Zircon ages and Hf isotopic compositions of plutonic rocks from the Central Tianshan (Xinjiang,northwest China) and their significance for early to mid-Palaeozoic crustal evolution

We present new zircon ages and Hf-in-zircon isotopic data for plutonic rocks and review the crustal evolution of the Chinese Central Tianshan (Xinjiang, northwest China) in the early to mid-Palaeozoic. The Early Ordovician (ca. 475–473 Ma) granitoid rocks have zircon ε_Hf(t) values either positive (+0.3 to +9.5) or negative (?6.0 to ?12.9). This suggests significant addition of juvenile material to, and coeval crustal reworking of, the pre-existing continental crust that is fingerprinted by numerous Precambrian zircon xenocrysts. The Late Ordovician–Silurian (ca. 458–425 Ma) rocks can be assigned to two sub-episodes of magmatism: zircon from rocks of an earlier event (ca. 458–442 Ma) has negative zircon ε_Hf(t) values (?6.3 to ?13.1), indicating a predominantly crustal source; zircon from later events (ca. 434–425 Ma) has positive zircon ε_Hf(t) values (+2.6 to +8.9) that reveal a predominantly juvenile magma source. The Early Devonian (ca. 410–404 Ma) rocks have near-zero zircon ε_Hf(t) values, either slightly negative or positive (?1.4 to +3.5), whereas the Mid-Devonian rocks (ca. 393 Ma) have negative values (?11.2 to ?14.8). The Late Devonian (ca. 368–361 Ma) granites are undeformed and are chemically similar to adakite but have relatively low negative whole-rock ε_Nd(t)values (?2.4 to ?5.3). We interpret the Early Ordovician to Mid-Devonian magmatic event to reflect combined juvenile crustal growth and crustal reworking processes via episodic mafic underplating and mantle–crust interaction. The Late Devonian episode may signify delamination of the over-thickened Chinese Central Tianshan crust.     

The U–Pb ages and Hf isotopes of detrital zircons from Hainan Island,South China: implications for sediment provenance and the crustal evolution

In situ U–Pb dating and Hf isotopic of detrital zircons from beach sediments of Yalong Bay were analyzed to trace sedimentary provenance and reveal the crustal evolution of Hainan Island in South China. The grain size distribution of the sediments displays a clear single-peak feature, indicating the sediments were formed under the same condition of hydrodynamic force. The detrital zircons had Th/U ratios of greater than 0.1, and REE pattern displayed a positive Ce anomaly and a negative Eu anomaly, indicating that these zircons are predominantly of magmatic origin. The U–Pb spectrum of detrital zircons mainly peaked at the Yanshanian (96–185 Ma), Hercynian–Indosinian (222–345 Ma) and Caledonian (421–477 Ma). A portion of the detrital zircons were of Neoproterozoic origin (728–1,003 Ma), which revealed that the basement in the eastern region of Hainan Island was mainly of Neoproterozoic, with rare Archean materials. The positive ε _Hf(t) values (0 to +10.1) of the Neoproterozoic detrital zircons indicated that the juvenile crust grew in the southeastern Hainan Island mainly during the Neoproterozoic period. The Neoproterozoic orogeny in the southeastern part of the island (0.7–1.0 Ga) occurred later than in the northwestern region of the island (1.0–1.4 Ga). Importantly, the Grenvillian orogeny in the southeastern area of Hainan Island shared the same timing with that of the western Cathaysia Block; i.e., both areas concurrently underwent this orogenic event, thereby forming a part of the Rodinia supercontinent. Afterwards, the crust experienced remelting and reworking during the Caledonian Hercynian–Indosinianand Yanshanian accompanied by the growth of a small amount of juvenile crust.     

Zircon U-Pb and Lu-Hf isotope constraints on Archean crustal evolution in Southeastern Guyana Shield

The southeastern Guyana Shield,northeast Amazonian Craton,in the north of Brazil,is part of a widespread orogenic belt developed during the Transamazonian orogenic cycle(2.26-1.95 Ga)that includes a large Archean continental landmass strongly reworked during the Transamazonian orogeny,named Amapa Block.It consists mainly of a high-grade metamorphic granulitic-migmatitic-gneiss complex,of Meso-to Neoarchean age and Rhyacian granitoids and supracrustal sequences.For the first time,coupled U-Pb and Lu-Hf isotope data were obtained on zircon by LA-ICP-MS from five tectono-stratigraphic units of the Archean basement and one Paleoproterozoic intrusive rock,in order to investigate the main episodes of crustal growth and reworking.Whole-rock Sm-Nd isotope data were compared to the zircon Lu-Hf data.Three main magmatic episodes were defined by U-Pb zircon dating,two in the Mesoarchean(~3.19 Ga and 2.85 Ga)and one in the Neoarchean(~2.69-2.65 Ga).SubchondriticεHf(t)values obtained for almost all investigated units indicate that crustal reworking processes were predominant during the formation of rocks that today make up the Amapa Block.Hf-TDMC model ages,ranging from2.99 Ga to 3.97 Ga,indicate that at least two important periods of mantle extraction and continental crust formation occurred during the Archean in southeastern Guyana Shield,an older one in the Eoarchean(~4.0 Ga)and a younger one in the Mesoarchean(~3.0-3.1 Ga).The latter is recognized as an important period of crustal accretion worldwide.The recognition of an Eoarchean episode to the southeastern most part of the Guyana Shield is unprecedented and was not recorded by whole-rock Sm-Nd data,which were restricted to the Meso-Paleoarchean(2.83 Ga to 3.51 Ga).This finding reveals t hat continental crust generation in the Amazonian Craton began at least 500 Ma earlier than previously suggested by the SmNd systematics.     

