald Clay) of marginal lacustrine situation with fluvial input, and (2) a Beaconites barretti-Planolites (or Taenidium-Planolites ) association of the fluvial (lacustrine delta) of the Lee Ness Sandstone (Ashdown Formation). The Wealden burrows offer no inherent indications of palaeosalinity, and inferences made on supposed occurrences of Ophiomorpha in the Wealden Group must be reassessed. Other occurrences of Ophiomorpha in non-marine facies are questioned.     

Stable isotope geochemistry and diagenetic mineralization associated with the Tono sandstone-type uranium deposit in Japan

The Tono sandstone-type uranium mine area, middle Honsyu, Japan is composed of Miocene lacustrine sedimentary rocks in the lower part (18–22 Ma) and marine facies in the upper part (15–16 Ma). Calcite and pyrite occur as dominant diagenetic alteration products in these Neogene sedimentary rocks. The characteristics of calcite and pyrite differ significantly between lacustrine and marine facies. Abundant pyrite, calcite, organic matter, and small amounts of marcasite or pyrrhotite occur in the lacustrine facies, whereas small amounts of calcite and framboidal pyrite, organic matter and no marcasite or pyrrhotite are found within the marine units. The δ¹³C values of calcite in the lacustrine deposits are low (−19 to −6‰ PDB) but those in marine formation are high (−11 to +3‰). This implies that the contribution of marine carbonate is larger in upper marine sedimentary rocks, and carbon in calcite in the lower lacustrine formation was derived both from oxidation of organic matter and from dissolved marine inorganic carbon. The δ³⁴S values of framboidal pyrite in the upper marine formation are low (−14 to −8‰ CDT), indicating a small extent of bacterial seawater sulfate reduction, whereas those of euhedral-subhedral pyrite in the lower lignite-bearing arkose sandstone are high (+10 to +43‰), implying a large extent of closed-system bacterial seawater sulfate reduction. The δ³⁴S and δ¹³C data which deviate from a negative correlation line toward higher δ¹³C values suggest methanogenic CO₂ production. During diagenesis of the lacustrine unit, large amounts of euhedral-subhedral pyrite were formed, facilitated by extensive bacterial reduction of seawater sulfate with concomitant oxidation of organic matter, and by hydrolysis reactions of organic matter, producing CH₄ and CO₂. Uranium minerals (coffinite and uraninite) were also formed at this stage by the reduction of U⁶⁺ to U⁴⁺. The conditions of diagenetic alteration within the lacustrine deposits and uranium mineralization is characterized by low Eh in which nearly equal concentrations of CH₄ and HCO₃ ⁻ existed and reduced sulfur species (H₂S, HS⁻) are predominant among aqueous sulfur species, whereas diagenetic alteration of the marine formations was characterized by a predominance of SO₄ ²⁻ among dissolved sulfur species. Modern groundwater in the lacustrine formation has a low Eh value (−335 mV). Estimated and measured low Eh values of modern and ancient interstitial waters in lacustrine environments indicate that a reducing environment in which U⁴⁺ is stable has been maintained since precipitation of uranium minerals. Received: 9 February 1996 / Accepted: 11 April 1997     

Characteristics of rare earth elements of lacustrine exhalative rock in the Xiagou Formation of Lower Cretaceous in Qingxi sag, Jiuxi basin

The exhalative rock occurring in the Xiagou Formation of Lower Cretaceous in Qingxi sag, Jiuxi basin is a sort of a rare lacustrine white smoke type, rich in ferrodolomites and albites. This paper introduces the geological background, mineral association, and lithology of the exhalative rock, and discusses its REE geochemical characteristics and connection with hydrothermal environment. It is shown that the exhalative rock has basal characteristics of hydrothermal depositional formation of LREE>HREE, with positive δCe and negative δEu, which is different from the characteristics of marine exhalative rock. Since the REE pattern and exceptional distribution of δEu and δCe are highly similar to the characteristics of alkalescent tholeiitic basalt in the same layer, the exhalative rock of Xiagou Formation is considered to be closely related to the origin of basalt in the same horizon. The fact that the amount of REE of exhalative rock decreases outwards indicates that exhalative rock in the Xiagou Formation may be connected with lacustrine hydrothermal convection circulation. Translated from Journal of Mineral and Petrology, 2006, 26(4): 41–47 [译自: 矿物岩石]     

