Hydrated minerals in the deposits of Aureum Chaos

Hydrated minerals have been detected in many martian chaos regions and chasmata, playing a major role in its past aqueous activity. Based on short wave infrared data from CRISM, imagery and elevation data, we identified and mapped hydrated minerals in Aureum Chaos to shed light on their stratigraphy and geological context.The Interior Layered Deposits (ILDs) display three stratigraphic units: The lowest unit shows massive and also layered, high-albedo monohydrated sulfate (MHS, best matching kieserite; 20–650 m thick) with intercalated hydroxylated ferric sulfates (HFSs, best matching jarosite) and ferric oxides. The overlying polyhydrated sulfate (PHS) is commonly layered (20–40 m thick), smooth to heavily fractured, of lower albedo and partially contains ferric oxides. Spectrally neutral, distinctly layered, and bumpy cap rock (40–300 m thick) forms the top.We found spectral and morphological similarities to Aram Chaos (PHS, MHS, ferric oxides; texture of ILD and cap rock) and Juventae Chasma (HFS). Besides, the phyllosilicate nontronite was found attributed to chaotic terrain as light toned fractured exposure and within dark, smooth mantling. The coexistence of sulfates and phyllosilicates indicates changes in the geochemistry of the aqueous environment.Since sulfates and phyllosilicates could be alteration products, the observed mineralogy presumably is not the original; conversions between PHS and MHS, MHS or PHS into jarosite, jarosite into iron oxides are considered. Due to its occurrence along mantling edges and on flat surfaces of MHS without textural differences, it appears that PHS is an alteration product of MHS, e.g. due to surface exposure. The facies and relative timing of sulfate formation remains undefined. However, two different formation models are considered. The first implies contemporaneous ILD and PHS deposition and diagenetic sulfate conversion (into MHS, iron oxides) due to overburden later on. This model is less conclusive than groundwater evaporation -the second model- due to the lack of a sharp PHS–MHS boundary that would indicate a diagenetic formation.Alternatively, the second model suggests subsequent sulfate formation. Groundwater would have penetrated into pre-existing sulfate-free ILD. The permeability and porosity of ILD material would have defined the rate of water absorption and sulfate precipitation (low in cap rock?), resulting in cementation of probably aeolian deposited ILDs. We think this model is more consistent and could explain ILD stratigraphy with the potential anhydrous cap rock on top.The surface age of chaotic terrain (late Hesperian) and mantling deposits (mid to late Amazonian) limit the ILD age and possibly the emplacement of sulfates. Phyllosilicates in the mantling are presumably allochthonous. Limiting the timing of in situ phyllosilicates is more complicated; they could be Noachian (excavated material, following the phyllosian era), or instead syn- or post-chaotic. A close spatial and temporal association of sulfates and phyllosilicates, in which nontronite represents the deep facies, and sulfates the evaporitic facies is known from Earth and is also possible and would combine groundwater alteration with the observed mineralogy.The preservation of nontronite, HFS and MHS probably reflects a relatively dry environment with intermittent aqueous activity since their emplacement.     

Mineralogy of Terra Meridiani and western Arabia Terra from OMEGA/MEx and implications for their formation

