阿尔泰小土尔根铜矿区岩体LA-ICP-MS锆石U-Pb定年及地质意义

小土尔根是近年来阿尔泰诺尔特盆地发现的首例斑岩铜矿床,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化受花岗闪长斑岩控制,少部分赋存在地层中。文章利用LA-ICP-MS锆石U-Pb测年法对矿区岩体进行了成岩年代学研究。含矿花岗闪长斑岩、黑云二长花岗岩和花岗斑岩中锆石的206Pb/238U年龄的加权平均值分别为(401.0±2.9)Ma、(398.1±2.2)Ma和(400.5±2.0)Ma,为早泥盆世同一岩浆侵入活动形成的不同侵入岩。侵入岩年龄结合凝灰岩年龄,将矿区地层划归早泥盆世诺尔特组。含矿花岗闪长斑岩锆石U-Pb年龄限定小土尔根斑岩铜矿床成矿时代略晚于401 Ma,即矿床形成于早泥盆世。     

新疆准噶尔北缘玉勒肯哈腊苏斑岩铜矿床年代学研究

玉勒肯哈腊苏铜矿是近几年准噶尔北缘卡拉先格尔斑岩铜矿带发现的又一个中型斑岩铜矿,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化主要受闪长玢岩控制,少部分赋存在似斑状黑云母石英二长岩和北塔山组火山岩、火山碎屑岩中。本文利用锆石LA-ICP-MSU-Pb法和辉钼矿Re-Os法对矿区岩体和矿化进行了成岩成矿年代学研究。结合前人的研究,认为矿区存在5次主要岩浆侵入事件:382Ma石英闪长岩侵入,379Ma形成含矿闪长玢岩,375～374Ma形成似斑状黑云石英二长岩,348Ma形成黑云母石英斑岩脉,266Ma形成二长斑岩,前三次岩浆侵入活动对应构造环境为板块俯冲阶段,后二次岩浆侵入活动为后碰撞阶段。9件辉钼矿样品Re-Os同位素等时线年龄为373.9±2.2Ma,表明铜钼成矿时代为中泥盆世晚期,与闪长玢岩侵入有关。     

江西北武夷高家山铜钼矿含矿岩体的特征与锆石U-Pb年代学研究

北武夷地区高家山矽卡岩型铜钼多金属矿床位于扬子地块与华夏地块碰撞对接带萍乡－广丰深大断裂的南侧,前人获得与成矿有关正长斑岩、花岗斑岩体的K-Ar法同位素年龄为63.6Ma、84.7Ma。本文对与成矿有关的正长斑岩和侵入于正长斑岩、花岗斑岩中的闪长玢岩分别进行了精确的锆石U—Pb定年研究,获得锆石 206Pb/238U年龄分别为232.7±0.6Ma和219.6±1.5Ma,属印支期。通过分析矿石的氧、硫同位素和成矿岩体的地质地球化学特点,认为高家山铜钼矿床与印支期富碱性岩浆活动存在密切的时空和成因联系。因此,成矿岩体年龄间接地反映了本矿床的形成时代为印支期,提供了北武夷地区印支期成矿作用的新信息。     

云南普朗复式岩体锆石U-Pb年龄和地球化学特征及其地质意义

根据接触关系和岩石学特征将普朗复式岩体划分为三个阶段的侵入岩,即第一阶段的石英闪长玢岩,第二阶段的石英二长斑岩和第三阶段的花岗闪长斑岩。利用单颗粒锆石U-Pb法测定的早、中、晚三个阶段侵入岩的结晶年龄分别为221.0±1.0Ma、211.8±0.5Ma和206.3±0.7Ma。这些年龄数据结合岩石化学和锶同位素资料,表明普朗复式岩体是在印支期由壳幔混源岩浆多次涌动侵入形成的。     

