U–Pb zircon age of the Walloon Coal Measures in the Surat Basin,southeast Queensland: implications for paleogeography and basin subsidence

The Jurassic Walloon Coal Measures of the Surat Basin were previously estimated to be of Middle Jurassic age, ranging from Aalenian to Callovian, based on an uncalibrated eastern Australian biostratigraphic framework. New U–Pb dates of 162.55 ± 0.05 Ma and 158.86 ± 0.04 Ma obtained from zircons in ash-fall volcanic tuffs now place the Walloon Coal Measures of the Surat Basin in the Upper Jurassic Oxfordian. The new dates have several implications for the interpretation of the Jurassic strata in the Surat Basin. First-order subsidence rates of 61 m/Myr for the Walloon Coal Measures are more akin to those of foreland basins than the previously assumed intracratonic setting. The dates also imply deposition of the Walloon coals in substantially higher latitudes than previously assumed and that they accumulated as peats in mires that experienced more than three months’ continual darkness each winter. Zircon dating of tuffs and associated geochemistry should assist with the correlation of the laterally impersistent coals, fluvial sandstone and mudstone of the Walloon Coal Measures, which are currently difficult to correlate over distances of more than a few kilometres. Dating of the palynostratigraphic zones APJ4.2 to APJ5 (Aequitriradites norrisii Association Zone to Murospora florida Association Zone) will also need to be recalibrated.     

Detrital zircon geochronology analysis of the Late Mesozoic deposition in the Turpan‐Hami basin: Implications for the uplift history of the Eastern Tian Shan,north‐western China

Analysing the provenance changes of synorogenic sediments in the Turpan‐Hami basin by detrital zircon geochronology is an efficient tool to examine the uplift and erosion history of the easternmost Tian Shan. We present detrital zircon U‐Pb analysis from nine samples that were collected within marginal lacustrine Middle‐Late Jurassic and aeolian‐fluvial Early Cretaceous strata in the basin. Middle‐Early Jurassic (159–172 Ma) zircons deriving from the southern Junggar dominated the Middle Jurassic sample from the western Turpan‐Hami basin, whereas Permian‐Carboniferous (270–330 Ma) zircons from the Bogda mountains were dominant in the Late Jurassic to Early Cretaceous samples. Devonian‐Silurian (400–420 Ma) and Triassic (235–259 Ma) zircons from the Jueluotage and Harlik mountains constituted the subordinate age groups in the Late Jurassic and Early Cretaceous samples from the eastern basin respectively. These provenance transitions provide evidence for uplift of the Bogda mountains in the Late Jurassic and the Harlik mountains since the Early Cretaceous.     

利用锆石裂变径迹研究漠河盆地隆升过程

通过对漠河盆地内32件样品的锆石裂变径迹进行详细分析,锆石单颗粒径迹年龄最大值为143.9±18.7Ma,最小年龄为58±12.1Ma,峰值年龄为92~98Ma和132~138Ma。结合盆地断裂展布及大地构造背景,认为漠河盆地在95Ma和135Ma发生了2次强隆升过程。结合盆地断裂系统、构造特征及区域地质背景,认为自晚侏罗世以来盆地形成受到蒙古-鄂霍次克海碰撞关闭和古太平洋板块俯冲碰撞双重作用的影响,盆地中晚侏罗世(135Ma左右)处于南北向挤压背景,形成东西向展布的前陆盆地;白垩纪中期,盆地处于伸展构造背景,属东北(同)大陆裂谷系的一部分。白垩纪中晚期(95Ma左右),漠河盆地由拉张环境再一次变为挤压环境,盆地形成了又一次的强隆升过程。     

Jurassic uplift and erosion of the northeast Queensland continental margin: evidence from (U–Th)/He thermochronology combined with U–Pb detrital zircon age spectra

