Climatic change in Central Asia during MIS 3/2: a case study using biological responses from Lake Baikal

A Marine Isotope Stage (MIS) 3/early MIS 2 section from a structural high along the east coast of the North Basin of Lake Baikal was analysed for diatoms, C/N ratios, and organic carbon isotope ratios. Diatoms were present throughout MIS 3 and early MIS 2, with high concentrations of the planktonic taxa Cyclotella sp. c.f. gracilis between 54 and 51.5 kyr BP indicating relatively warm, interstadial, conditions. Following a %TOC inferred climatic cooling between 43.2 and 39.1 kyr BP, evidence of a more muted δ¹³C_(organic) and %TOC inferred climatic warming from c. 39.1–34.7 kyr BP coincides with a period of very high diatom concentrations, indicating high aquatic productivity, at the Buguldeika Saddle in the South Basin of Lake Baikal. No evidence exists for a ‘Kuzmin’ catchment erosional event in the North Basin during MIS 3. This, however, may reflect the location of the coring site away from major riverine inputs. Abrupt climatic cooling at the culmination of both warm phases in the North Basin are associated, on the basis of the palaeomagnetic age-model and correlations to existing sites in Lake Baikal, with the initiation of Heinrich events 5 (c. 50 kyr BP) and 4 (c. 35 kyr BP), respectively, in the North Atlantic. The amount of organic material declines across the MIS 3/MIS 2 transition while constant C/N ratios suggest organic material to be predominantly derived from phytoplankton. An increase in δ¹³C_(organic) at the MIS 3/MIS 2 transition may therefore indicate changes in aquatic productivity, pCO₂ or the inorganic carbon pool.     

Temperature changes on the Tibetan Plateau during the past 600 years inferred from ice cores and tree rings

The climatological signal of δ¹⁸O variations preserved in ice cores recovered from Puruogangri ice field in the central Tibetan Plateau (TP) was calibrated with regional meteorological data for the past 50 years. For the period AD 1860–2000, 5-yearly averaged ice core δ¹⁸O and a summer temperature reconstruction derived from pollen data from the same ice core were compared. The statistical results provide compelling evidence that Puruogangri ice core δ¹⁸O variations represent summer temperature changes for the central TP, and hence regional temperature history during the past 600 years was revealed. A comparison of Puruogangri ice core δ¹⁸О with several other temperature reconstructions shows that broad-scale climate anomalies since the Little Ice Age occurred synchronously across the eastern and southern TP, and the Himalayas. Common cold periods were identified in the 15th century, 1625–1645 AD, 1660–1700 AD, 1725–1775 AD, 1795–1830 AD, 1850–1870 AD, 1890–1920 AD, 1940–1950 AD, and 1975–1985 AD. The period 1725–1775 AD was one of the most prolonged cool periods during the past 400 years and corresponded to maximum Little Ice Age glacier advance of monsoonal temperate glaciers of the TP.     

Estimation of net accumulation rate at a Patagonian glacier by ice core analyses using snow algae

Snow algae in a 45.97-m-long ice core from the Tyndall Glacier (50°59′05″S, 73°31′12″W, 1756 m a.s.l.) in the Southern Patagonian Icefield were examined for potential use in ice core dating and estimation of the net accumulation rate. The core was subjected to visual stratigraphic observation and bulk density measurements in the field, and later to analyses of snow algal biomass, water isotopes (¹⁸O, D), and major dissolved ions. The ice core contained many algal cells that belonged to two species of snow algae growing in the snow near the surface: Chloromonas sp. and an unknown green algal species. Algal biomass and major dissolved ions (Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻) exhibited rapid decreases in the upper 3 m, probably owing to melt water elution and/or decomposition of algal cells. However, seasonal cycles were still found for the snow algal biomass, ¹⁸O, D-excess, and major ions, although the amplitudes of the cycles decreased with depth. Supposing that the layers with almost no snow algae were the winter layers without the melt water essential to algal growth, we estimated that the net accumulation rate at this location was 12.9 m a^− 1 from winter 1998 to winter 1999, and 5.1 m from the beginning of winter to December 1999. These estimates are similar to the values estimated from the peaks of ¹⁸O (17.8 m a^− 1 from summer 1998 to summer 1999 and 11.0 m from summer to December 1999) and those of D-excess (14.7 m a^− 1 from fall 1998 to fall 1999 and 8.6 m a^− 1 from fall to December 1999). These values are much higher than those obtained by past ice core studies in Patagonia, but are of the same order of magnitude as those predicted from various observations at ablation areas of Patagonian glaciers.     