内蒙古白乃庙铜矿床的成矿时代—来自SHRIMP锆石U-Pb和辉钼矿Re-Os年龄的新证据

摘要：内蒙古白乃庙铜矿床位于兴蒙造山系满都拉-霍林郭勒弧盆系白乃庙早古生代岛弧内,该矿床包括南、北两个矿带,南矿带矿体产于白乃庙组绿片岩中,北矿带矿体产于花岗闪长斑岩内,对于该矿床及白乃庙组的形成时代争议较大。本文采用锆石SHRIMP U-Pb同位素定年获得了白乃庙组第三岩性段绿泥斜长片岩的形成年龄为439.8±6.7Ma,花岗闪长斑岩的形成年龄为433.9±2.2Ma、451.8±3.0Ma,采用辉钼矿Re-Os同位素分析获得辉钼矿的形成年龄为433.9±3.1Ma。结合前人成果,提出白乃庙组地层和花岗闪长斑岩的成岩时代与白乃庙铜矿的成矿时代均为晚奥陶-早志留世,它们同属加里东期构造-岩浆作用的产物。 关键词：绿泥斜长片岩;花岗闪长斑岩;锆石SHRIMP U-Pb年龄;辉钼矿Re-Os同位素年龄;白乃庙铜矿     

铜陵矿集区舒家店矿区中酸性侵入岩锆石U-Pb年代学研究

铜陵舒家店地区中酸性侵入岩发育,主要由舒家店岩体、林家冲岩体及其周围的小岩体构成。区内侵入岩可划分为高钾钙碱性系列和橄榄安粗岩系列。对两个主要岩体的钻孔岩心采样并对其进行了LA-ICP-MS锆石UPb定年工作。研究结果表明,舒家店地区中酸性侵入岩活动存在多期性,花岗闪长斑岩侵入年龄在147.0~146.9Ma,辉石二长闪长岩为144.8 Ma,石英二长闪长岩为141.0 Ma,花岗闪长岩为138.0 Ma,花岗斑岩在130.5~124.0Ma,长英质细晶岩为129.4 Ma,并给出区内中酸性岩浆侵位先后次序为:花岗闪长斑岩→辉石二长闪长岩→石英二长闪长岩→花岗闪长岩→花岗斑岩脉/长英质岩脉。     

西秦岭早子沟金矿中酸性侵入岩地球化学、年代学特征及成矿地质体的确定

西秦岭早子沟金矿是与岩浆活动有关的特大型金矿床,矿区中酸性侵入岩集中发育,主要有闪长玢岩、黑云石英闪长玢岩、花岗斑岩、石英闪长岩4种岩石类型。岩石微量元素均表现出富集大离子亲石元素Rb、K,亏损高场强元素Nb、Ta、P、Ti的特征。稀土元素总量整体上黑云石英闪长玢岩>闪长玢岩>石英闪长岩,闪长玢岩、黑云母石英闪长玢岩、花岗斑岩具有弱-中等的负铕异常(δEu=0.60～0.89),深部石英闪长岩以不具Eu异常(δEu=0.96～1.07)、“Nb-Ta谷”较深明显区别于浅部脉岩。石英闪长岩锆石U-Pb年龄为230 Ma,晚于浅部脉岩10～20 Ma,与蚀变矿物绢云母年龄基本一致,推测金成矿可能始于230 Ma,主成矿期为230～211 Ma,深部石英闪长岩为早子沟金矿的成矿地质体。     