Abstract

The Jurassic–Cretaceous Great Artesian Basin is the most extensive, and largest volume, sedimentary feature of continental Australia. The source of its mud-dominated Cretaceous infill is attributed largely to contemporary magmatism along the continental margin to the east, but the source of its Jurassic infill, dominated by quartz sandstone, remains unconstrained. This paper investigates the question of a Jurassic sediment source for the northern part of the basin. Jurassic uplift and exhumation of the continental margin crustal sector to the east provided the primary Jurassic sediment source. (U–Th)/He data are presented for zircon and apatite from Pennsylvanian to mid Permian granitoids of the Kennedy Igneous Association distributed within the northern Tasmanides between the Townsville and Cairns regions and for coeval granites of the Urannha batholith from the Mount Carlton district (N Bowen Basin), also within the northern Tasmanides. The data from zircon indicate widespread Jurassic exhumation of a crustal tract located to the east of the northern Great Artesian Basin and largely occupied by rocks of the Tasmanides. Detrital zircon age spectra for samples of the Jurassic Hutton and Blantyre sandstones from the northeastern margin of the Great Artesian Basin show their derivation to be largely from rocks of the northern Tasmanides. In combination, the detrital age spectra and (U–Th)/He data from zircon indicate exhumation owing to uplift generating appreciable physiographic relief along the north Queensland continental margin during the Jurassic, shedding sediment westward into the Great Artesian Basin during its early development. A portion of (U–Th)/He data for zircon are consistent with late Permian–mid Triassic exhumation within the Tasmanides, attributable to the influence of the Hunter--Bowen Orogeny. Evidence of Cretaceous and Paleocene exhumation episodes is also indicated for some samples, mainly by apatite (U–Th)/He analysis, consistent with data previously published from fission track studies. Overall, new data from the present study reveal that the exhumation related to Jurassic regional uplift and the subsequent erosional reworking of the northeast Australian continental margin is critical for the evolution and development of the northern side of the Great Artesian Basin in eastern Australia. Apart from this, another two previously suggested Permian–Triassic and Cretaceous exhumation and uplift episodes along the northeast Australian continental margin are also confirmed by the dataset of this study.

1. KEY POINTS

2. U–Pb detrital zircon ages of sandstone samples from the northeastern Eromanga Basin reveal Paleozoic (480–280 Ma) and Proterozoic (1800–1400 Ma) age clusters.

3. (U–Th)/He zircon and apatite dating results of granitoids samples from Cairns, Townsville and the Mount Carlton districts are dominated by Jurassic (198–164 Ma) and Permian–Triassic (272–238 Ma) age clusters.

4. Combination of above two datasets proves the regional uplift-driving Jurassic exhumation episode in the northeast Australian continental is vital for the development of the northern Great Artesian Basin.

     

Thermotectonic evolution of Precambrian basement rocks of the Kuruktag uplift,NE Tarim craton,China: evidence from apatite fission-track data

The Kuruktag uplift is located directly northeast of the Tarim craton in northwestern China. Neoarchaean-to-Neoproterozoic metamorphic rocks and intrusive rocks crop out widely in the uplift; thus, it is especially suited for a more complete understanding of the thermal evolution of the Tarim craton. Apatite fission-track (AFT) methods were used to study the exhumation history and cooling of these Precambrian crystalline rocks. Nine apatite-bearing samples were collected from both sides of the Xingdi fault transecting the Kuruktag uplift. Pooled ages range from 146.0 ± 13.4 to 67.6 ± 6.7 Ma, with mean track lengths between 11.79 ± 0.14 and 12.48 ± 0.10 μm. These samples can be divided into three groups based on age and structural position. Group A consists of five samples with AFT apparent ages of about 100–110 Ma and is generally associated with undeformed areas. Group B comprises three specimens with AFT apparent ages lower than 80 Ma and is mostly associated with hanging wall environments close to faults. Group C is a single apatite sample with the oldest relative apparent age, 146.0 ± 13.4 Ma. The modelled thermal history indicates four periods of exhumation in the Kuruktag uplift: late-Early Jurassic (180 Ma); Late Jurassic–Early Cretaceous (144–118 Ma); early-Late Cretaceous (94–82 Ma); and late Cenozoic (about 10 Ma). These cooling events, identified by AFT data, are assumed to reflect far-field effects from multi-stage collisions and accretions of terranes along the south Asian continental margin.     