Rapid responses of the prairie-forest ecotone to early Holocene aridity in mid-continental North America

The prairie-forest transition in midcontinental North America is a major physiognomic boundary, and its shifts during the Holocene are a classic example of climate-driven ecotonal dynamics. Recent work suggests asymmetrical Holocene behavior, with a relatively rapid early Holocene deforestation and more gradual reforestation later in the Holocene. This paper presents a new synthesis of the Holocene history of the Great Plains prairie-forest ecotone in the north-central US and central Canada that updates prior mapping efforts and systematically assesses rates of change. Changes in percent woody cover (%WC) are inferred from fossil pollen records, using the modern analog technique and surface-sediment pollen samples cross-referenced against remotely sensed observations. For contemporary pollen samples from the Great Plains, %WC linearly correlates to percent arboreal pollen (%AP), but regression parameters vary interregionally. At present, %AP is consistently higher than %WC, because of high background levels of arboreal pollen. Holocene maps of the eastern prairie-forest ecotone agree with prior maps, showing a rapid decrease in %WC and eastward prairie advance between 10,000 and 8000 ka (1 ka = 1000 calibrated years before present), a maximum eastward position of the ecotone from 7 to 6 ka, and increased %WC and westward prairie retreat after 6 ka. Ecotone position is ambiguous in Iowa and southeastern Minnesota, due to a scarcity of modern analogs for early-Holocene samples with high Ulmus abundances and for samples from alluvial sediments. The northern prairie-forest ecotone was positioned in central Saskatchewan between 12 and 10 ka, stabilized from 10 to 6 ka despite decreases in %WC at some sites, then moved south after 6 ka. In both east and north, ecotonal movements are consistent with a dry early Holocene and increasing moisture availability after 6 ka. Sites near the ecotone consistently show an asymmetric pattern of abrupt early Holocene deforestation (< 300 years) and gradual reforestation after 6 ka. Early Holocene decreases in %WC are faster than the corresponding drops in %AP, because the analog-based %WC reconstructions correct for the high background levels of arboreal pollen types that blur temporal variations in %AP. For example, at Elk Lake, the %AP decline lasts 1000 years, whereas the %WC decline occurs between adjacent pollen samples, approximately 300 years apart. Thus, early Holocene deforestation may have been even more abrupt than previously recognized. Rapid deforestation likely was promoted both by rapid climate changes around 8.2 ka and positive fire-vegetation feedbacks. Non-linear vegetational responses to hydrological variability are consistent with 1) other paleorecords showing rapid die-offs of some eastern tree species in response to aridity and 2) observations of threshold-type ecological responses to recent climate events. The 21st-century trajectory for the Great Plains prairie-forest ecotone is uncertain, because climate models differ over the direction of regional precipitation trends, but future drying would be more likely to trigger threshold-type shifts in ecotone position.     

The thermodynamics of dust formation: Evidence from meteorites

A substantial fraction of interstellar dust probably formed in the nebulae around protostars, a setting similar to that envisioned for meteoritic material. From studies of the mineralogy and composition of meteorites it is possible to obtain quantitative information on the conditions that prevailed in the nebula. For example, pressures in the range 10^–3 to 10^–6 atm are indicated. At these pressures the kinetics of nucleation and grain growth are favorable.The fact that the gas associated with interstellar dust has solar H/S ratios indicates that FeS, which forms at 680 K, independent of pressure, is not present in the dust. Since iron only becomes oxidized at even lower temperatures, also via pressure-independent reactions, oxidized iron is not expected in the dust. If most interstellar dust forms in nebulae and is ejected back into space, a relatively high temperature is implied, 700K. Dust formation around stars with high C/O ratios is expected to produce minerals found in the highly reduced enstatite chondrites.High-temperature fractionation processes ( 1000 K) played an important role in the nebula. Much of the Al, Ca, Ti, etc., evidently condensed and accreted into cm-sized objects, some of which are found in carbonaceous chondrites. These objects are explicable in terms of formation from a cooling neutral gas with cosmic composition. Their most important distinguishing characteristics are low volatile and low Si contents, coupled with high refractory element contents constrains formation via isothermal compression to grain temperature 1000 K.Invited contribution to the proceedings of a workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

A peat core based estimate of Late-glacial and Holocene methane emissions from northern peatlands

