Quantifying a realistic,worldwide wind and solar electricity supply

Nearly all long-term energy projections rely heavily on renewable energy sources on the assumption of abundance. Yet, already today, wind and solar projects can encounter local objections and competition with other uses. This paper presents the ranges of realistic potential supply for solar and wind electricity, using a 1 km² grid level analysis covering the whole world at country level. In addition, the potential for building-based solar electricity is assessed. We find that long-term combined potentials range between 730 and 3700 EJ/a worldwide, depending crucially on the acceptable share of land—up to 3.5% of total (non-ice covered) land on earth. Realistic potentials account for limitations such as land-use competition and acceptance, together with resource quality and remoteness as proxies for cost. Today's electricity demand (65 EJ/a) is well covered by the range, but constraints may occur in the long run locally. Amongst large countries, Nigeria and India may need imports to meet electricity demand.     

Water on an urban planet: Urbanization and the reach of urban water infrastructure

Urban growth is increasing the demand for freshwater resources, yet surprisingly the water sources of the world's large cities have never been globally assessed, hampering efforts to assess the distribution and causes of urban water stress. We conducted the first global survey of the large cities’ water sources, and show that previous global hydrologic models that ignored urban water infrastructure significantly overestimated urban water stress. Large cities obtain 78 ± 3% of their water from surface sources, some of which are far away: cumulatively, large cities moved 504 billion liters a day (184 km³ yr⁻¹) a distance of 27,000 ± 3800 km, and the upstream contributing area of urban water sources is 41% of the global land surface. Despite this infrastructure, one in four cities, containing $4.8 ± 0.7 trillion in economic activity, remain water stressed due to geographical and financial limitations. The strategic management of these cities’ water sources is therefore important for the future of the global economy.     

Land-cover change in the conterminous United States from 1973 to 2000

Land-cover change in the conterminous United States was quantified by interpreting change from satellite imagery for a sample stratified by 84 ecoregions. Gross and net changes between 11 land-cover classes were estimated for 5 dates of Landsat imagery (1973, 1980, 1986, 1992, and 2000). An estimated 673,000 km²(8.6%) of the United States’ land area experienced a change in land cover at least one time during the study period. Forest cover experienced the largest net decline of any class with 97,000 km² lost between 1973 and 2000. The large decline in forest cover was prominent in the two regions with the highest percent of overall change, the Marine West Coast Forests (24.5% of the region experienced a change in at least one time period) and the Eastern Temperate Forests (11.4% of the region with at least one change). Agriculture declined by approximately 90,000 km² with the largest annual net loss of 12,000 km² yr^?1 occurring between 1986 and 1992. Developed area increased by 33% and with the rate of conversion to developed accelerating rate over time. The time interval with the highest annual rate of change of 47,000 km² yr^?1 (0.6% per year) was 1986–1992. This national synthesis documents a spatially and temporally dynamic era of land change between 1973 and 2000. These results quantify land change based on a nationally consistent monitoring protocol and contribute fundamental estimates critical to developing understanding of the causes and consequences of land change in the conterminous United States.     

Kinematic metrics of the Loop Current in the Gulf of Mexico from satellite altimetry

We analyzed a 20-year time series (January 1st, 1993 through December 31st, 2012) of Loop Current (LC) surface area derived from satellite altimetry in the eastern Gulf of Mexico to estimate kinematical metrics of this potent flow. On average the LC intrudes to its maximum northward position about 216 ± 126 days after the previous eddy separation; and ∼30 ± 31 days later sheds a large anticyclonic eddy. When the northern extent of the LC intrusion following the previous eddy separation is greater than 27°N, the current retreats very quickly until it sheds another eddy with the entire separation process occurring on the order of 30 days. To first order the change in areal extent of the LC during intrusion into the Gulf occurs at an average rate of 225 km² day⁻¹, which corresponds to an intrusion velocity of 1.7 cm s⁻¹ of the LC front, and adds Caribbean water to the Gulf at a rate of 2.6 ± 0.7 Sv.     

