Neogene oxygen isotopic stratigraphy, ODP Site 1148, northern South China Sea

A detailed stable isotopic study based on benthic foraminifera from 1165 samples of ODP Site 1148 (18° 50.17.3’N, 116° 33.93’E, water depth 3308.3 m), northern South China Sea, provides an excellent oxygen isotopic record with an average resolution of 30 ka. It contains the most continuous δ¹⁸O data with highest resolution for the whole Neogene sequence in the world. The δ¹⁸O curve shows a step-like increasing upwards and records 5 increases, 3 decreases and 2 stable stages during the Neogene, reflecting the general trend of global cooling. Among these events the δ¹⁸O decrease at 17.2–14.5 Ma, and two δ¹⁸O increases at 14.5-13.6 and 3.0-2.4 Ma are most marked and globally comparable. The intervals at 13.6-10.2 and 6.0-3.0 Ma with the lowest-amplitude and least fluctuation in δ¹⁸O represent the most stable bottom water periods for the South China Sea.     

A record of Miocene carbon excursions in the South China Sea

High-resolution δ¹³C records are presented for the Miocene benthic foraminifersCibicidoides wuellerstorfi andC. kullenbergi (24-5 Ma) and the planktonic foraminiferGlobigerinoides sacculifer (18-5 Ma) from ODP Site 1148A (18° 50.17’N, 116° 33.93’E, water depth 3308.3 m), northern South China Sea. The general pattern of parallel benthic and planktonic δ¹³C shows a decrease trend of δ¹³C values from the early-middle Miocene to the middle-late Miocene. Two distinct δ¹³C positive excursions at 23.1-22.2 and 17.3-13.6 Ma, and two negative excursions at 10.2-9.4 and 6.9-6.2 Ma have been recognized. All these events are cosmopolitan, providing the good data for the stratigraphic correlation of the South China Sea with the global oceans as well as for studying the changes of the global carbon reservoir and its corresponding climate.     

Correlation between high-resolution climate records from a Nanjing stalagmite and GRIP ice core during the last glaciation

A 400-mm-long stalagmite from Tangshan Cave, Nanjing has been analyzed by a high-precision TIMS-U series dating method and also determined for oxygen and carbon stable isotopic compositions. The results provided a high-resolution paleoclimate record for eastern China during a time interval (from 54 000 to 19 000 aBP) of the last glaciation. The continuous record of oxygen-18 variations in the stalagmite, indicating a precipitation history of the East Asian monsoon, shows not only signals of the Heinrich events, but also the Dansgaard-Oeschger cycles which are first found in the last glacial climate record of the East Asian monsoon area. Although the stalagmite-based climatic signals match well with the GRIP ice core record, some differences between the two records can be recognized: (1) The last glacial climate changes in eastern China exhibited a long-term remarkably cooling trend, superimposed on which were four successive Bond’s cycles illustrated by the δ¹⁸O curve. This strong cooling tendency may be an effect of the strong summer monsoon event during the MIS 3 over the Tibetan Plateau. (2) There exist some phase differences of 1000–2000 years between the cooling events in the stalagmite-based climate signal and the GRIP ice core record. Such differences should be further verified by calibrations of multiple dating methods     

A possible Younger Dryas-type event during Asian monsoonal Termination 3

1 Introduction The Younger Dryas (YD) cold spell is one of the most prominent abrupt climate change events in the past and a key feature of the last glacial termination. A great agreement has been attained in terms of the tim- ing and geographic extent of…     

Chemocline instability and isotope variations of the Ediacaran Doushantuo basin in South China

Stable isotope analyses in sections across a shelf to basinal transect of the Ediacaran Doushantuo basin show substantial isotope variabilities. In Songlin section where sediments were deposited in an intrashelf basin, δ 13C values are persistently negative (_3‰ to _5‰, VPDB) through the entire Doushantuo Formation, similar to those obtained from the slope section in Wuhe (_5‰ to _10‰, VPDB). Shallow water sections in Weng'an and Duoding show two broad δ 13C anomalies overprinted with significant meter-scale variations, but none of the curves has similar absolute δ 13C values compared to the Yangtze Gorges areas in South China and other sections globally. Such isotope variations, if partially recording ancient seawater signature, imply spatial and temporal chemocline instability in the Doushantuo basin. In combination with available δ 13C records from other Ediacaran successions globally, the data from the Doushantuo basin are consistent, in first order, with the existence and oxidation of a large dissolved organic carbon (DOC) reservoir in Ediacaran oceans, but imply local environmental controls on Neoproterozoic isotope values and call attentions for using δ 13C anomalies as time lines in stratigraphic correlation.     

