Shattering and coagulation of dust grains in interstellar turbulence

We investigate shattering and coagulation of dust grains in turbulent interstellar medium (ISM). The typical velocity of dust grain as a function of grain size has been calculated for various ISM phases based on a theory of grain dynamics in compressible magnetohydrodynamic turbulence. In this paper, we develop a scheme of grain shattering and coagulation and apply it to turbulent ISM by using the grain velocities predicted by the above turbulence theory. Since large grains tend to acquire large velocity dispersions as shown by earlier studies, large grains tend to be shattered. Large shattering effects are indeed seen in warm ionized medium within a few Myr for grains with radius   a ≳ 10⁻⁶  cm. We also show that shattering in warm neutral medium can limit the largest grain size in ISM  ( a ∼ 2 × 10⁻⁵ cm)  . On the other hand, coagulation tends to modify small grains since it only occurs when the grain velocity is small enough. Coagulation significantly modifies the grain size distribution in dense clouds (DC), where a large fraction of the grains with   a < 10⁻⁶ cm  coagulate in 10 Myr. In fact, the correlation among   R_V   , the carbon bump strength and the ultraviolet slope in the observed Milky Way extinction curves can be explained by the coagulation in DC. It is possible that the grain size distribution in the Milky Way is determined by a combination of all the above effects of shattering and coagulation. Considering that shattering and coagulation in turbulence are effective if dust-to-gas ratio is typically more than ∼1/10 of the Galactic value, the regulation mechanism of grain size distribution should be different between metal-poor and metal-rich environments.     

Desorption from interstellar ices

The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H₂ formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E _t), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important.
Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H₂ formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions – rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.     

Far-ultraviolet extinction and diffuse interstellar bands

We relate the equivalent widths of the major diffuse interstellar bands (DIBs) near 5797 and 5780 Å with different colour excesses, normalized by E ( B − V ) , which characterize the growth of interstellar extinction in different wavelength ranges. It is demonstrated that the two DIBs correlate best with different parts of the extinction curve, and the ratio of these diffuse bands is best correlated with the far-ultraviolet (UV) rise. A number of peculiar lines of sight are also found, indicating that the carriers of some DIBs and the far-UV extinction can be separated in certain environments, e.g. towards the Per OB2 association.     

Limited diversity of the interstellar extinction law

We have applied the method of investigating extinction curves using statistically meaningful samples that was proposed by us 25 years ago. The extensive data sets of the ANS (Astronomical Netherlands Satellite) and 2MASS (Two Micron All Sky Survey) were used, together with UBV photometry to create average extinction curves for samples of OB stars. Our results demonstrate that in the vast majority of cases the extinction curves are very close to the mean galactic extinction curve. Only a few objects were found to be obviously discrepant from the average. The latter phenomenon may be related to nitrogen chemistry in translucent interstellar clouds (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

Optical emission at 5800 Å in the Red Rectangle and the 5797-Å diffuse interstellar band

An analysis of the intensity and spatial distribution of the discrete 5800-Å emission band in the spectrum of the Red Rectangle has been used to constrain the abundance and physical properties of the carrier of this emission. An origin in a large (>30 C atom) molecule is indicated. This molecule is formed in situ in the Red Rectangle, but is also a component of the diffuse interstellar medium. The UV photodissociation probability for this molecule is ≲10⁻⁵ per absorbed photon, and the luminescence efficiency is in the range 10⁻²–10⁻³. This molecule may be a product of the dissociation of carbonaceous dust.     

Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

New approaches to the modelling of surface chemistry on interstellar grains

In recent years, the need to replace rate equations for studying grain-surface chemistry in the modelling of interstellar clouds has become apparent. In this article, we discuss the three new replacement methods that have been suggested to date, and contrast their relative strengths and weaknesses. This revised version was published online in July 2006 with corrections to the Cover Date.     

On the mixing rules for astrophysical inhomogeneous grains

We present the computation of effective refractive coefficients for inhomogeneous two-component grains with three kinds of inclusions with   m _incl= 3.0 + 4.0i, 2.0 + 1.0i, 2.5 + 0.0001i  and a matrix with   m_m = 1.33 + 0.01i  for 11 volume fractions of inclusions from 0 to 50 per cent and wavelengths  λ= 0.5  , 1.0, 2.0 and 5.0 μm. The coefficients of extinction for these grains have been computed using a discrete dipole approximation. Computation of the extinction by the same method for grains composed of a matrix material with randomly embedded inclusions has been carried out for different volume fractions of inclusions. A comparison of extinction coefficients obtained for both models of grain material allows one to choose the best mixing rule for a mixture. In cases of inclusions with   m _incl= 2.0 + 1.0i  and 2.5 + 0.0001i the best fit for the whole wavelength range and volume fractions of inclusions from 0 to 50 per cent has been obtained for the Lichtenecker mixing rule. In the case of   m _incl= 3.0 + 4.0i  the fit for the whole wavelength range and volume fractions of inclusions from 0 to 50 per cent is not very significant but the best fit has been obtained for the Hanai rule. For volume fractions of inclusions from 0 to 15 per cent a very good fit has been obtained for the whole wavelength range for Rayleigh and Maxwell-Garnett mixing rules.     

On the band-to-continuum intensity ratio in the infrared spectra of interstellar carbonaceous dust

Published interpretations of the relative intensity variations of the unidentified infrared bands (UIBs) and their underlying continuum are discussed. An alternative model is proposed, in which a single carrier for both emits (a) mostly a continuum when it is electronically excited by photons (visible or UV), or (b) exclusively the UIBs, when only chemical energy is deposited by H capture on its surface, inducing only nuclear vibrations. The bands will dominate in atomic H regions but will be overcome by thermal continuum radiation when the ambient field is strong but lacks dissociating photons (900–1100 Å). The model applies to photodissociation regions as well as to limbs of molecular clouds in the interstellar medium and agrees quantitatively with recent satellite observations. It gives indications on atomic H density and UIB intensity provided the ambient radiation field is known. It invokes no chemical, electronic, structural or size change to interpret the observed intensity variations.