大别山西部河南罗山熊店加里东期榴辉岩锆石特征及SHRIMP分析结果

熊店榴辉岩产于大别山西部苏家河构造混杂岩带内,是典型的高压一超高压中温榴辉岩。作者应用岩学结合阴极发光和扫描电镜方法,较系统地研究了榴辉岩中锆石在岩石中的赋存状态、内部结构及表面特征。锆石主要产于石榴子石等变质矿物内,与主晶界面清晰,具有多晶面等变质锆石特有形貌特征,内部均或发育变质生长结构,从而说明它们是变质作用的产物。ＳＨＲＩＭＰ分析表明,锆石＾２０６Ｐｂ／＾２３８Ｕ年龄为３３５～４２４Ｍａ,     

Petrographic and SHRIMP Studies of Zircons fromthe Caledonian Xiongdian Eclogite, NorthwesternDabie Mountains

The Xiongdian eclogite occurring in the Sujiahe tectonic melange zone at Luoshan County, Henan Province, in the western Dabie Mountains, is typical high-pressure (HP)-ultrahigh-pressure (UHP) and medium-temperature eclogite. The occurrence, internal texture and surface characteristics of zircons in eclogite were studied rather systematically petrographically combined with the cathodoluminescence (CL) and scanning electron microscope (SEM) methods. Zircons are mainly hosted in garnet and other metamorphic minerals with sharp boundaries, have a multifaceted morphology and are homogeneous or exhibit a metamorphic growth texture in the interior, thus indicating that they are the product of metamorphism. SHRIMP analyses give zircon 206Pb/238U ages of 335 to 424 Ma and show a certain degree of radiogenic Pb loss; therefore it may be inferred that the age of 424? Ma represents the minimum age of a HP-UHP metamorphic age. From the above analyses coupled with previous Sm-Nd, 40Ar-39Ar, U-Pb and 207Pb/206Pb age d     

大别山西部熊店加里东期榴辉岩——同位素地质年代学的证据

以UP-Pb单颗粒锆石同位素稀释法、角闪石~(40)Ar—~(39)Ar坪年龄和Sm-Nd全岩及矿物等时线相结合的研究方法,系统地研究了大别造山带西部熊店榴辉岩的峰变质年龄,可能的原岩年龄和退变质年龄,建立了这一榴辉岩的构造-变质时间序列,提出了大别地区存在加里东期榴辉岩的确凿证据。     

Geochronological Study of Caledonian Granulite and High-Pressure Gneiss in the Dabie Mountains

Using the single-zircon evaporation technique and U-Pb method, the authors have conducted an isotope geochonological study of the Huilanshan granulite and Shima garnet-bearing plagioclase gneiss (" country rocks" of the Shima eclogite) in the Dabie Mountains. The study shows that these rocks have peak metamorphic ages of 443-455 Ma, which are essentially consistent with that of the Caledonian high-ultrahigh pressure eclogites. This indicates the existence of the Caledonian collisional orogeny in the Dabie Mountains.     

大别山东部榴辉岩同位素体系和变质作用的关系

大别山东部榴辉岩同位素地质年代学研究反映出三方面的问题:(1)Sm-Nd两点等时线的不确定性;(2)部分高压-超高压变质年龄实际是片麻岩的分析结果;(3)首批发表的"C型榴辉岩"Sm-Nd年龄,测定岩石不是榴辉岩.大别山东部榴辉岩年龄反映的是加里东期高压-超高压变质的年代学信息.进一步研究应着重于榴辉岩锆石成因及Sm-Nd体系适用性.岩相学是研究榴辉岩锆石成因的重要方法.     

Formation Depth Estimation of Coesite-Bearing Eclogite in Dabie UHPM Zone, China： Constrained by Isotopic Studies