Temporal and genetic relationships between the Kidston gold-bearing Breccia Pipe and the Lochaber Ring Dyke Complex, North Queensland, Australia: insights from in situ U–Pb and Hf-isotope analysis of zircon

An existing model for the temporal and genetic relationships between the Kidston gold-bearing Breccia Pipe and the nearby Lochaber Ring Dyke Complex has been evaluated using in situ U–Pb and Hf-isotope analyses of zircon grains. The Oak River Granodiorite, the host rock to the Kidston Breccia Pipe, has 1,551?±?6 Ma old zircon cores overgrown by 417.7?±?2.2 Ma rims. The Black Cap Diorite and Lochaber Granite within the Lochaber Ring Dyke Complex have crystallisation ages of 350.7?±?1.3 and 337.9?±?2.6 Ma respectively. The gold-rich Median Dyke within the Kidston Breccia Pipe has a crystallisation age of 335.7?±?4.2 Ma, and thus is temporally related to the Lochaber Granite. However, zircon grains from the Median Dyke have less radiogenic Hf-isotope compositions (? _Hf from ?7.8 to ?15.8) than those from the Black Cap Diorite ?_Hf?=?0.4 to ?7.2) and the Lochaber Granite (? _Hf?=??1.0 to ?7.5), but within the range defined by zircons from the Oak River Granodiorite ? _Hf?=??8.0 to ?29.2). The Hf-isotope data thus rule out the proposed fractional crystallisation relationship between the Kidston gold-bearing rocks and the Lochaber Ring Dyke Complex. The Kidston Median Dyke may have been produced by mixing between Lochaber Granite magmas and magmas derived by remelting of the Oak River Granodiorite, which was itself derived from Proterozoic crust. There is no evidence for a juvenile component in the Lochaber Ring Dyke Complex or the Median Dyke. The gold enrichment in the Kidston rocks thus may reflect the multi-stage reworking of the Proterozoic crust, which ultimately produced the Carboniferous felsic magmas.     

Constructing the latest Neoproterozoic to Early Paleozoic multiple crust-mantle interactions in western Bainaimiao arc terrane,southeastern Central Asian Orogenic Belt

Identifying the crust-mantle interactions in association with the evolution of the Precambrian microcontinents provides critical constraints on the accretionary evolution in the Central Asian Orogenic Belt(CAOB).The Bainaimiao arc terrane(BAT) is one of the most important Precambrian microcontinents in southeastern CAOB,however,few studies have paid attention to the types and the evolving processes of the crust-mantle interactions that occurred before its final accretion onto the northern North China Craton.This study presents an integrated study of geochronology,zircon Hf isotope and whole-rock geochemistry on the latest Neoproterozoic diabases and the Early Paleozoic arc intrusions in the western BAT.The latest Neoproterozoic(ca.546 Ma) diabases display low SiO_2(46.52-49.24 wt.%) with high MgO(8.23-14.41 wt.%),Cr(66-542 ppm) and Ni(50-129 ppm),consisting with mantle origin.Their highly negative zircon ε_(Hf)(t)(-12.0 to-24.7) and high Fe/Mn ratios(62.1-81.7)further indicate a significantly enriched mantle source.Considering that the BAT maybe initially separated from the Tarim Craton with a thickened crustal root,we propose that these diabases were generated through partial melting of an enriched lithospheric mantle source that had been hybridized by lower-crustal eclogites during foundering of the BAT lower crust.The Early Paleozoic(ca.475-417 Ma) arc intrusions in western BAT can be divided into Periods Ⅰ and Ⅱ at approximately 450 Ma.The Period Ⅰ(450 Ma) intrusions contain abundant mafic minerals like hornblende and pyroxene,and show positive zircon ε_(Hf)(t)(+1.5 to+10.9).They are predominantly medium-K calc-alkaline with broad correlations of SiO2 versus various major and trace elements,which correlate well with the experimental melts produced by the fractional crystallization of primitive hydrous arc magmas at 7 kbar.We assume they were formed through mid-crustal differentiation of the mantle wedge-derived hydrous basaltic melts.By contrast,the Period Ⅱ(≤450 Ma) intrusions are characterized by variable zircon e_(Hf)(t)(-15.0 to+11.5) with irregular variations in most major and trace elements,which are more akin to the arc magmas generated in an open system.The general occurrence of elder inherited zircons,along with the relatively high Mg#(45) of some samples,call upon a derivation from the reworking of the previously subduction-modified BAT lower crust with the input of mantle-derived mafic components.In combination with the Early Paleozoic tectonic melanges flanking western BAT,we infer that the compositional transition from Period Ⅰ to Ⅱ can be attributed to the tectonic transition from south-dipping subduction of Solonker ocean to north-dipping subduction of South Bainaimiao ocean in southeastern CAOB.The above results shed light not only on the latest Neoproterozoic to Early Paleozoic multiple crust-mantle interactions in western BAT,but also on the associated crustal construction processes before the final arc-continent accretion.     