Stratigraphic and depositional framework of the Walloon Subgroup,eastern Surat Basin,Queensland

The Middle Jurassic Walloon Subgroup is a prolific coal seam gas (CSG) resource in the Surat Basin, Queensland. Sedimentary framework models constrain stochastic reservoir models of the geological heterogeneity, but there is limited basin analysis information in the public domain. Here we present a regionally consistent stratigraphic framework model for the Walloon CSG play in the eastern Surat Basin. Lithostratigraphic correlation of open-file industry and government wireline logs supports the interpretation of six subunits in the eastern Surat Basin (oldest–youngest: Durabilla Formation; Taroom Coal Measures; Tangalooma Sandstone; and Juandah Coal Measures, informally divided into three members named the lower Juandah Coal Measures, Juandah sandstone and upper Juandah Coal Measures). Important findings are that subunits within the Walloon Subgroup do not correlate along the entire CSG play area; in many places, the overlying Springbok Sandstone (Upper Jurassic) has incised to the lower Juandah Coal Measures level, removing the upper coal seam groups. The Walloon Subgroup thins to the south through a combination of depositional thinning and truncation. Lithofacies analysis and isopach maps support deposition in a southerly prograding fluvial system or clastic wedge. This stratigraphic and depositional interpretation informs models for hydrogeological studies of the Walloon Subgroup and underpins a regional assessment of controls on microbial methane distribution.     

Lower Cretaceous turbidites in the Shiquanhe–Namco Ophiolite Mélange Zone,Asa area,Tibet:Constraints on the evolution of the Meso-Tethys Ocean

Turbidites from the Shiquanhe–Namco Ophiolite Mélange Zone(SNMZ) record critical information about the tectonic affinity of the SNMZ and the evolutionary history of the Meso-Tethys Ocean in Tibet.This paper reports sedimentologic,sandstone petrographic,zircon U-Pb geochronologic,and clastic rocks geochemical data of newly identified turbidites(Asa Formation) in the Asa Ophiolite Mélange.The youngest ages of detrital zircon from the turbiditic sandstone samples,together with ～115 Ma U-Pb concordant age from the tuff intercalation within the Asa Formation indicate an Early Cretaceous age.The sandstone mineral modal composition data show that the main component is quartz grains and the minor components are sedimentary and volcanic fragments,suggesting that the turbidites were mainly derived from a recycled orogen provenance with a minor addition of volcanic arc materials.The detrital U-Pb zircon ages of turbiditic sandstones yield main age populations of170–120 Ma,300–220 Ma,600–500 Ma,1000–700 Ma,1900–1500 Ma,and ～2500 Ma,similar to the ages of the Qiangtang Terrane(age peak of 600–500 Ma,1000–900 Ma,～1850 Ma and ～2500 Ma) and the accretionary complex in the Bangong–Nujiang Ophiolite Zone(BNMZ) rather than the age of the Central Lhasa Terrane(age peak of ～300 Ma,～550 Ma and ～1150 Ma).The mineral modal compositions,detrital U-Pb zircon ages,and geochemical data of clastic rocks suggest that the Asa Formation is composed of sediments primarily recycled from the Jurassic accretionary complex within the BNMZ with the secondary addition of intermediate-felsic island arc materials from the South Qiangtang Terrane.Based on our new results and previous studies,we infer that the SNMZ represents a part of the Meso-Tethys Suture Zone,rather than a southward tectonic klippe of the BNMZ or an isolated ophiolitic mélange zone within the Lhasa Terrane.The Meso-Tethys Suture Zone records the continuous evolutionary history of the northward subduction,accretion,arc-Lhasa collision,and Lhasa-Qiangtang collision of the Meso-Tethys Ocean from the Early Jurassic to the Early Cretaceous.     

Lithospheric thinning and ignition of a Cordilleran magmatic flare-up: Geochemical and O-Hf isotopic constraints from Cretaceous plutons in southern Korea