Analyses of Mars Express OMEGA hyperspectral data (0.4-2.7 μm) for Terra Meridiani and western Arabia Terra show that the northern mantled cratered terrains are covered by dust that is spectrally dominated by nanophase ferric oxides. Dark aeolian dunes inside craters and dark streaks extending from the dunes into the intercrater areas in mantled cratered terrains in western Arabia Terra have similar pyroxene-rich signatures demonstrating that the dunes supply dark basaltic material to create dark streaks. The dissected cratered terrains to the south of the mantled terrains are dominated spectrally by both low-calcium and high-calcium pyroxenes with abundances of 20-30% each retrieved from nonlinear radiative transfer modeling. Spectra over the hematite-bearing plains in Meridiani Planum are characterized by very weak but unique spectral features attributed to a mixture of a dark and featureless component (possibly gray hematite) and minor olivine in some locations. Hydrated minerals (likely hydrous ferric sulfates and/or hydrous hydroxides) associated with poorly ferric crystalline phases are found in the etched terrains to the north and east of the hematite-bearing plains where erosion has exposed ∼1 km of section of layered outcrops with high thermal inertias. These materials are also found in numerous craters in the northern Terra Meridiani and may represent outliers of the etched terrain materials. A few localized spots within the etched terrain also exhibit the spectral signature of Fe-rich phyllosilicates. The ensemble of observations show that the evidence for aqueous processes detected by the Opportunity Rover in Meridiani Planum is widespread and confirms the extended presence of surface or near-surface water over this large region of Mars. The scenarios of formation of Terra Meridiani (“dirty” acidic evaporite, impact surge or weathering of volcanic ash) cannot satisfactorily explain the mineralogy derived from the OMEGA observations. The formation of the etched terrains is consistent with leaching of iron sulfides and formation of sulfates and hydrated iron oxides, either in-place or via transport and evaporation of aqueous fluids and under aqueous conditions less acidic than inferred from rocks examined by Opportunity.     

The nature of coarse-grained crystalline hematite and its implications for the early environment of Mars

The Thermal Emission Spectrometer (TES) on the Mars Global Surveyor spacecraft has detected deposits of coarse-grained, gray crystalline hematite in Sinus Meridiani, Aram Chaos, and Vallis Marineris. We argue that the key to the origin of gray hematite is that it requires crystallization at temperatures in excess of about 100 °C. We discuss thermal crystallization (1) as diagenesis at a depth of a few kilometers of sediments originally formed in low-temperature waters, or (2) as precipitation from hydrothermal solution. In Aram Chaos, a combination of TES data, Mars Orbiter Camera images, and Mars Orbiter Laser Altimeter (MOLA) topography suggests that high concentrations of hematite were formed in planar strata and have since been exposed by erosion of an overlying light-toned, caprock. Lesser concentrations of hematite are found adjacent to these strata at lower elevations, which we interpret as perhaps due to accumulation from physical weathering. The topography and the collapsed nature of the chaotic terrain favor a hydrothermally charged aquifer as the original setting where the hematite formed. Concentration of iron into such an ore-like body would be chemically favored by saline, Cl-rich hydrothermal fluids. An alternative sedimentary origin requires post-depositional burial to a depth of ∼3-5 km to induce thermally driven recrystallization of fine-grained iron oxides to coarse-grained hematite. This depth of burial and re-exposure is difficult to reconcile with commonly inferred martian geological processes. However, shallow burial accompanied by post-burial hydrothermal activity remains plausible. When the hematite regions originally formed, redox balance requires that much hydrogen must have been evolved to complement the extensive oxidation. Finally, we suggest that the coexistence of several factors required to form the gray hematite deposits would have produced a favorable environment for primitive life on early Mars, if it ever existed. These factors include liquid water, abundant electron donors in the form of H₂, and abundant electron acceptors in the form of Fe³⁺.     

Sulfates and iron oxides in Ophir Chasma, Mars, based on OMEGA and CRISM observations