冈底斯中段岗讲斑岩铜钼矿床锆石U-Pb和辉钼矿Re-Os年代学及其地质意义

岗讲铜钼矿床是西藏冈底斯成矿带中段典型的斑岩型矿床,岗讲矿床成岩成矿时代、岩浆演化过程及其与成岩成矿关系尚不明确,利用LA-ICP-MS锆石U-Pb定年方法对岗讲矿区主要岩体二长花岗斑岩、花岗闪长斑岩和英云闪长玢岩成岩时代进行研究,获得锆石U-Pb年龄加权平均值分别为16.6±0.3 Ma (MSWD=0.94,n=10)、16.1±0.2 Ma (MSWD=1.07,n=12)、14.4±0.4 Ma (MSWD=1.12,n=7);同时采用辉钼矿Re-Os同位素测年方法首次对岗讲矿床石英硫化物脉中的辉钼矿进行定年,获得12件辉钼矿Re-Os同位素模式年龄集中于13.24±0.20 Ma~13.55±0.22 Ma,加权平均年龄为13.4±0.1 Ma (MSWD=0.65),等时线年龄为13.6±1.6 Ma (MSWD=1.2).结果表明:(1) 岗讲矿区复式岩体侵入序列为含巨斑黑云二长花岗岩-二长花岗斑岩-花岗闪长斑岩-流纹斑岩 (深部定名为英云闪长玢岩),成岩时限为16.6~14.4 Ma,成矿时代为13.4 Ma左右,成岩成矿是一个连续的岩浆演化过程;(2) 辉钼矿中Re含量为155.4~171.1 μg/g,均值为162.9 μg/g,指示其成矿物质中有幔源成分的加入;(3) 矿床产出于中新世印度-亚洲大陆碰撞后伸展构造环境.      

江西北武夷山高家山铜钼矿含矿岩体的特征与锆石U-Pb年代学研究

北武夷山地区高家山矽卡岩型铜钼多金属矿床位于扬子地块与华夏地块碰撞对接带萍乡-广丰深大断裂的甫侧,前人获得与成矿有关正长斑岩、花岗斑岩体的K-Ar法同位素年龄为63.6 Ma、84.7 Ma.本文对与成矿有关的正长斑岩和侵入于正长斑岩、花岗斑岩中的闪长玢岩分别进行了精确的锆石U-Pb定年研究,获得锆石206Pb/238U年龄分别为232.7±0.6 Ma和219.6±1.5 Ma,属印支期.通过分析矿石的氧、硫同位素和成矿岩体的地质地球化学特点,认为高家山铜钼矿床与印支期富碱性岩浆活动存在密切的时空和成因联系.因此,成矿岩体年龄间接地反映了本矿床的形成时代为印支期,提供了北武夷山地区印支期成矿作用的新信息.     

鄂西黄陵花岗岩基同位素年龄谱

采用Isoplot程序重新计算了鄂西黄陵花岗岩基主要岩套的Rb-Sr等时线年龄和锆石U-Pb一致曲线年龄,测定了各种类型脉岩的侵入年龄,最后获得该岩基岩浆活动的年龄谱是主体太平溪英云闪长岩岩套和黄陵庙花岗闪长岩岩套的侵位年龄分别是(833±29)Ma和(819±7)Ma,大老岭石英二长花岗岩岩套是(786±54)Ma,脉岩套侵入年龄从花岗闪长斑岩的813 Ma开始,到770Ma的辉绿岩和772Ma的石英脉侵入,整个岩基抬升作用完成,岩浆活动基本结束.在印支期(217±7)Ma时,岩基上NNW和NNE向大断裂发生了强烈的再次活动.Nd,Sr同位素证据表明,除大老岭岩套外,其他三个岩套的岩浆演化是连续的,这些岩浆起源于晋宁期扬子板块北缘发生的大洋板块消减作用.     