The formation depth of metamorphic rocks in the Dabie ultrahigh pressure metamorphic (UHPM) zone influences not only our understanding of formation mechanism and evolution processes of collision orogenic belt, but also the studies on earth's interior and geodynamic processes. In this study, the isotopic data of metamorphic rocks in the Dabie UHPM zone are discussed to give constraints on the formation depth in the Dabie UHPM zone. The εSr of eclogite in the Dabie UHPM zone varies from 18 to 42, and the εNd varies from -6.1 to -17, both of them show the characters of isotopic disequilibrium. The oxygen isotope studies indicate that the protoliths of these UHPM rocks have experienced oxygen isotope exchange with meteoric water (or sea water) before metamorphism and no significant changes in the processes of metamorphism on their oxygen isotope composition have been recorded in these rocks. Except for one sample from Bixiling, all samples of eclogite from Dabie UHPM zone show the 3He/4He ratios from 0.79×10-7 to 9.35×10-7, indicating the important contribution of He from continental crust. All Sr, Nd, O and He isotopic studies indicate that the UHPM rocks retain the isotopic characteristics of their protoliths of crust origin. No significant influence of mantle materials has been found in these metamorphic rocks. Trying to explain above isotopic characteristics, some researchers assume that the speeds of dipping thrust and uplifting of rocks were both very high. In this condition, there will not be enough time for isotopic exchange between crust protolith and mantle materials. Therefore, we can not see the tracer of mantle materials in these UHPM rocks. However, this assumption can not be justified with available knowledge. Firstly, it was estimated that the whole process of UHPM took at least 15 Ma. During such a long period, and at the metamorphic temperature of ≥700 ℃, the protolith of crust origin can not escape from isotopic exchange with mantle materials if the UHPM have happened in the mantle depth of ≥100 km. In contrast, all problems will be dismissed if we assume that the UHPM have happened at the depth still in crust.     

Role of Water in Deformed Omphacite in UHP Eclogite from the Dabie Mountains, Eastern China

Omphacite grains from UHP eclogite of the Dabie Mountains in eastern China are elongated and show strong lattice preferred orientations (LPOs). Observations by the transmission electron microscopy (TEM) identified not only structures of plastic deformation occurring as free dislocation, dislocation loops and dislocation walls, but also bubbles of water present in the deformed omphacite. The bubbles attach to the dislocation loops which are often connected to one another via a common bubble. Using infrared spectroscopy (IR), two types of hydrous components are identified as hydroxyl and free-water in the omphacite. An analysis of deformation mechanism of microstructure in omphacite suggests that the mineral deformed plastically under UHP metamorphic conditions by dislocation creep through hydrolitic weakening.     

Isotopic Geochronology of the Xianghongdian Alkaline Complex, Northern Margin of the Dabie Mountains, China

To the north of the Qinling-Dabie orogen there exists a Mesozoic (K1) granite-syenite belt called the Beihuaiyang granite-syenite belt, in which the Xianghongdian alkaline complex outcrops in the Devonian Foziling schist and also intruded into the slightly earlier volcanic rocks. This alkaline complex is composed of syenite, alkaline syenite and nepheline syenite, but the nepheline syenite occurs inside the alkaline syenite in the pod-like, irregular, lenticular or layered shape. Researches on the petrogenesis of the alkaline complex and the relationship between the alkaline syenite and the nepheline syenite must rely on precise isotopic ages. Previous researches have reported iso-topic dating results merely by the 40Ar/39Ar method on hornblende and biotite separated from the alkaline syenite and nepheline syenite. In view of this, the authors have made fairly detailed isotopic geochronological studies of the alkaline syenite and nepheline syenite by using Rb-Sr isochron for the whole rock and minerals,     

大别山苏家河地区榴辉岩和大理岩的地球化学研究

对大别山西段苏家河地区熊店和杨冲低温榴辉岩及胡家湾榴闪岩进行了详细的氢、氧和锶、钕同位素以及稀土元素和矿物化学分析。熊店榴辉岩和胡家湾榴闪岩的全岩δ＾１８Ｏ值较高（８．８‰￣１１．２‰）,而杨冲榴辉岩的全岩δ＾１８Ｏ值较低（４．３‰）,它们的全岩δＤ值为－５５‰￣７５‰。结合锶、钕同位素和稀土元素组成特征,推测苏家河榴辉岩（榴闪岩）的原岩可能为岛弧玄武岩,变质前曾与海水在不同温度下进行过氢、氧同位     

阿尔泰加里东期变质成因伟晶岩型白云母矿床的成矿年代证据及其意义

本次工作通过野外调查和同位素年代学研究,首次在阿尔泰西部的也拉曼大型含绿柱石白云母矿床(426±13Ma)、阿尔泰中部的那森恰大型含绿柱石白云母矿床(447.7±0.4Ma)及阿尔泰东部的青河拜兴白云母伟晶岩脉(436.0±0.5Ma)中获得了可靠的加里东期成矿的同位素年代证据,从而为解决是否存在加里东期成矿的问题提供了重要依据,并进一步认识到阿尔泰地区的伟晶岩及伟晶岩型稀有金属-白云母矿床并非只形成于海西期。     