We investigate the sulfate and iron oxide deposits in Ophir Chasma, Mars, based on short-wave infrared data from the Compact Reconnaissance Imaging Spectrometer for Mars - CRISM and from the Observatoire pour la Minéralogie, l’Eau, les Glaces et l’Activité - OMEGA. Sulfates are detected mainly in two locations. In the valley between Ophir Mensa and the southern wall of Ophir Chasma, kieserite is found both within the slope of Ophir Mensa, and superposed on the basaltic wall of the chasm. Here, kieserite is unconformably overlain by polyhydrated sulfate deposits and iron oxides. Locally, jarosite and unidentified phases with absorptions at 2.21 μm or 2.23 μm are detected, which could be mixtures of jarosite and amorphous silica or other poorly crystalline phases.The second large sulfate-rich outcrop is found on the floor of the central valley. Although the same minerals are found here, polyhydrated sulfates, kieserite, iron oxides, and locally a possibly jarosite-bearing phase, this deposit is very distinct. It is not layered, almost horizontal, and located at a much lower elevation of below −4250 m. Kieserite superposes polyhydrated sulfate-rich deposits, and iron oxides form lags.The facies of sulfate formation remains unclear, and could be different for the two locations. A formation in a lake, playa or under a glacier is consistent with the mineralogy of the central valley and its flat, low-lying topography. This is not conceivable for the kieserite deposits observed south of Ophir Mensa. These deposits are observed over several thousands of meters of elevation, which would require a standing body of water several thousands of meters deep. This would have lead to much more pervasive sulfate deposits than observed. These deposits are therefore more consistent with evaporation of groundwater infiltrating into previously sulfate-free light-toned deposits. The overlying polyhydrated sulfates and other mineral phases are observed in outcrops on ridges along the slopes of the southern chasm wall, which are too exposed to be reached by groundwater. Here, a water supply from the atmosphere by rain, snow, fog or frost is more conceivable.     

Diagenetic haematite and sulfate assemblages in Valles Marineris

Previous orbital mapping of crystalline gray haematite, ferric oxides, and sulfates has shown an association of this mineralogy with light-toned, layered deposits on the floor of Valles Marineris, in chaos terrains in the canyon’s outflow channels, and in Meridiani Planum. The exact nature of the relationship between ferric oxides and sulfates within Valles Marineris is uncertain. The Observatoire pour la Mineralogie, l’Eau, les Glaces et l’Activite (OMEGA) spectrometer initially identified sulfate and ferric oxides in the layered deposits of Valles Marineris. The Thermal Emission Spectrometer (TES) has also mapped coarse (gray) haematite in or at the base of these deposits. We use Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) spectra and Context Camera (CTX) and High Resolution Imaging Science Experiment (HiRISE) imagery from the Mars Reconnaissance Orbiter (MRO) to explore the mineralogy and morphology of the large layered deposit in central Capri Chasma, part of the Valles Marineris canyon system that has large, clear exposures of sulfate and haematite. We find kieserite (MgSO₄·H₂O) and ferric oxide (often crystalline red haematite) in the lower bedrock exposures and a polyhydrated sulfate without ferric oxides in the upper bedrock. This stratigraphy is duplicated in many other basinal chasmata, suggesting a common genesis. We propose the haematite and monohydrated sulfate formed by diagenetic alteration of a sulfate-rich sedimentary deposit, where the upper polyhydrated sulfate-rich, haematite-poor layers either were not buried sufficiently to convert to a monohydrated sulfate or were part of a later depositional phase. Based on the similarities between the Valles Marineris assemblages and the sulfate and haematite-rich deposits of Meridiani Planum, we hypothesize a common evaporite and diagenetic formation process for the Meridiani Planum sediments and the sulfate-bearing basinal Interior Layered Deposits.     

