Evolution of the southern Taiwan–Sinzi Folded Zone and opening of the southern Okinawa trough

Recent interpretation of seismic sections and free-air gravity anomalies in offshore northern Taiwan reveals that the southern Taiwan–Sinzi Folded Zone began to form in late Middle Miocene, though it was mainly constructed in the Late Pliocene with strong reverse faulting and folding. Two westward progradational sequences were deposited in the shelf basin with sediments supplied from the southern Taiwan–Sinzi Folded Zone and the southern Ryukyu Arc. These two structures are displaced by several northwest-striking dextral strike–slip faults that were active in the early Quaternary when the clockwise-rotated southern Ryukyu Arc and the folded southern Taiwan–Sinzi Folded Zone were broken. It is believed that recent extension in the southern Okinawa Trough started in the early Quaternary because uplift on the southern Taiwan–Sinzi Folded Zone continued to latest Pliocene–early Quaternary. Paleogene–Miocene sediments of the East China Sea Shelf in the western part of the southern Okinawa Trough Basin are interpreted to indicate that the East China Sea Shelf Basin extended to the east of the southern Taiwan–Sinzi Folded Zone.     

Ruby–sapphire–spinel mineralization in marble of the middle and southern Urals: Geology,mineralogy, and genesis

Ruby and spinel occurrences hosted in marble on the eastern slope of the Urals are considered. Ruby- and spinel-bearing marble is a specific rock in granite-gneiss complexes of the East Ural Megazone, which formed at the Late Paleozoic collision stage of the evolution of the Urals. Organogenic marine limestone is the protolith of the marble. No relict sedimentary bedding has been retained in the marble. The observed banding is a secondary phenomenon related to crystallization and is controlled by flow cleavage. Magnesian metasomatism of limestone with the formation of fine-grained dolomite enriched in Cr, V, Ti, Mn, Cu, Zn, Ga, and REE took place at the prograde stage of metamorphism. Dedolomitization of rocks with the formation of background calcite marble also developed at the prograde stage. Mg-calcite marble with spinel and ruby of the first type formed in the metamorphic fluid circulation zone. Magnesian metasomatism with the formation of bicarbonate marble with ruby, pink sapphire, and spinel of the second type developed at the early retrograde stage. The formation of mica-bearing mineralized zones with corundum and spinel of the third type controlled by cleavage fractures is related to the pneumatolytic–hydrothermal stage. The data on ruby-bearing marble in the Urals may be used for forecasting and prospecting of ruby and sapphire deposits hosted in marble worldwide.     

Sedimentological and geomorphological effects of the Sumatra–Andaman Tsunami in the area of Khao Lak,southern Thailand

The Sumatra–Andaman Tsunami left distinctive sedimentological and geomorphological signatures in the area of Khao Lak. Fine-grained sediments, predominantly layers of cohesive, carbonate-rich, fine-sandy silt with thicknesses of 1–10 cm, erosionally overlying pre-tsunami sandy soils and sediments, represent the most common tsunami deposits in the study area. Petrographically, they differ significantly from other coastal sediments and affiliated soils. Due to their grain size and corresponding clay mineral content, muddy shelf sediments (sub-wave base) are indicated as a main source. The present results suggest that indications of shelf influence, although varying regionally, might contribute to the identification of fine-grained tsunami sediments and their differentiation from storm sediments. However, the observed differences of tsunami sediments to soils and other coastal sediments, especially with respect to carbonate mineralogy, might disappear in short geological time under conditions of intensive weathering and bioturbation. At Cape Pakarang, hundreds of boulders with up to 24 tons were deposited on the foreshore and upper shoreface. Applying Nott’s (Earth Planet Sci Lett 210:269–276, 2003) formulas, minimum flow velocities of 3.9 m/s are required to transport the largest boulders. The devastating tsunami effect of both, onshore flow and backflow, is documented by damaged human constructions. Geomorphological effects include intensive widening of estuary mouths and the development of erosional channels. Now, estuary mouths are reduced, and erosional channels cut off from the sea due to the formation of a post-tsunami beach ridge.     