Globalisation of water resources: international virtual water flows in relation to crop trade

The water that is used in the production process of a commodity is called the ‘virtual water’ contained in the commodity. International trade of commodities brings along international flows of virtual water. The objective of this paper is to quantify the volumes of virtual water flows between nations in the period 1995–1999 insofar related to international crop trade and to analyse national virtual water balances in relation to national water needs and water availability. The basic approach is to multiply international crop trade flows (ton/yr) by their associated virtual water content (m³ ton⁻¹). The calculations show that the global volume of crop-related international virtual water flows between nations was 695 Gm³ yr⁻¹ in average over the period 1995–1999. For comparison: the total water use by crops in the world has been estimated at 5400 Gm³ yr⁻¹. This means that 13% of the water used for crop production in the world is not used for domestic consumption but for export (in virtual form). This is a conservative estimate because only a limited number of crops––although the most important ones––have been taken into account and because crop products (such as cotton clothes) have been excluded from the study. The countries with the largest net virtual water export are United States, Canada, Thailand, Argentina and India. The largest net import appears to be in Japan, the Netherlands, the Republic of Korea, China and Indonesia.     

Nitrate in groundwater of China: Sources and driving forces

Identifying the sources of reactive nitrogen (N) and quantifying their contributions to groundwater nitrate concentrations are critical to understanding the dynamics of groundwater nitrate contamination. Here we assessed groundwater nitrate contamination in China using literature analysis and N balance calculation in coupled human and natural systems. The source appointment via N balance was well validated by field data via literature analysis. Nitrate was detected in 96% of groundwater samples based on a common detection threshold of 0.2 mg N L^?1, and 28% of groundwater samples exceeded WHO's maximum contaminant level (10 mg N L^?1). Groundwater nitrate concentrations were the highest beneath industrial land (median: 34.6 mg N L^?1), followed by urban land (10.2 mg N L^?1), cropland (4.8 mg N L^?1), and rural human settlement (4.0 mg N L^?1), with the lowest found beneath natural land (0.8 mg N L^?1). During the period 1980–2008, total reactive N leakage to groundwater increased about 1.5 times, from 2.0 to 5.0 Tg N year^?1, in China. Despite that the contribution of cropland to the total amount of reactive N leakage to groundwater was reduced from 50 to 40% during the past three decades, cropland still was the single largest source, while the contribution from landfill rapidly increased from 10 to 34%. High reactive N leakage mainly occurred in relatively developed agricultural or urbanized regions with a large population. The amount of reactive N leakage to groundwater was mainly driven by anthropogenic factors (population, gross domestic product, urbanization rate and land use type). We constructed a high resolution map of reactive N source appointment and this could be the basis for future modeling of groundwater nitrate dynamics and for policy development on mitigation of groundwater contamination.     

Influence of regional pollution and sandstorms on the chemical composition of cloud/fog at the summit of Mt. Taishan in northern China

Cloud/fog samples were collected during spring of 2007 in the highly polluted North China Plain in order to examine the impact of pollution and dust particles on cloud water chemistry. The volume weighted mean pH of cloud water was 3.68. The cloud acidity was shown to be associated with air mass origins. Cloud water with its air mass trajectories originating from the southern part of China was more acidic than those from northern China. Anthropogenic source and dust had obvious impact on cloud water composition as indicated by the very high mean concentrations of SO₄^2? (1331.65 μeq L^? 1), NO₃^? (772.44 μeq L^? 1), NH₄⁺ (1375.92 μeq L^? 1) and Ca²⁺ (625.81 μeq L^? 1) in the observation periods. During sandstorm days, cloud pH values were relatively high, and the concentrations of all the ions in cloud water reached unusual high levels. Significant decreases in the mass concentrations of PM_2.5 and PM₁₀ were observed during cloud events. The average scavenging ratio for PM_2.5 and PM₁₀ was 52.0% and 55.7%, respectively. Among the soluble ions in fine particles, NO₃^?, K⁺ and NH₄⁺ tend to be more easily scavenged than Ca²⁺ and Na⁺.     