Northeast Asian continental margins contain the products of magma emplacement driven by prolonged subduction of the (paleo-)Pacific plate. As observed in many Cordilleran arcs, magmatic evolution in this area was punctuated by high-volume pulses amid background periods. The present study investigates the early evolution of the Cretaceous magmatic flare-up using new and published geochronological, geochemical, and O-Hf isotope data from plutonic rocks in the southern Korean Peninsula. After a long (～50 m.y.) magmatic hiatus and the development of the Honam Shear Zone through flat-slab subduction, the Cretaceous flare-up began with the intrusion of monzonites, granodiorites, and granites in the inboard Gyeonggi Massif and the intervening Okcheon Belt. Compared to Jurassic granitoids formed during the former flare-up, Albian (～111 Ma) monzonites found in the Eopyeong area of the Okcheon Belt have distinctly higher zircon ε_Hf(t) (?7.5 ± 1.3) and δ¹⁸O (7.78‰ ± 0.25‰) values and lower whole-rock La/Yb and Sr/Y ratios. The voluminous coeval granodiorite and granite plutons in the Gyeonggi Massif are further reduced in Sr/Y and to a lesser extent, in La/Yb, and have higher zircon ε_Hf(t) values (?13 to ?19) than the Precambrian basement (ca. ?30). These chemical and isotopic features indicate that Early Cretaceous lithospheric thinning, most likely resulting from delamination of tectonically and magmatically overthickened lithospheric keel that was metasomatized during prior subduction episodes, and consequent asthenospheric upwelling played vital roles in igniting the magmatic flare-up. The O-Hf isotopic ranges of synmagmatic zircons from the Albian plutons and their Paleoproterozoic and Jurassic inheritance attest to the involvement of lithospheric mantle and crustal basement in magma generation during this decratonization event. Arc magmatism then migrated trenchward and culminated in the Late Cretaceous, yielding widespread granitoid rocks emplaced at shallow crustal levels. The early Late Cretaceous (94–85 Ma) granites now prevalent in Seoraksan-Woraksan-Sokrisan National Parks are highly silicic and display flat chondrite-normalized rare earth element patterns with deep Eu anomalies. Synmagmatic zircons in these granites mimic their host rock’s chemistry. Delamination-related rejuvenation of crustal protoliths is indicated by zircon ε_Hf(t) values of granites (?6 to ?20) that are consistently higher than the Precambrian basement value. Concomitant core-to-rim variation in zircon O-Hf isotopic compositions reflects a typical sequence of crustal assimilation and fresh input into the magma chamber.     

Nature and origin of Mesozoic granitoids and associated mineralization in the Sanjiang Tethys Orogeny,SW China: the Xiuwacu complex example

ABSTRACT

The magmatic generation for the Late Triassic–Early Jurassic (~215–200 Ma) and Early Cretaceous–Late Cretaceous (~108–79 Ma) post-collisional granites in the Sanjiang Tethys orogeny remain enigmatic. The Xiuwacu complex, located in the southern Yidun Terrane, consists of biotite granite with a weight mean ²⁰⁶Pb/²³⁸U age of 199.8 ± 2.5 Ma, aplite granite of 108.2 ± 2.3 Ma, monzogranite porphyry of 80.8 ± 1.0 Ma, and diorite enclaves of 79.2 ± 0.9 Ma and 77.9 ± 0.8 Ma. The Late Triassic biotite granites show I-type granite affinities, with high SiO₂ contents, high Mg^# values, high zircon δ¹⁸O values, and negative whole-rock ?Nd(t) values, indicating a predominant ancient crustal source with the input of juvenile materials. Their fractionated REE patterns and concave-upward middle-to-heavy REE patterns require garnet-bearing amphibolite as the melt source. The Cretaceous highly fractionated aplite granites and monzogranite porphyries have relatively high SiO₂ contents, high (Na₂O + K₂O)/CaO ratios, high zircon δ¹⁸O values, and enriched whole-rock Sr–Nd isotopic signatures, suggesting that their parent magmas were likely originated from the ancient middle- to lower crust. Their significant negative Eu anomalies and obvious depletions in Nb, Sr, and Ti demonstrate that the Cretaceous granitic magmas had experienced more fractionation than the Late Triassic felsic magmas. The Late Cretaceous diorite enclaves show low SiO₂ contents, high Mg^# values, and high zircon δ¹⁸O values, suggesting that they were probably derived from the partial melting of subcontinental lithospheric mantle enriched by the Late Triassic subduction. The Late Triassic–Early Jurassic and Early Cretaceous–Late Cretaceous magmatism witnessed the post-collisional setting and intraplate extensional setting in response to the slab break-off and lithospheric-scale transtensional faulting, respectively. The partial melting of subduction-modified lithospheric mantle or/and residual sulphide cumulates within the lower crust during the origination of Late Cretaceous magmas could have provided metals for the formation of Xiuwacu deposit.     

