Subsurface Occurrence of Natural Gas Hydrate in the Nankai Trough Area: Implication for Gas Hydrate Concentration

Abstract. The Nankai Trough runs along the Japanese Islands, where extensive BSRs have been recognized in its forearc basins. High resolution seismic surveys and site-survey wells undertaken by the MITI have revealed the gas hydrate distribution at a depth of about 290 mbsf. The MITI Nankai Trough wells were drilled in late 1999 and early 2000. The highlights were successful retrievals of abundant gas hydrate-bearing cores in a variety of sediments from the main hole and the post survey well-2, keeping the cored gas hydrate stable, and the obtaining of continuous well log data in the gas hydrate-dominant intervals from the main hole, the post survey well-1 and the post survey well-3. Gas-hydrate dominant layers were identified at the depth interval from 205 to 268 mbsf. Pore-space hydrate, very small in size, was recognized mostly filling intergranular pores of sandy sediments. Anomalous chloride contents in extracted pore water, core temperature depression, core observations as well as visible gas hydrates confirmed the presence of pore-space hydrates within moderate to thick sand layers. Gas hydrate-bearing sandy strata typically were 10 cm to a meter thick with porosities of about 40 %. Gas hydrate saturations in most hydrate-dominant layers were quite high, up to 90 % pore saturation.
All the gas hydrate-bearing cores were subjected to X-ray CT imagery measurements for observation of undisturbed sedimentary textures and gas-hydrate occurrences before being subjected to other analyses, such as (1) petrophysical properties, (2) biostratigraphy, (3) geochemistry, (4) microbiology and (5) gas hydrate characteristics.     

Application of a Simulation Model for the Formation of Methane Hydrate to the Nankai Trough and the Blake Ridge: Natural Examples of Two End-member Cases

Abstract. Simulation experiments with a one-dimensional static model for formation of methane hydrate are used to demonstrate models of hydrate occurrence and its generation mechanism for two end-member cases. The simulation results compare well with experimental data for two natural examples (the Nankai Trough and the Blake Ridge).
At the MITI Nankai Trough wells, the hydrate occurrence is characterized by strongly hydrated sediments developing just above the BGHS. Such occurrence can be reproduced well by simulation in which the end-member case of upward advective fluid flow from below the BGHS is set. The strongly hydrated sediments is formed by oversaturated solution with free gas which directly enters the BGHS by the upward advective fluid flow. The recycling of dissociated methane of preexisting hydrate also contributes to the increase of hydrate saturation.
At the Site 997 in the Blake Ridge area, the hydrate occurrence is characterized by thick zone with poorly hydrated sediments and no hydrate zone developing above the hydrate zone. Such occurrence can be reproduced well by simulation in which the end-member case of in-situ biogenic production of methane in the sediment of methane hydrate zone is set. The distribution pattern of hydrate saturation is basically controlled by that of TOC. However, the hydrate concentration near the bottom of the hydrate zone is increased by the effect of recycling of dissociated methane of pre-existing hydrate. No hydrate zone expresses the geologic time needed until the local concentration of methane exceeds the solubility by gradual accumulation of in-situ biogenic methane with burial.     

The Geochemical Context of Gas Hydrate in the Eastern Nankai Trough

Abstract. Geochemical studies for gas hydrate, gas and organic matter collected from gas hydrate research wells drilled at the landward side of the eastern Nankai Trough, offshore Tokai, Japan, are reported. Organic matter in the 2355 m marine sediments drilled to Eocene is mainly composed of Type III kerogen with both marine and terrigenous organic input. The gas hydrate-bearing shallow sediments are immature for hydrocarbon generation, whereas the sediments below 2100 mbsf are thermally mature. The origins of gases change from microbial to thermogenic at around 1500 mbsf.
Carbon isotope compositions of CH₄ and CO₂, and hydrocarbon compositions consistently suggest that the CH₄ in the gas hydrate-bearing sediments is generated by microbial reduction of CO₂. The δ¹³C depth-profiles of CH₄ and CO₂ suggest that the microbial methanogenesis is less active in the Nankai Trough sediments compared with other gas hydrate-bearing sediments where solid gas hydrate samples of microbial origin were recovered. Since in situ generative-potential of microbial methane in the Nankai Trough sediments is interpreted to be low due to the low total organic carbon content (0.5 % on the average) in the gas hydrate-bearing shallow sediments, upward migration of microbial methane and selective accumulation into permeable sands should be necessary for the high concentration of gas hydrate in discrete sand layers.     

