Societal phosphorus metabolism in future coastal environments: Insights from recent trends in Louisiana,USA

Successful adaptation to global environmental change will require confronting multiple unfolding challenges in concert. Coastal regions vulnerable to sea level rise and tropical storms will likely also be influenced by resource limitation in an uncertain future. In this paper, we explore the interrelated dynamics of coastal population migration, economic instability, and anthropogenic phosphorus (P) flows. Accounting for P flows and improving human P use efficiency are critical tasks given the finite global supply of phosphate rock and widespread eutrophication. We use material flow analysis to examine societal P metabolism in the Upper Pontchartrain Basin in coastal Louisiana, USA for two 5-y time periods (2001–2005 and 2006–2010) to capture the effects of fertilizer economics and population growth partially driven by the impact of Hurricane Katrina in the lower basin in 2005. Mass balances encompass human-mediated P fluxes in food production and consumption subsystems across agricultural, developed, and forested landscapes. Drastic reductions in locally purchased inorganic P fertilizer (78% decline between periods) were correlated to increases in fertilizer prices. Total P input to the study region decreased from 5452 to 3268 Mg P y⁻¹ between periods. Changes in P flows were primarily driven by fertilizer economics, declining dairy production, and the influx of new residents, which has been characterized by decentralized settlement that limits P recycling. Societal P metabolic efficiency increased from 22% to 32% due largely to reduced fertilizer inputs. Leakage to the Pontchartrain Estuary and the Mississippi River represented 17–23% of total system P input, while the vast majority of P accumulated within soils, wastewater systems, and landfills. We discuss basin trends and management implications. A historic opportunity exists to encourage future coastal development characterized by synergies between local agriculture and human habitation to promote energy efficient nutrient recycling. The effect would be a decreased vulnerability to future fertilizer price spikes, along with the mitigation of current and future eutrophication.     

Globalisation of water resources: international virtual water flows in relation to crop trade

The water that is used in the production process of a commodity is called the ‘virtual water’ contained in the commodity. International trade of commodities brings along international flows of virtual water. The objective of this paper is to quantify the volumes of virtual water flows between nations in the period 1995–1999 insofar related to international crop trade and to analyse national virtual water balances in relation to national water needs and water availability. The basic approach is to multiply international crop trade flows (ton/yr) by their associated virtual water content (m³ ton⁻¹). The calculations show that the global volume of crop-related international virtual water flows between nations was 695 Gm³ yr⁻¹ in average over the period 1995–1999. For comparison: the total water use by crops in the world has been estimated at 5400 Gm³ yr⁻¹. This means that 13% of the water used for crop production in the world is not used for domestic consumption but for export (in virtual form). This is a conservative estimate because only a limited number of crops––although the most important ones––have been taken into account and because crop products (such as cotton clothes) have been excluded from the study. The countries with the largest net virtual water export are United States, Canada, Thailand, Argentina and India. The largest net import appears to be in Japan, the Netherlands, the Republic of Korea, China and Indonesia.     

Greenhouse gas mitigation in Chinese agriculture: Distinguishing technical and economic potentials

China is now the world's biggest annual emitter of greenhouse gases with 7467 million tons (Mt) carbon dioxide equivalent (CO₂e) in 2005, with agriculture accounting for 11% of this total. As elsewhere, agricultural emissions mitigation policy in China faces a range of challenges due to the biophysical complexity and heterogeneity of farming systems, as well as other socioeconomic barriers. Existing research has contributed to improving our understanding of the technical potential of mitigation measures in this sector (i.e. what works). But for policy purposes it is important to convert these measures into a feasible economic potential, which provides a perspective on whether agricultural emissions reduction (measures) are low cost relative to mitigation measures and overall potential offered by other sectors of the economy. We develop a bottom-up marginal abatement cost curve (MACC) representing the cost of mitigation measures applicable in addition to business-as-usual agricultural practices. The MACC results demonstrate that while the sector offers a maximum technical potential of 402 MtCO₂e in 2020, a reduction of 135 MtCO₂e is potentially available at zero or negative cost (i.e. a cost saving), and 176 MtCO₂e (approximately 44% of the total) can be abated at a cost below a threshold carbon price ≤¥ 100 (approximately €12) per tCO₂e. Our findings highlight the relative cost effectiveness of nitrogen fertilizer and manure best management practices, and animal breeding practices. We outline the assumptions underlying MACC construction and discuss some scientific, socioeconomic and institutional barriers to realizing the indicated levels of mitigation.     

