Evolution of an early Proterozoic foreland basin carbonate platform, lower Pethei Group, Great Slave Lake, north-west Canada

The Taltheilei, Utsingi, McLean and Blanchet formations form a 175–390 m thick carbonate platform-to-basin succession in the lower part of the PaleoProterozoic Pethei Group, preserved in the eastern arm of Great Slave Lake. Carbonates accumulated along the south-east margin of the Slave Craton within a foredeep formed during the collision of the Slave and Churchill Cratons. The rocks include eight, predominantly microbial, carbonate facies that comprise five facies associations representing (1) shallow-water rimmed shelf, (2) shallow-water open shelf, (3) shallow-water ramp, (4) upper slope and deep ramp, and (5) lower slope and basin plain environments. Microbialite facies grew by organically mediated precipitation of spar and micritic cement and trapping and binding of lime mud. These wholly subtidal facies typically reflect progressive shallowing and changing geometry of the lower Pethei sea floor, from ramp, to open shelf, to shallow rimmed shelf, with associated slope and basin plain deposition. Repeated relative sea-level changes influenced platform growth. This resulted in five shallowing upward packages; each separated by an incipient drowning event of varying magnitude. Antecedent topography and the size of the preceding drowning event strongly influenced the initial growth of each interval. This repeated pattern is attributed to interaction between (a) the inherent tendency of microbial carbonates to aggrade vertically, (b) changing sedimentation rates and (c) readjustments of relative base level. The lower Pethei succession is one of few PaleoProterozoic examples of carbonate platform growth within a foreland basin. It has (1) a low gradient profile, (2) extensive slope and basin plain carbonate production and sedimentation, (3) no ooids, (4) minor terrigenous clastic sediments, and (4) a mobile, submergent shelf rim lacking substantial carbonate sand shoals.     

Halite cementation and carbonate diagenesis of intra-salt reservoirs from the Late Neoproterozoic to Early Cambrian Ara Group (South Oman Salt Basin)

Late Neoproterozoic to Early Cambrian carbonates of the Ara Group form important intra‐salt ‘stringer’ reservoirs in the South Oman Salt Basin. Differential loading of thick continental clastics above the six carbonate to evaporite cycles of the Ara Group led to the formation of salt diapirs, encasing a predominantly self‐charging hydrocarbon system within partly highly overpressured carbonate bodies (‘stringers’). These carbonates underwent a complex diagenetic evolution, with one stage of halite cementation in a shallow (early) and another in a deep (late) burial environment. Early and late halite cements are defined by their microstructural relationship with solid bitumen. The early phase of halite cementation is post‐dated by solid reservoir bitumen. This phase is most pervasive towards the top of carbonate stringers, where it plugs nearly all available porosity in facies with initially favourable poroperm characteristics. Bromine geochemistry revealed significantly higher bromine contents (up to 280 p.p.m.) in the early halite compared with the late halite (173 p.p.m.). The distribution patterns and the (high) bromine contents of early halite are consistent with precipitation caused by seepage reflux of highly saturated brines during deposition of the overlying rock salt interval. Later in burial history, relatively small quantities of early halite were dissolved locally and re‐precipitated as indicated by inclusions of streaky solid bitumen within the late halite cements. Late halite cement also seals fractures which show evidence for repeated reopening. Initially, these fractures formed during a period of hydrothermal activity and were later reopened by a crack‐seal mechanism caused by high fluid overpressures. Porosity plugging by early halite cements affects the poroperm characteristics of the Ara carbonates much more than the volumetrically less important late halite cement. The formation mechanisms and distribution patterns of halite cementation processes in the South Oman Salt Basin can be generalized to other petroliferous evaporite basins.     

