A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.     

Low impact surface hardness testing (Equotip) on porous surfaces – advances in methodology with implications for rock weathering and stone deterioration research

The Equotip surface hardness tester is becoming a popular method for rock and stone weathering research. In order to improve the reliability of Equotip for on‐site application this study tested four porous limestones under laboratory conditions. The range of stone porosity was chosen to represent likely porosities found in weathered limestones in the field. We consider several key issues: (i) its suitability for soft and porous stones; (ii) the type of probe required for specific on‐site applications; (iii) appropriate (non‐parametrical) statistical methods for Equotip data; (iv) sufficient sampling size. This study shows that the Equotip is suitable for soft and porous rock and stone. From the two tested probes the DL probe has some advantages over the D probe as it correlates slightly better with open porosity and allows for more controlled sampling in recessed areas and rough or curved areas. We show that appropriate sampling sizes and robust non‐parametric methods for subsequent data evaluation can produce meaningful measures of rock surface hardness derived from the Equotip. The novel Hybrid dynamic hardness, a combination of two measuring procedures [single impact method (SIM) and repeated impact method (RIM)], has been adapted and is based on median values to provide a more robust data evaluation. For the tested stones in this study we propose a sample size of 45 readings (for a confidence level of 95%). This approach can certainly be transferred to stone and rock with similar porosities and hardness. Our approach also allows for consistent comparisons to be made across a wide variety of studies in the fields of rock weathering and stone deterioration research. Copyright © 2016 John Wiley & Sons, Ltd.     

The effect of rock moisture on Schmidt hammer rebound: tests on rock samples from Marion Island and South Africa

In an assessment of the influence of internal rock moisture content on Schmidt hammer readings, rebound (R) values are found to decrease with increasing moisture content. For samples of basalt, sandstone and dolerite the maximum decrease in R‐values is found between oven dry values and saturated rock rebound values, the magnitude of which varies from 2 to 10 points on the R‐scale. A quartzite block has the greatest decline of 6 points at 60 per cent saturation. For certain rock types under differing site‐to‐site field moisture conditions the moisture effect can be a significant factor in the interpretation of the relative state of weathering from rebound values. Copyright © 2002 John Wiley & Sons, Ltd.     

Use of the Acoustic Energy Meter (AEM) for rapid geomorphological field assessment of rock hardness: comparison with Schmidt hammer R‐value

Rapid, field‐based assessments of rock hardness are required in a broad range of geomorphological investigations where rock intact strength is important. Several different methods are now available for taking such measurements, in particular the Schmidt hammer, which has seen increasing use in geomorphology in recent decades. This is despite caution from within the engineering literature regarding choice of Schmidt hammer type, normalization of rebound (R‐) values, surface micro‐roughness, weathering degree and moisture content, and data reduction/analysis procedures. We present a pilot study of the use of an Acoustic Energy Meter (AEM), originally produced, tested and developed within the field of underground mining engineering as a rapid measure of rock surface hardness, and compare it with results from a mechanical N‐Type Schmidt hammer. We assess its capabilities across six lithological study sites in southeast Queensland, Australia, in the Greater Brisbane area. Each rock exposure has been recently exposed in the 20th/21st century. Using a ‘paired’ sampling approach, the AEM G‐value shows an inverse relationship with Schmidt hammer R‐value. While both devices show variability with lithology, the AEM G‐values show less scatter than the Schmidt hammer. We conclude that each device can contribute to useful rock hardness testing in geomorphological research, but the AEM requires further field testing in a range of environments, and in particular on older and naturally‐exposed rock surfaces. Future evaluations can extend this pilot study by focusing on sampling procedures, energy sources, and data reduction protocols, within the framework of a comparison study with other rock hardness testing apparatus. Copyright © 2016 John Wiley & Sons, Ltd.     

The role of rock surface hardness and internal moisture in tafoni development in sandstone

The development of cavernous weathering features such as tafoni remains poorly understood. In particular, the roles played by internal moisture and case hardening remain unclear. In this study, Electric Resistivity Tomography (ERT) has been used to map moisture distribution within inner walls of tafoni developed in sandstone, and an Equotip device used to measure rock surface hardness as a proxy measure of the degree of weathering and case hardening. Seven large tafoni in the Golden Gate Highlands National Park (South Africa), varying in size and degree of development have been monitored. A dynamic relationship between surface hardness, degree of weathering and internal moisture regimes has been found. We propose a new conceptual model which illustrates the complex interaction between case hardening and internal moisture and suggests a new direction for cavernous weathering research. Copyright © 2011 John Wiley & Sons, Ltd.     

