南海北部陆坡东沙海域海底丘状体气体与水合物分布

海底丘状体在天然气水合物发育区是一种常见的微地貌,对丘状体的研究有助于理解海底流体渗漏模式以及水合物的赋存规律。本文研究南海北部陆坡东沙海域天然气水合物发育区海底丘状体的特征及其与水合物的关系。研究所用的数据包括准三维多道地震数据、多波束数据以及浅地层剖面数据。在多波束海底地形图上,丘状体表现为局部的正地形,直径大约为300 m,高出周围海底约50 m。浅地层剖面上存在明显的声空白以及同相轴下拉现象,指示了海底丘状体气体的分布以及流体运移的路径。丘状体周围明显的BSR表明局部区域可能发育有水合物,水合物钻探结果也证实了这一推测。三维多道地震剖面上,丘状体正下方存在空白反射区域,这与泥火山的地震反射特征类似。但空白反射区域内存在强振幅能量,而且丘状体正下方存在连续的反射层,这表明该丘状体并非泥火山成因。综合钻探结果以及三维地震成像结果,认为水合物形成过程引起的沉积物膨胀以及海底碳酸盐岩的沉淀是形成该丘状体的主要原因。     

Distribution and expression of gas seeps in a gas hydrate province of the northeastern Sakhalin continental slope, Sea of Okhotsk

Multidisciplinary surveys were conducted to investigate gas seepage and gas hydrate accumulation on the northeastern Sakhalin continental slope (NESS), Sea of Okhotsk, during joint Korean–Russian–Japanese expeditions conducted from 2003 to 2007 (CHAOS and SSGH projects). One hundred sixty-one gas seeps were detected in a 2000 km² area of the NESS (between 53°45′N and 54°45′N). Active gas seeps in a gas hydrate province on the NESS were evident from features in the water column, on the seafloor, and in the subsurface: well-defined hydroacoustic anomalies (gas flares), side-scan sonar structures with high backscatter intensity (seepage structures), bathymetric structures (pockmarks and mounds), gas- and gas-hydrate-related seismic features (bottom-simulating reflectors, gas chimneys, high-amplitude reflectors, and acoustic blanking), high methane concentrations in seawater, and gas hydrates in sediment near the seafloor. These expressions were generally spatially related; a gas flare would be associated with a seepage structure (mound), below which a gas chimney was present. The spatial distribution of gas seeps on the NESS is controlled by four types of geological structures: faults, the shelf break, seafloor canyons, and submarine slides. Gas chimneys that produced enhanced reflection on high-resolution seismic profiles are interpreted as active pathways for upward gas migration to the seafloor. The chimneys and gas flares are good indicators of active seepage.     

Sediment mounds and other sedimentary features related to hydrate occurrences in a columnar seismic blanking zone of the Ulleung Basin, East Sea, Korea

A mound related to a cold vent in a columnar seismic blanking zone (CSBZ) was formed around site UBGH1-10 in the central Ulleung Basin (2077 m water depth), East Sea, Korea. The mound is 300–400 m wide and 2–3 m high according to multi-beam bathymetry, 2–7 kHz sub-bottom profiler data, and multi-channel reflection seismic data. Seafloor topography and characteristics were investigated using a remotely operated vehicle (ROV) around site UBGH1-10, which is located near the northern part of the mound. The origin of the mound was investigated through lithology, mineralogy, hydrate occurrence, and sedimentary features using dive cores, piston cores, and a deep-drilling core. The CSBZ extends to ∼265 ms two-way traveltime (TWT) below the seafloor within a mass-transport deposit (MTD) unit. Gas hydrate was entirely contained 6–141 m below the seafloor (mbsf) within hemipelagic deposits intercalated with a fine-grained turbidite (HTD) unit, characteristically associated with high resistivity values at site UBGH1-10. The hydrate is commonly characterized by veins, nodules, and massive types, and is found within muddy sediments as a fracture-filling type. Methane has been produced by microbial reduction of CO₂, as indicated by C₁/C₂₊, δ¹³CCH4, and δD₄CH analyses. The bowl-shaped hydrate cap revealed at 20–45 ms TWT below the seafloor has very high resistivity and high salinity, suggesting rapid and recent gas hydrate formation. The origin of the sediment mound is interpreted as a topographic high formed by the expansion associated with the formation of the gas hydrate cap above the CSBZ. The lower sedimentation rate of the mound sediments may be due to local enhancement of bottom currents by topographic effects. In addition, no evidence of gas bubbles, chemosynthetic communities, or bacterial mats was observed in the mound, suggesting an inactive cold vent.     

