Geochemical characterisation and erosion stability of fine‐grained groyne field sediments of the Middle Elbe River

Because of the significant reduction of flow velocity relative to the main current there is an accumulation of sediment material in the centre of the groyne fields over time (years to decades) up to a maximum of 1.5 m. Based on the element‐ and compound‐specific depth functions of this fine‐grained material with high organic matter content the sedimentation history of the Elbe River sediments concerning the environmentally relevant nutrients and pollutants can be reconstructed. It could be shown that the fresh sediments are less polluted than the deeper older ones. During the extreme flood of the river Elbe in August 2002 the critical erosion shear stress in the groyne fields was high enough to remobilise a considerable portion of the sediment depot. The hazard to the environment is high due to the fact that a significant part of the remobilised polluted sediments was distributed over the recent floodplain which is normally used as pasture. Thus these groyne field sediments represent a temporary danger for the water quality of the river Elbe. But the hazard of the solids sedimented in the recent floodplain of the river can be viewed as long‐lasting.     

Storage of sediment‐associated heavy metals along the channelized Odra River,Poland

The importance of long‐term storage of heavy metals in groyne fields, functioning over 150 years, is investigated for the River Odra (Oder), western Poland. Construction of groynes along the Odra preceded rapid development of heavy industrialization in the largest coal mine districts in Poland and the Czech Republic that resulted in persistent riverine pollution. The 187 km long Middle Odra reach was repeatedly channelized from the first half of the eighteenth century to the turn of the twentieth century, during which time partially filled groyne fields were dissected by new bank lines and groyne systems, with older groyne fields partially keyed into the floodplain. Consequently, concentrations of zinc, lead, cadmium, and copper within historically deposited groyne field sediments exceed local geochemical background levels by more than 60, 40, 15 and 10 times, respectively. Sediments contaminated with heavy metals occur within three distinctive geomorphic zones: zone I is up to 250 m wide and furthest from the present channel, comprising decimeter‐thick polluted sediments, overlying eighteenth century sand and gravel bars; zone II represents the former nineteenth century groyne fields, with widths between 10 and 100 m, filled with as much as 3 m of polluted sediments; zone III represents the twentieth century groyne fields, which are several to a dozen metres wide and filled with polluted sediments averaging depths of more than 2 m. This investigation indicates that large and extensive sediment quantities of moderately polluted sediments are stored immediately along the banks of the River Odra. These sediments could be a significant secondary pollution source and therefore careful maintenance of contemporary bank protection structures is required. Copyright © 2009 John Wiley & Sons, Ltd.     

On the correspondence between morphological and hydrodynamical patterns of groyne fields

This paper examines a variety of recirculation flow patterns that develop in the groyne fields on rivers. A comprehensive data set was obtained from flume experiments at Delft University of Technology and field measurements performed on the Elbe River in Germany. The analysis focuses on patterns of velocity, scour and deposition, and corresponding change of riverbed morphology. The results show that velocity patterns in the groyne fields depend mainly on the aspect ratio between groyne length and length of groyne field. When the aspect ratio is greater than 0·5, a one‐gyre pattern of recirculation develops, while at groyne fields with aspect ratios less than 0·5 a two‐gyre recirculation pattern emerges. The spatial distribution of fine‐sediment deposition between the groynes coincides with the locations of gyres. Moreover, the thickness of the fine‐sediment layer decreases toward the gyre margins where recirculation velocities are greatest. Although the total concentration of suspended sediment in the river does not change considerably as the flow moves through the groyne field, the biological and gravimetrical composition of the suspended material changes substantially within the groyne field. These changes are due to preferential deposition of coarse mineral particles and the replacement of those minerals with finer organic material. Copyright © 2002 John Wiley & Sons, Ltd.     

Event-scale floodplain accretion revealed through tree-ring analysis of buried plains cottonwoods,Powder River,MT, USA

