云南老王寨金矿区煌斑岩中云母的矿物化学

云南老王寨金矿区煌斑岩中呈斑晶和基质产出的云母以金云母为主，少量富镁黑云母，环带结构发育。矿物化学表明本区云母的寄主岩石属碱性岩系列，岩石类型为钙碱性煌斑岩；同时提供了煌斑岩源于交代富集地幔和受地壳物质混染程度低等成因信息。云母多种多样的环带结构暗示其寄主的煌斑岩具复杂的岩浆结晶演化过程。     

绢云母短波红外光谱特征及其在矿产勘查中的应用

蚀变矿物短波红外(SWIR)光谱特征日趋广泛地应用于矿产勘查研究中。绢云母作为热液矿床中最为发育的蚀变矿物之一,通过SWIR光谱技术提取其谱学特征,进而建立与矿床基础地质信息之间的相关性具有重要意义。然而,前人对于绢云母短波红外光谱特征的研究主要集中于单个矿床,缺少不同矿床间的对比。基于此,文章梳理了混合矿物光谱曲线中对单一矿物相对含量的提取方式,系统总结了温度、流体化学成分、流体pH值、寄主岩石、矿物结构、矿物粒度及共(伴)生矿物等因素对绢云母谱学特征空间变化规律的影响,最后,从契尔马克替换效应角度出发,分析对比了5种不同成因类型矿床中近矿端绢云母波长变化。虽然将绢云母短波红外光谱特征有效地应用于矿产勘查仍存在诸多问题,但作者相信,应用绢云母短波红外光谱特征进行矿产勘查依然具有良好的前景。     

青藏高原西部喜马拉雅期花岗岩类特征及岩石系列

青藏高原西部喜马拉雅期花岗岩类岩石组合为透辉石正长岩－透辉石花岗岩－黑云母（二长）花岗岩,主要造岩矿物有钾长石、斜长石、石英、黑云母、透辉石和角闪石。岩石化学成分富碱、高钾、Ｋ２Ｏ／Ｎａ２Ｏ比值大,微量元素富集Ｒｂ,Ｓｒ、Ｂａ、Ｔｈ、Ｕ和ＬＲＥＥ,Ｓｒ、Ｎｄ同位素组成具有幔源特征,岩石属于钾玄岩（ｓｈｏｓｈｏｎｉｔｅ）系列。     

贵州东部镇远地区钾镁煌斑岩的矿物学和岩石学研究

摘要：通过对贵州东部镇远地区的一套偏碱性的基性超基性煌斑岩的矿物学及岩石学研究,发现该套岩石具有多种钾镁煌斑岩的特征矿物和结构：含钛的钾碱镁闪石、钛金云母、低铝透辉石、含铁透长石,以及金云母的嵌晶状结构、橄榄石的＂犬牙＂结构。在岩石地球化学方面,它们与世界典型地区的钾镁煌斑岩相似。根据对比鉴定,将这套岩石定名为：（１）金云母钾镁煌斑岩;（２）含橄榄石嵌晶状钾镁煌斑岩。     

南天山英买来花岗岩:磁铁矿系列还是钛铁矿系列?

位于南天山中段英买来岩体的主体由中粗粒似斑状黑云母钾长花岗岩组成,局部有粗粒似斑状二云母钾长花岗岩。二者全岩化学成分相似,但在矿物组成上表现出一定差异。前者不透明矿物为钛铁矿,而后者出现原生白云母,不透明矿物全部为磁铁矿。根据石原舜三(1977)的划分方案,黑云母钾长花岗岩全部符合钛铁矿系列特征,而二云母钾长花岗岩虽然表现出不透明矿物为磁铁矿、所含黑云母富镁等看似符合磁铁矿系列的特征,但所有的磁铁矿均和黑云母、钾长石共生,因此推测磁铁矿是由黑云母分解析出而成,并结合其同样具有全岩Fe3+/(Fe3++Fe2+)低、且出现钛铁矿系列的特征共生矿物白云母,亦判定其属于钛铁矿系列。另外,英买来岩体的矿物学和地球化学特征均符合S型花岗岩的特征,说明在本区钛铁矿系列和S型花岗岩相当。研究结果也表明南天山地区在早二叠世还没有完全进入板内演化阶段。     

胜利油田惠民凹陷辉绿岩中黑云母矿物化学

黑云母是胜利油田惠民凹陷辉绿岩中的次要矿物,以斑晶、基质和次生云母三种产状产出,其中斑晶云母绝大部分已被绢云母、碳酸盐、石英和磁铁矿等替代。本文分析了基质和次生云母的化学成分,发现两者的成分具有明显差别,在云母分类命名图上,前者投于富镁黑云母和镁铁黑云母之间,后者落在富铁黑云母区域。基质云母化学成分判别本区辉绿岩主要属碱性系列、部分为钙碱性系列,同时指示成岩过程中存在较明显的地壳物质混染作用和结晶分异作用。     