Multi-gas emission envelopes to meet greenhouse gas concentration targets: Costs versus certainty of limiting temperature increase

This paper presents a set of technically feasible multi-gas emission pathways (envelopes) for stabilising greenhouse gas concentration at 450, 550 and 650 ppm CO₂-equivalent and their trade-offs between direct abatement costs and probabilities to meet temperature targets. There are different pathways within the envelope. Delayed response pathways initially follow the upper boundary of the emission envelope and reduce more by the end of the century. In contrast, early action pathways first follow the lower boundary and then the upper boundary. The latter require an early peak in the global emissions but keeps the option open for shifting to lower concentration targets in the future. Costs evaluations depend on the discount rate. Early action profiles have high costs early on, but learning-by-doing and smoother reduction rates over time lead to in most cases to lower costs across the century (net present value (NPV)). To achieve the 450 ppm CO₂-equivalent, the global emissions need to peak before 2020. The NPV of costs increase from 0.2% of cumulative gross domestic product to 1.0% as the shift is made from 650 to 450 ppm (discount rate 5%). However, the chances of limiting global mean warming to 2 °C above pre-industrial levels are very small for peaking and stabilisation at 650 ppm (1–23%) and 550 ppm (1–48%), but increase for a peaking at 510 ppm with subsequent stabilisation 450 ppm to 14–67%.     

Impacts of urban expansion on nitrogen and phosphorus flows in the food system of Beijing from 1978 to 2008

Rapid growth of metropolitan areas is associated with increased flows of nitrogen (N) and phosphorus (P) in the food production–consumption system. However, quantitative analyses of these flows during urban expansion and information about their controlling factors are scarce.Here, we report on N and P flows in the food system of Beijing, which experienced a remarkable growth in population number between especially 1978–2008, using a combination of statistical data bases, surveys and the NUFER model (nutrient flow in the food system, environment and resource). The N (or P) cost of food is defined as the amount of ‘new’ N (or P) used in food production for the delivery of 1 kg N (or P) in the food entering household. ‘New’ N (P) includes fertilizer N (P), biological N fixation, atmospheric N deposition, and imports of N (P) via feed and food. Recycled N (P) includes N (P) in crop residues, manures and wastes.We found that the rapid increase in temporary migrants greatly increased food imports to Beijing metropolitan areas and thereby led to an apparent decrease of the N and P cost of food. The input of ‘new’ N to the food system of Beijing metropolitan areas increased from 180 to 281 Gg, and for P from 33.5 to 50.4 Gg during 1978–2008, as a result of increases in population and changes in food consumption patterns per capita. The food and feed imports in per cent of total ‘new’ N and P inputs increased from 31 to 63% for N and from 18 to 46% for P during 1978–2008. The N and P cost of the food was relatively low compared to the mean of China, and decreased over time. About 52% of the new N input and 85% of the new P input was not recycled in 2008, it accumulated as wastes (in crop residues, animal excreta, and human excreta and household wastes). The N and P use efficiencies in crop and animal production were low, i.e., only 17% for N and 11% for P in 2008. Total losses of ammonia (NH₃) and nitrous oxide (N₂O) to air and of N to groundwater and surface waters increased by a factor of about 3, and losses of P to groundwater and surface waters increased by a factor of 37 in the period 1978–2008.Key measures for decreasing N and P accumulation and losses are (1) developing satellite towns, (2) expelling animal production to rural areas, and (3) effective collection of the wastes and animal manure, and the utilization of these in rural areas outside Beijing. These findings may also portend changes in other metropolitan areas in China and elsewhere in the rapidly developing world.     