Six plains cottonwoods along the axis of a meander were excavated to determine if dendrochronology could identify the year and location of germination and date past overbank sedimentation events. Samples from all excavated trees showed clear anatomical changes associated with burial, including increased vessel size, decreased definition of annual ring boundaries, and decreased ring widths. Some of these burial signatures were created by deposition of only a few centimeters of sediment, and most burial events were detected by multiple samples from the same tree. Four of the trees germinated at or near the upper surfaces of bar deposits, while two germinated within thin overbank deposits draped over bar deposits, indicating that germination is closely associated with bars. Dates and inferred thicknesses of overbank sedimentation events are consistent with repeated topographic surveys and data obtained from cesium-137 (¹³⁷Cs) analyses. However, the record of overbank sedimentation extracted from the trees does not entirely reflect the history of past peak discharges documented by stream gaging, largely because individual trees are progressively less likely to be flooded through time as the river migrates farther away. Germination dates and locations closely track past positions of the river channel. Germination elevations and the elevations of the tops of point bars appear to be decreasing with time as the bend migrates, implying vertical incision by Powder River at a rate of 7.1 ± 4.3 mm/yr. The rate of floodplain growth determined by elevation changes decreases progressively through time, ultimately reaching an apparent plateau after 0.8–1.3 m of vertical accretion. While similar patterns of vertical accretion have previously been interpreted as resulting from decreasing flood probability with increasing floodplain elevation, distance from the channel is also a first-order control on vertical floodplain growth. © 2019 John Wiley & Sons, Ltd.     

Can channel banks be the dominant source of fine sediment in a UK river?: an example using 137Cs to interpret sediment yield and sediment source

Cultivated fields have been shown to be the dominant sources of sediment in almost all investigated UK catchments, typically contributing 85 to 95% of sediment inputs. As a result, most catchment management strategies are directed towards mitigating these sediment inputs. However, in many regions of the UK such as the Nene basin there is a paucity of sediment provenance data. This study used the caesium‐137 (¹³⁷Cs) inventories of lake and floodplain cores as well as the ¹³⁷Cs activities of present day sediment to determine sediment provenance. Sediment yields were also reconstructed in a small lake catchment. Low ¹³⁷Cs inventories were present in the lake and floodplain cores in comparison to the reference inventory and inventories in cores from other UK catchments. Caesium‐137 activities in the present day sediments were low; falling close to those found in the channel bank catchment samples. It was estimated that 60 to 100% of the sediment in the Nene originated from channel banks. Pre‐1963 sediment yields were approximately 11.2 t km^?2 yr^?1 and post‐1963 was approximately 11.9 t km^?2 yr^?1. The lack of increased sediment yield post‐1963 and low sediment yield is unusual for a UK catchment (where a yield of 28 to 51 t km^?2 yr^?1 is typical for a lowland agricultural catchment), but is explained by the low predicted contribution of sediment from agricultural topsoils. The high channel bank contribution is likely caused by the river being starved of sediment from topsoils, increasing its capacity to entrain bank material. The good agreement between the results derived using cores and recently transported sediments, highlight the reliability of ¹³⁷Cs when tracing sediment sources. However, care should be taken to assess the potential impacts of sediment particle size, sediment focusing in lakes and the possible remobilization of ¹³⁷Cs from sedimentary deposits. Copyright © 2016 John Wiley & Sons, Ltd.     

An investigation of the spatial variability of the grain size composition of floodplain sediments

River floodplains have been widely recognized as important sinks for storing suspended sediment and associated contaminants transported by river systems. The grain size composition of floodplain deposits exerts an important influence on contaminant concentrations, and commonly exhibits significant spatial variability in response to the dynamic nature of overbank flow and sediment transport. Information on the spatial variability of the grain size composition of overbank deposits is therefore essential for developing an improved understanding of the processes controlling sediment transport on floodplains, and for investigating the fate of sediment-associated contaminants. Such information is also important for validating existing floodplain sedimentation models. This paper reports the results of a study aimed at investigating the spatial variability of the grain size composition of floodplain sediments at different spatial scales, through analysis of surface sediment samples representative of contemporary floodplain deposits collected from frequently inundated floodplain sites on five British lowland rivers. Significant lateral and downstream variations in the grain size composition of the sediment deposits have been identified in the study reaches. An attempt has been made to relate the observed spatial distribution of the grain size composition of the overbank deposits to the local floodplain geometry and topography. The importance of the particle size characteristics of the suspended sediment transported by the rivers in influencing the spatial variability of the grain size composition of the overbank sediments deposited on these floodplains is also considered. © 1998 John Wiley & Sons, Ltd.     

