Ross ice shelf cavity circulation,residence time,and melting: Results from a model of oceanic chlorofluorocarbons

Despite their harmful effects in the upper atmosphere, anthropogenic chlorofluorocarbons dissolved in seawater are extremely useful for studying ocean circulation and ventilation, particularly in remote locations. Because they behave as a passive tracer in seawater, and their atmospheric concentrations are well-mixed, well-known, and have changed over time, they are ideal for gaining insight into the oceanographic characteristics of the isolated cavities found under Antarctic ice shelves, where direct observations are difficult to obtain. Here we present results from a modeling study of air–sea chlorofluorocarbon exchange and ocean circulation in the Ross Sea, Antarctica. We compare our model estimates of oceanic CFC-12 concentrations along an ice shelf edge transect to field data collected during three cruises spanning 16 yr. Our model produces chlorofluorocarbon concentrations that are quite similar to those measured in the field, both in magnitude and distribution, showing high values near the surface, decreasing with depth, and increasing over time. After validating modeled circulation and air–sea gas exchange through comparison of modeled temperature, salinity, and chlorofluorocarbons with field data, we estimate that the residence time of water in the Ross Ice Shelf cavity is approximately 2.2 yr and that basal melt rates for the ice shelf average 10 cm yr⁻¹. The model predicts a seasonal signature to basal melting, with highest melt rates in the spring and also the fall.     

OSL and radiocarbon dating of a core from the Bohai Sea in China and implication for Late Quaternary transgression pattern

The Bohai Sea is a semi-enclosed continental shelf sea in northern China. Three transgression layers have been identified from the Late Quaternary strata in the western Bohai Sea and the coastal regions, which provide critical information on Late Quaternary sea-level fluctuations and landscape development. The three transgression layers were previously assigned to Marine Isotope Stage (MIS) 1 (transgression 1, T1), MIS 3 (T2) and MIS 5 (T3), respectively, mainly based on ¹⁴C dating. However, this chronological framework aroused an enigma that the regional sea level in MIS 3 was even higher than that of MIS 5, conflicting with the context of global sea-level pattern. In order to clarify this issue, here quartz optically stimulated luminescence (OSL) dating (four samples) was used to constrain the T2 chronology of borehole TJC-1 from the western Bohai Sea. Radiocarbon samples (eight) of peaty sediments were also measured for reference and comparison. All the four OSL samples showed saturation ages of >80 ka, suggesting that the T2 layer should have formed at least in MIS 5, instead of in MIS 3. Radiocarbon ages in T2 should have been severely underestimated, with a saturation age range of 22–30 cal ka BP, similar to all the previous published radiocarbon ages. The renewed OSL chronological framework for Late Quaternary transgressions in the western Bohai Sea is in better compliance with the history of global sea-level change.     