Evolution of the depositional environments of the Jurassic Walloon Coal Measures,Surat Basin,Queensland, Australia

The Jurassic Walloon Coal Measures of the Surat Basin in eastern Australia host the continent's most significant coal bed methane resources. Previous studies have interpreted the Walloon Coal Measures within a single depositional facies model encompassing a wholly terrestrial setting. Using a multidisciplinary approach (facies analysis, palynology and wireline logs), the evolution of the Walloon Coal Measures is described within a new chronostratigraphic framework defined by accurate and precise U–Pb tuff dates. Analysis of sedimentary facies indicates that the majority of the Walloon Coal Measures was deposited by relatively small (<300 m wide), low gradient rivers on a poorly‐drained floodplain with numerous small lakes and mires. However, this study also identified some marine‐influenced facies with brackish palynomorphs (notably dinoflagellate cysts) and tidal sedimentary structures. These facies appear to have been deposited in estuaries during times of transgression. The evidence for base level shifts suggests that the coals may not have coevally accumulated with at least some of the thicker sandstones. Palaeogeographic maps for eleven time intervals suggest that rivers drained towards to the south/south‐west and south‐east, as indicated by sandstone percentage and gross unit isopach maps, presumably into proximal estuarine complexes. Marine incursions into the continent probably came from the north and east during times of high eustatic sea level and as precursors to those of the more persistent and extensive transgressions of the Early Cretaceous. A similar multidisciplinary approach should help to elucidate the evolution of other fluviolacustrine systems in other basins and aid in resource prediction.     

Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China

The Tongcun Mo porphyry deposit in northwest Zhejiang is hosted in three porphyry units: Huangbaikeng, Songjiazhuang, and Tongcun, from southwest to northeast. U–Pb zircon ages of 162?±?3.0 Ma for the Huangbaikeng porphyry, 159.9?±?3.0 Ma for the Songjiazhuang porphyry, and 167.6–155.6 Ma for the Tongcun porphyry indicate that these intrusions formed during the Jurassic and are most likely associated with the northwestward subduction of the Izanagi Plate. Trace element compositions of zircons from the Tongcun deposit constrain the oxygen fugacity (fO₂) of the magma using zircon Ce anomalies and Ti-in-zircon temperatures. The average magmatic fO₂ for the porphyries in the Tongcun deposit is fayalite–magnetite–quartz (FMQ)?+?2.7, which is similar to the Shapinggou (FMQ?+?3.2) and Dabaoshan (FMQ?+?3.5) Mo porphyry deposits, but much higher than that of the reduced Cretaceous ore-barren Shangjieshou porphyry (FMQ-1.1) around 8 km away from the Tongcun deposit. The distinct difference in magmatic oxygen fugacity between the Jurassic and Cretaceous porphyries may help to explain the absence of Mo porphyry mineralization in northwest Zhejiang during the Cretaceous.     

Fission Track Thermochronology Evidence for the Cretaceous and Paleogene Tectonic Event of Nyainrong Microcontinent, Tibet

Fission track dating was applied to analyze the 20 samples from Nyainrong microcontinent, and we obtained 20 apatite and 15 zircon fission track ages. The results show single population grain ages with a single mean age and associated central ages mainly ranging from 108±7Ma to 35±4Ma.Their mean track lengths are 12.2–13.9 μm with a single peak. Zircon fission track age range from 78±3 Ma to 117±4 Ma. The results represented the two tectonic uplift events in the study area, namely the Cretaceous and Paleogene periods. According to thermal history modeling results, uplifting rates of two tectonic events is 0.31–0.1 mm/a and 0.07–0.04 mm/a respectively. Combined with field condition and study results, it is suggested that the Cretaceous tectonic uplift event was related to the closure ocean basin caused by Qaingtang–Lhasa collision, and the Paleogene tectonic uplift event was related to the south to thrust system caused by Indo–Asian collision.     

Geochronology and Genesis of the Tiegelongnan Porphyry Cu(Au) Deposit in Tibet: Evidence from U–Pb,Re–Os Dating and Hf,S, and H–O Isotopes

