Geochemistry of the lunar highlands

The principal rock types in the highlands are highland basalt (gabbroic anorthosite) with 28% Al₂O₃ and low K Fra Mauro basalt with 18% Al₂O₃. The chemistry of the highland soils and breccias can be represented by simple mixing models involving these rock types as major constituents. The mixing occurred during the intense highland cratering. Layering observed at the Apennine Front is interpreted as produced the Serenitatis basin collision. The plains-forming Cayley Formation and the Descartes Formation are not volcanic, but are derived from pre-existing highland crust.Although the overall chemical composition of the Moon has been affected by pre-accretion processes (e.g. loss of volatile elements), the composition of the highlands is mainly the result of postaccretion melting and element fractionation. Thus the individual rock types show involatile element distribution patterns, relative to primitive abundances, indicative of solid-liquid equilibria, evidence of post-accretion lunar igneous activity.The chemistry of the primitive green glass component (15426) indicates that the abundance of the involatile elements (REE, Ba, Zr, Hf, Th and U) in the source regions is at most only 2–3 times the abundances in chondrites.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Petrography and geochemistry of five new Apollo 16 mare basalts and evidence for post‐basin deposition of basaltic material at the site

Abstract— We present the petrography and geochemistry of five 2–4 mm basalt fragments from the Apollo 16 regolith. These fragments are 1) a high‐Ti vitrophyric basalt compositionally similar to Apollo 17 high‐Ti mare basalts, 2) a very high‐Ti vitrophyric basalt compositionally similar to Apollos 12 and 14 red‐black pyroclastic glass, 3) a coarsely crystalline high‐Al basalt compositionally similar to group 5 Apollo 14 high‐Al mare basalts, 4) a very low‐Ti (VLT) crystalline basalt compositionally similar to Luna 24 VLT basalts, and 5) a VLT basaltic glass fragment compositionally similar to Apollo 17 VLT basalts. High‐Ti basalt has been reported previously at the Apollo 16 site; the other basalt types have not been reported previously. As there are no known cryptomaria or pyroclastic deposits in the highlands near the Apollo 16 site (ruling out a local origin), and scant evidence for basaltic material in the Apollo 16 ancient regolith breccias or Apollo 16 soils collected near North Ray Crater (ruling out a basin ejecta origin), we infer that the basaltic material in the Apollo 16 regolith originated in maria near the Apollo 16 site and was transported laterally to the site by small‐ to medium‐sized post‐basin impacts. On the basis of TiO₂ concentrations derived from the Clementine UVVIS data, Mare Tranquillitatis (?300 km north) is the most likely source for the high‐Ti basaltic material at the Apollo 16 site (craters Ross, Arago, Dionysius, Maskelyne, Moltke, Sosigenes, Schmidt), Mare Nectaris/Sinus Asperitatis (?220 km east) is the most likely source for the low‐Ti and VLT basaltic material (craters Theophilus, Madler, Torricelli), and a large regional pyroclastic deposit near Mare Vaporum (?600 km northwest) is the most likely source region for pyroclastic material (although no source craters are apparent in the region).     

The Chandrayaan-1 X-ray Spectrometer: First results

We present X-ray fluorescence observations of the lunar surface, made by the Chandrayaan-1 X-ray Spectrometer during two solar flare events early in the mission (12th December 2008 and 10th January 2009). Modelling of the X-ray spectra with an abundance algorithm allows quantitative estimates of the MgO/SiO₂ and Al₂O₃/SiO₂ ratios to be made for the two regions, which are in mainly basaltic areas of the lunar nearside. One of these ground tracks includes the Apollo 14 landing site on the Fra Mauro Formation. Within the 1σ errors provided, the results are inside the range of basaltic samples from the Apollo and Luna collections. The Apollo 14 soil composition is in agreement with the results from the January flare at the 1σ uncertainty level. Discrepancies are observed between our results and compositions derived for the same areas by the Lunar Prospector gamma-ray spectrometer; some possible reasons for this are discussed.     