We estimate the intensity of Late-glacial and Holocene methane emissions from peatlands based on their paleo net primary production (PNPP). The PNPP is derived from the carbon accumulation rates of the studied bog profile (Etang de la Gruère, Switzerland), which are corrected for the degree of peat degradation. The obtained PNPP curve is taken as a proxy for methane emissions. It shows relatively high values (90 g C m^− 2 yr^− 1) early in the Bolling/Allerod and drops to low values (40 g C m^− 2 yr^− 1) during the Younger Dryas cold period. With the onset of the Holocene the PNPP increases strongly up to 150 g C m^− 2 yr^− 1 around ca. 10,000 Cal. yr bp. This is followed by a decline to minimum values (30 to 40 g C m^− 2 yr^− 1) between 6500 and 4000 Cal. yr bp. Thereafter, the PNPP starts to increase again to reach its highest value (175 g C m^− 2 yr^− 1) around 1000 Cal. yr bp.The PNPP curve correlates well with the evolution of the atmospheric methane concentrations as derived from Greenland ice-cores. For example, minima in atmospheric methane reported during the Younger Dryas and around 5200 Cal. yr bp are coinciding with the lowest values of PNPP and the negative atmospheric methane peak at 8200 Cal. yr bp corresponds to a marked decrease in PNPP.Our PNPP curve suggests that the methane emissions from northern peatlands evolved similar to those of low latitude wetlands and together they largely determined the evolution of atmospheric methane throughout the Late-glacial and the Holocene. The abruptness of the rise of atmospheric methane at the end of the Younger Dryas probably points to an additional source (e.g. marine gas hydrates), but very early in the Holocene the peatlands have likely become the dominant source of atmospheric methane.     

Climate changes and recent glacier behaviour in the Chilean Lake District

Atmospheric temperatures measured at the Chilean Lake District (38°–42°S) showed contrasting trends during the second half of the 20th century. The surface cooling detected at several meteorological stations ranged from − 0.014 to − 0.021 °C a^− 1, whilst upper troposphere (850–300 gpm) records at radiosonde of Puerto Montt (41°26′S/73°07′W) revealed warming between 0.019 and 0.031 °C a^− 1. Regional rainfall data collected from 1961 to 2000 showed the overall decrease with a maximum rate of − 15 mm a^− 2 at Valdivia st. (39°38′S/73°05′W). These ongoing climatic changes, especially the precipitation reduction, seem to be related to El Niño–Southern Oscillation (ENSO) phenomena which has been more frequent after 1976. Glaciers within the Chilean Lake District have significantly retreated during recent decades, in an apparent out-of-phase response to the regional surface cooling. Moreover, very little is known about upper troposphere changes and how they can enhance the glacier responses. In order to analyse their behaviour in the context of the observed climate changes, Casa Pangue glacier (41°08′S/71°52′W) has been selected and studied by comparing Digital Elevation Models (DEMs) computed at three different dates throughout the last four decades. This approach allowed the determination of ice elevation changes between 1961 and 1998, yielding a mean thinning rate of − 2.3 ± 0.6 m a^− 1. Strikingly, when ice thinning is computed for the period between 1981 and 1998, the resulting rate is 50% higher (− 3.6 ± 0.6 m a^− 1). This enhanced trend and the related area loss and frontal retreat suggests that Casa Pangue might currently be suffering negative mass balances in response to the upper troposphere warming and decreased precipitation of the last 25–30 yr, as well as debris cover would not prevent the glacier from a fast reaction to climate forcing. Most of recent glaciological studies regarding Andean glaciers have concentrated on low altitude changes, namely frontal variations, however, in order to better understand the regional glacier changes, new data are necessary, especially from the accumulation areas.     

Biomization and quantitative climate reconstruction techniques in northwestern Mexico—With an application to four Holocene pollen sequences