Seabed morphology and gas venting features in the continental slope region of Krishna–Godavari basin,Bay of Bengal: Implications in gas-hydrate exploration

Increased oil and gas exploration activity has led to a detailed investigation of the continental shelf and adjacent slope regions of Mahanadi, Krishna–Godavari (KG) and Cauvery basins, which are promising petroliferous basins along the eastern continental margin of India. In this paper, we analyze the high resolution sparker, subbottom profiler and multibeam data in KG offshore basin to understand the shallow structures and shallow deposits for gas hydrate exploration. We identified and mapped prominent positive topographic features in the bathymetry data. These mounds show fluid/gas migration features such as acoustic voids, acoustic chimneys, and acoustic turbid layers. It is interesting to note that drilling/coring onboard JOIDES in the vicinity of the mounds show the presence of thick accumulation of subsurface gas hydrate. Further, geological and geochemical study of long sediment cores collected onboard Marion Dufresne in the vicinity of the mounds and sedimentary ridges shows the imprints of paleo-expulsion of methane and sulfidic fluid from the seafloor.     

Experimental formation of massive hydrate deposits from accumulation of CH4 gas bubbles within synthetic and natural sediments

In order for methane to be economically produced from the seafloor, prediction and detection of massive hydrate deposits will be necessary. In many cases, hydrate samples recovered from seafloor sediments appear as veins or nodules, suggesting that there are strong geologic controls on where hydrate is likely to accumulate. Experiments have been conducted examining massive hydrate accumulation from methane gas bubbles within natural and synthetic sediments in a large volume pressure vessel through temperature and pressure data, as well as visual observations. Observations of hydrate growth suggest that accumulation of gas bubbles within void spaces and at sediment interfaces likely results in the formation of massive hydrate deposits. Methane hydrate was first observed as a thin film forming at the gas/water interface of methane bubbles trapped within sediment void spaces. As bubbles accumulated, massive hydrate growth occurred. These experiments suggest that in systems containing free methane gas, bubble pathways and accumulation points likely control the location and habit of massive hydrate deposits.     

Seismic expression of gas and gas hydrates across the western Black Sea

This study is a synthesis of gas-related features in recent sediments across the western Black Sea basin. The investigation is based on an extensive seismic dataset, and integrates published information from previous local studies. Our data reveal widespread occurrences of seismic facies indicating free gas in sediments and gas escape in the water column. The presence of gas hydrates is inferred from bottom-simulating reflections (BSRs). The distribution of the gas facies shows (1) major gas accumulations close to the seafloor in the coastal area and along the shelfbreak, (2) ubiquitous gas migration from the deeper subsurface on the shelf and (3) gas hydrate occurrences on the lower slope (below 750 m water depth). The coastal and shelfbreak shallow gas areas correspond to the highstand and lowstand depocentres, respectively. Gas in these areas most likely results from in situ degradation of biogenic methane, probably with a contribution of deep gas in the shelfbreak accumulation. On the western shelf, vertical gas migration appears to originate from a source of Eocene age or older and, in some cases, it is clearly related to known deep oil and gas fields. Gas release at the seafloor is abundant at water depths shallower than 725 m, which corresponds to the minimum theoretical depth for methane hydrate stability, but occurs only exceptionally at water depths where hydrates can form. As such, gas entering the hydrate stability field appears to form hydrates, acting as a buffer for gas migration towards the seafloor and subsequent escape.     