Intraurban variability of PM10 and PM2.5 in an Eastern Mediterranean city

The results of the first large scale chemical characterization of PM10 and PM2.5 at three different sites in the urban city of Beirut, Lebanon, are presented. Between May 2009 and April 2010 a total of 304 PM10 and PM2.5 samples were collected by sampling every sixth day at three different sites in Beirut. Observed mass concentrations varied between 19.7 and 521.2 μg m^? 3 for PM10 and between 8.4 and 72.2 μg m^? 3 for PM2.5, respectively. Inorganic concentrations accounted for 29.7–35.6 μg m^? 3 and 46.0–53.5 μg m^? 3 of the total mass of PM10 and PM2.5, respectively. Intra-city temporal and spatial variations were assessed based on the study of three factors: correlation coefficients (R) for PM and chemical components, coefficient of divergence (CODs), and source apportionment using positive matrix factorization (PMF). Based on R and COD of PM concentrations, the three sites appear homogeneous. However, when individual elements were compared, heterogeneity among sites was found. This latter was attributed to the variability in the percent contribution of biogenic and local anthropogenic source factors such as traffic related sources and dust resuspension. Other factors included the proximity to the Mediterranean sea, the population density and the topographical structure of the city. Hence, despite its small size (20.8 km²), one PM monitoring site does not reflect an accurate PM level in Beirut.     

Exchange rates,soybean supply response,and deforestation in South America

The advancement of South America's agro-pastoral frontier has been widely linked to losses in biodiversity and tropical forests, with particular impacts on the Brazilian cerrado, the Atlantic Forest, and the Amazon. Here we consider an important, yet largely overlooked, driver of South America's soybean expansion, namely the devaluation of local currencies against the US dollar in the late 1990s and early 2000s. Much interest has emerged in recent years over the environmental implications of soybean production in Brazil, with evidence of both direct incursions into moist tropical forest by soybean producers and of potential indirect effects, via the displacement of existing ranching operations. In this research we utilize historical trends in soybean prices, exchange rates, and cropland dedicated to soybean production in Bolivia, Paraguay, and Brazil to estimate the impact of currency devaluations on area of production. The results suggest that approximately 80,000 km², or 31% of the current extent of soybean production in these countries, emerged as a supply area response to the devaluation of local currencies in the late 1990s. The results also indicate that the more recent depreciation of the dollar and appreciation of the Brazilian real have counteracted a recent rise in global soybean prices, in the process sparing an estimated nearly 90,000 km² from new cropland, 40,000 km² of this in the Amazon alone. Amidst an increasingly neoliberal economic environment, where barriers to trade are jettisoned in favor of the free flow of commodities, relative currency values will occupy an important role in the future sourcing of both agricultural expansion and environmental degradation.     

The global metabolic transition: Regional patterns and trends of global material flows, 1950–2010

Since the World War II, many economies have transitioned from an agrarian, biomass-based to an industrial, minerals-based metabolic regime. Since 1950, world population grew by factor 2.7 and global material consumption by factor 3.7–71 Gigatonnes per year in 2010. The expansion of the resource base required by human societies is associated with growing pressure on the environment and infringement on the habitats of other species. In order to achieve a sustainability transition, we require a better understanding of the currently ongoing metabolic transition and its potential inertia. In this article, we present a long-term global material flow dataset covering material extraction, trade, and consumption of 177 individual countries between 1950 and 2010. We trace patterns and trends in material flows for six major geographic and economic country groupings and world regions (Western Industrial, the (Former) Soviet Union and its allies, Asia, the Middle East and Northern Africa, Latin America and the Caribbean, and Sub-Saharan Africa) as well as their contribution to the emergence of a global metabolic profile during a period of rapid industrialization and globalization. Global average material use increased from 5.0 to 10.3 tons per capita and year (t/cap/a) between 1950 and 2010. Regional metabolic rates range from 4.5 t/cap/a in Sub-Saharan Africa to 14.8 t/cap/a in the Western Industrial grouping. While we can observe a stabilization of the industrial metabolic profile composed of relatively equal shares of biomass, fossil energy carriers, and construction minerals, we note differences in the degree to which other regions are gravitating toward a similar form of material use. Since 2000, Asia has overtaken the Western Industrial grouping in terms of its share in global resource use although not in terms of its per capita material consumption. We find that at a sub-global level, the roles of the world regions have changed. There are, however, no signs yet that this will lead to stabilization or even a reduction of global resource use.     