Remote sensing and geological studies of the Hadley‐Apennine region of the Moon

Abstract— We have used data from the Clementine and Lunar Prospector spacecraft in conjunction with reflectance spectra collected with Earth‐based telescopes to study the geology of the Hadley‐Apennine portion of the lunar Imbrium basin. The Apennine Mountains and the Imbrium backslope are composed of Imbrium basin ejecta with a noritic or anorthositic norite composition. We find that the two major facies of Imbrium ejecta, the Apenninus material and the Alpes Formation, differ in iron and titanium content. “Pure” anorthosite has tentatively been identified in the ejecta of the crater Conon, based on low‐iron content. A difference in Th and rare earth element (REE) abundance between the northeast Apennine Mountains (lower) and the southwest Apennines (higher) is noted. Pyroclastic deposits are common in the region and are dominated by mare basalt material, probably plug rock ejected in vulcanian eruptions. The Apennine Bench Formation, which is likely to be a deposit of non‐mare volcanic material, has an Fe, Ti and Th composition consistent with that of Apollo 15 KREEP basalt samples thought to be fragments of the Bench. Aristillus crater is a Th and REE hot spot, and the stratigraphy of the impact target site has been reconstructed from knowledge of the composition of the crater interior and exterior deposits. We infer that the target consisted of highland basement, KREEP plutonics and volcanics, and both high‐ and low‐Ti mare basalt.     

An integrated approach to understanding Apollo 16 impact glasses: Chemistry,isotopes, and shape

Abstract The major‐ and minor‐element abundances were determined by electron microprobe in 1039 glasses from regoliths and regolith breccias to define the compositional topology of lunar glasses at the Apollo 16 landing site in the central highlands of the Moon. While impact glasses with chemical compositions similar to local materials (i.e., Apollo 16 rocks and regoliths) are abundant, glasses with exotic compositions (i.e., transported from other areas of the Moon) account for up to ?30% of the population. A higher proportion of compositionally exotic, angular glass fragments exists when compared to compositionally exotic glass spherules. Ratios of non‐volatile lithophile elements (i.e., Al, Ti, Mg) have been used to constrain the original source materials of the impact glasses. This approach is immune to the effects of open‐system losses of volatile elements (e.g., Si, Na, K). Four impact glasses from one compositionally exotic group (low‐Mg high‐K Fra Mauro; lmHKFM) were selected for ⁴⁰Ar/³⁹ Ar dating. The individual fragments of lmHKFM glass all yielded ages of ?3750 ± 50 Ma for the time of the impact event. Based on the petrography of these individual glasses, we conclude that the likely age of the impact event that formed these 4 glasses, as well as the possible time of their ballistic arrival at the Apollo 16 site from a large and distant cratering event (perhaps in the Procellarum KREEP terrain) (Zeigler et al. 2004), is 3730 ± 40 Ma, close to the accepted age for Imbrium.     

The Mineralogy,petrology and geochemistry of lunar samples - a review

Crystallization from the molten state has been an important process for the formation of rocks on the Moon; the phenomenon of fractional crystallization is therefore discussed. The principal chemical and mineralogical features of the Apollo 11, 12 and 14 basaltic crystalline rocks are described, and an account is given of other rock types and minerals which are represented among the coarser particles in the lunar soils. A comparison is made between the chemical compositions (major, minor and trace element concentrations) of rocks and soils.Based upon the above data, one possible model for the outer shell of the Moon is presented, which consists of an outer layer of Al-rich rocks underlain by a layer which is more ferromagnesian in character. Partial melting of the latter was probably responsible for the extrusion of lavas at the surface which spread to form the basalts (Apollo 11 and 12) of the non-circular maria. The Apollo 14 (Fra Mauro) basalts are relatively enriched in potassium, rare earth elements, zirconium, phosphorus and certain other elements and may derive from partial melting of the more aluminous upper layer.The separation of the outer Moon into two layers could have occurred through gravity-aided fractional crystallization at an early stage (first few hundred m yr) in lunar history.Paper presented to the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 1971.     

