Study of the influence of katabatic flows on the Antarctic circulation using GCM simulations

Summary A one dimensional analytical model of katabatic wind over the Antarctica has been developed. This parametric model is derived from the bulk two-layer model of Ball including the surface friction and taking into account the Earth's rotation and the geostrophic wind in the upper layer.This model is validated using the data set (70 soundings) collected during IAGO experiment at D47 (67°24S, 138°43E, altitude 1 564m), 110 km inland from the coast of Adélie Land.The parameteric model is then introduced into a GCM which is a spectral global version of the operational numerical weather prediction model used by the French weather service. The most significant effect of the parameterization is a 50 m increase of the geopotential height over the South Pole. The surface temperature at the South Pole increases (2°C) reducing the pole-midlatitude thermal gradient. The westerly circulation at 50° S is slowed down (4m/s at 850 hPa), and the surface pressure at the South Pole increases (4hPa). These results, consistent with an increase of katabatic winds, would however be improved by a better coupling between the parameterization and the GCM boundary layer.With 8 Figures     

Nitrate in the atmospheric boundary layer of the tropical South Pacific: Implications regarding sources and transport

Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m^–3 at each of these stations: 0.107±0.011 g m^–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m^–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m^–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of ²¹⁰Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with ⁷Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m^–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.     

A study of the structure of low-level katabatic winds at Mizuho Station,East Antarctica

Low-level katabatic wind profiles, which have shapes similar to those of the low-level jet (LLJ) wind profiles, are often observed during strong winds in the summer period at Mizuho Station, which is located at 70°42 S, 44°20 E in East Antarctica. The profiles may be classified according to the height of the maximum wind speed, z _m , found below 30 m height. The behavior of z m and of conditions in the layer above z mare explained well by the normalized frequency, f N = Nz/U at 30 m, whose value can be used to predict the existence of a LLJ wind profile. Subsidence and inertial oscillations above z m are related closely to the height and time variations of z m. Thus, not only effects emanating upward from surface but also momentum and heat transported downward from above are significant for the evolution of z m.     

Diurnal variation of horizontal wind direction fluctuations in complex terrain at Geysers,Cal.

Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km² Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s^-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.     

Quantitative estimates of full glacial temperatures in equatorial Africa from palynological data*

This paper presents a new reconstruction of the mean annual temperature obtained from a high altitude pollen sequence in equatorial Africa (3°28S, 29°34E, 2240 m). It has been achieved with an extended modern African reference data set by adding spectra from 228 new sites and using another selection for pollen taxa. The purpose of this paper is to test how the obtained temperature value depends upon the availability of modern analogues. The results are in good agreement with those previously published, reinforcing the validity of the method. The mean standard error is reduced by 0.3°C. The mean temperature for the Holocene appears + 1.4°C warmer than the present and the last glacial maximum (25-18 kyrs BP) cooling is better specified at – 3 ± 1.9° C, a conservative value, more consistent with reconstructed sea surface temperature in the equatorial ocean.Contribution to Clima Locarno - Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate Program     

The application of a two-dimensional numerical model of the planetary boundary layer to the Nanticoke region on the north shore of Lake Erie

A two-dimensional atmospheric boundary-layer model is applied to the Nanticoke region on the northern shore of Lake Erie (80 ° 03W and 42 ° 50N) to simulate numerically the observed wind and temperature profiles. In general, the profiles predicted by the model agree reasonably well with the observed profiles.     

On the stable stratification of the nocturnal lower troposphere inferred from lidar observations over Pune,India

The nocturnal structure of the lower troposphere is studied using aerosol profile data (50–2800 m AGL) obtained with a bistatic, continuous wave, Argon ion lidar system during October 1986–September 1989 at Pune (18°32 N, 73°51 E, 559m AMSL), India. The top of the nocturnal groundbased inversion is taken as the height above ground where the negative vertical gradient in aerosol concentration first reaches a maximum. During the post-sunset period over this station, this height is as low as 160m and frequently lies around 550m. Greater heights are observed in pre-monsoon months and smaller ones during the southwest monsoon season. Positive vertical gradients in aerosol concentration, indicative of stable/elevated layers, appear frequently around 750m. Temporal variations of aerosol concentration gradients in two adjacent air layers, 920–1000m and 100–1100m, provide evidence that stability increases downward in the early night hours.     