Origin and geochemistry of Miocene marine evaporites associated with red beds: Great Kavir Basin,Central Iran

During the Cenozoic numerous shallow epicontinental evaporite basins formed due to tectonic movements in the Northern Province of the Central Iran Tectonic Zone (the Great Kavir Basin). During the Miocene, due to sea‐level fluctuations, thick sequences of evaporites and carbonates accumulated in these basins that subsequently were overlain by continental red beds. Development of halite evaporites with substantial thickness in this area implies inflow of seawater along the narrow continental rift axis. The early ocean basin development was initiated in Early Eocene time and continued up to the Middle Miocene in the isolated failed rift arms. Competition between marine and non‐marine environments, at the edge of the encroaching sea, produced several sequences of both abrupt and gradual transition from continental wadi sediments to marginal marine evaporites in the studied area. These evaporites show well‐preserved textures indicative of relatively shallow‐brine pools. The high Br content of these evaporites indicates marine‐derived parent brines that were under the sporadic influence of freshening by meteoric water or replenishing seawater. However, the association of hopper and cornet textures denotes stratified brine that filled a relatively large pool and prevented rapid variations in the Br profile. Unstable basin conditions that triggered modification of parent brine chemistry prevailed in this basin and caused variable distribution patterns for different elements in the chloride units. The presence of sylvite and the absence of Mg‐sulphate/chlorides in the paragenetic sequence indicate SO₄−depleted parent brine in the studied sequence. Petrographic examinations along with geochemical analyses on these potash‐bearing halites reveal parental brines which were a mixture of seawater and CaCl₂‐rich brines. The source of CaCl₂‐rich brines is ascribed to the presence of local rift systems in the Great Kavir Basin up to the end of the Early Miocene. Copyright © 2007 John Wiley & Sons, Ltd.     

Three-dimensional sequence analysis of a subsurface carbonate ramp, Mississippian Appalachian foreland basin, West Virginia, USA

Well‐cuttings, wireline logs and limited core and outcrop data were used to generate a regional, three‐dimensional sequence framework for Upper Mississippian (Chesterian), Greenbrier Group carbonates in the Appalachian foreland basin, West Virginia, USA. The resulting maps were used to document the stratigraphic response of the basin to tectonics and to glacio‐eustasy during the transition into ice‐house conditions. The ramp facies include inner ramp red beds and aeolianites, lagoonal muddy carbonates, mid‐ramp ooid and skeletal grainstone shoal complexes, and outer ramp wackestone–mudstone, that grades downslope into laminated silty lime mudstone. The facies make up fourth‐order sequences, a few metres to over 90 m (300 ft) thick. The sequences are bounded along the ramp margin by lowstand sandstones and calcareous siltstones. On the ramp, sequence boundaries are overlain by thin transgressive siliciclastics and aeolianites, and only a few are calichified. Maximum flooding surfaces on the outer ramp lie beneath deeper water facies that overlie lowstand to transgressive siliciclastic or carbonate units. On the shallow ramp, maximum flooding surfaces overlie siliciclastic‐prone transgressive systems tracts, that are overlain by highstand carbonates with significant grainstone units interlayered with lagoonal lime mudstones. The fourth‐order sequences are the major mappable subsurface units; they are bundled into weak composite sequences which are bounded by red beds. In spite of differential subsidence rates across the foreland basin (1 to 3 cm/k.y. up to 25 cm/k.y.), eustatic sea‐level changes controlled regional sequence development. Thrust‐load induced differential subsidence of fault‐blocks, coupled with in‐plane stress, controlled the rapid basinward thickening of the depositional wedge, whose thickness and facies were influenced by subtle structures such as arches trending at high angles as well as parallel to the margin.     

Rise in seawater sulphate concentration associated with the Paleoproterozoic positive carbon isotope excursion: evidence from sulphate evaporites in the ∼2.2–2.1 Gyr shallow‐marine Lucknow Formation,South Africa

Abstract Past oceanic sulphate concentration is important for understanding how the oceans’ redox state responded to atmospheric oxygen levels. The absence of extensive marine sulphate evaporites before ～1.2 Gyr probably reflects low seawater sulphate and/or higher carbonate concentrations. Sulphate evaporites formed locally during the 2.22–2.06 Gyr Lomagundi positive δ¹³C excursion. However, the ～2.2–2.1 Gyr Lucknow Formation, South Africa, provides the first direct evidence for seawater sulphate precipitation on a carbonate platform with open ocean access and limited terrestrial input. These marginal marine deposits contain evidence for evaporite molds, pseudomorphs after selenite gypsum, and solid inclusions of Ca‐sulphate in quartz. Carbon and sulphur isotope data match the global record and indicate a marine source of the evaporitic brines. The apparent precipitation of gypsum before halite requires ≥2.5 mm L^?1 sulphate concentration, higher than current estimates for the Paleoproterozoic. During the Lomagundi event, which postdates the 2.32 Gyr initial rise in atmospheric oxygen, seawater sulphate concentration rose from Archean values of ≤200 μm L^?1, but dropped subsequently because of higher pyrite burial rates and a lower oceanic redox state.     