Trace fossils from Talchir carbonate concretions,Giridih basin,Jharkhand

The carbonate concretions occurring at the bottom of Talchir fissile shale facies preserved signatures of various trace fossils along with a cast of doubtful organisms and cyanobacterial mat structures. The host shale deposited under glacial melt water fed lacustrine condition. The concretions, formed in poorly oxygenated conditions, are either of syndepositional origin and/or deposited a little below the sediment water interface and were later exhumed to the depositional surface due to erosion of soft mud overlying them. The trace fossils are both megascopic and microscopic in nature. The megascopic trace fossils are identified on the basis of their morphology as Monocraterion and Rhizocorallium. Some of the megascopic structures described remain problematic at present. The microscopic trace fossils are formed due to the activity of marine meiofauna (possibly by nematodes), which, although produced morphologically show similar traces of known larger ichnogeneras but much smaller than them. The discovery of these trace fossils apparently indicate the influx of saline water into a lacustrine domain during the Talchir sedimentation at Giridih basin. Moreover, presence of the above two megascopic trace fossils in the marine lacustrine carbonate concretions may lead researchers to consider their much wider environmental significance than hitherto believed.     

Palaeoenvironmental and diagenetic reconstruction of a closed‐lacustrine carbonate system – the challenging marginal setting of the Miocene Ries Crater Lake (Germany)

Chemostratigraphic studies on lacustrine sedimentary sequences provide essential insights on past cyclic climatic events, on their repetition and prediction through time. Diagenetic overprint of primary features often hinders the use of such studies for palaeoenvironmental reconstruction. Here the potential of integrated geochemical and petrographic methods is evaluated to record freshwater to saline oscillations within the ancient marginal lacustrine carbonates of the Miocene Ries Crater Lake (Germany). This area is critical because it represents the transition from shoreline to proximal domains of a hydrologically closed system, affected by recurrent emergent events, representing the boundaries of successive sedimentary cycles. Chemostratigraphy targets shifts related to subaerial exposure and/or climatic fluctuations. Methods combine facies changes with δ ¹³C–δ ¹⁸O chemostratigraphy from matrix carbonates across five closely spaced, temporally equivalent stratigraphic sections. Isotope composition of ostracod shells, gastropods and cements is provided for comparison. Cathodoluminescence and back‐scatter electron microscopy were performed to discriminate primary (syn‐)depositional, from secondary diagenetic features. Meteoric diagenesis is expressed by substantial early dissolution and dark blue luminescent sparry cements carrying negative δ ¹³C and δ ¹⁸O. Sedimentary cycles are not correlated by isotope chemostratigraphy. Both matrix δ ¹³C and δ ¹⁸O range from ca −7·5 to +4·0‰ and show clear positive covariance (R  = 0·97) whose nature differs from that of previous basin‐oriented studies on the lake: negative values are here unconnected to original freshwater lacustrine conditions but reflect extensive meteoric diagenesis, while positive values probably represent primary saline lake water chemistry. Noisy geochemical curves relate to heterogeneities in (primary) porosity, resulting in selective carbonate diagenesis. This study exemplifies that ancient lacustrine carbonates, despite extensive meteoric weathering, are able to retain key information for both palaeoenvironmental reconstruction and the understanding of diagenetic processes in relation to those primary conditions. Also, it emphasizes the limitation of chemostratigraphy in fossil carbonates, and specifically in settings that are sensitive for the preservation of primary environmental signals, such as lake margins prone to meteoric diagenesis.     

Experimental investigation of the compositional variation of acyclic paraffins during expulsion from source rocks

Anhydrous non-isothermal heating experiments were conducted under controlled compressive stress on cylindrical plugs of six oil shales from Permian through Eocene age. The objective of this study was to compare the distribution of acyclic paraffins in initial, residual and expelled organic matter and to highlight causes of compositional differences resulting from expulsion. Pristane generation from kerogen is highest in the Eocene Messel shale and affects the pristane / phytane (pr / ph) ratio commonly used as a redox proxy. The isoprenoid to n-alkane ratios (pr / n-C₁₇, ph / n-C₁₈) decrease during generation and are lowest in the residual bitumen due to preferential generation and retention of n-alkanes. The n-alkane distribution shows that only lacustrine shales produce high wax oils. Evaporative fractionation leads to loss of n-alkanes up to n-C₂₀ with boiling points below 350 °C. This demonstrates that lacustrine and marine shales may lead to accumulation of low wax oils due to evaporative fractionation after expulsion.     