High-temperature–low-pressure metamorphism and the production of S-type granites of the Hillgrove Supersuite,southern New England Orogen,NSW, Australia

The high-temperature–low-pressure Wongwibinda Metamorphic Complex of the southern New England Orogen is bound by S-type granite plutons of the Hillgrove Supersuite to the north, east and south. New U–Pb geochronology of five samples of the Hillgrove Supersuite demonstrates that plutonism in the complex involved two pulses: ca 300 Ma and ca 292 Ma. This indicates that plutonism partially overlaps the age of high-T–low-P metamorphism (296.8 ± 1.5 Ma), but also postdates it. Zircon grains identified as xenocrysts based on age (≥310 Ma) have U–Pb–Hf isotopic character that largely overlaps detrital grains in the host Girrakool Beds, indicating that accretionary complex crust is the likely source of these xenocrysts. The ¹⁷⁶Hf/¹⁷⁷Hf initial character for zircon for the ca 300 Ma plutons (three samples) is less radiogenic than those in the ca 292 Ma plutons (two samples). The progression in ¹⁷⁶Hf/¹⁷⁷Hf initial character for zircon infers an increasing mantle component in the Hillgrove Supersuite with time. These data are evidence of a rift tectonic setting, where mantle-derived magmas are predicted to more readily migrate to shallower crustal levels as the crust thins and becomes hotter. Additionally, early episodes of partial melting in the system melt-depleted the metasedimentary sources, thus reducing the S-type component as anatexis progressed. The evolution of the Hillgrove Supersuite coincides with a period of early Permian slab roll back and extension accompanied by crustal rifting and thinning, leading to high-T–low-P metamorphism, anatexis and S-type granite production and the development of rift basins such as the Sydney–Gunnedah–Bowen system.     

Geochronology and geochemistry of Mesozoic mafic–ultramafic complexes in the southern Liaoning and southern Jilin provinces,NE China: Constraints on the spatial extent of destruction of the North China Craton

LA–ICP–MS zircon U–Pb ages, geochemical and Sr–Nd–Pb isotope data are presented for mafic–ultramafic complexes from the southern Liaoning–southern Jilin area with the aim of determining the nature of the Mesozoic lithospheric mantle and to further constrain the spatial extent of destruction of the North China Craton (NCC). The complexes consist of olivine-websterite, gabbro, dolerite, and gabbro-diorite. Zircons from the complexes show typical zoning absorption, are euhedral–subhedral in shape, and yield high Th/U ratios (1.23–2.87), indicating a magmatic origin. Zircon U–Pb age data indicate that they formed in the Early Cretaceous (129–137 Ma). Geochemically, they have SiO₂ = 44.3–49.8%, MgO = 6.8–26.5%, Cr = 102–3578 ppm, and Ni = 31–1308 ppm, and are characterized by enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs) and heavy rare earth elements (HREEs), as well as a wide range of Sr–Nd–Pb isotopic compositions [(⁸⁷Sr/⁸⁶Sr)i = 0.70557–0.71119; ε_Nd (t) = ?5.4 to ?20.1; (²⁰⁶Pb/²⁰⁴Pb)i = 15.13–17.85; Δ7/4 = ?11.49 to 16.00; Δ8/4 = 102.64–203.48]. Compared with the southern Liaoning mafic–ultramafic rocks, the southern Jilin mafic–ultramafic rocks have high TiO₂ and Al₂O₃ contents, high ε_Nd (t) values, low (La/Yb)_N values, low initial ⁸⁷Sr/⁸⁶Sr ratios, and low radiogenic Pb isotopic compositions. These findings indicate that the primary magmas of the southern Jilin complexes were derived from lithospheric mantle that was previously metasomatized by a melt derived from the delaminated ancient lower crust, whereas the primary magmas of the southern Liaoning complexes originated from partial melting of a lithospheric mantle source that was previously modified by melt derived from the broken-off Yangtze slab. Therefore, the lateral extent of the NCC destruction should include the southern Liaoning–southern Jilin area.     

Structural style and tectono-stratigraphic evolution of the Neogene–Quaternary Siderno Basin,southern Calabrian Arc,Italy

The Neogene–Quaternary Siderno Basin is located in the southern Calabrian Arc, along an E–W transect including the Ionian side and part of the Tyrrhenian margin. The orogenic belt was generated by ongoing northward subduction of Ionian oceanic lithosphere beginning in the Early Cretaceous. Since the Oligocene, the area has experienced complex tectonics, including NW–SE-oriented pull-apart basins. The forearc region contains >2000 m of Oligocene-to-Quaternary strata that cover pre-Tertiary rocks. The succession forms an E-dipping monocline, with tectonic growth structures increasing upward. Erosional truncations and thickness variations suggest a different evolution for the Siderno Basin, which in comparison with northern and southern parts of the Ionian accretionary wedge, evolved differently during the Serravallian–Tortonian stages. NW–SE and NE–SW fault systems are dominant, the first exhibiting strike–slip and normal kinematics in the Nicotera–Gioiosa and Molochio–Antonimina fault zones. These structures were active during infilling of the Neogene basin, and represent a complex transfer zone.