Reconstruction of eroded and deposited sediment volumes of the embanked River Waal,the Netherlands,for the period ad 1631–present

In the last few centuries humans have modified rivers, and rivers have responded with noticeable changes in sedimentary dynamics. The objective of this study is to assess these responses of the sedimentary dynamics. Therefore, we calculated a sediment budget for eroded and deposited sediment volumes in a ~12‐km long floodplain section of the largest semi‐natural embanked but still dynamic lower Rhine distributary, for ~50‐years time slices between ad 1631 and present. This is the period during which embanked floodplains were formed by downstream migration of meander bends between confining dykes. Our sediment budget involves a detailed reconstruction of vertical and lateral accretion rates and erosion rates of floodplain sediment. To do so, we developed a series of historical geomorphological maps, and lithogenetic cross‐sections. Based on the maps and cross‐sections, we divided the floodplain into building blocks representing channel bed and overbank sediment bodies. Chronostratigraphy within the blocks was estimated by interpretation of heavy metal profiles and from optically stimulated luminescence (OSL) dating results. Sediment budgets were hence calculated as a change of volume of each building block between time steps. The amount of lateral accretion initially increased, as a result of island and sand bar formation following embankment. From the eighteenth century onwards, there was a decrease of lateral processes in time, which is a result of straightening of the river by human activities, and a reduction of water and sediment supply due to the construction of a new upstream bifurcation. With straightening of the river, the floodplain area grew. Artificial fixation of the channel banks after ad 1872 prevented lateral activity. From then on, overbank deposition became the main process, leading to a continuous increase of floodplain elevation, and inherent decrease of flooding frequency and sediment accumulation rate. Copyright © 2014 John Wiley & Sons, Ltd.     

Impact of natural reforestation on floodplain sedimentation in the Dragonja basin,SW Slovenia

Changes in floodplain sediment dynamics have profound effects on riverine habitats and riparian biodiversity. Depopulation due to socio‐economic changes in the Dragonja catchment (91 km²) in southwestern Slovenia resulted in the abandonment of agricultural fields, followed by natural reforestation since 1945. This profoundly changed the water and sediment supply to the streams, as well as floodplain sediment deposition. This paper presents a reconstruction of the development of the Dragonja floodplain due to these land use changes during the last 60 years. The reconstruction is based on dating of floodplain sediments using ¹³⁷Cs profiles, measurement of actual sedimentation rates using artificial grass sedimentation mats, and linking this information to the present‐day hydrological behaviour of the river. The sedimentation mats showed that floodplain sedimentation was restricted to peak flows of considerable magnitude. Due to the reforestation, the return period of such high flows increased from 0·31 year in the period 1960–1985 to 0·81 year between 1986 and 2003, with commensurate changes in sedimentation rates. At the 1·5 m river terrace (formed about 60 years ago), ¹³⁷Cs‐based sedimentation rates (1960–1986) were roughly twice the rates inferred from the artificial grass mats (2001–2003). This finding matches the increase in the return period for larger peak events during the 1986–2003 period, which caused fewer major inundations at this level. Conversely, sedimentation rates determined for the lowest terrace at 0·5 m were similar for both techniques (and periods) because the return periods of the peak events responsible for sediment deposition at this lower level did not change much over the period 1986–2003. Copyright © 2006 John Wiley & Sons, Ltd.     

Benthic invertebrate assemblages and functional feeding groups in the Paraná River floodplain (Argentina)

The benthic invertebrate assemblages and functional feeding groups in different mesohabitats of the Middle Paraná River–floodplain system were analyzed. Benthic invertebrates and bottom sediments were sampled in a secondary channel (center and bank mesohabitats), a temporal marginal fluvial wetland adjacent to the river, an isolated lake and a connected lake during low water level. Cluster analysis of average invertebrate densities based on the Bray Curtis dissimilarity index yielded a group composed by the mesohabitats with higher species richness, the floodplain lakes, banks mesohabitats and the wetland. The center mesohabitat of the main channel characterized by sandy sediments with low organic matter content and the lowest invertebrate densities and species richness was classified separately. Alpha diversity increased from the center mesohabitat (6 taxa) to the adjacent wetland (71 taxa), and were similar between the floodplain lakes (24 and 22 taxa) and the river bank mesohabitat (24 taxa). Gamma and beta diversities (Whittaker index) were 92 and 2.19, respectively. The highest turnover of taxa was between the river and the other mesohabitats and the lowest between floodplain lakes. Detrended correspondence analysis (DCA) showed a clear separation of wetland and banks from other mesohabitats (axis 1 and 2 explained 52.25% variance) explained by shredders and collector-filterers. The other mesohabitats were arranged in a gradient from the main channel mostly related to collector-gatherers to the connected lake and the isolated lake that were mostly characterized by predators and scrapers. The invertebrate assemblage complexity and functional feeding groups composition increased in the lateral dimension, from the center of the main channel to the temporal marginal fluvial wetland due to the influences of the spatial heterogeneity caused by different sources of organic matter inputs.     

