碧口群火山岩性质及形成环境

中元古代—新元古代碧口群火山岩系分布在扬子地块北缘、秦岭造山带南侧。碧口群火山岩系具大陆裂谷火山岩特点,形成于大陆裂谷作用构造环境。火山岩系特征为：① 具双峰式火山岩组合,火山岩系由基性火山岩（细碧岩及细碧质凝灰岩）及酸性火山岩（石英角斑岩及石英角斑质凝灰岩）组成。② 基性火山岩包括两个岩浆系列的岩石,即碱性玄武岩浆系列及拉斑玄武岩浆系列。③ 火山岩富集LREE及LIL。微量元素及同位素（SmNd,RbSr）研究表明,基性火山岩形成于相似于洋岛玄武岩源的地幔柱源,酸性火山岩为地壳重熔的产物。扬子地块北缘分布有碧口群、西乡群等中元古代—新元古代大陆火山岩系,表明在这一时期大陆裂谷拉张火山作用发育,成为秦岭地壳的主要增生成壳期。     

碧口群火山旋回及其地质构造意义

通过详细的野外剖面观察和室内岩石地球化学研究,将碧口群火山岩划分为3个火山旋回,每个旋回下部为基性火山岩(细碧岩及细碧质凝灰岩),上部为酸性火山岩(石英角斑岩或石英角斑质凝灰岩).基性火山岩富集LREE及LIL.第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列.基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物.碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物.这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆.     

华北克拉通中元古代裂解事件:以渣尔泰-白云鄂博-化德裂谷带岩浆与沉积作用研究为例

华北克拉通存在三个主要的中元古代裂谷带,从南到北分别为熊耳裂谷带、燕辽裂谷带以及渣尔泰-白云鄂博-化德裂谷带。其中熊耳群中火山岩的峰期年龄为1780~1750Ma,其上还有形成于被动大陆边缘的五佛山群、汝阳群以及官道口群。中北部的燕辽裂谷带包括长城系、蓟县系和青白口系,其中长城系团山子组和大红峪组火山岩的年龄分别为~1640Ma和1626~1622Ma,蓟县系高于庄组、雾迷山组和铁岭组凝灰岩的年龄分别为1560Ma、1485Ma和1437Ma,而下马岭组凝灰岩年龄为1366~1380Ma。北缘渣尔泰-白云鄂博-化德裂谷带中渣尔泰群书记沟组玄武岩年龄为1743Ma,阿古鲁沟组酸性火山岩年龄为~810Ma,白云鄂博群尖山组中基性火山岩年龄为1728Ma,化德群比鲁特组火山碎屑岩年龄为1515Ma。中元古代岩浆事件除了裂谷带中的火山作用外,还包括三期基性岩墙群(~1780Ma太行-吕梁岩墙群、~1730Ma密云岩墙群和~1620Ma泰山岩墙群)以及1.76Ga到1.65Ga非造山岩浆组合(斜长岩-环斑花岗岩体-A型花岗岩)。中元古代中期,华北克拉通北缘发育了基性岩席(墙)、A型花岗岩以及碳酸岩脉,双峰式岩浆作用说明华北北缘在中元古代中期经历了裂谷作用,与哥伦比亚超大陆的最终裂解有关,并且与白云鄂博巨型REE-Nb-Fe矿床的形成具有成因上的联系。华北克拉通北部两个裂谷带中的地层具有可以对比的层序以及时代,而中元古代中期辉绿岩墙、A型花岗岩以及碳酸岩脉可以与其它克拉通同时期的非造山岩浆作用对比,证明华北克拉通经历了哥伦比亚超大陆的最终裂解。古地磁数据已经证明在哥伦比亚超大陆时期Siberia、Laurentia、Baltica、Amazion以及华北克拉通是连接在一起的,而北缘中元古代中期大陆裂谷相关岩浆岩的发现也说明它是与另一个古大陆相连的。华北克拉通南缘熊耳火山岩的构造背景到底是大陆裂谷还是大陆边缘弧则关系着其是与另一个克拉通相连还是面向大海,这需要我们进一步深入研究。     