BSRs and Associated Reflections as an Indicator of Gas Hydrate and Free Gas Accumulation: An Example of Accretionary Prism and Forearc Basin System along the Nankai Trough, off Central Japan

Abstract. Multi-channel seismic data obtained from the Nankai accretionary prism and forearc basin system has been studied to elucidate the migration and accumulation process of gas to the BGHS and examine the distribution pattern of BSRs and characteristic reflections associated with them.
BSRs are distributed widely in the Nankai accretionary prism and associated forearc basins (33,000 km²) and 90 % of them have migration and recycling origins. The widest distribution of the BSRs can be seen at the prism. A correlation between the BSR distributions and prism size shows that the BSRs tend to be more well-developed in a prism of large size. This suggests that a large prism may produce much amount of gas-bearing fluids that migrate to the BGHS and form the BSRs (tectonic control), hi the forearc basins, the BSRs are identified at topographic highs, anticlines and basin margins (structural control).
The upward migration of gas-bearing fluids is carried out through permeable sand layers and as a result, the distribution of BSRs is confined to alternating beds of sand and mud facies (sedimentary control). However, if there is enough time for upward migration and accumulation of gas to the BGHS, the BSRs can be generated widely in low-permeable mud facies (time control).
Those results imply that structural, tectonic, sedimentary and time controls are primary factors to decide the distribution of BSRs in the Nankai Trough area.     

Application of AVO Analysis to Seismic Data for Detection of Gas below Methane Hydrate Stability Zone in Nankai Trough Area

Abstract. For the purpose of development of methane hydrate, occurring in the deep marine subsurface, as a resource, the most important issue is to understand the methane hydrate system (generation, migration and accumulation) as well as to delineate the methane hydrate reservoir properties. We have applied the Amplitude Versus Offset (AVO) analysis to the seismic data acquired in the Nankai Trough, offshore Japan, in order to confirm the occurrence of gas just below the methane hydrate-bearing zone, assuming that gas will show a so-called Class-3 AVO response. Knowledge of the amount and occurrence of gas in the sediment below methane hydrate-bearing zone is one of the keys to understand the methane hydrate system.
We have utilized the qualitative analysis of AVO methodology to delineate how gas is located below the BSR, which is thought to be the reflection event from the interface between the methane hydrate-bearing zone and the underlying gas-bearing zone. In the region of MITI Nankai Trough Well PSW-3, we observe two BSRs separated by 25 ms. After AVO modeling using well data, we applied AVO attribute analysis and attribute crossplot analysis to the seismic data. Finally we applied an offset-amplitude analysis to CMP gather data at specific locations to confirm the results of AVO attribute analysis. The AVO analysis shows that there is very little gas located in the underlying sediment below methane hydrate-bearing zone. This result supports the fact that we could not obtain any clear evidence of gas occurrence just below the methane hydrate-bearing zone in the Nankai Trough well drilling.     