Lunar regolith breccia Dhofar 287B: A record of lunar volcanism

Abstract— Dhofar 287 (Dho 287), a recently found lunar meteorite, consists in large part (95%) of low‐Ti mare basalt (Dho 287A) and a minor, attached portion (?5%) of regolith breccia (Dho 287B). The present study is directed mainly at the breccia portion of this meteorite. This breccia consists of a variety of lithic clasts and mineral fragments set in a fine‐grained matrix and minor impact melt. The majority of clasts and minerals appear to have been mainly derived from the low‐Ti basalt suite, similar to that of Dho 287A. Very low‐Ti (VLT) basalts are a minor lithology of the breccia. These are significantly lower in Mg# and slightly higher in Ti compared to Luna 24 and Apollo 17 VLT basalts. Picritic glasses constitute another minor component of the breccia and are compositionally similar to Apollo 15 green glasses. Dho 287B also contains abundant fragments of Mg‐rich pyroxene and anorthite‐rich plagioclase grains that are absent in the lithic clasts. Such fragments appear to have been derived from a coarse‐grained, Mg#‐rich, Na‐poor lithology. A KREEP component is apparent in chemistry, but no highlands lithologies were identified. The Dho 287 basaltic lithologies cannot be explained by near‐surface fractionation of a single parental magma. Instead, magma compositions are represented by a picritic glass; a low‐Ti, Na‐poor glass; and a low‐Ti, Na‐enriched source (similar to the Dho 287A parental melt). Compositional differences among parent melts could reflect inhomogeneity of the lunar mantle. Alternatively, the low‐Ti, Na‐poor, and Dho 287A parent melts could be of hybrid compositions, resulting from assimilation of KREEP by picritic magma. Thus, the Dho 287B breccia contains lithologies from multiple magmatic eruptions, which differed in composition, formational conditions, and cooling histories. Based on this study, the Dho 287 is inferred to have been ejected from a region located distal to highlands terrains, possibly from the western limb of the lunar nearside, dominated by mare basalts and KREEP‐rich lithologies.     

Apollo 12 ropy glasses revisited

Abstract— We analyzed ropy glasses from Apollo 12 soils 12032 and 12033 by a variety of techniques including SEM/EDX, electron microprobe analysis, INAA, and ³⁹Ar-⁴⁰Ar age dating. The ropy glasses have KREEP-like compositions different from those of local Apollo 12 mare soils; it is likely that the ropy glasses are of exotic origin. Mixing calculations indicate that the ropy glasses formed from a liquid enriched in KREEP and that the ropy glass liquid also contained a significant amount of mare material. The presence of solar Ar and a trace of regolith-derived glass within the ropy glasses are evidence that the ropy glasses contain a small regolith component Anorthosite and crystalline breccia (KREEP) clasts occur in some ropy glasses. We also found within these glasses clasts of felsite (fine-grained granitic fragments) very similar in texture and composition to the larger Apollo 12 felsites, which have a ³⁹Ar-⁴⁰Ar degassing age of 800 ± 15 Ma (Bogard et al, 1992). Measurements of ³⁹Ar-⁴⁰Ar in 12032 ropy glass indicate that it was degassed at the same time as the large felsite although the ropy glass was not completely degassed. The ropy glasses and felsites, therefore, probably came from the same source. Most early investigators suggested that the Apollo 12 ropy glasses were part of the ejecta deposited at the Apollo 12 site from the Copernicus impact Our new data reinforce this model. If these ropy glasses are from Copernicus, they provide new clues to the nature of the target material at the Copernicus she, a part of the Moon that has not been sampled directly.     