粤西云开地区基底变质岩的组成和形成

云开地块被认为是华南西南部一个重要的前寒武纪变质基底出露区,但对其基底组成的认识仍存在较大争议。本文对云开地块内基底变质岩进行了岩石地球化学、锆石U-Pb-Hf同位素分析。分析结果表明云开地块的基底主要由于新元古代-早古生代的变质沉积岩组成。它们具有比上地壳平均成分更高的Si O2和相对更低的Al2O3、Ca O、Na2O,岩石成熟度中等。微量元素与PAAS相似,但Sr、Cr、Ni等强烈亏损,高场强元素Nb、Ta轻度亏损,而大多数样品的Zr、Hf、Th、U等轻度富集,说明源区更富集长英质组分而贫镁铁组分。地球化学特征和碎屑锆石组成指示这套沉积岩形成于被动大陆边缘环境,源区既有古老的再循环物质,也有大量未经明显改造的新元古代岩浆物质。综合本文和前人的锆石U-Pb定年数据,云开地块基底变质岩原岩可以分为两组:第一组样品形成较早(时代上限为850~522Ma),总体年龄谱特征显示出与华夏南岭地区的亲缘性。这组样品的源区主要有4次岩浆作用(2700~2400Ma、1800~1400Ma、1150~900Ma、850~700Ma),均涉及到古老地壳再循环以及新生地壳的加入,但以再循环的物质为主。最主要的新生地壳生长发生在新太古代和Grenville期。而第二组样品的沉积时代在517Ma之后,具有与扬子南缘新元古代沉积岩的相似性。这组亲扬子沉积物的源区具有不同的4次岩浆事件(2600~2350Ma、2000~1750Ma、1700~1500Ma、900~750Ma),新太古代晚期-古元古早期岩浆主要涉及古老基底再循环。古元古晚期-中元古早期岩浆大多起源于新生地壳物质,而新元古代是最重要的新生地壳生长期,同时也涉及大量古老地壳物质的再循环。不同时代沉积岩的碎屑物质组成变化表明大概在522~517Ma之间云开沉积盆地和物源区受到一定程度的构造运动影响,使得源区由华夏地块变成扬子地块。这期构造事件很可能是早古生代造山事件的初始阶段。根据本文资料和其他证据我们认为云开地块归属于华夏板块,扬子与华夏地块的分界线至少在云开地块以北,且很可能在平乐与平南之间。     

S?o Francisco-Congo Craton break-up delimited by U-Pb-Hf isotopes and trace-elements of zircon from metasediments of the Ara?uaí Belt

Detrital zircon U-Pb geochronology combined with Hf isotopic and trace element data from metasedimentary rocks of the Aracuai Belt in southeastern Brazil provide evidence for break-up of the Congo-Sao Francisco Craton. The U-Pb age spectra of detrital zircons from metasediments of the Rio Doce Group(RDG) range from 900-650 Ma and define a maximum depositional age of ca. 650 Ma. Zircon trace element and whole rock data constrain an oceanic island arc as source for the deposition setting of the protoliths to the metasediments. Zircon ε_(Hf)(t) values from these rocks are positive between +1 and +15, supporting previous evidence of a Neoproterozoic extensional phase and oceanic crust formation in a precursor basin to the Aracuai Belt. Recrystallization of detrital zircon at ca. 630 Ma is compatible with a regional metamorphic event associated with terrane accretion to the Paleoproterozoic basement after transition from an extensional to a convergent regime. The juvenile nature, age spectra and trace element composition recorded in detrital zircons of metasediments from the Aracuai Belt correspond with zircons from metasedimentary rocks and oceanic crust remnants of other orogenic belts to its south. This suggests that rifting and oceanic crust formation of the entire orogenic system, the so-called Mantiqueira Province, was contemporaneous, most likely related to the opening of a large ocean. It further indicates that the cratonic blocks involved in the orogenic evolution of the Mantiqueira Province were spatially connected as early as 900 Ma.     