Mixing states of cloud interstitial particles between water-soluble and insoluble materials at Mt. Tateyama,Japan: Effects of meteorological conditions

Mixing states of cloud interstitial particles between water-soluble and insoluble materials apparently differ under various cloud-forming conditions. To study the mixing states of cloud interstitial particles, we made observations at Mt. Tateyama, Japan (2300 m a.s.l.) during June 2007 using fog (> 10 μm)-cut inlets. Number concentrations of dried particles (0.3–0.5 μm diameter) selected for less-grown (LG) particles (particles smaller than 0.56 μm diameter at 88% relative humidity) were used to quantify tendencies of the growth characteristics of cloud interstitial particles. Size-segregated soot mass concentrations (< 0.4 and < 1.1 μm) were also measured for cloud interstitial particles. Three samples of cloud interstitial LG particles at 88% RH were investigated for water-soluble and insoluble components using dialysis (extraction) of water-soluble materials with transmission electron microscopy (TEM). For one TEM sample with high fractions of the LG particles and high soot mass concentrations under high precipitation (2–6 mm/h), most particles (0.1–0.5 μm) were found to be water insoluble. More than half of the water-insoluble particles were considered to be soot particles showing chain aggregations of electron-opaque spherules. Regarding the other two TEM samples with low fractions of the LG particles under less intense precipitation (ca. 1 mm/h), most particles were partly water soluble. The scavenging process in the precipitating cloud can change the population of particles left behind, preferentially leaving insoluble particles according to cloud formation conditions.     

Drivers,constraints and trade-offs associated with recultivating abandoned cropland in Russia,Ukraine and Kazakhstan

Further cropland expansion might be unavoidable to satisfy the growing demand for land-based products and ecosystem services. A crucial issue is thus to assess the trade-offs between social and ecological impacts and the benefits of converting additional land to cropland. In the former Soviet Union countries, where the transition from state-command to market-driven economies resulted in widespread agricultural land abandonment, cropland expansion may incur relatively low costs, especially compared with tropical regions.Our objectives were to quantify the drivers, constraints and trade-offs associated with recultivating abandoned cropland to assess the potentially available cropland in European Russia, western Siberia, Ukraine and Kazakhstan—the region where the vast majority of post-Soviet cropland abandonment took place. Using spatial panel regressions, we characterized the socio-economic determinants of cropland abandonment and recultivation. We then used recent maps of changes in cropland to (i) spatially characterize the socio-economic, accessibility and soil constraints associated with the recultivation of abandoned croplands and (ii) investigate the environmental trade-offs regarding carbon stocks and habitat for biodiversity.Less cropland abandonment and more recultivation after 2000 occurred in areas with an increasing rural population and a younger labor force, but also improved yields. Synergies were observed between cropland recultivation and intensification over the 2000s. From 47.3 million hectares (Mha) of cropland abandoned in 2009, we identified only 8.5 (7.1–17.4) Mha of potentially available cropland with low environmental trade-offs and low to moderate socio-economic or accessibility constraints that were located on high-quality soils (Chernozems). These areas represented an annual wheat production potential of ∼14.3 (9.6–19.5) million tons (Mt). Conversely, 8.5 (4.2–12.4) Mha had high carbon or biodiversity trade-offs, of which ∼10% might be attractive for cropland expansion and thus would require protection from recultivation. Agro-environmental, accessibility, and socio-economic constraints suggested that the remaining 30.6 (25.7–30.6) Mha of abandoned croplands were unlikely to provide important contributions to future crop production at current wheat prices but could provide various ecosystem services, and some could support extensive livestock production. Political and institutional support could foster recultivation by supporting investments in agriculture and rural demographic revitalization. Reclaiming potentially available cropland in the study region could provide a notable contribution to global grain production, with relatively low environmental trade-offs compared with tropical frontiers, but is not a panacea to address global issues of food security or reduce land-use pressure on tropical ecosystems.     