Field estimate of paleoseismic slip on a normal fault using the Schmidt hammer and terrestrial LiDAR: Methods and application to the Hebgen fault (Montana,USA)

The weathering characteristics of bedrock fault scarps provide relative age constraints that can be used to determine fault displacements. Here, we report Schmidt hammer rebound values (R‐values) for a limestone fault scarp that was last exposed in the 1959 Mw 7.3 Hebgen Lake, Montana earthquake. Results show that some R‐value indices, related to the difference between minimum and maximum R‐values in repeated impacts at a point, increase upward along the scarp, which we propose is due to progressive exposure of the scarp in earthquakes. An objective method is developed for fitting slip histories to the Schmidt hammer data and produces the best model fit (using the Bayesian Information Criterion) of three earthquakes with single event displacements of ≥ 1.20 m, 3.75 m, and c. 4.80 m. The same fitting method is also applied to new terrestrial LiDAR data of the scarp, though the LiDAR results may be more influenced by macro‐scale structure of the outcrop than by differential weathering. We suggest the use of this fitting procedure to define single event displacements on other bedrock fault scarps using other dating techniques. Our preliminary findings demonstrate that the Schmidt hammer, combined with other methods, may provide useful constraints on single event displacements on exposed bedrock fault scarps. Copyright © 2018 John Wiley & Sons, Ltd.     

Laboratory simulation of salt weathering under moderate ageing conditions: Implications for the deterioration of sandstone heritage in temperate climates

Salt weathering is a significant process affecting the deterioration and conservation of stone-built heritage in many locations and environments. While much research has focused on the impact of salt weathering under arid or coastal conditions with characteristic climatic conditions and salt types, many sites found to be experiencing salt-induced deterioration, such as sandstone rock-hewn cave temples in Gansu Province, China and sandstone buildings in the northern UK, experience high humidities, moderate temperature ranges, and different salt types. To evaluate the impact of salt weathering on sandstone-built heritage under such mild humid environmental conditions, a lab simulation experiment was designed. The experiment was carried out on three types of sandstone (used in the northern UK and Gansu Province, China) and utilized a realistic diurnal humidity and temperature cycle (85% RH/16°C + 60% RH/22°C), and three widespread damaging salts, that is, Na₂SO₄, MgSO₄, and the mixture of Na₂SO₄–MgSO₄. The nature and extent of deterioration was monitored by photography, weight loss, and the changes in petrophysical properties measured using hardness, ultrasonic pulse velocity (P-wave velocity), water absorption coefficient by capillarity, open porosity, and apparent density. All three sandstones were found to be susceptible to MgSO₄ and the mixture of Na₂SO₄–MgSO₄, but weakly affected by Na₂SO₄ under mild humid environmental conditions.     

Early diagenetic growth of carbonate concretions in the upper Doushantuo Formation in South China and their significance for the assessment of hydrocarbon source rock

Mineralogical and textural characteristics and organic carbon composition of the carbonate concretions from the upper Doushantuo Formation (ca. 551 Ma) in the eastern Yangtze Gorge area reveal their early diagenetic (shallow) growth in organic-rich shale. High organic carbon content (up to 10%) and abundance of framboidal pyrites in the hosting shale suggest an anoxic or euxinic depositional environment. Well-preserved cardhouse clay fabrics in the concretions suggest their formation at 0-3 m burial depth, likely associated with microbial decomposition of organic matter and anaerobic oxidation of methane. Gases through decomposition of organic matter and/or from methanogenesis created bubbles and cavities, and anaerobic methane oxidation at the sulfate reduction zone resulted in carbonate precipitation, filling in bubbles and cavities to form spherical structures of the concretions. Rock pyrolysis analyses show that the carbonate concretions have lower total organic carbon (TOC) content but higher effective carbon than those in the host rocks. This may be caused by enclosed organic matter in pores of the concretions so that organic matter was protected from further modification during deep burial and maintained high hydrocarbon generating potential even in over-matured source rock. As a microbialite sensu latu, concretions have special growth conditions and may provide important information on the microbial activities in depositional and early burial environments.     

