Physical properties and petrologic description of rock samples from an IOCG mineralized area in the northern Fennoscandian Shield, Sweden

The Tjårrojåkka Fe–Cu-prospect in northern Sweden is considered an example of a Fe-oxide Cu–Au (IOCG) deposit and is hosted in metamorphosed Paleoproterozoic volcanic and intrusive rocks. Rock samples from 24 outcrops were collected for petrophysical analysis (magnetic susceptibility, remanent magnetization, variation of magnetic susceptibility with temperature, Curie temperature and density). The major Cu-prospect in the area has been studied by magnetic and electron microprobe analyses of four selected rock samples. The samples are from an exploration well that intersects the main Cu-mineralized body.The magnetic analyses show that magnetite is the dominant magnetic mineral, while hematite and other Fe-minerals are present in minor amounts. The electron microprobe observations confirm the presence of magnetite and further indicate that hematite is an alteration product of magnetite. Moreover, microprobe observations indicate that Fe-sulfides are present in negligible amounts in the samples from the Tjårrojåkka area. The strong spatial relationship of Cu-minerals (e.g., chalcopyrite) and the oxidation of magnetite to hematite suggest that the presence of rocks with low magnetic susceptibility in areas dominated by high susceptibility rocks may be a signal of related Cu-prospects.     

Episodic fluid migration in the Fennoscandian Shield recorded by stable isotopes, rare earth elements and fluid inclusions in fracture minerals at Forsmark, Sweden

Drilling through the Palaeoproterozoic bedrock at Forsmark, central Sweden, during the site investigation for a potential geological repository of highly radioactive nuclear waste has provided high quality drill-core material from the upper 1 km of the Fennoscandian Shield. Analyses of stable isotopes (δ¹³C, δ¹⁸O, δ³⁴S, ⁸⁷Sr/⁸⁶Sr), rare earth elements and fluid inclusions in fracture filling calcite and pyrite from these drill cores have resulted in the discrimination of several episodes of fracture mineralisations. These events represent migration of fluids during a wide range of conditions, ranging from high-temperature hydrothermal to present-day groundwater circulation. Four major events have been distinguished: 1) Precipitation of epidote, chlorite and quartz under hydrothermal conditions (T > 150–200 °C) during the Proterozoic, sometime between 1.8 and 1.1 Ga. 2) Hydrothermal circulation at temperatures close to 200 °C with precipitation of adularia, albite, prehnite, laumontite, calcite and chlorite. Most of these minerals precipitated during a tectonothermal event between 1.1 and 1.0 Ga, possibly in response to far-field effects of the Sveconorwegian orogeny. 3) Precipitation of mainly quartz, calcite, pyrite and asphaltite occurred during the Palaeozoic, at temperatures between 60 and 190 °C (mainly at < 100 °C). Mixing of a fluid emanating from an organic rich overlying sedimentary cover and a deep basinal fluid from the crystalline bedrock is suggested to have caused this precipitation, possibly as a far-field response to the Caledonian orogeny and/or the development of the Caledonian foreland basin. 4) The youngest generation of fracture minerals is associated with formation of clay minerals and calcite with minor occurrences of pyrite and goethite. These minerals have probably precipitated episodically during a long time period (possibly from the Late Palaeozoic to the present) from various fluids at low temperature conditions (< 50 °C). Few calcites in equilibrium with the present groundwater suggest that the ongoing precipitation of calcite is very limited.     

A methodology to constrain the parameters of a hydrogeological discrete fracture network model for sparsely fractured crystalline rock,exemplified by data from the proposed high-level nuclear waste repository site at Forsmark,Sweden

The large-scale geological structure of the crystalline rock at the proposed high-level nuclear waste repository site at Forsmark, Sweden, has been classified in terms of deformation zones of elevated fracture frequency. The rock between deformation zones was divided into fracture domains according to fracture frequency. A methodology to constrain the geometric and hydraulic parameters that define a discrete fracture network (DFN) model for each fracture domain is presented. The methodology is based on flow logging and down-hole imaging in cored boreholes in combination with DFN realizations, fracture connectivity analysis and pumping test simulations. The simulations suggest that a good match could be obtained for a power law size distribution where the value of the location parameter equals the borehole radius but with different values for the shape parameter, depending on fracture domain and fracture set. Fractures around 10–100 m in size are the ones that typically form the connected network, giving inflows in the simulations. The report also addresses the issue of up-scaling of DFN properties to equivalent continuous porous medium (ECPM) bulk flow properties. Comparisons with double-packer injection tests provide confidence that the derived DFN formulation of detailed flows within individual fractures is also suited to simulating mean bulk flow properties and their spatial variability.     