The Tiegelongnan Cu (Au) deposit is the largest copper deposit newly discovered in the Bangong–Nujiang metallogenic belt. The deposit has a clear alteration zoning consisting of, from core to margin, potassic to propylitic, superimposed by phyllic and advanced argillic alteration. The shallow part of the deposit consists of a high sulphidation‐state overprint, mainly comprising disseminated pyrite and Cu–S minerals such as bornite, covellite, digenite, and enargite. At depth porphyry‐type mineralization mainly comprises disseminated chalcopyrite, bornite, pyrite, and a minor vein molybdenite. Mineralization is disseminated and associated with veins contained within the porphyry intrusions and their surrounding rocks. The zircon U–Pb ages of the mineralized diorite porphyry and granodiorite porphyry are 123.1 ± 1.7 Ma (2σ) and 121.5 ± 1.5 Ma (2σ), respectively. The molybdenite Re–Os age is 121.2 ± 1.2 Ma, suggesting that mineralization was closely associated with magmatism. Andesite lava (zircon U–Pb age of 111.7 ± 1.6 Ma, 2σ) overlies the ore‐bodies and is the product of post‐mineralization volcanic activity that played a critical role in preserving the ore‐bodies. Values of ?4.6 ‰ to + 0.8 ‰ δ³⁴S for the metal sulfides (mean ? 1.55 ‰) suggest that S mainly has a deep magmatic source. The H and O isotopic composition is (δD = ?87 ‰ to ?64 ‰; δ¹⁸O_H2O = 5.5 ‰ to 9.0 ‰), indicating that the ore‐forming fluids are mostly magmatic‐hydrothermal, possibly mixed with a small amount of meteoric water. The zircon ε_Hf(t) of the diorite porphyry is 3.7 to 8.3, and the granodiorite porphyry is 1.8 to 7.5. Molybdenite has a high Re from 382.2 × 10^?6 to 1600 × 10^?6. Re and Hf isotope composition show that Tiegelongnan has some mantle source, maybe the juvenile lower crust from crust–mantle mixed source. Metallogenesis of the Tiegelongnan giant porphyry system was associated with intermediate to acidic magma in the Early Cretaceous (~120 Ma). The magma provenance of the Tiegelongnan deposit has some mantle‐derived composition, possibly mixed with the crust‐derived materials.     

Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.     

From emplacement to unroofing: thermal history of the Jiazishan gabbro, Sulu UHP terrane, China

On the eastern extremity of the Jiaodong peninsula, China, shoshonitic magmas have been injected into the supracrustal rocks of the Sulu ultra-high pressure (UHP) terrane during the crustal exhumation phase. These granitoids (collectively termed the Shidao igneous complex or Jiazishan alkaline complex) show geochemical and isotopic signatures of an enriched subcontinental lithospheric mantle and intruded soon after the subducted Yangtze crust had reached peak metamorphic pressure conditions (240–220 Ma). We have applied various geochronometers to an alkali-gabbro sample from the Jiazishan pluton and the results allow reconstruction of the Triassic-to-present thermal history. Initial rapid cooling of the gabbro at crustal depths is indicated by the close agreement between the Sm-Nd mineral isochron age (228?±?36 Ma) and the Rb-Sr biotite age (207?±?1) Ma. This interpretation is confirmed by previously published U-Pb zircon ages (225–209 Ma), and ⁴⁰Ar/³⁹Ar amphibole and K-feldspar ages (～214 Ma) from the Jiazishan syenites. A titanite fission-track age of 166?±?8 Ma (closure temperature range 285–240°C) records widespread Jurassic magmatism in the Jiaodong peninsula, indicating that the gabbro reached upper crustal levels before it was reheated by nearby Jurassic plutons. A subsequent cooling and reheating event is indicated by an apatite fission-track age of 106?±?6 Ma which coincides with the emplacement of the adjacent Weideshan pluton (108?±?2 Ma) and postdates a period of regional lithospheric thinning beneath eastern China. A period of slow cooling (or thermal stability) from late Cretaceous to early Tertiary, documented by an apatite (U-Th)/He age of 39?±?5 Ma, was followed by a final stage of more enhanced cooling since the late Eocene. Results of this work imply that the eastern Sulu terrane has experienced a complex cooling and reheating history. Our data are consistent with a model of initial rapid cooling (sudden exhumation) of the UHP terrane, driven by the release of buoyancy forces, followed by two progressively slower cooling intervals (both after renewed crustal reheating) during the Jurassic and Cretaceous.     

Re–Os and U–Pb geochronology of porphyry Mo deposits in central Jilin Province: Mo ore-forming stages in northeast China