Origin of pockmarks and chimney structures on the flanks of the Storegga Slide,offshore Norway

Seafloor pockmarks and subsurface chimney structures are common on the Norwegian continental margin north of the Storegga Slide scar. Such features are generally inferred to be associated with fluid expulsion, and imply overpressures in the subsurface. Six long gravity and piston cores taken from the interior of three pockmarks were compared with four other cores taken from the same area but outside the pockmarks, in order to elucidate the origins and stratigraphy of these features and their possible association with the Storegga Slide event. Sulfate gradients in cores from within pockmarks are less steep than those in cores from outside the pockmarks, which indicates that the flux of methane to the seafloor is presently smaller within the pockmarks than in the adjacent undisturbed sediments. This suggests that these subsurface chimneys are not fluid flow conduits lined with gas hydrate. Methane-derived authigenic carbonates and Bathymodiolus shells obtained from a pockmark at >6.3 m below the seafloor indicate that methane was previously available to support a chemosynthetic community within the pockmark. AMS ¹⁴C measurements of planktonic Foraminifera overlying and interlayered with the shell-bearing sediment indicate that methane was present on the seafloor within the pockmark prior to 14 ka ¹⁴C years b.p., i.e., well before the last major Storegga Slide event (7.2 ka ¹⁴C years b.p., or 8.2 ka calendar years b.p.). These observations provide evidence that overpressured fluids existed within the continental margin sediments off Norway during the last major advance of Pleistocene glaciation.     

Asphalt mounds and associated biota on the Angolan margin

Release of hydrocarbons from sediments is important in increasing habitat heterogeneity on deep ocean margins. Heterogeneity arises from variation in abiotic and biotic conditions, including changes in substratum, geochemistry, fluid flow, biological communities and ecological interactions. The seepage of heavy hydrocarbons to the seafloor is less well studied than most other cold seep systems and may lead to the formation of asphalt mounds. These have been described from several regions, particularly the Gulf of Mexico. Here, we describe the structure, potential formation and biology of a large asphalt mound province in Block 31SE Angola. A total of 2254 distinct mound features was identified by side-scan sonar, covering a total area of 3.7 km² of seafloor. The asphalt mounds took a number of forms from small (<0.5 m diameter; 13% observations) mounds to large extensive (<50 m diameter) structures. Some of the observed mounds were associated with authigenic carbonate and active seepage (living chemosynthetic fauna present in addition to the asphalt). The asphalt mounds are seabed accumulations of heavy hydrocarbons formed from subsurface migration and fractionation of reservoir hydrocarbons primarily through a network of faults. In Angola these processes are controlled by subsurface movement of salt structures. The asphalt mounds were typically densely covered with epifauna (74.5% of mounds imaged had visible epifauna) although individual mounds varied considerably in epifaunal coverage. Of the 49 non-chemosynthetic megafaunal taxa observed, 19 taxa were only found on hard substrata (including asphalt mounds), 2 fish species inhabited the asphalt mounds preferentially and 27 taxa were apparently normal soft-sediment fauna. Antipatharians (3.6±2.3% s.e.) and poriferans (2.6±1.9% s.e.) accounted for the highest mean percentage of the observed cover, with actinarians (0.9±0.4% s.e.) and alcyonaceans (0.4±0.2% s.e.) covering smaller proportions of the area. Asphalt mounds represent a common and important habitat on several margin systems globally and should be recognised in future environmental assessment and management of these areas.     

Spatial distribution of seafloor bio-geological and geochemical processes as proxies of fluid flux regime and evolution of a carbonate/hydrates mound,northern Gulf of Mexico

Woolsey Mound, a carbonate/hydrate complex of cold seeps, vents, and seafloor pockmarks in Mississippi Canyon Block 118, is the site of the Gulf of Mexico Hydrates Research Consortium’s (GOMHRC) multi-sensor, multi-disciplinary, permanent seafloor observatory. In preparation for installing the observatory, the site has been studied through geophysical, biological, geological, and geochemical surveys. By integrating high-resolution, swath bathymetry, acoustic imagery, seafloor video, and shallow geological samples in a morpho-bio-geological model, we have identified a complex mound structure consisting of three main crater complexes: southeast, northwest, and southwest. Each crater complex is associated with a distinct fault. The crater complexes exhibit differences in morphology, bathymetric relief, exposed hydrates, fluid venting, sediment accumulation rates, sediment diagenesis, and biological community patterns. Spatial distribution of these attributes suggests that the complexes represent three different fluid flux regimes: the southeast complex seems to be an extinct or quiescent vent; the northwest complex exhibits young, vigorous activity; and the southwest complex is a mature, fully open vent. Geochemical evidence from pore-water gradients corroborates this model suggesting that upward fluid flux waxes and wanes over time and that microbial activity is sensitive to such change. Sulfate and methane concentrations show that microbial activity is patchy in distribution and is typically higher within the northwest and southwest complexes, but is diminished significantly over the southeast complex. Biological community composition corroborates the presence of distinct conditions at the three crater complexes. The fact that three different fluid flux regimes coexist within a single mound complex confirms the dynamic nature of the plumbing system that discharges gases into bottom water. Furthermore, the spatial distribution of bio-geological processes appears to be a valid indicator of multiple fluid flux regimes that coexist at the mound.     