In-situ hafnium and lead isotope analyses of detrital zircons from the Devonian sedimentary basin of NE Greenland: a record of repeated crustal reworking

An intramontane collapse basin developed within the hanging wall above the large-scale extensional Fjord Regional Detachment of NE Greenland in middle to late Devonian times. The continental clastic sediments within the basin are derived locally from Laurentian source rocks, which makes them well suited for a study of the crustal evolution of the source terrain. This is the first integrated in-situ Pb and Hf isotope study to be presented, and zircon data on a selected sandstone from the basin are combined with Sm-Nd whole-rock data on sand/siltstones. Nd whole-rock ages of two samples of sandstones and a siltstone are 2.0-2.1 Ga. Peak frequencies of zircon ²⁰⁷Pb/²⁰⁶Pb ages at 1,764-1,912 Ma, and ¹⁷⁶Hf/¹⁷⁷Hf values at 0.28142-0.28163 (t_DM=2.47 to 2.06) for the sandstone suggest the generation of a considerable volume of juvenile continental crust in the ultimate zircon provenance at 1.9-2.0 Ga. The Hf isotopic compositions of Archaean zircons in the sandstone are distinct from those of the source materials of Proterozoic protocrust at 1.9-2.0 Ga, but zircons with elevated Hf-t_DM ages of up to 2.47 Ga can be related to a component of Archaean crust or reworked Archaean material in the ultimate zircon source area. Zircon ²⁰⁷Pb/²⁰⁶Pb ages are also recorded at 1,480-1,572, 1,318 and 1,014 Ma (Grenvillian). The Hf isotope compositions of these zircons are consistent with reworking of the Proterozoic protocrust at these times, with little or no juvenile input. The Proterozoic zircons form two distinct groups defined by ¹⁷⁶Yb/¹⁷⁷Hf>0.05055 and ¹⁷⁶Yb/¹⁷⁷Hf<0.03301, and the latter group overlaps with Yb-Hf isotope data on the Archaean zircons. The two groups may represent zircons derived from evolved granites and intermediate to mildly felsic rocks, respectively. The repeated reworking of the continental crust also comprised erosion and deposition of sediments in the Proterozoic (the Krummedal sequence and the Eleonore Bay Supergroup, EBS) and intrusion of Caledonian anatectic granites in the EBS, which both represent provenance components to the Devonian sediments. No discrete Caledonian Pb-Pb zircon ages are recorded, but Caledonian magmatism may be represented by strongly discordant zircons which form arrays with a lower intercept age at ca. 400 Ma and an upper intercept at 1,600-2,000 Ma. One undated zircon records a ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282218, higher than that of the Proterozoic protocrust in Caledonian/late-Caledonian times (380-450 Ma) which may represent a Caledonian mantle contribution.     

Formation and evolution of Precambrian continental lithosphere in South China

An overview is presented for the formation and evolution of Precambrian continental lithosphere in South China. This is primarily based on an integrated study of zircon U–Pb ages and Lu–Hf isotopes in crustal rocks, with additional constraints from Re–Os isotopes in mantle-derived rocks. Available Re–Os isotope data on xenolith peridotites suggest that the oldest subcontinental lithospheric mantle beneath South China is primarily of Paleoproterozoic age. The zircon U–Pb ages and Lu–Hf isotope studies reveal growth and reworking of the juvenile crust at different ages. Both the Yangtze and Cathaysia terranes contain crustal materials of Archean U–Pb ages. Nevertheless, zircon U–Pb ages exhibit two peaks at 2.9–3.0 Ga and ~ 2.5 Ga in Yangtze but only one peak at ~ 2.5 Ga in Cathaysia. Both massive rocks and crustal remnants (i.e., zircon) of Archean U–Pb ages occur in Yangtze, but only crustal remnants of Archean U–Pb ages occur in Cathaysia. Zircon U–Pb and Lu–Hf isotopes in the Kongling complex of Yangtze suggest the earliest episode of crustal growth in the Paleoarchean and two episodes of crustal reworking at 3.1–3.3 Ga and 2.8–3.0 Ga. Both negative and positive ε_Hf(t) values are associated with Archean U–Pb ages of zircon in South China, indicating both the growth of juvenile crust and the reworking of ancient crust in the Archean. Paleoproterozoic rocks in Yangtze exhibit four groups of U–Pb ages at 2.1 Ga, 1.9–2.0 Ga, ~ 1.85 Ga and ~ 1.7 Ga, respectively. They are associated not only with reworking of the ancient Archean crust in the interior of Yangtze, but also with the growth of the contemporaneous juvenile crust in the periphery of Yangtze. In contrast, Paleoproterozoic rocks in Cathaysia were primarily derived from reworking of Archean crust at 1.8–1.9 Ga. The exposure of Mesoproterozoic rocks are very limited in South China, but zircon Hf model ages suggest the growth of juvenile crust in this period due to island arc magmatism of the Grenvillian oceanic subduction. Magmatic rocks of middle Neoproterozoic U–Pb ages are widespread in South China, exhibiting two peaks at about 830–800 Ma and 780–740 Ma, respectively. Both negative and positive ε_Hf(t) values are associated with the middle Neoproterozoic U–Pb ages of zircon, suggesting not only growth and reworking of the juvenile Mesoproterozoic crust but also reworking of the ancient Archean and Paleoproterozoic crust in the middle Neoproterozoic. The tectonic setting for this period of magmatism would be transformed from arc–continent collision to continental rifting with reference to the plate tectonic regime in South China.     