The NE–SW system shows two types of tectonic kinematics: (1) a compressive stage, with NW–SE-orientated shortening, responsible for inversion tectonics documented by east-verging folds, thrusts, and back-thrusts, and (2) emplacement of the variegated clay during the Langhian, which is related to back-thrust propagation. The strike–slip accommodated stress generated in the accretionary prism in response to subduction of Ionian lithosphere and progradation of the accretionary front of the Calabrian forearc.     

SHRIMP U–Pb zircon geochronology and Nd signatures of supracrustal sequences and orthogneisses constrain the Neoproterozoic evolution of the Pernambuco–Alagoas domain,southern part of Borborema Province,NE Brazil

The Borborema Province is the western part of a major Brasiliano belt that extends from Brazil through NW Africa in pre-drift reconstructions. This province resulted from convergence and collision among the West African, Congo-São Francisco, and Amazonian cratons about 600 Ma. This study focuses on the Pernambuco–Alagoas (PEAL) domain, which is a complex of magmatic, migmatitic, and metamorphic rocks, located in the southern part of the Borborema Province. U–Pb geochronology and Sm–Nd data for metasedimentary sequences (Rio Una, Inhapi) of the PEAL domain and a sample from a sequence of the Transversal Zone domain suggest that their deposition occurred during a Cryogenian extensional event, within the interval 850–631 Ma (or slightly younger). This extensional event occurred in the PEAL, Transversal Zone, and Sergipano domains before the onset of the Brasiliano collision and was followed by syn- and post-collisional magmatism. The Rio Una sequence and the sequence from Transversal Zone domain were deposited over a Rhyacian (ca. 2.0–2.2) basement having a juvenile Palaeoproterozoic Nd signature, whereas the Inhapi sequence was deposited over an Early Neoproterozoic (Tonian) basement. The deposition of the studied sequences is coeval with metasedimentary sequences to the north and south in other domains of the Borborema Province. However, differences in Nd isotopic signatures between the sequences from PEAL, Transversal Zone, and Sergipano domains suggest that they were formed in distinct basins. Metasedimentary sequences from the PEAL domain have Meso- and Palaeoproterozoic T _DM model ages. These data suggest that the orogens where the metasedimentary sequences are located have a strong ensialic component. T _DM model ages of ca. 1.0 Ga and εNd (0.6 Ga) values around zero recorded in granites from the southern part of the PEAL, suggesting that juvenile material was accreted to the southern part of the PEAL domain crust during the Tonian. The migmatites from the PEAL domain have a wide range of T _DM ages along with a wide range of εNd (0.6 Ga) values. The transition between the northern and southern parts of the PEAL domain denotes the approximate northern margin of a Late Mesoproterozoic to Early Neoproterozoic rift.     

Age and tectonic setting of the Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide deposit, southern Iran

The Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide (VMS) deposit occurs within the Surian volcano-sedimentary complex in the Sanandaj–Sirjan zone (SSZ) of southern Iran. The Surian complex is comprised of pelite, sandstone, calcareous shale, basalt, gabbro sills, and thin-bedded limestone. Mineralization occurs as stratiform sheet-like and tabular orebodies hosted mainly by greenschist metamorphosed feldspathic and quartz feldspathic sandstone, basalt, and pelites. The basalts of the Surian complex show predominantly tholeiitic to transitional affinities, with a few samples that are alkalic in composition. Primitive mantle-normalized trace and rare earth element (REE) patterns of the Surian basalts display depletions in light REE, negative anomalies of Nb, Ta, and Ti, and positive anomalies of P. Positive P anomalies are indicative of minor crustal contamination. Furthermore, Th enrichments in the mid-ocean ridge basalt-normalized patterns of the Surian basalts are characteristic of rifted arc basalts emplaced in continental margin subduction zones. The high MgO content (>6?wt.%) of most Surian basalts and low TiO₂ content of two samples (0.53 and 0.62?wt.%) are characteristic of boninites. The aforementioned features of the basalts indicate arc tholeiites emplaced in intra-arc rift environments and continental margin subduction zones. U–Pb dating by laser ablation- inductively coupled plasma mass spectrometry of detrital zircons extracted from the host feldspathic and quartz feldspathic sandstone yields various ages that are predominantly Permian and Triassic; however, the youngest zircons give a mean Early Jurassic concordant U–Pb age of 191?±?12?Ma. This age, together with geological and petrochemical data, indicate that VMS mineralization formed in the Early Jurassic in pull-apart basins within the SSZ. These basins and the VMS mineralization may be temporally related to an intra-arc volcano–plutonic event associated with Neo-Tethyan oblique subduction.     