AMS radiocarbon dating of pollen concentrates in a karstic lake system

In lake sediments where terrestrial macrofossils are rare or absent, AMS radiocarbon dating of pollen concentrates may represent an important alternative solution for developing a robust and high resolution chronology suitable for Bayesian modelling of age-depth relationships. Here we report an application of the heavy liquid density separation approach (Vandergoes and Prior, Radiocarbon 45:479–492, 2003) to Holocene lake sediments from karstic Lake Sidi Ali, Morocco. In common with many karstic lakes, a significant lake ¹⁴C reservoir effect of 450–900 yr is apparent, evidenced by paired dates on terrestrial macrofossils and either aquatic (ostracod) or bulk sediment samples. AMS dating of 23 pollen concentrates alongside laboratory standards (bituminous coal, anthracite, IAEA C5 wood) was undertaken. Concentrates were prepared using a series of sodium polytungstate (SPT) solutions of progressively decreasing density (1.9–1.15 g/cm³) accompanied by microscopic analysis of the resulting residues to allow quantification of the terrestrial pollen content. The best fractions (typically precipitating at 1.4–1.2 g/cm³) yielded dateable samples of 0.5–5 mg (from sediment samples of ∼15 g), with C content typically ∼50% by weight. Terrestrial pollen purity ranges from 29% to 88% (μ = 67%), reflecting the challenge of isolating pollen grains from common aquatic algae, e.g. Pediastrum and Botryococcus. A Poisson-process Bayesian depositional model incorporating radiocarbon (pollen and macrofossil) and ²¹⁰Pb/¹³⁷Cs data is employed. As all pollen samples incorporate some non-terrestrial organic matter, we assume an exponential outlier distribution treating each pollen concentrate datum as an old outlier and terminus post quem. This approach yields strong data-model agreement, and differences between the prior and posterior age distributions are furthermore consistent with theoretical offsets anticipated for the known reservoir ages and sample-specific terrestrial content. This application of the pollen concentrate dating approach reinforces the importance of microscopic inspection of the residues during the separation and sieving stages. Sample specific differences mean that the pollen concentrate preparation cannot be reduced to a simplistic “black box” protocol, and dating and subsequent age-model development must be supported by detailed analysis of the microfossil content of the sediments.     

Metal concentrations, fluxes, inventories and chronologies in sediments from Sepetiba and Ribeira Bays: A comparative study

Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from ²¹⁰Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y⁻¹ in the inner bay to 2.6 mm y⁻¹ close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y⁻¹ before the 1960s and 0.76 cm y⁻¹ since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m³ s⁻¹ to 160 m³ s⁻¹. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.     

Variability of dense water formation in the Ross Sea

This paper presents results from a model study of the interannual variability of high salinity shelf water (HSSW) properties in the Ross Sea. Salinity and potential temperature of HSSW formed in the western Ross Sea show oscillatory behaviour at periods of 5–6 and 9 years superimposed on long-term fluctuations. While the shorter oscillations are induced by wind variability, variability on the scale of decades appears to be related to air temperature fluctuations. At least part of the strong decrease of HSSW salinities deduced from observations for the period 1963–2000 is shown to be an aliasing artefact due to an undersampling of the periodic signal. While sea ice formation is responsible for the yearly salinity increase that triggers the formation of HSSW, interannual variability of net freezing rates hardly affects changes in the properties of the resulting water mass. Instead, results from model experiments indicate that the interannual variability of dense water characteristics is predominantly controlled by variations in the shelf inflow through a sub-surface salinity and a deep temperature signal. The origin of the variability of inflow characteristics to the Ross Sea continental shelf can be traced into the Amundsen and Bellingshausen Seas. The temperature anomalies are induced at the continental shelf break in the western Bellingshausen Sea by fluctuations of the meridional transport of circumpolar deep water with the eastern cell of the Ross Gyre. In the Amundsen Sea, upwelling due to a persistently cyclonic wind field carries the signal into the surface mixed layer, leading to fluctuations of the vertical heat flux, anomalies of brine release near the sea ice edge, and consequently to a sub-surface salinity anomaly. With the westward flowing coastal current, both the sub-surface salinity and deep temperature signals are advected onto the Ross Sea continental shelf. Convection carries the signal of salinity variability into the deep ocean, where it interacts with modified circumpolar deep water upwelled onto the continental shelf as the second source water mass of HSSW. Sea ice formation on the Ross Sea continental shelf thus drives the vertical propagation of the signal rather than determining the signal itself.     