Light-toned layered deposits in Juventae Chasma, Mars

We examine hypotheses for the formation of light-toned layered deposits in Juventae Chasma using a combination of data from Mars Global Surveyor's Mars Orbiter Camera (MOC), Mars Orbiter Laser Altimeter (MOLA), and Thermal Emission Spectrometer (TES), as well as Mars Odyssey's Thermal Emission Imaging System (THEMIS). We divide Juventae Chasma into geomorphic units of (i) chasm wall rock, (ii) heavily cratered hummocky terrain, (iii) a mobile and largely crater-free sand sheet on the chasm floor, (iv) light-toned layered outcrop (LLO) material, and (v) chaotic terrain. Using surface temperatures derived from THEMIS infrared data and slopes from MOLA, we derive maps of thermal inertia, which are consistent with the geomorphic units that we identify. LLO thermal inertias range from ∼400 to 850 J m⁻² K⁻¹ s^−1/2. Light-toned layered outcrops are distributed over a remarkably wide elevation range () from the chasm floor to the adjacent plateau surface. Geomorphic features, the absence of small craters, and high thermal inertia show that the LLOs are composed of sedimentary rock that is eroding relatively rapidly in the present epoch. We also present evidence for exhumation of LLO material from the west wall of the chasm, within chaotic and hummocky terrains, and within a small depression in the adjacent plateau. The data imply that at least some of the LLO material was deposited long before the adjacent Hesperian plateau basalts, and that Juventae Chasma underwent, and may still be undergoing, enlargement along its west wall due to wall rock collapse, chaotic terrain evolution, and exposure and removal of LLO material. The new data allow us to reassess possible origins of the LLOs. Gypsum, one of the minerals reported elsewhere as found in Juventae Chasma LLO material, forms only at low temperatures () and thus excludes a volcanic origin. Instead, the data are consistent with either multiple occurrences of lacustrine or airfall deposition over an extended period of time prior to emplacement of Hesperian lava flows on the plateau above the chasm.     

Silica-rich deposits and hydrated minerals at Gusev Crater, Mars: Vis-NIR spectral characterization and regional mapping

The Mars Exploration Rover (MER) Spirit has discovered surprisingly high concentrations of amorphous silica in soil and nodular outcrops in the Inner Basin of the Columbia Hills. In Pancam multispectral observations, we find that an absorption feature at the longest Pancam wavelength (1009 nm) appears to be characteristic of these silica-rich materials; however, spectral analyses of amorphous silica suggest that the ∼1009 nm spectral feature is not a direct reflection of their silica-rich nature. Based on comparisons with spectral databases, we hypothesize that the presence of H₂O or OH, either free (as water ice), adsorbed or bound in a mineral structure, is responsible for the spectral feature observed by Pancam. The Gertrude Weise soil, which is nearly pure opaline silica, may have adsorbed water cold-trapped on mineral grains. The origin of the ∼1009 nm Pancam feature observed in the silica-rich nodular outcrops may result from the presence of additional hydrated minerals (specific sulfates, halides, chlorides, sodium silicates, carbonates or borates). Using the ∼1009 nm feature with other spectral parameters as a “hydration signature” we have mapped the occurrence of hydrated materials along the extent of Spirit’s traverse across the Columbia Hills from West Spur to Home Plate (sols 155-1696). We have also mapped this hydration signature across large panoramic images to understand the regional distribution of materials that are spectrally similar to the silica-rich soil and nodular outcrops. Our results suggest that hydrated materials are common in the Columbia Hills.     

Early Mars may have had a methanol ocean

The detection of gray crystalline hematite deposits on Mars by Thermal Emission Spectrometer (TES) has been used to argue for the presence of liquid water on Mars in the distant past. By methanol-thermal treatment of anhydrous FeCl₃ at low temperatures (70-160 °C), crystalline gray hematite with layered structure was synthesized, based on this result an alternative explanation for the origin of martian hematite deposits is suggested. Methane could be abundant in the early martian atmosphere; process such as photochemical oxidation of methane could result in the formation of ocean or pool of organic compounds such as methanol, which provides an environment for the formation of large-scale hematite deposits on Mars.     

Spectral and geological study of the sulfate-rich region of West Candor Chasma, Mars