Geochemical and Sm–Nd isotopic study of titanite from granitoid rocks of the eastern Dharwar craton,southern India

Titanite occurs as an accessory phase in a variety of igneous rocks, and is known to concentrate geologically important elements such as U, Th, rare earth element (REE), Y and Nb. The differences in the abundances of the REEs contained in titanite from granitoid rocks could reflect its response to changes in petrogenetic variables such as temperature of crystallization, pressure, composition, etc. Widespread migmatization in the granodiorite gneisses occurring to the east of Kolar and Ramagiri schist belts of the eastern Dharwar craton resulted in the enrichment of the REEs in titanite relative to their respective host rocks. A compositional influence on the partitioning of REEs between titanite and the host rock/magma is also noticed. The relative enrichment of REEs in titanite from quartz monzodiorite is lower than that found in the granodioritic gneiss. Depletion of REE and HFSE (high field-strength elements) abundances in granitic magmas that have equilibrated with titanite during fractional crystallization or partial melting has been modelled. As little as 1% of titanite present in residual phases during partial melting or in residual melts during fractional crystallization can significantly lower the abundances of trace elements such as Nb, Y, Zr and REE which implies the significance of this accessory mineral as a controlling factor in trace element distribution in granitoid rocks. Sm–Nd isotope studies on titanite, hornblende and whole rock yield isochron ages comparable to the precise U–Pb titanite ages, invoking the usefulness of Sm–Nd isochron ages involving minerals like titanite.     

Fluid inclusion geochemistry and Ar–Ar geochronology of the Cenozoic Bangbu orogenic gold deposit,southern Tibet,China

Located along the southern part of the Yarlung Zangbo suture zone in southern Tibet, Bangbu is one of the largest gold deposits in Tibet. Auriferous sulfide-bearing quartz veins are controlled by second- or third-order brittle fractures associated with the regional Qusong–Cuogu–Zhemulang brittle-ductile shear zone. Fluid inclusion studies show that the auriferous quartz contains aqueous inclusions, two-phase and three-phase CO₂-bearing inclusions, and pure gaseous hydrocarbon inclusions. The CO₂-bearing inclusions have salinities of 2.2–9.5% NaCl_eq, and homogenization temperatures (Th) of 167–336 °C. The δD, δ¹⁸O, and δ¹³C compositions of the Bangbu ore-forming fluids are − 105.5 to − 44.4‰, 4.7 to 9.0‰ and − 5.1 to − 2.2‰, respectively, indicating that the ore-forming fluid is mainly of metamorphic origin, with also a mantle-derived contribution. The ³He/⁴He ratio of the ore-forming fluids is 0.174 to 1.010 R_a, and ⁴⁰Ar/³⁶Ar ranges from 311.9 to 1724.9. Calculations indicate that the percentage of mantle-derived He in fluid inclusions from Bangbu is 2.7–16.7%. These geochemical features are similar to those of most orogenic gold deposits. Dating by ⁴⁰Ar/³⁹Ar of hydrothermal sericite collected from auriferous quartz veins at Bangbu yielded a plateau age of 44.8 ± 1.0 Ma, with normal and inverse isochronal ages of 43.6 ± 3.2 Ma and 44 ± 3 Ma, respectively. This indicates that the gold mineralization was contemporaneous with the main collisional stage between India and Eurasia along the Yarlung Zangbo suture, which resulted in the development of near-vertical lithospheric shear zones. A deep metamorphic fluid was channeled upward along the shear zone, mixing with a mantle fluid. The mixed fluids migrated into the brittle structures along the shear zone and precipitated gold, sulfides, and quartz because of declining temperature and pressure or fluid immiscibility. The Bangbu is a large-scale Cenozoic syn-collisional orogenic gold deposit     

Palaeoweathering,composition and tectonics of provenance of the Proterozoic intracratonic Kaladgi–Badami basin,Karnataka, southern India: Evidence from sandstone petrography and geochemistry

