Early Mesozoic retrograded eclogite and mafic granulite from the Badu Complex of the Cathaysia Block,South China: Petrology and tectonic implications

The high-grade metamorphic terrane in the Badu region along the northeastern Cathaysia Block in South China preserves retrograded eclogites and mafic granulites. Here we present the petrology, mineral phase equilibria and P-T conditions based on pseudosection computations, as well as zircon U-Pb ages of these rocks. Mineral textures and reaction relationships suggest four metamorphic stages for the retrograded eclogite as follows: (1) eclogite facies stage (M1), (2) clinopyroxene retrograde stage (M2), (3) amphibole retrograde stage (M3), and (4) chlorite retrograde stage (M4). For the mafic granulite, three stages are identified as: (1) plagioclase-absent stage (M1), (2) granulite facies stage (M2) and (3) amphibolite facies stage (M3). Metamorphic evolution of both of the rock types follows clockwise P-T path. Conventional geothermometers and geobarometers in combination with phase equilibria modelling yield metamorphic P-T conditions for each metamorphic stage for the eclogite as 500–560 °C, 23–24 kbar (M1), 640–660 °C, 14–16 kbar (M2), 730–750 °C, and 11–13 kbar (M3). The chlorite retrograde stage (M4) is inferred to have occurred at lower amphibolite to greenschist facies conditions. Phase equilibria modelling of the mafic granulite shows P-T conditions for each metamorphic stage as 600–720 °C, > 13 kbar (M1) and 860–890 °C, 5–6 kbar (M2) and M3 at amphibolite facies conditions. LA-ICPMS zircon U-Pb dating and trace element analysis show that the high pressure metamorphism occurred at 245–251 Ma. Protolith age of the mafic granulite is 997 Ma, similar to that of the mafic to ultramafic rocks widely distributed in the Cathaysia Block and also along the Jiangnan belt. Subduction of ancient oceanic lithospheric materials (or crustal thickening) during Mesozoic and formation of eclogites suggest that the Cathaysia Block was perhaps in the Tethyan oceanic domain at this time. The granulite formation might have been aided by Mesozoic mafic magma underplating associated with lithospheric delamination, heating and retrogression of the eclogite accompanied by rapid uplift.     

The youngest eclogite in central Himalaya: P–T path,U–Pb zircon age and its tectonic implication

Relict omphacite inclusions have been discovered in mafic granulite at Dinggye of China, confirming the existence of eclogite in central Himalayan orogenic belt. Detailed petrological studies show that relict omphacite occur as inclusions in both garnets and zircons, and the peak mineral assemblage of eclogite-facies should be garnet, omphacite, rutile, muscovite and quartz which was strongly overprinted by granulite-facies minerals during the exhumation. Phase equilibria modeling and associated geothermometer predict that the minimum P–T conditions for peak eclogite-facies stage are 720–760 °C and 20–21 kbar, and those of overprinted granulite-facies are 750 °C and 7–9 kbar in water-undersaturated condition. Thus, a near isothermal decompression P–T path for central Himalayan eclogite has been obtained. Zircon SHRIMP U–Pb dating of two studied eclogite samples at Dinggye yields the peak metamorphic ages of 13.9 ± 1.2 Ma and 14.9 ± 0.7 Ma, respectively, which indicates that the Dinggye eclogite should be the youngest eclogite in Himalayan orogenic belt. Geochemical characteristics and zircon analyses show that the protoliths of eclogite in Dinggye are predicted to be continental rift-related basaltic rocks. The eclogite at Dinggye in central Himalaya should be formed by the crustal thickening during the long-lasting continental overthrusting by Indian plate beneath Euro-Asian continent, and its exhumation process may be related with channel flow and orogen-parallel extension. In the middle Miocene (~ 14 Ma), Indian continental crust had reached at least ~ 65 km depth in southern Tibet.     

High-temperature,high-pressure granulites (retrogressed eclogites) in the central region of the Lewisian,NW Scotland: Crustal-scale subduction in the Neoarchaean