Effects of groundwater extraction from crystalline hard rock on water chemistry in an acid forested catchment at Gårdsjön,Sweden

Atmospheric deposition of S in Sweden has decreased by some 80% over the last 15 a, resulting in a general reduction of SO₄ concentrations in ground and surface water. This project, however, shows that artificial hydrological alteration in an acid wetland can reverse this trend and increase acidity and SO₄ concentrations. The experiment involved the monitoring of two catchments in relatively virgin conditions. In one of the catchments, an experiment with intensive groundwater extraction from the bedrock was carried out. During the experiment, the runoff from the catchment decreased by 50%. Furthermore, the extraction of groundwater resulted in increased seasonal aeration of the centrally located wetland, leading to oxidation of reduced S bound to the soil layers of the wetland. The S changed to solute SO₄, with a subsequent SO₄ surge. Thus, the experiment resulted in an induced acidification of the wetland and runoff waters. The extraction of groundwater significantly increased the recharge of water from the overburden, glacial till and organic soils to groundwater in the bedrock, which in turn reduced the retention time in the bedrock aquifer. These changes resulted in the chemical signature of the groundwater in the bedrock becoming similar to those of the wetland. The findings revealed deterioration in the water quality in the bedrock due to increased concentrations of dissolved organic C and SO₄, as well as a decrease in pH.     

A field study (Massachusetts, USA) of the factors controlling the depth of groundwater flow systems in crystalline fractured-rock terrain

Groundwater movement and availability in crystalline and metamorphosed rocks is dominated by the secondary porosity generated through fracturing. The distributions of fractures and fracture zones determine permeable pathways and the productivity of these rocks. Controls on how these distributions vary with depth in the shallow subsurface (<300 m) and their resulting influence on groundwater flow is not well understood. The results of a subsurface study in the Nashoba and Avalon terranes of eastern Massachusetts (USA), which is a region experiencing expanded use of the fractured bedrock as a potable-supply aquifer, are presented. The study logged the distribution of fractures in 17 boreholes, identified flowing fractures, and hydraulically characterized the rock mass intersecting the boreholes. Of all fractures encountered, 2.5% are hydraulically active. Boreholes show decreasing fracture frequency up to 300 m depth, with hydraulically active fractures showing a similar trend; this restricts topographically driven flow. Borehole temperature profiles corroborate this, with minimal hydrologically altered flow observed in the profiles below 100 m. Results from this study suggest that active flow systems in these geologic settings are shallow and that fracture permeability outside of the influence of large-scale structures will follow a decreasing trend with depth.     

Glaciotectonic deformation during the Elsterian ice-sheet advance at the northeastern margin of the Sudetic Foreland, SW Poland

The glaciotectonic deformations near the northeastern margin of the Sudetic Foreland, SW Poland. were formed during one glacial episode. They are relatively small and are truncated. Deformation structures have no recognizable relationship to the thick Neogene clay in the basement; they have variable relations to the morphology and indicate transverse to opposite directions of the glacial push in very small areas within a distance of 2 to 5 km. This suggests an unusual deformational history. Deformations have probably been created due to sliearing en masse of the anisotropic sediments and during the ice-sheet advance. Deformation structures have been formed a few kilometres ahead of the curved ice margin, which created 'glaciotectonic hills' with strongly differentiated orientations of thrust structures and folds.     