Occurrence of Free-Gas Associated with Methane-Hydrate-Bearing Formations in the MITI Nankai Trough Wells, Offshore Tokai, Japan

Abstract. The MITI Nankai Trough wells were drilled for exploration of methane-hydrate-bearing sediments in association with seismic inferred bottom simulating reflectors (BSRs). In this project, log data showed low velocity compressional-wave (P-wave) layers below methane-hydrate-bearing formations. Dipole shear sonic acoustic tools (DSI) could not acquire accurate compres-sional velocity in this zone, thus it was not possible to accurately correlate between logging, VSP and surface seismic profiles.
Small amount of gas was presumed to cause the problem in obtaining the low velocity P-wave data. VSP interval velocity data was used to assess the DSI inferred low-velocity layer, which showed lower values than the velocity of the drilling muds. Synthetic seismogram was created by VSP-compensated velocity to compare against corridor stack of VSP. As a result, the depths above and below the methane-hydrate-bearing interval were correlated with synthetic seismograms and reflectivity events on the VSP profiles. By using this correlation technique, distribution of methane-hydrate-bearing formations and free-gas-bearing formations can be determined.     

Petrophysical Properties of Natural Gas Hydrates-Bearing Sands and Their Sedimentology in the Nankai Trough

Abstract. The Nankai Trough parallels the Japanese Island, where extensive BSRs have been interpreted from seismic reflection records. High resolution seismic surveys and drilling site-survey wells conducted by the MTI in 1997, 2001 and 2002 have revealed subsurface gas hydrate at a depth of about 290 mbsf (1235 mbsl) in the easternmost part of Nankai Trough. The MITI Nankai Trough wells were drilled in late 1999 and early 2000 to provide physical evidence for the existence of gas hydrate. During field operations, continuous LWD and wire-line well log data were obtained and numerous gas hydrate-bearing cores were recovered. Subsequence sedimentologic and geochemical analyses performed on the cores revealed important geologic controls on the formation and preservation of natural gas hydrate. This knowledge is crucial to predicting the location of other hydrate deposits and their eventual energy resource. Pore-space gas hydrates reside in sandy sediments from 205 to 268 mbsf mostly filling intergranular porosity. Pore waters chloride anomalies, core temperature depression and core observations on visible gas hydrates confirm the presence of pore-space hydrates within moderate to thick sand layers. Gas hydrate-bearing sandy strata typically were 10 cm to a meter thick. Gas hydrate saturations are typically between 60 and 90 % throughout most of the hydrate-dominant sand layers, which are estimated by well log analyses as well as pore water chloride anomalies.
It is necessary for evaluating subfurface fluid dlow behavious to know both porosity and permeability of gas hydrate-bearing sand to evaluate subsurface fluid flow behaviors. Sediment porosities and pore-size distributions were obtained by mercury porosimetry, which indicate that porosities of gas hydrate-bearing sandy strata are approximately 40 %. According to grain size distribution curves, gas hydrate is dominant in fine- to very fine-grained sandy strata.     

Geochemical Process of Gas Hydrate Formation in the Nankai Trough Based on Chloride and Isotopic Anomalies in Interstitial Water

Abstract: Interstitial water expelled from gas hydrate-bearing and -free sediments in the Nankai Trough are analyzed in terms of Cl-, SO₄²-, δ¹⁸O and δD. The baselines for the Cl- concentration and δ¹⁸O value are close to seawater values (530 mM and 0%), indicating that the interstitial water is of seawater origin. The δD values decrease with depth, implying isotopic exchange of hydrogen between upwelling biogenic methane depleted in D and interstitial water. The Cl- concentrations in gas hydrate-bearing sediments are anomalously low, while the δ¹⁸O and δD values are both high, suggesting that the water forming these gas hydrates was poor in Cl- and enriched in ¹⁸O and D during gas hydrate formation. Calculation of the gas hydrate saturations using Cl "and δ¹⁸O anomalies gives results of up to 80 % in sand, and shows that the δ¹⁸O baseline is not consistent with the Cl" baseline. The δ¹⁸O baseline increases by +1% in gas hydrate-free clay and silt. This is considered to be caused by clustering of water molecules after gas hydrate dissociation in response to the upward migration of the base of gas hydrate stability, as indicated by the presence of a double bottom-simulating reflector at this site. The water clusters enriched in ¹⁸O are responsible for the increase in the δ¹⁸O baseline with normal Cl". The abrupt shallowing of the base of gas hydrate stability may induce the dissociation of gas hydrates and the accumulation of gases in the new stability zone, representing a geological process that increases gas hydrate saturation.     