Origin of polyhalite deposits in the Zechstein (Upper Permian) Zdrada platform (northern Poland)

Polyhalite deposits in the Zechstein (Upper Permian) of northern Poland occur in the Lower Werra Anhydrite. In the Zdrada Sulphate Platform, the polyhalite appears to be a very early replacement of anhydrite. The replacement was caused by the halite-precipitating brines which contained potassium and magnesium ions. The formation of polyhalite was preceded by the syndepositional anhydritization of the original gypsum deposit which has often preserved its primary textures. This anhydritization on the platform and its slopes was a reaction of the precipitated gypsum in a hydrologically open evaporite basin, with brines of salt basins adjacent to the sulphate platform. These brines, when nearly saturated with respect to halite, and potassium and magnesium rich, reacted with anhydrite to precipitate polyhalite along the slopes of the Zdrada Platform. The oxygen and sulphur isotopic compositions of sulphate evaporites indicate that marine solutions were the only source of sulphate ions supplied to the Zechstein basin, and that anhydrite was transformed to polyhalite by reaction with marine brines more concentrated than those that precipitated precursor calcium sulphate minerals.     

The Messinian Sicilian stratigraphy revisited: new insights for the Messinian salinity crisis

Controversies around the Messinian salinity crisis (MSC) are because of the difficulties in establishing genetic and stratigraphic relationships between its deep and shallow‐water record. Actually, the Sicilian foreland basin shows both shallow and deep‐water Messinian records, thus offering the chance to reconstruct comprehensive MSC scenarios. The Lower Gypsum of Sicily comprises primary and resedimented evaporites separated in space and time by the intra‐Messinian unconformity. A composite unit including halite, resedimented gypsum and Calcare di Base accumulated between 5.6 and 5.55 Ma in the main depocentres; it records the acme of the Messinian Salinity Crisis during a tectonic phase coupled with sea‐level falls at glacials TG14‐TG12. These deposits fully post‐date primary gypsum, which precipitated in shallow‐water wedge‐top and foreland ramp basins between 5.96 and 5.6 Ma. This new stratigraphic framework results in a three‐stage MSC scenario characterized by different primary evaporite associations: selenite in the first and third stages, carbonate, halite and potash salt in the second one associated with hybrid resedimented evaporites.     

Study on Carbonate Sequence Stratigraphy of Ordovician in Northern Ordos Basin

INTRODUCTIONSeqUenCestratigraphyisderivedfromseismicstratigl'aphyanditSconCeptShaveholargelyappliedtosill~ticsetting(e.g.passivemargin,I'alnP,groWth--faulting,activemarginandnonmarinesettings).InrecentyearS,thestudyofseqUenCestratigraphyhasdlawnagreatattentionfromgeologistSovertheworld.Carbonaterocksareimportantcomponentsofthesedimentaryrecord,beingmajorresouras(e.g.salt,potash,~),containinghydrOCarbon"serves,andyieldingawealthofpaleoclilnaticandpaleo--enviromnentalinfonnation~r,1991…     

Chadian faunas and flora from dyserth: Depositional environments and palaeogeographic setting of Viséan strata in northeast wales