Spatiotemporal relationships of dike magmatism in the Kola region, the Fennoscandian Shield

A brief geological and petrographic characterization of the Early Precambrian dike complexes of the Kola region is given along with data on new estimates of dike age and analysis of their distribution over the entire Fennoscandian Shield. The emplacement of dikes in the Archean core of the shield continued after consolidation of the sialic crust 2.74?C1.76 Ga ago. After the Svecofennian Orogeny, dikes continued to form in the west in the area of newly formed crust, while the amagmatic period began in the Archean domain. The intense formation of dikes in the Svecofennian domain lasted approximately for 1 Ga (1.8?C0.84 Ga). The younger igneous rocks in the crustal domains of different age are less abundant and localized at their margins. A similar distribution of dikes is characteristic of other shields in different continents. This implies that the formation of the sialic crust in the shields is not completed by its consolidation and formation of the craton. For 1 Ga after completion of this process, the crust is underplated by mantle-derived magmas. This process is reflected at the Earth??s surface in the development of mantle-derived mafic and anorogenic granitoid magmatism. The process of crust formation is ended as the subcratonic lithosphere cools and the amagmatic period of the craton history is started. Beginning from this moment, the manifestations of cratonic magmatism were related either to the superposed tectonomagmatic reactivation of the cold craton under the effect of crust formation in the adjacent mobile belts or to the ascent of mantle plumes.     

Heat tracing to examine seasonal groundwater flow beneath a low-gradient stream in rural central Illinois,USA

The thermal profile of a streambed is affected by a number of factors including: temperatures of stream water and groundwater, hydraulic conductivity, thermal conductivity, heat capacity of the streambed, and the geometry of hyporheic flow paths. Changes in these parameters over time cause changes in thermal profiles. In this study, temperature data were collected at depths of 30, 60, 90 and 150 cm at six streambed wells 5 m apart along the thalweg of Little Kickapoo Creek, in rural central Illinois, USA. This is a third-order low-gradient baseflow-fed stream. A positive temperature gradient with inflection at 90-cm depth was observed during the summer period. A negative temperature gradient with inflection at 30 cm was observed during the winter period, which suggests greater influence of stream-water temperatures in the substrate during the summer. Thermal models of the streambed were built using VS2DHI to simulate the thermal profiles observed in the field. Comparison of the parameters along with analysis of temperature envelopes and Peclet numbers suggested greater upwelling and stability in temperatures during the winter than during the summer. Upwelling was more pronounced in the downstream reach of the pool in the riffle and pool sequence.     

Accuracy of CFC groundwater dating in a crystalline bedrock aquifer: Data from a site in southern Sweden

The concentrations of chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium were determined in groundwater in fractured crystalline bedrock at Finnsjön, Sweden. The specific goal was to investigate the accuracy of CFC dating in such an environment, taking potential degradation and mixing of water into consideration. The water was sampled to a depth of 42 m in three boreholes along an 800-m transect, from a recharge area to a local discharge area. The CFC-113 concentration was at the detection limit in most samples. The apparent recharge date obtained from CFC-11 was earlier than from CFC-12 for all samples, with a difference of over 20 years for some samples. The difference was probably caused by degradation of CFC-11. The CFC-12 dating of the samples ranged from before 1945 to 1975, with the exception of a sample from the water table, which had a present-day concentration. Conclusions about flow paths or groundwater velocity could not be drawn from the CFCs. The comparison between CFC-12 and tritium concentrations showed that most samples could be unmixed or mixtures of waters with different ages, and the binary mixtures that matched the measured concentrations were determined. The mixing model approach can be extended with additional tracers.