Correcting for potential 222Rn loss in 210Pb dating of sediments from the South Adriatic Pit

Measurement of ²²⁶Ra activity concentrations is often used to estimate supported levels of ²¹⁰Pb for purposes of geochronology. However, the implicit assumption that supported ²¹⁰Pb and ²²⁶Ra are in secular radioactive equilibrium may not always be true because of the migration of an intermediate product, gaseous ²²²Rn. As a consequence, supported ²¹⁰Pb activity concentration might be lower than the measured ²²⁶Ra value, which was the case in a core collected from the South Adriatic Pit. Here we present a new approach to improve the determination of supported ²¹⁰Pb, which is based on correction of ²²⁶Ra activity concentrations using the average (²¹⁰Pb/²²⁶Ra) activity ratio in deeper sediment layers. Using this approach, sedimentation rates for the South Adriatic Pit with a constant rate of supply model and a constant initial concentration model were 0.054 g/cm²/a and 0.070 g/cm²/a, respectively.     

罗斯海海域大地水准面异常的成因研究

本文利用数值法求解瞬时地幔对流问题以模拟大地水准面异常.利用两个较新的 S 波速度异常层析模型SEMUCB WM1 和TX2019slab,将其转换为密度异常作为控制方程的浮力驱动项;采取的黏度结构模型中,上下地幔的黏度比为1∶50.为了研究地幔不同结构对罗斯海海域大地水准面异常的影响,分别提取上、下地幔的密度异常正/...     

Age determination for a Neolithic site in northeastern Qinghai-Tibetan Plateau using a combined luminescence and radiocarbon dating

The archaeological Shaliuheqiaodong site, located at the junction between the estuary of Shaliu River and the northeast bedrock terrace of Qinghai Lake, is one of the earliest Neolithic Age sites in the Qinghai-Tibetan Plateau (QTP), which is critical for understanding patterns of prehistoric human inhabitation in the high plateau extreme environments. There are only two published radiocarbon ages by far for chronological control. Recently, a new section (Gangcha section) was found, with abundant charcoals and fish bones well-preserved in the matrix of aeolian sediments, providing a good opportunity for a combined study of luminescence and radiocarbon dating. In the current study, we obtained three luminescence ages on aeolian sediment, six radiocarbon ages (three on charcoals and three on fish bones). Our results showed that the luminescence ages (average of 3.2 ± 0.2 ka) are in agreement with charcoal radiocarbon ages (3165–3273 cal a BP) where applicable, and that the lake reservoir effect age of radiocarbon dating was approximately 0.3–0.7 cal ka BP and an average of 0.4 cal ka BP at ∼3.2 cal ka BP (age difference between that of charcoals and fish bones). The prehistoric residence in Qinghai Lake area seemed to be sequenced from 15 ka BP to 3.1 ka BP, based on our data and previously published data altogether. The obvious baked vestiges on the bones of fish and animals, as well as a number of artifacts, indicate that naked carps had become a food resource for prehistoric people at least since 3.2 cal ka BP.     

Characterization of organic matter in marine sediments to estimate age offset of bulk radiocarbon dating

Radiocarbon dating of Arctic marine sediment is often challenging due to the low availability of calcareous fossils. Consequently, bulk organic matter dating has at times been used to establish sediment core chronologies. Yet, radiocarbon dates based on bulk organic matter often appear to deviate vastly from dates based on fossils, mainly caused by input of allochthounous carbon, including terrigenous organic matter. In this study, we aim to examine the link between the composition of the bulk organic matter and the age offsets between the bulk radiocarbon dates and those obtained from calcareous foraminiferal tests. All samples are taken from the marine sediment core AMD14-204C from offshore Upernavik (eastern Baffin Bay). The radiocarbon dates for bulk organic matter are on average ∼3000 years older than the radiocarbon dates based on foraminifera, but with changing age offsets throughout the record. To investigate the cause of this age offset and its variations over time, we applied core scanning, X-ray Fluorescence analysis, stable isotopes, organic pyrolysis and microscopic organic petrology to examine the distribution and characterization of the organic matter. The results show that the older organic matter includes clastic input of reworked sedimentary rocks potentially originating from West Greenland and/or the Canadian Arctic Archipelago. Changes in the input of contemporary marine algal produced organic matter versus both terrigenous input and reworked ancient organic matter appear to control the age offsets between the bulk and foraminifera dates. A low Hydrogen Index and low δ¹³C_org values together with a high Oxygen Index, indicative of high influence of terrigenous organic matter, seem to correspond to samples with the largest age offsets; 1000–2000 years greater than in other samples. To examine the cause of the variations in the age offsets, a new quantification of the autochthonous organic matter as a fraction of the TOC was calculated. This shows that samples with the largest age offsets contained the lowest fraction (as low as ∼12%) of autochthonous organic matter in the TOC.     