KREEPy lunar meteorite Dhofar 287A: A new lunar mare basalt

Abstract— Dhofar 287 (Dho 287) is a new lunar meteorite, found in Oman on January 14, 2001. The main portion of this meteorite (Dho 287A) consists of a mare basalt, while a smaller portion of breccia (Dho 287B) is attached on the side. Dho 287A is only the fourth crystalline mare basalt meteorite found on Earth to date and is the subject of the present study. The basalt consists mainly of phenocrysts of olivine and pyroxene set in a finer‐grained matrix, which is composed of elongated pyroxene and plagioclase crystals radiating from a common nucleii. The majority of olivine and pyroxene grains are zoned, from core to rim, in terms of Fe and Mg. Accessory minerals include ilmenite, chromite, ulvöspinel, troilite, and FeNi metal. Chromite is invariably mantled by ulvöspinel. This rock is unusually rich in late‐stage mesostasis, composed largely of fayalite, Si‐K‐Ba‐rich glass, fluorapatite, and whitlockite. In texture and mineralogy, Dho 287A is a low‐Ti mare basalt, with similarities to Apollo 12 (A‐12) and Apollo 15 (A‐15) basalts. However, all plagioclase is now present as maskelynite, and its composition is atypical for known low‐Ti mare basalts. The Fe to Mn ratios of olivine and pyroxene, the presence of FeNi metal, and the bulk‐rock oxygen isotopic ratios, along with several other petrological features, are evidence for the lunar origin for this meteorite. Whole‐rock composition further confirms the similarity of Dho 287A with A‐12 and A‐15 samples but requires possible KREEP assimilation to account for its rare‐earth‐element (REE) contents. Cooling‐rate estimates, based on Fo zonation in olivine, yield values of 0.2–0.8°C/hr for the lava, typical for the center of a 10–20 m thick flow. The recalculated major‐element concentrations, after removing 10–15% modal olivine, are comparable to typical A‐15 mare basalts. Crystallization modeling of the recalculated Dho 287A bulk‐composition yields a reasonable fit between predicted and observed mineral abundances and compositions.     

PETROLOGICAL CHARACTER OF THE LUNA 16 SAMPLE FROM MARE FECUNDITATIS

We have classified 1858 lithic and vitreous fragments from the Luna 16 core-tube sample. They were taken from the soil fractions ranging in size from 150 to 425 μ, at levels A and G (γ). No important differences are observed between the proportions of particle types in levels A and G, nor between the soils of Luna 16 and those from the Apollo 11 landing site in the nearby Mare Tranquillitatis. Luna 16 basalts are texturally and mineralogically similar to Apollo 11 basalts, though the former are characterized by more Fe-rich olivines and pyroxenes and by lower ilmenite contents than are Apollo 11 basalts. The atomic ratio Al/Ti in Luna 16 basalt pyroxenes in about 1.5; Apollo 11 basalt pyroxenes have Al/Ti = 2.0, indicating the possibility of a lower mean valence for Ti in the Luna 16 material than in the Apollo 11 material. Most light-colored lithic fragments are anorthositic rather than noritic in character and are comparable to Apollo 11 anorthosites in mineral chemistry. We believe they are samples of terra regions to the north of the Luna 16 landing site. Triangular diagrams plotting normative plagioclase, normative mafics plus oxides, and normative orthoclase plus apatite neatly separate the three major types of lunar materials — mare basalts, anorthosites, and noritic rocks — and reveal that the Luna 16 regolith is composed of mare basalt and anorthosite, with very little norite component. Colorless-to-greenish glass occurs in the Luna 16 sample, which has high Fe and low Ti; it may represent gabbroic rock related to the anorthosites     