Boron in siliceous materials as a paleosalinity indicator1

The ¹⁰B(n, α)⁷Li nuclear reaction has been used with alpha-sensitive plastic track detectors to determine boron concentrations in siliceous live-collected and fossil sponge spicules. This radiographic technique allows B determinations with 5–6% uncertainties on objects 20–25 μm in diameter and for concentrations as low as 0.5 ppm. Boron concentrations in spicules from different specimens from the same location agreed to within 10% when the spicules were not: (1) smaller than 20 μm in diameter, (2) from dictyonine skeletons, (3) the extremely large root-like spicules found in some soft substrate hexactinellids, or (4) microscleres. These criteria also applied to spicules found in sediment samples. Spicules from live-collected sponges exhibited a taxonomy-independent correlation of B concentrations with water salinity for samples from regions of low water temperature and high productivity. Measured concentrations ranged from nearly 0 ppm B (freshwater sponges) to 500–700 ppm (marine sponges), with intermediate values for brackish-water specimens. However, spicules from tropical, low-productivity marine locations contained markedly less boron than spicules from temperate, high-productivity regions. Thus, water temperature and/or food supply also seem to influence B concentrations. Pleistocene spicules from deep-sea cores contained less boron than was expected in comparison with live-collected spicules based on present water temperatures and nutrient supplies, but B concentrations did not vary with depth in the cores. Infrared spectroscopy, electron microprobe analysis and visual inspection revealed no evidence for chemical or mineralogic alteration. It is not clear whether the lower B concentrations of the Pleistocene samples are the result of diagenetic processes or the as yet undefined effects of differences in food supply and/or environmental conditions.     

Sedimentology and isotope geochemistry of lacustrine carbonates of the Oligocene Campins Basin, north-east Spain

The non-marine Campins Basin developed in the Oligocene, during a period of early rifting of the Catalan Coastal Ranges. Lacustrine deposits, interbedded between two alluvial units, comprise shallow and deep lacustrine facies. The lower, shallow lacustrine facies are made up of microbialite buildups and thin limestone beds. In the studied area, these facies are overlain by deep lacustrine facies which consist of alternations of several, metre-thick carbonate- and mudstone-dominated intervals. In addition to calcite, which is characteristic of the shallow lacustrine facies, aragonite and abundant dolomite are present in the deep lacustrine facies. This mineralogical change in the sequence reflects an overall increase in the Mg/Ca ratio of the lake waters. The deep lacustrine sequences are interpreted as having formed in a hydrologically closed basin that was subject to changes in the Mg/Ca ratio of the water, probably related to variations in the evaporation/precipitation rate. The sedimentological, mineralogical and isotopic characteristics of the Campins Basin dolomites suggest that, in general, they are primary in origin. The stable isotope data show an approximate covariance between δ¹³C and δ¹⁸O in the lower shallow lacustrine carbonates (calcite) which suggests that they formed during the onset of closure of the lake. The δ¹³C and δ¹⁸O values of the deep lacustrine carbonates display three different clusters that are roughly related to the carbonate mineralogy. Normalisation with respect to calcite of the isotopic compositions of dolomite and aragonite from the deep lacustrine carbonates allows the integration of all these isotope values into one covariant trend. The sequential appearance of different carbonate minerals and the isotopic covariant trend may indicate an overall evaporative concentration of the lake waters. The change in slope of the covariant trend for the isotope values between the shallow and the deep lacustrine carbonates might reflect the change in the waterbody morphology recorded in the basin fill sequence.     

Lipid geochemistry of Lake Kinneret

Lake Kinneret, a relict lake from the Neogene, is characterised by the dominance among its phytoplankton of the dinoflagellate Peridinium cinctum. The lipid geochemistry of Lake Kinneret is discussed herein in terms of the biology, chemistry and hydrology of the lake. Lipids isolated from two sediment sections (surface and 15 cm deep), obtained from the deepest point of Lake Kinneret, include: (1) 4α-methyl-5α (H)-stanols and related derivatives characteristic of P. cinctum, the novel sterol 4a-methylgorgosterol, and peridinosterol and 4α-methylgorgostanol, not previously reported to occur in lacustrine sediments; (2) C₃₀ and C₃₂ alkane-1,15-diols, not previously reported to occur in contemporary lacustrine deposits, and (3) products of early diagenesis. Many similarities were observed with the more widely studied marine dinoflagellates and marine sediments with dinoflagellate input.     