Recurrence pattern of Holocene earthquakes along the Dead Sea transform revealed by varve-counting and radiocarbon dating of lacustrine sediments

A high-resolution Holocene seismic history of the Dead Sea Transform (DST) is established from laminated sedimentary cores recovered at the shores of the Dead Sea. Radiocarbon dating and annual laminae counting yield excellent agreement between disturbed sedimentary structures (identified as seismites) and the historical earthquake record: All recent and historical strong events of the area were identified, including the major earthquakes of A.D. 1927, 1837, 1212, 1033, 749, and 31 B.C. The total of 53 seismites recognized along the entire Holocene profile indicate varying recurrence intervals of seismic activity between a few and 1000 years, with a conspicuous minimum rate at 2100-31 B.C. and a noticeable maximum during the past six to eight centuries. Most of the epicenters of the correlated earthquakes are situated very close to the Dead Sea (within 150 km) or up to 400 km north of it along the DST. Between 1000 B.C. and A.D. 1063, and from A.D. 1600 to recent time the epicenters are all located on the northern segment of the DST, whereas prior to 1000 B.C. and between A.D. 1000 and 1600 they appear to scatter along several segments of the DST. We establish how the local intensity exerts a control on the formation of seismites. At historically estimated intensities greater than VII, all well documented earthquakes are correlated, whereas at intensities smaller than VI none are matching.The periods with enhanced earthquake rate along the DST correlate with those along the North Anatolian Fault as opposed to the intervening East Anatolian Fault. This may indicate some elastic coupling on plate-boundary scale that may also underlie escape and extrusion tectonics, typical of continental collision.     

Bacterial and organic matter distribution in the sediments of the Thracian Sea (NE Aegean Sea)

Recently, black carbon has been introduced as the form of carbon that may be separated from the biologically mediated carbon cycle thereby representing the non-bioavailable fraction of the estimated organic carbon. It has been speculated that the bioavailability of organic matter may be a limiting factor for the presence of active bacteria within the sediments. In order to address this question, marine sediments were collected from the Thracian Sea (Eastern Mediterranean), a complex system impacted by riverine inputs and Black Sea water masses. In addition to counts of total bacteria, we estimated the fraction of active bacteria by using a destaining step to the DAPI staining method. Black carbon was also estimated following the thermal oxidation method in order to determine the fraction of the refractory organic matter. The fraction of black carbon to total organic carbon varied from 16% to 53% indicating that black carbon constitutes a significant pool of sedimentary organic carbon in the Thracian sea. A fraction ranging from 18% to 97% was scored as nucleoid containing cells. We did not record any significant differences in the fraction of nucleoid-containing bacteria among sediment depths (P<0.05) indicating that there was no accumulation of dead bacterial cells with depth. The same was observed for the fraction of black carbon and bioavailable organic carbon with sediment depth (P<0.05) indicating that benthic consumers are not the key regulators of the organic matter pool in these sediments but have a minor effect. A possible reason for these observations and for the uncoupling between the active bacterial fraction and the bioavailability of organic matter could be (i) the presence of refractory components in the estimated bioavailable organic matter and (ii) the hydrological and geological complexity of the study area. The North Aegean marginal slopes are highly unstable experiencing frequent seismic events. These events are capable of inducing sediment transport from the upper slopes thus altering the entire sediment profile. On the other hand, the significant correlations that were recorded between nucleoid-containing cells and phytopigments (chlorophyll a, phaeopigments, chloroplastic pigment equivalents) at all sediment depths indicate that bacterial communities respond immediately to the deposited phytodetritus, using it as a primary source of carbon and energy. Our data suggests that the Thracian Sea sediments are by no means homogeneous and can best be described as a mosaic controlled by numerous local and regional environmental factors.     