Mental models of sea-level change: A mixed methods analysis on the Severn Estuary,UK

Global average sea levels are expected to rise by up to a metre by the end of the century. This long-term rise will combine with shorter-term changes in sea level (e.g. high tides, storm surges) to increase risks of flooding and erosion in vulnerable coastal areas. As communities become increasingly exposed to these risks, understanding their beliefs and responses becomes more important. While studies have explored public responses to climate change, less research has focused on perceptions of the specific risks associated with sea-level change. This paper presents the results of a mental models study that addressed this knowledge gap by exploring expert and public perceptions of sea-level change on the Severn Estuary, a threatened coastal environment in the southwest of the United Kingdom. A model was developed from the literature and expert interviews (N = 11), and compared with public perceptions elicited via interviews (N = 20) and a quantitative survey (N = 359). Whilst we find a high degree of consistency between expert and public understandings, there are important differences that have implications for how sea level risks are interpreted and for what are perceived as appropriate mitigation and adaptation practices. We also find a number of potential barriers to engaging with the issue: individuals express low concern about sea-level change in relation to other matters; they feel detached from the issue, seeing it as something that will happen in future to other people; and many perceive that neither the causes of nor responses to sea-level change are their responsibility. We point to areas upon which future risk communications should therefore concentrate.     

Vertical profiles of aerosol black carbon in the atmospheric boundary layer over a tropical coastal station: Perturbations during an annular solar eclipse

Altitude profiles of aerosol black carbon (BC) in the atmospheric boundary layer (ABL) over a tropical coastal station, Trivandrum have been examined on two days using an aethalometer attached to a tethered balloon. One of these days (15th January, 2010) coincided with a (annular) solar eclipse, the longest of this century at this location, commenced at 11:05 local time and ended by 15:05, lasting for 7 min and 15 s (from 13:10:42), with its maximum contact occurring at ~ 13:14 IST with ~ 92% annularity, thereby providing an opportunity to understand the eclipse induced perturbations. Concurrent measurements of the ABL parameters such as air temperature, relative humidity and pressure were also made on these days to describe the response of the ABL to the eclipse. BC profiles, in general, depicted similar features up to an altitude of ~ 200 m on the eclipse day and control day, above which it differed conspicuously with profiles on eclipse day showing increasingly lower concentration as we moved to higher altitudes. Examination of the meteorological profiles showed that the altitude of maximum convection rapidly fell down during the eclipse period compared to that on control day indicating a rather shallow convection on eclipse day. Comparison of diurnal variations of BC at the surface level showed that the rate of decrease in BC during daytime on the eclipse day was smaller than that on the control day due to the reduced convection, shallow ABL and consequent reduction in the ventilation coefficient. Moreover the time of the nocturnal increase has advanced by ~ 1:30 h on the eclipse day, occurred at around 19:30 IST in contrast to all the other days of January 2010, where this increase usually occur well after 20:30 IST, with a mean value of 21:00 IST. This is attributed to the weak sea-breeze penetration during the eclipse day, which led to an early onset of the land breeze.     

Intraurban variability of PM10 and PM2.5 in an Eastern Mediterranean city

The results of the first large scale chemical characterization of PM10 and PM2.5 at three different sites in the urban city of Beirut, Lebanon, are presented. Between May 2009 and April 2010 a total of 304 PM10 and PM2.5 samples were collected by sampling every sixth day at three different sites in Beirut. Observed mass concentrations varied between 19.7 and 521.2 μg m^? 3 for PM10 and between 8.4 and 72.2 μg m^? 3 for PM2.5, respectively. Inorganic concentrations accounted for 29.7–35.6 μg m^? 3 and 46.0–53.5 μg m^? 3 of the total mass of PM10 and PM2.5, respectively. Intra-city temporal and spatial variations were assessed based on the study of three factors: correlation coefficients (R) for PM and chemical components, coefficient of divergence (CODs), and source apportionment using positive matrix factorization (PMF). Based on R and COD of PM concentrations, the three sites appear homogeneous. However, when individual elements were compared, heterogeneity among sites was found. This latter was attributed to the variability in the percent contribution of biogenic and local anthropogenic source factors such as traffic related sources and dust resuspension. Other factors included the proximity to the Mediterranean sea, the population density and the topographical structure of the city. Hence, despite its small size (20.8 km²), one PM monitoring site does not reflect an accurate PM level in Beirut.     