A new fragment of the early earth crust: the Aasivik terrane of West Greenland

The Aasivik terrane is a ∼1500 km² complex of gneisses dominated by ∼3600 Ma components, which has been discovered in the Archaean craton of West Greenland, ∼20–50 km south of the Paleoproterozoic Nagssugtoqidian orogen. The Aasivik terrain comprises granulite facies tonalitic to granitic gneisses with bands of mafic granulite, which include disrupted mafic dykes. Four gneiss samples of the Aasivik terrain have given imprecise SHRIMP U–Pb zircon ages of 3550–3780 Ma with strong loss of radiogenic lead and new growth of zircon probably associated with a granulite facies metamorphic event(s) at ∼2800–2700 Ma. To the Southeast, the Aasivik terrane is in tectonic contact with a late Archaean complex of granitic and metapelitic gneisses with apparently randomly distributed mafic and ultramafic units, here named the Ukaleq gneiss complex. Two granitic samples from the Ukaleq gneiss complex have U–Pb zircon ages of 2817 ± 10 and 2820 ± 12 Ma and t_zircon ε_Nd values of 2.3–5.4. Given their composition and positive ε_Nd values, they probably represent melts of only slightly older juvenile crust. A reconnaissance SHRIMP U–Pb study of a sample of metasedimentary rock from the Ukaleq gneiss complex found ∼2750–2900 Ma zircons of probable detrital origin and that two or more generations of 2700–2500 Ma metamorphic zircons are present. This gneiss complex is provisionally interpreted as a late Archaean accretionary wedge. A sample of banded granulite facies gneiss from a complex of banded gneisses south of the Aasivik terrain here named the Tasersiaq gneiss complex has yielded two zircon populations of 3212 ± 11 and 3127 ± 12 Ma. Contacts between the three gneiss complexes are mylonites which are locally cut by late-post-kinematic granite veins with SHRIMP U–Pb zircon ages of ∼2700 Ma. The isotopic character and the relationships between the lithologies from the different gneiss complexes suggest the assembly of unrelated rocks along shear zones between 2800 and 2700 Ma. The collage of Archaean gneiss complexes were intruded by A-type granites, here named the Umiatsiaasat granites, at ∼2700 Ma, later than the tectonic intercalation of the gneiss complexes.     

Crustal reworking and orogenic styles inferred from zircon Hf isotopes:Proterozoic examples from the North Atlantic region

Zircon Hf evolutionary patterns are powerful tools to investiage magma petrogenesis and crustal evolution. The ~(176)Hf/~(177)Hf isotopic signature of a rock is particularly informative and can be used to derive an estimation of the time when mantle extraction and diagnose closed system reworking where successive samples through time define an Hf evolution array dependant on the source Lu/Hf ratio. However, many magmatic events require new mantle addition as the thermal impetus for melting pre-existing crust. In this situation, rather than simply reflecting reworking, the isotopic signature indicates mixing with contributions from both reworked crust and new radiogenic input. Different geodynamic settings have different propensities for either reworking or addition of new mantle-derived magma. Hence, Hf-time trends carry within them a record, albeit cryptic, of the evolving geodynamic environment as different tectonic configurations recycle and add new crust at different rates, magnitudes, and from different sources. As an example of the difference in apparent Hf evolution slopes, we present Hf-time compilations from three geographically distinct Meso-to Neoproterozoic orogenic belts in the North Atlantic Region whose geodynamic configurations remain a subject of debate. We use the εHf/Ma trajectory to assist in understanding their evolution. The εHf/Ma trajectory of the Sveconorwegian Orogen corresponds to a ~(176)Lu/~(177) Hf ratio of 0.012, which implies a process driven primarily by reworking of preexisting crust that is balanced with input from the depleted mantle resulting in a relatively shallowεHf/Ma slope. The Valhalla Orogen reveals a similar comparatively shallow εHf/Ma path. In stark contrast to these patterns is the steep εHf/Ma trajectory of the Grenville Orogen that requires a mixing process involving a greater contribution of old crust of at least ～ 1.8 Ga age. The degree of reworking required to produce the εHf/Ma trend of the Grenville Orogen is consistent with a continent-continent collisional orogeny whereas both Sveconorwegian and Valhalla orogens appear more consistent with accretionary margins.     

Cold plumes trigger contamination of oceanic mantle wedges with continental crust-derived sediments: Evidence from chromitite zircon grains of eastern Cuban ophiolites