New paleovegetation and paleoclimatic reconstructions from the Sierra Madre Occidental (SMO) in northwestern Mexico are presented. This work involves climate and biome reconstruction using Plant Functional Types (PFT) assigned to pollen taxa. We used fossil pollen data from four Holocene peat bogs located at different altitudes (1500‑2000 m) at the border region of Sonora and Chihuahua at around 28° N latitude (Ortega-Rosas, C.I. 2003. Palinología de la Ciénega de Camilo: datos para la historia de la vegetación y el clima del Holoceno medio y superior en el NW de la Sierra Madre Occidental, Sonora, Mexico. Master Thesis, Universidad Nacional Autónoma de México, México D.F.; Ortega-Rosas, C.I., Peñalba, M.C., Guiot, J. Holocene altitudinal shifts in vegetation belts and environmental changes in the Sierra Madre Occidental, Northwestern Mexico. Submitted for publication of Palaeobotany and Palynology). The closest modern pollen data come from pollen analysis across an altitudinal transect from the Sonoran Desert towards the highlands of the temperate SMO at the same latitude (Ortega-Rosas, C.I. 2003. Palinología de la Ciénega de Camilo: datos para la historia de la vegetación y el clima del Holoceno medio y superior en el NW de la Sierra Madre Occidental, Sonora, Mexico. Master Thesis, Universidad Nacional Autónoma de México, México D.F.). An additional modern pollen dataset of 400 sites across NW Mexico and the SW United States was compiled from different sources (Davis, O.K., 1995. Climate and vegetation pattern in surface samples from arid western U.S.A.: application to Holocene climatic reconstruction. Palynology 19, 95–119, North American Pollen Database, Latin-American Pollen Database, personal data, and different scientific papers). For the biomization method (Prentice, I.C., Guiot, J., Huntley, B., Jolly, D., Cheddadi, R., 1996. Reconstructing biomes from paleoecological data: a general method and its application to European pollen data at 0 and 6 ka. Climate Dynamics 12, 185–194), we modified the pollen-PFT and PFT-biomes assignation of Thompson and Anderson (Thompson, R.S., Anderson, K.H., 2000. Biomes of western North America at 18,000; 6000 and 0 14C yr BP reconstructed from pollen and packrat midden data. Journal of Biogeography 27, 555–584) for a better representation of the modern vegetation of NW Mexico. The biome reconstruction method was validated with the modern pollen sites and applied to the fossil sites. Our results show that, during the early Holocene, a cool conifer forest extended at least down to 1700 m, while today this biome is present above 2000 m in the Chihuahua state. The Younger Dryas event was recorded in one site with cold and dry conditions. The reconstructed annual temperature for this period was 3°–6 °C colder than today, and annual precipitation was 250 mm lower than at present (900 mm/yr). The middle Holocene after 9200 cal yr BP was marked by a warming trend, reaching temperatures 2 °C warmer than today at 7000 cal yr BP, and by the installation of a warm mixed forest, the present day biome, at 1700 m elevation, while at higher elevations (1900 m) the cool conifer forest was still present. Summer precipitation was 200 mm/yr above the early Holocene values, suggesting that monsoon-like conditions strengthened since 9200 cal yr BP at this region. During the last 4000 yr, the same warm mixed forest was reconstructed below 1700 m and a conifer forest above 1700 m. A great variability of vegetation and climate patterns was recorded for the last 3000 yr particularly at high elevation sites, where warming and cooling trends would be coeval of the Medieval warm period and Little Ice Age, likely related to ENSO variability.     

Reconstruction of paleotemperatures in the Northwest Pacific over the past 3000 years from δO values of the micro-bivalvia Carditella iejimensis found in a submarine cave

We measured the δ¹⁸O values of the whole shells of the cavernicolous micro-bivalvia Carditella iejimensis obtained from sediments within a submarine cave (31 m water depth) at Ie Island (Okinawa Island, Japan) in the subtropical Northwest Pacific. Our results show no significant millennial-scale trend in the δ¹⁸O record, implying that both springtime temperature and the δ¹⁸O of sea water at 30 m depth around the Okinawa Islands have been stable for the past 3000 years at values similar to those of today. Moreover, we found one exceptionally light δ¹⁸O value from specimens spanning the past 250 years. The δ¹⁸O-derived temperature represents a departure of 2.1 °C from the average value for the past 250 years, being equal to the departure recorded during unusually high temperatures in the spring of 1998. This finding may imply that such high springtime sea surface temperature has been a rare event over the past 3000 years.     