Pockmarks and seafloor instability in the Olbia continental slope (northeastern Sardinian margin, Tyrrhenian Sea)

The seafloor morphology and the subsurface of the continental slope of the Olbia intraslope basin located along the eastern, passive Sardinian margin (Tyrrhenian Sea) has been mapped through the interpretation of high-resolution multibeam bathymetric data, coupled with air-gun and sparker seismic profiles. Two areas, corresponding to different physiographic domains, have been recognized along the Olbia continental slope. The upper slope domain, extending from 500 to 850 m water depth, exhibits a series of conical depressions, interpreted as pockmarks that are particularly frequent in seafloor sectors coincident with buried slope channels. In one case, they are aligned along a linear gully most likely reflecting the course of one of the abandoned channels. The location of the pockmarks thus highlights the importance of the distribution of lithologies within different sedimentary bodies in the subsurface in controlling fluid migration plumbing systems. A linear train of pockmarks is, however, present also away from the buried channels being related to a basement step, linked to a blind fault. Two bathymetric highs, interpreted as possible carbonate mounds, are found in connection with some of the pockmark fields. Although the genetic linkage of the carbonate mounds with seafloor fluid venting cannot be definitively substantiated by the lack of in situ measurements, the possibility of a close relationship is here proposed. The lower slope domain, from 850 m down to the base of the slope at 1,200 m water depth is characterized by a sudden gradient increase (from 2° to 6°) that is driven by the presence of the basin master fault that separates the continental slope from the basin plain. Here, a series of km-wide headwall scars due to mass wasting processes are evident. The landslides are characterized by rotated, relatively undeformed seismic strata, which sometimes evolve upslope into shallow-seated (less than 10 m), smaller scale failures and into headless chutes. Slope gradient may act as a major controlling factor on the seafloor instability along the Olbia continental slope; however, the association of landslides with pockmarks has been recognized in several continental slopes worldwide, thus the role of over-pressured fluids in triggering sediment failure in the Olbia slope can not be discarded. In the absence of direct ground truthing, the geological processes linked to subsurface structures and their seafloor expressions have been inferred through the comparison with similar settings where the interpretation of seafloor features from multibeam data has been substantiated with seafloor sampling and geochemical data.     

Multi-beam and seismic investigations of the active Haima cold seeps,northwestern South China Sea

To confirm the seabed fluid flow at the Haima cold seeps, an integrated study of multi-beam and seismic data reveals the morphology and fate of four bubble plumes and investigates the detailed subsurface structure of the active seepage area. The shapes of bubble plumes are not constant and influenced by the northeastward bottom currents, but the water depth where these bubble plumes disappear (630–650 m below the sea level) (mbsl) is very close to the upper limit of the gas hydrate stability zone in the water column (620 m below the sea level), as calculated from the CTD data within the study area, supporting the “hydrate skin” hypothesis. Gas chimneys directly below the bottom simulating reflectors, found at most sites, are speculated as essential pathways for both thermogenic gas and biogenic gas migrating from deep formations to the gas hydrate stability zone. The fracture network on the top of the basement uplift may be heavily gas-charged, which accounts for the chimney with several kilometers in diameter (beneath Plumes B and C). The much smaller gas chimney (beneath Plume D) may stem from gas saturated localized strong permeability zone. High-resolution seismic profiles reveal pipe-like structures, characterized by stacked localized amplitude anomalies, just beneath all the plumes, which act as the fluid conduits conveying gas from the gas hydrate-bearing sediments to the seafloor, feeding the gas plumes. The differences between these pipe-like structures indicate the dynamic process of gas seepage, which may be controlled by the build-up and dissipation of pore pressure. The 3D seismic data show high saturated gas hydrates with high RMS amplitude tend to cluster on the periphery of the gas chimney. Understanding the fluid migration and hydrate accumulation pattern of the Haima cold seeps can aid in the further exploration and study on the dynamic gas hydrate system in the South China Sea.     