Major and trace elements in igneous rocks from apollo 15

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

The case for an Imbrium origin of the Apollo thorium-rich impact-melt breccias

Abstract— Mafic, Th-rich impact-melt breccias, most of which are identified with the composition known as low-K Fra Mauro (LKFM), are the most common rock type in the nonmare regoliths of the Apollo lunar landing sites. The origin of mafic impact-melt breccias bears on many lunar problems: the nature of the late meteoroid bombardment (cataclysm); the spatial distribution of KREEP, both near the surface and at depth; the ages of the major basins; and the composition of the early crust of the nearside lunar highlands. Thus, it is crucial that the origin of mafic impact-melt breccias be accurately understood. Because of both intra- and intersite differences in compositions of mafic impact-melt breccia samples, apparent differences in crystallization age, and differences in siderophile-element ratios, previous studies have argued that either (1) most mafic impact-melt breccias are the products of several large craters local to the site at which they were found but that some are of basin origin or that (2) they are all from the Imbrium (Apollos 14 and 15), Nectaris (Apollo 16), and Serenitatis (Apollo 17) basins. Here, we reconsider the hypothesis that virtually all of the Th-rich, mafic impact-melt breccias from the Apollo missions are products of the Imbrium impact. Ejecta deposit modeling based on modern crater scaling indicates that the Imbrium event produced ejecta deposits that average hundreds of meters thick or more at all Apollo highland sites, which is thicker than some previous estimates. Substantial amounts of Imbrium ejecta should have been sampled at every Apollo highland site. We suggest that the mafic impact-melt breccias may be the principal form of those ejecta. The Imbrium projectile impacted into Th-rich material that we regard as part of a unique, mafic, lunar geochemical province we call the High-Th Oval Region. Based on the surface distribution of Th, only basins within the High-Th Oval Region excavated Th-rich material; the Th concentrations of the highlands as observed by the Apollo orbiting γ-ray experiments are consistent with the estimates from ejecta modeling. Of the younger basin-forming impacts, only Imbrium was large enough to produce the copious amount of melt required by the ubiquitous presence of mafic impact-melt breccias in the Apollo-sampled regolith. The High-Th Oval Region still may have been molten or hot at shallow depths ～4 Ga ago when the Imbrium projectile struck. We reason that compositional heterogeneity of ejected melt breccia is to be expected under these circumstances. We argue that siderophile-element “fingerprints” of mafic impact-melt breccias are not inconsistent with production of all common types by a single projectile. We suggest that the narrow range of ages of 3.7–4.0 Ga for all successfully dated mafic impact-melt breccias may reflect a single event whose age is difficult to measure precisely, rather than a number of discrete impact events closely spaced in time, such that reported age variations among mafic impact-melt breccias reflect the ability to measure ⁴⁰Ar/³⁹Ar ages with greater precision than the accuracy with which measured portions of mafic impact-melt breccias have recorded the time of their formation.     

The comparative behavior of apatite‐zircon U‐Pb systems in Apollo 14 breccias: Implications for the thermal history of the Fra Mauro Formation

Abstract— We report secondary ion mass spectrometry (SIMS) U‐Pb analyses of zircon and apatite from four breccia samples from the Apollo 14 landing site. The zircon and apatite grains occur as cogenetic minerals in lithic clasts in two of the breccias and as unrelated mineral clasts in the matrices of the other two. SIMS U‐Pb analyses show that the ages of zircon grains range from 4023 ± 24 Ma to 4342 ± 5 Ma, whereas all apatite grains define an isochron corresponding to an age of 3926 ± 3 Ma. The disparity in the ages of cogenetic apatite and zircon demonstrates that the apatite U‐Pb systems have been completely reset at 3926 ± 3 Ma, whereas the U‐Pb system of zircon has not been noticeably disturbed at this time. The apatite U‐Pb age is slightly older than the ages determined by other methods on Apollo 14 materials highlighting need to reconcile decay constants used for the U‐Pb, Ar‐Ar and Rb‐Sr systems. We interpret the apatite age as a time of formation of the Fra Mauro Formation. If the interpretation of this Formation as an Imbrium ejecta is correct, apatite also determines the timing of Imbrium impact. The contrast in the Pb loss behavior of apatite and zircon places constraints on the temperature history of the Apollo 14 breccias and we estimate, from the experimentally determined Pb diffusion constants and an approximation of the original depth of the excavated samples in the Fra Mauro Formation, that the breccias experienced an initial temperature of about 1300–1100 °C, but cooled within the first five to ten years.     