Source parameters of bohai earthquake, July 18, 1969 and yongshan earthquake, May 11, 1974 determined by synthetic seismograms of teleseismic P waves

The source parameters of the Bohai Sea earthquake, July 18, 1969 and Yongshan, Yunnan earthquake, May 11, 1974 were determined by full — wave theory synthetic seismograms of teleseismic P waves. P+pP+sP wereform were calculated with WKBJ approximation and real integral paths. One — dimensional unilateral, finite propagation source was also considered. By trail — and — error in comparing the theoretical seismograms with the observational ones of WWSSN stations, the source parameters were obtained as follow: for Bohai earthquake, φ=195°, δ=85°, λ=65°,M _o=0.9×10¹⁹Nm,L=59.9km.V _R=3.5km/s, ∧ _R =160°; for Yongshan earthquake, φ=240°, δ=80°, ∧=150°,M _o=1.3×10¹⁸Nm,L=48.8km,V _R=3km/s, ∧ _R =−10°, where φ is strike, δ dip angle, λ slip angle,M _o seismic moment,L rupture length,V _R rupture propagation speed. As III type fractures the faulting propagated along the fault planes, and ∧ _R is the angle from the strike to the propagation direction. Yongshan earthquake showed complexity in its focal process, having four sub—ruptures during the first 60 seconds. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 1–8, 1991.     

Temporal and spatial variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>15</Superscript>N and <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O for atmospheric N<Subscript>2</Subscript>O above the oceanic surface from Shanghai to Antarctica

During the 22nd Chinese Antarctic Research Expedition (CHINARE-22), the atmospheric gas samples above the oceanic surface and near the surface were collected on the track for the scientific ship “Xuelong” and on Millor Peninsula of eastern Antarctica, respectively, using the Tedlar gas bags. Every day the sampling times were 10:00 and 22:00 (local time), respectively. In the laboratory, high-precision measurement of the isotopic compositions for N₂O in these gas samples was conducted using Thermo Finnigan MAT-253 Isotopic Mass Spectrometer with a fully automated interface for the pre-GC concentration (PreCon) of trace gases. The temporal and spatial variations of δ ¹⁵N and δ ¹⁸O in atmospheric N₂O were analyzed. The mean δ ¹⁵N and δ ¹⁸O-N₂O values above the oceanic surface were (7.21±0.50)‰ and (44.52±0.52)‰, respectively. From 30°N to Antarctica, the δ ¹⁵N (6.05‰–7.88‰) linearly increased with the rate of about 0.01‰ with the latitude while the δ ¹⁸O (43.05‰–48.78‰) showed a large fluctuation. The δ ¹⁵N negatively correlated with air temperature and N₂O concentration, and slightly positively correlated with δ ¹⁸O. The summertime variations of δ ¹⁵N and δ ¹⁸O-N₂O appeared the same trend on Millor Peninsula of eastern Antarctica. They significantly positively correlated with each other and negatively with N₂O concentration. The δ ¹⁵N and δ ¹⁸O-N₂O at different sites averaged (7.42±0.35)‰ and (44.69±0.49)‰, respectively, slightly higher than those above the oceanic surface, significantly higher than those of atmospheric N₂O in the low-latitude regions of Northern Hemisphere. The predominant factors affecting the spatial variations of δ ¹⁵N and δ ¹⁸O values were also discussed. The isotopic data given in this study can help to investigate the global and regional N₂O budgets. Supported by the National Natural Science Foundation of China (Grant Nos. 40676005 and 40406001)     

A quick cooling event of the East Asian monsoon responding to Heinrich Event 1: Evidence from stalagmite δ<Superscript>18</Superscript>O records

Based on TIMS U-series dating results and annual band counting method, an annual-resolution time scale from 17450 to 14420 aBP has been established for a stalagmite from the Hulu Cave at Tangshan, Nanjing. A high-resolution oxygen isotopic record reveals decadral-centural oscillations in air temperature in the East Asian monsoon climate area during the last glacial maximum. The most conspicuous feature in the oxygen isotopic record in the period is the particular cold event synchronized with the last Heinrich event (H1) in the northern Atlantic deep-sea records. This particular cold event, beginning at 16140 ± 100 aBP, shows a rapid cooling down with a magnitude of 7–8°C in air temperature within 36 years. Furthermore, δ¹⁸O record demonstrates that the event lasted 790 years with gradually warming tendency (10 cycles of air temperature oscillations) after the remarkable cooling down. We believed that this unique pattern of event recorded in the stalagmite δ⁸O might be controlled by various factors including changes of insolation at mid-latitude Northern Hemisphere, the southern extend of the last ice-rafted event in the North Atlantic and changes of the Equatorial Pacific sea surface temperature.     