Sources of anthropogenic fire ignitions on the peat-swamp landscape in Kalimantan,Indonesia

Fire disturbance in many tropical forests, including peat swamps, has become more frequent and extensive in recent decades. These fires compromise a variety of ecosystem services, among which mitigating global climate change through carbon storage is particularly important for peat swamps. Indonesia holds the largest amount of tropical peat carbon globally, and mean annual CO₂ emissions from decomposition of deforested and drained peatlands and associated fires in Southeast Asia have been estimated at ∼2000 Mt y-1. A key component to understanding and therefore managing fire in the region is identifying the land use/land cover classes associated with fire ignitions. We assess the oft-asserted claim that escaped fires from oil palm concessions and smallholder farms near settlements are the primary sources of fire in a peat-swamp forest area in Central Kalimantan, Indonesia, equivalent to around a third of Kalimantan's total peat area. We use the MODIS Active Fire product from 2000 to 2010 to evaluate the fire origin and spread on the land use/land cover classes of legal, industrial oil palm concessions (the only type of legal concession in the study area), non-forest, and forest, as well as in relation to settlement proximity. We find that most fires (68–71%) originate in non-forest, compared to oil palm concessions (17%–19%), and relatively few (6–9%) are within 5 km of settlements. Moreover, most fires started within oil palm concessions and in close proximity to settlements stay within those boundaries (90% and 88%, respectively), and fires that do escape constitute only a small proportion of all fires on the landscape (2% and 1%, respectively). Similarly, a small proportion of fire detections in forest originate from oil palm concessions (2%) and within close proximity to settlements (2%). However, fire ignition density in oil palm (0.055 ignitions km⁻²) is comparable to that in non-forest (0.060 km-2 ignitions km-²), which is approximately ten times that in forest (0.006 ignitions km⁻²). Ignition density within 5 km of settlements is the highest at 0.125 ignitions km⁻². Furthermore, increased anthropogenic activity in close proximity to oil palm concessions and settlements produces a detectable pattern of fire activity. The number of ignitions decreases exponentially with distance from concessions; the number of ignitions initially increases with distance from settlements, and, around from 7.2 km, then decreases with distance from settlements. These results refute the claim that most fires originate in oil palm concessions, and that fires escaping from oil palm concessions and settlements constitute a major proportion of fires in this study region. However, there is a potential for these land use types to contribute substantially to the fire landscape if their area expands. Effective fire management in this area should therefore target not just oil palm concessions, but also non-forested, degraded areas where ignitions and fires escaping into forest are most likely to occur.     

Current trends of rubber plantation expansion may threaten biodiversity and livelihoods

The first decade of the new millennium saw a boom in rubber prices. This led to rapid and widespread land conversion to monoculture rubber plantations in continental SE Asia, where natural rubber production has increased >50% since 2000. Here, we analyze the subsequent spread of rubber between 2005 and 2010 in combination with environmental data and reports on rubber plantation performance. We show that rubber has been planted into increasingly sub-optimal environments. Currently, 72% of plantation area is in environmentally marginal zones where reduced yields are likely. An estimated 57% of the area is susceptible to insufficient water availability, erosion, frost, or wind damage, all of which may make long-term rubber production unsustainable. In 2013 typhoons destroyed plantations worth US$ >250 million in Vietnam alone, and future climate change is likely to lead to a net exacerbation of environmental marginality for both current and predicted future rubber plantation area. New rubber plantations are also frequently placed on lands that are important for biodiversity conservation and ecological functions. For example, between 2005 and 2010 >2500 km² of natural tree cover and 610 km² of protected areas were converted to plantations. Overall, expansion into marginal areas creates potential for loss-loss scenarios: clearing of high-biodiversity value land for economically unsustainable plantations that are poorly adapted to local conditions and alter landscape functions (e.g. hydrology, erosion) – ultimately compromising livelihoods, particularly when rubber prices fall.     

