Morphology and mineralogy of weathering crusts on highly porous oolitic limestones, a case study from Budapest

Black crusts are very common on limestones in polluted urban environments, but white crusts are less frequently developed. On the soft, porous and inherently weak oolitic limestone of Budapest both crusts are frequent, and indeed white ones are more common on the stone walls of the studied fortress. In this paper, black and white crusts and the host rock have been described using morphological criteria, mineralogical analyses (XRD, DTA), elements analyses (microprobe) and micro-morphological (SEM) tests. The analyses have shown that on white crusts the surface dissolution is combined with the precipitation of gypsum and calcite in the pores and accumulation of gypsum on the underside of the crust. Thin white crusts are removed by a combination of salt crystallisation (gypsum) and frost action while very thick stone layers scale off due to freeze-thaw cycles. Black crusts are enriched in gypsum relative to white crusts. Gypsum accumulates on the crust surface and signs of dissolution have not been observed. Airborne particulates (flyash, silt-sized quartz, and organic debris) adhere to the crust surface of sheltered black crusts. These particles are later incorporated into the expanding gypsum crystals, that are visible on the underside of the crust. The host rock also contains gypsum, but it is washed off the surface when the crust is removed. Further exposure of the host rock may lead to the dissolution of calcite crystals as it is observed by SEM. The micro-environment influences the crust formation and adherence of the crusts. On frequently wet and dry surfaces crust removal is more common. The crust serves as a protective layer on the stone surface, but this protection is temporary since trigger mechanisms such as salt crystallisation or frost action can cause rapid surface loss.Special Issue: Stone decay hazards     

Effect of groundwater and sea weathering cycles on the strength of chalk rock from unstable coastal cliffs of NW France

The aim of this paper is to evaluate the role of groundwater and sea weathering on the strength of the chalk rocks exposed on the coastline of the English Channel in Normandy, NW France. We present a study of the rock strength variations of three representative chalk units (Lewes Chalk, Seaford Chalk and Newhaven Chalk) exposed at various locations on the coastal chalk cliffs. The combination of UCS tests and SEM observations have been used (1) on dry natural chalk samples, (2) on chalk samples at various moisture contents, (3) on dry chalk samples submitted to a 10-day cycle of alternating wetting and drying by distilled water and by sea water. Dry chalk samples show low UCS strength (3.46–4 MPa) indicative of very weak rocks. When chalk samples are submitted to progressive water wetting, they present a decrease of UCS strength and Young's modulus of 40% to 50%. This behaviour begins at low values of water content within the chalk, i.e., for a degree of water saturation ranging between 10% and 17%. When chalk samples are submitted to an artificial weathering cycle with distilled water, a decrease in strength is observed, whereas the Young's modulus increases. SEM observations indicate the occurrence of microcracks and particle aggregates in the sample. When chalk samples are submitted to an artificial weathering with sea water, the decrease of UCS strength and Young's modulus achieves a minimum. SEM observations indicate salt crystals within the chalk. On the coastal cliffs of NW France, weathering processes depend both on chalk lithology, which show a range of sensitivity to weathering and on the location of the chalk in the coastal area. Processes allied to the degree of weathering (e.g., salt crystallisation or fresh water disaggregation) differ in the chalk massif, on the cliff face and on the shore platform.     

The influence of petrophysical properties on the salt weathering of porous building rocks

The influence of pore structure, water transport properties and rock strength on salt weathering is evaluated by means of a thorough rock characterisation and a statistical analysis. The pore structure was described in terms of its porosity, pore size distribution (quantified by mean pore radius) and specific surface area, density and water transport was characterised by means of water permeability (saturated flow) and capillary imbibition (unsaturated flow); whilst the rock strength test was carried out using uniaxial compressive strength, compressional and shear wave velocities, dynamic elastic constants and waveform energy and attenuation were obtained from the digital analysis of the transmitted signal. A principal component analysis and a stepwise multiple regression model was carried out in order to examine the direct relationships between salt weathering and petrophysical properties. From the principal component analysis, two main components were obtained and assigned a petrophysical meaning. The first component is mostly linked to mechanical properties, porosity and density whereas the second component is associated with the water transport and pore structure. Salt weathering, quantified by the percentage of weight loss after salt crystallisation, was included in both principal components, showing its dependence on their petrophysical properties. The stepwise multiple regression analysis found that rock strength has a predominant statistical weight in the prediction of salt weathering, with a minor contribution of water transport and pore structure parameters.     

