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我国北方两种高岭石的电子顺磁共振研究 总被引:4,自引:2,他引:4
笔者对我国北方两种不同类型的高岭石进行了化学分析、差热和热重分析、X射线衍射、红外吸收光谱及电子顺磁共振等研究。结果表明,在酸性还原条件下形成的高岭石中,铁主要以Fe2+的形式置换结构中的Al3+,同时也有部分铁以亚铁化合物形式存在;在氧化条件下形成的高岭石中,铁主要以Fe3+形式存在于晶体结构和杂质铁氧化合物中,也有部分以Fe2+置换Al3+形式存在。 相似文献
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以电子探针(EPMA)为主要研究手段,结合常规化学分析、化学物相分析、透反射显微镜研究,对黔西北某地低品位铁矿中铁—钛的赋存状态进行了详细研究。研究结果表明,矿石中铁主要以褐铁矿形式存在,少量以赤铁矿产出。载铁矿物与粘土矿物常常混杂出现,分布不均,团块大小差异也大,矿物间的嵌布关系复杂;钛在矿石中一是以微细粒的独立矿物金红石、锐钛矿、钛铁矿与脉石矿物相互混杂分布,另一种则是蚀变残留于褐铁矿中类质同象的钛。根据铁、钛赋存特征研究结果,对该矿石提出了"分散—絮凝—磁选"分离预富集铁—钛矿物、"直接还原法"实现铁钛分离的工艺建议。 相似文献
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金红石中铁的存在形式的研究 总被引:4,自引:2,他引:4
本文对我国不同地区和不同成因类型矿床及人工合成的金红石的20个样品进行了矿物学研究。结果表明,大多数金红石样品中都含有钛铁矿的嵌晶,金红石和嵌晶钛铁矿晶粒中多含有含钛赤铁矿(Titano-hematite)的出溶相。金红石晶粒中的含钛赤铁矿于600℃消失;而钛铁矿中的含钛赤铁矿于800℃消失,且整个晶粉转变成亚铁假板钛矿(Ferro-pseudobrookite)。总结出金红石中铁的三种存在形式:类质同象置换钛的Fe~(3+)、固溶体出溶相含钛赤钛铁矿中的Fe~(3+)及钛铁矿中所含的Fe~(2+)。 相似文献
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主要研究了磷酸铝(Al PO4)的加入量对氧化亚铁硫杆菌HX3培养液中铁矿物形成的影响,并对相应沉淀产物进行了结构表征分析。结果表明,Al PO4的加入对细菌培养过程中Fe2+的氧化无明显影响,但可促进Fe3+的水解和初始铁矿物相的形成,也可加速黄钾铁矾的转化形成。Al/Fe(摩尔比)为0. 04~1的培养液中主要形成产物为施威特曼石和黄钾铁矾; Al/Fe为0. 4和1时另有磷酸铁矿形成。较高的Al/Fe比值和磷酸根含量有利于磷酸铁矿的形成。 相似文献
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十红滩铀矿床形成于新疆吐哈盆地西南缘艾丁湖斜坡带的中侏罗统西山窑组河流相砂岩中,属典型的层间氧化带砂岩型铀矿床.物相分析表明,容矿层中铁的存在形式分别为FeCO3、Fe2 O3、硅酸盐铁和FeS2,其含量在各地球化学亚带间发生有规律的变化.黄铁矿是容矿层二价铁的主要形式,具有两期成因特点,属硫酸盐微生物还原作用的产物.分析了铁的地球化学行为在铀成矿过程中的作用,认为在氧化带铁的氧化作用催化了铀的氧化、溶解以及迁移,为铀成矿提供了重要的铀源条件.矿石带中黄铁矿在铀成矿过程中发挥着吸附剂的作用,其与沥青铀矿等具有同成因特点. 相似文献
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十红滩铀矿床形成于新疆吐哈盆地西南缘艾丁湖斜坡带的中侏罗统西山窑组河流相砂岩中,属典型的层间氧化带砂岩型铀矿床。物相分析表明,容矿层中铁的存在形式分别为FeCO3、Fe2O3、硅酸盐铁和FeS2,其含量在各地球化学亚带间发生有规律的变化。黄铁矿是容矿层二价铁的主要形式,具有两期成因特点,属硫酸盐微生物还原作用的产物。分析了铁的地球化学行为在铀成矿过程中的作用,认为在氧化带铁的氧化作用催化了铀的氧化、溶解以及迁移,为铀成矿提供了重要的铀源条件。矿石带中黄铁矿在铀成矿过程中发挥着吸附剂的作用,其与沥青铀矿等具有同成因特点。 相似文献
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《吉林大学学报(地球科学版)》2015,(Z1)
<正>铁钛氧化物在火成岩和变质岩中广泛存在,不仅具有重要的地磁学意义,还可以作为地质"温度计"和"氧逸度计"反映岩体的形成条件。铁钛氧化物在结晶时主要形成3个系列的固溶体,包括:1)立方晶系"尖晶石型"的磁铁矿(Fe2+Fe3+2O4)—钛铁晶石(Fe2+2Ti O4)固溶体;2)三方晶系"刚玉型"的赤铁矿(Fe2O3)—钛铁矿(Fe Ti O3)固溶体;3)正交晶系的"假板钛矿"系列固溶体Fe3+2Ti O5—Fe2+Ti2O5。人工合成实验证明 相似文献
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Keller P. Nicolini Katia C. Lombardi Wido H. Schreiner Irineu Mazzaro Fernando Wypych Antonio S. Mangrich 《Mineralogy and Petrology》2009,97(1-2):139-144
We report on a paramagnetic anisotropy study of three layered phyllosilicates. The mineral samples were characterized through X-ray powder diffraction (XRPD), X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR). Based on EPR measurements of samples oriented parallel or perpendicular to the magnetic field lines, we show how the substitutional iron is transformed from Fe(II) (biotite) into Fe(III) (muscovite and kaolinite) species and from axial Fe(III) coordination sites (muscovite) to rhombic (kaolinite) sites in response to weathering. 相似文献