The source and origin of the exotic component and kreep-rich materials on the moon

Trace element concentrations in the lunar soils are inversely correlated to the grain size -i.e., the finer the grain size the higher the trace element content. These enrichments are attributed to the combined effects of comminution of local rocks and a preferential addition of the exotic component to the finer grain sizes. The exotic component appears similar to Fra Mauro materials and there is a strong correlation between the percentage of exotic component and distance from Fra Mauro site. Based on trace element characteristics, it is suggested that exotic component is finely comminuted KREEP and is dispersed on the lunar surface from the Fra Mauro and other high gamma-ray active regions in the Imbrium-Procellarum regions. The major and trace element chemistry of these materials is considered to be due to impact melting of trace-element-rich accessory phases followed by variable dilution with partial melts of the bulk solid phases of plagioclase, low Ca pyroxene and olivine. The generation of KREEP and exotic component is an impact produced local process and need not imply a global occurrence of radioactive crust on the Moon.     

Annealing of radiation damage in zircons from Apollo 14 impact breccia 14311: Implications for the thermal history of the breccia

Impact breccia 14311, was collected from the Apollo 14 landing site as a potential sample of the underlying Fra Mauro Formation. Published zircon U‐Pb ages of >4000 Ma date the source material of the breccia and the apatite U‐Pb age of ~3940 Ma is interpreted as dating thermal resetting of the apatite U‐Pb systems. In this contribution we present new age information on the late stage thermal history of the breccia based on the annealing of radiation damage in the zircons. From Raman spectroscopic determination of the radiation damage within SIMS analytical spots on the zircons and the U and Th concentrations determined on these spots, we demonstrate that the radiation damage in the zircons has been annealed and we estimate the age of annealing at 3410 ± 80 Ma. This age is interpreted as a cooling age following heating of the breccia to above the annealing temperature of ~230 °C for stage 1 radiation damage in zircon, but below the temperature needed to reset the U‐Pb system of apatite (~500 °C). It is proposed that this thermal event was associated with the prolonged period of Mare volcanism, from 3150 to 3750 Ma, that generated massive basalt flows in the vicinity of the sample location.     

The relationship between geology and geochemistry in the Undarum/Spumans/Balmer region of the Moon

A detailed study of geochemical variation in the Undarum/Spumans/Balmer region identifies major rock components which form the region's regolith. The northern portion of the region contains numerous small mare deposits, which cluster in the Undarum and Spumans areas particularly. In the southern portion of the region lies the Balmer basin chemical anomaly, which correlates with extensive plains deposits. Regional maps of the orbital geochemical variables (Mg, Al, Fe, Ti, and Th) are examined individually, then correlated to one another and to the most recent geological map of the region. Results of the study indicate the presence of basalt components, which show considerable variation in character and which are correlated with both mare and plains features in a region otherwise dominated by ANT suite material. The northeastern area is the most characteristically anorthositic part of the region and mare plains deposits from this area have relatively anorthositic composition. A basalt intermediate in composition between mare basalt and Fra Mauro basalt is proposed as a probable component of the Balmer plains deposits. Southeastern Crisium basalts, and the parts of other mare deposits that are distributed along a structurally-related ring have a similar character. The major basalt deposits around the eastern part of Fecunditatis appear to have a different character. All deposits, particularly those in the northeastern area, appear to be mare basalt contiminated with ANT suite material from the surrounding highlands. In general, the surface geochemistry of the Undarum/Spumans/Balmer region is quite heterogeneous, showing a distinct north/south dichotomy.     