大别山碧溪岭榴辉岩的K-Ca同位素定年:多硅白云母含过剩氩的新证据

40K可以进行分支衰变成40 Ar和40 Ca。在正常情况下 ,这对40 K 40 Ar或3 9Ar 40 Ar年龄与40 K 40 Ca年龄在误差范围内应该一致。测定了国家钾标样的含量、国家钾长石 (W 0 3116 )和球团矿 (W 72 0 0 )的钾钙含量、国内K Ar法标准矿物黑云母 (ZBH 2 5 )和角闪石 (ZBJ)的钾钙含量以及Tachiti标样的 (40 Ca/42 Ca)比值和含量 ,结果实测值与标称值在误差范围内一致。对大别山碧溪岭超高压变质榴辉岩的多硅白云母、绿辉石和石榴子石进行了 (40 Ca/42 Ca)和 (40 K/42 Ca)的测定。由15组数据构成的等时线斜率S =0 .12 0 8± 0 .0 4 2 3,相应的K Ca年龄为 2 2 8± 75Ma。然而多硅白云母和绿辉石的3 9Ar 40 Ar等时线年龄分别为 80 7.1± 32 .6Ma和 4 5 6 .7± 2 7.2Ma ,在误差范围内明显地高于40 K 40 Ca等时线年龄 ,这给出了前者存在过剩氩的直接证椐。此外 ,K Ca等时线的初始值 (40 Ca/42 Ca) i 为 15 1.4 2 4± 0 .0 13,相应的 ξCa为 +2 7。由于地幔岩的 ξCa≈ 0 ,所以前者表明榴辉岩的原岩具有典型的大陆地壳性质 ,这为大别山超高压变质岩体是由大陆物质俯冲至上地幔的深度 ,然后折返至大陆的形成过程提出了又一个判据     

大别山双河地区超高压变质岩矿物超微构造的HRTEM研究

报道了大别山双河地区超高压榴辉岩和硬玉石英岩矿物超微构造及缺陷结构的高分辨透射电镜研究结果。在天然变形绿辉石晶内的自由位错、位错倾斜壁、位错环、位错网、亚晶界、堆垛层错等亚构造中 ,发现了纳米级水分子团 ,这种球形状水分子团包体的存在是导致绿辉石晶体水解弱化和塑性变形的重要因素。在榴辉岩矿物中广泛发育的层错、(10 0 )变形双晶、晶畴结构、界面与晶面的交叉滑移、晶格畸变等变形构造及缺陷结构 ,指示超高压岩石经历了快速折返。在硬玉单晶大约 5 0 0nm的微晶畴内 ,发现了C2 /c和P2 1/n两种结构 ,C2 /c结构的晶体学参数对应于硬玉 ,而P2 1/n结构的晶体学参数对应于绿辉石 ,纳米级P2 1/n出溶结构的存在 ,表明在退变质过程中 ,硬玉在纳米尺度上部分转变为绿辉石 ,并且未能达到平衡。也说明在主体岩石的抬升过程中 ,硬玉晶体伴随有复杂的非平衡退变质作用。对于大别山超高压变质岩的p T轨迹描述及其构造解释具有重要意义。     

大别山朱家冲斜长角闪岩-角闪榴辉岩-柯石英榴辉岩相转变实验研究

在750～1200C、1.0～4.5GPa条件下对取自于大别山朱家冲的斜长角闪岩进行了重结晶实验,并对其在高压-超高压区域的相关系进行了简要讨论。结果表明,在750 C时,斜长角闪岩随压力的前进演化经历了斜长角闪岩(Ga+Amp+Ep+Bi+Pl+Qz,1.0～1.5 GPa)、角闪榴辉岩(Ga+Cpx+Amp+Ep+Ph+Qz,1.75～2.25 GPa)、石英榴辉岩(Ga+Cpx+Zo+Ph+Qz,2.5 GPa)、柯石英榴辉岩(Ga+Cpx+Zo+Ph+Cs,3.0～3.5 GPa)和硬柱石榴辉岩(Ga+Cpx+Law+Ph+Cs,4.0～4.5 GPa)5个阶段,每个阶段之间的相关系可由一些特定的变质反应来限定。角闪石是榴辉岩演化早期和晚期阶段的主要共生矿物,它可以被看做是一种指示性矿物,其稳定上限低于2.5 GPa。黝帘石-蓝晶石-柯石英组合的出现指示大别山榴辉岩的压力上限未达到硬柱石的稳定区域,其形成压力不会超过4.0～4.5 GPa。榴辉岩中含水矿物的前进替代证明在俯冲带中有部分地表水被携带至地幔,而连续的脱水作用也为俯冲板片的部分熔融提供了水源。     