内蒙古长山壕金矿区花岗岩同位素年代学研究及地质意义

长山壕金矿床是近年来在内蒙古中西段找到的一特大型金矿床。尽管金矿化在中元古界白云鄂博群变质沉积岩内呈层状、似层状和透镜状产出,但是与各类花岗岩类侵入岩具有密切空间分布关系。本次研究采用LA-ICP-MS方法分别对有关花岗岩类侵入岩进行了系统年代学研究,花岗斑岩和二长花岗斑岩样品的锆石U-Pb年龄值分别为290.9±2.8Ma (MSWD=1.4)和287.5±1.9Ma (MSWD=2.4);2件黑云母花岗岩样品的年龄值分别为267.9±1.2Ma (MSWD=0.95)和274.0±2.3Ma (MSWD=1.4)。根据上述同位素年龄数据,同时结合金矿区野外地质调查和岩(矿)相学证据,可以认为,长山壕金矿区花岗斑岩和二长花岗斑岩及相关金矿床的形成时间为早二叠世早期,并且遭受到早二叠世晚期-中二叠世早期构造-岩浆活动的叠加改造,矿区切穿含金矿脉黑云母花岗岩体的存在就是很好的例证。强烈的中酸性岩浆作用为金矿床的形成提供了动力、热力和物质来源,初步研究结果表明,长山壕金矿床是海西期构造-岩浆作用及相关流体活动的产物,属于与侵入岩有关的中温热液脉型金矿床。     

Timing and duration of hydrothermal activity at the Los Bronces porphyry cluster: an update

New geochronological data from the Los Bronces cluster of the Río Blanco-Los Bronces mega-porphyry Cu-Mo district establish a wide range of magmatism, hydrothermal alteration, and mineralization ages, both in terms of areal extent and time. The northern El Plomo and southernmost Los Piches exploration areas contain the oldest barren porphyritic intrusions with U-Pb ages of 10.8?±?0.1 Ma and 13.4?±?0.1 Ma, respectively. A hypabyssal barren intrusion adjacent northwesterly to the main pit area yields a slightly younger age of 10.2?±?0.3 Ma (San Manuel sector, U-Pb), whereas in the Los Bronces (LB) open-pit area, the present day mineral extraction zone, porphyries range from 8.49 to 6.02 Ma (U-Pb). Hydrothermal biotite and sericite ages are up to 0.5 Ma younger but consistent with the cooling of the corresponding intrusion events of each area. Two quartz-molybdenite B-type veins from the LB open pit have Re-Os molybdenite ages of 5.65?±?0.03 Ma and 5.35?±?0.03 Ma consistent with published data for the contiguous Río Blanco cluster. The San Manuel exploration area within the Los Bronces cluster, located about 1.5–2 km southeast of the open-pit extraction zone, shows both the oldest hydrothermal biotite (7.70?±?0.07 Ma; ⁴⁰Ar/³⁹Ar) and breccia cement molybdenite ages (8.36?±?0.06 Ma; Re-Os) registered in the entire Río Blanco-Los Bronces district. These are also older than those reported from the El Teniente porphyry Cu(-Mo) deposit, suggesting that mineralization in the late Miocene to early Pliocene porphyry belt of Central Chile commenced 2 Ma before the previously accepted age of 6.3 Ma.     

华北克拉通北缘鸡冠山斑岩钼矿床成矿年代及印支期成矿事件

鸡冠山斑岩钼矿床是华北克拉通北缘少为人知的中生代西拉沐伦钼矿带中最大的钼矿床之一。它与鸡冠山次火山杂岩有关,杂岩体受NW向、NE向及NEE向三组断裂控制。锆石SHRIMP U-Pb定年表明,发育钼矿化的矿区内最晚的花岗斑岩侵位于245±2.7Ma。这表明,鸡冠山钼矿化发生在印支期。结合已有资料分析,认为华北克拉通北缘曾在印支期发生重要的岩浆-成矿事件。     

三江北段纳日贡玛黑云母花岗斑岩LA-ICP-MS锆石U-Pb定年及其地质意义

西南三江北段是青海省重要的斑岩型铜钼矿成矿带,纳日贡玛铜钼矿是近年来在三江北段发现的与侵入岩有关的斑岩型铜钼矿。利用锆石U-Pb方法测得纳日贡玛黑云花岗斑岩的形成年龄为41.53Ma ±0.24Ma,属于喜马拉雅早期。纳日贡玛斑岩型铜钼矿的成矿时代主要在40.86~40.80Ma之间。在多期热液叠加、多期成矿作用中,纳日贡玛斑岩型铜钼矿的热液应是纳日贡玛黑云花岗斑岩（41.53Ma ±0.24Ma）和纳日贡玛斜长花岗斑岩（41.00Ma ±0.18Ma）共同提供的。由于该区有较多的中酸性岩体存在,因而确定这些侵入体的形成年龄,对于在该区寻找同时代的斑岩型铜钼矿有重要的理论意义和现实意义。     