Quaternary uplift of northern England

Upland flats, attributable to erosion, have long been recognised in the landscape of the Lake District region of NW England, at altitudes of up to ~ 800 m O.D. Extrapolation using uplift rates derived from dated Pleistocene sites (karstic caves and other features) in the adjacent Pennine uplands suggests that if this succession of flats formed close to sea-level they date from the Middle Pliocene onwards, indicating a subsequent time-averaged uplift rate of almost 0.3 mm a^− 1. Numerical modelling indicates that erosion of surrounding areas at a typical rate of 0.2 mm a^− 1 since 3.1 Ma could have caused this uplift, as well as constraining the local effective viscosity of the lower crust as ~ 4 × 10¹⁸ Pa s and the typical local Moho temperature as ~ 650 °C. It is thus feasible that most of the topography of northern England has developed since the Middle Pliocene, as a consequence of coupling between erosion and the resulting induced flow in the lower continental crust. The much faster vertical crustal motions indicated in this part of northern England, compared with SE England, are thus mainly a consequence of much greater mobility of the lower crust in the north, due to its younger thermal age and the heating effect of radioactive Palaeozoic granites. Uplift of this magnitude, which has previously gone unrecognised, may have affected post-Pliocene global climate.     

Airborne laser altimetry survey of Glaciar Tyndall, Patagonia

The first airborne laser altimetry measurements of a glacier in South America are presented. Data were collected in November of 2001 over Glaciar Tyndall, Torres del Paine National Park, Chilean Patagonia, onboard a Twin Otter airplane of the Chilean Air Force. A laser scanner with a rotating polygon-mirror system together with an Inertial Navigation System (INS) were fixed to the floor of the aircraft, and used in combination with two dual-frequency GPS receivers. Together, the laser–INS–GPS system had a nominal accuracy of 30 cm after data processing. On November 23rd, a total of 235 km were flown over the ablation area of Glaciar Tyndall, with 5 longitudinal tracks with a mean swath width of 300 m, which results in a point spacing of approximately 2 m both along and across track. A digital elevation model (DEM) generated using the laser altimetry data was compared with a DEM produced from a 1975 map (1:50,000 scale — Instituto Geográfico Militar (IGM), Chile). A mean thinning of − 3.1 ± 1.0 m a^− 1 was calculated for the ablation area of Glaciar Tyndall, with a maximum value of − 7.7 ± 1.0 m a^− 1 at the calving front at 50 m a.s.l. and minimum values of between − 1.0 and − 2.0 ± 1.0 m a^− 1 at altitudes close to the equilibrium line altitude (900 m a.s.l.). The thinning rates derived from the airborne survey were similar to the results obtained by means of ground survey carried out at  600 m of altitude on Glaciar Tyndall between 1975 and 2002, yielding a mean thinning of − 3.2 m a^− 1 [Raymond, C., Neumann, T.A., Rignot, E., Echelmeyer, K.A., Rivera, A., Casassa, G., 2005. Retreat of Tyndall Glacier, Patagonia, over the last half century. Journal of Glaciology 173 (51), 239–247.]. A good agreement was also found between ice elevation changes measured with laser data and previous results obtained with Shuttle Radar Topography Mission (SRTM) data. We conclude that airborne laser altimetry is an effective means for accurately detecting glacier elevation changes in Patagonia, where an ice thinning acceleration trend has been observed during recent years, presumably in response to warming and possibly also drier conditions.     

Vegetation and climate variability during the Last Interglacial evidenced in the pollen record from Lake Baikal

A pollen record from the core sediments collected in the northern part of Lake Baikal represents the latest stage of the Taz (Saale) Glaciation, Kazantsevo (Eemian) Interglacial (namely the Last Interglacial), and the earliest stage of the Zyryanka (Weichselian) Glaciation. According to the palaeomagnetic-based age model applied to the core, the Last Interglacial in the Lake Baikal record lasted about 10.6 ky from 128 to 117.4 ky BP, being more or less synchronous with the Marine Isotope Stage 5e. The reconstructed changes in the south Siberian vegetation and climate are summarised as follows: a major spread of shrub alder (Alnus fruticosa) and shrub birches (Betula sect. Nanae/Fruticosae) in the study area was a characteristic feature during the late glacial phase of the Taz Glaciation. Boreal trees e.g. spruce (Picea obovata) and birch (Betula sect. Albae) started to play an important role in the regional vegetation with the onset of the interglacial conditions. Optimal conditions for Abies sibirica–P. obovata taiga development occurred ca. 126.3 ky BP. The maximum spread of birch forest-steppe communities took place at the low altitudes ca. 126.5–125.5 ky BP and Pinus sylvestris started to form forests in the northern Baikal area after ca. 124.4 ky BP. Re-expansion of the steppe communities, as well as shrubby alder and willow communities and the disappearance of forest vegetation occurred at about 117.4 ky BP, suggesting the end of the interglacial succession. The changes in the pollen assemblages recorded in the sediments from northern Baikal point to a certain instability of the interglacial climate. Three phases of climate deterioration have been distinguished: 126–125.5, 121.5–120, and 119.5–119 ky BP. The penultimate cooling signal may be correlated with the cool oscillation recorded in European pollen records. However, such far distant correlation requires more careful investigation.     