Sulfates have been discovered by the OMEGA spectrometer in different locations of the planet Mars. They are strongly correlated to light toned layered deposits in the equatorial regions. West Candor Chasma is the canyon with the thickest stack of layers and one with the largest area covered by sulfates. A detailed study coupling mineralogy derived from OMEGA spectral data and geology derived from HRSC imager and other datasets leads to some straightforward issues. The monohydrated sulfate kieserite is found mainly over heavily eroded scarps of light toned material. It likely corresponds to a mineral present in the initial rock formed either during formation and diagenesis of sediments, or during hydrothermal alteration at depth, because it is typically found on outcrops that are eroded and steep. Polyhydrated sulfates, that match any Ca-, Na-, Fe-, or Mg-sulfates with more than one water molecule, are preferentially present on less eroded and darker outcrops than outcrops of kieserite. These variations can be the result of a diversity in the composition and/or of the rehydration of kieserite on surfaces with longer exposure. The latter possibility of rehydration in the current, or recent, atmosphere suggests the low surface temperatures preserve sulfates from desiccation, and, also can rehydrate part of them. Strong signatures of iron oxides are present on sulfate-rich scarps and at the base of layered deposits scarps. They are correlated with TES gray hematite signature and might correspond to iron oxides present in the rock as sand-size grains, or possibly larger concretions, that are eroded and transported down by gravity at the base of the scarp. Pyroxenes are present mainly on sand dunes in the low lying terrains. Pyroxene is strongly depleted or absent in the layered deposits. When mixed with kieserite, local observations favor a spatial mixing with dunes over layered deposits. Sulfates such as those detected in the studied area require the presence of liquid water to form by precipitation, either in an intermittent lacustrine environment or by hydrothermal fluid circulation. Both possibilities require the presence of sulfur-rich groundwater to explain fluid circulation. The elevation of the uppermost sulfate signatures suggests the presence of aquifers up to 2.5 km above datum, only 1 km below the plateau surface.     

Keys to gully formation processes on Mars: Relation to climate cycles and sources of meltwater

Advances in dating gullies on Mars using superposition relationships and a stratigraphic marker horizon link gully chronostratigraphy to recent climate cycles. New observations of gully morphology show the close association of gully source regions, channels, and fan deposits with well-documented ice-rich latitude-dependent mantle deposits, the deposition of which is interpreted to be coincident with recent ice ages. On the basis of these close correlations, we interpret the formative processes for mid-latitude gullies to involve melting of these ice-rich mantling deposits and the generation of an aqueous phase leading to fluvial activity. Continued monitoring of gullies by spacecraft in the current “interglacial” climate period (∼0.4 Ma to the present) will permit assessment of changing rates and styles of gully activity in the now largely depleted source areas.     

Fresnel modeling of hematite crystal surfaces and application to martian hematite spherules

The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm⁻¹ feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm⁻¹ feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.     

Spectral and thermodynamic constraints on the existence of gypsum at the Juventae Chasma on Mars

The spectral imaging of the Mars obtained with the Mars Express/OMEGA experiment demonstrates that a majority of the sulfates-rich regions are associated with the interior light-toned layered deposits within the canyon system in the equatorial zone of the planet. While all sulfates-rich deposits inside the canyons are characterized by the presence of the kieserite and hydrated magnesium sulfates, the spectral features of gypsum were detected only in the Juventae Chasma and the Iani Chaos. The detection of gypsum in the upper part of the layered deposits, stacking the erosional remnant on the floor of the Juventae Chasma (above the spectral signature of the kieserite and polyhydrated sulfates detected on the flanks of the remnant) represents a more intriguing case. To clarify the question of the presence of gypsum in the Juventae Chasma, we present reanalyzed OMEGA spectra within that area and performed the chemical equilibrium modelling of sulfates precipitation sequence at the freezing and the evaporation of a hypothetical aqueous solution which could have existed within the Chasma in the past. Our results did not confirm the presence of distinct spectral signatures of gypsum. The results of equilibrium modelling also exclude significant precipitation of gypsum during the latest stage of the aqueous sedimentation, responsible for the formation of the upper part of the erosional remnant.     

A new hematite formation mechanism for Mars

Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al₂O₃) oxidized at high (700 and 900 °C) temperatures in air and CO₂, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe²⁺ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.     