Eclogites and associated high-pressure (HP) rocks in collisional and accretionary orogenic belts preserve a record of subduction and exhumation, and provide a key constraint on the tectonic evolution of the continents. Most eclogites that formed at high pressures but low temperatures at > 10–11 kbar and 450–650 °C can be interpreted as a result of subduction of cold oceanic lithosphere. A new class of high-temperature (HT) eclogites that formed above 900 °C and at 14 to 30 kbar occurs in the deep continental crust, but their geodynamic significance and processes of formation are poorly understood. Here we show that Neoarchaean mafic–ultramafic complexes in the central granulite facies region of the Lewisian in NW Scotland contain HP/HT garnet-bearing granulites (retrogressed eclogites), gabbros, lherzolites, and websterites, and that the HP granulites have garnets that contain inclusions of omphacite. From thermodynamic modeling and compositional isopleths we calculate that peak eclogite-facies metamorphism took place at 24–22 kbar and 1060–1040 °C. The geochemical signature of one (G-21) of the samples shows a strong depletion of Eu indicating magma fractionation at a crustal level. The Sm–Nd isochron ages of HP phases record different cooling ages of ca. 2480 and 2330 Ma. We suggest that the layered mafic–ultramafic complexes, which may have formed in an oceanic environment, were subducted to eclogite depths, and exhumed as HP garnet-bearing orogenic peridotites. The layered complexes were engulfed by widespread orthogneisses of tonalite–trondhjemite–granodiorite (TTG) composition with granulite facies assemblages. We propose two possible tectonic models: (1) the fact that the relicts of eclogitic complexes are so widespread in the Scourian can be taken as evidence that a > 90 km × 40 km-size slab of continental crust containing mafic–ultramafic complexes was subducted to at least 70 km depth in the late Archaean. During exhumation the gneiss protoliths were retrogressed to granulite facies assemblages, but the mafic–ultramafic rocks resisted retrogression. (2) The layered complexes of mafic and ultramafic rocks were subducted to eclogite-facies depths and during exhumation under crustal conditions they were intruded by the orthogneiss protoliths (TTG) that were metamorphosed in the granulite facies. Apart from poorly defined UHP metamorphic rocks in Norway, the retrogressed eclogites in the central granulite/retrogressed eclogite facies Lewisian region, NW Scotland have the highest crustal pressures so far reported for Archaean rocks, and demonstrate that lithospheric subduction was transporting crustal rocks to HP depths in the Neoarchaean.     

P-T evolution of metapelites from the Bajgan complex in the Makran accretionary prism,south eastern Iran

The Bajgan Complex, one of the basement constituents of the arc massif in Iranian Makran forms a rugged, deeply incised terrain. The complex consists of pelitic schists with minor psammitic and basic schists, calc silicate rocks, amphibolites, marbles, metavolcanosediments, mafic and felsic intrusives as well as ultramafic rocks. Metapelitic rocks show an amphibolite facies regional metamorphism and contain garnet, biotite, white mica, quartz, albite ± rutile ± apatite. Thermobarometry of garnet schist yields pressure of more than 9 kbar and temperatures between 560 and 675 °C. The geothermal gradient obtained for the peak of regional metamorphism is 19 °C/km, corresponding to a depth of ca. 31 km. Replacement of garnet by chlorite and epidote suggest greenschist facies metamorphism due to a decrease in temperature and pressure through exhumation and retrograde metamorphism (370–450 °C and 3–6 kbar). The metapelitic rocks followed a ‘clockwise’ P–T path during metamorphism, consistent with thermal decline following tectonic thickening. The formation of medium-pressure metamorphic rocks is related to presence of active subduction of the Neotethys Oceanic lithosphere beneath Eurasia in the Makran.     

Variable P–T paths and HP-UHP metamorphism in a Precambrian terrane,Gridino, Russia: Petrological evidence and geodynamic implications

The Gridino Complex represents one of the oldest eclogite-facies terranes on Earth. It consists of blocks, boudins and lenses of eclogites, pyroxenites, and epidosites as well as deformed eclogitized dikes within biotite-amphibole gneisses. Detailed petrological studies of the pyroxenites and different types of eclogites reveal considerable diversity in metamorphic pressure (P) – temperature (T) conditions (from 1.3 GPa at 660 °C to 3.0 GPa at 660 °C) and fluid regimes (wet vs. dry) experienced by these rocks. Dike-related rocks escaped prograde metamorphism and reached higher pressures than the lenses and blocks that experienced considerable prograde metamorphic reworking. The variability in P–T conditions and the shapes of P–T paths are in agreement with the results of thermomechanical modeling and data from (U)HP metamorphic rocks exhumed during continent–continent collision in the Phanerozoic. The T/P ratio estimated for an eclogitized dike from Eclogitovii Island of the Gridino Complex corresponds to the gradients of < 350 °C/GPa attributed to high-pressure (HP)–ultrahigh-pressure (UHP) metamorphic belts, which are often considered as representative of modern style plate tectonics operating in the Phanerozoic Eon. The data presented in this paper suggest that occurrences of HP-UHP metamorphic terrains might be extended back towards the time of either the assembly of Columbia in the Paleoproterozoic or Kenorland in the Neoarchean.     