湖泊营养类型的FUZZY聚类分析

通过1985—1988年对洱海水体的水质、生物等参数的观测分析,研究其富营养现状及变化规律。结果表明,洱海已从1985年的贫中营养型湖泊向中营养型湖泊过渡。其营养状况的变化与流域气候、湖水水位以及非点源污染有关。     

Chemical and isotopic compositions of thermal springs,fumaroles and bubbling gases at Tacaná Volcano (Mexico–Guatemala): implications for volcanic surveillance

This study presents baseline data for future geochemical monitoring of the active Tacaná volcano–hydrothermal system (Mexico–Guatemala). Seven groups of thermal springs, related to a NW/SE-oriented fault scarp cutting the summit area (4,100m a.s.l.), discharge at the northwest foot of the volcano (1,500–2,000m a.s.l.); another one on the southern ends of Tacaná (La Calera). The near-neutral (pH from 5.8 to 6.9) thermal (T from 25.7°C to 63.0°C) HCO₃–SO₄ waters are thought to have formed by the absorption of a H₂S/SO₂–CO₂-enriched steam into a Cl-rich geothermal aquifer, afterwards mixed by Na/HCO₃-enriched meteoric waters originating from the higher elevations of the volcano as stated by the isotopic composition (δD and δ¹⁸O) of meteoric and spring waters. Boiling temperature fumaroles (89°C at ~3,600m a.s.l. NW of the summit), formed after the May 1986 phreatic explosion, emit isotopically light vapour (δD and δ¹⁸O as low as −128 and −19.9‰, respectively) resulting from steam separation from the summit aquifer. Fumarolic as well as bubbling gases at five springs are CO₂-dominated. The δ¹³C_CO2 for all gases show typical magmatic values of −3.6 ± 1.3‰ vs V-PDB. The large range in ³He/⁴He ratios for bubbling, dissolved and fumarolic gases [from 1.3 to 6.9 atmospheric ³He/⁴He ratio (R _A)] is ascribed to a different degree of near-surface boiling processes inside a heterogeneous aquifer at the contact between the volcanic edifice and the crystalline basement (⁴He source). Tacaná volcano offers a unique opportunity to give insight into shallow hydrothermal and deep magmatic processes affecting the CO₂/³He ratio of gases: bubbling springs with lower gas/water ratios show higher ³He/⁴He ratios and consequently lower CO₂/³He ratios (e.g. Zarco spring). Typical Central American CO₂/³He and ³He/⁴He ratios are found for the fumarolic Agua Caliente and Zarco gases (3.1 ± 1.6 × 10¹⁰ and 6.0 ± 0.9 R _A, respectively). The L/S (5.9 ± 0.5) and (L + S)/M ratios (9.2 ± 0.7) for the same gases are almost identical to the ones calculated for gases in El Salvador, suggesting an enhanced slab contribution as far as the northern extreme of the Central American Volcanic Arc, Tacaná.     

Geochemical model of a magmatic–hydrothermal system at the Lastarria volcano, northern Chile

Lastarria volcano (25°10′ S, 68°31′ W; 5,697 m above sea level), located in the Central Andes Volcanic Zone (northern Chile), is characterized by four distinct fumarolic fields with outlet temperatures ranging between 80°C and 408°C as measured between May 2006–March 2008 and April–June 2009. Fumarolic gasses contain significant concentrations of high temperature gas compounds (i.e., SO₂, HCl, HF, H₂, and CO), and isotopic ratios (³He/⁴He, δ¹³C–CO₂, δ¹⁸O–H₂O, and δD–H₂O) diagnostic of magmatic gas sources. Gas equilibria systematics, in both the H₂O-H₂-CO₂-CO-CH₄ and alkane–alkene C₃ system, suggest that Lastarria fumarolic gasses emanate from a superheated vapor that is later cooled and condensed at relatively shallow depths. This two-stage process inhibits the formation of a continuous aquifer (e.g., horizontal liquid layer) at relatively shallow depth. Recent developments in the magmatic gas system may have enhanced the transfer and release of heat causing shallow aquifer vaporization. The consequent pressure increase and aquifer vaporization likely triggered the inflation events beginning in 2003 at the Lastarria volcano.     

Variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O in precipitation from the Muztagata Glacier,East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ ¹⁸O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ ¹⁸O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ ¹⁸O and temperature suggests that δ ¹⁸O can be used as an indicator of temperature in this region. The δ ¹⁸O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.     

Preliminary results of the close-off depth and the stable isotopic records along a 109.91 m ice core from Dome A,Antarctica

A 109.91 m ice core was recovered from Dome A (or Dome Argus), the highest ice feature in Antarctica, during the 2004/05 austral summer by the 21st Chinese National Antarctic Research Expedition (CHINARE-21). Both methane profile along the core and firn densification model calculation suggest that the close-off depth is at about 102.0 m with an ice age about 4200 a. Stable isotopes (δ18O and δD) of the chips samples produced during each run of ice core drilling at Dome A, together with those of the other co...     

An abrupt cooling event early in the last interglacial in the northern South China Sea

The high-resolution quantitative analysis of the planktonic foraminifera and the δ¹⁸O records of the section between 96.49– 137.6 mcd at ODP Site 1144 on the continental slope of northern South China Sea reveals an abrupt cooling event of sea surface temperature (SST) during the last interglacial (MIS 5.5, i.e. 5e). The dropping range of the winter SST may come to 7.5°C corresponding to 1.2‰ of the δ¹⁸O value of sea surface water. This event is comparable with those discovered in the west Europe and the northern Atlantic Ocean, but expressed in a more intensive way. It is inferred that this event may have been induced by middle- to low-latitude processes rather than by polar ice sheet change. Since the Kuroshio-index speciesPulleniatina obliquiloculata displayed the most distinct change at the event, it may also be related to the paleoceanographic change of the low-latitude area in the western Pacific Ocean. This event can be considered as one of “Younger Dryas-style coolings” and is indicative of climate variability of the last interglacial stage.     

Strontium isotope geochemistry of the Lemachang independent silver ore deposit, northeastern Yunnan, China

Sr isotope geochemical studies (the 87Sr/86Sr and ?18O-87Sr/86Sr systems) on the wall rocks and ores from the Lemachang independent Ag deposit in northeastern Yunnan provide strong evidence that the ore-forming fluids had flown through radiogenetically Sr-enriched rocks or strata prior to their entry into the locus of ore precipitation, and water-rock interaction is the main mechanism of Ag ore precipitation. The radiogenetically Sr-enriched source region may be the Proterozoic basement (the Kunyang and Hekou groups). Moreover, the theoretical modeling of the Sr isotopic system indicates that the ore-forming fluids contain as much as 3×10?6 Sr with isotopic composition of Sr being 0.750 and that of oxygen 7.0‰. The ore-forming temperatures were estimated at 150-250℃ for the carbonate rock-type ores and at 200-260℃ for the clastic rock-type.     

Long-term variations in the second sectorial Stokes harmonics on the basis of TOPEX/POSEIDON altimetry between 1993 and 2000

The long-term variations in the second degree sectorial Stokes parameters of the geopotential have been determined from TOPEX-POSEIDON (T/P) satellite altimeter data, covering the period of January 1, 1993 to January 3, 2001 (T/P cycles 11-305). It is the first attempt to determine the variations in the second sectorial harmonics in the Earth’s inertia tensor due to the ocean dynamics. The variations amount to about 1 × 10⁻¹⁰ (J ₂ ⁽²⁾ ≈ 1.6 × 10⁻⁶ and S ₂ ⁽²⁾ ≈ −0.9 × 10⁻⁶). The variations are about 5% of the tidal effect. This corresponds to variations in the directions of the equatorial axes of the Earth’s inertia ellipsoid of up to 10 arc-seconds. Consequently, the annual and semi-annual variations of the Earth’s equatorial flattening is about 10⁻⁹; i.e. it corresponds to a change of 8 units of its denominator of 91 030. (The equatorial flattening ≈ 1/91 030). Since the coverage of the Earth’s ocean surface is not worldwide, and the inclination of T/P is i = 66°, it is only 58.2% (min. depth of the ocean 2 000 m) of the Earth’s surface which is processed, the torque, resulting from the seasonal transfer of masses within a sea surface layer, is not zero. It amounts up to 10¹⁶ kg m²s⁻², which is comparable to the total indirect tidal torque due to the Moon and the Sun, ∼ 3.9 × 10¹⁶ kg m²s⁻². However, the above estimate strongly depends on the adopted thickness of the sea surface layer, ΔR = 50 m. For a larger thickness of ΔR = 100 m, the seasonal torque amounts to about ∼ 2.3 × 10¹⁶ kg m²s⁻².     