Pits and uplifts on Europa

A survey of depression and uplift features on Europa, based on Galileo regional mapping images, shows that these features come in a wide range of sizes, with numbers increasing greatly with decreasing size, down to the limits of resolution. Size distributions are similar in the northern leading and southern trailing hemispheres, where they are distinctly different from the southern leading and northern trailing hemispheres, suggesting an oblique, antipodal symmetry pattern, similar to that of chaotic and tectonic terrain. This pattern is suggestive of polar wander. Uplifts are usually polygonal or irregular in shape and rarely are cracked. Patches of chaotic terrain, which we had surveyed earlier, are not included in the current study because their topography is generally unclear, and because there is no a priori known genetic linkage with the pits and uplifts.These results contradict generalizations based on the earlier “pits, spots, and domes” (PSD) taxonomy. Most of the type examples for PSDs were simply patches of chaotic terrain selected from a limited portion of their full size range. The use of the term lenticula to collectively describe PSDs is inconsistent with the IAU definition of lenticula: a small dark spot seen at low resolution. Pits and uplifts do not correlate with lenticulae, although chaos often does. Properties of PSDs that have been widely cited as primary evidence for convective upwelling in thick ice (e.g., that uplifts are generally dome-shaped and often cracked; that pits and domes are regularly spaced; that there is a typical diameter of ∼10 km) were premature and not supported by subsequent data. Most pits and uplifts are less than 10 km across so, if they formed by diapirism or convective upwelling, the sources must have been very shallow, less than 5 km deep. How they actually formed remains unknown.     

Geomorphological characterisation and interpretation of a mid-latitude glacier-like form: Hellas Planitia, Mars

We describe and interpret the surface terrain types associated with a widely-reported ∼4 km long, mid-latitude martian viscous flow feature (VFF). The feature is located in the southern hemisphere, on the poleward-facing rim of a ∼60 km-diameter crater in eastern Hellas Planitia. High Resolution Imaging Science Experiment (HiRISE) images, analysed in both 2D and 3D, reveal that the upper margin of the feature is bounded by steep (∼30°) headwalls, typically some tens of metres high, that are formed from unconsolidated material and characterised by a series of slope-parallel linear incisions. Below these incised headwalls, the feature flows at a general angle of ∼10° from a broad upper basin to a confined lower tongue that is bounded by a nested sequence of elongate raised ridges. These characteristics are typical of several VFFs in the region and are strikingly similar to moraine-bounded valley glaciers on Earth, and we sub-classify this feature as a ‘glacier-like form’ (GLF)¹. The GLF comprises five distinctive surface terrain types that contrast sharply with surface characteristics outside its bounding moraines. Four of these terrains (scaly terrain, polygonized terrain, linear terrain and mound-and-tail terrain) are located within the GLF’s innermost bounding moraine, while the fifth (rectilinear-ridge terrain) is located between its frontal moraines. These terrains are mapped, characterised and associated with possible mechanisms of formation to draw inferences about the GLF’s glaciology and glacial history. This analysis suggests that the GLF reached its maximal extent in the geologically-recent past, and that it may have been partially wet-based at that time. Subsequent to this phase, the GLF experienced an extended period of general recession that has been punctuated by several episodes of still-stand or advance. Currently, the GLF’s basin appears to be composed of a lower zone that is dominated by an exposed former glacier bed and an upper zone that may still contain a now-degraded and dust-mantled viscous mass, similar to many partially-glacierized basins on Earth.     

Remote sensing of lunar pyroclastic mantling deposits

Mantling deposits on the Moon are considered to be pyroclastic units emplaced on the lunar surface as a result of explosive fire fountaining. These pyroclastic units are characterized as having low albedos, having smooth fine-textured surfaces, and consisting in part of homogeneous, Febearing volcanic glass and partially crystallized spheres. Mantling units exhibit low returns on depolarized 3.8-cm radar maps, indicating an absence of surface scatterers in the 1- to 50-cm-size range. A number of reflectance spectra from several regional pyroclastic deposits are presented for the first time; these data support a previous interpretation that mantling units have a unique spectral signature which is indicative of the presence of a significant Fe-bearing volcanic glass component. The Rima Bode region is discussed as an example of an area in which several types of remote sensing data (including 3.8-cm radar, spectral reflectance, and multispectral vidicon data) were used to reconstruct the geologic events surrounding the emplacement of a regional pyroclastic mantling deposit. The recognition of numerous varieties of volcanic glass samples, especially relatively high-albedo (e.g., green, yellow) glasses, suggests the existence of additional, unrecognized mantling deposits with albedos higher than those studied to date. On the basis of the remote sensing data summarized and presented, five new areas have been identified which may represent higher-albedo regional pyroclastic deposits.     