The 183-WSL fast rain rate retrieval algorithm: Part I: Retrieval design

The Water vapour Strong Lines at 183 GHz (183-WSL) fast retrieval method retrieves rain rates and classifies precipitation types for applications in nowcasting and weather monitoring. The retrieval scheme consists of two fast algorithms, over land and over ocean, that use the water vapour absorption lines at 183.31 GHz corresponding to the channels 3 (183.31 ± 1 GHz), 4 (183.31 ± 3 GHz) and 5 (183.31 ± 7 GHz) of the Advanced Microwave Sounding Unit module B (AMSU-B) and of the Microwave Humidity Sounder (MHS) flying on NOAA-15-18 and Metop-A satellite series, respectively.The method retrieves rain rates by exploiting the extinction of radiation due to rain drops following four subsequent steps. After ingesting the satellite data stream, the window channels at 89 and 150 GHz are used to compute scattering-based thresholds and the 183-WSLW module for rainfall area discrimination and precipitation type classification as stratiform or convective on the basis of the thresholds calculated for land/mixed and sea surfaces. The thresholds are based on the brightness temperature difference Δ_win = T_B89 ? T_B150 and are different over land (L) and over sea (S): cloud droplets and water vapour (Δ_win < 3 K L; Δ_win < 0 K S), stratiform rain (3 K < Δ_win < 10 K L; 0 K < Δ_win < 10 K S), and convective rain (Δ_win > 10 K L and S). The thresholds, initially empirically derived from observations, are corroborated by the simulations of the RTTOV radiative transfer model applied to 20000 ECMWF atmospheric profiles at midlatitudes and the use of data from the Nimrod radar network. A snow cover mask and a digital elevation model are used to eliminate false rain area attribution, especially over elevated terrain. A probability of detection logistic function is also applied in the transition region from no-rain to rain adjacent to the clouds to ensure continuity of the rainfall field. Finally, the last step is dedicated to the rain rate retrieval with the modules 183-WSLS (stratiform) and 183WSLC (convective), and the module 183-WSL for total rainfall intensity derivation.A comparison with rainfall retrievals from the Goddard Profiling (GPROF) TRMM 2A12 algorithm is done with good results on a stratiform and hurricane case studies. A comparison is also conducted with the MSG-based Precipitation Index (PI) and the Scattering Index (SI) for a convective-stratiform event showing good agreement with the 183-WSLC retrieval. A complete validation of the product is the subject of Part II of the paper.     

Distribution of inorganic nitrogen-containing species in atmospheric particles from an island in the Yellow Sea

In this study, total suspended particles (TSP) and size-segregated atmospheric aerosol samples were measured on Qianliyan Island in the Yellow Sea in spring (April–May), summer (July–August) and fall (October–November) of 2006 and in water (January–February) of 2007. The mass concentration of the TSP varied from 75.6 to 132.0 μg/m³. The average concentration were 9.37 ± 7.56 μg/m³ and 5.32 ± 4.25 μg/m³ for nitrate and ammonium in the TSP, respectively. TSP concentration showed a significant correlation with those of nitrate (n = 27, r = 0.73) and ammonium (n = 27, r = 0.60). The mass-size distribution of atmospheric particles exhibited two modes with an accumulation mode at 0.43–1.1 μm and a coarse mode at 3.3–4.7 μm throughout the sampling months. A bi-modal size distribution of nitrate in concentration occurred in the April–May, October–November and January–February, but a uni-modal size distribution occurred in the August. The uni-modal size distribution of ammonium at 0.43–0.65 μm was observed throughout the sampling months. The average of inorganic nitrogen in mass concentration accounted for 4.0% of the total mass of aerosol particles while ammonium-N was the dominant fraction of TIN (Total Inorganic Nitrogen), contributing to 62–71% of the TIN.     

Circulation analysis in the northwest Indian Ocean using ARGO floats and surface drifter observations,and SODA reanalysis output