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粘土矿物高岭石的有序化程度与其成因关系密切,而又受诸因素的作用和影响,通过对我国沉积岩中高岭石的大量研究和资料收集,获得新的发现和认识。无序高岭石一般在常温常压下通过结晶八面体中离子交换而形成,并可在较稳定的地质条件下长期保存,或因相领晶层错动而无序等。但总的说,在地热与高温热水作用或水岩作用中它常由无序向有序化固相发展。过去国内一般认为高度有序化高岭石系受成脉岩或喷出岩热液蚀变而成。这种情况在国内外都是存在的。然而研究后发现大范围更高度有序化高岭石则是煤系紫压(高岭石软质粘土)受后生阶段区域岩浆上升热水进入粒间空隙叠加于地温等作用之上而形成的。 相似文献
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在吉林东部花岗岩区地下水化学成分和化学类型研究的基础上,以Na作为参比元素,确定了花岗岩风化过程中22种主量元素和微量元素的相对活动顺序。花岗岩区地下水的地球化学类型属低矿化度(变化范围为69.51×10-6~386.49×10-6,平均值为199.48×10-6)的HCO3-Ca和HCO3-Na-Ca型。花岗岩风化过程中元素的活动性顺序(RM)从大到小依次为:B、Ca、Mo、Zn、Sr、Na、Mg、Cr、Cu、Ni、K、Co、Li、V、As、Ba、Si、Y、Fe、Ti、Al、Mn。风化产物中的粘土矿物主要为高岭土、蒙脱石,反映出本区花岗岩的风化淋滤程度较弱的特点。 相似文献
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对鄂西仁和坪向斜二叠系梁山组煤系高岭岩成矿地质特征及矿石组分的研究表明,该地区高岭岩矿床属碎屑沉积型,以硬质高岭岩为主,矿层层位稳定,矿石中高岭石多呈隐晶至微晶片状结构,且纯度高(高岭石含量90%~95%),具有低Mn(<30×10-6)高Ti(>0.5%)的特点,矿石中Fe、Mg、Ca、Na、K、Mn、S、As及重金属元素Cu、Pb、Zn、Cd、Tl等有害组分含量普遍较低。综合分析认为本区高岭岩属功能化极强的优质高岭石原料,在橡胶、塑料、涂料、药用包装等领域有广阔的应用前景。 相似文献
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Doris Stüben 《中国地质大学学报(英文版)》2004,15(1):75-83
INTRODUCTIONBeijingfacesseveredustpollutionduetosuchsourcesasdustimportedfromwesterndeserts,industryandpowerplants,domesticcombustionprocessesandtraffic .Inthelastdecades ,theurbanpopulationhasgrowntomorethan10million .TheeconomicgrowthofChinahasalsoleftitsfootprintsinBeijing .Newindustrialzonesanddomesticar easweredeveloped ,inducinganincreasingtrafficcirculation(Shi,2 0 0 1) .Thedroughtclimateinalmostthewholeyear ,thestrongmonsoonsinwinterbringingdustsfromtheGobidesert,theheavytraffic… 相似文献
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本文对罗马尼亚东南部康斯坦萨高岭土矿床进行矿物学研究,该矿床在白垩系古海纳组地层中.经化学分析、X射线衍射分析、红外光谱分析、差热和电子显微镜扫描等研究,其矿物组成主要为结晶度差的高岭石、少量蒙脱石、伊利石及其混层矿物。铁和钛的有害组份较高。它的成因是由中酸性火成岩受风化作用,经剥蚀、搬运、在较稳定的沉积环境中.经过几次海浸沉积形成的。在沉积后,粘土矿物随着埋藏深度的加大,致使粘土矿物发生转化。 相似文献
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Lunar mare basalts are a product of partial melting of the lunar mantle under more reducing conditions when compared to those expected for the Earth’s upper mantle. Alongside Fe, Ti can be a major redox sensitive element in lunar magmas, and it can be enriched by up to a factor of ten in lunar basaltic glasses when compared to their terrestrial counterparts. Therefore, to better constrain the oxidation state of Ti and its coordination chemistry during lunar magmatic processes, we report new X-ray absorption near edge structure (XANES) spectroscopy measurements for a wide range of minerals (pyroxene, olivine, Fe–Ti oxides) and basaltic melt compositions involved in partial melting of the lunar mantle. Experiments were conducted in 1 bar gas-mixing furnaces at temperatures between 1100 and 1300 °C and oxygen fugacities (fO2) that ranged from air to two orders of magnitude below the Fe–FeO redox equilibrium. Run products were analysed via electron microprobe and XANES Ti K-edge. Typical run products had large (>?100 µm) crystals in equilibrium with quenched silicate glass. Ti K-edge XANES spectra show a clear shift in energy of the absorption edge features from oxidizing to reducing conditions and yield an average valence