U—Pb Dating of Marble Assoicated With Eclogite from the Dabie Mountains,East China

Marble is associated with ultrahigh pressure eclogite in the Dabie Mountains, East China. U-Pb isotope data for the marble define a²³⁸U-²⁰⁶Pb isochron age of 435 ± 45 Ma with an initial²⁰⁶Pb/²⁰⁴Pb value of 18.075 ± 0.006. The age of ∼435 Ma is interpreted to represent the time of limestone diagenesis rather than the time of metamorphic resetting accompanied by the formation of the ultrahigh pressure eclogites at Triassic. The paleontologic and stratigraphic studies also favor a local excursion in the carbon isotopic composition of the latest Ordovician water within a sedimentary basin between the Sino-Korean and Yangtze cratons. Because the latest Ordovician limestone was involved in the eclogite formation, the continental collision between the Yangtze and Sino-Korean plates would postdate Ordovician. This project was financially supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.     

Formation Depth of Coesite-Bearing Eclogite, Dabie UHPM Zone, China

The plastic deformation of garnet in coesite-bearing eclogite,quartz eclogite and garnet amphibolite of the UHPM complex in Yingshan County in the Dabie Mountains has been studied. The stress generated by the strong tectonic movement was an important component of the total pressure that resulted in the formation of the eclogite in the Dabie UHPM zone. The three-dimensional tectonic principal stresses and additional tectonic stress-induced hydrostatic pressure ［ps=(σ1 σ2 σ3)/3］ are reconstructed according to the differential stress and the strain ratio(α) of the garnet in the minor coesite-bearing eclogite of the Yingshan County. Then the gravity-induced hydrostatic pressure(pg) is calculated following the equation p minus ps,where p is estimated to be 2.8 Gpa based on the quartz-coesite geobarmeter. Therefore,the thickness of the rock column overlying the coesite-bearing eclogite in the Ying-shan County is determined ≥32 km. This estimation,significantly different from ≥100 km,the previous one obtained solely based on the weight/specific weight ratio(W/SW),offers a proper explanation for the puzzle that no tracer of the addition of mantle-derived material has been found in the Dabie UHPM zone during the process of UHPM,although a number of researchers claim that this process took place at the depth of the mantle(≥100 km). It is concluded that attention should be paid to the additional tectonic stress-induced hydrostatic pressure in the study of UHPM zones.     

Retrogressive Microstructures of the Eclogites from the Northern Dabie Mountains, Central China： Evidence for Rapid Exhumation

The ultrahigh-pressure eclogites from the northern Dabie Mountains in central China occurred as tectonic lens or blocks within granitic gneisses or meta-peridotites. Petrologic studies suggest that the studied eclogites experienced strongly retrogressive metamorphism and produced a series of characteristic retrogressive microstructures. The retrograde structures mainly include: (1) oriented needle mineral exsolution, e. g. , quartz needles in Na-clinopyroxene and rotile, clinopyroxene and apatite exsolution in garnet formed under decreasing pressure conditions during exhumation; (2) symplectite, especially, two generations of symplectites developed outside the garnet grains, which are called ““double symplectite““ here; (3) compositional zoning of minerals such as garnet and clinopyroxene; (4) minerals with a reaction rim or retrograde rim, e.g. , omphacite with a diopside rim, diopside with an amphibole rim and rutile with a rim of ilmenite. These retrograde textures, especially mineral zoning and symplectite, provide important petrologic evidence for the exhumation process and uplift of high-grade metamorphic rocks such as eclogite in the northern Dabie Mountains, indicating a rapid exhumation process.     