This study incorporates observations from Array of Real-time Geostrophic Oceanography (ARGO) floats and surface drifters to identify seasonal circulation patterns at the surface, 1000 m, 1500 m, and 2000 m in the northwest Indian Ocean, and quantify velocities associated with them. A skill comparison of the Simple Ocean Data Assimilation (SODA) reanalysis output was also performed to contribute to the understanding of the circulation dynamics in this region.Subsurface currents were quantified and validated using the ARGO float data. Surface currents were identified using surface drifter data and compared to the subsurface observations to enhance our previous understanding of surface circulations. Quantified Southwest Monsoon surface currents include the Somali Current (v_max = 179.5 cm/s), the East Arabian Current (v_max = 52.3 cm/s), and the Southwest Monsoon Current (v_max = 51.2 cm/s). Northeastward flow along the Somali coast is also observed at 1000 m (v_max = 26.1 cm/s) and 1500 m (v_max = 12.7 cm/s). Currents associated with the Great Whirl are observed at the surface (v_max = 161.4 cm/s) and at 1000 m (v_max = 16.2 cm/s). In contrast to previous studies, both ARGO and surface drifter data show the Great Whirl can form as early as the boreal Spring intermonsoon, lasting until the boreal Fall intermonsoon. The Arabian Sea exhibits eastward/southeastward flow at the surface, 1000 m, 1500 m, and 2000 m. Quantified Northeast Monsoon surface currents include the Somali Current (v_max = 97.3 cm/s), Northeast Monsoon Current (v_max = 30.0 cm/s), and the North Equatorial Current (v_max = 28.5 cm/s). Southwestward flow along the Somali coast extends as deep as 1500 m.Point-by-point vector and scalar correlations of SODA output to ARGO and surface drifter data showed that surface SODA output and surface drifter data generally produced a strong correlation attributed to surface currents strongly controlled by the monsoons, while subsurface correlations of SODA output and ARGO were mostly insignificant due to variability associated with intermonsoonal transitions. SODA output produced overall smaller velocities than both observational datasets. Assimilating ARGO velocities into the SODA reanalysis could improve subsurface velocity assimilation, especially during the boreal fall and spring when ARGO observations suggest that flow is highly variable.     

Below-cloud rain scavenging of atmospheric aerosols for aerosol deposition models

Below-cloud aerosol scavenging is generally estimated from field measurements using advanced instruments that measure changes in aerosol distributions with respect to rainfall. In this study, we discuss various scavenging mechanisms and scavenging coefficients from past laboratory and field measurements. Scavenging coefficients derived from field measurements (representing natural aerosols scavenging) are two orders higher than that of theoretical ones for smaller particles (D_p < 2 μm). Measured size-resolved scavenging coefficients can be served as a better option to the default scavenging coefficient (e.g. a constant of 10^?4 s^?1 for all size of aerosols, as used in the CALPUFF model) for representing below-cloud aerosol scavenging. We propose scavenging correction parameter (C_R) as an exponential function of size-resolved scavenging coefficients, winds and width in the downwind of the source–receptor system. For a wind speed of 3 m s^?1, C_R decrease with the width in the downwind for particles of diameters D_p < 0.1 μm but C_R does not vary much for particles in the accumulation mode (0.1 < D_p < 2 μm). For a typical urban aerosol distribution, assuming 3 m s^?1 air-flow in the source–receptor system, 10 km downwind width, 2.84 mm h^?1 of rainfall and using aerosol size dependent scavenging coefficients in the C_R, scavenging of aerosols is found to be 16% in number and 24% in volume of total aerosols. Using the default scavenging coefficient (10^?4 s^?1) in the CALPUFF model, it is found to be 64% in both number and volume of total aerosols.     

Loop Current Eddy formation and baroclinic instability

The formation of three Loop Current Eddies, Ekman, Franklin, and Hadal, during the period April 2009 through November 2011 was observed by an array of moored current meters and bottom mounted pressure equipped inverted echo sounders. The array design, areal extent nominally 89° W to 85° W, 25° N to 27° N with 30–50 km mesoscale resolution, permits quantitative mapping of the regional circulation at all depths. During Loop Current Eddy detachment and formation events, a marked increase in deep eddy kinetic energy occurs coincident with the growth of a large-scale meander along the northern and eastern parts of the Loop Current. Deep eddies develop in a pattern where the deep fields were offset and leading upper meanders consistent with developing baroclinic instability. The interaction between the upper and deep fields is quantified by evaluating the mean eddy potential energy budget. Largest down-gradient heat fluxes are found along the eastern side of the Loop Current. Where strong, the horizontal down-gradient eddy heat flux (baroclinic conversion rate) nearly balances the vertical down-gradient eddy heat flux indicating that eddies extract available potential energy from the mean field and convert eddy potential energy to eddy kinetic energy.     