The origin of zircon grains, and other exotic minerals of typical crustal origin, in mantle-hosted ophiolitic chromitites are hotly debated. We report a population of zircon grains with ages ranging from Cretaceous (99 Ma) to Neoarchean (2750 Ma), separated from massive chromitite bodies hosted in the mantle section of the supra-subduction (SSZ)-type Mayarí-Baracoa Ophiolitic Belt in eastern Cuba. Most analyzed zircon grains (n = 20, 287 ± 3 Ma to 2750 ± 60 Ma) are older than the early Cretaceous age of the ophiolite body, show negative ε_Hf(t) (−26 to −0.6) and occasional inclusions of quartz, K-feldspar, biotite, and apatite that indicate derivation from a granitic continental crust. In contrast, 5 mainly rounded zircon grains (297 ± 5 Ma to 2126 ± 27 Ma) show positive ε_Hf(t) (+0.7 to +13.5) and occasional apatite inclusions, suggesting their possible crystallization from melts derived from juvenile (mantle) sources. Interestingly, younger zircon grains are mainly euhedral to subhedral crystals, whereas older zircon grains are predominantly rounded grains. A comparison of the ages and Hf isotopic compositions of the zircon grains with those of nearby exposed crustal terranes suggest that chromitite zircon grains are similar to those reported from terranes of Mexico and northern South America. Hence, chromitite zircon grains are interpreted as sedimentary-derived xenocrystic grains that were delivered into the mantle wedge beneath the Greater Antilles intra-oceanic volcanic arc by metasomatic fluids/melts during subduction processes. Thus, continental crust recycling by subduction could explain all populations of old xenocrystic zircon in Cretaceous mantle-hosted chromitites from eastern Cuba ophiolite. We integrate the results of this study with petrological-thermomechanical modeling and existing geodynamic models to propose that ancient zircon xenocrysts, with a wide spectrum of ages and Hf isotopic compositions, can be transferred to the mantle wedge above subducting slabs by cold plumes.     

Ages and Hf isotopes of detrital zircons from the Permian strata in the Bengbatu area (Inner Mongolia) and tectonic implications

The Central Asian Orogenic Belt (CAOB) was built up through protracted accretion and collision of a variety of terranes/micro-continents during Neoproterozoic–Mesozoic time. To understand potential links among Paleozoic subduction and accretionary processes that were operative during the development of the southeastern CAOB, we conducted a combined U-Pb and Hf-isotope analysis of detrital zircons from previously defined Devonian, Carboniferous and Early Permian strata in the Bengbatu area, Inner Mongolia. Detrital zircons from (meta-) sandstones in these strata commonly yield major Paleozoic age populations at ca. 300–261 Ma, 351–300 Ma and 517–419 Ma, and also give several Precambrian ages that range from 2687 Ma to 544 Ma. The youngest ages redefine the deposition of all these strata to be in the Middle Permian (Wordian–Capitanian) or later, much younger than previously considered. These ages, coupled with regional magmatic records, support an interpretation of most surrounding areas as possible detritus sources, including the Mongolian arcs to the north, the Northern Accretionary Orogen to the south, and the intervening Erenhot–Hegenshan Ophiolite Belt. Zircons with magmatic ages of ca. 500–350 Ma and ca. 300–261 Ma display a large range of ε_Hf(t) values (?13.97 to +15.31), whereas ca. 350–300 Ma zircons are dominated by positive ε_Hf(t) values (+0.14 to +16.00). These results support the occurrence of two significant shifts of the zircon ε_Hf(t) values, which has tectonic implications for the understanding of the Carboniferous–Permian evolution of the southeastern CAOB. A marked shift from mixed to positive zircon ε_Hf(t) values at 350–330 Ma likely manifests the incipient opening of the Hegenshan Ocean, due to the slab rollback of the subducting Paleo-Asian Oceanic lithosphere. Another shift from positive to mixed zircon ε_Hf(t) values at ca. 300 Ma likely corresponds to a tectonic switch from syn-orogenic subduction-related to post-orogenic extensional setting, genetically related to the tectonic collapse of a formerly overthickened crust.     

Zircon U–Pb and Hf evidence for coupled subduction of oceanic and continental crust during the Carboniferous in the Huwan shear zone,western Dabie orogen,central China

Both oceanic and continental HP rocks are juxtaposed in the Huwan shear zone in the western Dabie orogen, and thus provide a window for testing the buoyancy‐driven exhumation of dense oceanic HP rocks. The HP metamorphic age of the continental rocks in this zone has not been well constrained, and hence it is not known if they are of the same age as the exhumation of the HP oceanic rocks. In situ laser ablation (multiple collector) inductively coupled plasma mass spectrometry (LA‐(MC‐)ICP‐MS), U–Pb, trace element and Hf isotope analyses were made on zircon in a granitic gneiss and two eclogites from the Huwan shear zone. U–Pb age and trace element analysis of residual magmatic zircon in an eclogite constrain its protolith formation at 411 ± 4 Ma. The zircon in this sample displays ε_Hf (t) values of +6.1 to +14.4. The positive ε_Hf (t) values up to +14.4 suggest that the protolith was derived from a relatively depleted mantle source, most likely Palaeotethyan oceanic crust. A granitic gneiss and the other eclogite yield protolith U–Pb ages of 738 ± 6 and 700 ± 14 Ma, respectively, which are both the Neoproterozoic basement rocks of the Yangtze Block. The zircon in the granitic gneiss has low ε_Hf (t) values of ?14.2 to ?10.5 and old T_DM2 ages of 2528–2298 Ma, suggesting reworking of Palaeoproterozoic crust during the Neoproterozoic. The zircon in the eclogite has ε_Hf (t) values of ?1.0 to +7.4 and T_DM1 ages of 1294–966 Ma, implying prompt reworking of juvenile crust during its protolith formation. Metamorphic zircon in both eclogite samples displays low Th/U ratios, trace element concentrations, relatively flat heavy rare earth element patterns, weak negative Eu anomalies and low ¹⁷⁶Lu/¹⁷⁷Hf ratios. All these features suggest that the metamorphic zircon formed in the presence of garnet but in the absence of feldspar, and thus under eclogite facies conditions. The metamorphic zircon yields U–Pb ages of 310 ± 3 and 306 ± 7 Ma. Therefore, both the oceanic‐ and continental‐type eclogites share the same episode of Carboniferous eclogite facies metamorphism. This suggests that high‐pressure continental‐type metamorphic rocks might have played a key role in the exhumation and preservation of oceanic‐type eclogites through buoyancy‐driven uplift.     