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Resumen Precisión en la datación de aguas subterráneas utilizando CFC en un acuífero de rocas cristalinas: datos provenientes de un sitio al sur de Suecia.Se determinaron las concentraciones de clorofluorucarbonos (CFC-11, CFC-12, y CFC-113) y de tritio en aguas subterráneas alojadas en rocas cristalinas fracturadas de Finnsjön, Suecia. El objetivo específico consistió en investigar la precisión de la datación de aguas subterráneas con CFC en este tipo de ambiente, tomando en consideración la degradación potencial y la mezcla de agua. Las muestras de agua se tomaron a una profundidad de 42 m en tres pozos ubicados a lo largo de una línea de 800 m transversal a una zona de recarga y de zona de descarga local. En la mayoría de las muestras se encontró que la concentración de CFC-113 estuvo en el límite de detección. La edad que se estimó en todas las muestras para la recarga aparente en base a CFC-11 fue más joven que la edad proveniente de CFC-12, con una diferencia de más de 20 años para algunas muestras. Esta diferencia fue causada probablemente por la degradación del CFC-11. La datación CFC-12 de las muestras varió de antes de 1945 a 1975, con la excepción de una muestra tomada en el nivel freático, la cual presentó concentración actual. No fue posible obtener conclusiones acerca de las trayectorias de flujo o la velocidad de agua subterránea a partir de los CFCs. La comparación entre las concentraciones de CFC-12 y tritio mostró que la mayoría de las muestras pueden tener composición sencilla o bien consistir de mezclas de aguas de diferentes edades. Esta comparación también permitió determinar las mezclas binarias que corresponden a las concentraciones medidas. Pueden utilizarse trazadores adicionales para ampliar el modelo de mezclas propuesto.

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Résumé Précision de la datation au CFC dans un aquifère rocheux-fracturé: données dun site du sud de la Suède.Les concentrations en chlorofluorocarbones (CFC-11, CFC-12, CFC-113) et entritium ont été déterminées dans leau souterraine dun massif fracturé à Finnsjön en Suède. Le but de cette étude est de mieux cerner la précision de la méthode de datation au CFC dans ce type denvironnement hydrogéologique, tout en considérant déventuels phénomènes de dégradation et de mélange deaux. Leau a été échantillonnée à une profondeur de 42 mètres dans trois forages alignés sur 800 mètres entre une zone de recharge et une zone de déversement. Les concentrations en CFC-113 sont dans la plupart des échantillons à la limite de détection. Pour tous les échantillons, la date de la recharge établie avec le CFC-11 est antérieure à la date établie avec le CFC-12. La différence entre les deux dates peut dépasser 20 ans et sexplique—probablement—par la dégradation du CFC-11. Les dates de recharge de la nappe mesurées au CFC-12 sont comprises entre 1945 et 1975, excepté pour un échantillon qui possède une concentration actuelle. Il nest pas possible de tirer des conclusions concernant la direction des écoulements et la vitesse de leau souterraine. La comparaison entre CFC-12 et tritium montre que des échantillons pourraient être soit le résultat du mélange deaux dâges différents, soit des échantillons non-mélangés. Dans le cas dun mélange binaire, les rapports du mélange composant la concentration mesurée sont déterminés. Lapproche par modèle de mélange peut être étendue à des traceurs additionnels.

     

Hydrogeochemistry of the groundwater flow system in a crystalline terrain: a study from the Kurunegala district,Sri Lanka

Water samples collected from dug wells and tube wells from the Kurunegala District of Sri Lanka have been studied for their major hydrogeochemical parameters to understand the chemical quality of water in the terrain. The region is composed of Precambrian metamorphic rocks where groundwater is only available in the regolith and along weak structural discontinuities. The study of the major chemical constituents of groundwater revealed several relationships with the aquifer lithology. Groundwater from mafic rocks have high dissolved solids, while quartzose metaclastic rocks yield water with low dissolved solids. The study area displays very low SO₄ ²⁻ contents of the groundwater. The chloride content is higher in the dry regions and in terrains underlain by pink granite and marble/calc gneiss while areas with marble, as expected, show high concentrations of Ca and Mg ions. The waters in the region can be classified into non-dominant cations to Na + K dominant and Cl⁻ and HCO₃ ⁻ dominant types. Water from charnockite-bearing areas tends to have non-dominant cations and more CO₃ ²⁻ + HCO₃ ⁻ types. Effects such as soluble salts in the regolith, fracture intensity and climatic variations play a significant role in the behavior of the hydrogeochemistry in the area.     