for Fe–Ti oxides (armalcolite and ilmenite) of 3.6, i.e., a 40% of the overall Ti is Ti3+ under fO2 conditions relevant to lunar magmatism (IW ??1.5 to ??1.8). Pyroxenes and olivine have average Ti valence of 3.75 (i.e., 25% of the overall Ti is trivalent), while in silicate glasses Ti is exclusively tetravalent. Pre-edge peak intensities also indicate that the coordination number of Ti varies from an average V-fold in silicate glass to VI-fold in the Fe–Ti oxides and a mixture between IV and VI-fold coordination in the pyroxenes and olivine, with up to 82% [IV]Ti4+ in the pyroxene. In addition, our results can help to better constrain the Ti3+/∑Ti of the lunar mantle phases during magmatic processes and are applied to provide first insights into the mechanisms that may control Ti mass-dependent equilibrium isotope fractionation in lunar mare basalts. 相似文献
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金洋、蒙西和雪纳高岭土化学成分以SiO2和Al2O3为主,K、Na、Ca、Mg含量低,而Fe、Ti含量较高;矿物成分以高岭石为主,还含有少量一水软铝石、石英、蒙脱石等。XRD和IR分析结果表明,金洋和蒙西高岭石的有序度较高,HI结晶指数分别为1.19和1.23,而雪纳高岭石的衍射峰峰形弥散,对称程度差,HI结晶指数仅有0.56。二甲基亚砜和甲酰胺与煤系高岭土相互作用后均能进入高岭石层间并撑大其晶面间距,其中金洋高岭土的插层率最高,雪纳次之,蒙西高岭土的插层效果最差。 相似文献
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《Applied Geochemistry》2002,17(7):885-902
An ancient saprolite has developed on the Palaeoproterozoic granulite, granite gneiss and amphibolite bedrock of the Vuotso–Tankavaara area of central Finnish Lapland. The present day climatic regime in Finnish Lapland lies within the northern boreal zone and so the saprolite there can be regarded as fossil. Cores of saprolite were collected from 4 sections (42 samples) and analyzed chemically and mineralogically. In the study area, progressive weathering of the rocks has been marked by gradual enrichment in Al, Fe and Ti; and depletion of Na, K and Ca. The higher concentration of Fe(III) and water and reduced Na and Ca in weathered bedrock in the 4 sections are indicative of oxidation, hydration and leaching processes involved during weathering. The primary minerals in the saprolite are plagioclase feldspar, K-feldspar, quartz, garnet (almandine) and hornblende; the common secondary minerals are kaolinite, halloysite, and vermiculite in addition to minor amounts of sericite. Intense weathering is indicated by: (1) the presence of kaolinite and halloysite in 4 sections of different bedrock types, and (2) the comparatively lower SiO2/Al2O3 (wt.%) ratio (2.30) of weathered granulites (3 sections) as compared to fresh granulite (4.33) and that of weathered amphibolite (2.68) as compared to fresh amphibolite (3.56). In general, kaolinite and halloysite have formed through the weathering of feldspars, garnet, and biotite. Vermiculite is the most probable alteration product of biotite. The formation of kaolinite and halloysite in Finnish Lapland indicates wetter and warmer climatic conditions during the time of their formation than at present. The possible time for formation of the saprolite is early Cretaceous–early Tertiary into Middle Miocene. 相似文献