New floral and faunal data from the oldest Dinantian limestones (Foel Formation) in the Dyserth area, suggest that these sediments are of Chadian age, rather than the Asbian age concluded by earlier workers. The basal late Chadian limestones rest conformably on Dinantian Basement Beds of ?Chadian age or older. The initial inundation of St. George's Land occurred during Chadian times, when shallow-water marine limestones accumulated in the Dyserth area and further to the south, together with terrestrially derived siliciclastics, containing drifted plant fragments. Periodically, a restricted hypersaline lagoonal environment was established but an open marine, neritic environment with abundant stenohaline fauna prevailed in this area. These Chadian sediments accumulated on the proximal part of a carbonate ramp and are presumed to have passed laterally downslope into deeper water basinal facies with Waulsortian buildups of the Irish Sea Basin. In the later Arundian, a carbonate ramp–to–platform transition occurred, with widespread deposition of shallow-water carbonates. In the Asbian this platform developed a rimmed margin, with buildups forming a linear belt between platform and basin. An almost complete Chadian to Brigantian Lower Carboniferous sequence can now be recognized in North Wales. This succession is comparable with the shelf succession in south Cumbria on the northern margin of the Irish Sea Basin.     

潜江盐湖盆地生储盖组合特征

潜江盐湖盆地是我国内陆独一无二的高盐度盐湖沉积盆地。本文在分析其岩性韵律特征的基础上,探讨了潜江盐湖生储盖组合特征。研究表明,潜江凹陷潜江组是在干湿频繁交替的古气候条件下,在高盐度、强蒸发、还原—强还原水体中,由北部单向碎屑物源及凹陷周缘卤水与盐源补给形成的盐系地层,岩性组合的有序变化形成了多套生储盖组合系统,不但反映出潜江盐湖沉积的特殊性和复杂性,而且具有十分优越的成油气地质条件。     

鄂尔多斯盆地北部奥陶系碳酸盐岩层序地层研究

碳酸盐岩的物源性质、形成背景、沉积机理和扩散方式都与碎屑岩有很大的差异．对于碳酸盐岩层序地层，需要从成因上、从台地的性质与演化、海不的进退、台地的淹没与暴露等方面进行研究．在总结露头层序地层工作方法的基础上，阐述了密集段、首次洪泛面和层序边界的识别标志，建立了高分辨率层序地层格架．鄂尔多斯盆地早奥陶世三道坎组沉积时，为碳酸盐岩－碎屑岩混合缓坡背景；桌子山组及克里摩里组沉积时为镶边陆架与末端陡倾缓坡的背景；乌拉力克组及中奥陶世时，转化为拗拉槽背景．由此分别建立了碳酸盐岩－碎屑岩缓坡模式和镶边陆架与末端陡倾缓坡的综合模式     

Chemical composition of seawater in Neoproterozoic: Results of fluid inclusion study of halite from Salt Range (Pakistan) and Amadeus Basin (Australia)

Data on chemical composition of brines in primary inclusions of marine halites and on mineralogy of marine evaporites and carbonates lead to the conclusion that during the Phanerozoic two long-term cycles of chemical composition of seawater existed. During each of those cycles, seawater dominantly a Na-K-Mg-Ca-Cl (Ca-rich) type changed to a Na-K-Mg-Cl-SO₄ (SO₄-rich) type. Recrystallised halite from the uppermost Neoproterozoic Salt Range Formation (ca. 545 Ma) in Pakistan, contains solitary inclusions indicating SO₄-rich brines. This supports the concept derived from the study on primary fluid inclusions from the Neoproterozoic Ara Formation of Oman; SO₄-rich seawater existed during latest Neoproterozoic time (ca. 545 Ma). In contrast, samples of recrystallised halite from the Bitter Springs Formation (840–830 Ma) in Australia contain inclusion brines that are entirely Ca-rich, indicating that basin brines and seawater were Ca-rich during deposition of central Australian evaporites. These combined data supported by the timing of aragonite and calcite seas suggest that during the Proterozoic, significant oscillations of the chemical composition of marine brines, and seawater, occurred, which are similar to those known to exist during the Phanerozoic. It is suggested that Ca-rich seawater dominated for a substantial period of time (more than 200 Ma), at 650 Ma, this was replaced by SO₄-rich seawater, finally returning to Ca-rich seawater at 530 Ma.     