Central Jilin Province lies along the eastern edge of the Xing–Meng orogenic belt of northeast China. At least 10 Mo deposits have been discovered in this area, making it the second-richest concentration of Mo resources in China. To better understand the formation and distribution of porphyry Mo deposits in the area, we investigated the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of mineralization. Our new geochronological data show the following: the Jidetun Mo deposit yields molybdenite Re–Os model ages of 164.6–167.1 Ma, an isochron age of 168 ± 2.5 Ma, and a weighted mean model age of 165.9 ± 1.2 Ma; the Houdaomu Mo deposit yields molybdenite Re–Os model ages of 167.4–167.7 Ma, an isochron age of 168 ± 13 Ma, and a weighted mean model age of 167.5 ± 1.2 Ma; and the Chang’anpu Mo deposit yields a zircon U–Pb age for granodiorite porphyry of 166.9 ± 1.5 Ma (N = 16). These new age data, combined with existing molybdenite Re–Os dates, show that intense porphyry Mo mineralization was coeval with magmatism during the Middle Jurassic (167.8 ± 0.4 Ma, r > 0.999). The geotectonic mechanisms responsible for Mo mineralization were probably related to subduction of the Palaeo-Pacific plate beneath the Eurasian continent. Combining published molybdenite Re–Os and zircon U–Pb ages for northeast China, the Mo deposits are shown to have been formed during multiple events coinciding with periods of magmatic activity. We identified three phases of mineralization, two of which had several stages: the Caledonian (485–480 Ma); the Indosinian comprising the Early–Middle Triassic (248–236 Ma) and Late Triassic (226–208 Ma) stages; and the Yanshanian phase comprising the Early–Middle Jurassic (202–165 Ma), Late Jurassic–early Early Cretaceous (154–129 Ma), and Early Cretaceous (114–111 Ma) stages. Although Mo deposits formed during each phase/stage, most of the mineralization occurred during the Early–Middle Jurassic.     

A Triassic to Jurassic arc in north Borneo: Geochronology,geochemistry, and genesis of the Segama Valley Felsic Intrusions and the Sabah ophiolite

New field, geochemical, and geochronological data from the Segama Valley Felsic Intrusions (SVFI) of Sabah, north Borneo, shows them to be arc-derived tonalites; not windows or partial melts of a crystalline basement beneath Sabah. U-Pb zircon ages date emplacement in the Triassic and Jurassic: 241.1 ± 2.0 Ma, 250.7 ± 1.9 Ma, 178.7 ± 2.4 Ma, and 178.6 ± 1.3 Ma; contemporaneous with peaks in magmatism and detrital zircons in Sarawak and west Kalimantan (west Borneo). Isotopic data for Sr, Nd, and Pb from whole rocks, and for Hf and O from zircon all show mantle and/or MORB affinities indicating a mantle-derived origin. Enrichment of fluid mobile trace elements and trace element ratios indicate that the most likely setting for this is in a continuation of the Sundaland continental arc. There is no evidence in the field, geochemical, or zircon U-Pb data for continental basement in the Segama Valley region.The intrusive nature of the Segama Valley tonalites constrains the emplacement age of their supra-subduction zone host rocks to at least the Triassic. This new data expands the Triassic and Jurassic extent of Borneo and the Sundaland arc, and challenges models of Borneo's development predominantly through allochthonous terrane accretion in the Cretaceous. Instead, we propose a model of protracted autochthonous growth through supra-subduction zone crustal extension and associated magmatism.     

Two Periods of Skarn Mineralization in the Baizhangyan W–Mo Deposit,Southern Anhui Province,Southeast China: Evidence from Zircon U–Pb and Molybdenite Re–Os and Sulfur Isotope Data

The recently discovered Baizhangyan skarn‐porphyry type W–Mo deposit in southern Anhui Province in SE China occurs near the Middle–Lower Yangtze Valley polymetallic metallogenic belt. The deposit is closely temporally‐spatially associated with the Mesozoic Qingyang granitic complex composed of g ranodiorite, monzonitic g ranite, and alkaline g ranite. Orebodies of the deposit occur as horizons, veins, and lenses within the limestones of Sinian Lantian Formation contacting with buried fine‐grained granite, and diorite dykes. There are two types of W mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization. Among skarn mineralization, mineral assemblages and cross‐cutting relationships within both skarn ores and intrusions reveal two distinct periods of mineralization, i.e. the first W–Au period related to the intrusion of diorite dykes, and the subsequent W–Mo period related to the intrusion of the fine‐grained granite. In this paper, we report new zircon U–Pb and molybdenite Re–Os ages with the aim of constraining the relationships among the monzonitic granite, fine‐grained granite, diorite dykes, and W mineralization. Zircons of the monzonitic granite, the fine‐grained granite, and diorite dykes yield weighted mean U–Pb ages of 129.0 ± 1.2 Ma, 135.34 ± 0.92 Ma and 145.3 ± 1.7 Ma, respectively. Ten molybdenite Re–Os age determinations yield an isochron age of 136.9 ± 4.5 Ma and a weighted mean age of 135.0 ± 1.2 Ma. The molybdenites have δ³⁴S values of 3.6‰–6.6‰ and their Re contents ranging from 7.23 ppm to 15.23 ppm. A second group of two molybdenite samples yield ages of 143.8 ± 2.1 and 146.3 ± 2.0 Ma, containing Re concentrations of 50.5–50.9 ppm, and with δ³⁴S values of 1.6‰–4.8‰. The molybdenites from these two distinct groups of samples contain moderate concentrations of Re (7.23–50.48 ppm), suggesting that metals within the deposit have a mixed crust–mantle provenance. Field observation and new age and isotope data obtained in this study indicate that the first diorite dyke‐related skarn W–Au mineralization took place in the Early Cretaceous peaking at 143.0–146.3 Ma, and was associated with a mixed crust–mantle system. The second fine‐grained granite‐related skarn W–Mo mineralization took place a little later at 135.0–136.9 Ma, and was crust‐dominated. The fine‐grained granite was not formed by fractionation of the Qingyang monzonitic granite. This finding suggests that the first period of skarn W–Au mineralization in the Baizhangyan deposit resulted from interaction between basaltic magmas derived from the upper lithospheric mantle and crustal material at 143.0–146.3 and the subsequent period of W–Mo mineralization derived from the crust at 135.0–136.9 Ma.     