Geologically constraining India in Columbia: The age,isotopic provenance and geochemistry of the protoliths of the Ongole Domain,Southern Eastern Ghats,India

The Ongole Domain in the southern Eastern Ghats Belt of India formed during the final stages of Columbia amalgamation at ca. 1600 Ma. Yet very little is known about the protolith ages, tectonic evolution or geographic affinity of the region. We present new detrital and igneous U–Pb–Hf zircon data and in-situ monazite data to further understand the tectonic evolution of this Columbia-forming orogen.Detrital zircon patterns from the metasedimentary rocks are dominated by major populations of Palaeoproterozoic grains (ca. 2460, 2320, 2260, 2200–2100, 2080–2010, 1980–1920, 1850 and 1750 Ma), and minor Archaean grains (ca. 2850, 2740, 2600 and 2550 Ma). Combined U–Pb ages and Lu–Hf zircon isotopic data suggest that the sedimentary protoliths were not sourced from the adjacent Dharwar Craton. Instead they were likely derived from East Antarctica, possibly the same source as parts of Proterozoic Australia. Magmatism occurred episodically between 1.64 and 1.57 Ga in the Ongole Domain, forming felsic orthopyroxene-bearing granitoids. Isotopically, the granitoids are evolved, producing εHf values between − 2 and − 12. The magmatism is interpreted to have been derived from the reworking of Archaean crust with only a minor juvenile input. Metamorphism between 1.68 and 1.60 Ga resulted in the partial to complete resetting of detrital zircon grains, as well as the growth of new metamorphic zircon at 1.67 and 1.63 Ga. In-situ monazite geochronology indicates metamorphism occurred between 1.68 and 1.59 Ga.The Ongole Domain is interpreted to represent part of an exotic terrane, which was transferred to proto-India in the late Palaeoproterozoic as part of a linear accretionary orogenic belt that may also have included south-west Baltica and south-eastern Laurentia. Given the isotopic, geological and geochemical similarities, the proposed exotic terrane is interpreted to be an extension of the Napier Complex, Antarctica, and may also have been connected to Proterozoic Australia (North Australian Craton and Gawler Craton).     

In-situ U–Pb geochronology and Hf isotope analyses of the Rayner Complex,east Antarctica

In-situ zircon U–Pb and Hf isotopic analysis via laser ablation microprobe-inductively coupled plasma mass spectrometer (LAM-ICPMS) of samples from Kemp and MacRobertson Lands, east Antarctica suggests that the Kemp Land terrane evolved separately from the rest of the Rayner Complex prior to the ca. 940 Ma Rayner Structural Episode. Several Archaean metamorphic events in rocks from western Kemp Land can be correlated with events previously reported for the adjacent Napier Complex. Recently reported ca. 1,600 Ma isotopic disturbance in rocks from the Oygarden Group may be correlated with a charnockitic intrusion in the Stillwell Hills before ca. 1,550 Ma. Despite being separated by some 200 km, T^Hf_DM ages indicate felsic orthogneiss from Rippon Point, the Oygarden Group, Havstein Island and the Stillwell Hills share a ca. 3,660–3,560 Ma source that is indistinguishable from that previously reported for parts of the Napier Complex. More recent additions to this crust include Proterozoic charnockite in the Stillwell Hills and the vicinity of Mawson Station. These plutons have distinct ¹⁷⁶Hf/¹⁷⁷Hf ratios and formed via the melting of crust generated at ca. 2,150–2,550 Ma and ca. 1,790–1,870 Ma respectively.     

Petrogenesis of the microcrystalline-dioritic enclaves from Jiuling granitoids in the eastern segment of Jiangnan Orogen and constraints on magma source materials