上扬子区(四川盆地)寒武系的含盐性与地质背景

据记载,分布于上扬子区寒武系的石膏岩仅有零星资料。如今,大量蒸发岩如溶蚀角砾岩、硬石膏、石盐岩及富钾卤水等已被发现。沉积相经历了从盆地相、台地相到蒸发岩相的演化过程。在中、下寒武统中找到海退沉积序列。古构造-古地理背景是蒸发岩沉积的重要控矿条件之一。周边板块运动及塑性基底的褶皱,导致台缘隆起及台内坳陷的形成。岩相古地理图展示从碳酸盐、硫酸盐到氯化物盐类的“泪滴式”沉积相带。蒸发岩沉积于台缘隆起及礁生长进入堰塞潟湖至盐湖阶段。在稳定坳陷区沉积盆地中蒸发岩系发育;石盐岩较厚,其溴氯比值为0.2—0.4;古气候炎热、干燥;在蒸发岩体周围有沉积(封层)水及溶滤水,其含钾(K~+)量为0.10—4.76g/L;水文地球化学比值(如钾氯比值、钾盐比值及钾溴比值等)指示含钾异常;盐湖浓缩卤水达到氯化物盐类沉积阶段及相应的构造封闭程度;含盐地质标志广泛分布等等。鉴于上述,估计该区可能具备钾盐成矿条件。然而目的层埋藏太深,因此笔者建议,应在浅埋部位进行有效的成矿预测,为普查指出远景区。     

Evolution of a Callovian-Oxfordian carbonate margin in the Neuquén Basin of west-central Argentina: facies, architecture, depositional sequences and global sea-level changes

This paper reviews a detailed stratigraphic and sedimentologic study of a carbonate complex developed on the foreland side of the Neuquén Embayment, a protected shallow-water epicratonic site behind the active edge of the South American plate. Superb outcrops at the core of basement-involved Andean structures expose the shelf-to-basin transition and reveal with clarity the external and the internal architecture of the depositional sequences and component system tracts. Platform carbonates are largely represented by ooid and mainly rhodoid grainstones, with associated patches of coral framestone. The deeper platform and slope facies are composed of oncoidal and skeletal micritic limestones with scattered coral-sponge-algal build-ups. The overall composition and facies pattern bears resemblance to other Late Jurassic carbonate complexes form Europe and with the Smackover Formation from the Gulf Coast Basin of North America.

Analysis based on mapping of the stratal patterns and facies associations in outcrops allowed the recognition of four depositional sequences. Timing provided by ammonite biochronology suggests that eustatic fluctuations were a major factor influencing the carbonate-margin architecture, and regulated episodes of condensed sedimentation, shifts of the depositional belts, and development of stratigraphic discontinuities. The onset and the end of carbonate sedimentation were associated with episodes of marine retreat and accumulation of evaporites and eolian-fluvial deposits at basin-centre locations. However, most of the marine fluctuations recorded within the carbonate complex were insufficient to expose the shelf break (Type 2), and accordingly lowstand system tracts are poorly represented. On the shelf the transgressive system tracts are represented by thin grain-supported carbonate blankets. These taper out downslope into omission surfaces or are replaced by patches of small sponge buildups. Highstand system-tract organization changes through time, reflecting changes in productivity and accomodation, presumably tied to second-order sea-level changes. Callovian highstand accumulation featured a catch-up carbonate system and produced a thin-aggradational ramp configuration, whereas conditions during middle-late Oxfordian allowed a keep-up system and produced outbuilding depositional geometries with steeper slopes.     

Geochemistry and mineralogy of a recent sabkha along the coast of Sinai, Gulf of Suez