High-Latitude Springtime Photochemistry. Part I: NOx, PAN and Ozone Relationships

Springtime measurements of NO_x, ozone, PAN,J(NO₂), and other compounds were made near Ny-Ålesund,Svalbard (78°54N, 11°53E), in 1994 and Poker Flat,Alaska (65°08N, 147°29W), in 1995. At Svalbard medianmixing ratios for PAN and NO_x of 237 and 23.7 pptv,respectively, were observed. The median mixing ratios at Poker Flat for PANand NO_x were 79.5 and 85.9 pptv, respectively. These data areused to estimate thermal PAN decomposition using several differentapproaches. At Svalbard PAN decomposition was very small, while at PokerFlat up to 30 pptv/h PAN decomposed. At both sites the NO_x/PANratio increased with temperature between –10 and 20°C implyingthat PAN decomposition is an important NO_x source. In-situozone production was calculated from the measured NO, NO₂,O₃, J(NO₂), and temperature data, using thesteady state assumption Median ozone production was 605 pptv/h at PokerFlat, and one order of magnitude smaller at Svalbard during the daytime.Only at Poker Flat could a direct influence on the diurnal ozone cycle beobserved from in-situ production. These results imply that PAN decompositionis a major source of NO_x in the high latitude troposphere, andthat this contributes to the observed spring maximum in surface ozone.     

Studies of the atmospheric stability characteristics during the solar eclipse of February 16, 1980

Observations made with a monostatic sodar and from a 120 m instrumented tower have been used to study the variations in the atmospheric boundary layer at Tarapur (19° 50 N, 72° 41 E) during the solar eclipse of February 16, 1980. Atmospheric instability was reduced below normal values during the eclipse but the atmosphere at no time became stable.     

Analysis of the Saharan dust regional transport

Summary The Balkan Peninsula is situated in the impact zone of Saharan dust storms. The case of Saharan dust transport to Belgrade in the period of 14–17 April 1994 is analyzed using the Eta model for synoptic and meso scale processes. Air back trajectories are calculated at six model levels from 434 up to 5129m with horizontal grid resolutions of 1°×1° and 10×10. Following cyclonic circulation the dust was picked up from North Africa, and transported over Mediterranean. Simultaneously, according to the analysis of the three lowest trajectories, transport of trace metals from Macedonia and southern Serbia by the Koshava wind might be dominant in the observed episode. Turbulent flow enhanced the coagulation process of initially clean dust particles with particles containing Pb and Cd. The coagulation and scavenging processes below and in clouds increased deposition rates of Pb and Cd in Belgrade in the course of wet removal, and consequently trough resuspension processes. Dry deposition samples contained characteristic particles up to 30µm in diameter with Fe content of 11 to 15 atomic% and significant ratio Si/Fe of 3 to 5, determined for selected single particles by the SEM/EDX method. Following dry and wet deposition of Cd and Pb, a residual effect of dustfall is noticed throughout the vegetational period.     

The wind regime in coastal areas with special reference to results obtained from the Swedish wind energy program

The paper describes various aspects of the wind regime in coastal areas as obtained from several experimental programs along the Baltic coast of Sweden. The studies include the change with distance inland of mean wind structure as well as the turbulence structure in various conditions. It is found that wind spectra are usually well described by local similarity in its high frequency part, even in complex terrain. The low frequency parts of the spectra show clear spectral lag effects. The effects of a small slope, ca 5 m height change over 300 m travel distance, is clearly seen in some spectra, and it is shown that current flow over a hill theory can be used to account for it. The change of mean wind speed throughout the entire boundary layer as the wind passes a low but wooded island (Gotland), ca 30 km wide, has been studied in a series of relatively strong wind, near neutral cases. Some unexpected features are found; in particular the wind speed decreases more rapidly with distance inland than predicted by current numerical models. Two cases with a low level jet are discussed in some detail. Arguments are presented for the phenomenon to be caused by frictional decoupling at the Latvian coast, about 200 km upwind — the jet being thus an analogy in space to the classical Blackadar nocturnal jet frequently observed in continental areas.     

Effects of heat and water vapor transport on eddy covariance measurement of CO2 fluxes

Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO₂ concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO₂, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO₂. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= _cw for CO₂, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux _c w. Thus, when the net flux of CO₂ is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., _c w = – _c w. Corrections for the mean convective flux are particularly significant for CO₂ because _cw and _c w are often of similar magnitude. The correct measurement of the net CO₂ flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.     