High Resolution, Deep-Tow Seismic Survey to Investigate the Methane Hydrate Stability Zone in the Nankai Trough

Abstract. A high frequency deep-tow seismic survey was carried out in the Nankai Trough area in 1996. The objective of the survey was to obtain high resolution seismic sections and velocity profiles of the methane hydrate zone, inferred from the strong BSR events seen on conventional seismic data in the area. A special feature of the survey is that both the source and the streamer cable are towed close to the seabed. This special acquisition geometry requires special data processing to handle the varying source and receiver depths. A CMP floating datum processing sequence was designed which led to high quality sections of the shallow geology. A key step in the processing was devising a residual statics technique to compensate for errors in the measured depths.
The processing sequence was applied to a number of lines, totaling 200 km. The final data quality was highly variable. Some lines produced high quality sections and others, much poorer sections with few interpretable events. Conventional seismic data in the area also shows variation in the data quality so part of the reason is a variation in the sub-sea geology, but the deep-tow data is much more sensitive to change in conditions than conventional data. With the current acquired data and processing sequence the deep-tow system offers most advantages when 1) the water depth is around 1 km or greater, 2) the seabed and underlying geology is not too complex, and 3) the acquisition proceeds smoothly with regular shotpoints, slowly varying depths, and with accurate positioning.     

Lithology, Biostratigraphy, and Magneto stratigraphy of Gas Hydrate-Bearing Sediments in the Eastern Nankai Trough

Abstract: Stratigraphic controls on the formation and distribution of gas hydrates were examined for sediments from a BH-1 well drilled in the landward slope of the Nankai Trough, approximately 60 km off Omaezaki, Japan. Three lithologic units were recognized in the 250 m-thick sequence of sediments: Unit 1 (0–70 mbsf) consists of calcareous silt and clay with thin volcanic ash layers, Unit 2 (70–150 mbsf) consists of calcareous silt and clay with volcanic ash and thin sand layers, and Unit 3 (150–250 mbsf) consists of weakly consolidated calcareous silt and clay with thick and frequent sand layers. Soupy structures and gas bubbles in the sediments indicate the presence of two hydrate zones between 40 and 130 mbsf and below 195 mbsf. Nannofossil biostratigraphy and magnetostratigraphy indicate that the sequence recovered at the BH-1 well is mostly continuous and represents sediments deposited from 0 to 1.5 Ma. Calculation of the sedimentation rate reveals a condensed section between 65 and 90 mbsf. The inferred distribution of gas hydrates in the BH-1 well appears to be strongly controlled by the stratigraphy and lithology of the sediments. Thick, gently inclined sand layers in Unit 3 provide a conduit for the migration of gases from deeper regions, and are considered responsible for the formation of the hydrate zone below 195 mbsf. At shallower levels, thin, gently inclined sand layers are also considered to allow for the migration of gases, leading to the formation of the upper hydrate zone between 40 and 130 mbsf. The overlying sub-horizontal silt and clay of the condensed section, truncating the underlying gently inclined sand and silt/clay layers, may provide an effective trap for gases supplied through the sand layers, further contributing to hydrate formation in the upper hydrate zone.     

Terrestrial organic matter controlling gas hydrate formation in the Nankai Trough accretionary prism, offshore Shikoku, Japan

Sediment core samples from Sites 1175, 1176, and 1178, ODP Leg 190, Nankai Trough were analyzed for sedimentary organic matter and inorganic elemental compositions to clarify geochemical conditions for the formation of gas hydrate. Low chloride concentrations and anomalously low core temperature infer the existence of gas hydrate at Site 1178. Trace amounts of gas hydrate are also suggested for Site 1176. Site 1175 does not have any significant evidence of gas hydrate, although all the three sites are within the gas hydrate stability zone. The sediment from Site 1178 is characterized by abundant terrigenous organic matter, older geologic ages, and comparatively higher maturity levels, suggesting high rates of CO₂ generation during diagenesis. The CO₂ generation potential of sediment may be one of the crucial conditions for the formation of gas hydrate.     