Refined age and geological context of two of Australia’s most important Jurassic vertebrate taxa (Rhoetosaurus brownei and Siderops kehli), Queensland

Australia’s Jurassic vertebrate fossil record remains extremely sparse with only two dinosaur taxa and two temnospondyl amphibians identified to date. Of these, the spectacular and extremely well-preserved giant amphibian, Siderops kehli, and the only known pre-Cretaceous sauropod in Australia, Rhoetosaurus brownei, are perhaps the most important. The age of both specimens, and the stratigraphic context of Rhoetosaurus brownei, are weakly constrained and imprecisely defined, limiting our understanding of their evolutionary relationships within a broader Gondwanan context. To clarify and contextualise the evolutionary relationships and ages of these two iconic Jurassic taxa, we used UPb detrital zircon geochronology to date the sandstone matrix from around the bones of the historic museum specimens. The robust maximum depositional age for Siderops was calculated at 176.6 Ma ± 2 Ma, indicating that it is no older than late Toarcian, which refines existing biostratigraphic estimates. The Rhoetosaurus maximum depositional age was determined to be 162.6 ± 1.1 Ma, no older than early Oxfordian, demonstrating that the fossils are younger than expected, and definitely recovered from the Walloon Coal Measures.     

Early Cretaceous A-type granites and Mo mineralization,Aershan area,eastern Inner Mongolia,Northeast China: geochemical and isotopic constraints

The Jiazishan porphyry-type molybdenum deposit is located in the eastern Inner Mongolia Autonomous Region in China. Mineralization occurs mainly as veins, lenses, and layers within the host porphyry. To better understand the link between mineralization and host igneous rocks, we studied samples from underground workings and report new SHRIMP II zircon U–Pb and Re–Os molybdenite ages, and geochemical data from both the molybdenites and the porphyry granites. Seven molybdenite samples yield a Re–Os isochron weighted mean age of 135.4 ± 2.1 Ma, whereas the porphyry granite samples yield crystallization ages of 139 ± 1.5 Ma (Jiazishan deposit) and 133 ± 1 Ma (Taolaituo deposit). The U–Pb and Re–Os ages are similar, suggesting that the mineralization is genetically related to Early Cretaceous porphyry emplacement. Re contents of the molybdenite range from 21.74 ppm to 52.08 ppm, with an average of 35.92 ppm, whereas δ³⁴ S values of the sulphide vary from 1.3‰ to 4.2‰. The ores have ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.178–18.385, 15.503–15.613, and 37.979–38.382, respectively. We also obtained a weighted mean U–Pb zircon age of 294.2 ± 2.1 Ma for the oldest granite in Jiazishan area. All granites are A-type granites. These observations indicate that the molybdenites and the porphyry granites were derived from a mixed source involving young accretionary materials and enriched subcontinental lithospheric mantle. A synthesis of geochronological and geological data reveals that porphyry emplacement and Mo mineralization in the Jiazishan deposit occurred contemporaneously with Early Cretaceous tectonothermal events associated with lithospheric thinning, which was caused by delamination and subsequent upwelling of the asthenosphere associated with intra-continental extension in Northeast China.