Reactive monazite and robust zircon growth in diatexites and leucogranites from a hot,slowly cooled orogen: implications for the Palaeoproterozoic tectonic evolution of the central Fennoscandian Shield,Sweden

Monazite in melt-producing, poly-metamorphic terranes can grow, dissolve or reprecipitate at different stages during orogenic evolution particularly in hot, slowly cooling orogens such as the Svecofennian. Owing to the high heat flow in such orogens, small variations in pressure, temperature or deformation intensity may promote a mineral reaction. Monazite in diatexites and leucogranites from two Svecofennian domains yields older, coeval and younger U–Pb SIMS and EMP ages than zircon from the same rock. As zircon precipitated during the melt-bearing stage, its U–Pb ages reflect the timing of peak metamorphism, which is associated with partial melting and leucogranite formation. In one of the domains, the Granite and Diatexite Belt, zircon ages range between 1.87 and 1.86 Ga, whereas monazite yields two distinct double peaks at 1.87–1.86 and 1.82–1.80 Ga. The younger double peak is related to monazite growth or reprecipitation during subsolidus conditions associated with deformation along late-orogenic shear zones. Magmatic monazite in leucogranite records systematic variations in composition and age during growth that can be directly linked to Th/U ratios and preferential growth sites of zircon, reflecting the transition from melt to melt crystallisation of the magma. In the adjacent Ljusdal Domain, peak metamorphism in amphibolite facies occurred at 1.83–1.82 Ga as given by both zircon and monazite chronology. Pre-partial melting, 1.85 Ga contact metamorphic monazite is preserved, in spite of the high-grade overprint. By combining structural analysis, petrography and monazite and zircon geochronology, a metamorphic terrane boundary has been identified. It is concluded that the boundary formed by crustal shortening accommodated by major thrusting.     

Numerical simulation of groundwater flow in regional rock aquifers, southwestern Quebec, Canada

The St. Lawrence Lowlands platform, Quebec, Canada, is a densely-populated area, heavily dependent on groundwater resources. In 1999, the Geological Survey of Canada initiated a large-scale hydrogeological assessment study over a 1,500 km² region northwest of Montreal. The objectives were to define the regional groundwater flow, and to give quantitative estimates of the groundwater dynamic parameters and of the available groundwater resources. The applied approach consisted of defining the hydrogeologic framework, hydraulic properties of the aquifer units, and groundwater dynamic components. Lower Paleozoic sedimentary rocks represent regional aquifer units. Coarse Quaternary fluvio-glacial sediments locally overlay the rock sequence and constitute an interface aquifer unit. Fine marine sediments confine most of the regional aquifers. Collected GIS based information was synthesized in a finite element numerical model. The regional saturated steady-state flow was calibrated under current stress conditions assuming an equivalent porous medium approach. Water budget calculations show that the total groundwater flow in regional aquifers amounts to 97.7 Mm³/y. Infiltration from precipitation provides 86.6% of the groundwater supply, while 9.6% comes from subsurface inflow and the remaining 3.8% is induced recharge from surface waters. Discharge from regional aquifers occurs through flow to streams (76.9%), groundwater withdrawal (18.4%), and underground outflow (4.7%).

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Resumen La plataforma de Tierras Bajas San Lorenzo, Quebec, Canadá, es un área densamente poblada que depende fuertemente de recursos de agua subterránea. En 1999 el Servicio Geológico de Canadá inició un estudio de evaluación hidrogeológica a gran escala sobre un área de 1,500 km² en la región noroeste de Montreal. Los objetivos fueron definir el flujo regional de agua subterránea y aportar estimados cuantitativos de los parámetros dinámicos de agua subterráne y de los recursos disponibles de agua subterránea. El enfoque aplicado consistió en definir el marco hidrogeológico, propiedades hidráulicas de las unidades acuíferas, y los componentes dinámicos de agua subterránea. Rocas sedimentarias del Paleozoico Inferior representan unidades regionales de acuíferos. Sedimentos fluvio-glaciares Cuaternarios gruesos sobreyacen localmente la secuencia rocosa y constituyen una unidad acuífera interfacial. Sedimentos marinos finos confinan la mayoría de acuíferos regionales. Información colectada basada en SIG se sintetizó en un modelo numérico de elemento finito. El flujo regional saturado en régimen permanente se calibró bajo condiciones de stress asumiendo un enfoque de medio poroso equivalente. Los cálculos de balance hídrico muestran que el flujo total de agua subterránea en acuíferos regional alcanza 97.7 Mm³/año. Infiltración a partir de lluvia aporta el 86.6% del abastecimiento al agua subterránea, mientras que el 9.6% proviene de entradas subsuperficiales y el restante 3.8% consiste de recarga inducida a partir de aguas superficiales. La descarga proveniente de acuíferos regionales ocurre a través de flujo a ríos (76.9%), utilización de agua subterránea (18.4%), y salida subterránea (4.7%).