冲绳海槽天然气水合物稳定带厚度的计算

水合物稳定带（HSZ）的研究对天然气水合物的成矿与分布规律以及资源评价研究都具有重要的指导意义，文章根据天然气水合物的相平衡条件和相应的压力-温度方程，参照有关的身体算法，讨论了海底天然气水合物稳定带厚度的理论计算方法，并根据稳定带厚度的理论计算方法，在Windows中文平台上编制了简单实用的程序，利用该程序对冲绳海槽水合物稳定带的厚度进行了计算，并讨论了冲绳海槽水合物稳定带厚度的分布特征。     

Detection and Evaluation of Gas Hydrates in the Eastern Nankai Trough by Geochemical and Geophysical Methods

Abstract: Interstitial waters extracted from the sediment cores from the exploration wells, “BH‐1” and “MITI Nankai Trough”, drilled ～60 km off Omaezaki Peninsula in the eastern Nankai Trough, were analyzed for the chloride and sulfate concentrations to examine the depth profiles and occurrence of subsurface gas hydrates. Cored intervals from the seafloor to 310 mbsf were divided into Unit 1 (～70 mbsf, predominated by mud), Unit 2 (70–150 mbsf, mud with thin ash beds), Unit 3 (150–250+ mbsf, mud with thin ash and sand), and Unit 4 (275–310 mbsf, predominated by mud). The baseline level for Cl “concentrations was 540 mM, whereas low chloride anomalies (103 to 223 mM) were identified at around 207 mbsf (zone A), 234–240 mbsf (zone B), and 258–265 mbsf (zone C) in Unit 3. Gas hydrate saturation (Sh %) of sediment pores was calculated to be 60 % (zone A) to 80 % (zones B and C) in sands whereas only a few percent in clay and silt. The total amount of gas hydrates in hydrate‐bearing sands was estimated to be 8 to 10 m³ of solid gas hydrate per m², or 1.48 km³ CH₄ per 1 km². High saturation zones (A, B and C) were consistent with anomaly zones recognized in sonic and resistivity logs. 2D and high‐resolution seismic studies revealed two BSRs in the study area. Strong BSRs (BSR‐1) at ～263 mbsf were correlated to the boundary between gas hydrate‐bearing sands (zone C) and the shallower low velocity zone, while the lower BSRs (BSR‐2) at～289 mbsf corresponded to the top of the deeper low velocity zone of the sonic log. Tectonic uplift of the study area is thought to have caused the upward migration of BGHS. That is, BSR‐1 corresponds to the new BGHS and BSR‐2 to the old BGHS. Relic gas hydrates and free gas may survive in the interval between BSR‐1 and BSR‐2, and below BSR‐2, respectively. Direct measurements of the formation temperature for the top 170 m interval yield a geothermal gradient of ～4.3d?C/ 100 m. Extrapolation of this gradient down to the base of gas hydrate stability yields a theoretical BGHS at～230 mbsf, surprisingly ～35 m shallower than the base of gas hydrate‐bearing sands (zone C) and BSR‐1. As with the double BSRs, another tectonic uplift may explain the BGHS at unreasonably shallow depths. Alternatively, linear extrapolation of the geothermal gradient down to the hydrate‐bearing zones may not be appropriate if the gradient changes below the depths that were measured. Recognition of double BSRs (263 and 289 mbsf) and probable new BGHS (～230 mbsf) in the exploration wells implies that the BGHS has gradually migrated upward. Tectonically induced processes are thought to have enhanced dense and massive accumulation of gas hydrate deposits through effective methane recycling and condensation. To test the hypothetical models for the accumulation of gas hydrates in Nankai accretionary prism, we strongly propose to measure the equilibrium temperatures for the entire depth range down to the free gas zone below predicted BGHS and to reconstruct the water depths and uplift history of hydrate‐bearing area.     