Ice elevation and areal changes of glaciers from the Northern Patagonia Icefield, Chile

High thinning rates (up to − 4.0 ± 0.97 m a^− 1) have been measured at Campo de Hielo Patagónico Norte (CHN) or Northern Patagonia Icefield, Chile between 1975 and 2001. Results have been obtained by comparing a Digital Elevation Model (DEM) derived from regular cartography compiled by Instituto Geográfico Militar of Chile (IGM) based upon 1974/1975 aerial photographs and a DEM generated from Advanced Space-borne Thermal Emission and Reflection Radiometer (ASTER) satellite images acquired in September 2001. A complete cloud-free Landsat ETM+ satellite image mosaic acquired in March 2001 was used to update the available glacier inventory of the CHN, including all glaciers larger than 0.5 km² (48 new glaciers). A new delineation of ice divides was also performed over the accumulation areas of glaciers sharing the high plateau where the existing regular cartography exhibits poor coverage of topographic information. This updated glacier inventory produced a total ice area for 2001 of 3953 km², which represents a decrease of 3.4 ± 1.5% (140 ± 61 km² of ice) with respect to the total ice area of the CHN in 1979 calculated from a Landsat MSS satellite image. Almost 62% of the total area change between 1979 and 2001 took place in glaciers located at the western margin of the CHN, where the maximum area loss was experienced by Glaciar San Quintín with 33 km². At the southern margin, Glaciar Steffen underwent the largest ice-area loss (12 km² or 2.6% of the 1979 area), whilst at the eastern margin the greatest area loss took place in Glaciares Nef (7.9 km², 5.7% of the 1979 area) and Colonia (9.1 km², 2.7% of the 1979 area). At the northern margin of the CHN the lower debris-covered ablation area of Glaciar Grosse collapsed into a new freshwater lake formed during the late 1990s. The areal changes measured at the CHN are much larger than previously estimated due to the inclusion of changes experienced in the accumulation areas. The CHN as a whole is contributing melt water to global sea level rise at rates  25% higher than previous estimates.     

Revisiting 26Al‐26Mg systematics of plagioclase in H4 chondrites

Zinner and Göpel ( 1992 , 2002 ) found clear evidence for the former presence of ²⁶Al in the H4 chondrites Ste. Marguerite and Forest Vale. They assumed that the ²⁶Al‐²⁶Mg systematics of these chondrites date “metamorphic cooling of the H4 parent body.” Plagioclase in these chondrites can have very high Al/Mg ratios and low Mg concentrations, making these ion probe analyses susceptible to ratio bias, which is inversely proportional to the number of counts of the denominator isotope (Ogliore et al. 2011 ). Zinner and Göpel ( 2002 ) used the mean of the ratios to calculate the isotope ratios, which exacerbates this problem. We analyzed the Al/Mg ratios and Mg isotopic compositions of plagioclase grains in thin sections of Ste. Marguerite, Forest Vale, Beaver Creek, and Sena to evaluate the possible influence of ratio bias on the published initial ²⁶Al/²⁷Al ratios for these meteorites. We calculated the isotope ratios using total counts, a less biased method of calculating isotope ratios. The results from our analyses are consistent with those from Zinner and Göpel ( 2002 ), indicating that ratio bias does not significantly affect ²⁶Al‐²⁶Mg results for plagioclase in these chondrites. Ste. Marguerite has a clear isochron with an initial ²⁶Al/²⁷Al ratio indicating that it cooled to below 450 °C 5.2 ± 0.2 Myr after CAIs. The isochrons for Forest Vale and Beaver Creek also show clear evidence that ²⁶Al was alive when they cooled, but the initial ²⁶Al/²⁷Al ratios are not well constrained. Sena does not show evidence that ²⁶Al was alive when it cooled to below the Al‐Mg closure temperature. Given that metallographic cooling rates for Ste. Marguerite, Forest Vale, and Beaver Creek are atypical (>5000 °C/Myr at 500 °C) compared with most H4s, including Sena, which have cooling rates of 10–50 °C/Myr at 500 °C (Scott et al. 2014 ), we conclude that the Al‐Mg systematics for Ste. Marguerite, Forest Vale, and Beaver Creek are the result of impact excavation of these chondrites and cooling at the surface of the parent body, instead of undisturbed cooling at depth in the H chondrite parent body, like many have assumed.     