Metamorphic P–T path of mafic granulites from Eastern Hebei: Implications for the Neoarchean tectonics of the Eastern Block,North China Craton

This study documents the metamorphic evolution of mafic granulites from the Eastern Hebei Complex in the Eastern Block of the North China Craton. Mafic granulites from Eastern Hebei occur as boudins or enclaves within Neoarchean high-grade TTG gneisses. Petrographic observations reveal three characteristic metamorphic mineral assemblages in the mafic granulites: the pre-peak hornblende + plagioclase + ilmenite + quartz + sphene assemblage (M₁) existing as mineral inclusions within coarse-grained peak assemblage (M₂) represented by garnet + clinopyroxene + orthopyroxene + plagioclase + hornblende + ilmenite + quartz, and post-peak assemblage (M₃) marked by garnet + quartz ± ilmenite symplectites surrounding the peak pyroxene and plagioclase. Based on pseudosection modeling calculated in the NCFMASHTO model system using the program THERMOCALC, P–T conditions of the pre-peak (M₁), peak (M₂) and post-peak (M₃) assemblages are constrained at 600–715 °C/6.0 kbar or below, 860–900 °C/9.6–10.3 kbar, and 790–810 °C/9.6–10.4 kbar, respectively. These P–T estimates, combined with their mineral compositions and reaction relations, define an anticlockwise P–T path incorporating isobaric cooling subsequent to the peak medium-pressure granulite-facies metamorphism for the mafic granulites from Eastern Hebei. Such an anticlockwise P–T path suggests that the end-Neoarchean metamorphism of the Eastern Hebei Complex correlated closely with underplating and intrusion of voluminous mantle-derived magmas. In conjunction with other geological considerations, a mantle-plume model is favored to interpret the Neoarchean tectonothermal evolution of the Eastern Hebei Complex and other metamorphic complexes in the Eastern Block. The prograde amphibolite-facies metamorphism (M₁) was initiated due to the upwelling of the relatively cooler mantle plume head, followed by the peak medium-pressure granulite-facies metamorphism (M₂) as triggered by the uprising hotter plume “tail”, and finally when plume activity ceased, the heated metamorphic crust experienced nearly isobaric cooling (M₃).     

Structural events and metamorphic consequences in Almora Nappe,during Himalayan collision tectonics

Almora Nappe in Uttarakhand, India, is a Lesser Himalayan representative of the Himalayan Metamorphic Belt that was tectonically transported over the Main Central Thrust (MCT) from Higher Himalaya. The Basal Shear zone of Almora Nappe shows complicated structural pattern of polyphase deformation and metamorphism. The rocks exposed along the northern and southern margins of this nappe are highly mylonitized while the degree of mylonitization decreases towards the central part where the rocks eventually grade into unmylonitized metamorphics.Mylonitized rocks near the roof of the Basal Shear zone show dynamic metamorphism (M₂) reaching upto greenschist facies (～450 °C/4 kbar). In the central part of nappe the unmylonitized schists and gneisses are affected by regional metamorphism (M₁) reaching upper amphibolite facies (～4.0–7.9 kbar and ～500–709 °C). Four zones of regional metamorphism progressing from chlorite–biotite to sillimanite–K-feldspar zone demarcated by specific reaction isograds have been identified. These metamorphic zones show a repetition suggesting that the zones are involved in tight F₂ – folding which has affected the metamorphics. South of the Almora town, the regionally metamorphosed rocks have been intruded by Almora Granite (560 ± 20 Ma) resulting in contact metamorphism. The contact metamorphic signatures overprint the regional S₂ foliation. It is inferred that the dominant regional metamorphism in Almora Nappe is highly likely to be of pre-Himalayan (Precambrian!) age.     

Geochemistry,provenance, and metamorphic evolution of Gabal Samra Neoproterozoic metapelites,Sinai, Egypt

Metapelites are exposed at Wadi Ba’ba, east of Abu Zenima city; represent the northwestern extension of the Fieran-Solaf Metamorphic Complex, Sinai Peninsula, Egypt. The metapelites are characterized by qtz + pl (An_24–28) + bt + grt ± crd ± sil mineral assemblage, indicating upper amphibolite facies with peak metamorphic conditions of 700 °C and pressures of 7 kbar, as determined by conventional geothermobarometeric methods. This resulted in incipient migmatization, forms patches of leucosomes and melanosomes. Geochemical investigation indicates that the precursor sediments of the metapelites had been deposited as immature Fe-rich shales from source materials of dominantly intermediate composition. Source area exhibited weak to moderate chemical weathering in a tectonically active continental marginal basin within a continental-arc system. A strong shallow-dipping foliation, characterizing the metapelites, was folded around an open antiform with sub-horizontal south plunging hinge.Phase equilibria calculations in the KFMASH system indicate that the peak metamorphic conditions formed at 730–750 °C and 6.8–7.9 kbar. This was followed by a retrogression formed at 770–785 °C and 3.9–4.5 kbar. Hence, this implies an isothermal decompression and rapid exhumation of the metapelites from depth (25–29 km) in the lower crustal level at peak conditions, continuous to include shallow to middle crustal level (14–17 km), at overprint retrograde conditions. Subsequent isobaric cooling took place at 720–750 °C and 3.6–4.5 kbar. The resulting isothermal decompression followed by isobaric cooling clockwise P–T path of the metapelites is more likely, in which the high-temperatures attained maximum conditions during isothermal decompression were enhanced by heat flux, due to the presence of an active magmatic arc that formed on top of subducting young lithosphere. This is supported by a moderate geothermal gradient of 27–43 °C/km and dating compatibility of the Sinai granitoids and the metamorphic complexes. The P–T path segment records the tectonothermal histories of crustal thickening as a result of the East and West Gondwana collision at the metamorphic peak. This was subsequent by extensional and crustal thinning with syn-metamorphic magmatic intrusions, during P–T path retrogression, which resulted in the final assembly of the Arabian–Nubian Shield during Neoproterozoic.     