Optical dating of young tidal sediments in the Danish Wadden Sea

We have tested the applicability of optically stimulated luminescence (OSL) to the dating of young estuarine sediments (<1000 years) to determine whether this method can be used to complement and support existing techniques, such as ²¹⁰Pb dating. The degree of bleaching before deposition is investigated by examining the age trend in various sediment cores, and where possible, by comparison with independent age control provided by ²¹⁰Pb dating. The consistency between optical ages and ²¹⁰Pb ages is shown to be satisfactory on a time-scale down to only a few years.

We conclude that OSL provides reliable and reproducible results in cores from sub-, inter- and supra-tidal sediments, ranging from only a few years up to 1000 years old, confirming its value in the estimation of estuarine accretion rates. With OSL it is, for the first time, possible to date sediment cores from silty and sandy tidal flats, providing a new approach to the problem of evaluation of stability and calculation of sediment budgets for estuaries and coastal lagoons.     

Luminescence dating of marine sediments from the Sea of Japan using quartz OSL and polymineral pIRIR signals of fine grains

Luminescence dating has long been used for chronological constraints on marine sediments due to the ubiquitous dating materials (quartz and feldspar grains) and its applicability over a relatively long time range. However, one of the main difficulties in luminescence dating on marine sediments is partial bleaching, which causes age overestimations. Especially, partial bleaching is typically difficult to be detected in the fine grain fraction (FG) of marine sediments. The recently developed feldspar post-IR IRSL (pIRIR) protocol can detect non-fading signals and thus avoid feldspar signal instability. In the current study, fine grains were extracted from a gravity core in the northern Sea of Japan, and the aim is to test the feasibility of using different luminescence signals with various bleaching rates to explore the bleaching conditions of fine grain fraction in marine sediments. The results suggest that the quartz OSL signal and polymineral pIRIR signals at stimulation temperatures of 150 °C and 225 °C (pIRIR₁₅₀ and pIRIR₂₂₅) of FG were well bleached prior to deposition. The OSL ages were used to establish a chronology for this sedimentary core and the resulting age-depth relationship is self-consistent and comparable with radiocarbon dates. We conclude that different luminescence signals with various bleaching rates can be used to test the bleaching conditions of fine grain fraction in marine sediments; and the luminescence dating can be applied to marine sediments with great potential.     

Annual and spatial variations of chemical and physical properties in the Ross Sea surface waters (Antarctica)

Temperature, salinity, meltwater percentage, water column stability, dissolved oxygen and nutrients were measured in seawater samples collected at three fixed depths (0, 20, 100 m) in 104 stations located in three different areas of the Ross Sea (Antarctica), during four Italian Antarctic surveys carried out between 1998 and 2006. Nutrient data were used to quantify the nutrient removal, which appears particularly high in 2006, especially in polynya area. The N:P and Si:N disappearance ratios were studied to estimate the dominant phytoplanktonic community. No significant differences in the nutrient drawdown ratio were observed, in fact the N:P ratio was always below the Redfield standard ratio.     

Sponges and sediments as monitoring tools of metal contamination in the eastern coast of the Red Sea, Saudi Arabia

Sediments and sponges were collected from various locations along the eastern coast of the Red Sea, the Kingdom of Saudi Arabia. Total concentrations of Cd, Zn, Ag, Cu, Pb, As and Hg in the sediments were measured. Metal contamination was not significant in most of the studied sites and only one site was moderately polluted by Zn, Cu, and Pb. Sponges accumulated specific metals readily even though the metal exposure was low in the ambient environment. Contrasting interspecies differences in metal accumulation patterns were observed among the nine collected species of sponges. Significant positive correlations were found between the metal concentrations in the two species of sponges collected from the same sites. The strong ability to accumulate specific metals and the diversity of sponges that live in the Red Sea coastal areas make them a promising biomonitor of metal contamination in the areas.     