印度中部MaДЖГaBaH金刚石岩管的物质成分特征

本文报道MaДЖГaBaH（印度中部）火山岩管含金刚石岩石的综合研究结果，首次分析了这个岩管岩石中的金云母、蛇纹石、硫化物的成分。按成分MaДЖГaBaH岩管的岩石实际上完全缺乏碳酸盐物质，TiO2和P2O5含量较高，含有高钛金云母和指示矿物（镁名榴石、铬铁矿、钛铁矿）含量低而不同于典型的金伯利岩。同时这种岩石与含钾镁煌斑岩也有显著差别：含K2O很低（0．46－1．79％），没有发现单斜辉石、钾碱镁闪石。这种岩石似乎是金伯利岩和钾美煌斑岩之间的过渡类型。     

胜利油田惠民凹陷辉绿岩中黑云母矿物化学

黑云母是胜利油田惠民凹陷辉绿岩中的次要矿物,以斑晶、基质和次生云母三种产状产出,其中斑晶云母绝大部分已被绢云母、碳酸盐、石英和磁铁矿等替代.本文分析了基质和次生云母的化学成分,发现两者的成分具有明显差别,在云母分类命名图上,前者投于富镁黑云母和镁铁黑云母之间,后者落在富铁黑云母区域.基质云母化学成分判别本区辉绿岩主要属碱性系列、部分为钙碱性系列,同时指示成岩过程中存在较明显的地壳物质混染作用和结晶分异作用.     

甘肃西秦岭区新生代碱性火山岩中的钛金云母

本文对甘肃西秦岭区新生代火山岩及所携带的上地幔包体中钛金云母进行矿物学和矿物化学研究。本区火山岩中的金云母与金伯利岩、钾镁煌斑岩和一般云煌岩中的金云母不同，其化学成分显示了一种过渡类型特征。巨晶和粗晶金云母是在＞１３００℃，３０×１０￣８ｐａ，富ＣＯ＿２和Ｈ＿２Ｏ的条件下的早期结晶相。微晶金云母为近液相线快速冷却的产物。橄榄岩包体和球状体中金云母的成因似与流体交代作用有关，这种钛金云母的出现进一步证明新生代火山岩起源于被交代了的地幔，交代流体具有富Ｋ、Ｎａ、Ｔｉ等不相容元素和挥发分ＣＯ＿２、Ｈ＿２的特征。     

钾玄岩系列:藏东玉龙铜矿带含矿斑岩元素地球化学特征

西藏东部玉龙铜矿带,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多等斑岩型Ｃｕ,Ｍｏ,Ｐｂ,Ｚｎ,Ａｕ,Ａｇ和Ｐｔ等多金属矿床．由于分析技术条件的限制,前人所获得的含矿斑岩微量元素数据精度较低．采用先进的ＰＥＥｌａｎ６０００型电感耦合等离子质谱仪（ＩＣＰ－ＭＳ）分析微量元素（包括稀土元素）,结果表明含矿斑岩和共生的钾质碱性深成岩、火山岩和煌斑岩在时空上具一致性,岩石化学成分均富碱（ｗ（Ｋ２Ｏ）＋ｗ（Ｎａ２Ｏ）＞８％）,高钾和ｗ（Ｋ２Ｏ）／ｗ（Ｎａ２Ｏ）比值远大于１,微量元素富集Ｓｒ,Ｂａ等大离子亲石元素和轻稀土元素等,均显示出钾玄岩系列岩石的特征,暗示西藏东部玉龙铜矿带的含矿斑岩属于典型的钾玄岩系列的斑岩     

