Hydrochemical study of groundwater in recharge area,Wadi Fatimah basin,Saudi Arabia

The present study deals with the hydrochemical characteristics of groundwater in the upper catchment of Wadi Fatimah basin. The analysis of data indicated strongly that the chloride and sulfate in the groundwater are mainly of marine origin, concentrated by high evaporation processes. Flushing is the most important factor that modifies the ionic concentrations and almost stands for the short-term variation in groundwater chemistry. Weathering reactions of the rock-forming minerals take place under relatively high P_CO2 condition in water and soil zone; it can be an important long-term neutralization process. It is accounted as a contributor for Ca and Mg ions in the groundwater. Using the chloride method the recharge rate has been estimated at 72 mm yr^–1.     

Hydrochemical classification and multivariate statistical analysis of groundwater from Wadi Sahba area in central Saudi Arabia

The central region of Saudi Arabia is underlain by thick sedimentary formations belonging to the Mesozoic and Cenozoic era. These sedimentary formations form a prolific aquifer supplying groundwater for agricultural and domestic usage in and around Riyadh. The region south of Riyadh City is well known for agricultural activities. Wadi Sahba, which is an eastward extension of Wadi Nisah, has readily available groundwater resources in the Cretaceous Biyadh sandstone aquifer to sustain agricultural activities. The objective of the present study was the hydrochemical assessment of groundwater in the area to understand the main hydrological processes which influence groundwater chemistry. To achieve this objective, 20 groundwater samples were collected from agricultural farms in the Wadi Sahba in central Saudi Arabia, and the major physiochemical constituents were analyzed and interpreted. The average TDS value of the analyzed samples is 1578.05 mg/l, whereas the average EC concentration is 3220.05 μS/cm. Groundwater facies classification inferred from the Piper plot shows that groundwater in the study area belongs to the Ca-SO₄-Cl type and Ca-Na-SO₄-Cl type. The Ca-SO₄-Cl type of groundwater facies is influenced mainly by gypsum dissolution and base ion exchange, whereas the Ca-Na-SO₄-Cl type is influenced by gypsum and halite dissolution. All the groundwater samples are undersaturated with respect to these two principal mineral phases. The Q-mode cluster analysis results in two main groups of groundwater samples, mainly based on the TDS content. Cluster 1 has an average TDS value of 1980 mg/l, whereas cluster 2 has an average TDS of 1176 mg/l. The groundwater facies identified through the Piper plot reflects the major hydrological processes controlling groundwater chemistry in the area and was found to be more useful in this study as compared to cluster analysis.     

Hydrogeology and hydrochemistry of a shallow alluvial aquifer,western Saudi Arabia

A hydrogeological and hydrochemical study was conducted on a shallow alluvial aquifer, Wadi Wajj, in western Saudi Arabia to assess the influence of protection measures on groundwater quality. The hydrochemistry was assessed up-gradient and down-gradient from potential contamination sources in the main city in dry and wet seasons prior to and after the installation of major drainage and wastewater facilities. Wadi Wajj is an unconfined aquifer where water is stored and transmitted through fractured and weathered bedrock and the overlying alluvial sediments. Natural recharge to the aquifer is about 5% of rainfall-runoff. Hydrochemistry of the aquifer shows temporal and seasonal changes as influenced by protection measures and rainfall runoff. Both groundwater and runoff showed similar chemical signature, which is mostly of chloride-sulfate-bicarbonate and sodium-calcium type. Groundwater downstream of the city, though of poorer quality than upstream, showed significant improvement after the installation of a concrete runoff tunnel and a wastewater treatment plant. Concentrations of many of the groundwater quality indicators (e.g., TDS, coliform bacteria, and nitrate) exceed US Environmental Protection Agency drinking-water standards. Heavy metal content is, however, within allowable limits by local and international standards. The chemical analyses also suggest the strong influence of stream runoff and sewage water on the groundwater quality.