Mineral chemical constraints on the petrogenesis of mafic and intermediate volcanic rocks from the Erciyes and Hasandağ volcanoes,Central Turkey

Hasandağ and Erciyes stratovolcanoes, which produced both calc-alkaline and alkaline eruptive products, are the two important volcanic complexes in Central Anatolia. There are three geochemical evolution stages in the history of the Hasandağ strato volcanic complex: (1) Keçikalesi tholeiitic, (2) Hasandağ calc-alkaline and (3) Hasandağ alkaline. Volcanologic and petrologic characteristics of the Hasandağ and Erciyes calc-alkaline series show that water played an important role on the genesis of these rocks. These rocks are phenocryst-rich with vesicular texture, and contain hydrous mineral phases. The approximate pressure and temperature estimates obtained from the mineral chemistry studies of the Hasandağ strato volcanic complex indicate crystallization temperature of 1100 °C with 2.5–3.4 kbar pressure interval for the first stage of Keçikalesi tholeiitic volcanism, and about 850 °C temperatures with 4.3–9.6 kbar pressure intervals for the second stage of Hasandağ calc-alkaline volcanism.The geochemical evolution of Erciyes volcanic complex also exhibits three distinct evolutionary stages: (1) Koçdağ alkaline, (2) Koçdağ calc-alkaline and (3) Erciyes calc-alkaline. The temperature of Koçdağ alkaline volcanism is 1097–1181 °C and in a range of 5.1–6.7 kbar pressure, for Koçdağ calc-alkaline volcanism 850–1050 °C temperature to 2.0–6.6 kbar pressure interval, and for Erciyes calc-alkaline volcanism about 950 °C temperature, to 3.2–7.9 kbar pressure intervals were calculated. Polybaric origin of magma chambers for calc-alkaline and alkaline rocks and disequilibrium parameters observed in phenocrysts indicate that the rocks were affected by magma mixing processes in crustal magma chambers. The disequilibrium features of amphibole and plagioclase phenocrysts in these rocks point the latent heat in magma chambers and periodic recharging with mafic magma chambers and also show that magmas reequilibrate before the eruption.     

Provenance of the Greater Himalayan sequence: Evidence from mafic granulites and amphibolites in NW Bhutan

Mafic granulites and amphibolites in the Masang Kang area of NW Bhutan Himalaya have been investigated for their geochemical and isotopic characteristics in order to determine their protolith history. Bulk-rock major and trace element geochemistry indicate that the rocks were originally tholeiitic and alkali basalts with minor ultramafics. U–Pb zircon SIMS data suggest an age of 1742 ± 39 Ma for mafic magmatism. The age-corrected ε_Nd(1742) values of the rocks are highly variable, ranging from high positive (+ 8.4) to negative (? 3.3). The positive value suggests a primitive magma source, similar to that of rift-related tholeiites. We suggest that the rocks of the Masang Kang suite were produced during a major late Paleoproterozoic thermal event that caused the mobilization and enrichment of the sub-continental lithospheric mantle beneath the north Indian margin. The geochemical signature of these rift-related metabasic rocks may have been produced during an earlier episode of oceanic underplating or subduction from which the fluid required to mobilize and enrich the overlying sub-lithospheric mantle may have been derived. Though their occurrence is rare, Paleoproterozoic igneous rocks within the Greater Himalayan Sequence (GHS), in addition to sources identified throughout the LHS, may have contributed to the detrital zircon population that form the 1.7–1.9 Ga peak in the age spectra of the Lesser Himalayan Sequence (LHS). In addition, the coeval Paleoproterozoic magmatism in both LHS and GHS suggests that the two lithotectonic units may have belonged to the same continental plate at that time period.     

Discovery of an eclogite belt in the Lhasa block,Tibet: A new border for Paleo-Tethys?

A newly discovered eclogite belt in the eastern part of the Lhasa Block, Tibet, is about 500–1000 m wide and at least 60 km long in an E–W direction. The eclogites occur as tectonic slices in garnet-bearing, mica–quartz schist. They are generally fresh and form thick, massive layers that consist chiefly of garnet (Grt) + omphacite (Omp) + phengite (Phe) + rutile (Rut) + quartz (Qtz). P–T calculations based on the Grt–Omp–Phe mineral assemblage yielded peak metamorphic conditions of 2.7 GPa and 730 °C, close to the phase boundary between coesite and quartz and thus the eclogites can be regarded as part of a very high-pressure metamorphic belt. Petrochemical data suggest that the eclogite protoliths were typical MORB basalts, derived from depleted mantle. SHRIMP U–Pb dating of zircons from the eclogite yielded metamorphic ages ranging from 242 ± 15 to 292 ± 13 Ma, with an average value of 262 ± 5 Ma. The MORB eclogites are interpreted to be remnants of Paleo-Tethyan oceanic lithosphere. The eclogites, along with Permian island arc volcanic rocks to the north, are believed to mark a Carboniferous–Permian suture zone dividing the Lhasa Block into a northern and southern segment. This newly identified suture zone suggests that the border of the Paleo-Tethyan Ocean jumped southward from north of the Bangong-Nujiang suture to within what is now the Lhasa Block.     