Petrographic and geochemical data on the sandstones of the Proterozoic intracratonic Kaladgi–Badami basin, southern India are presented to elucidate the palaeoweathering pattern, and composition and tectonics of their provenance. The Kaladgi–Badami basin, hosting the Kaladgi Supergroup, occupies an E–W trending area. The Supergroup unconformably overlies Archaean basement TTG gneisses, granites and greenstones, comprises a cyclic arenite–pelite–carbonate association and is divided into the Bagalkot and Badami Groups. The immature arkosic character of the basal Saundatti Quartzite Member (Bagalkot Group) containing fresh and angular feldspars, along the northern margin of the basin, suggests that during the initial stage of deposition, this part of the basin received sediments from a restricted, uplifted and less weathered source dominated by K-rich granites occurring to the north. In contrast, the Saundatti Quartzite along the southern margin displays a mostly mature, quartz-rich character with less abundant but severely weathered feldspars, and higher SiO₂ and CIA but lower Al₂O₃, TiO₂, Rb, Sr, Ba, K₂O, K₂O/Na₂O, Zr/Ni and Zr/Cr. This is interpreted in terms of a tectonically stable, considerably weathered mixed source (Archaean gneisses, granites and greenstones) along the southern fringe of the basin. The highly mature (quartz arenite) Muchkundi Quartzite Member (also of the Bagalkot Group), occurring higher up in the succession, exhibits minor but severely altered feldspars, and higher SiO₂, Na₂O, CIA, Cr and Ni with lower K₂O, Al₂O₃, TiO₂ and K₂O/Na₂O. This reflects that with the passage of time the source evolved to a uniform, extensively weathered, tectonically stable peneplained provenance which consisted of less evolved TTG gneisses and greenstones. This was followed by closure, deformation and upliftment of the basin hosting the Bagalkot Group and subsequent deposition of the Badami Group. Sandstone Members of this younger Group (Cave-Temple Arenite and Belikhindi Arenite) range widely in mineralogy (quartz arenite to arkose) and chemistry (including CIA), and point to a source that varied from uplifted, less weathered K-rich granites to less evolved, peneplained TTG gneisses and greenstones or even Bagalkot sediments. Variable alteration of feldspars in the Kaladgi sandstones and severe depletion of Ca, Na and Sr in the associated shales indicate a humid tropical (tropical and subtropical) climate facilitating chemical weathering.     

U–Pb geochronology and Pb isotope characteristics of the Chahgaz volcanogenic massive sulphide deposit,southern Iran

The Chahgaz Zn–Pb–Cu volcanogenic massive sulphide (VMS) deposit occurs within a metamorphosed bimodal volcano–sedimentary sequence in the south Sanandaj–Sirjan Zone (SSZ) of southern Iran. This deposit is hosted by rhyodacitic volcaniclastics and is underlain and overlain by rhyodacitic flows, volcaniclastics, and pelites. Peperitic textures between rhyodacite flows and contact pelites indicate that emplacement of the rhyodacite occurred prior to the lithification of the pelites. The rhyodacitic flows are calc-alkaline, and show rare earth and trace elements features characteristic of arc magmatism. Zircons extracted from stratigraphic footwall and hanging-wall rhyodacitic flows of the Chahgaz deposit yield concordant U–Pb ages of 175.7 ± 1.7 and 172.9 ± 1.4 Ma, respectively, and a mean age of 174 ± 1.2 Ma. This time period is interpreted to represent the age of mineralization of the Chahgaz deposit. This Middle Jurassic age is suggested as a major time of VMS mineralization within pull-apart basins formed during Neo-Tethyan oblique subduction-related arc volcano-plutonism in the SSZ. Galena mineral separates from the layered massive sulphide have uniform lead isotope ratios of ²⁰⁶Pb/²⁰⁴Pb?=?18.604–18.617, ²⁰⁷Pb/²⁰⁴Pb?=?15.654–15.667, and ²⁰⁸Pb/²⁰⁴Pb?=?38.736–38.769; they show a model age of 200 Ma, consistent with the derivation of Pb from a Late Triassic, homogeneous upper crustal source.     

Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit,southern Jiangxi tungsten district,China

The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average ²⁰⁶Pb/²³⁸U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average ²⁰⁶Pb/²³⁸U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.     

S,Pb, and Sr isotope geochemistry and genesis of Pb–Zn mineralization in the Huangshaping polymetallic ore deposit of southern Hunan Province,China