川西新元古代双峰式火山岩成因的微量元素和Sm-Nd同位素制约及其大地构造意义

系统的微量元素和Sm-Nd同位素分析表明,川西地区早震旦世苏雄组双峰式火山岩中的大多数玄武岩具有高的正ε_Nd(T)值(+5～+6)、大离子亲石元素和LREE富集,与现代典型的洋岛玄武岩和大陆溢流玄武岩省中的碱性玄武岩有非常相似的地球化学和同位素组成特征。酸性火山岩的ε_Nd(T)值较低(+1.1～+2.6),地球化学特征总体上与A₂-型花岗岩相似,它们是受地壳混染的OIB型玄武质岩浆在地壳中部的一个“双扩散”岩浆房通过结晶分异形成的。苏雄组双峰式火山岩形成于典型的大陆裂谷环境,非常类似于现代与地幔柱活动有关的高火山活动型裂谷火山岩,扬子块体西缘 800Ma前的裂谷作用和火山活动应是约825Ma前的华南地幔柱活动引发的结果。     

碧口群火山旋回及其地质构造意义

通过详细的野外剖面观察和室内岩石地球化学研究,将碧口碧火山岩划分为3个火山旋回,每个旋回下部为基性火山岩（细碧岩及细碧质凝灰岩）,上部为酸性火山岩（石英角斑岩或石英角斑质凝灰岩）。基性火山岩富集LREE及LIL。第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列。基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物。碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物。这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆。     

北祁连山元古代末—寒武纪海相火山作用与成矿作用的关系

元古代末－寒武纪是北祁连山与海相火山岩有关的块状铜金金属硫化物矿床的主要成矿时期。含矿火山岩系产于大陆裂谷作用的初期阶段。这一时期陆壳拉强速度缓慢，碱性玄武岩浆可停滞于地壳中，导致地壳深熔，由此大量酸性岩浆产生。酸性岩浆上升、喷出并形成火山岩穹的中心，然后，基性岩浆喷溢，并覆盖在酸性火山岩之上，由此形成双层的火山岩穹。火山央穹驱使海底热卤水对流和循环，同时火山喷出物提供了丰富的成矿元素，进而一系列     

祁连山西段古元古代北大河岩群中斜长角闪岩的地球化学特征及构造背景

以大陆碎块形式残存于北祁连造山带内部的古元古代北大河岩群早期发育有大量的斜长角闪岩,其原岩为玄武岩,Alk-∑FeO-MgO图解、REE特征、里特曼组合指数等均显示斜长角闪岩属钙碱性系列范围,个别显示弱碱性,斜长角闪岩具有较高的Al2O3、∑FeO和低的Mg#,这些特点反映其成分演化程度较高,表明火山岩的形成与古老地壳的活化有关,有较强分异的稀土元素分配模式,在Ti-Zr-Y图、Ni-FeO/MgO图解和Ta/Yb-Th/Yb图解上斜长角闪岩均显示火山弧或活动大陆边缘的特点,在玄武岩的地球化学形式图、稀土元素整体特征与钙碱性岛弧玄武岩基本相同;87Sr/86Sr=0.71617～0.72033,143Nd/144Nd=0.512414～0.512495,εNd=-2.79～-4.37.显示出壳源性质或者是受到大陆下地壳的混染作用而形成.因此推测斜长角闪岩的原岩为不同程度部分熔融的岩浆弧作用的产物,说明在古元古代华北克拉通和柴达木克拉通之间存在古洋盆的俯冲消减.     

湖南中—新元古代火山—侵入岩地球化学及成因意义

江南造山带西段湖南中、新元古代火山－侵入岩具有截然不同的地球化学特征。中元古代火山－侵入岩金属亚碱性玄武岩类，MgO,Ni,Cr含量及Al2O3/TiO2比值高，稀土元素分馏形式多样，更多地具有岛弧火山岩的特征，新元古代中基性火山－侵入岩MgO,Ni,Cr含量较低；其中的基性岩大多属碱性玄武岩类，并较富TiO2,Al2O3/TiO2比值较低，HFSE明显富集，微量元素标准化曲线与OIB类似，具有裂谷玄武岩的特征。中元古代南桥玄武岩εNd(t)为6．86－8．98，具有明显的N－MORB特征，是俯冲带附近的古洋壳残片，为九岭古岛弧提供了新的证据。中元古代的益阳玄武岩εNd(t)为1．56－1．76，Nb,Ti,Zr亏损，Th相对富集，具俯冲带火山岩的地球化学特征，同时这些玄武岩具有高MgO、高Al2O3/TiO2比值和Ni,Cr含量，具科马提质玄武岩的特性，可能是局部地幔柱－弧相互作用的产物。新元古代早期益阳安山质集块岩Th,La,Sm和Nd富集，Nb,Ti,Zr和Hf亏损，εNd(t)值为－0．53－－1．05，是格林威尔造山运动的产物。新元古代黔阳，古丈、高桥火山－侵入岩原始地幔标准化曲线近似于OIB，具裂谷玄武岩的特征，黔阳，古丈基性岩εNd(t)值在1．09－1．69，来源于软流圈地幔，湖南这些中－新元古代火－侵入岩的地球化学特征记录了Radinia超大陆在该区从拼合到裂解的演化踪迹。     