Systematic changes in metamorphic styles along the Dabie–Hongseong and Himalayan collision belts,and their tectonic implications

Different continental collision belts show contrasting metamorphic trend along their length, including the distribution of extreme metamorphism; i.e., ultrahigh-pressure (>100 km depth) and ultrahigh-temperature (900–1150 °C) metamorphisms. However, no previous study has succeeded in explaining these trends. The present study investigates the main factors that control the metamorphic trends along collision belts, with reference to the Dabie–Hongseong collision belt between the North and South China blocks and the Himalayan collision belt between the Indian and Asian blocks. In the Dabie–Hongseong collision belt, collision began in the east before 245 Ma and propagated westward until ca. 220 Ma. In the eastern part of the belt, the amount of oceanic slab that subducted before collision was insufficient to pull down the continental crust to the depths of ultrahigh-pressure metamorphism; however, ultrahigh-pressure metamorphism occurred in the western part of the belt. Slab break-off also migrated from east to west, with a westward increase in the depth of break-off (from ca. 10 kbar in the west to ca. 35 kbar in the east). These lateral trends along the belt resulted in a westward change from ultrahigh-temperature (915–1160 °C, 9.0–10.6 kbar) to high-pressure (835–860 °C, 17.0–20.9 kbar) and finally ultrahigh-pressure metamorphism (680–880 °C, 30–40 kbar). In the Himalayan collision belt, collision started from the west at 50 Ma and propagated eastward. The amount of oceanic slab subducted prior to collision was sufficient to pull down the continental crust to the depths of ultrahigh-pressure metamorphism in the west, but not in the east. Slab break-off started in the west at ca. 46 Ma and propagated eastward, with an eastward decrease in the depth of slab break-off from 27–29 to 17–18 kbar. Consequently, the metamorphic trend along the belt changes eastward from ultrahigh-pressure (690–750 °C, 27–29 kbar) to high-pressure and finally high-pressure granulite facies metamorphism (890 °C, 17–18 kbar). The differences in metamorphic trend between the Dabie–Hongseong and Himalayan collision belts reflect the amount of oceanic crust subducted prior to collision and the depth and timing of slab break-off along each belt.     

High-pressure and ultrahigh-temperature metamorphism at Komateri,northern Madurai Block,southern India

We report for the first time the evidence for prograde high-pressure (HP) metamorphism preceding a peak ultrahigh-temperature (UHT) event in the northernmost part of the Madurai Block in southern India. Mg–Al-rich Grt–Ged rocks from Komateri in Karur district contain poikiloblastic garnet with numerous multi-phase inclusions. Although most of the inclusion assemblages are composed of gedrite, quartz, and secondary biotite, rare staurolite + sapphirine and spinel + quartz are also present. The X_Mg (=Mg/[Fe+Mg]) of staurolite (0.45–0.49) is almost consistent with that reported previously from Namakkal district in the Palghat–Cauvery Shear Zone system (X_Mg = 0.51–0.52), north of the Madurai Block. The HP event was followed by peak UHT metamorphism at T = 880–1040 °C and P = 9.8–12.5 kbar as indicated by thermobarometric computations in the Grt–Ged rock and associated mafic granulite. Symplectic intergrowth of spinel (X_Mg = 0.50–0.59, ZnO < 1.7 wt.%) and quartz, a diagnostic indicator of UHT metamorphism, probably formed by decompression at UHT conditions. The rocks subsequently underwent retrograde metamorphism at T = 720–760 °C and P = 4.2–5.1 kbar. The P–T conditions and clockwise exhumation trajectory of the Komateri rocks, comparable to similar features recorded from the Palghat–Cauvery Shear Zone system, suggest that the Madurai Block and the Palghat–Cauvery Shear Zone system underwent similar HP and UHT metamorphic history probably related to the continent–continent collision during the final stage of amalgamation of Gondwana supercontinent.     