The Huangshaping Pb–Zn–W–Mo polymetallic deposit, located in southern Hunan Province, China, is one of the largest deposits in the region and is unique for its metals combination of Pb–Zn–W–Mo and the occurrence of significant reserves of all these metals. The deposit contains disseminated scheelite and molybdenite within a skarn zone located between Jurassic granitoids and Carboniferous sedimentary carbonate, and sulfide ores located within distal carbonate-hosted stratiform orebodies. The metals and fluids that formed the W–Mo mineralization were derived from granitoids, as indicated by their close spatial and temporal relationships. However, the source of the Pb–Zn mineralization in this deposit remains controversial.Here, we present new sulfur, lead, and strontium isotope data of sulfide minerals (pyrrhotite, sphalerite, galena, and pyrite) from the Pb–Zn mineralization within the deposit, and these data are compared with those of granitoids and sedimentary carbonate in the Huangshaping deposit, thereby providing insights into the genesis of the Pb–Zn mineralization. These data indicate that the sulfide ores from deep levels in the Huangshaping deposit have lower and more consistent δ³⁴S values (− 96 m level: + 4.4‰ to + 6.6‰, n = 13) than sulfides within the shallow part of the deposit (20 m level: + 8.3‰ to + 16.3‰, n = 19). The δ³⁴S values of deep sulfides are compositionally similar to those of magmatic sulfur within southern Hunan Province, whereas the shallower sulfides most likely contain reduced sulfur derived from evaporite sediments. The sulfide ores in the Huangshaping deposit have initial ⁸⁷Sr/⁸⁶Sr ratios (0.707662–0.709846) that lie between the values of granitoids (0.709654–0.718271) and sedimentary carbonate (0.707484–0.708034) in the Huangshaping deposit, but the ratios decreased with time, indicating that the ore-forming fluids were a combination of magmatic and formation-derived fluids, with the influence of the latter increasing over time. The lead isotopic compositions of sulfide ores do not correlate with sulfide type and define a linear trend in a ²⁰⁷Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagram that is distinct from the composition of the disseminated pyrite within sedimentary carbonates and granitoids in the Huangshaping deposit, but is similar to the lead isotopic composition of sulfides within coeval skarn Pb–Zn deposits in southern Hunan Province. In addition, the sulfide ores have old signatures with relative high ²⁰⁷Pb/²⁰⁶Pb ratios, suggesting that the underlying Paleoproterozoic basement within southern Hunan Province may be the source of metals within the Huangshaping deposit.The isotope geochemistry of sulfide ores in the Huangshaping deposit shows a remarkable mixed source of sulfur and ore-forming fluids, and the metals were derived from the basement. These features are not found in representative skarn-type Pb–Zn mineralization located elsewhere. The ore-forming elements (S, Pb, and Zn) from the granitoids made an insignificant contribution to sulfide precipitation in this deposit. However, the emplacement of granitoids did provide large amounts of heat and fluids to the hydrothermal system in this area and extracted metals from the basement rocks, indicating that the Jurassic magmatism associated with the Huangshaping deposit was crucial to the Pb–Zn mineralization.     

The origin of fluids and nature of fluid–rock interaction in mid-crustal auriferous mylonites of the Renco mine, southern Zimbabwe

Geothermometric constraints on auriferous shear zones of the Renco mine in the Northern Marginal Zone of the late-Archaean, granulite-facies Limpopo Belt in southern Zimbabwe indicate that deformation and associated mineralization occurred at temperatures of at least 600 °C up to more likely 700 °C. Mid- to upper-amphibolite facies conditions during mineralization correspond to the regional-scale retrogression of granulite facies wall rocks during the late-Archaean thrusting of high-grade metamorphic rocks of the Northern Marginal Zone onto low- to medium-grade granite-greenstone terrains of the Zimbabwe craton. Mineral assemblages indicate that the ore fluid was moderately oxidized with log f_O2 values between 10⁻¹⁷ and 10⁻¹⁸ bars with high H₂S activities of 0.25–0.75. Elements enriched in the shear zones include Au, S, Fe, Cu, Mo, Bi, Te, Ni, Co, and H₂O, Au and Cu being the most enriched. Geochemically, Au correlates with Cu but not with S, which, together with the fact that gold is only rarely intergrown or in direct contact with sulfides, possibly indicates a transport of gold as a chloride complex. The siting of gold along fractures or within implosion breccias suggests that gold was precipitated due to fluid immiscibility induced by catastrophic fluid pressure drops during seismic slip events. Fluid inclusions are predominantly CO₂ (±CH₄ ± N₂)-rich, but petrographic work indicates that fluid inclusions have undergone extensive post-entrapment modifications due to the pervasive recrystallization of mineral textures in the high-temperature shear zones. The mineralized shear zones are enriched in ¹⁸O compared to wall-rock enderbites, which is interpreted to represent an influx of externally derived fluids of probably metamorphic origin. Based on temporal and spatial relationships between mineralization, late-Archaean overthrusting of the Northern Marginal Zone onto the Zimbabwe craton, and coeval amphibolite-facies hydration of granulites, we suggest that the Renco mineralization formed in a mid-crustal environment from metamorphic fluids that were generated from dehydration of subcreted greenstone terrains of the Zimbabwe craton. Received: 27 October 1998 / Accepted: 13 August 1999     

Geochronological and geochemical study of gneiss–schist complexes and associated granitoids,Beishan Orogen,southern Altaids