南大别太湖地区榴辉岩峰期变质温压条件及所揭示的构造含义

通过岩石学、矿物成分和峰期变质温压条件的研究表明，南大别变质块体由超高压带、高压/超高压“混合”带和高压带3个变质单元组成，具有区域上的温压渐变趋势。应用5个Grt-Cpx温度计和Grt-Cpx-Phe压力计。对榴辉岩的峰期变质温压条件计算显示，自北向南，可分为4个温压域，温度压力逐渐降低：760～950℃，3．5～4．1GPa→660-750℃，2．7～3．1GPa→640-780℃，2．0～2．7GPa→550～680℃，1．5～2．3GPa，这表明南大别变质块体在俯冲过程中是一个连续的块体。然而，超高压带和高压带之间的压力差异以及不同变质带内相邻榴辉岩之间的压力差、无序分布特征及其与围岩的构造接触关系显示，南大别变质块体经历了强烈的缩短过程，现今榴辉岩的分布特征反映的是折返至地表的状态。     

大别山菖蒲—碧溪岭地区高压—超高压榴辉岩相变质岩和有关岩石的岩石类型及其原岩性质

安徽岳西菖蒲—碧溪岭地区出露两条北北西向的高压—超高压变质岩带:西带由土桥冲至菖蒲水电站,该带由层状硬玉石英岩类、大理岩及少量的石英深色榴辉岩以及浅色榴辉岩等组成;东带由小南山岭至碧溪岭,主要由层状的浅色榴辉岩系列和层状深色榴辉岩系列岩石组成。该区发育的层状浅色榴辉岩和层状的深色榴辉岩两种榴辉岩在岩石组合、矿物组合、矿物成分等方面有明显差别。浅色榴辉岩一般由硬玉质绿辉石(Jd 65～45)、+镁铝以及钙铝端元成分(Pyr+Gro,60±)的石榴子石+蓝晶石±多硅白云母±石英及次生的角闪石、绿帘石组成。其中夹有硬玉质绿辉石石英岩、富蓝晶石岩石、石榴子石岩和硬玉石榴白云片岩等岩石薄层。深色榴辉岩由绿辉石(Jd20～50)±富铁铝端元的石榴子石(Alm 50～60)+金红石±石英及次生的角闪石等组成。石英深色榴辉岩由绿辉石(Jd 40～45)+镁铝端元的石榴子石(Pyr 10～30)+石英+金红石及次生的角闪石、长石组成。深色榴辉岩与石榴橄榄岩分布上紧密相随。浅色榴辉岩的原岩为基性凝灰质沉积岩,相伴随的硬玉石英岩、硬玉岩、白云片岩的原岩大致分别为粉砂岩、长石砂岩、泥质粉砂岩;深色榴辉岩为基性凝灰质熔岩。大理岩的原岩为灰岩。同时,本文的研究表明,在相同的变质作用条件下,榴辉岩相岩石中石榴     

最优化的矿物扩散地质速率计:北大别黄土岭麻粒岩缓慢冷却的证据

对北大别黄土岭麻粒岩中石榴子石进行了详细的电子探针工作，并根据一颗石榴子石的成分环带，建立了扩散模型并进行了数值模拟，结合最优化的方法，得到了极其缓慢的冷却速率0.1℃/a。从扩散动力学数值模拟的角度对大别山造山带的冷却速率进行了探索性研究。该结果表明，黄土岭麻粒岩在受麻粒岩相改造后经历的是一个极其缓慢、持续时间很长的冷却过程。     

大别山北部榴辉岩和英云闪长质片麻岩锆石U-Pb年龄及多期变质增生

大别山北部榴辉岩及英云闪长质片麻岩的锆石U-Pb年龄分析表明：北部榴辉岩相峰期变质时代为226～230Ma左右;北部塔儿河一带英云闪长质片麻岩经历过印支期变质事件;大别山北部与南部超高压岩石中一致的（226～230Ma）高压或超高压变质年龄表明,北部镁铁-超镁铁质岩带中部分岩石也曾作为扬子俯冲陆壳的一部分,在印支期发生过高压或超高压变质作用;本区锆石发生过两期变质增生事件,一是印支期高压或超高压变质,另一期是燕山期热变质事件;榴辉岩及英云闪长质片麻岩的原岩形成时代为晚元古代;锆石U-Pb年龄可用多期变质增生模型来解释。