The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates

Saline solution properties, viscosity in particular, are shown to be critical in salt weathering associated with sodium and magnesium sulfate crystallization in porous limestone. The crystallization of sodium and magnesium sulfate within a porous limestone has been studied at a macro- and microscale using different techniques, including mercury intrusion porosimetry, environmental scanning microscopy and X-ray computed tomography. Such analysis enabled the visualization of the crystallization process in situ, and at high magnification, yielding critical information as to where and how salts crystallize. Sodium sulfate decahydrate (mirabilite) tends to crystallize in large pores as euhedral micron-sized crystals formed at low supersaturation near to the surface of the stone. In contrast, magnesium sulfate heptahydrate (epsomite) tends to precipitate as anhedral wax-like aggregates formed at high supersaturation and distributed homogeneously throughout the stone pore system filling large and small pores. While the former crystallization behavior resulted in scale formation, the latter led to crack development throughout the bulk stone. Ultimately, the contrasting weathering behavior of the two sulfates is explained by considering differences in flow dynamics of solutions within porous materials that are mainly connected with the higher viscosity of magnesium sulfate saturated solution (7.27 cP) when compared with sodium sulfate saturated solution (1.83 cP). On the basis of such results, new ways to tackle salt weathering, particularly in the field of cultural heritage conservation, are discussed.     

Laboratory and pilot studies on reclamation of a salt-affected alluvial soil

Soil column experiments showed that a surficial sodic soil is efficiently reclaimed using freshwater, after the addition of saturated gypsum solution. Gypsum application in the field was beneficial in terms of maintaining high soil permeability, increased water infiltration and neutral pH after a rainfall event. In the present paper, two different reclamation techniques for the plough layer of a sandy loam sodic soil were tested in laboratory columns, 25 cm long and 10 cm in diameter; the first using freshwater alone and the second using a saturated gypsum solution. The dynamics of salt removal were studied by continuous analysis of the water drained from the bottom of the columns. When freshwater was used, sodium presented the lower removal rate and adversely affected soil permeability. When gypsum solution was used, calcium was present in the flushing solution and the effect of sodium dominance on clay dispersion and soil clogging was limited. The results presented in this study are of practical importance with respect to the reclamation of sodic soils found in the coastal area of the east Nestos Delta, Greece, where freshwater is limited, due to seawater intrusion, and saline groundwater is used for irrigation.     

Constraints on paleowater dissolved loads and on catchment weathering over the past 16 ka from Sr/Sr ratios and Ca/Mg/Sr chemistry of freshwater ostracode tests in sediments of Lake Constance, Central Europe

Sr isotope and Ca/Mg/Sr chemical compositions of freshwater ostracode tests separated from a sediment core represent the last 16 ka of sedimentation in Lake Constance, Central Europe. The chemical evolution of the paleowater's dissolved load of Lake Constance was estimated by correcting the ostracode data for Ca/Mg/Sr fractionation due to biogenic calcification. Since the Late Pleistocene deglaciation, the Ca/Sr molar ratios of paleowaters increased systematically from about 100 (a near marine signature) to about 200. Ca/Mg molar ratios varied in the range of 1–25. The ⁸⁷Sr/⁸⁶Sr ratios indicate Late Pleistocene paleowater compositions of 0.7086–0.7091, significantly more radiogenic than present day waters (0.7085). Sr isotopes and Ca/Mg/Sr chemical data together show that weathering of Mesozoic evaporites consistently dominated the dissolved Sr load (80–90%). Carbonate and silicate weathering were less important (1–10%). Trends of Sr dissolved loads were therefore not related to Mg which was mainly mobilized by carbonate weathering. Biotite weathering was an important source of radiogenic Sr in the paleowaters. The short-term release (duration about 600–800 years) of radiogenic Sr during glacier retreat started 15.2 ka ago and was due to enhanced biotite weathering at the glacier base. Long-term release of radiogenic Sr was due to biotite weathering in glacial soils and silicate rocks, and has gradually declined since the Late Pleistocene/Holocene transition.     

Influence of shear speed and normal stress on the shear behavior and shear zone structure of granular materials in naturally drained ring shear tests

“Sliding Surface Liquefaction” is a process causing strength loss and consequent rapid motion and long runout of certain landslides. Using a new ring shear apparatus with a transparent shear-box and digital video camera system, shear-speed-controlled tests were conducted on mixed grains (mixture of three different sizes of sand and gravel) and mixed beads to study shear behavior and shear zone development process under the naturally drained condition in which pore pressure is allowed to dissipate through the opened upper drainage valve during shearing. Higher excess pore water pressure and lower minimum apparent friction were observed in the tests where grain crushing was more extensive under higher normal stress and higher shear speed. Along with the diffusion of silty water generated by grain crushing, smaller particles were transported upward and downward from the shear zone. Concentration of larger grains to the central and upper part of the shear zone was confirmed by means of visual observation together with grain size analysis of sliced samples from several layers after the test. On the other hand, smaller particles were accumulated mostly below the layer where larger grains were accumulated. The reason why larger grains were accumulated into the shear zone may be interpreted as follows: grains under shearing are also subjected to vertical movement, the penetration resistance of larger grains into a layer of moving particles is smaller than that into the static layer. Therefore, larger grains tend to move into the layer of moving grains. At the same time, smaller particles can drop into the pores of underlying larger grains downward due to gravity.