Counterclockwise tectonometamorphic evolution of the Pringles Metamorphic Complex,Sierras Pampeanas of San Luis (Argentina)

The crystalline basement of the Sierra de San Luis, which belongs to the Eastern Sierras Pampeanas in central Argentina, consists of three main units: (1) Conlara, (2) Pringles, and (3) Nogolí metamorphic complexes. In the Pringles Metamorphic Complex, mafic–ultramafic bodies occur as discontinuous lenses along a narrow central belt concordant with the general NNE–SSW structural trend. A metamorphic gradient from granulite to greenschist facies is apparent on both sides of the mafic–ultramafic bodies. This work focuses on the characteristics of the mylonitization overprinted on the mafic–ultramafic intrusives in the Pringles Metamorphic Complex and their gneissic–migmatitic surroundings, both previously metamorphosed within the granulite facies. Petrogenetic grid and geothermobarometry applied to the paragenesis equilibrated during the mylonitic event, together with mineral deformation mechanisms, indicate that mafic and adjacent basement mylonites developed under upper amphibolite transitional to granulite facies metamorphic conditions at intermediate pressures (668–764 °C, 6.3–6.9 kbar, 0.3 < XCO₂ < 0.7). However, the following mylonitic assemblages can be distinguished from the external limits of the Pringles Metamorphic Complex to its center: lower amphibolite facies ⇒ middle amphibolite facies ⇒ upper amphibolite transitional to granulite facies. Geothermobarometry applied to mylonitic assemblages indicate a temperature gradient from 555 °C to 764 °C and pressures of 6–7 kbar for the mylonitic event. This event is considered to have developed on a preexisting temperature gradient attributed to the intrusion of mafic–ultramafic bodies. The concentration of sulfides in mylonitic bands and textural relationships provide evidence of remobilization of primary magmatic sulfides of the mafic–ultramafic rocks (+PGM) during the mylonitic event. A lower-temperature final overprint produced brittle fracturing and localized retrogression on mafic–ultramafic minerals and ores by means of a water-rich fluid phase, which gave rise to a serpentine + magnetite ± actinolite association. Concordantly in the adjacent country rocks, fluids channeled along preexisting mylonitic foliation planes produced local obliteration of the mylonitic texture by a randomly oriented replacement of the mylonite mineralogy by a chlorite + sericite/muscovite + magnetite assemblage. Observed mineral reactions combined with structural data and geothermobarometry suggest a succession of tectonometamorphic events for the evolution of the Pringles Metamorphic Complex of Sierra de San Luis, developed in association with a counterclockwise P–T–d path. The most likely geological setting for this type of evolution is a backarc basin, associated with east-directed Famatinian subduction initiated in Mid-Cambrian times and closed during the collision of the allochthonous Precordillera terrane in Mid-Ordovician times.     

Neoproterozoic granitic activities in the Xingdi plutons at the Kuluketage block,NW China: Evidence from zircon U–Pb dating,geochemical and Sr–Nd–Hf isotopic analyses

Neoproterozoic igneous rocks are widely distributed in the Kuluketage block along the northern margin of the Tarim Craton. However, the published literature mainly focuses on the ca. 800 Ma adakitic granitoids in the area, with the granites that intrude the 735–760 Ma mafic–ultramafic rocks poorly studied. Here we report the ages, petrography and geochemistry of two granites in the Xingdi mafic–ultramafic rocks, in order to construct a new view of the non-adakitic younger granites. LA-ICP-MS zircon U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 743.0 ± 2.5 Ma for the No.I granite (G1) and 739.0 ± 3.5 Ma for the No.II granite (G2). A clear core-rim texture of similar age and a high zircon saturation temperature of ca. 849 ± 14 °C were observed for the No.I granite; in contrast, G2 has no apparent core-rim texture but rather inherited older zircons and a lower zircon saturation temperature of ca. 763 ± 17 °C. Geochemical analysis revealed that G1 is an alkaline A-type granite and G2 is a high-K calc-alkaline I-type granite. Both granites share similar geochemical characteristics of arc-related magmatic rocks and enriched Sr–Nd–Hf isotopes, likely due to their enriched sources or mixing with enriched magma. Whereas G1 and its host mafic rocks form typical bimodal intrusions of the same age and similar Sr–Nd–Hf isotope compositions, G2 is younger than its host mafic rocks and its Sr–Nd–Hf isotope composition indicates a lower crust origin. Although they exhibit arc-related geochemical features, the two granites likely formed in a rift setting, as inferred from thier petrology, Sr–Nd–Hf isotopes and regional tectonic evolution.     

Syn-kinematic emplacement of the Pangong metamorphic and magmatic complex along the Karakorum Fault (N Ladakh)

This paper investigates the age, P–T conditions and kinematics of Karakorum Fault (KF) zone rocks in the NW part of the Himalaya–Karakorum belt. Granulite to greenschist facies assemblages were developed within the KF zone during strike-slip shearing. The granulites were formed at high temperature (800 °C, 5.5 kbar), were subsequently retromorphosed into the amphibolite facies (700–750 °C, 4–5 kbar) and the greenschist facies (350–400 °C, 3–4 kbar). The Tangtse granite emplaced syn-kinematically at the contact between a LT and the HT granulite facies. Intrusion occurred during the juxtaposition of the two units under amphibolite conditions. Microstructures observed within the Tangtse granite exhibit a syn-magmatic dextral S–C fabric. Compiled U–Pb and Ar–Ar data show that in the central KF segment, granulite facies metamorphism occurred at a minimum age of 32 Ma, subsequent amphibolite facies metamorphism at 20–18 Ma. Further shearing under amphibolite facies (650–500 °C) was recorded at 13.6 ± 0.9 Ma, and greenschist-facies mica growth at 11 Ma. These data give further constrains to the age of initiation and depth of the Karakorum Fault. The granulite-facies conditions suggest that the KF, accommodating the lateral extrusion of Tibet, could be at least a crustal or even a Lithosphere-scale shear zone comparable to other peri-Himalayan faults.     