Most efforts in the study of sea-marginal sabkhas have concentrated on the Persian Gulf, but little is known about the sediments and mineralogy of sabkhas marginal to other seas. The purpose of this paper was to present some geochemical and mineralogical observations in a recent sabkha on the coast of Sinai along the Gulf of Suez. The sabkha is composed of coarse clastic sediments with marine-derived groundwater at depth of about 1 m. The general morphology, climate and water salinity of the Gulf of Suez resemble those of the Persian Gulf, despite the fact that the content of authigenic evaporites in this sabkha is more sparse. The evaporite minerals accumulated only in the upper 30–40 cm of the sabkha, below that and down to the groundwater table, there is no accumulation of evaporites. Laterally, the salinity of the groundwater in the sabkha and the concentration of evaporites in the sediments above it increase constantly with distance from the shore. In contrast to the Persian Gulf where anhydrite is a major evaporite mineral, in Belayim gypsum is the only calcium sulphate mineral in the recent sabkha. Anhydrite is found only in an old elevated sabkha where it recrystallized from gypsum. The gypsum occurs as interstitial crystal concentrations or lithified horizons almost exclusively at the depth of 20–40 cm below the sabkha surface. Above that, in the uppermost horizons, there is in situ accumulation of interstitial halite crystals. The total concentrations of gypsum and halite are almost equal in this sabkha. The sea water recharge in El Belayim is almost exclusively by seepage through the sabkha sediments and not by flooding. The groundwater under this sabkha is only slightly more saline than the Gulf water, thus, not heavy enough for extensive downward refluxing. The major hydrodynamic process must be upward migration of the brines from the groundwater, precipitating on the way gypsum and later halite with some magnesite. Since the sediments of the sabkha are too coarse to support extensive capillary movement, the brines must, therefore, migrate upwards due to ‘evaporative pumping’.     

Aspects of dinantian sedimentation in the edale basin,north derbyshire

The Dinantian Edale Basin is located to the north of the Derbyshire carbonate platform and underlies the Upper Carboniferous of the central Pennines. The Edale Basin was thought to be part of a large basin which extended from the Derbyshire carbonate platform to the Askrigg Block. The presence of aggregate grains and ooids in the Alport Borehole suggests that a carbonate platform, possibly located on the Holme structural high, was present underneath the central Pennines. This platform is called the Holme Platform. The Arundian to early Asbian section of the Alport Borehole represents deposition of resedimented shallow-water carbonates with occasional bioturbated periplatform carbonates and basinal shales on the middle part of a carbonate ramp. Volcaniclastic sediments may have been derived from a volcanic centre within the Edale Basin. A change in sedimentation during the mid-Asbian to the deposition of basinal shales and distal carbonate turbidites is attributed to starvation of the basin. This may have been caused by a combination of the development of accretionary rimmed carbonate shelves and the repeated emergence of shelf carbonates deposited on surrounding carbonate platforms. The late Asbian/early Brigantian section of the Edale Borehole is interpreted as a distal equivalent of the ‘Beach Beds’ which outcrop at the north margin of the Derbyshire carbonate platform. The ‘Beach Beds’ represent bioclastic turbidites derived from the Derbyshire carbonate platform. Throughout the Brigantian, sedimentation in the Edale Basin was dominated by the deposition of distal carbonate turbidites and basinal shales. Variation of dip through the Alport Borehole indicates the common occurrence of slumps throughout the sequence and the presence of either an angular unconformity or a fault within the early Brigantian section.     

Sequence stratigraphy and paleogeography reconstruction of the reference Lower-Middle Turonian successions of Jebel Bireno (Central Tunisia): a semi-quantitative approach

The Early-Middle Turonian carbonates of central Tunisia (Kef Formation, Bireno Member) are considered as ramp deposits. The correspondence analysis statistical method used here is based on the relative abundance of carbonate components and the occurrences of specific structures within beds. It was applied to the bed-by-bed sampled succession in the Jebel Bireno area in central Tunisia concerning 399 samples from 11 studied stratigraphic sections. We propose the reconstruction of the facies based on the allochem distribution (Axis 1) along the proximal to distal ramp environments. The proposed pattern brings out successive facies shifts interpreted in terms of sequence stratigraphy: along Axis 1, abrupt shifts to negative values correspond to sequence boundaries and/or regressions; positive excursions express transgressive events or maximum flooding surfaces. Trends in this Axis 1 and key surfaces allow the identification of main system tracts of third-order sequences as well as variations of paleogeography. Four dated sequences were identified within the Jebel Bireno Early-Middle Turonian series. Correlation of system tracts highlights facies and thickness variations mainly controlled by N130–N90 trending synsedimentary normal faults. Paleogeographic maps for the Bireno Mb plead in favor of a distal ramp, subtidal high-energy deposits (barrier), and proximal ramp environment.     