Exploring the vertical extent of breaking internal wave turbulence above deep-sea topography

A mooring equipped with 200 high-resolution temperature sensors between 6 and 404 m above the bottom was moored in 1890 m water depth above a steep, about 10° slope of Mount Josephine, NE-Atlantic. The sensors have a precision of less than 0.5 mK. They are synchronized via induction every 4 h so that the 400 m range is measured to within 0.02 s, every 1 s. Thin cables and elliptical buoyancy assured vertical mooring motions to be smaller than 0.1 m under maximum 0.2 m s⁻¹ current speeds. The local bottom slope is supercritical for semidiurnal internal tides by a factor of two. Exploring a one-month record in detail, the observations show: 1/semidiurnal tidal dominance in variations of dissipation rate ε, eddy diffusivity K_z and temperature, but no significant correlation between the records of ε and total kinetic energy, 2/a variation with time over four orders of magnitude of 100-m vertically averaged ε, 3/a local minimum in density stratification between 50 and 100 m above the bottom, 4/a gradual decrease in daily or longer averaged ε and K_z by one order of magnitude over a vertical distance of 250 m, upwards from 150 m above the bottom, 5/monthly mean values of <[ε]> = 2 ± 0.5 × 10⁻⁷ m² s⁻³, <[K_z]> = 8 ± 3 × 10⁻³ m² s⁻¹ averaged over the lower 150 m above the bottom.     

Severe weather reports and proximity to deep convection over Northern Argentina

Conventional surface data and quantitative estimations of precipitation are used to document the occurrence and spatial distribution of severe weather phenomena associated with deep moist convection over southeastern South America.Data used in this paper are 24-hour rainfall, maximum hourly gusts and present weather reports from the surface station network for Argentina to the north of 40°S and cover the period 2000–2005. Hourly rainfall estimated with the CMORPH technique (CPC MORPHing technique, R. J. Joyce et al., 2004) is included in the analysis in order to increase the density of the precipitation database from January 2003 to December 2005. Extreme events are detected by means of a 95th-percentile analysis of the 24-hour rainfall and wind; values greater than 30 mm and 25 m s^?1 respectively are considered extreme in the study area. These results are related to the presence of deep convection by considering the 235 K and 218 K cloud shield evolution in Geostationary Operational Environmental Satellite-12 Infrared (GOES-IR) imagery evaluated by the Forecasting and Tracking of Cloud Cluster (FORTRACC) technique. Rainfall above 30 mm day^?1 and present convection-related weather events tend to occur in the northeast of the country.Finally, an analysis is made of the relationship between severe phenomena and the location and lifecycle of Mesoscale Convective Systems (MCSs) defined by the 218 K or 235 K levels. According to the reports, favorable locations for severe weather concentrate to the northeast of the cloud shield anvil centroid although most of the cases are found in the northwest. This feature can be seen in systems with anvil areas larger than 250,000 km² in association to the predominant mid-level wind shear direction from the northwest over the area. Moreover, systems with centers located north of 30°S present a more circular shape while those to the south are more elongated with a NW–SE main axis clearly related to the presence and interaction with frontal zones over the area. Most of the events occur previous to the moment when the systems reach their maximum extension, between 2 and 10 h after the initiation of the system depending on the size of the MCSs.     