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Résumé Une étude hydrogéologique et géochimique a été menée sur l’aquifère phréatique alluviale Wadi Wajj dans l’Ouest de l’Arabie Saoudite afin d’évaluer l’influence de mesures de protection sur la qualité de l’eau souterraine. L’hydrogéochimie de l’eau a été étudiée en amont et en aval de sources potentielles de contamination dans la ville principale, pendant les saisons sèches et humides, avant et après l’installation de réseaux majeurs de drainage et d’eaux usées. L’aquifère Wadi Wajj est libre, l’eau est stockée et s’écoule dans les sédiments alluviaux et dans le socle fracturé et altéré sous-jacent. La recharge naturelle de l’aquifère représente 5% des eaux de pluie et de ruissellement. L’hydrogéochimie de l’eau de l’aquifère montre que les changements saisonniers et temporaires sont influencés par les mesures de protection et par le ruissellement des eaux pluviales. L’eau souterraine et l’eau de ruissellement ont présenté le même faciès chimique, de type bicarbonatée-sulfatée-chlorée et calco-sodique. En aval de la ville, l’eau souterraine, bien que de moins bonne qualité qu’en amont, a présenté une nette amélioration après l’installation d’un système de récupération et d’une station de traitement des eaux usées. Les concentrations de plusieurs paramètres indicateurs de la qualité de l’eau (tels que la charge totale dissoute, les coliformes, et les nitrates) dépassent les normes de potabilité de l’eau de consommation de l’agence américaine de la protection de l’environnement. Les teneurs en métaux lourds en revanche n’excèdent pas les normes locales et internationales. Les analyses chimiques indiquent aussi l’influence importante de l’écoulement par ruissellement et des eaux usées sur la qualité de l’eau souterraine.

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Resumen Un estudio hidrogeológico e hidroquímico fue hecho en un acuífero somero de Wadi Wajj, en Arabia Saudi oeste para evaluar la influecia de medidas de protección en la calidad del agua subterránea. La hidroquímica fue evaluada gradiente-arriba y gradiente-abajo de las fuentes potenciales de contaminación de la ciudad principal durante las estaciones seca y lluviosa, antes y después de la instalación de sistemas principales de drenaje y aguas servidas. Wadi Wajj es un acuífero no-confinado donde el agua es almacenada y transmitida a través de roca fracturada y meteorizada, y los sedimentos aluviales que le sobreyacen. La recarga natural del acuífero es de cerca del 5% de la precipitación-escorrentía. La hidroquímica del acuífero muestra cambios temporales y estacionales influenciados por las medidas de protección y la escorrentía de precipitación. Ambas, agua subterránea y escorrentía mostraron composición química similar, siendo mayoritariamente de tipos cloruro-sulfato-bicarbonato y sodio-calcio. El agua subterránea aguas arriba de la ciudad, aunque de calidad más pobre que aguas abajo, mostró significante mejoría después de la instalación de un tunel de concreto para escorrentía y una planta de tratamiento de aguas servidas. Las concentraciones de muchos de los indicadores de calidad de agua subterránea (e.g., STD, coliformes, y nitrato) exceden los estándares de la Agencia de Protección Ambiental USA para agua potable. El contenido de metales pesados está, sin embargo, dentro de los límites permisibles de los estándares locales e internacionales. Los análisis químicos también sugieren la fuerte influencia de la escorrentía y aguas residuales en la calidad del agua subterránea.

     

Use of chloride-mass balance and environmental isotopes for evaluation of groundwater recharge in the alluvial aquifer, Wadi Tharad, western Saudi Arabia

Groundwater recharge estimation has become a priority issue for humid and arid regions, especially in regions like Saudi Arabia, where the precipitation varies over space and time as a result of topography and seasonality. Wadi Tharad is a typical arid area in western Saudi Arabia. Within its drainage area of 400 km², the groundwater system shows a graded hydrochemical zonation from the hydrocarbonate in the upper reach to the chloride zone in the lower reach. The saturation index (SI) varies depending on the concentrations of carbonate minerals; the mean for calcite and dolomite is about in equilibrium (e.g., zero value). As halite and gypsum indices are negative, it is undersaturated. Isotopic compositions of H and O in the groundwater show that the groundwater recharge resources are mainly from meteoric water. The chloride-mass balance method was refined to estimate the amount of recharge, which is probably 11% of the effective annual rainfall. These results can be used to improve the accuracy of future groundwater management and development schemes.     

Geochemistry and petrogenesis of a peralkaline granite complex from the Midian Mountains, Saudi Arabia

A zoned intrusion with a biotite granodiorite core and arfvedsonite granite rim represents the source magma for an albitised granite plug near its eastern margin and radioactive siliceous veins along its western margin. A study of selected REE and trace elements of samples from this complex reveals that the albitised granite plug has at least a tenfold enrichment in Zr, Hf, Nb, Ta, Y, Th, U and Sr, and a greatly enhanced heavy/light REE ratio compared with the peralkaline granite. The siliceous veins have even stronger enrichment of these trace elements, but a heavy/light REE ratio and negative eu anomaly similar to the peralkaline granite. It is suggested that the veins were formed from acidic volatile activity and the plug from a combination of highly fractionated magma and co-existing alkaline volatile phase. The granodiorite core intrudes the peralkaline granite and has similar trace element geochemistry. The peralkaline granite is probably derived from the partial melting of the lower crust in the presence of halide-rich volatiles, and the granodiorite from further partial melting under volatile-free conditions.     