Numerous dark enclaves with different shapes are found in Jiuling Neoproterozoic granitoids. Precise LA-ICP-MS U-Pb dating was conducted on zircons extracted from two microcrystalline enclave samples, yielding crystallization ages of 822.6±5.8 Ma and 822.2±6.2 Ma, respectively. The consistent ages within analytical errors with the host granitoids suggested that they were the products of the same magmatism. The microcrystalline-dioritic enclaves commonly show plastic forms and contain similar plagioclase megacrysts to the host rocks, and both of the enclaves and host granitoids showed a complex composition and structural imbalance in plagioclases. Furthermore, the apatites with a euhedral acicular shape occurred widely in the microcrystalline-dioritic enclaves. All of these petrographic features above imply magma mixing is involved in their diagenesis. The enclaves and host granitoids show a marked zircon trace element difference and Hf isotopic signatures without correlation in zircon trace element pairs but form their own system between enclaves and host granitoids. Additionally, most of the zircons show extremely high ε_Hf (t) with ε_Hf (t) =3.54–11.94 from the southern samples, and ε_Hf (t) =1.0–9.09 from the central region. Some zircons with the higher ε_Hf (t) are similar to the zircons from the juvenile island arc in the eastern segment of Jiangnan Orogen. Integrated geological and Hf isotopic characteristics suggest microcrystalline-dioritic enclaves were derived from the partial melting process of the Mesoproterozoic crust which enriched juvenile island arc materials and mixed with the granitic magma that remelted from the Mesoproterozoic continental crust which relatively enriched ancient sediments and mixed with the host granitoid in diagenesis.     

Archaean crustal growth through successive partial melting events in an oceanic plateau‐like setting in the Tanzania Craton

The detrital zircon population in quartzitic conglomerates from the northern Tanzania Craton yield ages between 2640 Ma and 2790 Ma which includes most of the igneous history from this part of the craton. The igneous evolution is characterised by mafic volcanism with an oceanic plateau‐like geochemical signature at ~2800 Ma followed by diorite and tonalite–trondhjemite–granodiorite dominated magmatism between 2790 and 2700 Ma, which transitioned into more evolved high‐K magmatism between 2700 and 2620 Ma. The ε_Hf values of the detrital zircons range from +2.4 to ?1.4 and change with time from radiogenic Hf pre‐2700 Ma (98% positive ε_Hf) to unradiogenic Hf post‐2700 Ma (41% positive ε_Hf). The petrological progression from mafic to felsic crust is reflected in the detrital age distribution and Hf isotopes and is consistent with juvenile mafic crust slowly maturing into more evolved felsic crust through a series of successive partial melting events in an oceanic‐plateau‐like environment.     

Zircon U-Pb-Hf constraints from Gongga Shan granites on young crustal melting in eastern Tibet

The Gongga Shan batholith is a complex granitoid batholith on the eastern margin of the Tibetan Plateau with a long history of magmatism spanning from the Triassic to the Pliocene. Late Miocene-Pliocene units are the youngest exposed crustal melts within the entire Asian plate of the Tibetan Plateau.Here, we present in-situ zircon Hf isotope constraints on their magmatic source, to aid the understanding of how these young melts were formed and how they were exhumed to the surface. Hf isotope signatures of Eocene to Pliocene zircon rims(ε_Hf(t)=-4 to +4), interpreted to have grown during localised crustal melting, are indicative of melting of a Neoproterozoic source region, equivalent to the nearby exposed Kangding Complex. Therefore, we suggest that Neoproterozoic crust underlies this region of the Songpan-Ganze terrane, and sourced the intrusive granites that form the Gongga Shan batholith. Localised young melting of Neoproterozoic lower or middle crust requires localised melt-fertile lithologies. We suggest that such melts may be equivalent to seismic and magnetotelluric low-velocity and high-conductivity zones or "bright spots" imaged across much of the Tibetan Plateau. The lack of widespread exposed melts this age is due either to the lack of melt-fertile rocks in the middle crust, the very low erosion level of the Tibetan plateau, or to a lack of mechanism for exhuming such melts. For Gongga Shan, where some melting is younger than nearby thermochronological ages of low temperature cooling, the exact process and timing of exhumation remains enigmatic, but their location away from the Xianshuihe fault precludes the fault acting as a conduit for the young melts. We suggest that underthrusting of dry granulites of the lower Indian crust(Archaean shield) this far northeast is a plausible mechanism to explain the uplift and exhumation of the eastern Tibetan Plateau.     

Reworking of the Gangdese magmatic arc,southeastern Tibet: post‐collisional metamorphism and anatexis

The Gangdese magmatic arc, southeastern Tibet, was built by mantle‐derived magma accretion and juvenile crustal growth during the Mesozoic to Early Cenozoic northward subduction of the Neo‐Tethyan oceanic slab beneath the Eurasian continent. The petrological and geochronological data reveal that the lower crust of the southeastern Gangdese arc experienced Oligocene reworking by metamorphism, anatexis and magmatism after the India and Asia collision. The post‐collisional metamorphic and migmatitic rocks formed at 34–26 Ma and 28–26 Ma respectively. Meta‐granitoids have protolith ages of 65–38 Ma. Inherited detrital zircon from metasedimentary rocks has highly variable ages ranging from 2708 to 37 Ma. These rocks underwent post‐collisional amphibolite facies metamorphism and coeval anatexis under P–T conditions of ~710–760 °C and ~12 kbar with geothermal gradients of 18–20 °C km ^{? 1}, indicating a distinct crustal thickening process. Crustal shortening, thickening and possible subduction erosion due to the continental collision and ongoing convergence resulted in high‐P metamorphic and anatectic reworking of the magmatic and sedimentary rocks of the deep Gangdese arc. This study provides a typical example of the reworking of juvenile and ancient continental crust during active collisional orogeny.