On micas from magmatic and metamorphic rocks

Micas from magmatic and metamorphic rocks differ from one another in chemical composition and in trace element content. The chemical composition of micas is discussed in relation to their occurrence, paragenesis and sequence of crystallization. On the basis of previous studies of the relationship between the physical properties and the chemical composition of 34 chemically analysed micas, reliable physical methods have been established which permit identification of different mica varieties in the same rock. Structural formulae and trace element content of micas from basic and granitic rocks, as well as from skarns, schists, ortho- and paragneisses are discussed. The relationship between the components of the tetrahedral and octahedral layers and of the interlayer are illustrated as ratios. Poorly differentiated, hybrid and metasomatic rocks often contain more than one variety of mica. Some prophyritic basalts and lamprophyres contain an early phlogopite which is paragenetically related to pyroxene phenocrysts and late biotite which occurs in the groundmass and in the fractures as a result of the crystallization of residual magma. The biotitemuscovite assemblage was observed in granodiorites, quartz-monzonites, schists and gneisses. In the albite-K-feldspar granites, muscovite predominates and the biotite is usually altered. The chemical composition of micas from metamorphic rocks depends on the grade of metamorphism and on the nature of associated minerals. The biotite from paragneisses contains considerable quantities of octahedral alumina. Pre-metamorphic micas show variable deficiencies of the (OH, F) group. The micas are useful minerals in determining the degree of differentiation and subsequent alteration of igneous rocks. The present study was carried out on the basis of 34 recent complete chemical analyses andca 100 X-ray fluorescence analyses. Dedicated to Professor Dr.Carl W. Correns on the occasion of his 70th birthday.     

Compositions of micas in peraluminous granitoids of the eastern Arabian shield

Compositions and pleochroism of micas in fourteen peraluminous alkali-feldspar granites in the eastern part of the Late Proterozoic Arabian Shield are unlike those of micas (principally biotite) in most calc-alkaline granitoid rocks. Compositions of these micas are distinguished by elevated abundances of Li₂O, F, and numerous cations and by low MgO abundances. These micas, constituents of highly evolved rare-metal enriched granitoids, represent an iron-lithium substitution series that ranges from lithium-poor siderophyllite to lithium-rich ferroan lepidolite. The eastern Arabian Shield also hosts six epizonal granitoids that contain colorless micas. Compositions of these micas, mostly muscovite, and their host granitoids are distinct from those of the iron-lithium micas and their host granitoids. Compositions of the analyzed micas have a number of petrogenetic implications. The twenty granitoids containing these micas form three compositional groups that reflect genesis in particular tectonic regimes; mica compositions define the same three groups. The presence of magmatic muscovite in six of these shallowly crystallized granitoids conflicts with experimental data indicating muscovite stability at pressures greater than 3 kbar. Muscovite in the Arabian granitoids probably results from its non-ideal composition; the presence of muscovite cannot be used as a pressure indicator. Finally, mineral/matrix partition coefficients are significantly greater than 1.0 for a number of cations, the rare-earth elements in particular, in many of the analyzed iron-lithium micas. Involvement of these types of micas in partial melting or fractionation processes can have a major influence on silicate liquid compositions.     

藏东玉龙铜矿带含矿斑岩及成岩系列

西藏东部新生代玉龙铜矿带含矿斑岩,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多等,均为同期不同阶段侵入地质体构成的复式岩体。岩石类型有石英二长斑岩、二长花岗斑岩、正长花岗斑岩和碱长花岗斑岩。岩石化学成分均富碱（Ｎａ２Ｏ＋ｋ２Ｏ〉８％）、高钾和Ｋ２Ｏ／Ｎａ２Ｏ比值远大于１等,属于碱性钾质系列,即钾玄岩系列。     

The Origin and Features of the Two Intermediate-Acid Intrusive Series in Tongling Area, Anhui, China

1. Introduction Tongling district is situated in the southern part of the Yangtze River, Anhui province, China (Fig. 1). It is one of the most important metal basements in China, being rich copper material resources, also named "ancient copper capital of China". Studies showed that each copper ore deposit is bound up with the intermediate-acid intrusive rocks in the area. Therefore, many researchers (e.g. Chang Yinfu et al, 1987; Xing Fengming, et al, 1995; Zhou Xinrou, et al, 1993; and…     

Coexisting K-rich alkaline and shoshonitic magmatism of arc affinities in the Proterozoic: a reassessment of syenitic stocks in the southwestern Grenville Province