The role of eddies in solute transport and recovery in rock fractures: Implication for groundwater remediation

A better understanding of solute transport and retention mechanism in rock fractures has been challenging due to difficulty in their direct observations in microscale rough‐walled fractures. Six representative troughs in a rough‐walled fracture were selected for microscale observations of eddy formation with increasing flow velocity and its effect on spatiotemporal changes of solute concentration. This experimental study was enabled by a microscale visualization technique of micro particle image velocimetry. With increasing flow velocity (Re ≤ 2.86), no eddies were generated, and solutes along the main streamlines transported rapidly, whereas those near the wall moved slowly. A larger amount of solutes remained trapped at all troughs at Re = 2.86 than Re < 1. For Re = 8.57, weak eddies started to be developed at the troughs on the lee side, which little contributed to overall solute flushing in the fracture. Accordingly, a large of amount of water was needed for solute flushing. The flow condition of 1 < Re < 10, before a full development of eddies, was least favourable in terms of time and amount of remediation fluid required to reach a target concentration. After large eddies were fully developed at troughs on the lee side for Re = 17.13, solutes were substantially reduced by eddies with less amount of water. Fully developed eddies were found to enhance solute transport and recovery, as opposed to a general consensus that eddies trap and delay solutes. Direct inflow into troughs on the stoss side also made a great contribution to solute flushing out of the troughs. This study indicates that fully developed eddies or strong inflows at troughs are highly possible to form for Re > 10 and this flow range could be favourable for efficient remediation.     

Petrography and geochemistry of upper Triassic sandstones from the Tumengela Formation in the Woruo Mountain area,North Qiangtang Basin,Tibet: Implications for provenance,source area weathering,and tectonic setting

The petrography and major and trace element concentrations of the sandstones from the Tumengela Formation in the Woruo Mountain area, North Qiangtang Basin, are studied to determine their provenance, intensity of weathering and tectonic setting. The detrital compositions of the Tumengela sandstone samples are dominated by quartz (58.0–70.1 %, average 64.7 %) and lithic fragments (21.8–35.9 %, average 27.3 %), but low in feldspar content (4.9–12.9 %, average 8.0 %). The sandstones can be classified as litharenite and feldspathic litharenite according to their detrital compositions, which is consistent with the geochemical data. The detrital modal compositions reflect that these sandstones are probably derived from a recycled orogenic source. The index of chemical variability (ICV) and SiO₂/Al₂O₃ ratio values suggest that the compositional maturity and recycling were moderate. The weathering indices such as the chemical index of alteration (CIA), plagioclase index of alteration (PIA), chemical index of weathering (CIW), and Al₂O₃–(CaO* + Na₂O)–K₂O (A–CN–K) diagram indicate that the intensities of weathering in the source area were moderate. The Al₂O₃/TiO₂, Th/Co, La/Sc, La/Co, Th/Sc, Cr/Th ratio values and the discriminant function of the Tumengela sandstones indicate that the sediments were mainly derived from felsic source rocks, while also mixed with intermediate source rocks. The comparison of rare earth element patterns and its Eu anomalies to the probable source rocks infer that the sandstones were derived from the combination of granite, rhyolite, dacite, and gneisses. The proximal central uplift belt was probably the primary provenance area as evidenced by the petrographical and geochemical features of the Tumengela sandstones. The multidimensional tectonic discrimination diagram based on major elements show a collision setting (80 %) combined with a rift setting (20 %) for the Tumengela sandstones, which is consistent with the general geology of the study areas.     

The use of a portable fluxgate magnetometer for the estimation in the field of the direction and stability of remanent magnetization of rock specimens

Summary A portable magnetometer of the fluxgate type is described, which is capable of measuring in the field the direction and intensity of remanent magnetization of rock samples of 2 cm diameter with an accuracy of the order of 6° for intensities of 10^–3 emu/cc or more. The measurement and calculation can be carried out in less than five minutes, and a precision of the order of 2° can be obtained if more readings are taken so that ten minutes are required for a complete measurement. The chief limitation to the precision of measurement was found to be inhomogeneity of magnetization of the specimens. The instrument has been used to estimate stability of natural remanent magnetization where A.C. cleaning apparatus is not available, and the method of doing so is briefly described.Now with English Electric Computers.     

Changes in the early part of the seismic coda due to localized scatterers: The estimation ofQ in a stope environment