Isotopic biogeochemistry of dissolved organic nitrogen: A new technique and application

We present a new technique for isolating and isotopically characterizing dissolved organic nitrogen (DON) for non-marine waters, δ¹⁵N values for DON from lacustrine samples and data suggesting that this technique will be applicable to marine samples. Our technique involves preconcentration of DON via rotary evaporation and removal of dissolved inorganic nitrogen (DIN) via dialysis using a membrane that retains material above 100 Da. Results demonstrate quantitative removal of DIN, complete recovery of DON (95% or greater) and retention of isotopic integrity (isotope effect less than 0.4‰) for a solution containing a DON standard (tripeptide) and DIN in deionized water. Reproducibility of carbon and nitrogen isotope values and elemental concentrations is demonstrated for DOM from Chefswet Basin, Lake Superior and Grand Traverse Bay, Lake Michigan. The applicability of this technique to marine samples is suggested by demonstrating 99% removal of DIN from a sample of Gulf Stream water amended with ammonium and nitrate.     

A geochemical investigation of crude oils and source rocks from Biyang Basin, China

China has a number of petroliferous lacustrine sedimentary basins of varying salinity and age (mainly Eocene). A geochemical investigation has been undertaken on several oils and source rocks from the Eocene lacustrine Biyang Basin. The distributions of n-alkanes, isoprenoids, steranes, and terpanes have been studied and used to characterize the sedimentary environment of deposition, maturity, biodegradation and undertake possible correlations. The ratios of C₃₀-hopane/gammacerane, 4-methyl-steranes/regular steranes, steranes/hopanes, C₂₁ tricyclic/C₃₀ hopane are proposed to be indicative of the depositional environment whereas ß-carotane appears to be a source related indicator. The geochemical data obtained in this study suggest that the major source rocks in the Biyang Basin were deposited in a saline/hypersaline depositional environment.     

Alluvial fan–lacustrine association in the fault tip end of a half-graben, northern Triassic Cuyo basin, western Argentina

The Triassic deposits of Cerro Puntudo in the San Juan province of western Argentina constitute the northernmost exposures of the northern portion of the nonmarine Cuyo rift basin, also known as the Las Peñas-Tamberías half-graben. The local column, with an exposed thickness of approximately 400 m, consists of abundant basal and topmost coarse alluvial fan conglomerates and breccias (facies associations I and II) and a relatively thin (approximately 50 m) intervening sequence of marginal, shallow lacustrine deposits characterized by stromatolitic (domal) limestones, tuffaceous mudstones, and fine-grained sandstones (facies association III). Subaerial exposure in the lacustrine deposits is evidenced by desiccation cracks and brecciation. A very thin (0–6 m), laterally, discontinuous succession of lacustrine deposits with similar characteristics is interbedded with the basal conglomerates. Laterally, this lacustrine interval was eroded by overlying conglomerates. The basal conglomerates commonly show crude normal grading, faint cross-bedding, and b-axis clast imbrication. The predominance of coarse deposits and paleocurrents from NW to SE, indicative of an axial flow pattern, suggest that these exposures correspond to the northern end of the Cuyo basin, which is characterized by a shallow, alluvial fan-encased, carbonate-rich lake margin. This lacustrine interval can be correlated with the thicker lacustrine section exposed to the south at Quebrada del Tigre and Ciénaga Larga along the border fault margin of a nonmarine half-graben. The correlation with these sections suggests that the Cerro Puntudo lacustrine deposits are the shallowest equivalent of more profundal, organic-rich lacustrine sediments exposed in the deepest segment of the border fault margin. These thickness and facies variations are the result of differential subsidence along the border fault margin between the low accommodation, fault tip end represented by the Cerro Puntudo section and the high accommodation, central segment located to the south.     