扬子地块北缘西乡群孙家河组火山岩形成时代及元素地球化学研究

西乡群孙家河组为一套低绿片岩相浅变质火山-沉积岩系,主要由基性-中基性-酸性火山岩和凝灰岩、沉凝灰岩、泥岩、硅质岩组成,火山岩岩石类型包括玄武岩、安山岩、英安岩和流纹岩.LA-ICPMS锆石U-Pb定年揭示流纹岩形成时代为832.9±4.9Ma,辉石玄武岩的形成时代为845.0±17Ma,两者在误差范围内一致,属新元古代同期岩浆作用产物.元素地球化学研究表明,孙家河组玄武岩属拉斑玄武岩系列,具有受地壳混染的板内玄武岩的地球化学特点.玄武岩-安山岩-英安岩主量元素成分投点呈规律性变化、REE球粒陨石标准化及微量元素原始地幔标准化分配型式具有一致性并相互重叠,不相容元素Th和相容元素Cr相关模拟图中沿分离结晶线分布,证明玄武岩-安山岩-英安岩为同一基性岩浆分离结晶的产物.REE和微量元素分配型式以及微量元素比值对的显著差异,暗示流纹岩与玄武岩-安山岩-英安岩来源于不同源区.Sr-Nd同位素研究表明,玄武岩-安山岩-英安岩样品的ε_(Nd)(t)值均大于0以及在ε_(Nd)(t)-(~(87)Sr/~(86)Sr)_t图解中位于OIB成分区,表明其源区应为与洋岛玄武岩类似的地幔源区;流纹岩样品具有可与基性熔岩相比拟的ε_(Nd)(t)值,暗示流纹岩最有可能是初生玄武质地壳部分熔融而成.本文所研究的原划孙家河组火山岩系列的形成时代、构造环境的确定以及扬子陆块乃至世界上同一时间内普遍发育大陆裂谷岩浆岩组合的地质事实,说明原划孙家河组以及西乡群中的确存在新元古代的组成部分,它们应是新元古代大陆裂谷的产物,它和扬子地块820M8后造山裂解环境花岗岩均是新元古代晚期Rodinia超大陆裂解作用的岩浆响应.     

云南前寒武纪基底形成与变质时代及其成矿作用年代学研究

新的同位素年代学、岩石学与地球化学研究表明云南前寒武纪各岩群普遍由跨越古、中和新元古代不同时代的构造片岩组成.哀牢山群和瑶山群是相连接的同一地层单元,主体岩石形成于1 300~1 600 Ma.昆阳群下亚群泥质碳酸盐沉积岩Pb-Pb等时年龄在1 700~1 600 Ma之间,上亚群大营盘组为1 260 Ma.苍山群的变拉斑系列形成于岛弧环境,其钕模式年龄值在1 500~2 000 Ma,Sm-Nd等时年龄近于为1 650 Ma,εNd(t)=+7.4.形成于板内环境的碱性系列玄武岩,钕模式年龄值在1 000~1 100 Ma.苴林群变拉斑玄武岩钕模式年龄为1 600~1 700 Ma,εNd(t)=+6.6;变碱性玄武岩样品为800~1 000 Ma,可与苍山群相比较.钕模式年龄和Pb同位素填图表明昆阳群与大红山群,苴林群与苍山群分别归属于扬子和印支块体的准同时地层.成矿年龄测定表明前寒武纪地层中成矿作用表现为700~900 Ma的改造成矿,与大规模从基性到酸性的岩浆活动密切相联系.900~1000 Ma板内环境碱性玄武岩的广泛出现,标致着大陆裂解的开始.晋宁期花岗岩活动从早期(800~830 Ma)的偏中酸性到晚期(680~780 Ma)的酸性,表明构造环境从拉张向挤压环境发展,体现了Rodinia超大陆形成、裂解到冈瓦纳大陆形成的过程.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案（1999/30/EC）,对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.