An abiotic origin for hydrocarbons in the Allan Hills 84001 martian meteorite through cooling of magmatic and impact‐generated gases

Abstract— Thermodynamic calculations of metastable equilibria were used to evaluate the potential for abiotic synthesis of aliphatic and polycyclic aromatic hydrocarbons (PAHs) in the martian meteorite Allan Hills (ALH) 84001. The calculations show that PAHs and normal alkanes could form metastably from CO, CO², and H² below approximately 250–300°C during rapid cooling of trapped magmatic or impact‐generated gases. Depending on temperature, bulk composition, and oxidation‐reduction conditions, PAHs and normal alkanes can form simultaneously or separately. Moreover, PAHs can form at lower H/C ratios, higher CO/CO² ratios, and higher temperatures than normal alkanes. Dry conditions with H/C ratios less than approximately 0.01–0.001 together with high CO/CO² ratios also favor the formation of unalkylated PAHs. The observed abundance of PAHs, their low alkylation, and a variable but high aromatic to aliphatic ratio in ALH 84001 all correspond to low H/C and high CO/CO² ratios in magmatic and impact gases and can be used to deduce spatial variations of these ratios. Some hydrocarbons could have been formed from trapped magmatic gases, especially if the cooling was fast enough to prevent reequilibration. We propose that subsequent impact heating(s) in ALH 84001 could have led to dissociation of ferrous carbonates to yield fine‐grain magnetite, formation of a CO‐rich local gas phase, reduction of water vapor to H², reequilibration of the trapped magmatic gases, aromatization of hydrocarbons formed previously, and overprinting of the synthesis from magmatic gases, if any. Rapid cooling and high‐temperature quenching of CO‐, H²‐rich impact gases could have led to magnetite‐catalyzed hydrocarbon synthesis     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Late glacial and Holocene environmental change in the Lake Baikal region documented by oxygen isotopes from diatom silica

We investigate late glacial and Holocene climate change recorded in Lake Baikal using the oxygen isotope composition of diatom silica (δ¹⁸O_DIAT). Evaporation from the lake is minor, and the temperature fractionations of δ¹⁸O are unable to explain variations in the δ¹⁸O_DIAT record alone. Isotopically, low meltwater input from glaciers may have some influence on δ¹⁸O_DIAT, but the assumed periods of climatic warming and wastage do not coincide with large shifts in δ¹⁸O_DIAT. There is a gradual oxygen isotope lowering from 27.0‰ to 20.6‰ over the late glacial, while, during the Holocene, δ¹⁸O_DIAT values return to relatively high values. Previous studies of the modern oxygen and hydrogen isotope composition of Lake Baikal's inputs reveal that fluvial input to the lake's North Basin are isotopically lower than fluvial input from South Basin rivers. This north–south gradient of river δ¹⁸O and δD is mainly due to the greater input from isotopically low winter precipitation in the north and isotopically higher summer precipitation in the south. As a result, the δ¹⁸O_DIAT record from Lake Baikal can at least in part be explained by varying input from these sources related to seasonal changes in precipitation. Changes in atmospheric conditions may have a role in altering seasonality and the distribution of precipitation over Lake Baikal's catchment. A feedback mechanism is well known linking higher Eurasian spring snow cover extent (ESSC) to the development of anticyclonic conditions and low precipitation the following summer in the areas south of Lake Baikal. A simultaneous increase in the importance of depleted water (snowmelt) input from the north and decreased enriched summer precipitation in the south is needed to explain depletions in δ¹⁸O of lake water and subsequently δ¹⁸O_DIAT during colder periods. The opposite of this situation is required to enrich lake water during warmer periods. The analysis of δ¹⁸O from diatom silica is a useful proxy for environmental change, especially in lakes, like Lake Baikal, where carbonates are absent or diluted. However, analysis must be based on near pure diatom samples as even trace amounts of silt can have a dominating effect on δ¹⁸O_DIAT values.     