中国海域的天然气水合物资源

天然气水合物是甲烷等天然气在高压、低温条件下形成的冰状固体物质。据估算,全球天然气水合物中碳的含量等于石油、煤等化石能源中碳含量的2倍。在人类面临化石能源即将枯竭的时候,各国科学家和政府都把目光投向这一未来能替代化石能源的新能源。新生代构造演化历史、沉积条件、沉积环境等显示,南海具有生成和蕴藏巨大天然气水合物资源的条件;南海海域的地震反射剖面多处显示存在BSR反射波;2007年已钻探见到水合物样品。东海冲绳海槽在第四纪的沉积速率高(10~40cm/ka),槽坡存在泥底辟构造和断裂活动,从上新世以来发生过两次构造运动,这些对天然气水合物的形成是十分有利的;因此,中国海域的天然水合物资源是十分丰富的,在不远的将来它可能成为新的替代能源。     

Characteristics of Intraslab Stress Field and Tectonic Implication in the Nankai Trough, Japan

1. IntroductionThe Nankai Trough region (Fig. 1.1) of southwest Japan is one of the most tectonically complex subduction zones in the world. The subduction of the Philippine Sea plate (PH) beneath the Eurasian plate (EU) has caused a series of large and great interplate earthquakes. It is generally accepted that great earthquakes have occurred at intervals of 100-150 years along the Nankai subduction zone since the 684 Hakuho earthquake (Fig. 1.2). However, a large earthquake (M>7.5) has…     

日本南海海槽俯冲增生楔前缘的构造变形特征

对增生楔不同压力—温度条件下的构造变形、流体活动、沉积特征、岩石物性和化学组成等多方面的直接观测,可以帮助分析俯冲带地震的蕴育和发生的环境与机理。通过参加IODP的日本南海海槽发震带研究项目(NanTroSEIZE)第一阶段316航次所收集到的大量第一手数据和资料,分别在4个站位上(C0004,C0006,C0007,C0008)对日本南海海槽增生楔前缘岩芯尺度上的构造变形进行了详细分析,并且讨论了岩芯尺度上的构造变形与增生楔中大尺度的非序列分支逆冲断层和前缘逆冲断层的构造变形之间的关系。发现逆冲变形不是只在大尺度的逆冲断层面上进行,而是弥散分布在主逆冲断层面、次级逆冲断层面以及断层面之间的更小的尺度上。小尺度构造的倾向与大尺度断层的倾向有较好的一致性,表明它们是在相同的应力场下所形成的。在增生楔浅部高角度的正断层比较发育,显示张性应力场特征,同时所获得的岩芯尺度上的地层倾角较大并倾向与反射地震以及区域地质分析结果非常吻合,而在深部,特别是在大尺度逆冲断层发育带附近,各种类型的断层、滑移变形带、节理等非常普遍,同时层理与劈理的产状的复杂变化更多地受控于复杂的逆冲断层带的作用。     

An organic geochemical study of KP-2 core on the mud volcano at Nankai Trough

Organic geochemical data was collected from a KP-2 piston core sample obtained from a mud volcano in the Nankai Trough, off the southeast coast of Japan. The Nankai Trough was investigated geologically and was found to have a large amount of methane hydrates. Biomarkers indicating anaerobic oxidation of methane (AOM) were expected to be found in the sediment of the mud volcano collected by KP-2 core. But the gas chromatography-mass spectrometry (GC-MS) analysis of the samples showed only one biomarker related to the methane-oxidizing Archaea, namely 2,6,10,15,19-pentamethyleicosane (PME), could be detected throughout the KP-2 core. Phytane was predominant in the upper part of the KP-2 core; however, a series of 2,2-dimethylalkanes (2,2-DMAs) were characterized in the lower part of KP-2 core. The individual δ¹³C values of 2,2-DMAs, which were − 29.1 to − 27.3‰ indicate that the origin of 2,2-DMAs was not related to methane-oxidizing Archaea.     