Geology,geochemistry and genesis of the Makou magnetite-apatite deposit in the Luzong volcanic basin,Middle-Lower Yangtze River Valley Metallogenic Belt,Eastern China

The Middle-Lower Yangtze River Valley Metallogenic Belt (MLYB) is located on the northern margin of the Yangtze Plate (Eastern China). Ore deposits in the belt are mainly clustered in seven ore districts, and are closely associated with Mesozoic intermediate-felsic magmatic rock. Among the seven ore districts, the Luzong and Ningwu districts host large-scale iron resources in volcanic basins. The Makou magnetite-apatite deposit in the southern Luzong Basin was previously interpreted to be related to a quartz syenite porphyry. In this study, we conducted field geological studies and determined the age and geochemistry of the Makou intrusive rocks. Petrography and electron probe micro analysis (EPMA) indicated that the Makou ore-hosting rocks have intense albite alteration. The wallrock alteration is spatially restricted, and comprises albite alteration (Stage I), magnetite mineralization (Stage II), quartz-sulfide alteration (Stage III) and carbonate alteration (Stage IV) stages. Fluid inclusions in syn-mineralization apatite homogenized at 252.2–322.6 °C, which slightly lower than is typical for magnetite-apatite deposits in the region. Field study revealed that the quartz syenite porphyry at Makou disrupted the orebodies along clear-cut intrusive contacts, and that the quartz syenite porphyry does not contain iron mineralization, suggesting it has no direct genetic relationship with the iron mineralization. The ore-hosting albitite and ore-forming biotite diorite have LA-ICP-MS zircon U-Pb ages of 129.6 ± 1.2 Ma and 131.2 ± 3.3 Ma, respectively, and the iron mineralization was dated by mass spectrometer phlogopite ⁴⁰Ar-³⁹Ar at 130.76 ± 0.77 Ma. We propose that the Makou magnetite-apatite deposit is genetically related to the biotite diorite, rather than to the quartz syenite porphyry in the mine pit. The biotite diorite closely resembles intrusions related to magnetite-apatite deposits elsewhere in the region.     

胶东邢家山地区燕山早期钼钨成矿母岩锆石U-Pb年龄及其意义

对从幸福山花岗岩中挑出的岩浆锆石进行了LA-ICP-MS分析,得出了由15个点组成的加权平均值为(157±2)Ma的年龄。此15个测试点均处于岩浆锆石的振荡环带上,且此年龄与邢家山钼钨矿辉钼矿Re-Os年龄一致,代表该花岗岩的结晶年龄。本次测试所得到的另外2组捕获锆石年龄(2798±13)Ma和(2250±18)Ma暗示该岩浆源区可能存在的新太古代-古元古代侵入岩基底,(230±6)Ma则可能暗示着该区存在三叠纪的岩浆活动。中生代以来(190~110 Ma),中国东部构造岩浆活动特征较为一致,与之相对应存在多期成矿作用。胶东地区广泛出露的玲珑花岗岩与幸福山花岗岩岩石地球化学特征及年龄基本一致,可能该区也存在着大规模的钼多金属成矿作用,只是大部分为后期构造抬升所剥蚀,邢家山钼钨矿是保存下来的代表。也说明,栖霞—福山地区中生代以来剥蚀程度相对较小,矿床保存条件较好,故应重视该区中浅成矿床(斑岩-矽卡岩型、卡林型、造山型浅成矿床等)的寻找。     

Geochemistry of middle-late Mesozoic mafic intrusions in the eastern North China Craton: New insights on lithospheric thinning and decratonization