Mineralogical characterization of Mars Science Laboratory candidate landing sites from THEMIS and TES data

Data from the Mars Global Surveyor Thermal Emission Spectrometer (TES) and the Mars Odyssey Thermal Emission Imaging System (THEMIS) instruments are used to assess the mineralogic and dust cover characteristics of landing regions proposed for the Mars Science Laboratory (MSL) mission. Candidate regions examined in this study are Eberswalde crater, Gale crater, Holden crater, Mawrth Vallis, Miyamoto crater, Nili Fossae Trough, and south Meridiani Planum. Compositional units identified in each region from TES and THEMIS data are distinguished by variations in hematite, olivine, pyroxene and high-silica phase abundance, whereas no units are distinguished by elevated phyllosilicate or sulfate abundance. Though phyllosilicate minerals have been identified in all sites using near-infrared observations, these minerals are not unambiguously detected using either TES spectral index or deconvolution analysis methods. For some of the sites, small phyllosilicate outcrop sizes relative to the TES field of view likely hinder phyllosilicate mineral detection. Porous texture and/or small particle size (<∼60 μm) associated with the phyllosilicate-bearing surfaces may also contribute to non-detections in the thermal infrared data sets, in some areas. However, in Mawrth Vallis and Nili Fossae, low phyllosilicate abundance (<10-20 areal %, depending on the phyllosilicate composition) is the most likely explanation for non-detection. TES data over Mawrth Vallis indicate that phyllosilicate-bearing surfaces also contain significant concentrations (>15%, possibly up to ∼40%) of a high-silica phase such as amorphous silica or zeolite. High-silica phase abundance over phyllosilicate-bearing surfaces in Mawrth Vallis is higher than that of surrounding surfaces by 10-15%. With the exception of these high-silica surfaces in Mawrth Vallis, regions examined in this study exhibit similar bulk mineralogical compositions to that of most low-albedo regions on Mars; the MSL scientific payload will thus be able to provide important information on surface materials typical of low-albedo regions in addition to investigating the origin of phyllosilicate and/or sulfate deposits. With the exception of Gale crater, all of the landing sites have relatively low dust cover compared to classic high-albedo regions (Tharsis, Arabia and Elysium) and to previous landing sites in Gusev Crater, Utopia Planitia, and Chryse Planitia.     

Shallow depth extent of the Lesutoskraal granophyre dike in the Vredefort impact structure: Geophysical surveys and trenching data

Recent observations and geophysical studies at the Vredefort impact structure have indicated that the impact melt dikes in the central uplift of the structure have small depth extents. In this study, we performed magnetic and electrical resistivity tomography (ERT) surveys of the Lesutoskraal granophyre dike (LGD) and trenched to confirm its depth extent. The ERT survey showed that outcrops of the LGD are associated with shallow resistive zones with <3 m depth extent, but such zones do not occur where outcrops are absent. Visual observations in the trench confirmed that the dike has a small depth extent (~0.75 m) at this location. However, the magnetic survey revealed anomalies along the entire strike of the dike, even where no outcrops occur. We suggest that remagnetization of the host rock within a metamorphic contact aureole could explain the presence of magnetic anomalies in the absence of outcrops. Considering the results of the ERT survey, the observations made in the trench, and the surface distribution of outcrops of the LGD, we confirm that this dike has a small depth extent (<3 m) along its entire length and propose that outcrops represent the intersection of the dike terminus with the current erosional surface.     