Borehole image analysis of the Nankai Accretionary Wedge, ODP Leg 196: Structural and stress studies

Electrical images recorded with Resistivity-At-Bit (RAB) from two sites drilled during Ocean Drilling Program (ODP) Leg 196 were analyzed to study the effects of subduction at the Nankai margin. For the first time in the history of scientific deep-sea drilling in ODP, in situ complete borehole images of the décollement zone were obtained. Analyses of all drilling-induced fracture data indicated that the maximum horizontal compressive stress (S_Hmax) axes have an azimuth of 303°, and analyses of breakout data from RAB images indicated an azimuth of 310°. These azimuths approximate the convergence direction of the Philippine Sea plate towards the Eurasian plate. The frontal thrust at Site 808 was encountered at about 389 mbsf. Density, porosity, resistivity, and gamma ray data change across the frontal thrust. The décollement zone at the deformation front was identified between 937 and 965 mbsf. The base of the décollement is sharply defined as the maximum extent of conductive fracturing and is marked by abrupt changes in physical properties [Mikada, H., Becker, K., Moore, J.C., Klaus, A., Austin, G.L., Bangs, N.L., Bourlange, S., Broilliard, J., Brückmann, W., Corn, E.R., Davis, E.E., Flemings, P.B., Goldberg, D.B., Gulick, S.S., Hansen, M.B., Hayward, N., Hills, D.J., Hunze, S., Ienaga, M., Ishiguro, H., Kinoshita, M., Macdonald, R.D., McNeill, L., Obana, S., Hong, O.S., Peacock, S., Pettigrew, T.L., Saito, S., Sawa, T., Thaiprasert, N., Tobin, H.J., Tsurumi, H., 2002. Proc. ODP, Initial Rep., 196, College Station, TX, (Ocean Drilling Program)]. The upper boundary of the décollement is marked by several sets of conductive fractures and by high variability in physical properties. The décollement zone is characterized by intense brittle fracturing. These fractures are considered to be the consequence of cyclic stresses and high fluid pressures in this zone. We analyzed fracture dips and their orientations at both sites and found that they are all consistent with a unique stress field model surrounding the two sites.     

过冷度对气体水合物合成影响的实验研究

过冷度是甲烷水合物合成过程的主要驱动力,在沉积物中进行不同过冷度下甲烷水合物合成实验,有利于找出水合物合成过程的动力学影响因素,进而研究自然界沉积物中水合物的成藏过程。在定容条件下,以不同的过冷度进行甲烷水合物在沉积物中的合成实验。实验结果表明甲烷水合物在沉积物条件下的合成过程包括气液溶解、核化、生长、稳定4个阶段。在相同初始状态,不同过冷度条件下的水合物合成后系统状态均处在相平衡曲线上,而随着过冷度的减小,气体转换率和水合物的饱和度不断降低。通过实验数据回归得出在沉积物条件下过冷度与甲烷水合物诱导时间的经验关系式。通过对比发现,沉积物中水合物合成所需要的过冷度仅为2.5 ℃,大大低于不含沉积物的纯水体系。     

SDS和THF对甲烷水合物合成影响的实验研究

甲烷水合物的人工合成是实验室内进行水合物模拟地层钻探研究的关键步骤。利用水合物合成及模拟微钻实验系统,分别进行了加入少量十二烷基硫酸钠(SDS)和四氢呋喃(THF)的甲烷水合物人工合成试验。通过对比实验,分析研究了SDS和THF对甲烷水合物生成速度及生成量的影响。实验表明,在纯水体系中加入微量的SDS和THF,不仅能够促进甲烷水合物快速成核,还可以增加甲烷水合物的合成量,从而节省了大量的实验时间,这也便于对含水合物沉积地层钻探钻井液设计和水合物模拟地层微钻实验的深入研究。