Presolar silicon carbide grains and their parent stars

Abstract— Carbon stars are an important source of presolar TiC, SiC, and graphite grains found in meteorites. The elemental abundances in the stellar sources of the SiC grains are inferred by using condensation calculations. These elemental abundances, together with C isotopic compositions, are used to identify possible groups of carbon stars that may have contributed SiC grains to the presolar dust cloud. The most likely parent stars of meteoritic SiC mainstream grains are N-type carbon stars and evolved subgiant CH stars. Both have s-process element abundances higher than solar and 10 < ¹²C/¹³C < 100 ratios. The J stars and giant CH stars, with solar and greater than solar abundances of s-process elements, respectively, are good candidate parents for the ‘A’ and ‘B’ SiC grains with low ¹²C/¹³C ratios. A special subgroup of CH giant stars with very large ¹²C/¹³C ratios could have parented the ‘Y’ SiC grains with ¹²C/¹³C ratios > 100. The carbon star population (e.g., N, R, J, CH groups) needed to provide the observed SiC grains is compared to the current population of carbon stars. This comparison suggests that low-metallicity CH stars may have been more abundant in the past (>4.5 Ga ago) than at present. This suggestion is also supported by condensation-chemistry modeling of the trace element patterns in the SiC grains that shows that subsolar Fe abundances may be required in the stellar sources for many SiC grains. The results of this study suggest that presolar SiC grains in meteorites can provide information about carbon stars during galactic evolution.     

Isotopic abundance in the CN coma of comets: Ten years of measurements

Over the past 10 years the isotopic ratios of carbon (¹²C/¹³C) and nitrogen (¹⁴N/¹⁵N) have been determined for a dozen comets, bright enough to allow obtaining the required measurements from the ground. The ratios were derived from high-resolution spectra of the CN coma measured in the B²∑⁺−X²∑⁺ (0, 0) emission band around 387 nm. The observed comets belong to different dynamical classes, including dynamically new as well as long- and short-period comets from the Halley- and Jupiter-family. In some cases the comets could be observed at various heliocentric distances. All values determined for the carbon and nitrogen isotopic ratios were consistent within the error margin irrespective of the type of comet or the heliocentric distance at which it was observed. Our investigations resulted in average ratios of ¹²C/¹³C=91±21 and nitrogen ¹⁴N/¹⁵N=141±29. Whilst the value for the carbon isotopic ratio is in good agreement with the solar and terrestrial value of 89, the nitrogen isotopic ratio is very different from the telluric value of 272.     

Provincialism in trends and high frequency changes in the northwest North Atlantic during the Holocene

In the present paper, we report on micropaleontological (dinocysts) and isotopic (¹⁸O and ¹³C in foraminifers) analyses performed in Holocene sediments from fifteen cores raised from the central and northwest North Atlantic. Sea-surface temperature (SST), sea-surface salinity (SSS), thus potential density, and sea-ice cover are reconstructed based on dinocyst assemblages. After proper calibration, oxygen isotope data on the mesopelagic foraminifer Neogloboquadrina pachyderma left coiled (Npl) are converted into potential density values deeper in the water column, thus allowing documentation of vertical density gradients and identification of intervals favourable for winter convection to occur with formation of intermediate Labrador Sea Water (LSW). The most important findings from this study include: (1) the existence of an early-mid Holocene thermal optimum with positive anomalies up to 6 °C above present along the main SW–NE axis of the North Atlantic Current, but no significant SST maximum at most sites along eastern Canadian margins; (2) the evidence for larger than present amplitude of annual SSTs during the early Holocene, thus for a stronger seasonality; (3) minimum sea-ice cover from 11 500 to 6000 cal years BP, and a slight increase of sea-ice variability, and average seasonal duration of 0.5 to 1 month per year afterwards; (4) variable SSS during the entire Holocene, suggesting changes in the routing and rates of freshwater–meltwater discharges from the Arctic and eastern Canada; (5) the setting of conditions compatible with LSW production after 8 ka only, and likely a more steady production during the late Holocene; (6) an overall trend for a potential density increase of the Labrador Sea, throughout the Holocene, matching a decreasing trend eastward, thus suggesting a progressive enhancement of the western branch of the Atlantic Meridional Overturning with respect to its northeastern route; and (7) indication of maximum production and fast dispersal of LSW in the entire North Atlantic during recent times only, as suggested by linearly-converging δ¹⁸O-values of Npl from all sites, towards its modern relatively homogeneous composition ( 2.5/2.6‰). The overall picture of the Holocene North Atlantic arising from this study is that of a basin marked by a strong regionalism with large discrepancies in hydrographical trends and high frequency oscillations, at least partly controlled by freshwater–meltwater routes and rates of export from the Arctic.