Two geologic systems providing terrestrial analogues for the exploration of sulfate deposits on Mars: Initial spectral characterization

We present the Messinian evaporite suite (Mediterranean region) and the Solfatara hydrothermal system (Phlegraean Fields volcanic province, Italy), discuss their implications for understanding the origin of sulfates on Mars and show preliminary sets of VNIR laboratory and in situ reflectance spectra of rocks from these geologic systems. The choice was based on a number of evidence relative to Mars: (1) the chemistry of the Martian sulfates, suggesting fluid interactions with possibly alkali-basaltic rocks and/or regolith; (2) close range evidence of sulfates within sedimentary formations on Mars; (3) sulfate spectral signatures associated to large-scale layered patterns interpreted as thick depositional systems on Mars. The Messinian evaporites comprise three units: primary shallow-water sulfates (primary lower gypsum: PLG), shallow- to deep-water mixed sulfates and clastic terrigenous deposits (resedimented lower gypsum: RLG), and shallow-water associations of primary sulfates and clastic fluvio-deltaic deposits (upper evaporites: UE). The onset of the Messinian evaporites records the transition to negative hydrologic budget conditions associated with the Messinian Salinity Crisis, which affected the entire Mediterranean basin and lasted about 640 kyr. The Solfatara is a still evolving hydrothermal system that provides epithermal deposits precipitated from the interaction of fluids and trachybasaltic to phonolitic rocks. Thermal waters include alkali-chloride, alkali-carbonate and alkali-sulfate endmembers.The wide spectrum of sedimentary gypsum facies within the Messinian formation includes some of the depositional environments hitherto identified on Mars and others not found on Mars. The PLG unit includes facies associations correlated over long distances, that could be a possible analog of the stratified rock units exposed from Arabia Terra at least as far as Valles Marineris. The facies cycles within the UE unit can be compared to the sequences of strata observed in craters such as Holden and Eberswalden. The UE unit records paleoenvironmental changes which are ultimately controlled by terrestrial climatic variations. They can be considered as a reliable climatic proxy and may be useful for the reconstruction of climatic events on Mars. The intermediate Messinian RLG unit has not, at present, a well-defined depositional counterpart on Mars, although there are some similarities with the northern lowlands and Vastitas Borealis Formation. The dramatic variation of hydrologic budget conditions at the onset of the Messinian evaporites may provide criteria for the interpretation of similar variations on Mars.The volcanic rocks at the Solfatara bear some similarities with the “alkaline magmatic province” observed at the Gusev crater on Mars, and the assemblages of hydrothermal phases resulting from the Solfatara's parent rocks could be analogues for processes involving Gusev-type rocks.The Messinian sulfates have a prevalent Ca-sulfatic composition and wide textural variability. Preliminary laboratory reflectance spectra of rock samples in the VNIR region reveal the signature of sulfates and mixtures of several Fe-bearing phases. At the Solfatara, in situ reflectance measurements of epithermal minerals close to active fumaroles showed the presence of Fe-bearing sulfates, hematite, Al- and K-sulfates and abundant amorphous fraction. XRD analysis supported this interpretation.The range of depositional facies observed in the Messinian units and the variety of minerals detected in the Solfatara will be useful for the interpretation of close range data of Mars. The spectral characterization at various scales of the Messinian sedimentary facies and the Solfatara hydrothermal minerals will both help in the exploration of Mars from orbit and with close range inspection.     

A systematic spectroscopic study of eight hydrous ferric sulfates relevant to Mars

Ferric sulfates were observed on Mars during orbital remote sensing and surface explorations. These observations have stimulated our systematic experimental investigation on the formative conditions, stability fields, phase boundaries, and phase transition pathways of these important minerals. We report here the results from the first step of this project: eight synthesized anhydrous and hydrous crystalline ferric sulfates and their structural characters reflected through spectroscopic studies. A few phenomena observed during the 150 sets of on-going experiments for stability field study are also reported, which reveal the structural distortions that can happen under environmental conditions relevant to Mars.