The anatomy and provenance of thick volcaniclastic flows in the Cretan Basin, South Aegean Sea

Santorini volcano has been the largest source of volcaniclastic sediment in the Eastern Mediterranean during the late Quaternary. A dozen cores from the Cretan Basin, south of Santorini, have sampled two megabeds that consist of gravity emplaced volcaniclastic sequences. The uppermost megabed U consists of a succession of five (U₅–U₁) base cut out turbiditic units. Lower megabed A is a single turbiditic event. Only the uppermost U₂ and U₁ turbidites are separated from the underlying beds by hemipelagic marls. The texture and composition of the U and A megabeds closely match the texture and composition of the fine, vitric ash of the “Minoan” deposits on Santorini islands, dating from about 3500 yr BP. These megabeds are therefore attributed to rapid accumulation of separate gravity flows fed by the “Minoan” eruption, except for the upper U₂ and U₁ turbidites deposited from subsequent gravity flows transporting eroded volcaniclastic sediments. With the exception of the margin south of Santorini, dozens of cores retrieved around the margins of the Cretan Basin have a continuous late Quaternary succession that shows no evidence for massive sediment remobilization into the deeper basin, including the passage of the “Minoan” tsunami.

Extensive high-resolution 3.5 kHz records revealed the acoustic character, architecture and distribution of the U and A megabeds and four underlying late Quaternary volcanogenic megabeds in the Cretan Basin. The acoustic facies of megabeds are typical of megaturbidites and consist of an upper, transparent, lower velocity layer that corresponds to the fine-grained upper turbiditic silt and clay section and a lower, strongly reflective higher velocity section that corresponds to the lowest, coarser-grained base of the turbidite that is developed over a sharp erosional surface. Penetration of the high-resolution records reveals the existence of at least six megabeds. Correlation with core lithology and the physical properties of the various lithofacies, including down-core velocity profiles, has allowed us to determine the thickness and volumes of the upper four megabeds which are: U ≤ 9 m thick, volume 3.7 km³; A ≤ 25 m thick, volume 12.2 km³; B ≤ 22 m thick, volume 10.3 km³; C ≤ 15 m thick, volume 8 km³. These thick megabeds are the uppermost products of repeated explosive eruption of Santorini in the late Quaternary. Calculated sedimentation rates from and after the “Minoan” eruption are 9.4 m/1000 yr that rise to over 15.7 m/1000 yr if megabed B was also deposited during this eruption.     

Modeling of rising methane bubbles during production leaks from the gas hydrate sites of India

Natural gas hydrates is considered as a strategic unconventional clean hydrocarbon resource in the energy sector. Understanding the behavior of the rising methane gas bubbles during production leaks from the deep marine gas hydrate reservoirs well head is essential for environmental impact studies and to design environmental monitoring systems. Numerical model for quantitatively characterizing the vertical dissolution pattern of the wellhead released methane gas bubbles is analyzed for three potential gas hydrate locations in India. Simulation results indicate that the methane bubbles with diameter of 10?mm can transport methane gas till 650, 800, and 750?m from the seabed in the Krishna–Godavari(KG), Mahanadi and Andaman basins respectively. Results brought out that potential well head damage during methane hydrate production at 1050?m water depth could release up to 28?m³ of methane gas, in which 50% of the molar mass shall get dissolved within 40?m of water column from the seafloor.     

南海神狐海域天然气水合物饱和度的数值模拟分析

珠江口盆地神狐海域是天然气水合物钻探和试验开采的重点区域,大量钻探取心、测井与地震等综合分析表明不同站位水合物的饱和度、厚度与气源条件存在差异。本文利用天然气水合物调查及深水油气勘探所采集的测井和地震资料建立地质模型,利用PetroMod软件模拟地层的温度场、有机质成熟度、烃源岩生烃量、流体运移路径以及不同烃源岩影响下的水合物饱和度,结果表明:生物成因气分布在海底以下1500 m范围内的有机质未成熟地层,而热成因气分布在深度超过2300 m的成熟、过成熟地层。水合物稳定带内生烃量难以形成水合物,形成水合物气源主要来自于稳定带下方向上运移的生物与热成因气。模拟结果与测井结果对比分析表明,稳定带下部生物成因气能形成的水合物饱和度约为10%,在峡谷脊部的局部区域饱和度较高;相对高饱和度(>40%)水合物形成与文昌组、恩平组的热成因气沿断裂、气烟囱等流体运移通道幕式释放密切相关,W19井形成较高饱和度水合物的甲烷气体中热成因气占比达80%,W17井热成因气占比为73%,而SH2井主要以生物成因为主,因此,不同站位甲烷气体来源占比不同。     