Hydrochemical evaluation of the coastal Quaternary aquifer east of Tripoli, Libya

Chemical analyses of more than 80 water wells penetrating the first aquifer in the coastal areas east of Tripoli indicate three different hydrochemical facies. Sodium chloride type water is mainly related to the encroachment of sea water as a result of excessive abstraction. The chemical interaction between groundwater and the aquifer materials led to the formation of calcium bicarbonate type water. Calcium chloride type is developed when the intruded sea water, very rich in Na ions, forced through the aquifer materials, and part of these cations replaced the Ca at the exchange sites of the clay minerals.Plotted against chloride, the concentrations of the Na, K, Ca, Mg, sulphate and bicarbonate species deviate considerably from the ideal mixing curves of fresh groundwater and sea water. Sulphate and bicarbonate enrichments are strongly related to the oxidation of sulphides and dissolution of calcite minerals present in the aquifer materials. Sea water intrusion and reverse cation exchanges reactions are the most important phenomena in the chemical evolution of the salinised groundwater.     

Multivariate geostatistical methods of mean annual and seasonal rainfall in southwest Saudi Arabia

A multivariate geostatistics (cokriging) is used for regional analysis and prediction of rainfall throughout the southwest region of Saudi Arabia. Elevation is intruded as a covariant factor in order to bring topographic influences into the methodology. Sixty-three representative weather stations are selected for a 21-year period covering different microclimate conditions. Results show that on an annual basis, there is no significant change using elevation. On the seasonal basis, the cokriging method gave more information about rainfall occurrence values, its accuracy related to the degree of correlation between elevation and rainfall by season. The prediction of spring and winter rainfall was improved owing to the importance of orographic processes, while the summer season was not affected within its monsoon climatology. In addition, fall season shows inverse and weak correlation of elevation with rainfall. Cross-validation and cokriging variances are also used for more accuracy of rainfall regional estimation. Moreover, even though the correlation is not significant, the isohyet values of cokriged estimates provided more information on rainfall changes with elevation. Finally, adding more secondary variables in addition to elevation could improve the accuracy of cokriging estimates.     

A GIS approach for the assessment of groundwater quality in Wadi Rabigh aquifer,Saudi Arabia

A classification approach has been implemented in the present work by integrating traditional water sample analysis methods and Geographic Information System (GIS) capabilities in order to classify zones with acceptable groundwater quality for drinking. GIS extrapolation capabilities with their multi-conditional layering facilities were integrated together in order to assess in the determination of areas suitable for drinking purposes. This technique was implemented in Wadi Rabigh, Western Saudi Arabia, due to its significance as one of the most promising areas in the Western Province in the Kingdom of Saudi Arabia, owing to the establishment of King Abdullah Commercial City and King Abdullah University for Science and Technology (KAUST) nearby. Results show that only a limited area in the aquifer can be used for domestic purposes. This area is located in two separate patches in the upstream part of the aquifer while most of the aquifer water is categorized as brackish which might be used for agriculture purposes to a certain extent. The downstream area of the aquifer is very saline due to sea water intrusion effect.     

Hydrochemical assessment of groundwater from shallow aquifers in parts of Wadi Al Hamad,Madinah, Saudi Arabia

The present study was carried out in the Mulaylih area which forms a part of Wadi Al Hamad in the Madinah Province of Saudi Arabia. Thirty groundwater samples from agricultural farms were collected and analyzed for various physio-chemical parameters including trace elements. The area is occupied by the Quaternary alluvium deposits which form shallow unconfined aquifers. Evaporation and ion exchange are the major processes which control the major ion chemistry of the area. The extreme aridity has results in high total dissolved solid values (average of 9793.47 mg/l). Trace element concentrations are low and are mainly attributed to geogenic sources (silicate weathering). Na-Cl groundwater type is the main hydrochemical facies found in the area. The waters are found to be oversaturated with calcite/aragonite and dolomite. The average nitrate concentration was found to be 134.10 mg/l and is much higher than the WHO recommended limit of 50 mg/l in drinking water. Their high values are mainly associated with the application of N-fertilizers on the agricultural farms. The average fluoride concentration in the study was found to be 1.54 mg/l. The relation between F and Cl and Cl and Na reveals that the fluoride concentrations are mainly attributed to geogenic sources. A comparison of the groundwater quality with the Saudi drinking water standards shows that the water is unfit for drinking. The high salinity and sodicity of the groundwater make it unfit for irrigation. Principal component analysis resulted in extraction of four principal components accounting for 79.5% of the total data variability and supports the fact that the natural hydrochemical processes (evaporation and ion exchange) control the overall groundwater chemistry.     