Observations and operational model simulations reveal the impact of Hurricane Matthew (2016) on the Gulf Stream and coastal sea level

In October 7–9, 2016, Hurricane Matthew moved along the southeastern coast of the U.S., causing major flooding and significant damage, even to locations farther north well away from the storm’s winds. Various observations, such as tide gauge data, cable measurements of the Florida Current (FC) transport, satellite altimeter data and high-frequency radar data, were analyzed to evaluate the impact of the storm. The data show a dramatic decline in the FC flow and increased coastal sea level along the U.S. coast. Weakening of the Gulf Stream (GS) downstream from the storm’s area contributed to high coastal sea levels farther north. Analyses of simulations of an operational hurricane-ocean coupled model reveal the disruption that the hurricane caused to the GS flow, including a decline in transport of ∼20 Sv (1 Sv = 10⁶ m³ s⁻¹). In comparison, the observed FC reached a maximum transport of ∼40 Sv before the storm on September 10 and a minimum of ∼20 Sv after the storm on October 12. The hurricane impacts both the geostrophic part of the GS and the wind-driven currents, generating inertial oscillations with velocities of up to ±1 m s⁻¹. Analysis of the observed FC transport since 1982 indicated that the magnitude of the current weakening in October 2016 was quite rare (outside 3 standard deviations from the mean). Such a large FC weakening in the past occurred more often in October and November, but is extremely rare in June-August. Similar impacts on the FC from past tropical storms and hurricanes suggest that storms may contribute to seasonal and interannual variations in the FC. The results also demonstrated the extended range of coastal impacts that remote storms can cause through their influence on ocean currents.     

Biogeophysical impacts of land use on present-day climate: near-surface temperature change and radiative forcing

Changes in land cover affect climate through the surface energy and moisture budgets, but these biogeophysical impacts of land use have not yet been included in General Circulation Model (GCM) simulations of 20th century climate change. Here, the importance of these effects was assessed by comparing climate simulations performed with current and potential natural vegetation. The northern mid-latitude agricultural regions were simulated to be approximately 1–2 K cooler in winter and spring in comparison with their previously forested state, due to deforestation increasing the surface albedo by approximately 0.1 during periods of snow cover. Some other regions such as the Sahel and India experienced a small warming due to land use. Although the annual mean global temperature is only 0.02 K lower in the simulation with present-day land use, the more local temperature changes in some regions are of a similar magnitude to those observed since 1860. The global mean radiative forcing by anthropogenic surface albedo change relative to the natural state is simulated to be −0.2 Wm², which is comparable with the estimated forcings relative to pre-industrial times by changes in stratospheric and tropospheric ozone, N₂O, halocarbons, and the direct effect of anthropogenic aerosols. Since over half of global deforestation has occurred since 1860, simulations of climate since that date should include the biogeophysical effects of land use.     

The possible role of Brazilian promontory in Little Ice Age

The Gulf Stream, one of the strongest currents in the world, transports approximately 31 Sv of water (Kelly and Gille, 1990, Baringer and Larsen, 2001, Leaman et al., 1995) and 1.3 × 10¹⁵ W (Larsen, 1992) of heat into the Atlantic Ocean, and warms the vast European continent. Thus any change of the Gulf Stream could lead to the climate change in the European continent, and even worldwide (Bryden et al., 2005). Past studies have revealed a diminished Gulf Stream and oceanic heat transport that was possibly associated with a southward migration of intertropical convergence zone (ITCZ) and may have contributed to Little Ice Age (AD ∼1200 to 1850) in the North Atlantic (Lund et al., 2006). However, the causations of the Gulf Stream weakening due to the southward migration of the ITCZ remain uncertain. Here we use satellite observation data and employ a model (oceanic general circulation model – OGCM) to demonstrate that the Brazilian promontory in the east coast of South America may have played a crucial role in allocating the equatorial currents, while the mean position of the equatorial currents migrates between northern and southern hemisphere in the Atlantic Ocean. Northward migrations of the equatorial currents in the Atlantic Ocean have little influence on the Gulf Stream. Nevertheless, southward migrations, especially abrupt large southward migrations of the equatorial currents, can lead to the increase of the Brazil Current and the significant decrease of the North Brazil Current, in turn the weakening of the Gulf Stream. The results from the model simulations suggest the mean position of the equatorial currents in the Atlantic Ocean shifted at least 180–260 km southwards of its present-day position during the Little Ice Age based on the calculations of simple linear equations and the OGCM simulations.     