Optically stimulated luminescence dating of single and multiple grains of quartz from perennially frozen loess in western Yukon Territory, Canada: Comparison with radiocarbon chronologies for the late Pleistocene Dawson tephra

Optically stimulated luminescence (OSL) dating of perennially frozen loess was tested on quartz grains extracted from deposits associated with the late Pleistocene Dawson tephra in western Yukon Territory, Canada. OSL samples were obtained from ice-rich loess bracketing the Dawson tephra, while radiocarbon (¹⁴C) samples were collected from the bulk sediments directly underlying the tephra and from a ground-squirrel burrow 2.7 m below the tephra. Here we report the OSL characteristics and ages of the extracted quartz grains, as well as additional radiocarbon ages for samples described in Froese [2002. Age and significance of the late Pleistocene Dawson tephra in eastern Beringia. Quaternary Science Reviews 21, 2137–2142; 2006. Seasonality of the late Pleistocene Dawson tephra and exceptional preservation of a buried riparian surface in central Yukon Territory, Canada. Quaternary Science Reviews 25, 1542–1551]. We refine the time of Dawson tephra deposition to between 25,420±70 and 25,290±80 ¹⁴C a BP. Bayesian analysis of constraining radiocarbon ages places the deposition of the Dawson tephra at between 30,433 and 30,032 cal a BP. Linear modulation (LM) OSL analysis of multi-grain aliquots of quartz showed that the initial part of the decay curve is dominated by a rapidly bleached (‘fast’) component; these samples, however, had relatively dim continuous wave (CW) OSL signals at the multi-grain aliquot (each composed of 80 grains) and single-grain scales of analysis. The single-aliquot regenerative-dose protocol was applied to multi-grain aliquots and single grains to obtain equivalent dose (D_e) values for samples collected from below and above the Dawson tephra. The D_e values were examined graphically and numerically, the latter using the central age, minimum age, and finite mixture models. For multi-grain aliquots, the central age model gave weighted mean D_e values between 30 and 50 Gy, which greatly underestimated the expected D_e of 74–81 Gy for both samples studied. Possible reasons for these underestimations are discussed, and a solution proposed based on single-grain analysis. Measurements of single grains produced D_e values in agreement with the expected D_e, and yielded OSL ages of 28±5 and 30±4 ka for the samples taken from above and below the Dawson tephra, respectively. Examination of individual grains with differing luminescence behaviors showed that a significant number of the measured quartz grains exhibited anomalous luminescence properties that would have compromised the results obtained from multi-grain aliquots. We therefore recommend analysis of individual grains to overcome the age-shortfall from multi-grain analysis of these and similar samples of quartz.     

南海北部海底沉积物在温度变化下的三种声速类型

研究南海北部海底沉积物温度变化状态下声速性质,得出以下结论:(1) 南海北部海底沉积物具有声速温度正增长(STPIK)、声速温度负增长(STNIK)和声速温度波动(STWK)三种类型,后两种类型在世界其他范围内海域未见报道.(2) 声速温度正增长类型和声速温度负增长类型沉积物的温度变化对声速影响都具有十分显著的线性关系,但是原状样品由于组成不均匀性,增大了声速的非线性变化.(3)南海北部海底沉积物的孔隙度、密度等主要物理参数差异不明显,难以直接解释三类样品的温度-声速性质的不同.(4)对于STPIK类型沉积物,理论分析与实验结果的统一性,可以运用海底沉积物与海水声速比进行校正不同温度状态下的海底沉积物的声速.(5)对于STNIK和STWK类型沉积物,需要深入研究,从理论和实验角度揭开其机理和成因.海底沉积物声速-温度特性研究将为提高南海北部海域天然气水合物声学探测精度和准确度提供声速性质依据.     