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Résumé La plateforme Lowllands du Saint-Laurent, Québec, Canada, est une aire densément peuplée, dépendant grandement des ressources en eau souterraine. En 1999, le Service Géologique du Canada a initié une étude hydrogéologique à grande-échelle sur 1500 km² au Nord-Ouest de Montréal. Le sobjectifs ont été de définir la dynamique de lécoulement régional, et de donner des estimations quantitatives des paramètres dynamiques des ressources disponibles en eau souterraine. Lapproche utilisée consista à définir le cadre hydrogéologique de travail, les propriétés hydrauliques des unités aquifères, et les composantes dynamiques des eaux souterraines. Les roches sédimentaires du Paléozoïque Inférieur représentent les unités aquifères régionales. Les sédiments marins fins confinent la plus grande partie des aquifères régionaux. Les informations de base, collectées dans un SIG, ont été synthétisées dans un modèle numérique aux éléments finis. Lécoulement permanent régional, en zone saturée, a été calibré en conditions de stress en assumant une approche de milieu poreu équivalent. Les calculs du bilan hydrologique montrent que lécoulement total des eaux souterraines dans les aquifères régionaux atteind 97,7 Mm³/an. Linfiltration à partir des précipitations apporte 86.6% de leau souterraine exploitée; sachant que 9,6% proviennent découlement de subsurfaces, et que les 3,8% restants proviennent de la recharge via les eaux de surface. Le débit pompé des aquifères régionaux apparaît à travers lécoulement des cours deau, le rabattement des eaux souterraines (18.4%), et lécoulement ascendant (4.7%).

     

A Tectonic Remnant of the Mesoarchean Oceanic Lithosphere in the Belomorian Province,Fennoscandian Shield

Geotectonics - The results of detailed geological mapping, coupled with the isotope-geochemical study of a metamorphosed mafic-ultramafic complex known as the Central Belomorian Belt located in the...     

Modeling anthropogenic boron in groundwater flow and discharge at Volusia Blue Spring (Florida,USA)

Volusia Blue Spring (VBS) is the largest spring along the St. Johns River in Florida (USA) and the spring pool is refuge for hundreds of manatees during winter months. However, the water quality of the spring flow has been degraded due to urbanization in the past few decades. A three-dimensional contaminant fate and transport model, utilizing MODFLOW-2000 and MT3DMS, was developed to simulate boron transport in the Upper Florida Aquifer, which sustains the VBS spring discharge. The VBS model relied on information and data related to natural water features, rainfall, land use, water use, treated wastewater discharge, septic tank effluent flows, and fertilizers as inputs to simulate boron transport. The model was calibrated against field-observed water levels, spring discharge, and analysis of boron in water samples. The calibrated VBS model yielded a root-mean-square-error value of 1.8 m for the head and 17.7 μg/L for boron concentrations within the springshed. Model results show that anthropogenic boron from surrounding urbanized areas contributes to the boron found at Volusia Blue Spring.     

Paleohydrogeological events recorded by stable isotopes,fluid inclusions and trace elements in fracture minerals in crystalline rock,Simpevarp area,SE Sweden