Sedimentary Facies Architectures of Third-Order Sequences from Early to Middle Triassic in Nanpanjiang Basin

There are complex and regular changes on sedimentary facies from the Early to the Middle Triassic in the Nanpanjiang basin. After the obvious drowned event of carbonate platforms in the transitional period between Permian and Triassic, carbonate platforms have evolved into the ramp type from the rimmed-shelf type. The differentiation of sedimentary facies becomes dearer in space, which are marked by the changes from an attached platform to a turbidity basin and several isolated platforms in the basin. The striking characteristics are the development of oolitic banks on isolated platforms in Nanning and Jingxi and the reef- and bank-limestones in the margin of the attached platform in the Early Triassic. Despite the difference of the time-span and the architectnre of fades succession of third-order sedimentary sequences, the process of the third-order relative sea-level changes reflected by the sedimentary facies succession of the third-order sequences is generally synchronous. Therefore, six third-order sequences could be discerned in the strata from the Early to the Middle Triassic in the Nanpanjiang basin. Using two types of facies changing surfaces and two types of diachronisms in stratigraphic records as the key elements, the sedimentary facies architectures of the third-order sequences that represent sequence stratigraphic frameworks from the Early to the Middle Triassic in the Nanpanjiang basin could be constructed.     

The evolution of marine evaporitic brines in inland basins: The Jordan-Dead Sea Rift valley

Marine-evaporitic brines frequently display Na, Cl and Br concentrations that significantly deviate from seawater evaporation paths, yielding markedly conflicting degrees of evaporation calculated for a specific brine. Here we present 493 new and 33 previously reported analyses of Ca-chloridic waters of Neogene age from the Dead Sea Rift (DSR) valley to explain such offsets. The DSR brines plot along an almost perfect mixing line (R² = 0.990) on a Br/Cl-Na/Cl diagram, extending between two end members A and B. Points A and B are located at Na/Cl = 0.804 and Br/Cl = 0.00193, and at Na/Cl = 0.00773 and Br/Cl = 0.0155, respectively, within the halite and bischofite stability fields.Brines A and B originated in a dual-mode evaporation basin. Brine A formed under the classic lagoon scenario (mode A), with seawater inflow and brine outflow at steady state. Occasional drops in water level, imposed by climatic or tectonic causes, resulted in outflow cutoff and in rapid concentration buildup. The second mode (B) initiated upon equilibration of the activity of water in the brine with the overlying relative humidity, resulting in composition and salinity approaching that of brine B, sustaining it until the next reversal to mode A.Thick evaporite deposits inhibited infiltration of brines A and B into the subsurface terrain, a process that was enabled only when the brine reached the permeable carbonate rock rim and border faults of the basin. Hence, brines that formed during the relatively short shifts from mode A to mode B could not penetrate into the deep subsurface, and bittern minerals that were formed during the frequent mode shifts were dissolved and flushed out into the sea upon the next resumption of outflow.The proposed model accounts for the deviations of brines from the marine evaporitic evolution curve by brine mixing, rather than due to a change in ocean chemistry. It also explains the absence of bittern minerals in the thick halite and gypsum/anhydrite succession, and the compositional gap between the widely different end member hypersaline fluids. This model applies directly to the studied DSR brines and evaporites, but it may be relevant to other inland evaporitic basins.     

Are secular variations in seawater chemistry reflected in the compositions of basinal brines?

It has been proposed that brines in Phanerozoic sedimentary basins inherited their chemistries and salinities from evaporated paleoseawaters during times when the world oceans were Ca-rich and SO₄-poor, such as the Silurian and Devonian. However, the compositions of typical Silurian and Devonian-hosted brines in the Illinois and Michigan basins show significant deviations from calculated Silurian seawater evaporation trends, reflecting instead, diagenetic control of compositions. In addition, brines in many basins show evidence for the dissolution of halite being an important source of salinity in addition to, or instead of, evaporated seawater. As long as there is halite present, generation of salinity could continue to occur long after the deposition of evaporites and the influx of evaporated seawater. Thus, even the concept of assigning an age to a basinal brine is problematic given the dynamics of fluid flow, mixing, and solute transport which can occur in sedimentary sequences.