Assessing metal toxicity in sediments using the equilibrium partitioning model and empirical sediment quality guidelines: A case study in the nearshore zone of the Bohai Sea,China

Surface sediments were collected from five nearshore (wastewater discharges, aquaculture facilities and a seaport) sites in Bohai Bay and Laizhou Bay, China. The equilibrium partitioning (EqP) model and empirical sediment quality guidelines (SQGs) were applied to assess the potential metal toxicity in the collected sediments. The results show that, based on the EqP model, 35% of stations exhibited potential metal toxicity. Several metals (Cu, Ni and Cr) exceeded the empirical SQGs (9–93% of the time), however these guidelines may not be suitable for use in the Bohai Sea owing to the background concentrations. The EqP model is a more useful method for assessing potential metal toxicity in Bohai Sea sediment than the empirical SQGs. Additionally, we have provided new understanding about methods for assessing sediment metal toxicity in the Bohai Sea that may be useful in other coastal areas in China.     

Thermally re-distributed IRSL (RD-IRSL): A new possibility of dating sediments near B/M boundary

This study attempted to probe a geologically more stable IR stimulated luminescence signal (IRSL) that explored so far. IRSL, probes the proximal pairs and, pIRSL measurements at elevated temperatures consume more distant pairs. We surmised that the residual IRSL after pIR-IRSL should arise from most distant pairs and hence should be more stable. A thermal stimulation after pIR-IRSL leads to redistribution of charges including distant pairs and this can be probed by further IRSL and pIRSL (post IR IRSL) measurements. This post IRSL following a thermal treatment is termed as redistributed IRSLs (RD IRSL and RD pIRSL) and contributes about 10% of total IRSL counts from a pristine sample. As expected RD, IRSLs are poor to be solar bleachable. Burial age of around 800 ka(with 30–40 %) using RD-IRSL and RD-pIRSL were comparable with the palaeomagnetic dating and were a factor of three higher than conventional pIR-IRSL, TRL, IR-RL and VSL ages.     

Timing of Holocene lake highstands around Dawa Co in inner Tibetan Plateau: Comparison of quartz and feldspar luminescence dating with radiocarbon age

Lakes over the inner Tibetan Plateau (TP) are very sensitive to the regional environmental transformations and climate changes. Well-preserved lake sediments around these lakes provide critical geomorphological and sedimentary evidence that can be used to infer the past hydroclimate changes. In this study, a lacustrine section from a sandy shoreline (∼74 m above the modern lake) situated to the northwest of modern Dawa Co in the inner TP was investigated using both luminescence and radiocarbon dating methods. Our results demonstrated: (1) the quartz optically simulated luminescence (OSL) dating yielded much younger ages (∼4 ka) than that of the post-infrared IRSL (pIRIR) dating of the K-feldspar fraction; (2) fading test showed g-values ranging between 1.34 and 4.46%/decade for quartz OSL signals, which is considered to be responsible for the underestimation of the corresponding ages; (3) the AMS ¹⁴C age of the charcoal sample from the section is in line with the K-feldspar pIRIR₂₂₅ ages, confirming the reliability of the pIRIR₂₂₅ dates and the underestimation of the quartz OSL ages. The anomalous fading of quartz OSL signals and the consequent age underestimation have been reported in several other lakes on the TP, we presented here for the first time firm evidence of the phenomenon with the help of a robust independent control of AMS ¹⁴C age of the charcoal. Based on the pIRIR₂₂₅ and AMS ¹⁴C ages, we conclude that Dawa Co underwent a prominent highstand during the early Holocene (∼9–7 ka), which was probably controlled by the large amounts of glacial meltwater input and the increased monsoonal precipitation.