The tectonic nature of metamorphic terranes and their role in orogenesis are problematic. Here we present new U–Pb ages and geochemical data for widespread metamorphic rocks and associated granitoids from Northwest China. Orthogneisses from the metamorphic complexes have crystallization ages of ～457, ～452, and ～526 Ma. One paragneiss (schist) has a maximum depositional age of 312 ± 7 Ma. Three foliated granites were emplaced at ～450, ～349, and ～410 Ma, and all lack inherited Precambrian ages. The metamorphic terranes may have undergone multiple petrotectonic events as revealed by the metamorphic ages. Both the orthogneisses and granitoids show enrichment in large ion lithophile elements (LILEs) and light rare Earth elements (LREEs), and depletion in high field strength elements (HFSEs), which indicate that they formed in a subduction-generated accretionary arc setting. Our study demonstrates that the metamorphic terranes in the Beishan area, originally considered as Precambrian basement with suspected Neoarchaean to Palaeoproterozoic ages, are actually parts of early Palaeozoic arcs. The protoliths were probably metamorphosed arc plutonic and sedimentary rocks. Combined with other studies, we speculate that the Beishan Orogen formed by progressive arc accretion during the latest Neoproterozoic to early Palaeozoic time. This new interpretation has implications for other high-grade metamorphic terranes within orogens that have been assumed to represent ancient or pre-existing micro-continental blocks. If so, the importance of collision as a mechanism of mountain building has been overestimated, and the accretionary process as a mechanism of continental growth has been underestimated.     

Stratigraphic assessment of the Arcelia–Teloloapan area,southern Mexico: implications for southern Mexico's post-Neocomian tectonic evolution

Stratigraphic assessment of the “Tierra Caliente Metamorphic Complex” (TCMC) between Arcelia and Teloloapan in southern Mexico, based on photo interpretation of Landsat Thematic Mapper images and field mapping at the 1:100,000 scale, tests different tectonic evolution scenarios that bear directly on the evolution of the southern North American plate margin. The regional geology, emphasizing the stratigraphy of a portion of the TCMC within the area between Arcelia and Teloloapan is presented. Stratigraphic relationships with units in adjacent areas are also described. The base of the stratigraphic section is a chlorite grade metamorphic sequence that includes the Taxco Schist, the Roca Verde Taxco Viejo Formation, and the Almoloya Phyllite Formation. These metamorphic units, as thick as 2.7 km, are covered disconformably by a sedimentary sequence, 2.9 km thick, composed of the Cretaceous marine Pochote, Morelos, and Mexcala Formations, as well as undifferentiated Tertiary continental red beds and volcanic rocks. The geology may be explained as the evolution of Mesozoic volcanic and sedimentary environments developed upon attenuated continental crust. Our results do not support accretion of the Guerrero terrane during Laramide (Late Cretaceous–Paleogene) time.     

Metallogeny of the northeastern Gangdese Pb–Zn–Ag–Fe–Mo–W polymetallic belt in the Lhasa terrane,southern Tibet

The northeastern Gangdese Pb–Zn–Ag–Fe–Mo–W polymetallic belt (NGPB), characterized by skarn and porphyry deposits, is one of the most important metallogenic belts in the Himalaya–Tibetan continental orogenic system. This belt extends for nearly four hundred kilometers along the Luobadui–Milashan Fault in the central Lhasa subterrane, and contains more than 10 large ore deposits with high potential for development. Three major types of mineralization system have been identified: skarn Fe systems, skarn/breccia Pb–Zn–Ag systems, and porphyry/skarn Mo–Cu–W systems. In this study, we conducted a whole-rock geochemical, U–Pb zircon geochronological, and in situ zircon Hf isotopic study of ore-forming rocks in the NGPB, specifically the Jiangga, Jiaduopule, and Rema skarn Fe deposits, and the Yaguila Pb–Zn–Ag deposit. Although some of these deposits (porphyry Mo systems) formed during the post-collisional stage (21–14 Ma), the majority (these three systems) developed during the main (‘soft collision’) stage of the India–Asia continental collision (65–50 Ma). The skarn Fe deposits are commonly associated with granodiorites, monzogranites, and granites, and formed between 65 and 50 Ma. The ore-forming intrusions of the Pb–Zn–Ag deposits are characterized by granite, quartz porphyry, and granite porphyry, which developed in the interval of 65–55 Ma. The ore-forming porphyries in the Sharang Mo deposit, formed at 53 Ma. The rocks from Fe deposits are metaluminous, and have relatively lower SiO₂, and higher CaO, MgO, FeO contents than the intrusions associated with Mo and Pb–Zn–Ag mineralization, while the Pb–Zn–Ag deposits are peraluminous, and have high SiO₂ and high total alkali concentrations. They all exhibit moderately fractionated REE patterns characterized by lower contents of heavy REE relative to light REE, and they are enriched in large-ion lithophile elements and relatively depleted in high-field-strength elements. Ore-forming granites from Fe deposits display ⁸⁷Sr/⁸⁶Sr_(i) = 0.7054–0.7074 and ε_Nd(t) = − 4.7 to + 1.3, whereas rocks from the Yaguila Pb–Zn–Ag deposit have ⁸⁷Sr/⁸⁶Sr_(i) = 0.7266–0.7281 and ε_Nd(t) = − 13.5 to − 13.3. In situ Lu–Hf isotopic analyses of zircons from Fe deposits show that ε_Hf(t) values range from − 7.3 to + 6.6, with T_DM(Hf)^C model ages of 712 to 1589 Ma, and Yaguila Pb–Zn–Ag deposit has ε_Hf(t) values from − 13.9 to − 1.3 with T_DM(Hf)^C model ages of 1216 to 2016 Ma. Combined with existing data from the Sharang Mo deposit, we conclude that the ore-forming intrusions associated with the skarn Fe and porphyry Mo deposits were derived from partial melting of metasomatized lithospheric mantle and rejuvenated lower crust beneath the central Lhasa subterrane, respectively. Melting of the ancient continental material was critical for the development of the Pb–Zn–Ag system. Therefore, it is likely that the source rocks play an important role in determining the metal endowment of intrusions formed during the initial stage of the India–Asia continental collision.     