Stable isotopic studies of dinosaur eggshells from the Nanxiong Basin, South China

Stable carbon and oxygen isotopes have been observed in dinosaur eggshell samples,identified as Macroolithus yaotunensis,collected in two sections of the Nanxiong Basin,Guangdong Province,South China.Multiple positiveδ18O perturbations that occurred during the K/T transition of about 150 ka suggest that there may have been at least three periods of the extreme dry climate with a mean annual air temperature over 27℃.δ13C ranges from -8.37‰ to -11.60‰ of the dinosaur eggshells,added to the metabolic enrichment of 16‰,may indicate that the dinosaurs represented by this type of eggshells probably consumed the plant species of C3 type with the δ13C values of -24.3‰- -27.6‰.Moreover,the trend toward more negative δ13C values of the eggshells during the K/T transition could be an indirect consequence of a lasting increase in atmospheric CO2 concentration.     

Temporal variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O of atmospheric water vapor at Delingha

Oxygen stable isotope of atmospheric water vapor is widely used to study the modern process of climate. Atmospheric water vapor samples were collected at Dlingha, northeast of Tibetan Plateau during the period from July 2005 to February 2006. The variation of δ ¹⁸O and the relationships between δ ¹⁸O and both the temperature and specific humidity are analyzed in this paper. Results show that the seasonal variation of δ ¹⁸O of atmospheric water vapor at Delingha is remarkable with higher δ ¹⁸O in summer and lower δ ¹⁸O in winter. The temporal variation of vapor δ ¹⁸O shows obvious fluctuations, with magnitude of over 37‰ The daily variation of the δ ¹⁸O is highly correlated with air temperature. The relationship between δ ¹⁸O and atmospheric water vapor content is complex. Study shows that δ ¹⁸O of atmospheric water vapor is positively correlated with specific humidity in winter in seasonal scale and inversely correlated with specific humidity in summer rainy period. The δ ¹⁸O values of atmospheric water vapor are lower than those of precipitation at Delingha, and the average difference is 10.7‰ Variations of δ ¹⁸O of atmospheric water vapor is also found to be affected by precipitation events, The model results show that the precipitation effect could have caused the vapor δ ¹⁸O in the raining season to lower by 7% in average in July and August. Supported by the National Natural Science Foundation of China (Grant Nos. 40671043, 40571039 and 40771048) and National Basic Research Program of China (Grant No. 2005CB422002)     

Stable isotopic records of the glacial deep-water properties in the South China Sea

Based on the oxygen and carbon stable isotopic records of benthic foraminifera in nine deep-sea cores of the South China Sea (SCS), the bathymetric profiles of δ¹⁸O and δ¹³C since the last glacial maximum (LGM) are preliminarily established. The bathymetric gradients of deep-water δ¹⁸O and δ¹³C in the SCS are obviously greater during the LGM than during the Holocene, showing the existence of the deep thermocline and nutricline at water depth of about 2 000 m. Particularly, the differences in δ¹⁸O and δ¹³C between the LGM and Holocene, from which the ice-volume effect and the global mean shift have been subtracted respectively, are positive values at water depths of 1 000–2 500 m in the SCS. This indicates the existence of deep-water mass with relatively cool temperature or higher salinity, better ventilation and more δ¹³C within the water depth range of the SCS during the LGM, which is distinctly different from that at present. These changes further confirm the existence of the glacial “North Pacific Deep Water” which, however, is possibly confined to the water depth range of 1 000–2 500 m. Project supported by the National Natural Science Foundation of China (Grant Nos. 49576286 and 49732060).     

Climatic significance of δ <Superscript>18</Superscript>O records from an 80.36 m ice core in the East Rongbuk Glacier,Mount Qomolangma (Everest)

The δ ¹⁸O variations in an 80.36 m ice core retrieved in the accumulation zone of the East Rongbuk Glacier, Mount Qomolangma (Everest), is not consistent with changes of air temperature from both southern and northern slopes of Himalayas, as well as these of the temperature anomalies over the Northern Hemisphere. The negative relationship between the δ ¹⁸O and the net accumulation records of the ice core suggests the “amount effect” of summer precipitation on the δ ¹⁸O values in the region. Therefore, the δ ¹⁸O records of the East Rongbuk ice core should be a proxy of Indian Summer Monsoon intensity, which shows lower δ ¹⁸O values during strong monsoon phases and higher values during weak phases.