Gas migration through Opouawe Bank at the Hikurangi margin offshore New Zealand

This study presents 2D seismic reflection data, seismic velocity analysis, as well as geochemical and isotopic porewater compositions from Opouawe Bank on New Zealand’s Hikurangi subduction margin, providing evidence for essentially pure methane gas seepage. The combination of geochemical information and seismic reflection images is an effective way to investigate the nature of gas migration beneath the seafloor, and to distinguish between water advection and gas ascent. The maximum source depth of the methane that migrates to the seep sites on Opouawe Bank is 1,500–2,100 m below seafloor, generated by low-temperature degradation of organic matter via microbial CO₂ reduction. Seismic velocity analysis enabled identifying a zone of gas accumulation underneath the base of gas hydrate stability (BGHS) below the bank. Besides structurally controlled gas migration along conduits, gas migration also takes place along dipping strata across the BGHS. Gas migration on Opouawe Bank is influenced by anticlinal focusing and by several focusing levels within the gas hydrate stability zone.     

Salt Diapirs, Salt Brine Seeps, Pockmarks and Surficial Sediment Creep and Slides in the Canary Channel off NW Africa

Circular to elliptical mounds in the Canary Channel with reliefs of 75 to 375 m and diameters of 4 to 8 km partially surrounded by moats with reliefs of 25 to 75 m, were formed by piercement of the seafloor by Mesozoic evaporites. Several long gullies, < 1km wide, with abrupt terminations and pockmarks associated with these mounds were probably eroded by dense brine and hydrocarbon seeps. The salt brines that eroded the gullies were formed where salt diapirs intersect the seafloor, or in the subsurface by circulating ground water heated by igneous activity along the Canary Ridge. If the brines originated in the subsurface they reached the seafloor along faults. Displacement of the surficial sediments by sliding and creep is probably the result of the expulsion of hydrocarbons and/or vertical motion of the Mesozoic evaporites. Microtopographic features along or near the east flank of the Canary Ridge are the creation of uplift of the ridge, hydrothermal activity, mass wasting processes and turbidity currents.     

东沙群岛西南海区泥火山的地球物理特征

多道反射地震和CHIRP浅地层剖面显示在南海东沙群岛西南陆坡和白云凹陷东部陆坡之间的深水(600~1 000m)陆坡上矗立着一系列高出周围海底50~100m的丘形地质体,其内部地层发生褶皱,反射波呈现杂乱和空白,海底声波屏蔽严重。浅地层剖面还显示丘状构造带有气体羽状构造,从海底进入水体高达50m。海底沉积取样分析表明,这些海丘区的表层分布着生物成因的致密碳酸盐结核。可以推断东沙西南的丘形地质体就是泥火山带,并且可能是一个重要的水合物潜在区。东沙西南海区泥火山表现出构造挤压和带状分布的特点,不同于南海北部神狐和九龙甲烷礁已发现水合物区的非泥火山,也不同于全球其他典型被动大陆边缘的泥火山特征,其构造成因和水合物潜力有待进一步研究。     

Fault system and thermal regime in the vicinity of site NGHP-01-10, Krishna–Godavari basin, Bay of Bengal