Measurement of atmospheric total ozone by the filter photometric method

The total ozone content in the atmosphere was determined from the multichannel photometer observations of direct solar radiation made in the urban environment at Pune (18° 32 N, 73° 51E, 559 m ASL) and Sinhagad hill station (18° 22N, 73° 45E, 1305 m ASL) during March 1980-February 1982. The total ozone content of the atmosphere was computed making use of the differential absorption of solar radiation due to ozone at 0.4 and 0.6 m wavelengths in the Chappuis band. The values of the ozone data obtained from the photometer observations at Pune and Sinhagad were compared with the corresponding ozone data obtained from the Dobson spectrophotometer located at Pune. Values of ozone obtained by the photometric method were found to be smaller by 8–18% than the Dobson values when Vigroux's absorption coefficients were used. Similarly, when the absorption coefficients of Inn and Tanaka (1953) were used, the ozone values obtained by the photometric method were smaller by 4–14% than the Dobson values. The ozone values at the hill station obtained from the photometric method were in better agreement (5%) with the Dobson values.     

Atmospheric trace gas measurements at Palmer Station,Antarctica: 1982–83

In early 1982 a station capable of sampling atmospheric trace gas constituents on a continuous basis was established at Palmer Station, Anvers Island, adjacent to the Antarctic Peninsula (64° 46S 64° 04W). Sampling operations began about 1 February 1982. This is an initial report on this station, its location, equipment and general research objectives along with some initial sampling results. The constituents being measured and recorded were: ozone, methane, carbon dioxide, carbon monoxide, CCl₃F (fluorocarbon-11), CCl₂F₂ (fluorocarbon-12), carbontetrachloride, methylchloroform, nitrous oxide, and Aitken nuclei (CN). Data storage, data processing, and sampling system control is handled by a Hewlett-Packard 85 system. Preliminary analyses of about the first 20–22 months of data are presented and show not only the expected long-term trends but also shorter period concentration cycles that seem to be related to synoptic meteorology.     

Occurrence of roll circulations in a shallow boundary layer

Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z _i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.     

Clear sky ultraviolet-B radiation in the English Midlands: A comparison of measured and modelled values

Summary Spectral measurements were made of solar ultraviolet-B (UVB) irradiance at Sutton Bonington (52° 50N, 1° 15W) under cloudless skies using a Licor LI 1800 scanning spectroradiometer. The finite bandpass of the instrument and the steep shape of the UVB spectra caused overestimation of irradiance at short wavelengths. Spectra were corrected mathematically for these effects.The corrected spectra were compared to estimates of global UVB irradiance as a function of zenith angle and amount of ozone. Comparisons were made at 300 nm, 310 nm and 320 nm. Estimates were significantly greater (p = 0.05) than the measurements except at 320 nm where differences were not significant. The differences may have been the result of overestimation of UVB at short wavelengths, since some of the assumptions on which the estimates were based may not be valid for Sutton Bonington conditions.

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Zusammenfassung Unter wolkenlosem Himmel wurden in Sutton Bonington (52° 50N, 1° 15W) mittels eines Licor LI 1800 Spektroradiometer-Scanners Spektralmessungen von Ultraviolett-B (UVB)-Strahlung durchgeführt. Die endliche Bandbreite des Instruments und der steile Anstieg der UVB-Spektren führten zu einer Überschätzung der Strahlung im kurzwelligen Bereich. Die Spektren wurden in dieser Hinsicht mathematisch korrigiert.Die korrigierten Spektren wurden mit den Schätzwerten der globalen UVB-Strahlung — als Funktion von Zenithwinkel und Ozonmenge — bei 300nm, 310nm und 320nm verglichen. Hiebei erwiesen sich die Schätzwerte wesentlich höher (p = 0,05) als die Meßwerte, nur bei 320nm waren die Unterschiede nicht signifikant. Die Unterschiede könnten aus der Überschätzung von UVB im kurzwelligen Bereich resultieren, da einige der Schätzungsvoraussetzungen auf die Bedingungen in Sutton Bonington nicht zutreffen dürften.

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On leave from Department of Agronomy and Soils, Washington State University, Pullman, WA, U.S.A.