Fracture minerals calcite, pyrite, gypsum, barite and quartz, formed during several events have been analysed for δ¹³C, δ¹⁸O, δ³⁴S, ⁸⁷Sr/⁸⁶Sr, trace element chemistry and fluid inclusions in order to gain knowledge of the paleohydrogeological evolution of the Simpevarp area, south-eastern Sweden. This area is dominated by Proterozoic crystalline rocks and is currently being investigated by the Swedish Nuclear Fuel and Waste Management Co. (SKB) in order to find a suitable location for a deep-seated repository for spent nuclear fuel. Knowledge of the paleohydrogeological evolution is essential to understand the stability or evolution of the groundwater system over a time scale relevant to the performance assessment for a spent nuclear fuel repository. The ages of the minerals analysed range from the Proterozoic to possibly the Quaternary. The Proterozoic calcite and pyrite show inorganic and hydrothermal-magmatic stable isotope signatures and were probably formed during a long time period as indicated by the large span in temperatures (c. 200–360 °C) and salinities (0–24 wt.% eq. CaCl₂), obtained from fluid inclusion analyses. The Paleozoic minerals were formed from organically influenced brine-type fluids at temperatures of 80–145 °C. The isotopic results indicate that low temperature calcite and pyrite may have formed during different events ranging in time possibly from the end of the Paleozoic until the Quaternary. Formation conditions ranging from fresh to brackish and saline waters have been distinguished based on calcite crystal morphologies. The combination of δ¹⁸O and crystal morphologies show that the fresh–saline water interface has changed considerably over time, and water similar to the present meteoric water and brackish seawater at the site, have most probably earlier been residing in the bedrock. Organic influence and closed system in situ microbial activity causing disequilibrium are indicated by extremely low δ¹³C (down to −99.7‰), extreme variation in δ³⁴S (−42.5‰ to +60.8‰) and trace element compositions. The frequency of calcite low in δ¹³C and high in Mn, as well as pyrite with biogenically modified δ³⁴S decreases with depth. Strontium isotopes have been useful to separate the different generations and the Sr isotope ratios in the groundwaters have been determined mainly by in situ water–rock interaction processes. The difficulty of separating late Paleozoic calcite from possibly recent calcite, and the fact that these calcites are usually found in the same fracture systems indicate that water conducting structures have been intermittently conductive from the Paleozoic and onwards. The methodology used has been successful in separating the different generations and characterising their formation conditions.     

Water–rock interaction induced by contaminated groundwater in a karst aquifer, Greece

The karst system of SW Trifilia is composed of a thick sequence of carbonate sediments, which have experienced two types of dolomitization and dedolomitization processes and comprise an extended aquifer. The application of fertilizers in the region have not only caused the degradation of the groundwater quality but also induced hydrochemical changes exerting major control on dolomitization processes. Factor analysis indicates high correlation coefficient between NH ₄ ⁺ , NO ₃ ⁻ , Ca²⁺ and Mg²⁺, which can be attributed to cation-exchange processes involving clay minerals. The application of a conservative mixing model showed that the calculated groundwater types indicate a cation-exchange process between NH ₄ ⁺ , derived from fertilizers, and between Ca²⁺ and Mg²⁺. Mg²⁺ released from smectite interlayers, exchanged for NH ₄ ⁺ in the groundwater and favor a dolomitization process through the partial replacement of Ca²⁺ in the lattice of calcite (dedolomite) contained in precursor dolomites. This recent stage dolomitization occurred near the water level and within the phreatic zone only and had not influenced the whole karst massif; it also resulted in low Mg/Ca values found in the zone characterized by intensive application of nitrogen-based fertilizers and the absence of overlying impermeable strata.     

Effects on groundwater flow of abandoned engineered structures for the safety assessment of the proposed high-level nuclear waste repository site at Forsmark,Sweden

Effects on groundwater flow of abandoned engineered structures in relation to a potential geological repository for spent high-level nuclear fuel in fractured crystalline rock at the Forsmark site, Sweden, are studied by means of numerical modeling. The effects are analyzed by means of particle tracking, and transport-related performance measures are calculated. The impacts of abandoned, partially open repository tunnels are studied for two situations with different climate conditions: a “temperate” climate case with present-day boundary conditions, and a generic future “glacial” climate case with an ice sheet covering the repository. Then, the impact of abandoned open boreholes drilled through the repository is studied for present-day climate conditions. It is found that open repository tunnels and open boreholes can act as easy pathways from repository level to the ground surface; hence, they can attract a considerable proportion of particles released in the model at deposition hole positions within the repository. The changed flow field and flow paths cause some changes in the studied performance measures, i.e., increased flux at the deposition holes and decreased transport lengths and flow-related transport resistances. However, these effects are small and the transport resistance values are still high.