Biotite-rich syenitic stocks in the Mont-Laurier area of the southwestern Grenville Province are shown to belong to the first recorded Proterozoic example of an ultrapotassic, K-rich alkaline and shoshonitic rock association with clear arc affinities. The plutons investigated were previously considered mostly syenitic, typical of nepheline syenite alkaline suites, slightly metamorphosed and late-tectonic with respect to the Grenville orogeny. We find that they postdate the regional metamorphism and comprise a felsic to ultramafic range of rock types belonging to two series: (1) a potassic-to-ultrapotassic, silica-undersaturated series of biotite-rich nepheline-bearing syenite, syenite, monzonite, diorite and pyroxenite, and (2) a shoshonitic, critically silicasaturated series of quartz syenite and amphibole-bearing syenite, with rare monzonite and diorite. The ubiquitous biotite, previously regarded as metamorphic, is reinterpreted as igneous and diagnostic of the potassic character. The shoshonitic and potassic series display the strong enrichment in Al, Ca, K and large-ion-lithophile elements relative to the high-field-strength elements (e.g. Ba/Nb722, La/YB45) and the low contents in Mg that are characteristic of arc-related magmas. The syenitic rocks consistently share the distinctive arc-related geochemical signature of their mafic counterparts. Syenites may thus represent a potential source of paleotectonic information for high grade terranes. Geochemical discriminants (Nb_N/Ta_N and Hf_N/Ti_N ratios) indicate that the shoshonitic and potassic series are unrelated by closedsystem fractionation processes. Rather, the chemical differences between the two series probably reflect differences in source characteristics and conditions of melting. Similar plutons occur throughout the Central Metasedimentary Belt of the southwestern Grenville Province. They define a 1089 to 1076 Ma, 450-km-long grenvillian potassic alkaline plutonic (PAP) province. The presence of this K-rich alkaline province indicates that the scarcity of K-rich rocks in the Precambrian could be only apparent and a consequence of misidentification of K-rich plutons in metamorphosed Precambrian terranes. These 1.1 Ga ultrapotassic to shoshonitic plutonic rocks are geochemically similar to shoshonites and leucitites of the Sunda arc. This similarity suggests that subduction-type enrichment processes were operating in the Proterozoic in ways similar to those of modern settings.     

Si+4 Content of natural phengites

The chemical compositions of white micas separated from adjacent rocks of glaucophane and greenschist facies are compared with respect to their Si⁺⁴ content. The micas are predominantly phengitic, i.e. between muscovite, K[Al₂Si₃AlO₁₀(OH)₂] and celadonite, K[(R⁺²R⁺³)Si₄O₁₀(OH)₂] in composition. Constancy of Si content in micas coming from rocks of different bulk chemical composition but closely similar physical conditions indicates that the silica content of a potassic dioctahedral mica can be used to indicate the pressure and temperature conditions of its formation. This conclusion is in part based upon previous experimental data obtained for synthetic phengites.     

Mica Types as Indication of Magma Nature, Central Anatolia, Turkey

This study focuses on the nature of giant micas occurring at the contact between the ?zvatan (foid-bearing) syenites and the metamorphic basement in Central Anatolia. The studied micas are dark greenish-black in color and crystallized within vein shape like bodies as a narrow lens. The origin and processes responsible for the formation of these independent crystals of the giant micas were investigated by mineralogical, petrographical and geochemical analyses with the use of Confocal Raman Spectroscopy (CRS), Fourier Transform Infrared (FTIR) Spectroscopy, X-Ray Diffraction (XRD), Polarized Energy Dispersive X-Ray Fluorescence Spectrometer (PED-XRF) and Electron Probe Micro Analysis (EPMA). According to XRD, CRS, FTIR and EPMA data, the giant micas are phlogopite. EPMA results reveal that studied mica minerals represent the products of re-equilibrated primary mica characterized by high MgO and FeO and low Al2O3 and TiO2 contents. The trace element concentrations of the giant micas display similar patterns with the upper crust. The giant micas are crystallized within small cubicles from an alkaline magma and their composition is possibly modified by a mixing event between the crust- and mantle-derived magmas and contaminated at varying extent by the basement metamorphic rocks.     

松辽盆地长岭断陷早白垩世火山岩地球化学研究

长岭断陷早白垩世火山岩富硅、富碱,岩石以非碱性系列为主,包括钙碱性和高钾钙碱性系列,碱性系列火山岩为钾玄岩系列。酸性岩与中、基性岩的微量元素特征差别明显,岩石总体微量元素特征与造山带火山岩相似,富集LREE、Rb、K和大离子亲石元素,TiO2含量低,贫Sr。火山岩的形成与造山带岩石圈拆沉作用引起地壳拉张减薄的大地构造背景有关。研究区基性火山岩为地幔岩部分熔融作用的产物,岩浆演化过程中存在单斜辉石和橄榄石等矿物的分离结晶作用,中性岩为原生玄武质岩浆分异演化的产物,营城组酸性火山岩的形成与构造活动存在直接关系,为构造剪切挤压应力致使上地壳重熔的结果。     

Rock Series and Genetic Types of Granitoids in the Western Kunlun Orogenic Belt, China

A systematic geological and geochemical study was conducted for the granitoids of different periods in the western Kunlun erogenic belt. The study indicates that the granitoids belong to tholeiitic, calc-alkaline, high-K calc-alkaline, alkaline and shoshonitic series, and that there are 5 genetic types, i.e., I-, S-, M-, A- and SH-type, of which SH-type is first put forward in this paper, which corresponds to shoshonitic granitoids.