Physical model experiments for sediment supply to the old Rhine through induced bank erosion

A mobile-bed, undistorted physical model （1：40） has been used to investigate different sediment supply strategies to the Old Rhine through bank protection removal and modifications of groyne dimensions and configuration, which cause bank erosion. This trained channel was previously the main bed of the upper Rhine downstream of Basel （Switzerland）, but it has an artificially low flow regime since the construction of the Grand Canal d＇Alsace, a navigation canal, and a flow control dam at Kembs （France）. Training works and subsequent channel incision have also greatly reduced sediment transport rates and created a heavily armoured bed. The modelled pilot site has a groyne field on the left bank. Results show that the currently existing groynes at the site are not effective in creating high bank-side velocities conducive to bank erosion, even for flow rates significantly higher than the mean annual flow rate. The river bank has also proved to be more resistant than previously thought, allowing long stretches of bank protection to be safely removed. The physical model testing process has produced a new configuration for the groyne field, where two higher, larger island groynes are placed further apart than the three existing attached groynes. This innovative approach has proved effective, causing bank erosion for flow rates below the mean annual flow rate, with consistent erosion being observed. It has also been found that such a configuration does not pose a hazard for the Grand Canal d＇Alsace, which is situated next to the Old Rhine, through excessive bank erosion during high flow events.     

Recent increase of river–floodplain suspended sediment exchange in a reach of the lower Amazon River

We analyzed variation of channel–floodplain suspended sediment exchange along a 140 km reach of the lower Amazon River for two decades (1995–2014). Daily sediment fluxes were determined by combining measured and estimated surface sediment concentrations with river–floodplain water exchanges computed with a two‐dimensional hydraulic model. The average annual inflow to the floodplain was 4088 ± 2017 Gg yr^?1 and the outflow was 2251 ± 471 Gg yr^?1, respectively. Prediction of average sediment accretion rate was twice the estimate from a previous study of this same reach and more than an order of magnitude lower than an estimate from an earlier regional scale study. The amount of water routed through the floodplain, which is sensitive to levee topography and increases exponentially with river discharge, was the main factor controlling the variation in total annual sediment inflow. Besides floodplain routing, the total annual sediment export depended on the increase in sediment concentration in lakes during floodplain drainage. The recent increasing amplitude of the Amazon River annual flood over two decades has caused a substantial shift in water and sediment river–floodplain exchanges. In the second decade (2005–2014), as the frequency of extreme floods increased, annual sediment inflow increased by 81% and net storage increased by 317% in relation to the previous decade (1995–2004). Copyright © 2017 John Wiley & Sons, Ltd.     

Residence time of alluvium in an aggrading fluvial system

Relationships between the surface area and age of alluvial deposits were used to estimate the residence time of alluvium in the 2205 km² Waipaoa River basin, New Zealand. The contemporary Waipaoa River is an efficient transporter of sediment to the continental shelf, but the basin has been characterized by rapid channel and valley aggradation in the historic period, and by extensive mid‐ to late Holocene alluvial storage in the lower reaches. The area‐weighted mean age of alluvial deposits in the lower part of the river basin is ～4400 yr. These deposits comprise terrace remnants isolated by downcutting, and Holocene to Recent sediments that are potentially remobilizable by the modern river. Even though the amount of storage is small relative to downstream transport, the majority of the potentially remobilizable alluvium is likely to remain in storage for >100 yr, and its half‐life (time for 50 per cent removal) is >2000 yr. Within the confines of the flfloodplain, the apparent ‘loss’ of older deposits is due primarily to burial, but losses of the most recent deposits are due almost entirely to remobilization (30–40 per cent), with the remainder preserved in the alluvial record for at least 10⁴ yr. Most of this sediment is likely to remain in storage until there is a shift to a degradational state. Copyright © 2006 John Wiley & Sons, Ltd.     