A geological excursion in the Wadi Fatima area, near Jiddah, Saudi Arabia

Wadi Fatima, east of jiddah on the Red Sea coast of Saudi Arabia, is a microcosm of the geology of the jiddah area. Rocks ranging in age from 800-million-year-old metamorphic rocks to Tertiary lava flows are exposed, and illustrate the geological richness of western Saudi Arabia. The valley is a major south-west-trending fault zone that has been active since Precambrian times. A major Tertiary dyke swarm in the vicinity of Wadi Fatima is related to the opening of the Red Sea as the African-Arabian landmass split apart.     

Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.     

Groundwater management scenarios for the Biyadh-Wasia aquifer systems in the eastern part of Riyadh region,Saudi Arabia

Groundwater stored in the deep seated sedimentary aquifers is the most important source of water supply. The lack of sufficient groundwater recharge and the overdependence on groundwater might lead to unavailability of this precious natural resource if proper management practices are not adopted. Finite difference modelling using the MODFLOW program was carried out in the east of Riyadh city to simulate the groundwater level conditions under different abstraction scenarios. The simulated aquifer system combines the Wasia and Biyadh aquifer (composed of sandstone) and Aruma aquifer (limestone) which lies between 24°30'00"- 25°30'00" N and longitudes 47°00'00"- 48°00'00"E. The transmissivity and storage coefficient values of Biyadh aquifer are 7.0x10^-3 to 7.0x10^-2 m²/day and 3.7x10^-4 to 9.4x10^-4 respectively. The transmissivity and storage coefficient values of Wasia aquifer ranges from 6.7x10^-3 to 8.5x10^-2 m²/day and 2x10^-4 to 2.3x10^-4 respectively. The model calibration involved altering the values of model input parameters to match field conditions within certain acceptable limits to forecast the aquifer response over a period of 35 years (2015-2050). The modelling grid consisted of 20 and 24 columns with the grids spacing of 4 km for the small grids and 6 km for large grids. The results showed that though the Wasia aquifer was productive, it showed a large decline in water levels if water abstraction continued at the present rate. If the existing trends of groundwater withdraw continues; the piezometric heads in Wasia and Biyadh aquifers will decline by the year 2050. A reduction in 25% of the existing groundwater pumping rate in the well field will minimize the rate of groundwater decline in the aquifer to a considerable extent.     

Geophysical characteristics of Wadi Hanifah water system, Riyadh, Saudi Arabia

Integrated geophysical techniques including resistivity image, vertical electrical sounding (VES), and seismic refraction have been conducted to investigate the Wadi Hanifah water system. The groundwater in Wadi Hanifah has problems caused by the high volumes of sewage water percolating into the ground. The combination of VES, resistivity image, and seismic refraction has made a valuable contribution to the identification of the interface between the contaminated and fresh water in Wadi Hanifah area. The contaminated groundwater has lower resistivity values than fresh groundwater due to the higher concentration of ions which reduces the resistivity. Resistivity image and sounding in this area clearly identified the nature of the lithological depth and proved useful at identifying water-bearing zones. Fresh groundwater was found in the study area at a depth of 100 m within the fractured limestone. Water-bearing zones occur in two aquifers, shallow contaminated water at 10 m depth in alluvial deposits and the deeper fresh water aquifer at a depth of about 100 m in fractured limestone. The interface between the contaminated water (sanitary water) and fresh water marked out horizontally at 100 m distance from the main channel and vertically at 20 m depth.     

Assessment of several flood estimation methodologies in Makkah metropolitan area, Saudi Arabia

Estimation of floods in a hydrological basin is essential for efficient flood management and development planning. Several approaches have been proposed to estimate flood peak discharge based on topographic and morphometric characteristics of ungauged hydrological basins. Two global approaches, namely the rational and the curve number methods, along with four national regression models have been compared over Makkah metropolitan area, Saudi Arabia. The curve number methodology has been taken as the basis of comparison due to its precision and wide utilization. Results show that the rational method produces differences equal to 44% in terms of peak discharges. Moreover, the best national regression model gives difference in the order of 18% with respect to the curve number results. Other national models give results very far away from those of the curve number (up to 95%), which can be considered as measures for their awful accuracy. Hence, the curve number is recommended as an optimum methodology for flood estimation, in Makkah city, in case of availability of geological, metrological, land use, and topographic datasets. Otherwise, a specific national regression model (Al-Subai) may be utilized in a simple way.     

柴达木盆地大柴旦地区地下水水化学特征及演化规律

地下水在干旱/半干旱地区的生态环境保护中起着主导作用.柴达木盆地北缘的大柴旦湖地处西北干旱区,其生态环境较为脆弱,了解该地区的地下水水化学演化特征,对这一生态敏感地区的地下水可持续利用至关重要.本研究通过采集该地区28个具有代表性的水样,运用数理统计、Piper图、Gibbs图、离子比值、饱和指数和反向水文地球化学模拟...