A single scattering model was used to analyse the temporary changes in the mean density of scattered waves in a discrete random medium. The model of the mean energy density, originally proposed bySato (1977) for spherical radiation and isotropic scattering, has been modified and applied to a medium in which the scatterers are confined to a specified volume. The time variation of the early part of the mean energy density function for the different source durations was investigated. The dominant effect on the theoretical mean energy density is caused by the specified volume containing scatterers. The duration of the source pulse influences the early part of the coda fort/t ₀<1.2, wheret is the lapse time measured from the source origin time, andt ₀is arrival time of the body wave.The analysis of the coda signal of micro-events occurring immediately in front of the face enables us to estimate the size of the fracture zone induced by the stope. The model of the mean energy density of coda for a medium containing scatterers close to the seismic source was used to analyse a large number of events recorded close to an advancing mine face in a deep level gold mine in South Africa. The coda decay rate has two trends: the first, with a steep decay of coda, is produced by a larger deviation of rock parameters and/or larger size of the scatterers; the second trend, which decays more slowly, has the corresponding mean-free path ranging from 20 m to 200 m. The analysis indicates that the rock mass about 15–20 m from the stope contains a large proportion of fractured and blocked rock, which is the source of scattering. The scattering of theS-wave was much stronger and more stable, with the mean-free path varying from 11 m to 45 m. This is due to the shorter wavelength of theS wave in comparison with theP wave. The quality factor for theP coda wave varies from 30 to 100 in the fracture zone of stope and outside this zone it has a value of 300. The quality factor of theS wave varies from 20 to 78 in the equivalent volume. For rock surrounding the stope the ratioQ _sp ^–1 /Q _ss ^–1 varied from 0.31 to 0.69. This suggests that the radii of scatterers are smaller than 3.5 m.     

The degree of trace metal pyritization in subtidal sediments of a mariculture area: application to the assessment of toxic risk

Four 2–3 m sediment cores were taken at the sites on the periphery of mussel raft concentrations in the subtidal zone of the inner Ría de Vigo (Galicia, NW Spain) with a view to evaluate the potential risk to mariculture from sediment-borne trace elements (As, Cd, Cr, Cu, Mn, Ni, Pb and Zn). The distribution of each of these elements in reactive, organic, pyrite and silicate-bound fractions was determined at 64 samples, and these data were used to calculate the degree of trace metal pyritization (DTMP) of each metal/metalloid. In the top 10–20 cm, relatively oxic conditions led to As, Cd, Cu, Pb and Zn having large reactive fractions due to their association with Fe and Mn oxyhydroxides. At lower levels, anoxic conditions favoured by intense diagenesis led to the precipitation of trace metals and metalloids as sulphides, with or without association with pyrite. Particularly large pyrite fractions in the 20–100 cm layer are attributed to the organic matter of this layer being more marine in origin than that of deeper sediments. DTMP was greatest for Cu and As, and least for Pb, Zn and Cr. The risk of trace element toxicity in the event of disturbances instituting oxic conditions in these sediments is discussed.     

Threshold level approach for streamflow drought analysis in the Central Andes of Argentina: a climatological assessment

A streamflow drought climatology was developed over the Central Andes of Argentina, a semi-arid region highly vulnerable to climatic variations, based on the analysis of daily historical streamflow records. A threshold level approach was applied on a daily basis for three different severity levels in order to depict the main characteristics of droughts – number of drought events, mean duration and mean severity – over the period 1957–2014. Based on three annual indices that summarize the frequency of drought events, their duration and severity, we identified the main regional dry periods and the main modes of variability through an empirical decomposition. These modes are linked to La Niña conditions on inter-annual time scales and the Pacific Decadal Oscillation for the decadal variations, showing the influence of the tropical Pacific Ocean in the development of streamflow drought conditions and its relevance for potential predictability of hydroclimatic variations over the region.     

The use of GIS and remote sensing for the assessment of waterlogging in the dryland irrigated catchments of Farafra Oasis,Egypt

This paper investigates the interplay of the hydrogeological characteristics, soil properties and recent land reclamation projects on the distribution of waterlogging and salinization within the Farafra Oasis. The multi‐temporal remote sensing data and field observations show that new reclaimed areas have been recently cultivated in distant areas from the old agricultural land. These new cultivations have developed widespread waterlogging, seepage channels and soil salinization. Analyses of the Shuttle Radar Topography Mission digital elevation model (DEM) showed that both old and new agricultural areas are located within same closed drainage basin. The fluvial channels of these catchments, which were developed during wet climatic pluvial, have largely been obliterated by the prevailing aridity and often buried under aeolian deposits. However, the new cultivations have been developed on the fingertips of these fluvial channels, while the old fields occupy the low‐level playas. The soil of the new cultivated areas is mainly lithic with a high calcium carbonate content, thus limiting the downward percolation of excess irrigation water and therefore developing perched water table and seepage through the palaeo‐channels. The automatically extracted drainage networks from DEM resemble fluvial patterns and coincide with the seepage channels slowly heading toward old cultivation. The inactive alluvial channels and landforms have to be considered when planning for new cultivation in dryland catchments to better control waterlogging and salinization hazard. It is highly recommended that newly developed seepage channels have to be detected and intercepted before reaching old agriculture areas. Therefore, the ‘dry‐drainage’ concept can be implemented as the seepage water can be conveyed into nearby playas reserved for evaporation. Copyright © 2012 John Wiley & Sons, Ltd.     