Elevated sedimentation in lake records linked to agricultural activities in the Ishikari River floodplain,northern Japan

The purpose of this study was to examine the historical change in sedimentation rates in lakes that have been impacted by river regulation and agricultural activities in the Ishikari River floodplain. We dated sediment cores using caesium‐137 (¹³⁷Cs) dating and tephrochronology, and we estimated sediment sources from ¹³⁷Cs concentrations in the topsoil of representative land covers. We found that, between 1739 and 1963, the distance between the lake and the main river channel and whether or not the lake was connected to the river affected the sedimentation rates. After 1963, agricultural drainage systems were established in the Ishikari River floodplain. The average sedimentation rate before and after the construction of drainage ditches varied between 1–66 and 87–301 mg cm^–2 a^–1, respectively. The increase in the sedimentation rate after 1963 was caused by the construction of a number of drainage networks, as well as extensive cultivation activity and/or fragmentation of the swamp buffers surrounding the lakes. The ¹³⁷Cs activities at the surfaces of the lake as well as the catchment‐derived ¹³⁷Cs contributions and ¹³⁷Cs inventory in the lake profiles were used to examine the sediment influx from the various drainage areas after the establishment of the drainage system. Our results indicate that the majority of the lake sediments were derived from cultivated areas, and therefore the catchment‐derived ¹³⁷Cs contribution in the lakes was strongly correlated with the sedimentation rate. The ¹³⁷Cs inventory across all of the lake profiles was also significantly greater than the atmospheric fallout. We identified a negative correlation between the ¹³⁷Cs lake profile inventory and the sedimentation rate. This is because the sediment originating from the drainage areas contained low ¹³⁷Cs concentrations, which diluted the overall concentration of ¹³⁷Cs in the lake sediment. Copyright © 2009 John Wiley & Sons, Ltd.     

Optimum configuration of groynes for stabilization of alluvial rivers with fine sediments

Severe bank erosion at lowland rivers in Bangladesh devours vast tract of lands and renders thousands of people homeless at high flood; also,rapid deposition changes bed topographies and seriously redu...     

Contribution to understanding the historical evolution of meandering rivers using dendrochronological methods: example of the Mała Panew River in southern Poland

The Ma?a Panew is a meandering river that flows 20 km through a closed forest. During times of high discharge the riverbed and floodplain are transformed under the influence of riparian trees. The changes provide the opportunity to measure the intensity of erosion and sediment accumulation based on tree ages, the dating of coarse woody debris (CWD) in the riverbed, and the dating of eccentric growth of tilting trees and exposed roots. The bed and floodplain in reaches of the Ma?a Panew River with low banks were greatly altered as a result of long periods of flooding between 1960 and 1975. Banks were undercut during these floods and black alders tilted. Those parts of alder crowns or stems which tilt and sink generate small sand shadows. When erosion is intensive alder clumps are undercut from concave banks and become mid‐channel islands, while on the other side of the channel meandering bar levels are created. The reaches with higher banks were altered by large floods, especially in 1985 and 1997. The concave banks are undercut and sediment with CWD is deposited within the riverbed, forming sand shadows behind the CWD. Copyright © 2006 John Wiley & Sons, Ltd.     

Trace metals distribution pattern in floodplain sediments of a lowland river in relation to contemporary valley bottom morphodynamics

The distribution of trace metals in alluvial sediments depends on their natural background concentrations, and on the dynamics of contemporary depositional and erosional (mainly flood‐induced) processes. Geological and geochemical investigations were carried out in the valley of Vistula River near Magnuszew (central Poland). Sediment samples were collected from a depth of 35 cm and comprise sediments of all defined geomorphological features. Identification and geological interpretation of the morphodynamic sediment features was supported by aerial photographs and high‐resolution satellite images. These studies revealed that the distribution of trace metals is closely linked to the morphogenesis of the alluvial floodplain. The highest concentrations of Cu, Co, Zn, V, Cr and Ni were observed in crevasse‐splays deposits. By contrast, Sr, Pb and As were concentrated in deposits which fill oxbow lakes (partly infilled with organic deposits). The lowest concentrations of trace metals were detected in flood sediments deposited within erosional troughs. The geomorphological and sedimentological history of the fluvial features explains the pattern of heavy metal distribution on the current floodplain surface. Copyright © 2014 John Wiley & Sons, Ltd.     