Livestock production and the water challenge of future food supply: Implications of agricultural management and dietary choices

Human activities use more than half of accessible freshwater, above all for agriculture. Most approaches for reconciling water conservation with feeding a growing population focus on the cropping sector. However, livestock production is pivotal to agricultural resource use, due to its low resource-use efficiency upstream in the food supply chain. Using a global modelling approach, we quantify the current and future contribution of livestock production, under different demand- and supply-side scenarios, to the consumption of “green” precipitation water infiltrated into the soil and “blue” freshwater withdrawn from rivers, lakes and reservoirs. Currently, cropland feed production accounts for 38% of crop water consumption and grazing involves 29% of total agricultural water consumption (9990 km³ yr⁻¹). Our analysis shows that changes in diets and livestock productivity have substantial implications for future consumption of agricultural blue water (19–36% increase compared to current levels) and green water (26–69% increase), but they can, at best, slow down trends of rising water requirements for decades to come. However, moderate productivity reductions in highly intensive livestock systems are possible without aggravating water scarcity. Productivity gains in developing regions decrease total agricultural water consumption, but lead to expansion of irrigated agriculture, due to the shift from grassland/green water to cropland/blue water resources. While the magnitude of the livestock water footprint gives cause for concern, neither dietary choices nor changes in livestock productivity will solve the water challenge of future food supply, unless accompanied by dedicated water protection policies.     

Below-cloud rain scavenging of atmospheric aerosols for aerosol deposition models

Below-cloud aerosol scavenging is generally estimated from field measurements using advanced instruments that measure changes in aerosol distributions with respect to rainfall. In this study, we discuss various scavenging mechanisms and scavenging coefficients from past laboratory and field measurements. Scavenging coefficients derived from field measurements (representing natural aerosols scavenging) are two orders higher than that of theoretical ones for smaller particles (D_p < 2 μm). Measured size-resolved scavenging coefficients can be served as a better option to the default scavenging coefficient (e.g. a constant of 10^?4 s^?1 for all size of aerosols, as used in the CALPUFF model) for representing below-cloud aerosol scavenging. We propose scavenging correction parameter (C_R) as an exponential function of size-resolved scavenging coefficients, winds and width in the downwind of the source–receptor system. For a wind speed of 3 m s^?1, C_R decrease with the width in the downwind for particles of diameters D_p < 0.1 μm but C_R does not vary much for particles in the accumulation mode (0.1 < D_p < 2 μm). For a typical urban aerosol distribution, assuming 3 m s^?1 air-flow in the source–receptor system, 10 km downwind width, 2.84 mm h^?1 of rainfall and using aerosol size dependent scavenging coefficients in the C_R, scavenging of aerosols is found to be 16% in number and 24% in volume of total aerosols. Using the default scavenging coefficient (10^?4 s^?1) in the CALPUFF model, it is found to be 64% in both number and volume of total aerosols.     

Distribution of inorganic nitrogen-containing species in atmospheric particles from an island in the Yellow Sea

In this study, total suspended particles (TSP) and size-segregated atmospheric aerosol samples were measured on Qianliyan Island in the Yellow Sea in spring (April–May), summer (July–August) and fall (October–November) of 2006 and in water (January–February) of 2007. The mass concentration of the TSP varied from 75.6 to 132.0 μg/m³. The average concentration were 9.37 ± 7.56 μg/m³ and 5.32 ± 4.25 μg/m³ for nitrate and ammonium in the TSP, respectively. TSP concentration showed a significant correlation with those of nitrate (n = 27, r = 0.73) and ammonium (n = 27, r = 0.60). The mass-size distribution of atmospheric particles exhibited two modes with an accumulation mode at 0.43–1.1 μm and a coarse mode at 3.3–4.7 μm throughout the sampling months. A bi-modal size distribution of nitrate in concentration occurred in the April–May, October–November and January–February, but a uni-modal size distribution occurred in the August. The uni-modal size distribution of ammonium at 0.43–0.65 μm was observed throughout the sampling months. The average of inorganic nitrogen in mass concentration accounted for 4.0% of the total mass of aerosol particles while ammonium-N was the dominant fraction of TIN (Total Inorganic Nitrogen), contributing to 62–71% of the TIN.