Drilling/coring activities onboard JOIDES Resolution for hydrate resource estimation have confirmed gas hydrate in the continental slope of Krishna-Godavari (KG) basin, Bay of Bengal and the expedition recovered fracture filled gas hydrate at the site NGHP-01-10. In this paper we analyze high resolution multi-channel seismic (MCS), high resolution sparker (HRS), bathymetry, and sub-bottom profiler data in the vicinity of site NGHP-01-10 to understand the fault system and thermal regime. We interpreted the large-scale fault system (>5 km) predominantly oriented in NNW-SSE direction near NGHP-01-10 site, which plays an important role in gas hydrate formation and its distribution. The increase in interval velocity from the baseline velocity of 1600 m/s to 1750–1800 m/s within the gas hydrate stability zone (GHSZ) is considered as a proxy for the gas hydrate occurrence, whereas the drop in interval velocity to 1400 m/s suggest the presence of free gas below the GHSZ. The analysis of interval velocity suggests that the high concentration of gas hydrate occurs close to the large-scale fault system. We conclude that the gas hydrate concentration near site NGHP-01-10, and likely in the entire KG Basin, is controlled primarily by the faults and therefore has high spatial variability.We also estimated the heat flow and geothermal gradient (GTG) in the vicinity of NGHP-01-10 site using depth and temperature of the seafloor and the BSR. We observed an abnormal GTG increase from 38 °C/km to 45 °C/km at the top of the mound, which remarkably agrees with the measured temperature gradient at the mound (NGHP-01-10) and away from the mound (NGHP-01-03). We analyze various geological scenarios such as topography, salinity, thermal non-equilibrium of BSR and fluid/gas advection along the fault system to explain the observed increase in GTG. The geophysical data along with the coring results suggest that the fluid advection along the fault system is the primary mechanism that explains the increase in GTG. The approximate advective fluid flux estimated based on the thermal measurement is of the order of few tenths of mm/yr (0.37–0.6 mm/yr).     

A new coral reef province in the Gulf of Carpentaria, Australia: Colonisation, growth and submergence during the early Holocene

Multibeam sonar mapping, drill cores and underwater video data have confirmed the existence of a previously unknown coral reef province in the Gulf of Carpentaria, Australia. Seven reefs, comprised of coral limestone that support living corals have been mapped so far and as many as 50 other reefs may exist in the region. U/Th ages show that reef growth commenced shortly after limestone pedestals were submerged by rising sea level around 10.5 kyr BP, making them the oldest Holocene reefs known in Australia. Reef growth persisted for ~ 2.0 kyr but it had ceased at most locations by ~ 7.0 kyr BP. Measurements of reef growth rates (0.95 to 4 m kyr^− 1), indicate that the reefs were unable to keep pace with contemporaneous rapid sea level rise (> 10 m kyr^− 1), which is consistent with a “give up” reef growth history. Core samples from reef platforms demonstrate that Pleistocene limestone is exposed at depths of 27 and 30 m below present mean sea level. These depths represent regionally significant phases of reef growth during a prolonged sea level still stand. We conclude that the reefs are therefore mostly relict features, whose major phase of growth and development relates to an earlier, pre-Holocene sea level still stand.     

南海北部陆坡沉积物“Ba峰”及其天然气水合物分解指示意义

深海,特别是天然气水合物区的沉积物-孔隙水体系中,Ba循环受到孔隙水中的硫酸盐(SO24-)和甲烷(CH4)之间的氧化还原反应的强烈制约。沉积物中"Ba峰"的存在体现了SO2-4亏损的长时间累积效应,并与海平面变化制约下的天然气水合物分解有关。南海北部陆坡ODP1146站钻孔上部深度185m沉积物中发育了4个"Ba峰",其中发育于深度约58m的"Ba峰"(F3)与当前SO2-4-CH4反应界面(SMI)深度一致,推断其他3个"Ba峰"(F1、F2和F4)对应的SMI深度分别约为24m、46m和84m。"Ba峰"最大峰值与沉积物Cl通量减小和冰期-间冰期转换带的对应性表明:在冰期,海平面大幅度降低诱发的浅水区(如东沙群岛附近)天然气水合物的分解持续释放了低盐度、高浓度CH4流体,其中部分流体迁移至ODP1146站所在的陆坡区沉积物中,导致了间隙水中SO2-4的持续亏损和自生Ba的长时间累积,结果在冰期-间冰期转换阶段形成显著的"Ba峰";同时,部分逸散于大气中的CH4加快了冰期的结束。在距今约50万年的冰期-间冰期旋回制约下的海平面周期性变化过程中,南海北部浅水区天然气水合物分解释放的低盐度和高浓度CH4流体也间歇地迁移至深水陆坡沉积区,导致了多个"Ba峰"的形成和沉积埋藏。"Ba峰"可以用于评价历史时期南海北部陆坡天然气水合物分解释放甲烷通量的变化。