A high-pressure folded klippe at Tehuitzingo on the western margin of an extrusion zone,Acatlán Complex,southern México

High-pressure (HP) rocks at Tehuitzingo, on the western margin of the HP belt within the Paleozoic Acatlán Complex (southern México), occur in a klippe that was thrust over low-grade clastic rocks. The youngest detrital zircon cluster in the low-grade rocks yielded U-Pb ages of 481 ± 16 Ma, which provide an older limit for deposition. The HP rocks are composed of metabasites, serpentinite, granite (482 ± 3 Ma) and mica schist (youngest concordant detrital zircon: 433 ± 3 Ma). The schist and granite are inferred to be high-grade equivalents of lower Paleozoic, low-grade rocks exposed elsewhere in the Acatlán Complex, from which they are inferred to have been removed by subduction erosion. Mineral analyses indicate that the subducted rocks underwent HP metamorphism and polyphase deformation at depths of ~ 50 km (~ 16 kbar and 750 °C: eclogite facies). Subsequent retrogression passed through epidote-amphibolite to greenschist facies, which was synchronous with W-vergent thrusting over the low-grade clastic rocks. Deposition of the low-grade rocks and thrusting are bracketed between either 481–329 Ma (Ordovician-Mississippian), and was followed by F₃ synformal folding. Cooling through ca. 385 °C is indicated by 329 ± 1 and 316–317 ± 2 Ma, ⁴⁰Ar/³⁹Ar muscovite plateau ages in HP rocks, which are 5–17 my younger than those of the adjacent Piaxtla eclogites suggesting younger exhumation. The petrology, P-T conditions and ages of the Piaxtla Suite is consistent with an extrusion channel within the Acatlán Complex along the active western margin of Pangea during the Carboniferous. Detrital zircon populations in the low-grade psammite (ca. 481, 520–650, 720, 750, 815, 890, 1050 and 2750 Ma) and the HP schist (ca. 457–480, 534, 908, 954–1150, 1265, 1845 and 2035 Ma) indicate derivation from the Ordovician Acatlán granitoids, Neoproterozoic Brasiliano orogens, 900–750 Ma Goiás arc (Amazonia), 1–1.3 Ma Oaxaquia, and more ancient sources in Oaxaquia/Amazonia.     

Palaeozoic polymetamorphism in the North Qinling orogenic belt,Central China: Insights from petrology and in situ titanite and zircon U–Pb geochronology

The Qinling orogenic belt experienced multiple phases of orogenesis during the Palaeozoic. Unraveling the timing and P–T conditions of these events is the key to understanding the convergence processes between the South China and the North China Blocks. The Songshugou Complex, located in the southern part of the North Qinling orogenic belt, has registered multistage metamorphism in Palaeozoic, and thus potentially provides insights into the tectonic evolution of the Qinling orogenic belt. In this study, three metabasic rocks (a garnet pyroxenite, a garnet amphibolite and a gneissic amphibolite) from the Songshugou Complex were selected for petrological study and zircon and titanite U–Pb dating. Our results show that the metabasic rocks experienced three metamorphic events during the Palaeozoic. The first metamorphic event (M1) is characterized by high pressure conditions. Two zircon grains in equilibrium with garnet and in absence of plagioclase were recognized from the garnet pyroxenite sample. They yielded Ti-in-zircon temperatures of 660–851 °C at ∼12.0 kbar and a weighted mean age of 498 ± 15 Ma, providing the constraints on the temperature and timing of prograde or peak metamorphism (M1-1). Zircons that are inequilibrium with garnet from the garnet pyroxenite and the garnet amphibolite gave U–Pb ages of 494 ± 9 Ma and 484 ± 4 Ma, and Ti-in-zircon temperatures of 793 ± 33 °C and 738 ± 18 °C, respectively. Thus, these zircons were formed on the retrograde amphibolite-facies conditions at ∼8.0 kbar (M1-2). Titanite inclusions were found in actinolite cores of zoned amphibole from the garnet amphibolite. They yielded a U–Pb age of ∼470 Ma and Zr-in-titanite temperature of 676 ± 23 °C at pressure of ∼7.0 kbar, suggesting that the amphibolite-facies retrogression perhaps persisted to ∼470 Ma.Weakly zoned zircons from the garnet amphibolite and inclusion-free titanites from the garnet pyroxenite gave consistent U–Pb ages of 418 ± 5 Ma and 423 ± 10 Ma, and Ti-in-zircon temperature of 742 ± 26 °C and Zr-in-titanite temperature of 764 ± 18 °C at ∼7.0 kbar, respectively. It is suggested that a heating event (M2) is registered by a subsequent phase of amphibolite-facies metamorphism. The ilmenite-bearing titanite crystals from the garnet pyroxenite yielded a U–Pb age of 352 ± 4 Ma, recording a late thermal event (M3).On the basis of combined petrological and geochronological results, we propose a revised tectonic model for the North Qinling orogeny in Palaeozoic. The high pressure granulites were formed by the northward subduction of the Shangdan oceanic slab and the arc-continent collision at ca. 500 Ma. Their exhumation happened at ca. 494–484 Ma as a result of slab breakoff. Subsequent amphibolite-facies metamorphism dated at ca. 440–420 Ma are coeval with the widespread magmatism in the North Qinling Terrane, which are likely caused by the reinitiation northward-subducted of Shangdan oceanic slab. At ca. 350 Ma, the North Qinling Terrane was likely affected by another thermal overprinting event.     