Radiocarbon chronology of Holocene hydrologic changes in northeastern Mali

A detailed chronology of hydrological changes that occurred in northeastern Mali during the Holocene is based on approximately 30 ¹⁴C dates of molluscs which were collected from the lacustrine and paludal deposits of the Ine Sakane sand sea. The presence of cemented paleodunes indicates that the end of the Pleistocene was and arid period. This was followed by an early Holocene lacustrine episode (ca. 9500–6500 yr B.P.) during which numerous lakes occupied depressions formed in the Cretaceous limestones and between the sand ridges. These lakes reflect a significant rise in the water table. Between ca. 6500 and 5500 yr B.P. the lakes dried up, although the water table remained close to the ground surface in several areas. Calcareous concretions formed at the water table fringe during this time, thereby “fossilizing” some of the middle Holocene dunes. A second lacustrine episode is dated between ca. 5500 and 4500 yr B.P.; it corresponds to the establishment of numerous Neolithic settlements in the area. Arid conditions have developed since about 4500 yr B.P. to attain the conditions of the present day. The isotopic composition (¹⁸O and ¹³C) of the fauna reflects highly variable hydrological conditions. Groundwaters were recharged by precipitation which was occasionally very depleted in heavy oxygen (δ¹⁸O ? ?13%.). Evaporation induced an enrichment in ¹⁸O; high concentrations characterize some lakes. The ¹³C content of fossil shells reflect: (1) species ecological requirements, (2) isotopic composition of the total inorganic dissolved carbon (TIDC) in groundwaters, and (3) the lake metabolism.     

Climatic changes in the Chalbi Desert,North Kenya

The Chalbi flat, located 60 km outside the rift to the east, forms a moist, salt-clay encrusted playa which also functions as an inland sink for alluvial fans. Residual lacustrine beds, including freshwater carbonates and travertines, crop out along its higher periphery. Mammalian bones of lacustrine and terrestrial elements, and K/Ar dating of the capping lava suggest a lake or a swamp environment 2–2.5 million years ago. Radiocarbon dating of Melanoides tuberculata and Planorbis and a sediment assemblage composed of clotted micrite, calcareous molds, root marks and stromatolites point to an additional early Holocene Chalbi lake or swamps 11000-9500 yr BP. The data suggest wet environmental conditions outside the rift, which is consistent with the occurrence of a wet period in the early to middle Holocene in intertropical Africa, but out of phase with the climatic conditions in Sinai and Israel and with the high-latitude maximum lake levels and glacier advance. These relations have probably been caused by migration of climatic belts.     

Evidence for plunging river plume deposits in the Pahrump Hills member of the Murray formation,Gale crater,Mars

Recent robotic missions to Mars have offered new insights into the extent, diversity and habitability of the Martian sedimentary rock record. Since the Curiosity rover landed in Gale crater in August 2012, the Mars Science Laboratory Science Team has explored the origins and habitability of ancient fluvial, deltaic, lacustrine and aeolian deposits preserved within the crater. This study describes the sedimentology of a ca 13 m thick succession named the Pahrump Hills member of the Murray formation, the first thick fine‐grained deposit discovered in situ on Mars. This work evaluates the depositional processes responsible for its formation and reconstructs its palaeoenvironmental setting. The Pahrump Hills succession can be sub‐divided into four distinct sedimentary facies: (i) thinly laminated mudstone; (ii) low‐angle cross‐stratified mudstone; (iii) cross‐stratified sandstone; and (iv) thickly laminated mudstone–sandstone. The very fine grain size of the mudstone facies and abundant millimetre‐scale and sub‐millimetre‐scale laminations exhibiting quasi‐uniform thickness throughout the Pahrump Hills succession are most consistent with lacustrine deposition. Low‐angle geometric discordances in the mudstone facies are interpreted as ‘scour and drape’ structures and suggest the action of currents, such as those associated with hyperpycnal river‐generated plumes plunging into a lake. Observation of an overall upward coarsening in grain size and thickening of laminae throughout the Pahrump Hills succession is consistent with deposition from basinward progradation of a fluvial‐deltaic system derived from the northern crater rim into the Gale crater lake. Palaeohydraulic modelling constrains the salinity of the ancient lake in Gale crater: assuming river sediment concentrations typical of floods on Earth, plunging river plumes and sedimentary structures like those observed at Pahrump Hills would have required lake densities near freshwater to form. The depositional model for the Pahrump Hills member presented here implies the presence of an ancient sustained, habitable freshwater lake in Gale crater for at least ca 10³ to 10⁷ Earth years.