We present detailed geochronological, geochemical and Sr-Nd-Pb isotopic data for late Mesozoic mafic intrusions in the Taili region (western Liaodong Province) of the eastern North China Craton (NCC). We obtained laser-ablation inductively-coupled plasma mass spectrometry U-Pb zircon ages from lamprophyres with ages ranging from 139 to 162 Ma and diorites with clusters of ages at 226 ± 11 Ma, 165 ± 5.8 Ma and 140 ± 4.8 Ma. We interpret the Triassic zircons in diorites to be inherited from the Paleo-Asian Ocean slab. Both the lamprophyres and diorites contain abundant inherited grains (2644–2456 Ma) that were likely derived from the ancient NCC basement, reflecting a contribution from old lower crustal material. Like contemporaneous late Mesozoic mafic rocks in the Jiaodong and Liaodong Peninsula areas of the NCC, the Taili lamprophyres reveal a strong subduction signature in their normalized trace element patterns, including depletion of high field strength elements and enrichment of large ion lithophile elements. The rare-earth element patterns of the Taili intermediate-mafic intrusions are best explained if they were principally derived from partial melting of amphibole-bearing lherzolite in the spinel-garnet transition zone. Slab-derived melts likely contributed to the formation of late Mesozoic mafic rocks along three margins of the craton: due to accretion of the Yangtze Block along the southern margin of the craton, subduction of the Paleo-Asian Ocean along the northern margin, and subduction of the Paleo-Pacific oceanic plate along the eastern margin of NCC. We present a synthesis of the geochemical, spatial, and temporal patterns of magmatic rocks and periods of deformation that contributed to decratonization of the NCC in response to the Mesozoic tectonic evolution of adjacent plates along its northern, southern, and eastern margins.     

滇西马厂箐斑岩型铜钼(金)矿床成岩成矿时代研究

滇西马厂箐铜钼(金)矿床是金沙江-哀牢山构造带与喜马拉雅期富碱斑岩有关的典型斑岩型矿床之一。富碱斑岩侵入体为多期、多阶段岩浆活动形成的复式岩体,已有的研究资料表明岩浆活动时限在64～29 Ma。文中提供的锆石LA ICP MS U Pb和辉钼矿Re Os同位素年代学研究资料显示,马厂箐含矿岩体锆石U Pb年龄(封闭温度约800 ℃时)为(3793±082) Ma,代表了富碱斑岩的成岩年龄;辉钼矿的Re Os年龄(封闭温度约500 ℃)为(3472±05) Ma,代表成矿时代。该研究结果与前人确定的晚期富碱斑岩岩浆活动的时间(32 Ma)相近,也与前人获得的蚀变黑云母K Ar定年(封闭温度300 ℃)结果(351±08) Ma相近,因此可以认为成矿作用与岩体快速冷却过程中发生成矿流体大量分离和出溶有关。成岩作用与成矿作用的时间跨度大约为2 Ma。因此,金沙江-哀牢山多金属成矿带的斑岩型铜钼矿床是与富碱斑岩成岩作用近同期成矿作用的产物,成矿作用时限集中在40~35 Ma左右。     

青藏高原北部风火山花岗斑岩锆石U-Pb同位素测年及其地质意义

青藏高原北部风火山花岗斑岩与逆冲推覆构造存在密切关系,岩浆侵位发生在区域地质构造演化的重要历史时期。对风火山北麓花岗斑岩及暗色包体,在显微观测和矿物鉴定的基础上,通过单颗粒锆石离子探针U-Pb同位素测年,获得高精度的测年资料。测得早期岩浆锆石结晶平均年龄为(34.5±1.4) Ma,对应于岩浆源区地壳局部熔融时代;晚期岩浆锆石结晶平均年龄为(27.6±0.5)Ma,对应于岩浆向上侵入雅西错群的岩浆侵位时代。风火山北麓花岗斑岩属青藏高原北部出露的最年轻花岗岩,岩体内部不同类型锆石的U-Pb同位素测年为区域地层、区域构造和高原隆升的研究提供了重要的年代学约束。