Mesoarchean convergent margin processes and crustal evolution: Petrologic,geochemical and zircon U–Pb and Lu–Hf data from the Mercara Suture Zone,southern India

The Mercara Shear Zone is sandwiched between the Western Dharwar Craton and the Coorg Block in the Southern Granulite Terrain of India, and is marked by steep gravity gradients interpreted to suggest the presence of underplated high-density material in the lower crust. Here we present geological, petrological and geochemical data, together with zircon U–Pb ages and Lu–Hf isotopes from a suite of metaigneous (TTG-related gneisses, charnockite, metagabbro, mafic granulite) and metasedimentary (quartz mica schist, khondalite, garnet biotite gneiss, kyanite–sillimanite bearing metapelite) rocks from this zone. Geochemical data on the magmatic suite suggests formation through subduction-related arc magmatism, whereas the metasediments represent volcano-sedimentary trench sequences. Phase equilibrium modeling of mafic granulites from the Mercara Shear Zone suggests P–T range of 10–12 kbar at 700 °C to 900 °C. The zircon data yield weighted mean ²⁰⁷Pb/²⁰⁶Pb ages of 3229 ± 80 Ma for metagabbro, 3168 ± 25 Ma for the charnockite, and 3181 ± 20 Ma for the mafic granulite. Ages ranging from 3248 ± 28 Ma to 3506 ± 26 Ma were obtained from zircons in the kyanite/sillimanite bearing metapelite, 3335 ± 44 Ma from khondalite, 3135 ± 14 Ma from garnet biotite gneiss, 3145 ± 17 Ma to 3292 ± 57 Ma from quartz mica schist and 3153 ± 15 Ma to 3252 ± 36 from TTG gneiss. The tightly defined ages of 3.1 to 3.2 Ga from igneous zircons in the magmatic suite suggest prominent Mesoarchean convergent margin magmatism. The timing of high grade metamorphism as constrained from metamorphic overgrowths in zircons is ca. 3.0 Ga which might mark the collisional event between the Western Dharwar Craton and the Coorg Block. Hf isotope features suggest magma derivation mostly from juvenile sources and the Lu–Hf model ages indicate that the crust building might have also involved partial recycling of basement rocks as old as ca. 3.8 Ga. Our study defines the Mercara Shear Zone as a terrane boundary, and possible Mesoarchean suture along which the Coorg Block was accreted to the Western Dharwar Craton. The accretion of these continental fragments might have coincided with the birth of the oldest supercontinent “Ur”.     

Geochemistry and magmatic setting of Wadi El-Markh island-arc gabbro–diorite suite,central Eastern Desert,Egypt

Wadi El-Markh gabbro–diorite complex is composed of pyroxene hornblende gabbros, hornblende gabbros, diorites and quartz diorites. According to their bulk rock geochemistry and mineral chemistry, the gabbroic and dioritic rocks represent fractionates along a single line of descent and crystallized from a calc-alkaline mafic magma. When compared to the primitive mantle, all members of the gabbroic–dioritic rock suite are enriched in the large ion lithophile elements relative to the high field strength elements and display distinctive negative Nb and P₂O₅ anomalies. This signals an arc setting. Fractionation modeling involving the major elements reveals that the hornblende gabbros were generated from the parent pyroxene hornblende gabbros by 61.86% fractional crystallization. The diorites were produced from the hornblende gabbros by fractional crystallization with a 58.97% residual liquid, whereas the quartz diorites were formed from the diorites by 26.58% fractional crystallization. According to geothermobarometry based on amphibole mineral chemistry, the most primitive pyroxene hornblende gabbros crystallized at ～830 °C/～5 kbar. The crystallization conditions of the quartz diorites were estimated at ～570 °C/～2 kbar. In consequence the Wadi El-Markh gabbro–diorite complex represents a single magmatic suite of which fractionates crystallized in progressively shallower levels of an arc crust.