Compositional and lithological diversity among brecciated lunar meteorites of intermediate iron concentration

Abstract— We present new compositional data for 30 lunar stones representing about 19 meteorites. Most have iron concentrations intermediate to those of the numerous feldspathic lunar meteorites (3–7% FeO) and the basaltic lunar meteorites (17–23% FeO). All but one are polymict breccias. Some, as implied by their intermediate composition, are mainly mixtures of brecciated anorthosite and mare basalt, with low concentrations of incompatible elements such as Sm (1–3 μg/g). These breccias likely originate from points on the Moon where mare basalt has mixed with material of the FHT (Feldspathic Highlands Terrane). Others, however, are not anorthosite‐basalt mixtures. Three (17–75 μ/g Sm) consist mainly of nonmare mafic material from the nearside PKT (Procellarum KREEP Terrane) and a few are ternary mixtures of material from the FHT, PKT, and maria. Some contain mafic, nonmare lithologies like anorthositic norites, norites, gabbronorites, and troctolite. These breccias are largely unlike breccias of the Apollo collection in that they are poor in Sm as well as highly feldspathic anorthosite such as that common at the Apollo 16 site. Several have high Th/Sm compared to Apollo breccias. Dhofar 961, which is olivine gabbronoritic and moderately rich in Sm, has lower Eu/Sm than Apollo samples of similar Sm concentration. This difference indicates that the carrier of rare earth elements is not KREEP, as known from the Apollo missions. On the basis of our present knowledge from remote sensing, among lunar meteorites Dhofar 961 is the one most likely to have originated from South Pole‐Aitken basin on the lunar far side.     

Major and trace element chemistry of Boulder 1 at Station 2, Apollo 17

Twenty-seven samples of matrix and clast materials from Boulder 1 at Station 2, Apollo 17 have been analyzed for major and trace elements as part of the study of this boulder by Consortium Indomitabile. Both unusual and common types of material have been characterized. Gray and black competent breccia (GCBx and BCBx) and anorthositic breccia (AnBx) have compositions which are common at the Apollo 17 site and were common at the site of boulder formation. Light friable breccias (LFBx) have compositions which are not found at the Apollo 17 site other than in the boulder. Pigeonite basalt is a new type of lunar rock and has characteristics that would be expected of a highland volcanic rock. It is associated with LFBx material, and like LFBx material it is exotic to the Apollo 17 site. Coarse norite is an old primitive rock which is no longer (if ever) found as millimeter fragments at the Apollo 17 site. It was, however, present as millimeter fragments associated with GCBx and BCBx materials at the site and time of boulder formation. Therefore the boulder-forming process combined materials from at least two different localities or vertical strata; at least one of these (LFBx) has not been previously sampled and analyzed.     

The Hadley‐Apennine KREEP basalt igneous province

Abstract– We have studied 27 KREEP basalt fragments in six thin sections of samples collected from four Apollo 15 stations. Based on local geology and regional remote sensing data, these samples represent KREEP basalt lava flows that lie beneath the younger, local Apollo 15 mare basalts and under other mare flows north of the Apollo 15 site. Some of these rocks were deposited at the site as ejecta from the large craters Aristillus and Autolycus. KREEP basalts in this igneous province have a volume of 10³–2 × 10⁴ km³. Mineral and bulk compositional data indicate that the erupted magmas had Mg# [100 × molar Mg/(Mg + Fe)] up to 73, corresponding to orthopyroxene‐rich interior source regions with Mg# up to 90. Minor element variations in the parent magmas of the KREEP basalts, inferred from compositions of the most magnesian pyroxene and most calcic plagioclase in each sample, indicate small but significant differences in the concentrations of minor elements and Mg#, reflecting variations in the composition of lower crustal or mantle source regions and/or different amounts of partial melting of those source regions.