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With 4 Figures     

Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2

The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O₂ of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O₂ versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(H_{decomposition}–H_{O 2 reaction}), between these two reactions pathways. For (H)[22–0.5(H_{O 2 reaction})], alkoxy radical decomposition dominates over the reaction with O₂ at room temperature and atmospheric pressure of air, while for (H)[25-0.5(H_{O 2 reaction})], the O₂ reaction dominates over decomposition (where the units of H are in kcal mol^–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.     

Glaciers and Climate in the Andes between the Equator and 30° S: What is Recorded under Extreme Environmental Conditions?

Sublimation and melt disturb the environmental information obtained from ice core records in the Andes. In two case studies we demonstrate to what extent these post-depositional processes may remove major parts of the accumulated snow cover. Dark ash layers from the Tungurahua eruption changed the albedo of surface snow on Chimborazo glacier (6268 m, 1°30 S,78°36 W, Ecuador) between two ice core drilling campaigns and forced substantial melt. Re-distribution and washout of the chemical constituents shifted the concentration profiles obtained in December 1999 as compared to an equivalent core drilled in December 2000. The stable isotope records showed that approximately the water equivalent (weq) of an annual layer had melted, and that the percolating melt water penetrated within the firn layer to a depth of at least 16.5 m without refreezing. In the second example, from a site on the dry axis between the tropical and extra-tropical precipitation belts, significant loss of accumulated snow layers occurred by sublimation. A surface experiment at Cerro Tapado glacier (5536 m, 30°08 S,69°55 W, Chile) revealed that losses of 2 mm weq (5 mm snow) per day occurred during the dry period following the 1997/98 El Niño. This loss generally included the entire surface layer enriched in stable isotopes, and thus caused minimal disturbance of the isotopic signature (and hence climatic information) of the net accumulation, yet chemical constituents again experienced considerable changes in concentration. From annual layer counting and direct dating it is obvious that the major part of the accumulated ice on both glaciers is younger than 100 years; however, isotopic and chemical variations at least in the basal ice from Cerro Tapado clearly point to climate conditions different from the recent centuries. This evidence is supported by mass balance considerations derived from a glacier-climate model. The possibility of a third type of disturbance aside from sublimation and melting – in this case a significant hiatus in the environmental chronology – also deserves consideration for other icecore records from this region. Potential disruptions or discontinuities need to be carefully evaluated given the profound changes in climatic and glaciological conditions since the Last Glacial Maximum throughout Holocene times.     

Climatology of Ozone, PAN, CO, and NMHC in the Free Troposphere Over the Southern North Atlantic

Free tropospheric measurements of ozone, peroxyacetylnitrate andprecursors (CO, NMHC) that were made within the framework of the EUROTRACsub-project TOR (Tropospheric Ozone Research) between 1990 and 1995 at theGAW station Izana, Tenerife (28°18N, 16°30W) arediscussed. The average annual cycles reveal the importance of transport fromnorthern mid-latitudes and the role of photo-chemistry. According toair-mass trajectories, which were supplied to us from AEROCE(Atmosphere/Ocean Chemistry Experiment), transport from northernmid-latitudes is associated with high precursor concentrations in winter,whereas ozone concentrations in winter are not much influenced by transportpatterns, suggesting a rather uniform distribution over the northern part ofthe Northern Hemisphere around mean value of 43 ± 5 ppb. In summer,high ozone concentrations of up to 90 ppb are often encountered duringtransport from north, while the levels of precursors are much lower than inwinter, because of photochemical destruction. Trajectories from southerlylatitudes and the Sahara usually have the lowest ozone concentrationsassociated with them.     

Latitudinal variation of air sea fluxes in the western Indian ocean during austral summer and fall

Daily and zonal (latitudinal belt) averages of heat and momentum fluxes were computed using bulk aerodynamic formulae, from the meteorological parameters measured onboard M. S. Thuleland during the sixth Indian scientific expedition to Antarctica (26th November, 1986 to 22nd March, 1987). Both estimates showed significant variations, the momentum flux showing the largest variation. The maximum values of sensible and latent heat fluxes were observed over the 30°–40° S and 10°–20° S zones during the southern summer and fall respectively while the minimum values of latent heat flux were observed in the 60°–70° S zone for both seasons. The sensible heat flux minimum was observed in the 50°°60° S and 60°–70° S zones for summer and fall, respectively. Higher momentum flux values over the 40°–50° S zone in summer shifted to the 50°–60° S zone during fall.