湖沼学是研究内陆水体的多学科整合科学——兼论我国湖沼学发展面临的挑战与机遇

湖沼学是研究内陆水体的多学科交叉综合性科学,自从Forel F.A.于1892年首次对湖沼学做出定义以来已有近130年历史.湖沼学的主要分支学科包括地质湖沼学(包括古湖沼学)、物理湖沼学、化学(生物地球化学)湖沼学和生物湖沼学.湖沼学的关键自然属性是通过跨学科的整合,从水生态系统水平综合分析相关过程与机理,并对生态系统变化进行预测.因此,湖泊学也是支撑水资源与生态系统保护、管理与修复的核心科学.然而,目前我国湖沼学发展面临分支学科发展不平衡、研究碎片化等问题,而人类活动加剧和气候变化对内陆水体生态系统的影响及管理对策是湖沼学研究面临的挑战与机遇.我国湖沼学研究亟需围绕人类活动、气候变化的影响,重点开展以下几个方面的工作:1)水动力与水文地貌特征变化及其环境生态效应; 2)营养盐和有机质生物地球化学循环及其环境生态效应; 3)食物网结构与功能; 4)外来入侵物种的影响与控制对策; 5)与水环境有关的传染病防治; 6)地表水生态评价; 7)生态系统演变机理与退化生态系统修复等.     

The use of a spatially heterogeneous simulation model for studying biotransformation processes of nitrogen and phosphorus compounds and the dynamics of oxygen dissolved in water in the ecosystem of Neva Bay, the Gulf of Finland: 2. Input data for calculations, modeling results, and their analysis

The data collected for model calculations is systematized for natural and design conditions. The natural conditions did not take into account the effect of the complex of water-protection structures on the hydrological regime of Neva Bay and on the biogenic load onto this water area, while the design conditions, conversely, reflected the possible impact of those structures on the hydrology and ecology of the area. Numerical experiments were used to study the processes of transformation of N and P compounds and the dynamics of dissolved O₂ in Neva Bay water area. In the comparison of the calculated and observed concentrations of biogenic substances, Theil criterion was evaluated to assess the adequacy of the model in reproducing the concentration fields of the distribution of biogenic substances over Neva Bay water area. The major qualitative and quantitative features of the formation of the spatial heterogeneity and the time variations in the concentrations of biogenic element compounds over Neva Bay water area are identified. Possible improvements of the model in the reproduction of the complex of processes that are of particular importance for the development of substance transformations in shallow ecosystems are considered.     

The glutathione antioxidant system as a biomarker suite for the assessment of heavy metal exposure and effect in the grey mangrove, Avicennia marina (Forsk.) Vierh

Alterations in the glutathione antioxidant system and lipid peroxidation in Avicennia marina were studied under laboratory and field conditions. The activity of glutathione peroxidase (GPx) was found to respond to Zn exposure, and a significant positive relationship between leaf Zn concentration and GPx activity was observed after 96 h and 8 weeks. Lipid hydroperoxides increased proportionally with increasing leaf Zn concentration after 2 and 8 weeks, while no changes in total glutathione were observed. Induction of GPx at 96 h predicted effects at the individual level at a later time interval (reduced biomass at 8 weeks). Results from the field revealed that increasing leaf metal concentration (Zn, Cu or Pb) produced a proportional increase in GPx activity whereas lipid hydroperoxides and total glutathione were not affected. The utility of GPx as an early warning biomarker is suggested, since GPx activity increases in a dose-dependant fashion in response to accumulated leaf metals, and is predictive of later effects on growth.     

The EU Directive on port reception facilities for ship-generated waste and cargo residues: the results of a second survey on the provision and uptake of facilities in North Sea ports

The aim of this paper is to evaluate the results of a survey of the availability and uptake of port reception facilities within the North Sea area. The evaluation is based primarily on original survey data from the autumn of 2002 which followed on from a similar survey conducted in the summer of 2000. The EU Directive on port reception facilities for ship-generated waste etc. (Directive 2000/59/EC) was due to enter into force in December 2002, and required all EU ports to provide reception facilities to meet the needs of the vessels normally calling in at them. This paper examines the readiness of North Sea ports to meet that requirement and also considers the actual uptake levels of facilities, where ports were able to provide such information.