Concentrations and sources of PAHs at three stations in Istanbul,Turkey

The chemical mass balance model was applied to atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) in Istanbul, Turkey. A total of 326 airborne samples were collected and analyzed for 16 PAHs and Total Suspended Particles (TSP) in the September 2006–December 2007 period at three monitoring stations: Yildiz, DMO (urban sites) and Kilyos (rural site). The total average PAH concentrations were 100.66 ± 61.26, 84.63 ± 46.66 and 25.12 ± 13.34 ng m^?3 and the TSP concentrations were 101.16 ± 53.22, 152.31 ± 99.12, 49.84 ± 18.58 μg m^?3 for Yildiz, DMO and Kilyos stations respectively. At all the sites, the lighter compounds were the most abundant, notably Nap, AcPy and PA. The average correlation values between TSP and total heavier PAH were greater than 0.5 for Yildiz and DMO stations. The patterns of PAH and TSP concentrations showed spatial and temporal variations. PAH concentrations were evaluated for the PAH contribution from four sources (diesel engines, gasoline engines, natural gas combustion, and coal + wood burning). Vehicle emissions appear to be the major source with contributions of 61.2%, 63.3% and 54.1% for Yildiz, DMO and Kilyos stations respectively. Seasonal and yearly variations had different trends for all sites.     

An operational MODIS aerosol retrieval algorithm at high spatial resolution,and its application over a complex urban region

Aerosol retrieval algorithms for the MODerate Resolution Imaging Spectroradiometer (MODIS) have been developed to estimate aerosol and microphysical properties of the atmosphere, which help to address aerosol climatic issues at global scale. However, higher spatial resolution aerosol products for urban areas have not been well-researched mainly due to the difficulty of differentiating aerosols from bright surfaces in urban areas. Here, an aerosol retrieval algorithm using the MODIS 500-m resolution bands is described, to retrieve aerosol properties over Hong Kong and the Pearl River Delta region. The rationale of our technique is to first estimate the aerosol reflectances by decomposing the top-of-atmosphere reflectances from surface reflectances and Rayleigh path reflectances. For the determination of surface reflectances, a Minimum Reflectance Technique (MRT) is used, and MRT images are computed for different seasons. For conversion of aerosol reflectance to aerosol optical thickness (AOT), comprehensive Look Up Tables specific to the local region are constructed, which consider aerosol properties and sun-viewing geometry in the radiative transfer calculations. Four local aerosol types, namely coastal urban, polluted urban, dust, and heavy pollution, were derived using cluster analysis on 3 years of AERONET measurements in Hong Kong. The resulting 500 m AOT images were found to be highly correlated with ground measurements from the AERONET (r² = 0.767) and Microtops II sunphotometers (r² = 0.760) in Hong Kong. This study further demonstrates the application of the fine resolution AOT images for monitoring inter-urban and intra-urban aerosol distributions and the influence of trans-boundary flows. These applications include characterization of spatial patterns of AOT within the city, and detection of regional biomass burning sources.     

Nitrate in groundwater of China: Sources and driving forces

Identifying the sources of reactive nitrogen (N) and quantifying their contributions to groundwater nitrate concentrations are critical to understanding the dynamics of groundwater nitrate contamination. Here we assessed groundwater nitrate contamination in China using literature analysis and N balance calculation in coupled human and natural systems. The source appointment via N balance was well validated by field data via literature analysis. Nitrate was detected in 96% of groundwater samples based on a common detection threshold of 0.2 mg N L^?1, and 28% of groundwater samples exceeded WHO's maximum contaminant level (10 mg N L^?1). Groundwater nitrate concentrations were the highest beneath industrial land (median: 34.6 mg N L^?1), followed by urban land (10.2 mg N L^?1), cropland (4.8 mg N L^?1), and rural human settlement (4.0 mg N L^?1), with the lowest found beneath natural land (0.8 mg N L^?1). During the period 1980–2008, total reactive N leakage to groundwater increased about 1.5 times, from 2.0 to 5.0 Tg N year^?1, in China. Despite that the contribution of cropland to the total amount of reactive N leakage to groundwater was reduced from 50 to 40% during the past three decades, cropland still was the single largest source, while the contribution from landfill rapidly increased from 10 to 34%. High reactive N leakage mainly occurred in relatively developed agricultural or urbanized regions with a large population. The amount of reactive N leakage to groundwater was mainly driven by anthropogenic factors (population, gross domestic product, urbanization rate and land use type). We constructed a high resolution map of reactive N source appointment and this could be the basis for future modeling of groundwater nitrate dynamics and for policy development on mitigation of groundwater contamination.     