137Cs湖泊沉积年代学方法应用的局限——以Crawford湖为例

＾１３７Ｃｓ湖泊沉积年代学方法是测定现代湖泊沉积物沉积年代和沉积速率的重要同位素年代学方法之一。对加拿大Ｃｒａｗｆｏｒｄ湖采集的沉积孔柱内＾１３７Ｃｓ垂直分布的研究发现,该方法给出时的标有明显偏差。比较＾２１０Ｐｂ和纹层等年代方法的结果,其１９６３年时标蓄积峰值所在位置明显移向表层,而作为１９５４年时标的该核素出现蓄积的层位则远早于该年沉积物蓄积层位。研究还表明,孔柱中较高的间隙水含量、缺少足以吸     

Modern (<100 years) sedimentation in the Taiwan Strait: Rates and source-to-sink pathways elucidated from radionuclides and particle size distribution

A large number of sediment cores collected during 2005-2010 from the Taiwan Strait were analyzed for radionuclides (²¹⁰Pb, ¹³⁷Cs and ⁷Be) to elucidate sedimentation dynamics in this all-important gateway linking two largest marginal seas in the western Pacific (namely, the South China Sea and the East China Sea). Apparent sediment accumulation rates derived from ²¹⁰Pb and ¹³⁷Cs profiles vary from <0.1 to >2 cm/yr, averaging ∼0.4 cm/yr and showing a spatial pattern closely related to hydrodynamics and sediment source-to-sink pathways. Spatial-temporal variation of ⁷Be activity in surface sediments off Taiwan’s west coast indicates episodic deposition of flood layers and their mobility from river estuaries toward the north. In conjunction with particle size distribution in surface sediments and the structure of sediment strata revealed by sub-bottom echo images; the radionuclide data can be used to outline three different sediment source-to-sink dispersal systems. Based on sediment loads of surrounding rivers and the distribution of sediment accumulation rates, lateral transport is required to account for the budget and size distribution of sediments in the strait.     

The role of vegetation in the retention of fine sediment and associated metal contaminants in London's rivers

Many urban rivers receive significant inputs of metal‐contaminated sediments from their catchments. Restoration of urban rivers often creates increased slack water areas and in‐channel vegetation growth where these metal‐contaminated sediments may accumulate. Quantifying the accumulation and retention of these sediments by in‐channel vegetation in urban rivers is of importance in terms of the planning and management of urban river restoration schemes and compliance with the Water Framework Directive. This paper investigates sediment properties at four sites across three rivers within Greater London to assess the degree to which contaminated sediments are being retained. Within paired restored and unrestored reaches at each site, four different bed sediment patch types (exposed unvegetated gravel, sand, and silt/clay (termed ‘fine’) sediments, and in‐channel vegetated sediments) were sampled and analysed for a range of metals and sediment characteristics. Many samples were found to exceed Environment Agency guidelines for copper (Cu), lead (Pb) and zinc (Zn) and Dutch Intervention Values for Cu and Zn. At all sites, sediments accumulating around in‐channel vegetation were similar in calibre and composition to exposed unvegetated fine sediments. Both bed sediment types contained high concentrations of pseudo‐total and acetic acid extractable metal concentrations, potentially due to elevated organic matter and silt/clay content, as these are important sorbtion phases for metals. This implies that the changed sediment supply and hydraulic conditions associated with river restoration may lead to enhanced retention of contaminated fine sediments, particularly around emergent plants, frequently leading to the development of submerged and emergent landforms and potential river channel adjustments. High pseudo‐total metal concentrations were also found in gravel bed sediments, probably associated with iron (Fe) and manganese (Mn) oxyhydroxides and discrete anthropogenic metal‐rich particles. These results highlight the importance of understanding the potential effects of urban river restoration upon sediment availability and channel hydraulics and consequent impacts upon sediment contaminant dynamics and storage. Copyright © 2014 John Wiley & Sons, Ltd.     

Heavy metals in surface sediments from nine estuaries along the coast of Bohai Bay,Northern China

Concentrations of heavy metals in river water and sediment were investigated in nine estuaries along the coast of Bohai Bay, Northern China. Multivariate statistical techniques such as principal component analysis and cluster analysis, in combination with metal concentration analysis and correlation analysis, were used to identify the possible sources of the metals and the pollution pattern in nine estuaries along the coast of Bohai Bay. The environmental risks of metals, evaluated by sediment quality guidelines and background values, revealed Hg contamination in the estuaries. However, levels of Cd in estuarine sediments were low, and they were less than those levels in river sediments, partly due to the high mobility and dilution of river or seawater. Cd did not contribute to sediment deposits in estuaries. High organic matter from effluents from large municipal sewage treatment plants was predominantly responsible for restricting Hg mobility from the river to Bohai Bay.