The Pelona–Orocopia–Rand and related schists of southern California: a review of the best-known archive of shallow subduction on the planet

ABSTRACT

The Pelona–Orocopia–Rand and related schists of southern California are an archetypal example of an exhumed shallow subduction complex. ‘The schist’ comprises mainly trench materials underthust beneath continental arc rocks during Late Cretaceous–early Cenozoic collision of one or more oceanic plateaux with southern California. The arc-on-trench relationship, without intervening mantle or lowermost crust, implies that significant subduction erosion accompanied shallow subduction. Upsection increases in metamorphic grade (~150 ± 100°C/km) and spatial variations in age and peak temperature provide an ~50 million year long record of tectonic underplating within a cooling system. Evidence for palaeoseismic events in earliest formed and hottest (locally transitional granulite grade) schists provides a possible field-based record of episodic tremor and slow slip events such as detected in several modern shallow subduction zones. Structural ascent of the schist was achieved in distinct Late Cretaceous–early Eocene and late Oligocene–early Miocene extensional pulses, the first during collapse of gravitationally unstable upper plate assemblages and accompanied by trench-directed (top-NE) lower plate extrusion and the second corresponding temporally, spatially, and in character with core complex formation in the SW United States. The line between schist and core complex belts is blurred by the recent discovery of schist within 40 km of the nearest core complex and containing synkinematic Miocene intrusions, a hallmark of SW U.S. core complexes. The history of schist assembly, metamorphism, and exhumation provides the most complete field-based record of thermo-mechanical processes, subduction erosion and tectonic underplating in particular, that operated during a shallow subduction event. Future cross-disciplinary investigations of, and comparisons between, the schist and other possible ancient (e.g. Swakane gneiss, Sanbagawa belt, Qiangtang terrane) and modern (e.g. Cascadia, SW Japan, central Mexico, Chile) shallow subduction zones will yield new insights into the tectonic and petrologic processes that operate within such systems.     

U–Pb geochronology and petrology of the late Paleozoic Gil Marquez pluton: magmatism in the Variscan suture zone,southern Iberia,during continental collision and the amalgamation of Pangea

The origin of plutonic complexes that stitch suture zones developed during collision is not well understood. In southern Iberia, the Pulo du Lobo suture zone (PDLZ) is intruded by the syn- to postcollisional Gil Marquez pluton (GMP), thought to be part of the Sierra Norte Batholith. U–Pb (LA-ICPMS, zircon) data on various phases of the GMP yield from oldest to youngest: (1) a 354.4 ± 7.6 Ma unfoliated gabbro; (2) a 345.6 ± 2.5 Ma foliated intermediate phase; (3) a 346.5 ± 5.4 Ma unfoliated porphyritic granite; (4) a 335.1 ± 2.8 Ma unfoliated biotite granite. This sequence is consistent with cross-cutting relationships observed in the field. The range in ages is consistent with interpretations that the GMP is part of the composite (ca. 350–308 Ma) SNB. Inherited ages preserved in the GMP intermediate and felsic phases indicate that its magmas traversed through South Portuguese Zone and PDLZ crust during emplacement. The ca. 345 Ma emplacement of the late kinematic foliated intermediate phase constrains the age of late-stage strike slip deformation within the PDLZ, and the lack of a foliation in the older gabbro indicates that is was not proximal to a shear zone neither at the time of emplacement, nor during its subsequent history. The unfoliated porphyritic granite and unfoliated biotite granite cut the foliation of the intermediate phase indicating emplacement during the waning stages of collision, while the ca. 335 Ma biotite granite intrudes the Santa Ira Flysch, thereby providing a tight constraint for the latest stage of deformation in the PDLZ.