Characterization of water-soluble inorganic ions in size-segregated aerosols in coastal city,Xiamen

The samples of water-soluble inorganic ions (WSIs), including anions (F^?, Cl^?, SO₄^2?, NO₃^?) and cations (NH₄⁺, K⁺, Na⁺, Ca²⁺, Mg²⁺) in 8 size-segregated particle matter (PM), were collected using a sampler (with 8 nominal cut-sizes ranged from 0.43 to 9.0 μm) from October 2008 to September 2009 at five sites in both polluted and background regions of a coastal city, Xiamen. The results showed that particulate matters in the fine mode (PM_2.1, Dp < 2.1 μm) comprised large part of mass concentrations of aerosols, which accounted for 45.56–51.27%, 40.04–60.81%, 42.02–60.81%, and 40.46–57.07% of the total particulate mass in spring, summer, autumn, and winter, respectively. The water-soluble ionic species in the fine mode at five sampling sites varied from 15.33 to 33.82 (spring), 14.03 to 28.06 (summer), 33.47 to 72.52 (autumn), and 48.39 to 69.75 μg m^? 3 (winter), respectively, which accounted for 57.30 ± 6.51% of the PM_2.1 mass concentrations. Secondary pollutants of NH₄⁺, SO₄^2? and NO₃^? were the dominant contributors of WSIs, which suggested that pollutants from anthropogenic activities, such as SO₂, NOx were formed in aerosols by photochemical reactions. The size distributions of Na⁺, Cl^?, SO₄^2? and NO₃^? were bimodal, peaking at 0.43–0.65 μm and 3.3–5.8 μm. Although some ions, such as NH₄⁺ presented bimodal distributions, the coarse mode was insignificant compared to the fine mode. Ca²⁺ and Mg²⁺ exhibited unimodal distributions at all sampling sites, peaking at 2.1–3.3 μm, while K⁺ having a bimodal distributions with a major peak at 0.43–0.65 μm and a minor one at 3.3–4.7 μm, were used in most of samples. Seasonal and spatial variations in the size-distribution profiles suggested that meteorological conditions (seasonal patterns) and sampling locations (geographical patterns) were the main factors determining the formation of secondary aerosols and characteristics of size distributions for WSIs.     

Exploring the vertical extent of breaking internal wave turbulence above deep-sea topography

A mooring equipped with 200 high-resolution temperature sensors between 6 and 404 m above the bottom was moored in 1890 m water depth above a steep, about 10° slope of Mount Josephine, NE-Atlantic. The sensors have a precision of less than 0.5 mK. They are synchronized via induction every 4 h so that the 400 m range is measured to within 0.02 s, every 1 s. Thin cables and elliptical buoyancy assured vertical mooring motions to be smaller than 0.1 m under maximum 0.2 m s⁻¹ current speeds. The local bottom slope is supercritical for semidiurnal internal tides by a factor of two. Exploring a one-month record in detail, the observations show: 1/semidiurnal tidal dominance in variations of dissipation rate ε, eddy diffusivity K_z and temperature, but no significant correlation between the records of ε and total kinetic energy, 2/a variation with time over four orders of magnitude of 100-m vertically averaged ε, 3/a local minimum in density stratification between 50 and 100 m above the bottom, 4/a gradual decrease in daily or longer averaged ε and K_z by one order of magnitude over a vertical distance of 250 m, upwards from 150 m above the bottom, 5/monthly mean values of <[ε]> = 2 ± 0.5 × 10⁻⁷ m² s⁻³, <[K_z]> = 8 ± 3 × 10⁻³ m² s⁻¹ averaged over the lower 150 m above the bottom.